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Reviewed on 06/03/2004
After
2 Hazards identification
Classification of the substance or mixture
GHS07
H332
H315
H319
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
Harmful by inhalation.
Xi; Irritant
R36/38:
Label elements
Labelling according to EU guidelines:
Code letter and hazard designation of product:
Xn Harmful
Risk phrases:
20
Harmful by inhalation.
36/38 Irritating to eyes and skin.
Safety phrases:
9
Keep container in a well-ventilated place.
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
36/37 Wear suitable protective clothing and gloves.
Hazard description:
WHMIS classification
(Contd. on page 2)
USA
DR
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Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
Chemical characterization: Substances
(CAS#) Description:
Trioctyl phosphate (CAS# 78-42-2); 100%
Identification number(s):
EINECS Number: 201-116-6
5 Firefighting measures
Extinguishing media
Suitable extinguishing agents
Use carbon dioxide, extinguishing powder or foam. Water may be ineffective but may be used
for cooling exposed containers.
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Phosphorus oxides
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
DR
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Not determined.
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Sublimation temperature / start:
-90C (-130 F)
216C (421 F) (4mm Hg)
Not determined
Flash point:
216C (421 F)
Not applicable.
Ignition temperature:
Not determined
Decomposition temperature:
Not determined
Auto igniting:
Not determined.
Danger of explosion:
Explosion limits:
Lower:
Upper:
Not determined
Not determined
0.133 hPa
922.76 kg/m
(Contd. on page 4)
USA
DR
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Relative density
Vapour density
Evaporation rate
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
No further relevant information available.
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral
LD50
7600 mg/kg (mam)
12800 mg/kg (mouse)
37 gm/kg (rat)
46 gm/kg (rabbit)
Dermal
LD50
20 gm/kg (rabbit)
Inhalative
LC50/30M 450 mg/m3 (guinea pig)
7600 mg/m3 (mam)
Irritation of skin moderate 250 mg (rabbit)
Irritation of eyes mild
500 mg (rabbit)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Other information (about experimental toxicology):
Tumorigenic effects have been observed on tests with laboratory animals.
Subacute to chronic toxicity:
Inorganic phosphorus compounds may cause irritation and hemorrhages in the stomach as well as
liver and kidney damage. Bone structure may be attacked, especially the jaw and teeth.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully
known.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or
carcinogenic and/or neoplastic data for components in this product.
No classification data on carcinogenic properties of this material is available from the EPA,
IARC, NTP, OSHA or ACGIH.
12 Ecological information
Toxicity
Acquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
(Contd. on page 5)
USA
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13 Disposal considerations
Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
Not a hazardous material for transportation.
DOT regulations:
Hazard class:
None
(cross-border)
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or
mixture
Product related hazard informations:
Hazard symbols:
Xn Harmful
Risk phrases:
20
Harmful by inhalation.
36/38 Irritating to eyes and skin.
Safety phrases:
9
Keep container in a well-ventilated place.
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
36/37 Wear suitable protective clothing and gloves.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
Information about limitation of use: For use only by technically qualified individuals.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
Employers should use this information only as a supplement to other information gathered by
them, and should make independent judgement of suitability of this information to ensure
proper use and protect the health and safety of employees. This information is furnished
without warranty, and any use of the product not in conformance with this Material Safety
Data Sheet, or in combination with any other product or process, is the responsibility of the
user.
Department issuing MSDS: Health, Safety and Environmental Department.
(Contd. on page 6)
USA
DR
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Contact:
Zachariah C. Holt
Global EHS Manager
Abbreviations and acronyms:
ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning
the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
USA