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Refrigeration and air conditioning systems are getting wide applications and
importance in each and every field in todays scenario. The applications of refrigeration
and air conditioning ranges from homes to large industries like shipping. But, these
consume very large amount of energy. Also, these systems contribute heavily in global
warming and ozone layer depletion. So, it is not advisable in todays world.
So, in order to reduce the harmful effects of these systems, some protocols are
generated and updated time to time by United Nations Framework Convention on
Climate Change (UNFCCC), and are compulsory to the countries of the world. Hence, to
achieve the targets of these protocols for increasing the effectiveness of whole
Refrigeration and air conditioning systems the manufacturers of refrigerants are continue
working together toward the goal of reduced environmental impact via reduced emissions
and improved energy efficiency by new types such as,
a) New eco-friendly Refrigerants.
b) Non-conventional Refrigeration and air conditioning methods.
The former refrigerants, which when used in these systems, produces green house gases,
which are should be replaced by non-ozone depleting refrigerants. Also, the energy
conserving refrigeration and air conditioning methods are to be implemented!
The paper reviews some of the environment friendly refrigeration and air
conditioning systems, using new technologies, new medium of heat transfer and also
new parts of the system having less cost and giving high efficiency.
Key words:
Refrigeration, air conditioning, Protocols, refrigerants, solar refrigeration system,
INDEX
Topic
Sr.
no.
1
Introduction
Conclusion
References
1.
Page
no.
Introduction:
The word Refrigerate means to chill or freeze a substance, i.e. to lower its
temperature by removing some of its heat. Thus Refrigeration is a process of removing
heat from a substance and rejecting the heat so removed to the atmosphere which is at a
higher temperature level. Hence, the refrigeration is defined as the science of producing
and maintaining temperature below that of the surrounding atmosphere. Heat always
passes from hot body to cold body until the thermal equilibrium is reached. It means that
continuously extraction of heat from a body whose temperature is already below the
temperature of its surroundings.
Air conditioning means conditioning of air for maintaining specific conditions of
temperature, relative humidity and low dust levels inside an enclosed space. The
conditions to be maintained are governed by the applications. In addition to the control of
temperature and relative humidity, it is necessary to maintain proper air circulation and a
low dust level in the conditioned space.
History:
Many times, stuffs are to be transferred from one place to another. Then these
stuffs may suffer different climates, especially when the distance to be travelled is large.
(E.g. when the goods are to be travelled from one country to another by train or ship).
III.
Aircrafts.
In the aircrafts, both, refrigeration and air conditioning systems are used. In case
of cargo planes, the refrigeration systems, and in case of passenger planes, air
conditioning systems are used, for human comfort.
V.
In offices.
In offices and factories, air conditioning systems is now a common thing. Air
conditioning systems not only provide a comfort zone for employees, but also
increase the work efficiency of them.
In laboratories.
3.2 Refrigerants
Refrigerants are substances with low boiling points and large latent heats, at
pressures above atmospheric pressure, which are used in the refrigeration systems as a
working fluid.
Refrigerant is the blood in the refrigeration system. Refrigerant is the substance,
through which, heat transfer takes place in the whole Refrigeration cycle. In the
compressor, the refrigerant vaporizes to high pressure and temperature. In the
condenser, the temperature of the refrigerant reduces, but the pressure remains constant.
Here, the refrigerant is in partially vapor and partially liquid state. In the expansion
device, the pressure of the refrigerant reduces, and the refrigerant is in liquid state now.
In the evaporator, the refrigerant takes the heat from the space to be cooled, and gets
heated again.
These are some important types of refrigerants, which are commonly used in the
existing systems.
1.
2.
3.
4.
5.
CFC Refrigerants
These refrigerants were developed more than 70 years ago and are harmful to our
respiratory systems and the ozone layer. Their production was stopped since 1995 but
is still being used widely in existing residential air conditioning units as many types of
equipment have a lifetime of up to 30 years. Todays refrigerants used are from
reclaimed units that are no longer in operation. The common ones still used are:
R-11
Trichlorofluoromethane
R-12
Dichlorodifluoromethane
R-113
Trichlorotrifluoroethane
R-114
Dichlorotetrafluoroethane
R-115
Chloropentafluoroethane
HCFC Refrigerants
These air conditioner refrigerants are considered partially halogenated as they
consists of methane or ethane in combination with chlorine and fluorine. They are
shorter lifespan and are less destructive to the ozone layer compared to CFCs. They are
an interim solution to a totally free from chlorine refrigerant that are being
developed. Their production is scheduled to be phased out totally in 2030. The common
ones used are:
R-22
Chlorodifluoromethane
R-123
Dichlorotrifluoroethane
R-22 is used extensively in residential, commercial and industrial applications. The
schedule of phase-out:
2015 Production freeze and use limitations
2020 Prohibited for new air conditioning and refrigeration use
2030 Total phase-out
HFC Refrigerants
These air conditioner refrigerants contain no chlorine atom and are not destructive
to the ozone layer though they have a slight effect on global warming. R-134a is used in
new systems that are specially designed for its use. The common HFCs are:
R-134a
Tetrafluoroethane
R-124
Chlorotetrafluoroethane
The 1997 Kyoto Protocol puts R-134a as one of the 6 greenhouse gases that must be
reduced. There is no phase-out date for this refrigerant and it is expected to be highly
used in the HVAC industry.
Refrigerant Blends
These air conditioner refrigerants are also known as azeotropic and zeotropic.
Their use is increasing as they are environmental friendly. The setback is that the total air
conditioning systems production cost is higher. However, as more manufacturers switch
to this type of refrigerants, the cost/unit will drop eventually. The common refrigerant
blends used in the air conditioning industry are:
R-410A
R-32/R-125 (50/50)
R-407C
R-32/R-125/R-134a (23/25/52)
R-410A is used as a replacement refrigerant for residential air conditioning applications.
R-407C is used as R-22 replacement.
CFC
HCFC
HFC
LPG
1.0
0.07
7300
1500
1200
The table shows that the LPG refrigerant (R-600a) has zero ozone depletion
potential and a near zero global warming potential. The above values combined with
some of the other properties of LPG refrigerants make them an obvious choice as a
refrigerant in future refrigeration. In fact, countries like Europe and Cuba are already
using hydrocarbon refrigerants in their refrigerators since 1993 and have found no trouble
whatsoever using them.
Translating Table 1 to dollars and cents may help us appreciate the significance of
CFC and HFC GWPs. An Australian proposal for a tax on emitted carbon dioxide of
1.25 $/tone was abandoned in January 1994. Partly because a tax, which adds only 0.2
cents/kWhr to the price of coal, fired electricity would not significantly reduce CO2
emissions. If the global warming contribution of R-134a was taxed at the same rate it
would be 1.5$/kg R-134a which gives R-600a a 3.67$/kg price advantage. Some
governments may do more than tax R-134a to meet their treaty commitments.
refrigeration applications in spite of its being toxic, explosive and flammable within
certain conditions. Ammonia is used as refrigerant prominently in the refrigeration
systems of food industry like dairies, ice creams plants, frozen food production plants,
cold storage warehouses, processors of fish, poultry and meat and number of other
applications.
Properties and Advantages of Ammonia Refrigerant
The working fluid is aqua ammonia solution. The ammonia acts as a refrigerant
and aqua (water) acts as an absorber. In this system, the low pressure ammonia vapour
leaving the evaporator, enters the absorber where it is absorbed by the weak solution
which contains less ammonia.
The water has ability to absorb very large quantity of ammonia vapour and the
strong aqua ammonia solution is formed. The absorption of ammonia vapour in water
lowers the pressure in the absorber, which draws more ammonia vapour from the
evaporator and thus the temperature of solution.
Some form of cooling arrangement is provided in the absorber to remove the heat of
solution evolved there. This is necessity in order to increase the absorption capacity of
water because at higher temperature water absorbs less ammonia vapour.
The strong solution formed in the absorber is pumped to the generator by the liquid
pump which increases the pressure of the solution. The strong solution of aqua ammonia
in the generator is heated by some external source.
During the heating process, the ammonia vapour rises at high pressure leaving
behind the hot aqua ammonia solution in the generator. This weak solution flows back to
the absorber at low pressure after passing through the expansion valve.
The high pressure ammonia vapour from the generator is condensed in the condenser to
high pressure liquid ammonia. This liquid ammonia is passed through expansion valve
and receiver and then to evaporator. This completes the simple vapour absorption system.
4.2 Advanced refrigeration and air conditioning systems
The new refrigeration systems, working on this Vapour Absorption system are proven
very effective in todays world of energy scarcity. The new systems use non conventional
energy resources which lead to production of clean energy. There are two main energy
resources, which are successfully implemented in the refrigeration and air conditioning
systems, viz.
1. Geothermal air conditioning systems.
2. Solar air conditioning systems.
4.2.1 Geothermal air conditioning systems
Introduction
The geothermal system is also called the ground source heat pump. Geo means
earth and thermal refers to heat. In the todays world, it has become a necessity to have
controlled environmental temperatures for many advance processes and also for human
comfort. These systems rely usually on two sources of energy either fuel powered or
electric powered systems. Both of these traditional methods have disadvantages which
could be overcome by using a geothermal system. These two traditional methods of
heating pose a threat to the environment in terms of the emissions they produce to
generate heat or electricity respectively. The first method that is fuel powered direct air
conditioning systems involve burning of fossil fuels such as gas or oil to run the heating
system which immediately throws questions on how feasible it is with respect to
pollution norms. The second option that is electricity controlled air conditioning systems
raises questions on the rising electricity costs and availability in the country like India.
Geothermal air conditioning system todays most energy efficient and lowest
running cost air conditioning system in the world. This system totally changes the way air
conditioning / heating of buildings is conceived at the starting stage and totally removes
the restraints put on architects by the existing cumbersome air conditioning systems.
Working principle
This works on the basic principle that the temperature remains constant below
earth throughout the year irrespective of the temperature above ground. The temperature
below earth is generally constant around 27 Deg. Centigrade to 20 Deg Centigrade at a
depth of 5 to 20 feet below ground depending upon Geographical location and soil
conditions. So, making use of this condition, the earth is used as either source or sump of
heat.
Working
Ground source units are used to pull the heat from the earth and deliver it to
homes/buildings. These heat pumps not only provide heating but also can be used for
cooling purposes. The cooling requires a reverse process wherein heat is derived from the
building and then delivered to the earth. The heating system typically involves closed
loop systems wherein water in the closed loops is made to run through the ground near
the building which absorbs the heat energy under the earth.
This water is pumped back into the building via the closed loop system and thus
heating the building. After the heat is transferred to the building the same water is pushed
back in to the earth and the process is repeated. In the summer time this process is
reversed. This system may also be used to produce electricity. This involves digging
deeper into the earth where the heat energy present is to the extent which could convert
water sent into steam. The working is similar as the water is sent via pipes and the steam
is used to drive large turbines which lead to the production of electricity.
refrigeration system, and delivered to the building space as warm, comfortable heat. The
efficiency of the system is not affected by variations / extremities of weather above
ground. Due to the constant temp below earth the efficiency is enhanced many times with
respect to other available systems which are ultimately dependent on ambient
temperature of outside air for removal of heat. This is the most used system around the
world.
The refrigerant and Absorbent combination is the working fluid. In the absorber,
the absorbent absorbs the refrigerant at low pressure and temperature.
The circulating water with the help of a pump creates a strong solution. This
strong solution sends to generator by pump. This strong solution in generator is heated by
solar hot water system, which increase the temperature of strong solution and vapour
generation and separation starts. The remaining weak solution flows down through heat
exchanger and expansion valve and is throttled in absorber for further cooling.
The vapour formed in generator rises up, and enters in condenser and condenses
to liquid form. This liquid passes through second heat exchanger and rejects heat to cool
refrigerant vapour.
The pressure of the liquid drops in expansion valve before entering the
evaporator. The heat from the application causes evaporation of the liquid refrigerant
causing refrigeration effect and process is repeated.
Passive solar cooling
In this type of cooling solar thermal energy is not used directly to create a cold
environment or drive any direct cooling processes. Instead, solar building design aims at
slowing the rate of heat transfer into a building in the summer, and improving the
removal of unwanted heat. It involves a good understanding of the mechanisms of heat
transfer: heat conduction, convective heat transfer, and thermal radiation, the latter
primarily from the sun.
For example, a sign of poor thermal design is an attic that gets hotter in summer
than the peak outside air temperature. This can be significantly reduced or eliminated
with a cool roof or a green roof, which can reduce the roof surface temperature by around
70 F (40 C) in summer. A radiant barrier and an air gap below the roof will block about
97% of downward radiation from roof cladding heated by the sun.
Solar thermal energy conversion
In this, the solar energy is used to convert the water into the steam, which in turn
runs the turbine. The turbine is connected to the compressor, which is connected to the
condenser and the refrigeration cycle continues.
In this type of air conditioning, the heat energy from the sun is collected on the
solar collector. The water is circulated though this collector. The heat energy, which is
stored in the collector, is given to the water. Due to this, the temperature of the water
increases and it gets converted into steam. This steam is passed over the turbine blades,
causing it to rotate. The turbine shaft is coupled with the rotary compressor shaft, causing
it to rotate. This compressor pumps the refrigerant into the system, and the air
conditioning is achieved.
4.Conclusion
The technological advancement in todays scenario is taking place by keeping in mind
hazardous effect on the mother earth. Therefore, the new technologies of Refrigeration
and Air conditioning are being developed keeping in mind the hazardous effects of
existing systems on the environment in terms of Ozone layer depletion. These new and
environment friendly techniques of Refrigeration and Air conditioning developed are
needs to be implemented effectively. Also, there should be more research on these
technologies so that more eco friendly and economical techniques can be developed.
Also, there should be research on the existing systems so that with small
modifications, their hazardousness can be reduced to minimum level, so that there will
not be any need of replacing the whole system.
5.References
1. Khurmi,Gupta, Refrigeration and Air Conditioning, Ch. Vapour
Absorption Systems, Page no. 238-249. Ch. Refrigerants, Page no. 250269.
2. Domkundwar Arora Domkundwar, Refrigeration and Air Conditioning,
Ch. 10. Non Conventional Refrigeration Systems. Page no. 10.1-10.31.
3. Yogi Goswami, Principals of Solar Engineering Ch. 6. Solar Cooling
and Dehumidification, Page no. 169-210
4. http://www.moef.gov.bd/html/mv_bangladesh/data/india.pdf
5. http://www.energy-concepts.com/isaac