d-

.
0,001%, 810-6 610-7.

S.

(ZnS)

(HgS).

(CdS)
. ,
CdS . ,
(ZnCO3).
.

) .

. ,
:
2ZnS+3O2=2SO2+2ZnO+212
ZnO++88 =+Zn

.
(. . ).
,
.

ZnO

ZnSO 4 ,
.
HgO
1

 :
HgS+O2=SO2+Hg+ 42
,
.

(Zn) (Cd, Hg) .
.
( ) .
:

, / 3

(Hg = 1)

Zn

Cd

Hg

7,1

8,7

13,6

420

321

-39

913

770

357

16

13

.
,
.

.
(. . ), .
,
. , , ,
.
.
.
2

 ,
, .
, Zn Cd , ,
,
. l H2SO4
, , .
. ,
3Hg + 8HNO3 = 3Hg(NO3)2 + 2NO + 42

Zn + 2NaOH = Na2ZnO2 + 2
.
Zn, Cd Hg
. , Zn Cd
, . Zn
Cd ,
. ,
( ) .
,
, Zn Cd.

, .
ZnCdHg .
()
.
ZnO Cd Hg
(CdO) - (HgO) .
. HgO

3

. Zn, Cd Hg ,
, .
[ ()2]

Zn Cd.
(
)
(, Na2ZnO2).
.
.
[Hg(OH)2]
. ,

2NaOH + Hg(NO3)2 = 2NaNO3 + HgO + H2O
.
, .
Zn2+, Cd2+ Hg2+,
. .
ZnCdHg ,
( ) .
(23, H2S . .), ,
. HgCl 2 (
)
.
Cd2+ Hg2+ ( Zn2+)
, 2. ,
Cd Hg ( ), 1
rJ .
4

 [Hg(CN)2],
. , Cd2+ Hg2+ .
Zn
. , Cd Hg
. Zn, Cd Hg
, [3]

2 [ 4 ]

K2[HgJ4].
Zn Cd ,
.
Hg22+,
,
: HgHg.
,
Hg22+.
, Hg 2,
.

[Hg2(NO3)2],

HNO3 :
6Hg + 8HNO3 = 3Hg2(NO3)2 + 2NO + 42
Hg22+ .

.
(
).

Hg2(NO3)2

(Hg2Cl2),
5

.

, :
Hg2Cl2+Cl2 = 2HgCl2

(
Hg2(NO3)2
). ,
,
2HgCl2+SO2+2H2O=H2SO4+Hg2Cl2+21

.