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Neutral
Basic
Amphoteric
xii. Which of the compound has Sp(2) hybridization
NH?
C?H?
C?H?
H?O
xiii. In hydrogen halides, which of the following possess the largest ionic character?
HF
HI
HCl
HBr
xiv. Which atomic orbital is always involved in sigma bonding?
s-Orbital
p-Orbital
d-Orbital
t-Orbital
xv. The colour of light depends upon its
Wave length
Velocity
Source
None
xvi. The rate of diffusion of C?H? and CO? are the same because
They are gases
Both Contain Carbon
Their Molecular Mass are same
C?H? is an Organic Compound
xvii. The molecular formula of Vitamin C is C?H?O?. Its empirical formula is
C?H?O?
C?H?O?
CH?O
CHO?
SECTION B (Short Answer Questions)
Q.2. Answer any TEN questions from this Section. All questions carry equal marks. The answer to each questions
should not exceed 6-8 lines. (40 Marks)
i. Define the following terms
Atomic Number
Empirical Formula
Molecular Formula
Atomic Mass
Significant Figures
Mole
Extensive Properties
Intensive Properties
Avogadros Number
Limiting Reactant
Molar Volume
ii. Describe Rutherfords Atomic Model and state its defects.
OR
Write the postulates of Bohrs Atomic Theory.
OR
Derive an expression for the energy of an electron in nth orbit.
OR
Bohrs radius is 0.529A. Find the radius of 2nd orbit of hydrogen atom.
iii. Define Ionic bond. Explain the formation of ionic bond with the example of Sodium Chloride and give its properties.
OR
What do you understand by the ionic character of a covalent bond with one example?
OR
Define Coordinate Covalent bond and explain it with the formation of (NH??)
iv. An organic compound producing air pollution contains 8.73% carbon 77.45% chlorine and 13.82% fluorine; find the
molecular formula of the compound if its molecular mass is 137.5. (Atomic Masses: C = 12, Cl = 35.5, F = 19)
OR
A 500cm(3) vessel contains 2gm of He and 8gm of CH?. What is the total pressure of the mixture of these gases at
-3C. (Atomic Masses: He = 4, C = 12, H = 1)
v. Give the main postulates of Kinetic Molecular Theory of Gases.
OR
State the following Gas Laws.
Boyles Law
Charles Law
Grahams Law
Daltons Law of Partial Pressure
Avogadros Law
vi. Write the electronic configuration for the ground state Na (Za = 11) and Mg?(2) (Z = 12).
OR
Calculate the wave number of radiation emitted in Lyman series when electron jumps from 2nd to 1st orbit.
vii. Give scientific reasons for the following
a. The rates of diffusion of CO? and C?H? gases are the same.
b. FeSO?.7H?O and ZnSO?. 7H?O are isomorphous.
c. Graphite is very soft where as diamond is very hard.
d. The boiling point of a liquid remains constant although heat is continuously supplied to the liquid.
e. A negative catalyst decreases the rate of reaction.
f. A falling drop of a liquid is always spherical.
g. Ionization potential of oxygen is smaller than that of Nitrogen.
h. Evaporation is a cooling process.
i. Honey is more viscous than water.
j. Zinc dust when reacted with HCl produces hydrogen at a faster rate than a big piece of Zinc.
viii. The equilibrium constant for the reaction N?(g) + O?(g) ? 2NO(g) at 2000C is the initial concentration of N? and
O? are 10 moles/dm(3).
OR
Find the molarity of 0.5gm of NaOH in 250cm(3) of aqueous solution.
OR
The solubility of AgCl at 25C is 1.4 x 10(-3) gm/dm(3). What is its solubility product?
OR
600J of heat was given to a gas at 1.01 x 10? N/m(2) pressure. The initial energy was increased by 300 J; find the
increase in volume.
ix. A 100 cm(3) gas cylinder filled with chlorine under 160 torr pressure is connected by stop-cock with another
cylinder of 400 cm(3) filled with nitrogen under pressure of 200 torr. What will be the total pressure when stop cock is
opened?
OR
Calculate the mass of ZnSO?, the volume of H? and the number of molecules of H? which will be produced by
reacting 163.5gm of Zn with H?SO?, at S.T.P. (Atomic Masses: Zn = 65.4, S = 32, O = 16, H = 1).
x. Explain Evaporation in liquids and Deformity in solids in terms of the Kinetic Molecular Theory.
OR
Differentiate between Crytalline solids and amorphous Solids.
OR
Differentiate between Isomorphism and polymorphism.
OR
What is an Ideal gas? What are the cause of deviation of the real gases from the ideal behaviour?
OR
Determine the General Gas Equation from the gas laws.
xi. What are Cathode Rays? How are they produced? Write down five properties of Cathode Rays along with their
experimental proofs.
OR
What is the relationship between X-Rays and Atomic Number
OR
What is Radioactivity? Describe the experiment to distinguish the three types of radio active radiations.
OR
Write down five properties of each Alpha (?), Beta (?), Gamma (?) rays.
xii. In a reaction A + B ? 2C, 7 moles/dm(3) of B were mixed and allowed to attain equilibrium. If Kc = 2.25; find out
the concentration of A, B and C at equilibrium.
OR
Will PbCrO? precipitate from a solution mixing 200cm(3) of 2.5 x 10?? M Pb(NO?) and 600cm(3) of 1.5 x 10?? M K?
CrO??
xiii. State the First Law of Thermodynamics and Derive the Equations:
a. ?H = ?E = P?V
b. Qp = ?H
c. ?E = Qv
OR
State and explain Hesss Law of Constant Heat Summation.
OR
Give unit cell of a cubic or orthorhombic system.
xiv. What do you understand the term Hybridization? Discuss Sp(3), Sp(2) and Sp hybridization with examples.
OR
Draw the S-orbital and p-orbital.
OR
Write down the names of the spectral lines of hydrogen atom.
OR
Write down the values of all the four quantum numbers for each of the two electrons of helium atom.
xv. Write short notes on following
Viscosity
Electron Affinity
Common Ion Effect
Neutralization
Ionization Potential
Hydrolysis
Electronegativity
Surface Tension
Hydration
Buffer Solution
Vapour Pressure
SECTION C (Detailed Answer Questions)
(28 Marks)
Q.3. (a) Write short notes on the following.
Hydrogen Bonding
pH
Concentration of Solution and its Various Units
Common Ion Effect
Planks Quantum Theory
Molarity
Arrhenius Theory of Ionization
Heat of Formation
Q.3. (b) Define Rate of Reaction, describe the methods to dormine the rate of reaction and also describe the factors
on which the rate of reaction depends?
OR
Differentiate between the following.
Neutral Radioactivity and Artificial Radioactivity
Principal Quantum Number and Azimuthal Quantum Number
Orbit and Orbital
Line Spectrum and Continuous Spectrum
Activation Energy and Threshold Energy
Rate of Reaction and Rate Constant
Positive Catalyst and Negative Catalyst
Q.3. (c) Describe the following rules of electronic configuration.
i. Paulis Exclusion Principle
ii. Aufbau Principle
iii. (n + 1) Rule
iv. Hunds Rule of Maximum Multiplicity
Q.4. (a) For the Chemical reaction F? + 2CIO? ? 2FCIO?, Calculate the rate constant when initial concentration of F?
is 0.1 mol/dm(3), of ClO? is 0.01 mol/dm(3) and the rate of reaction is 1.2 x 10(-3) mol/dm(3) sec.
Q.4. (b) What do you understand by the term Electrode Potential? How is the Electrode Potential of Zinc and Copper
discovered?
OR
Define solubility product and give its examples and applications.
Q.4. (c) Write down the points of Electron Pair Repulsion Theory and Hybrid Orbital anode. Describe the shapes and
structures of CH?, BeCl?, H?O and NH? on the basis of Electron Pair Repulsion Theory.
Q.5. (a) What is Dipole Moment? Explain the shapes of CO? and H?O with the help of Dipole Moment.
OR
State Le-Chatliers Principles. Apply the Principle on Habers Process in terms of pressure and temperature for the
maximum yield of NH?.
N?(g) + 3H?(g) ? 2NH?(g) + Heat
Q.5. (b) State the Law of Mass Action. Derive the equilibrium. Constant Kc for reaction nA + nB ? nC = yD. Apply the
Law of Mass Action on Contact Process to derive its equilibrium expression.
2SO?(g) + O?(g) ? 2SO?(g)
Q.5. (c) Differentiate between the following.
Sp(3) Hybridization and Sp(2) Hybridization
Atomic Orbital and Molecular Orbital
Valence Bond Theory and Molecular Orbital Theory
Polar Covalent Bond and Non-Polar Covalent Bond
Sigma Bond and Pi Bond
Exothermic Reactions and Endothermic Reactions.
Question # 5
Give the basis of the molecular orbital theory and explain the paramagnetic character of O 2
Or
Define orbital. Discuss shape of its two types.
Or
Differentiate between orbit and orbital
Or
What is Atomic Orbital Hybridization? Explain bonding and structure of ethane (C 2H4) on the basis of
hybridization
Or
What is metallic bond? Explain its formation by both electron gas theory and molecular orbital theory
Or
Explain the molecular orbital structures of following molecular on the basis of the MOT
Or
What is hybridization? Discuss sp2 hybridization with example
Question # 6
Prove that i) q = E ii) q = H
Or
Explain enthalpy and prove that H = qP
Or
State first law of thermodynamics. Prove that E = q v
Or
What is enthalpy system and how to measured
Question # 7
The solubility of CaF2 in water at 25 C is 2.0510 mol dm-3. What is the value of Ksp at 25C?
Or
Ca(OH)2 is a sparingly soluble compound. Its solubility product is 6.510 -6. Calculate the solubility of
Ca(OH)2
Or
What is a solubility product? The solubility of CaF 2 in water at 25C is found to be 2.05 x 10 -4 mol dm-3.
What is the value of Ksp at this temperature? (Atomic Mass of Ca = 40, F = 19)
Or
The solubility of PbF2 at 25C is 0.64 g dm-3. Calculate Ksp of PbF2. (Molecular Mass of PbF2 is 245.2)
Question # 8
Describe the electrolysis of concentrated solution of sodium chloride?
Or
What is electrochemical series? Give its any three applications.
Or
Discuss electrolysis processes of industrial importance
Or
Describe the electrolysis of molten sodium chloride and a concentrated solution of sodium chloride
Question # 9
Describe Daltons law of partial pressure. Write its three applications
Question # 10
Explain hydrogen bonding in NH3, H2O and HF. How it is helpful in explaining the structure of ice
Or
Which of the hydrogen halides has the highest percentage of ionic character?
Or
How does hydrogen bonding explain the formation of ice and its lesser density than liquid water?
Or
How does hydrogen bonding explain the formation of ice and its lesser density than liquid water?
Or
Describe the construction and working standard hydrogen electrode (SHE)
Question # 11
How will you describe the paramagnetic character of oxygen on the basis of M.O.T.?
Question # 12
State and explain Grahams Law of diffusion of gases?
Or
Derive Boyles Law and Grahams Law of diffusion of gases on the basis of kinetic molecular theory of
gases
Or
Derive van der Waals equation for real gases with reference to volume correction and pressure correction
in ideal gas equation
Or
How do you differentiate between diffusion and effusion of gases?
Or
Why the volume of gas is generally expressed in g dm -3 rather than g cm-3?
Question # 13
Stat different forms of Raoults law
Or
Give three statements of Raoults law and also mention how Raoults law helps in determining the ideality
of a solution
Question # 14
The unit of rate constant is the same as that of the rate of reaction is:
1.
2.
3.
4.
Question # 15
What is neutron? How was it discovered? Give its two properties.
Question # 16
Define the following giving one example in each:
1.
Enthalpy of solution
2.
Enthalpy of atomization
3.
System
4.
Surrounding
Question # 17
Name various methods for finding order of reaction. Explain half life method for determining order of
reaction
Or
What is order of reaction? Describe two methods for finding order or reaction.
Question # 18
Describe Millikans oil drop method for determination of charge of electron
Or
Question # 28
Differentiate between exothermic reaction and endothermic reaction
Question # 29
Define crystallization and its process
Question # 30
Describe Nickel cadmium cell (rechargeable)
Question # 31
What is the percentage ionization of acetic acid in a solution in which 0.1 moles of it has been dissolved
per dm3 of the solution?
Question # 32
State Le-Chateliers Principle. Describe the effect of change in temperature of a system in equilibrium by
this principle
Question # 33
Define limiting reactant. How it is helpful to control the chemical reaction?
Question # 34
Classify solids on the basis of boning. How ironic solids are formed?
Or
Differentiate between solids gases and liquids gases
State and explain with an example, the Hesss law of constant summation
Or
Write a note on synthesis of ammonia gas by Habers process keeping in mind the applications of
chemical equilibrium in industry
Question # 35
Define buffer solutions. Derive hendersens equation for calculation of pHof an acidic buffer?
Question # 36
Give the main postulates of VSEPR theory
Or
Explain the structure and geometry of BeCL2 and SnCL2 on the basis of VSEPR theory
Or
VSEPR theory demands that lone pair occupies more space than bond pair. Explain with reasons. Also
write the limitations of VSEPR theory?
Question # 37
How does the Arrhenius equation help to determine the energy of activation?
Question # 38
What are the conclusions drawn by Moseley from a detailed analysis of the spectra
.( ) .
One molal solution of glucose is dilute as compared to one molar solution of glucose. Justify it. OR What
is molarity? Calculate the molarity of a solution containing 9 grams of glucose (C61-11206) in 250 cm3 of
solution. OR Define molal boiling constant with an example.
Salt bridge is not required in lead storage call. Why? OR What is the function of salt bridge in galvanic
cell?
Write down reactions taking place at the electrodes on the discharging of Nickle-Cadmium Cell.
Calculate the oxidation number of Cr in K2CrO4 and Cr202-2. OR Find out the oxidation state of Mn in (a)
KMnO4 (ii) K2MnO4. OR Calculate oxidation number of chromium in CrCt3. OR Calculate the oxidation
number of `Mn in KMnO4.
Define and give an example of the process of activation of a catalyst. OR What is poisoning of a catalyst?
Give an example. OR How a catalyst is specific in its action?
N2 and CO have same number of electrons, protons and neutrons. Justify. OR Why N2 and CO have the
same number of protons, electrons and neutrons?
Define the term molecule. Give two examples also. OR Separate the following molecules as polar or nonpolar: (i) CO2 (ii) CH3OH (iii) CC Q4 (iv) HF
What is vapour pressure? OR What is Daltons law of partial pressure? OR Write down the values of
atmospheric pressure in four different units. OR Lowering of vapour pressure is colligative property.
Explain. OR What will be the effect of change of pressure on the synthesis of NH3? OR Derive the units
for gas constant R in general gas equation when pressure is in Nm-2 and volume in m3.
What is the size of atom? OR Why cationic radius radius is smaller than parent atom? OR What are
defects in Rutherfords atomic model? OR Why the radius of an atom cannot be determined precisely?
OR Mg atom is twice heavier than that of carbon atom. Justify. OR Why is the -radius of a cation smaller
than its parent atom? OR The radius of first orbit of hydrogen atom is 0.529 A. Calculate the radius of 31
orbit of hydrogen atom.
What are the defects in Rutherfords atomic model?
Write the electronic configuration of Cr for which atomic number is 24.
Give the chemistry of electrolysis of aqueous solution of sodium chloride. OR Write electrode reactions of
electrolysis of fused sodium chloride.
Define autocatalysis with an example.
Give assumption of stoichiometry.
Why is there a need to crystallize the crude product?
What are isotherms?
Define Avogadros law.
What is common ion effect? Give an example. OR Differentiate between Zeeman effect and stark effect.
OR State Joule Thomson effect. Write its application.
Give statement of Distribution Law.
The electrical condUctivity of metals decrease with the increase in temperature. Why? OR Define upper
consulate temperature with example.
Mention two defects of Bohrs model. OR According to Bohrs model in which orbit electron can move?
How the wave nature of electron was verified experimentally? OR Explain electron gas theory.
Differentiate between homogeneous catalysis and heterogeneous catalysis.
What is difference between qualitative analysis and quantitative analysis?
A weak acid has strong conjugate base. Justify.
Define hydrolysis with example. OR Differentiate between hydration and hydrolysis.
Voltaic cell is reversible cell, State.
What are isotopes? Why they have same chemical but different physical properties?
What is mole? OR Why the sum of mole fractions of all components of a solution is always equal to unity?
What is the basic principle of crystallization?
Define amorphous solids.
Define the octet rule.
Define state of Equilibrium.
Define optimum pH?
What is Lyman series?
Define Balmer series.
What is vaccum distillation?
Define polarizability.
Define unit cell.
Define vander walls equation.
Why is HF a weaker acid than HC1?
Justify that heat of formation of compound is sum of all the other enthalpies.
Calculate the density of methane at STP.
Why regular air cannot be used in divers tank?
What is the first law of thermodynamics?
What are London dispersion forces?
What do you mean by chemical equilibrium?
Give two statements of Raoults law.
Diamond is insulator and hard. Give reason. OR Diamond is hard and an electrical insulator. Give
reason..
State spin quantum number (s) briefly. OR What is Plancks quantum theory?
Cathode rays are material particles. Explain with reason. OR Why of cathode rays is equal to that of
electrons? OR Why the nature of cathode rays is independent of the nature of the gas used in discharge
tube? OR Whichever gas is used in the discharge tube, the nature of the cathode rays remains the same.
Why? OR How the K-series, L-series and M-series of x-rays spectrum are produced? OR Give reason for
the production of positive rays. OR Why value for the cathode rays is just equal to that of electron?
Define ionization energy and write its variation in the periodic table. OR Name the factors which affect the
ionization energy of an element. OR How does ionization energy vary in a group of periodic table? OR
Why ionization energy decreases down the group although the nuclear charge increases? OR Define
electronegativity. Give its trend in the periodic table.
The bond angles of H20 and NH3 are not 109.5 like that of CH4. Although 0-atom and N-atom are SP3
hybridized like C- in CH4, give reason. OR The bond angles of H2O and NH3 are not 109.5 like that of
CH4 although oxygen and nitrogen atoms are SP3 hybridized. Why? OR Explain the term bond order.
OR What is Bond Energy? OR How the nature of a chemical bond is predicted with the help of
electronegativity values of two bonded atoms? OR Why n-bonds are more diffused than a-bonds? OR NH
3 and N F Shave different bond angles. Justify. OR Define coordinate covalent bond and give one
example. OR it-bonds are more diffused than a-bonds. Give reason. OR Define bond order. Calculate
bond order of hydrogen molecule. OR Define bond energy with two parameters which determine its
strength.
The dipole moments of CO2 and CS2 are zero but that of SO2 is 1.61D. OR Why the dipole moment of
SO2 is 1.61 D but that of SO3 is zero? OR What are dipole-dipole forces of attraction? Explain with an
example.
What is the basic assumption of VSEPR theory, and discuss the shape of a molecule (BF3) containing
three electron pairs? OR Write down two postulates of VSEPR theory. OR State the geometry of NH3
molecule on the basis of VSEPR theory.
Define the term state function, give two examples.
Explain the term enthalpy. OR Explain the term enthalpy of atomization. OR The enthalpy of neutralisation
of all the strong acids and strong bases has the same value. Justify. OR State enthalpy of combustion
with example.
State Le-Chateliers principle and discuss the effect of change in concentration of a product on reversible
reaction.
Explain the term buffer capacity. OR What are buffer solutions? How a basic buffer can be prepared? OR
Write two uses of buffer solution.
Give the two applications of the solubility product. OR How the type of bonding affects solubility of
compounds? OR Define solubility product. Give its one application.
Depression in freezing point is a colligative property. Justify. OR Why Beckmanns thermometer is used to
measure the depression in freezing point?
What is meant by molality? Give its formula.
Why the NaCt and KNO3 are used to lower the melting point of ice?
What is electrochemical series? OR How electrochemical series help us in determining the chemical
reactivity of metals?
Lead accumulators is a chargeable battery. Justify. OR What is difference between cell and battery?
Differentiate between average rate and instantaneous rate. OR What is specific rate constant or velocity
constant? OR Why different liquids evaporate at different rates even at the same temperature? OR How
surface area affects the rate of a chemical reaction? OR What happens to the rate of a chemical reaction
with the passage of time?
What are enzymes? Give two examples in which enzymes act as catalyst. OR Enzymes are specific in
action. Justify.
Why theoretical yield is greater than actual yield?
What is mass spectrum? OR Why atomic spectrum isline spectrum? OR Define spectrums. OR What is
the difference between continuous spectrum and line spectrum?
Define empirical formula and molecul1ar formula with example. OR Write four steps for determining
empirical formula. OR Define molecular formula of a compound. How is it related with its empirical
formula? OR What Gram formula?
What is solvent extraction? OR Write down the name of Eight solvent used in crystallization. OR Define
distribution law and how it is helpful in solvent interaction. OR Boiling points of the solvents increase due
to the presence of solutes. Justify it. OR Why is the vapour pressure of a solution less than pure solvent?
Calculate the value of R in SI unit. OR Calculate the value of gas constant It in SI-units.
Give four fundamental postulates of kinetic molecular theory of gases. OR Derive Grahams law of
diffusion in the light of kinetic molecular theory of gases. OR Write two faulty assumptions of kinetic
molecular theory of gases. OR Write down the faulty postulates of kinetic molecular theory of gases. OR
Explain Boyls law according to kinetic molecular theory of gases.
Why one feels sense of cooling under the fan after bath? OR Explain with reason, Evaporation causes
cooling. OR One feels sense of cooling under the fan after bath. Explain with reason.
Write down two applications of liquid crystals. OR Vacuum distillation can be used to avoid decomposition
of a sensitive liquid. Explain with reason. OR How the liquid crystals help in the detection of the blockage
in veins and arteries?
Define isomorphism and polymorphism with example. OR What is the relationship between polymorphism
and allotropy?
Calculate mass of an electfon from its e value. m OR What is mass spectrometer? OR Define relative
atomic mass. OR Define Molar mass. OR State the law of mass action. OR What is Avogadros number?
Give equation to relate the Avogadros number and mass of an element. OR Calculate the mass of
electron when its e/m value is 1.7588 x 101 C OR Calculate fraction of total pressure exerted by oxygen
when equal masses of CH4 and 02 are mixed in an empty container at 25C. OR Calculate mass in kg of
2.6 x 1020 molecules of SO2. OR No individual neon atom in the sample of the element has a mass of
20.18 amu. Explain with reason.
State Heisenbergs Uncertainty Principle and give its mathematical expression.
Define orbital. OR Why the energy of antibonding molecular orbital is higher than corresponding bonding
molecular orbitals? OR Distribute tk electron in orbitals of 29Cu and 26Fe. OR Justify that the distance
gaps between different orbitals go on increasing from the lower to higher orbits. OR Sketch the molecular
orbital picture of 02. OR Define Hydrogen Bonding.
State the Hesss law of constant heat summation. OR Give statement of Hesss law.
Write two applications of equilibribm constant.
Define pH and p0H.
effective knowledge to the readers, in any case our entire team and/or publishers will not be responsible
for the accuracy or misusage of all published material.
.( ) .
(C) 1.84 mg
(D) 1.673mg
0.1 mole of solute dissolved in 100g of the solvent will be
(A) 0.1 molal
(B) 1.0 molal
(C) 0.5 molal
(D) None of these
Solvent extraction method is particularly useful technique for separation when the product to be separated
is
(A) Non-volatile or thermally unstable
(B) Volatile or thermally stable
(C) Non-volatile or thermally stable
(D) Volatile or thermally unstable
Solvent extraction is an equilibrium process and it is controlled by
(A) Law of mass action
(B) Distribution law
(C) The amount of solvent used
(D) The amount of solute
Law of mass action was derived by Gulberg and wage in
(A) 1909
(B) 1906
(C) 1846
(D) 1864
In solvent extraction the law applied is
(A) Law of mass action
(B) Distribution law
(C) Coulombs law
(D) Boyles law
Solvent extraction is a process
(A) Exothermic
(B) Endothermic
(C) Equilibrium
(D) Non-equilibrium
London dispersion forces are the only forces present among the
(A) Molecules of water in liquid state
(B) Atoms of helium in gaseous state at high temperature
(C) Molecules of solid iodine
(D) Molecules of hydrogen chloride gas
The molecules of CO2 in dry ice form the
(A) Ionic crystals
(B) Covalent crystals
(C) Molecular crystals
(D) Any type of crystals
(B) CHC 3
(C) H2O
(D) BF3
An orbital which is spherical and symmetrical is
(A) s-orbital
(B) p-orbital
(A) d-orbital
(A) f-orbital
Quantum number values for 21 orbitals are
(A) n = 2, = 1
(B) n = 1, = 2
(C) n = 1, =0
(D) n = 2, t =0
The four equivalents SP3 hybrid orbitals in space are at an angle of
(A) 120
(B) 107.5
(C) 104.5
(D) 109.5
The nature of positive rays depends on
(A) The nature of electrode
(B) The nature of discharge tube
(C) The nature of residual gas
(D) The temperature
Cathode in NICAD is
(A) Ag2O
(B) N102
(C) Cd
(D) Zn
Cathode rays strike alumina and produce a colour
(A) Red
(B) Blue
(C) Yellow
(D) Green
Positive ions are called
(A) cations
(B) Annions
(C) Molecules
(D) Hydrated ions
The e value for the positive rays is maximum for
(A) Hydrogen
(B) Helium
(C) Oxygen
(D) Nitrogen
Pressure remaining constant at which temperature of the volume Of a gas will become twice of what it is
at 0C
(A) 546C
(B) 200C
(C) 546 K
(D) 273 K
Water may boil at 120C when external pressure is
(A) 369 torr
(B) 700 torr
(C) 760 torr
(D) 1489 torr
Dissolves in water in the presence of KI due to the formation of
(A) 12
(B) 1(C) 13
(D) 14
The mass of one mole of electrons is
(A) 1.008 mg
(B) 0.55 mgV
(C) 0.184 mg
(D) 1.673 mg
One mole of SO2 consists of
(A) 6.02 x 1023 atoms of oxygen
(B) 18.1 x 1023 molecules of SO2
(C) 6.02 x 1023 atoms of sulphur
(D) 4 gram atoms of SO2
The volume of one mole CO2 is maximum at
(A) S.T.P
(B) 127 and 1 atm.
(C) 0C and 2 atm.
(D) 273C and 2 atm.
The number of moles of CO2 which contains 8.0 g of oxygen
(A) 0.25
(B) 0.50
(C) 0.75
(D) 1.0
Percentage of oxygen in water is
(A) 80%
(B) 88.89%
(C) 8.8 %
(D) 9.8%
When water freezes at 0C, its density decreases due to
(A) Empty spaces present in the structure of ice
An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by
filtration. What are the main ions in the filtrate?
(A) Ag+ and Ba2+ and NO3(B) Ag+ and NO3- only
(C) Ba2+ and NO3- only
(D) Ba2+ and NO3- and CeWhich of the following is purified by submission
(A) Naphtalene
(B) Benzoic acid
(C) Ammonium chloride
(D) All of these
If a strip of Cu metal is placed in a solution of FeSO4
(A) Cu will be deposited
(B) Fe is precipitated out
(C) Cu and Fe both dissolve
(D) no reaction occurs
Dry Ice (Solid CO2) is art example of solid
(A) Covalent
(B) Molecular
(C) Ionic
(D) Metallic
Specific rate constant is equal to rate of reaction, when concentration of reactants are
(A) Zero
(B) Four
(C) Three
(D) Unity
In zero order reaction, the rate is independent of
(a) Temperature of reaction
(B) Concentration of reactants
(C) Concentration of products
(D) None of these
The rate of reaction
(A) Increases as the reaction proceeds
(B) Decreases as the reaction proceeds
(C) Remains the same as reaction proceeds
(D) May decrease or increase as the reaction proceeds
The comparative rates at which the solutes move in paper chromatography, depend upon
(A) The size of paper
(B) Rf values of solutes
(C) Temperature of experiment
(D) Size of the chromatographic tank used
Glycerine decomposes at its
(A) Melting point
A real gas obeying van der Waals equation will resemble ideal gas if
(A) Both a and `b are large
(B) Both a and `b are small
(C) A is small and b is large
(D) a is large and b is small
If a and b are zero for certain gas then gas is
(A) Ideal
(B) Real
(C) Non ideal
(D) May be any diatomic gas
Amorphous means
(A) Arranged
(B) Ordered
(C) Shaped
(D) Shapeless
In endothermic reaction tH is taken as
(A) Positive
(B) Negative
(C) Zero
(D) May be any value
In endothermic reactions the heat content of the
(A) Product is more than that of reactantsV
(B) Reactants is more than that of products
(C) Both I and II,
(D) Reactants and products are equal
Which one of the following is a pseudo solid
(A) CaF2
(B) NaCC
(C) Borax
(D) Glass
Standard enthalpies are measured at
(A) 273k
(B) 298k
(C) 373k
(D) All of these
The maximum number of electrons in a sub-shell is given by
(A) 2C+1
(B) 2C1
(C) 2(2C+1)
(D) 2(2C1)
When HCC is added to H2S aqueous solution its ionization
(A) Increases
(B) Decreases
.( ) .
Describe Millikans Oil Drop Method for the measurement of charge on electron.
Describe the construction and the working of standard hydrogen electrode. OR What is standard
hydrogen electrode (SHE)? How it is used to measure the electrode potential of zinc?
Give three statements of Raoults law and also mention how Raoults law helps in determining the ideality
of a solution. OR Explain Raoults law when both components in the solution. OR State and explain
Raoults law in three forms.
How does the Arrhenius equation help us to calculate the energy of activation of a reaction?
What are ionic solids? Give their properties in detail. OR What are molecular solids? Write their
properties. OR What are molecular solids? Give examples and explain their properties.
Calculate the number of grams of At2S3 which can be prepared by the reaction of 20g of At and 30g of
sulphur. How much the notAimiting reactant is in excess?
What is crystallization? Explain all steps of crystallization.
A mixture of two liquids, hydrazine, N2H and N20 are used in rockets. They produce N2 and water
vapours. How many grams of N2 gas will be formed by reacting 100g of N2H and 200g of N20.
Define electron affinity. Name the factors affecting it. How does it vary in the periodic table?
Where is plasma found? Write few applications of plasma.
Define enthalpy of reaction. How is it measured by glass calorimeter? OR Define enthalpy of
neutralization. Also discuss glass calorimeter in detail.
Describe Linds method for the liquefaction of gases.
Describe the electrolysis of molten sodium chloride and a concentrated solution of sodium chloride.
Define electrode potential. Describe the construction of voltaic cell and reaction occurring in the cell. OR
Explain the term: (i) half life period (ii) order of reaction. OR Write the electrochemical reactions involved
therein. OR N2 (g) , and H2 (g) combine to give NH3 (g). The value of Kc in this reaction is 6.0 x 10-2.
Calculate the value of Kp for this reaction. OR How rate of reaction depends upon the following factors (i)
Nature of reactants (ii) Surface area.
What are liquid crystals? Give three uses in daily life.
What is hybridization? Discuss sp2 hybridization with example. OR Explain structure of CH on the basis
of hybridization theory.
What is electrochemical series? Give its applications.
What are buffer solution? Why do we need them in daily life.
What are azeotropic mixtures? Explain them with the help of graphs.