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the Solvent Bonding and the Ink-jet Printing using Water-based Ink
H. Kanazawa, A. Inada and Y. Yamaguchi
Department of Industrial Systems, Faculty of Symbiotic Systems Science,
Fukushima University, 1 Kanayagawa, Fukushima 960-1296, Japan
kana@sss.fukushima-u.ac.jp
1
Introduction
Experimental
2.1 Materials
Polymeric materials of films, sheets, fibers, boards,
rods and tubes were used after washing in methanol.
Commercial hydrophilic monomers, polymers and reagents were used after a simple purification.
2.2 Treatment
The present method is composed of two processes, an
activation process and a chemical reaction process. It is
named as KANA-USA method. First, polymeric materials
were activated by old oxidation methods or energy irradia-
2.3 Measurements
2.3.1 Adhesive polyvinylpyrrolidone (PVP), starch, a
woodwork bond (polyvinylacetate (PVAC)-water mixture :
Konishi Co. Jp), cyanoacrylate adhesive (CA; Aron alpha:
Toa Gosei Kagaku Co.), epoxy resin adhesive (Quick 5 ;
mixture of epoxy resin and polythiol, Konishi Co. Ltd.), a
cyanoacrylate-primer set (Cemedine PPX; primer : organic
amine 1% and heptane 99%; Cemedine Co. Ltd.), etc. were
used.
2.3.2 Adhesion strength a tensile shear bond strength test
and a T peel test were carried out using a Shimadzu
AGS-H5KN.
2.3.3 IR spectra polymeric materials were observed by a
Shimadzu IRPrestige-21 equipped with a Smiths DuraSampl IR II (ATR accessory).
2.3.4 Paints Commercial water-based paints (Asahipen,
Co. Ltd., Japan) which contain synthetic resins (acrylic,
silicone and fluorocarbon resins), pigments and organic
solvents, and water-based urethane car-use paints were
used.
2.3.5 Solvent bonding Modified polymeric material tubes
were coated with normal organic solvents, and they were
connected to each other, and the tubes were laid for several
minutes, and the solvent bonding was finished.
2.3.6 Printing An inkjet printing of modified materials
was carried out by a commercial ink-jet printer with water-based ink.
Scheme 1
Conclusions
The present method gave the improvement in the adhesion, painting and printing properties of chemically stable
polymeric materials. The modified property is durable as
compared with usual corona or plasma discharges.The
modified polymeric materials are useful in many fields and
for preparing new FRP.
Reference