Model Paper 18 em

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BOARD OF INTERMEDIATE EDUCATION

SENIOR INTER CHEMISTRY
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MODEL PAPER (ENGLISH VERSION)

TIME: 3 HOURS
SECTION - A
I.
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MAX.MARKS: 60
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i) Very Short Answer Type questions.
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ii) Answer ALL questions.

ii) Each question carries TWO marks.
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10 2 = 20
1.
What is "Cryoscopic Constant"?
2.
The standard emf of Daniell cell is 1.1 V. Calculate the standard Gibbs energy for the cell reaction.
3.
Zn(s) + Cu+2(aq) Zn+2(aq) + Cu(s)

How does PCl3 react with
d
a
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a) water
b) C2H5OH
4.
H2O is neutral while H2S is acidic. Explain.
5.
What is "misch metal"? Give its composition and use.
6.
7.
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What are "Matte" and "Blister Copper"?
.
a
h
A polymer contains 10 molecules with molecular mass 10,000 and 10 molecules with molecular mass
1,00,000. Calculate number average molecular mass.
b
i
t
8.
What are "thermoplastic polymers". Give 2 examples.
9.
Ortho Nitrophenol is more acidic than Ortho Methoxy Phenol Explain why?
10.
Complete the following conversions:
a
r
p
i) CH3NC + HgO
ii) ? + 2 H2O CH3NH2 + HCOOH
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d
a
SECTION - B
II.
i) Short Answer Type questions.
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ii) Answer any SIX questions.
iii) Each question carries FOUR marks.

11.
6 4 = 24
Describe 2 main types of semi conductors. Classify the following as p-type or n-type semi conductor.
a) Ge doped with In
b) Si doped with B
12.
13.
What are different types of adsorption? Give any four differences between these types.
What is mole fraction? Calculate the mole fraction of Benzene in solution containing 30% by mass in
CCl4.
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NEW SYLLABUS
14.
Write any 2 ores with formulae of the following metals.

a) Al
b) Zn
c) Fe
d) Cu
15.
Explain Werner's theory of coordination compounds with suitable examples.
16.
Write a short note on functions of different hormones in the body.
17.
Write IUPAC names of the following compounds.

a) C2H5NHC3H7
b) PhCH2CN
c)
18.
b
i
t
d)
Br
a
r
p
Br
Explain
a) Antiseptics
b) Food Preservatives
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a
h
CH2NC
NH2
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a
SECTION - C
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III. i) Long Answer Type questions.

ii) Answer any TWO questions.
iii) Each question carries EIGHT marks.
2 8 = 16
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19.
Give a detailed account of the collision theory of reaction rates of bimolecular gaseous reactions.
20.
a) How Cl2 is prepared in laboratory? How does it react with the following.
i) Iron
ii) hot, conc. NaOH
.
a
h
iii) Na2S2O3
b) How are XeO3 and XeOF4 prepared? Describe their molecular shapes.
21.
b
i
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a) Explain the following reactions.

i) Reimer - Tiemann reaction.
ii) Williamson's ether synthesis.
a
r
p
b) What are ambident nucleophiles?

c) What are enantiomers?
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ANSWERS
1.
What is "Cryoscopic constant"?
A:
The depression in freezing point of 1 molal solution.

Tf = Kf. m units of Kf = K kg mol-1
2.
a
h
b
i
t
G = -n F Ecell
= -2 96487 1.1 = -21227 J mol-1
3.
a
r
p
How does PCl3 react with

a) Water
A:
n
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The standard emf of Daniell cell is 1.1 V. Calculate the standard Gibbs energy for the cell
reaction.
Zn(s) + Cu+2(aq) Zn+2(aq) + Cu(s)
A:
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b) C2H5OH
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a
a) PCl3 on reaction with water gives Phosphorous acid

P Cl3 + 3H OH 3 HCl + H3PO3
b) PCl3 on reaction with C2H5OH gives ethyl chloride
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3 C2H5 OH + P Cl3 3 C2H5Cl + H3PO3

4.
H2O is neutral while H2S is acidic. Explain.
A:
The bond dissociation enthalpy of O-H bond is greater than that of S-H bond. So H2O is neutral. H2S
is acidic.
H2S
5.
A:
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2 H+ + S-2
.
a
h
What is misch metal? Give its composition and use.
Misch metal is an alloy of 95% Lanthanoid metal and 5% Iron and traces of S, C, Ca, Al. It is used to
make bullets.
b
i
t
6.
What is "Matte" and "Blister Copper"?
A:
Matte: A mixture of Cu2S (major) and FeS (minor), which is produced when Copper pyrites is heated
in reverberatory furnace along with Silica.
a
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p
Blister Copper: Due to evolution of SO2 gas the surface of Copper gets blisters. So it is called blister
Copper.
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a
2 Cu2O + Cu2S 6 Cu + SO2

7.
A polymer contains 10 molecules with molecular mass 10,000 and 10 molecules with molecular
mass 1,00,000. Calculate number average molecular mass.
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A:
N1M1 + N2M2
(10 10,000) + (10 1,00,000)
Mn = = = 55,000
N1 + N2
10 + 10
8.
What are "thermoplastic polymers"? Give 2 examples.
A:
The polymers having linear structure are formed either by addition or by condensation polymerisation.
Which are soften on heating and hardening on cooling.
e.g.: P.V.C. polyethene
9.
A:
Ortho Nitrophenol is more acidic than ortho methoxy phenol. Explain why?
OH
OH
NO2
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OCH3
n
.
Acid is H+ donor. Methoxy group (-OCH3) is electron releasing group. It prevents the formation of H+
ion. So it decreases acidic nature of phenol.
a
h
Where as nitro group (-NO2) is electron with drawing. So it facilitates the formation of H+ ion. So
ortho nitro phenol is more acidic.
10.
i) CH3NC + HgO
a
r
p
ii) ? + 2H2O CH3NH2 + HCOOH

A:
b
i
t
Complete the following conversations:
i) CH3NC + HgO CH3NCO + Hg
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a
Methyl isocyanate
OHii) CH3NC + 2 H2O
or H3O
11.
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SECTION - B
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Describe 2 main types of semi conductors. Classify the following as p-type or n-type semi
conductor.
a) Ge doped with In
A:
CH3NH2
+ HCOOH
Methyl amine
b) Si doped with B
.
a
h
The process of addition of impurities (13th group or 15th group elements) to the elements (very low
conducting 14th group) in order to increase conductivity is called "doping". 2 types of semiconductors
are formed due to doping. They are
b
i
t
n-type semiconductor: when 15th group element is added to Silicon, 4 covalant bonds will be formed
and 5th electron of 15th group element remains free. As the conductivity of Silicon is increased due to
negatively charged electron (n = negative), it is called n-type semi conductor.
a
r
p
P-type semi conductor: when 13th group elemant is added to Silicon, 3 covalent bonds will be formed
and electron vacancy is formed and forms positive charge (P = positive) it is called p-type semi
conductor
u
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a
Ge doped with In: Ge is 14th group element, It is doped with 13th group element In. So p-type
semiconductor is formed.
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Si doped with B: Si is 14th group element. It is doped with 13th group element B. So p-type semi
conductor is formed.
12.
What are different types of adsorption? Give any four differences between these types.
A:
There are two types of adsorption. They are

1) Physical adsorption
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2) Chemical adsorption.
Physical Adsorption
n
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Chemical adsorption
! It is caused due to weak Van der waals ! It is caused due to strong chemical bonds.
forces.
a
h
b
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! Enthalpy of adsorption is low (20 to 40 ! Enthalpy of adsorption is high (80 + 240

kJ/mol)
kJ/mol)
! It occurs only in one layer.
! It occures in many layers.
a
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! It is irreversible.
! It is reversible.
13.
What is mole fraction? Calculate the mole fraction of benzene in solution containing 30% by mass
in CCl4.
A:
Mole fraction (X): The ratio of number of moles of one component to total number of moles of all the
components in the solution.
u
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n
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No. of moles of the component

Mole fraction of a component =
total no. of moles of all the components in the solution.
30
=
C6H6
78
CCl4
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n
70
=
154
n
.
a
h
C6H6
XC H = Mole fraction of benzene =

n
+n
6 6
C6H6
CCl4
30
78
=
30
70
+
78
154
b
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t
a
r
p
0.385
= = 0.458
0.385 + 0.454
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XCCl = 1 - 0.4589 = 0.5411

4
14.
Write any 2 ores with formulae of the following metals.
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a) Al
A:
b) Zn C) Fe d) Cu
a) Ores of Al: Bauxite - Al2O3.2H2O

Cryolite - Na3AlF6
b) Ores of Zn: Zinc blende = ZnS
Calamine - ZnCO3
c) Ores of Fe: Haematite - Fe2O3

Magnetite - Fe3O4
d) Ores of Cu: Cuprite - Cu2O

Copper pyrites - CuFeS2
15.
Explain Werner's theory of coordination compounds with suitable examples.
A:
Alfred Werner gave satisfactory, explanation to the mechanism of formation of complex compound.
Some of the important postulates are:
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! Every complex compound has central metal atom or ion.
n
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! Central metal atom/ion shows 2 types of valencies

Primary Valence:
a
h
! It is equal to oxidation state of Central metal atom.
b
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! It is ionisable valence.
! It is non directional and represented by -line
! It is satisfied by -ve ions only.
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Secondary Valence:
! It is equal to coordination number of central metal ion.
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! It is satisfied by ligands.
! It is non ionisable valence.
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! It is directional and represented by ..... line.

! It is satisfied by -ve ions as well as neutral molecules.
Cl-
Cl-
Co+3
H3N
Cl
Cl-
.
a
h
Co+3
NH3
Cl-
[Co(NH3)4Cl2]Cl
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n
NH3
NH3
NH3
H3N
Cl-
b
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t
NH3
[Co(NH3)3Cl3]
a
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p
16.
Write a short note on functions of different hormones in the body.
A:
I. Steroid hormones:
u
d
a
A) Sex hormones:
i) Male Sex hormones: Testosterone - deep voice, facial hair.
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ii) Female sex hormones: Estradiol - breast development, long hair, shrill voice.
Control of menstrual cycle.
Progesterone - Preparing uterus for the inplantation of fertilised egg.
B) Cortico Steroids:
i) Glucocorticoids: - Controls carbohydrate metabolism

- modulate inflamatory reactions.
ii) Mineralo Corticoids: - Control the level of excretion of H2O & Salt by the kidney.
Keeps away from Addison's disease
II. Non - Steroid hormones:
i) Peptide hormones: Insulin - decrease the glucose level in the blood.
Glucagon - increase the glucose level in the blood.
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ii) Amino acid derivatives: Thyroxine - keeps away from obesity & hyperthyroidism.
17.
a) C2H5NHC3H7
b) PhCH2CN
a
h
CH2NC
NH2
c)
b
i
t
d)
Br
a
r
p
Br
H
A:
n
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Write IUPAC names of the following compounds.
a) C2H5
N - N - Ethyl propanamine
u
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a
C3H7
CH2CN
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b)
- Phenylethane nitrile
NH2
1
c)
CH2NC
1
- 4 - Bromophenyl methyliso cyanide.
b
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t
3
4
Br
a
r
p
Explain
a) Antiseptics
A:
.
a
h
Br
d)
18.
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- 3 - Bromobenzenamine
b) Food preservatives.
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a
a) Antiseptics: The chemicals which are used to kill or prevent the growth of microorganizams.
e.g.: Soframycin, 0.2% phenol, tincutre of Iodine.
b) Food preservatives: The chemicals which are used to preseve the food from the spoilage due to
microbial growth.
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e.g.: Salt, Sugar, Sodium benzoate, Vegetable Oil.
19.
A:
SECTION - C
Give a detailed, account of the collision theory of reaction rates of bimolecular gaseous reactions.
This theory was proposed by Arrhenius and developed by Max Trautz & William Lewis to explain the
rates of gaseous reactions.
! It is based on kinetic molecular theory of gases.
! According to this theory the reactant molecules are assummed to be hard spheres.
! Collisions must takes place between reactant molecules to occur a reaction.
! Collisions are possible if 2 or more molecules are present.
! The minimum energy must be possessed by the reactant molecules to give products is called
"threshold energy (ET)".
t
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! Molecules having other than threshold energy are called normal molecules.
! Collsions between normal molecules are called "normal collisions", which do not lead the chemical
reaction. Hence products will not be formed.
a
h
! In addition to the normal molecules, the molecules must acquire some extra amount of energy, called
"Activation energy (Ea)".
Ea = ET - ER
b
i
t
a
r
p
Where ER is energy possessed by reactants.
! The molecules possessing threshold energy are called "activated molecules".
u
d
a
! Proper orientation of reactant molecules lead to the bond formation and products are formed.
! Improper orientation makes the molecules bounce back and no products are formed.
CH3 + OH CH3OH + Br
en
Improper
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orientation
+ -
OH No products
H -C- Br
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+ -
H -C- Br + OH
.
a
] bh
i
t
a
H
H
-
+
-
Proper
HO ....... C ....... Br HO - C - H + Br
orientation
H
H
H
Intermediate
Diagram showing molecules having proper and
improper orentation
r
p
! Collisions occuring between activated molecules with proper orientation are called effective
collisions.
u
d
a
! Effective collisions are less in number when compared to normal collisions.

! The number of collisions per second per unit volume of the reaction mixture is known as collision
frequency (Z).
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! Activation energy also effects the rate of a reaction.

! For a bimolecular elementary reaction.
A + B Products
Rate = P. ZAB. e-Ea/RT
ZAB = collision frequency of the reactants A & B.

P = Probability factor
Ea = Activation energy
R = Universal gas constant.
T = Absolute temperature.
! Rate of a reaction is determined by Ea & Proper orientation of the molecules.
Drawbacks:
t
e
! It considers atoms or molecules as hard spheres.
n
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! It ignores structural aspects of the molecules.

20.
a) How Cl2 is prepared in laboratory? How does it react with the following?
i) Iron
ii) hot, conc. NaOH
iii) Na2S2O3
Describe their molecular shapes.

A:
a
h
b
i
t
b) How are XeO3 and XeOF4 prepared?
a
r
p
a) Preparation of Cl2
Lab. method: Cl2 is formed when NaCl is heated with Conc. H2SO4 & MnO2.
4 NaCl + 4 H2SO4 + MnO2 4 NaHSO4 + 2 H2O + MnCl2 + Cl2
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Reactions:
i) With Iron: Cl2 reacts with Fe to form FeCl3
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2 Fe + 3 Cl2 2 Fe Cl3
ii) With hot Conc. NaOH : Cl2 gives Sodium Chloride and Sodium chlorate when reacts with hot
Conc. NaOH
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6 NaOH + 3 Cl2 5 NaCl + NaClO3 + 3 H2O
iii) With Na2S2O3: Cl2 reacts with Na2S2O3 to form precipitated Sulphur.
.
a
h
Na2S2O3 + Cl2 + H2O Na2SO4 + 2 HCl + S
b) XeO3: Complete hydrolysis of XeF6 gives XeO3
..
b
i
t
XeF6 + 3 H2O XeO3 + 6 HF

Xe undergoes sp3 hybridisation.
Xe
ra
The shape of XeO3 is pyramidal.
XeOF4: Partial hydrolysis of XeF6 gives XeOF4
p
u
XeF6 + H2O 2 HF + XeOF4
Xe undergoes sp3d2 hybridisation. The shape of XeOF4 is square pyramidal.

21.
d
a
a) Explain the following reactions.
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O
F
F
Xe
..
i) Reimer - Tiemann reaction.
ii) Williamson's ether synthesis.
b) What are ambident nucleophiles?

c) What are enantiomers.
A:
a) i) Reimer - Tiemann reaction: The reaction in which phenol is heated with CHCl3 and acqueous
NaOH to give salicylaldehyde.
OH
OH
CHO
65C
+ CHCl3 + 3 NaOH
+ 3 NaCl + 2 H2O
salicylaldehyde
ii) Williamsons' Ether synthesis: The reaction between alkyl halide & Sodium alkoxide gives either
symmetrical ether or unsymmetrical ether.
t
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.
C2H5O Na + I C2H5 NaI + C2H5OC2H5.
..
O
..
a
h
..
b
i
t
..
N =O
..
Nitrite :
..
..
..
b) Ambident Nucleophiles: Species having 2 nucleophilic centres are called ambident nucleophiles.
e.g.: Cyanide :
C N
a
r
p
c) Enantiomers: A pair of stereo isomers having non-super imposable mirror images.

CH3
e.g.: H - C - OH
C2H5
CH3
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a
HO - C - H
C2H5
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Writer: A.N.S. Sankara Rao
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www.eenadupratibha.

BOARD OF INTERMEDIATE EDUCATION

MODEL PAPER (ENGLISH VERSION)

i) Very Short Answer Type questions.

ii) Answer ALL questions.

What is "Cryoscopic Constant"?

Zn(s) + Cu+2(aq) Zn+2(aq) + Cu(s)

H2O is neutral while H2S is acidic. Explain.

What is "misch metal"? Give its composition and use.

What are "Matte" and "Blister Copper"?

What are "thermoplastic polymers". Give 2 examples.

Complete the following conversions:

i) Short Answer Type questions.

ii) Answer any SIX questions.

iii) Each question carries FOUR marks.

Write any 2 ores with formulae of the following metals.

Explain Werner's theory of coordination compounds with suitable examples.

Write a short note on functions of different hormones in the body.

Write IUPAC names of the following compounds.

III. i) Long Answer Type questions.

iii) Each question carries EIGHT marks.

ii) hot, conc. NaOH

a) Explain the following reactions.

b) What are ambident nucleophiles?

What is "Cryoscopic constant"?

The depression in freezing point of 1 molal solution.

How does PCl3 react with

a) PCl3 on reaction with water gives Phosphorous acid

b) PCl3 on reaction with C2H5OH gives ethyl chloride

3 C2H5 OH + P Cl3 3 C2H5Cl + H3PO3

H2O is neutral while H2S is acidic. Explain.

What is misch metal? Give its composition and use.

What is "Matte" and "Blister Copper"?

2 Cu2O + Cu2S 6 Cu + SO2

What are "thermoplastic polymers"? Give 2 examples.

ii) ? + 2H2O CH3NH2 + HCOOH

Complete the following conversations:

i) CH3NC + HgO CH3NCO + Hg

There are two types of adsorption. They are

! Enthalpy of adsorption is low (20 to 40 ! Enthalpy of adsorption is high (80 + 240

! It occures in many layers.

No. of moles of the component

XC H = Mole fraction of benzene =

XCCl = 1 - 0.4589 = 0.5411

Write any 2 ores with formulae of the following metals.

a) Ores of Al: Bauxite - Al2O3.2H2O

b) Ores of Zn: Zinc blende = ZnS

c) Ores of Fe: Haematite - Fe2O3

d) Ores of Cu: Cuprite - Cu2O

Explain Werner's theory of coordination compounds with suitable examples.

! Every complex compound has central metal atom or ion.

! Central metal atom/ion shows 2 types of valencies

! It is equal to oxidation state of Central metal atom.

! It is equal to coordination number of central metal ion.

! It is non ionisable valence.

! It is directional and represented by ..... line.

Write a short note on functions of different hormones in the body.

i) Male Sex hormones: Testosterone - deep voice, facial hair.

i) Glucocorticoids: - Controls carbohydrate metabolism

Write IUPAC names of the following compounds.

- 4 - Bromophenyl methyliso cyanide.

e.g.: Salt, Sugar, Sodium benzoate, Vegetable Oil.

Where ER is energy possessed by reactants.