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Note
Department of Engineering, High Politechnic College, University of Almera, La Caada de San Urbano s/n, 04120 Almera, Spain
Department of Civil, Structural and Environmental Engineering, Trinity College Dublin, Dublin, Ireland
Institute of Materials Science of Sevilla (ICMS), Joint Center of the Spanish National Research Council (CSIC) and University of Sevilla (US), c/Amrico Vespucio 49, 41092-Sevilla, Spain
a r t i c l e
i n f o
Article history:
Received 13 November 2015
Received in revised form 26 January 2016
Accepted 27 January 2016
Available online 3 February 2016
Keywords:
Phyllite clays
Lime
Compaction
Permeability
Plasticity
Road subgrade
a b s t r a c t
This paper represents a new advance in the study of engineering properties and material applications of phyllite
clays. Considering their potential use as construction materials for structures subjected to low stress levels, this
laboratory research investigated the stabilization and improvement in engineering properties of a Spanish
phyllite clay achieved by the addition of 3, 5 and 7 wt.% lime. Geotechnical properties investigated include the
consistency limits, compaction, California Bearing Ratio, swelling potential and water-permeability. The phyllite
claylime mixtures had good compaction properties and very to extremely low permeability-coefcient values,
with a semi-logarithmic correlation between increasing permeability and increasing proportion of lime additive.
The addition of 3 wt.% lime was sufcient to reach the index of capacity amble specied in the Sheet of Technical
General Prescriptions for Works of Roads and Bridges PG3 (Spanish Highways Agency, 2008), signicantly reducing the plasticity index value, with the compacted mixture undergoing no swelling under soakage. The required pavement thicknesses for the raw phylliteclay material and the phyllite claylime mixtures are
compared and discussed. Potential applications for phyllite claylime mixtures include for pavements/road subgrade, earth construction, building materials and for impermeabilization purposes.
2016 Elsevier B.V. All rights reserved.
1. Introduction
Well established soil improvement and stabilization techniques for
clayey soils by the addition of cementing agents (e.g. lime, cement, asphalt, coal waste, ash, etc.) are often used to obtain engineering materials having superior properties/performance (Attom and Al-Shariff,
1998; Basha et al., 2005; Castro-Fresno et al., 2011; Di Sante et al.,
2014; George et al., 1992; Gidley and Sack, 1984; Kamon and
Nontananandh, 1991; Kolias et al., 2005; Miller and Azad, 2000;
Modarres and Nosoudy, 2015; Seco et al., 2011). Soil type, application
and environmental conditions can signicantly inuence the choice of
technical methods and procedures employed, as well as the resulting
characteristics of the treated soil. Hence, prior to the application of soil
improvement/stabilization procedures, an accurate characterization of
the local soils and an understanding of local conditions for a given country are deemed mandatory (Ali, 2004). For instance, expansive phenomena may cause serious problems in arid climates, whereby the supply of
water from any source is liable to cause ground heave in soils or rocks
possessing swelling potential (Al-Rawas et al., 2005).
Phyllite clays or phyllites are rocks (metamorphosed to a low extent) of slate clay materials that are found in vast areas around the
world. Phyllites belong to the foliated and platy group composed of tabular and elongated minerals (the lamination and foliation make them
Corresponding author.
E-mail address: canomanuel@hotmail.es (M. Cano).
http://dx.doi.org/10.1016/j.clay.2016.01.042
0169-1317/ 2016 Elsevier B.V. All rights reserved.
break along planes) and they are thinly bedded. Phyllites contain an
abundance of ne grained phyllosilicates, which gives them an unctuous feel, and the existence of preferential cleavage makes them easily
breakable into thin sheets (Adom-Asamoah and Owusu-Afrifa, 2010;
Alcntara-Ayala, 1999; Garzn et al., 2009a; Lonergan and Platt, 1995;
Oliva-Urcia et al., 2010; Ramamurthy et al., 1993; Sanz de Galdeano
et al., 2001; Valera et al., 2002). In a recent paper, de Oliveira et al.
(2015) considered phyllite as a granulated metamorphic rock, citing
previous work performed by Arnold et al. (1998). However, Arnold
et al. (1998) considered phyllite as low-grade metamorphic rock, classied as greenschist facies with thin-shaly foliated texture, formed from
pelitic rocks. de Oliveira et al. (2015) studied the effect of the substitution of hydrated lime with Brazilian phyllite on mortar quality. They
concluded that the contribution of the phyllite to mortar quality was
lower than that of the lime and, therefore, produced a reduction in mortar quality, rather than improving it.
The present investigation concerns the stabilization and improvement in the engineering properties/performance achieved for Spanish
phylliteclay material by the addition of lime. The addition of lime stabilizes clay, although the percentage of lime content required changes
with clay type/minerals. Hence, the proper design of claylime mixtures
includes careful identication of pertinent soil characteristics and a
well-developed experimental testing program aimed at identifying the
appropriate mix proportions to achieve the required material properties/performance. Composite materials having attributes superior to
those of the original soil (clay), but produced with low or at similar
330
relative cost, are an attractive proposition for applications in the construction and building industries.
Due to their good compaction properties and very low permeability,
traditional uses of phyllites in southeast Spain have been for very specific purposes, including: as cover for and to impermeabilize roofs and the
central area of ponds; as core material in zoned dam/reservoir construction; and for waste landll applications (Alcntara-Ayala, 1999; Castillo,
2010; Garzn et al., 2009a, b; Garzn et al., 2010; Lonergan and Platt,
1995; Sanz de Galdeano et al., 2001). A systematic program of testing
was performed on materials sampled from several phylliteclay deposits located in the Almera and Granada provinces (Andalusia Region,
Spain) by Garzn et al. (2009a); Garzn et al., 2009b; Garzn et al.,
2010). The materials had good compaction properties and, hence, low
water-permeability values and stiff response on loading. Despite the
low porosity attained for dry-side compaction, the material underwent
some collapse settlement on soaking at stresses greater than 100 kPa. At
low applied stress, the compacted material did not display important
swelling on soaking (despite the presence of active clay minerals) on account of its low specic surface and low water-retention ability. Nevertheless, the expansivity of these phyllite clays limits their used in some
applications, such as earth construction where low stress levels are envisaged; e.g. as road subgrade material.
Recently, we reported on new phyllite claycement composites having improved engineering properties and material applications (Garzn
et al., 2015). In the present paper, we present the experimental ndings
of an original investigation performed to examine the improvement in
engineering properties/performance of Spanish phylliteclays achieved
by the addition of up to 7 wt.% lime. The main focus of this research was
to investigate the effectiveness of lime addition in producing a reduction
in the phyllite clay activity (i.e. decrease its plasticity index value), and
therefore its expansivity, in order to meet regulatory requirements for
its potential use as road subgrade material. The engineering properties
of the phyllite claylime mixtures investigated include their consistency
limits, compaction, California Bearing Ratio, swelling potential and
water-permeability. The required pavement thicknesses for the raw
phyllite clay and phyllite claylime mixtures are also compared and
discussed. To the authors' knowledge, this is the rst international report presenting such data for phyllite claylime mixtures.
2. Experimental
Select phylliteclay samples were sourced from Berja, Almera,
Spain. In its natural state, this material has a very low gravimetric
water content ranging 12% (mean of 1.8%), a void ratio (volume of
voids to volume of solids) value of ~0.39 and a dry density of 2.03 Mg/
m3 (Garzn et al., 2010). The representative bulk phylliteclay sample
used in the present investigation was oven dried at 105110 C to constant mass, allowed to cool to ambient laboratory temperature (20 C),
disaggregated, and then sieved to obtain the fraction passing the 20mm sieve (grading curve for which is presented in Fig. 1).
Garzn et al. (2010); Garzn et al., 2015) reported the predominant
silica-alumina chemical composition of these phyllite clays, with typically 4550 wt.% of silica and 2224 wt.% of alumina. Minor amounts
of other oxides were also found present, such as CaO (1.74.4 wt.%),
MgO (2.83.4 wt.%), Na2O (1.82.4 wt.%), K2O (3.33.9 wt.%) and iron
oxide as Fe2O3 (8.39.4 wt.%). The mineralogical composition) of these
samples was determined by X-ray powder Diffraction (XRD) as chlorite
and illite (main clay minerals), quartz and some minor aluminosilicates,
potassium feldspar and an interstratied phase with phyllosilicates,
which was identied as mixed-layer illitesmectite or possible chloritesmectite. The loss in dry mass of a representative test-specimen
of the natural material after 1 h of thermal treatment at 1000 C ranged
6.87.0 wt.%, which was associated with phyllosilicates having structural OH groups (i.e. chlorite, illite and interstratied phase).
The lime used in preparing the soil mixtures was a powdered sample
of industrial hydrated lime material (96 wt.% passing the 125 m sieve),
Fig. 1. Grading curve for fraction of disaggregated phylliteclay sample passing the 20-mm
sieve.
Fig. 2. Consistency limits and classication of the phylliteclay material for different
proportions of lime additive: (a) liquid and plastic limits; (b) plasticity index;
(c) Casagrande's plasticity chart (adapted from BS 5930: BSI, 2015). Note: inclined line
in Fig. 2(c) is referred to as the A line.
331
Fig. 3. Compaction properties of the phyllite clay material for different proportions of lime
additive: (a) dry density against water content relationships; (b) maximum dry density
and optimum water content. MP, modied Proctor; SP, standard Proctor.
332
requirement, generally stated in compaction specications, can be determined. With increasing proportion of lime additive from 0 to
7 wt.%, the maximum dry density value achieved was found to decrease
almost linearly from 2.27 to 2.10 Mg/m3, with the corresponding optimum water content (OWC) value increasing from 6.5% to 9.5%. Also included in Fig. 3 are the results of standard Proctor compaction testing for
the raw phyllite clay (0 wt.%). These results, considering phyllites as
clayey materials according to their mineralogy, are consistent with
those reported by several authors for other clayey materials and soils
(Ayuso, 1982; Basha et al., 2005; Bell, 1996; Kezdy, 1979; Miller and
Azad, 2000; Ola, 1977).
For the present investigation, the reduction in MP maximum dry
density values achieved with increasing proportion of lime additive
(Fig. 3b) may be explained by the lower density of the lime material
(relative to that of the phyllite clay) and higher rigidity of the soil skeleton produced for the phyllite claylime mixtures. The moderate increase in OWC values is assumed due to the increase in LL and PL
values detected with increasing proportion of lime additive (Fig. 2a).
These kinds of changes are associated with pozzolanic reactions occurring between the clay minerals (chlorite and illite as main components
in the phyllite clay) present and the added lime. The OH ions of the hydrated lime produce an increase in pH, favoring pozzolanic reactions between the silica and alumina of the lattices of clay minerals and the
available calcium ions.
However, conicting opinions are reported in the literature about
the timing, sequence and modes of reactions, and whether such reactions occur in solution or at the surface or edges of the clay particles,
causing structural changes that lead to particle cementation (Di Sante
et al., 2014). Such processes could be operating to form a cementitious
material for the phyllitelime mixtures under investigation. Reported
studies have used several techniques to examine the pozzolanic activity
of related clay materials (Al-Rawas et al., 2005; Ayuso, 1982; Basha
et al., 2005; Bell, 1996; Castro-Fresno et al., 2011; Di Sante et al., 2014;
George et al., 1992; Miller and Azad, 2000; Ola, 1977; Snchez de
Rojas et al., 2006; Seco et al., 2011).
Table 1 lists CBR test results for 95% and 100% MP compaction, calculated road pavement thickness requirements based on same (determined using Eq. (1)), and swelling test results for the phylliteclay
material and phyllite claylime mixtures (37 wt.%). Table 2 lists measured water-permeability coefcient values for MP-compacted phyllite
clay samples having different proportions of lime additive (07 wt.%).
Fig. 4 shows the results of the CBR tests performed at 95% and 100% of
the MP maximum dry density values after these test-specimens had
been allowed to soak in water for 4 days. The raw phyllite clay
(0 wt.%) had CBR values of 1.7% and 2.5% for 95% and 100% MP, respectively (typical of clay soils). Measured CBR values for the phyllite clay
lime mixtures were signicant greater, ranging 2022% and 3542%
for 95% and 100% MP, respectively. The addition of 3 wt.% lime produced
the most dramatic increase in CBR, with the 5 and 7 wt.% lime additions
producing diminishing returns. For material MP-compacted at the OWC,
the raw phyllite clay had a measured swelling value of 3.6% axial strain,
whereas the phyllite claylime mixtures underwent no swelling under
soakage.
Fig. 4 also shows indicative values of the overall pavement thickness
(in meters) required for MP-compacted material to support vehicular
trafc, deduced using Peltier's formulation (Eq. (1)). With the increase
Table 2
Evolution of permeability coefcient value for MP-compacted phyllite clay samples with
addition of lime.
Material
Phyllite clay
Phyllite clay with 3 wt.% lime
Phyllite clay with 5 wt.% lime
Phyllite clay with 7 wt.% lime
1.81
35.3
62.1
241
in CBR values described above, compared with the raw phyllite clay,
the required pavement thickness for the 3 wt.% lime mixture was 73%
and 81% lower for 95% and 100% MP compaction, respectively. Further
increases in the proportion of lime additive produced diminishing
returns, with 75% and 84% reductions in the overall pavement thickness
achieved for the 7 wt.% lime mixture. Standard Proctor (SP) compaction
is arguably more appropriate than MP compaction for low stress applications; e.g. ways and roads made on esplanades of phyllite claylime
mixtures, particularly given the modest values of overall pavement
thickness (b 15 cm for 37 wt.% lime, Table 1 and Fig. 4) deduced for
the MP case. In the absence of such data, the MP results presented provide qualitative information for the SP case on the merits of lime addition to the phyllite clay. In terms of engineering behavior investigated,
SP compaction would result in lower maximum dry density and higher
OWC values (see Fig. 3a), lower CBR values, and hence greater pavement thickness requirements compared with the MP-compacted materials. Nevertheless, the presented results indicated that, in practice,
potentially signicant reductions in construction costs for ways and
roads made on esplanades of phyllite clays can be achieved with the addition of 3 wt.% lime. This proportion of lime addition was sufcient to
satisfy the plasticity requirements described in the Sheet of Technical
General Prescriptions for Works of Roads and Bridges PG3 (Spanish
Highway Agency, 2008), and was shown to substantially reduce overall
pavement thickness requirements, meaning that the phyllite clay
3 wt.% lime mixture can be used as road subgrade material.
As described in the Introduction, other potential applications for the
phyllite claylime mixtures are in earth construction, as building materials and for impermeabilization purposes. For instance, Fig. 5 shows
measured water-permeability coefcient (k) values for the MPcompacted materials plotted against the proportion of lime additive,
with the best-t line indicating an exponential increase in k values
with increasing proportion of lime additive over the range of 07 wt.%
lime investigated.
Di Sante et al. (2014) also reported an increase in k values with increasing proportion of lime additive for a lime-treated clayey soil, although without a mathematical correlation, as found in the present
investigation. Here, the MP-compacted raw phyllite clay had a k value
of 1.8 1011 m/s, and together with the 3 and 5 wt.% lime mixtures,
was categorized as having extremely low permeability (i.e.
k b 1 10 9 m/s). The 7 wt.% lime mixture, having a k value of
2.4 109 m/s, was categorized as very low permeability material. SP
compaction is likely to produce higher k values (greater volume of
pore voids), but for material SP-compacted wet of OWC is not expected
to signicantly increase layer thickness requirements for
impermeabilization purposes. Further research is necessary to validate
this hypothesis.
Table 1
Results of CBR tests, calculated road pavement thickness requirements (from Eq. (1)), and swelling tests for the phyllite clay and phyllite claylime mixtures (37 wt.%). Note: E1 and E2,
thickness of road pavement required based on measured CBRs for 100% and 95% of MP maximum dry density, respectively.
Test material
E1 (cm)
E2 (cm)
Swelling (%)
Phyllite clay
Phyllite clay with 3 wt.% lime
Phyllite clay with 5 wt.% lime
Phyllite clay with 7 wt.% lime
2.5
34.9
37.9
42.0
1.7
19.6
21.2
22.2
48.0
9.0
8.4
7.6
53.7
14.6
13.7
13.2
3.6
0
0
0
333
Acknowledgments
Fig. 4. Potential use of phyllite claylime mixtures for pavement construction; (a) CBR
values; (b) overall pavement thickness. Note MP, modied Proctor; E1 and E2, required
pavement thickness (in meters) based on measured CBR values for 100% and 95% of MP
maximum dry density, respectively.
Fig. 5. Water-permeability coefcient against proportion of lime additive for MPcompacted phyllite clay.
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