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Joseph J. McAllister
www.wetplateemporium.com
www.facebook.com/joseph.j.mcallister
Author Notes:
Original process by Joseph J. McAllister 2012. If you want to post my process to a website,
please contact me, list my name and links. You can post it in forums or groups or share it at will.
Thanks.
THIS COPY IS
VERSION 3.5
Check for a Newer Update Online
HOW TO TUTORIALS
How to Make Glass Cyanotypes [pdf]
How to Make Glass Van Dyke Brown Prints [pdf]
Electrolytic Etching of Brass [pdf]
How to Make Ground Glass View Plates [pdf]
Bellows Replacement [pdf]
VIDEOS
Glass Cyanotype Process [Youtube]
Glass Cyanotype Test 1: Ferric Ferrocyanide (Prussian Blue) + Potassium Cyanide [Youtube]
Van Dyke Brown Microforms (Microphotographs)
Wet Plate Emporium Portfolio Book [Youtube]
Notes:
Filter the cyanotype solution before using to get any un-dissolved crystals out.
Coffee
Gallic Acid
Borax
Hydrogen Peroxide
TONING TESTS
25 ml / water 500 ml
Light Blue
25 g / water 500 ml
Dark Purple
straight
Nothing
Gloves/ Respirator
Safe/ Leaves chalky grit
Do not mix these baths together. You only need one bath per print to get the result of each bath. I
dont recommend using any of these processes. They are listed as formulas & tests that provided
useless results.
PROCESS
1) Mixing
[Safe light]
Pour water into a stainless steel sauce pan
Add cyanotype chemicals one at a time, stirring to dissolve
(Filter emulsion to get any un-dissolved crystals out)
(Tilt the pan to check that the emulsion is free of un-dissolved crystals)
Slowly stir in gelatin
(Dissolve cold: Cakes in hot water)
Slowly heat to 1200 F (480 C) stirring constantly
(Remove from heat as soon as it reaches 1200 F or crystal formation will start &
gel will burn on the sides of the pan)
(Continue stirring the emulsion and tilting the pan until the gel coating the bottom
of the pan is free of small gelatin specs)
Let cool in fridge in light tight container
2) Coating
Heat slowly in electric mini crock pot
(If the gel boils its ruined. Turn off after coating plates)
(Do not use a fast heating device. It will ruin the emulsion)
Fill ladle with emulsion
(Use a stainless steel spoon to skim bubbles off surface before pouring)
Ladle emulsion onto center of plate
(Hold the plate waiter style with one hand & pour with the other)
(Try to cover 80% of the plate with emulsion in the center)
Tip plate to each corner allowing the gel to move slowly and not drip over the sides
(Use two fingers to smear gel if spots are missed as you tip to each corner)
Pour excess back into emulsion until stream turns to drips
(Keep plate vertical: Do not allow gel to run back onto the plate
The coating is only as thick as what is left on the plate after pouring off & what
drains off as it dries vertically. Do not level until the plate is ready to expose!
The coating will seem so thin that it will look as if the plate is clean with no gel at
all. That is actually the correct amount. Thick gel will expose slowly, and blister
off the plate when drying.)
Place drip edge on paper towel and allow it to soak up the brim
(Keep moving it to a new spot on the paper towel. When it starts to slow down it
is ready for drying)
Use a paper towel to wipe off any emulsion that may have spilled onto the back
3) Drying I
Fan dry until dry to the touch (25 min)
Flip the plate & fan dry (10 min)
(This step is to allow the gel berm at the button to dry)
(The plate is done drying when the berm on the edge is dry enough that it wont
stick to the paper during printing).
(Do not over dry. The plate should have a clear dry film, not chalky or crystallized)
Inspect gel for crystals, bubbles and uneven coating
(If the coating is bad, the plate is not worth printing)
(Use a razor blade to scrape off any over spill on the back, especially around the
berm. Then use half of a damp paper towel to clean the over spill & the dry half
of the towel to dry it)
4) Exposure
Print until solarized
(Expose until the contrast of the blue gel and the black of the print are equal, or until the
emulsion stops reacting to light. The emulsion should be smooth and free of gelatin
stops. See printing defects.)
5) Wash I
Fill a developing tray with cold tap water. Ice may be used to cool the water a bit colder
then tap water, if youre having weak gel issues. Lower the top of the plate into the water
at a 45o angle, so it touches the bottom of the tray. Now, lower the rest of the plate into
the bath, letting the water slowly cover the plate until it is horizontal in the tray.
Wait 10 seconds. You should see the see the highlights lighten, and the shadows turn
dark, but remove it if you see the highlights loosing detail.
Slowly raise the plate up at a 45o angle, and raise the plate out of the bath. Let the water
pour off the plate at this angle until the water running off the plate slows from a stream to
drips. Now raise the plate up vertically and allow the last few drops of water to leave the
plate. (The first wash is only used to harden the gel. Do not expect to remove all the
green at this point.)
6) Drying II
Fan dry vertically
7) Wash II (Desensitizing)
[White light]
Soak the plate in a tray of water and agitate it 30 sec
Wash with cold water under a faucet 30 sec
(The gel should be very strong at this point)
(Use the faucets stream to work out a bit of the green & purple tint)
Place the wet plate in a white developing tray, and allow direct sunlight to shine on the
plate
(The white tray acts as a reflector)
(The sun light will clear the purple and green in 1-2 minutes)
In room light, soak the plate in distilled water and agitate the tray 30 sec
(This removes hard water spots from the final plate)
(The contrast of the plate will increase slightly, when it starts to lighten, remove it
from the water)
8) Drying III (Final drying)
Fan dry vertical
9) Cleaning
When the plate is dry, place the emulsion side down on a dry towel and clean the glass
side with a small towel soaked with Windex glass cleaner.
10) Framing
Frame glass side out, backed with white paper. Pack the frame so the paper is pressed
tightly against the glass or the image will appear blurred.
Notes:
Heating the emulsion above melting temperature causes the cyanotype to form large crystals to
form in the emulsion (See printing defects: snowflake crystallization).
Oxalic acid (ox-l-ic), hydrogen peroxide baths seem to have no effect on removing the purple
tone from the plates
Tartaric acid (tar-taric) can be substituted for Oxalic acid in a cyanotype recipe
Annie Oakley (August 13, 1860 November 3, 1926), born Phoebe Ann Moses, American
sharpshooter at Buffalo Bill's Wild West show. 8x10 Glass Cyanotype (Joseph J. McAllister 2013).
BASE FORMULAS
You can use any cyanotype formula. (These are listed for a quick reference).
Dick Sullivans Cyanotype Formula
Green ferric ammonium citrate
27.2 grams
E. Valentas Sensitizer (speed)
Potassium ferricyanide
9.2 grams
Herschels Original formula
Oxalic acid
1 grams
Oxalic or tartaric acid (speed & range)
Ammonium dichromate
0.2 grams
Robert Hunt (speed/ shelf life, stops blue
(Optional)
formation)
Water
200 ml.
50 grams
40 grams
500 ml
Notes:
21F7 Prussian blue (Berlin, Milori or Paris blue).
Cyanotypes are composed of the substance Prussian blue (ferric ferrocyanide), which was
originally an artists pigment.
GELATIN
Knox original gelatin unflavored (32 oz). Food Grade. Wal-Mart $8.99.
GELATIN HARDENERS
ADDING MORE GELATIN
One way to increase the gel strength is to put some powdered gel into a cup and add a little cold
water to turn it into a thick lumpy gel. Heat up the emulsion in a crock pot and put the new gel on
top. The new gel will liquefy along with the emulsion.
GELATIN RATIO
Getting the right gelatin ratio is not as simple as it sounds. The difference between a gel that is
too strong or too weak is very slim. If the gel is too strong, it goes on too thick and blisters off the
plate during exposure or after drying. If the gel is too weak, you end up with gel spots and the
image washes off the plate in the first bath.
FORMALDEHYDE
Formaldehyde CH2O or HCHO. A saturated water solution of formaldehyde, that contains 40%
formaldehyde by volume or 37% by mass, is called "100% formalin". A few drops of formalin can
be used as a gelatin hardener in emulsions or as a bath. (I have not tried this method, so you
should do research about its use as a gelatin hardener with dry plate photography before trying).
TYPES
Glass Cyanotype
Cyanotype Orotype
Coffee Toned Cyanotype Orotype
Coffee Toned Glass Cyanotype
Cyanotype Lantern Slide
Brass Cyanotype
Blue
Blue & Gold
Black & Gold
Sepia, Black or Black, Brown, Green & Blue
Blue, Gray or Black
Blue & Gold
EXPOSURE
(Layers from front to back in contact printing frame)
1 - Glass front
2 - Black paper vignette
3 - 8x10 Sheet Film
(Emulsion side up or it may be ruined by gel over pour)
4 - Dry plate cyanotype (Emulsion face down towards white paper)
5 - White paper
(Reflectivity decreases exposure time)
6 - Black paper
(blocks light from entering back)
7 - Glass back
Notes:
Use dodge and burn techniques to insure even exposure
Check the glass to make sure its not heating up. If it is, back the light up. If the glass heats up the
gel will start cracking and blistering off the plate
Expose plate using a 500 watt tungsten fennel at 3.5 ft with medium focus
Make sure the plate is facing the light directly and not at an angle
If using the sun to expose, do not allow the plate to heat up
The exposure needs to be sandwiched to the glass or it will just wash off. This is why we expose
with the emulsion side down.
During exposure, the gel will turn from blue to light blue repeatedly allowing a deeper layer to be
sensitized by the light. Print until the contrast of the blue emulsion and the black negative are
equal in contrast (solarized). This shows that the emulsion layers are thick enough to make a
good print.
LOADING FILM
Load film in dark with film identification marks at the lower right hand corner. This is how you
know the gray emulsion sided is up and ready to be exposed.
Exposure Timer
Aperture
Lux
Fill
2 1k Fresnels
4 sec
f:45
Incident: 3
-0.5
Development
ASA
Brand
7 min
100
Arista
This lighting setup above is an example of using a long exposure with 2 darkroom development
timers to take a self portrait.
Dark room timer setup for self portrait using sheet film.
f/32
f/45
f/64
PUSHING DEVELOPMENT
If your negative doesnt have detail, you might be pushing the developing time too long and increasing the
print contrast. When the negative is in the developer the dark areas that create your highlights develop
first, then the details of the mid tones, and finally the details of the brightest areas of the negative that
create your shadows.
In the final print, blown out high lights might be caused by an over developed negative (the darks of the
negative become too dense). Lack of detail in the shadows may mean the image wasnt developed long
enough for the shadow detail to appear in the negative. Be careful not to over develop the film. The
details of the face are the most important part of the image and will be lost in an over developed negative.
Shadow details are the least important.
IN PHOTOSHOP
Check your negatives by scanning them & inverting them in Photoshop. A negative with a lot
density may appear to be a good negative, but after viewing it in Photoshop you may realize the
dark density means your highlight are blown out. In Photoshop examine the image for good detail
in the highlights. You dont want to see washed out faces or white clothing without detail.
FILM SUPPLIES
Arista EDU Ultra B&W 100 ISO (8x10 50 sheets)
$145.99
$56.99
$15.59
Arista Premium Liquid Film Developer 5 Liters (Makes 13.21 Gallons) SW 14.5 LBS
$26.99
Arista Premium Odorless Liquid Fixer 5 Liter (Concentrate to Make 13.21 Gallons)
$28.59
$18.99
$18.99
DENSITY
Using a light density print
Using a light density print
Using a light density print
TIME
10 min
1 hr
6 hrs
RESULT
Gray
Sepia
Black/ Brown/ Green/ Blue
This step should not be done until the plate has been fixed with a water bath, dried, then washed,
light bleached (using sunlight to remove green and purple), and dried again. Basically, the plate
should be a finished cyanotype plate before doing this.
Pour the coffee into a developing tray. Add ice too cool it down. When the ice has melted and the
coffee is around 65o F, lay the image in the tray. Dont place the image in hot coffee. Heat
liquefies the emulsion. After toning, place the plate in a tray of tap water and rock it for 15
seconds, then do the same with a tray of distilled water. Be aware that the water baths can wash
out some of the coffee. Examine the plate, and consider if a longer toning bath is needed. If not,
fan dry the plate.
Jefferson Finis Davis (June 3, 1808 December 6, 1889) President of the Confederate States of
America 1861 - 1865. Coffee Toned Glass Cyanotype (Joseph J. McAllister 2012). Toned 10
minutes.
Annie Oakley (8/13/1860 11/3/1926). Cyanotype Toned Glass Cyanotype (Joseph J. McAllister
2012). Toned 10 minutes.
CYANOTYPE OROTYPE
For an authentic method of bronzing the cyanotype, add bronzing powder to Sandarac varnish.
Bronzing powder can be found at Michaels Art Supply stores in the gold leafing section. For a
quick modern alternative, use Rust-Oleum bright coat metallic finish from Lows or Home Depot.
Lay the plate flat on a table with a newspaper under it, wear a 3M painters respirator, layer the
coat up to full thickness, blow drying the surface each time before adding another coat. Apply the
lacquer or varnish directly to the emulsion side.
ARTIST TAPE
Artist's Loft Artist Tape from Michaels Arts & Crafts is a paper based tape that is 3/4" wide. It is
a perfect match for the tape used on 19th Century lantern slides. Stack the lantern slide layers
then apply the tape in 4 strips across the back covering approximately 1/8 of the edges. Fold the
tape over and cut at the corners. Do the top and bottom first, then left and right. Now do the same
to the front side.
GOLD LEAF PRINTING
Gold leaf printing is very hard to come by. Printing companies will only do gold leaf if youre
ordering a thousand prints or more. A quick method to make a few gold leaf prints is to use a
toner transfer method. Print a vignette template onto black construction paper using a laser jet
printer (inkjet will not work). The template will be black and white with thick black lines where the
gold will be transferred. Fine detail designs will not work. Lay a gold leaf foil transfer sheet from
Michaels Arts & Crafts over the vignette. Place a piece of printer paper over that (to protect your
iron). Then iron the gold leaf onto the paper. The toner ink will melt and act as an adhesive. Now
take paint brush and work the loose foil off the paper. This will make a mess of gold leaf particles
which you can reuse or vacuum up later.
Another method is to use a foil-it machine which uses heated rollers to melt the toner, but the little
machines are hard to find. Probably sold by a scrap booking supply retailer.
LINKS
Scrap Booking Paper
Artist's Loft Artist Tape
Gold Leaf Foil Transfer Sheets
5x7 Cyanotype Lantern Slide with Gold Leaf (Joseph J. McAllister 2013).
Note:
If the plate was toned for only 10 minutes, do not rinse the plate before fan drying it. Allow the
coffee to dry on the surface of the plate. Fan dry vertical.
BRONZING
For an authentic method of bronzing the cyanotype, add bronzing powder to Sandarac varnish.
Bronzing powder can be found at Michaels Art Supply stores in the gold leafing section. For a
quick modern alternative, use Rust-Oleum bright coat metallic finish from Lows or Home Depot.
Lay the plate flat on a table with a newspaper under it, wear a 3M painters respirator, layer the
coat up to full thickness, blow drying the surface each time before adding another coat. Apply the
lacquer or varnish directly to the emulsion side.
Annie Oakley & Jefferson Davis. Coffee Toned Cyanotype Orotypes (Joseph J. McAllister 2012).
Annie Oakley (8/13/1860 11/3/1926). Coffee Toned Cyanotype Orotype (Joseph J. McAllister
2012).
BRASS CYANOTYPES
For the brass plates, use 22g. (0.025) or 26g. (0.016) brass sheets. These can be cut using a
paper trimmer. When coating metal, the big problem is that the metal sheet is not flat in your hand.
As the metal warps with the weight of gravity, the emulsion forms puddles. When coating, place
the plate in a developing tray so the plate stays flat, then coat & develop as before.
FLAKING ISSUE
Another issue with brass cyanotypes is that after they are finished, is they bend slightly while you
are handling them, the emulsion can flake off. They should be laid flat, coated with 1 coat of RustOleum crystal clear enamel, and blow dried quickly so the paint doesnt dissolve the gelatin.
Make sure that you dont dry spray the plate. You want to get a good shiny coat in one try without
any dry patches, dripping or pooling. Brass Cyanotypes are only safe once they are framed
behind glass.
LINKS
Brass Sheet 22g. (0.025)
Amazon
$42
12x24
Amazon
$44
12x24
eBay
Jefferson Finis Davis (June 3, 1808 December 6, 1889) President of the Confederate States of
America 1861 - 1865. 8x10 Brass Cyanotype (Joseph J. McAllister 2012).
George Armstrong Custer (December 5, 1839 June 25, 1876). 8x10 Brass Cyanotype (Joseph
J. McAllister 2012).
FRAMING
Frame the images with the glass side facing out, and back with white paper. Pack the frame so
the paper is pressed tightly against the glass or the image will appear blurred. Surprisingly, the
images look good in just about any frame. Personally, I like to pick out odd frames that seem like
an odd match, like the frames below. Im usually surprised that an unusual frame can be more
interesting then a standard Victorian frame.
Annie Oakley (August 13, 1860 November 3, 1926), Framed 8x10 Coffee Toned Cyanotype
Orotypes (Joseph J. McAllister 2013).
Annie Oakley (August 13, 1860 November 3, 1926), Framed 8x10 Cyanotypes (Joseph J.
McAllister 2013).
PRINTING DEFECTS
AIR BELLS
Air bells are a common flaw in dry plates. They are little bubbles of air trapped in the emulsion.
FRILLING
Wrinkling of a gelatin layer at the edges during processing caused by the gel expanding and
lifting from the plate.
BLISTERING
Cracking and peeling of the gel layer from the plate during drying. This is caused from the gel
layer being too thick. This can also happen during exposure when the glass heats up and the
emulsion starts to dry and detach form the plate.
GELATIN SPOTS
Black chips in the final image. This happens when the gel is overheated and forms a hard burnt
layer against the walls of the crock pot which may have been scrapped into the gel using a spoon.
Never scrape the sides of the crock pot when pouring the gel back into the storage container.
GELATIN SPOTS
Gelatin spots appear when the gel is too weak. In weak gels the image usually washes off the
plate in the first bath as well.
DRIPS
Drips happen during coating of the plate when the emulsion starts to cool before pour off. To
avoid drips, make sure the emulsion is hot enough, and cover at least 80% of the plate when
applying the emulsion.
EDGE BERM
Edge berm is the build up of gel at the pour off edge. It forms when the plate is fan drying
vertically. This can be avoided almost completely by taking time to absorb the emulsion at the
drip corner after coating. Continue until the rate of emulsion being absorbed by the paper towel
slows down.
DOUBLE EXPOSURE
Double exposures can happen during exposure when the glass in the contact printing frame
heats up. As the glass expands, gravity takes hold and the print slides down. Try to avoid printing
with the frame vertical. Be aware of this if you are using a cheap or oversized printing frame that
was not really designed for printing.
NEGATIVE PRINT
On occasion I have a print that turns negative when it is put into the initial water bath. This
happens when the image is over exposed in direct sun light to the point where an ugly gray color
starts forming. As you soak the image it will turn to a positive over 3-4 minutes of sitting it in the
water bath.
The image below was completely negative when I first put it into the water bath. It took 5 minutes
for the image to appear.
HISTORY
CYANOTYPE
Invented in 1842, by Sir John Frederick William Herschel, 1st Baronet, KH, FRS, and popular as a
photo medium from 1880-1920, and used to print blue prints for maps and architecture in
modern day.
GLASS CYANOTYPES IN THE 19TH CENTURY
Historically, cyanotypes on glass are a bit of a mystery. The process was so rare in the 1800s
that it was almost completely undocumented. I have never come across a historical image of a
glass cyanotype. The first one was probably made sometime after 1871, after dry plates using
silver bromo-iodide mixed with gelatin were invented. Another reason why glass cyanotypes are
so rare is that cyanotypes were a very unpopular photographic method in the Victorian era. Critics
of the method despised the brilliant Persian blue color, in favor of more subtle colors like toned
Albumen Prints. The process was mainly used as a fast way to proof negatives.
Glass cyanotypes are sometimes referenced as cyanotype lantern slides. Several old 19th
century manuscripts mention that the process can be done on glass, but only a few tell a basic
idea of how this might have been accomplished. One such writing implied that glass could be
coated with gelatin and sensitized with cyanotype.
DRY PLATE 1871
Dry plate, also known as silver gelatin process, was invented by Dr. Richard L. Maddox in 1871.
In 1879, the first dry plate factory had been established, the Keystone Dry Plate Works. In 1873,
Charles Bennett discovered a method of hardening the emulsion, making it more resistant to
touch. In 1878, Bennett discovered that by prolonged heating, the sensitivity of the emulsion
could be greatly increased. George Eastman developed a machine to coat plates in 1879 and
opened the Eastman Dry Plate Company.
GLASS CYANOTYPES MODERN PROCESS
I didnt have much to go on but the references that a plate coated in gelatin could be sensitized
with cyanotype. I imagine that meant soaking it in cyanotype solution. I was thinking of dry plate
method, where the gelatin is already photo sensitive, and kept in the dark like modern sheet film.
For convenience and an even mixture with fewer defects I decided the results of dry plate
methods were superior to wet plate sensitizing methods. I first experimented with gelatin to make
a strong gel that could withstand processing, but be soft enough to allow the unexposed
cyanotype chemicals to be washed out. I also wanted to come up with the easiest method for
mixing the emulsion. After a few weeks of experimenting, I came up with my first working batch;
an easy to make light sensitive gelatin with high image quality.
OROTYPE
Edward S. Curtis invented orotype photographs in 1916 which he nicknamed Curt-Tone (also
known as orotone, goldtone or aurotypes). The photographs are an inter-negative ambrotype
backed with a banana oil varnish giving the images a bronze tone.
BRASS CYANOTYPE
The brass-cyanotype was invented by Joseph J. McAllister in 2012, while experimenting with
applications for glass cyanotypes. This photo type is a dry plate cyanotype coated on brass,
creating a blue and gold image.
a photographic fixer, in 1839. Herschels research was read at the Royal Society in London in
March 1839 & January 1840.
LINKS
Unblinking Eye: Cyanotype Formulas
Bostick & Sullivan
Photo Formulary
Free Style Photo: Arista 8x10 Film Supplies