Final Year Project

A PLANT DESIGN PROJECT ON
PURIFICATION OF SYNTHESIS GAS (208MMSCFD): REMOVAL OF ACID

GASES BY MDEA SOLUTION
Session 2009-2013
Supervised By:
Prof. Dr. Arshad Chughtai
Submitted By:
Waqas Iqbal
CE09-10M08
Abdul Salam
CE09-10M21
Haroon Saeed
CE09-10M34
Ahmad Riaz Khan
PG09-10M05
Institute Of Chemical Engineering and Technology

University ofthe Punjab,
Lahore.
Approval Certificate
It is certified that this report is submitted by the following students.
Waqas Iqbal
CE09-10M08
Abdul Salam
CE09-10M21
Haroon Saeed
CE09-10M34
Ahmad Riaz Khan
PG09-10M05
SUPERVISOR:
Prof. Dr. Arshad Chughtai
Institute of Chemical Engineering and Technology,
University of the Punjab, Lahore.
External Examiner:
.........................................
Signature
..
Signature
II
Supervisor
Prof.Dr. Arshad Chughtai
Innovators:
Waqas Iqbal
waqasiqbal.ce
@gmail.com
Abdul Salam
engr.abdulsalam09
@gmail.com
Haroon Saeed
haroon1988icet
@gmail.com
Ahmad Riaz Khan

ark.khan.78
@gmail.com
Message:
Throughout our university life we learned a lot of things not just about study but also
about life from our fellows and our teachers. We have made lifelong friendship,
memories and lived a dream life. Our teachers played hugely important role in
grooming our personality, they not only taught us engineering but more importantly
they tried best to make us a good human being and a responsible citizen. Words are not
enough to thanks them and we promise we will carry on this identity of I.C.E.T to new
level where ever we will go in future INSHAALLAH
III
Acknowledgement
All praises to Almighty ALLAH who gave us light in darkness and gave us ability and
strength to complete our research project and all respects are for His Prophet
Muhammad (PBUH, on whom be ALLAHS blessings and salutations)
We take immense pleasure in thanking our worthy teachers for their valuable help
regarding our research project. We all owe special thanks to our project supervisor
Prof. Dr. Arshad Chughtai, who helped us throughout our research work and during
the compilation of this Design project. His motivation, guidance and kind words
always encouraged us to work with commitment. Whenever we found ourselves in any
sort of trouble, we always found him available to cater the issue. This sort of
generosity and favor is highly commendable.
We are grateful to our parents for their special prayers that helped us achieve this
tedious task in the compilation of this design project.
IV
ABSTRACT
Synthesis gas produced from wood feed stock usually contains gaseous impurities
such as carbon dioxide and hydrogen sulphide which are acids in aqueous solution
thus highly corrosive to the processing equipment and poisonous to Catalyst,
impurities laden-gas is also highly toxic and malodorous and is referred to as sour
gas.
The purpose of project is to design Amine Treating Unit (ATU). There are many
processes for the recovery of acid gas from Synthesis gas but we selected Absorption
Process by using Amine solvents (MDEA), because the design of the process is
economically most favorable. The economics of the plant also make balance with the
efficiency and is most suitable to the oil and gas reserves of Pakistan.
The process selected for this purpose is the Absorption Process by using Amine
solvents (MDEA) and the unit is designed to treat 208MMSCFD of Synthesis gas. This
Design Project includes introduction and processing of various methods employed for
the Acid gas recovery from Synthesis gas.
ChemCAD, Aspen HYSYS, MS Excel, and MS Visio are the softwares that has been
used for the calculations and designing of the project.
The details of this Project contains material and energy balances across the Amine
treating unit (ATU), individual equipments design, instrumentation and control, cost
estimation, and Operational Problems of Amine treating unit (ATU).
In summary, the focus on the future improvements in the Absorption process by using
Amine Solvents makes this project distinctive and particularly relevant for educating
present or perspective engineers. We worked very hard to complete this project. Our
aim is to stimulate young future engineers. We also strived to develop the design of the
Amine Treating unit (ATU) that will capture engineers attention and is easy for the
engineers to use and adapt.
Table of Contents
1. INTRODUCTION
1.1 Synthesis Gas
1.2 Synthesis Gas: A Historical Overview
1.2.1 Historical Terminology Related to Different types of Synthesis gas
1.2.2 From Feedstock to Synthesis Gas: A brief over view
1.3 Need of Purification of Synthesis Gas
1.4 Application of Synthesis Gas
1.5 Principal Gas Phase Impurities
1.6 Gas purification
10
1.6.1 Absorption
11
1.6.2 Adsorption
21
1.6.3 Membrane Permeation
22
1.6.4 Chemical conversion
24
1.6.5 Condensation
24
2. PROCESS SELECTION
2.1 Process Selection
25
2.2 Process Description
28
2.3 Equipments used in The Process
29
2.4 Process Flow Diagram for Amine Sweetening Process
33
3. MATERIAL BALANCE
3.1 Introduction
34
3.2 Synthesis Gas Composition
35
3.3 Inlet Gas Separator
36
3.4 Mass Balance on Absorber
41
3.5 Mass balance on Stripper
44
3.6 Balance across over-head separator
46
VI
3.7 Balance across the overhead reflux drum
47
3.8 Overall material balance
47
4. ENERGY BALANCE
4.1 Introduction
48
4.2 Conservation of Energy
48
4.3 Forms of Energy
49
4.4 Inlet Separator
50
4.5 Absorber
59
4.6 Lean Solvent Exchanger
69
4.7 Lean/Rich amine exchanger
70
4.8 Over head Stripper Condenser
71
4.9 Stripper
74
4.10 Energy Balance across Hydraulic Turbine
79
5. EQUIPMENT DESIGN
5.1 Inlet Separator
81
5.2 Plate Heat Exchanger
85
5.3 Absorber Design
96
5.4 Stripper Design
109
5.5 MDEA Surge Drum
119
6. INSTRUMENTATION & PROCESS CONTROL

6.1 Amine Plant Control
120
6.2 Process Instrumentation Diagram for Amine plant
121
7. COST ESTIMATION
7.1 Plant Cost Estimation
122
7.2 Capital Investment
122
7.2.1 Direct costs
122
VII
7.2.2 Indirect costs
123
7.3 Types of Cost Estimation
123
7.4 Methods of Estimating Capital Investment
123
7.5 Percentage of Delivered Equipment Cost
123
7.6 Direct Cost
126
7.7 In-Direct cost
127
8. HAZOP STTUDY
8.1 HAZOP study
128
8.1.1 Objectives of HAZOP study
129
8.1.2 HAZOP Team
129
8.1.3 Strength of HAZOP
129
8.1.4 Weakness of HAZOP
129
8.1.5 Responsibility of HAZOP Team Members
130
8.1.6 Guide Words
130
8.2 HAZOP Study of storage Tank for MDEA
131
9. OPERATIONAL PROBELMS
9.1 Problems occurring during operation
134
9.2 Foaming
134
9.3 Corrosion
135
9.4 Chemical Losses
137
9.5 Losses due to Volatility
137
9.6 Entrainment
137
10. BIBLOGRAPHY
138
VIII
Chapter 1
Introduction
Chapter 1
Introduction
1.1 Synthesis Gas:

The word Synthesis gas now a day primarily refer to the mixture of Carbon monoxide and
hydrogen gas in different proportion containing small amount of carbon dioxide and other
traces. There are other names as well for this mixture of carbon dioxide and hydrogen
depending upon their origin and uses. For example:
On the basis of Application

1. CO and H2 mixture is also called as Methanol Synthesis Gas Because of their use in
production of Methanol CH3OH.
2. Oxo Gas Is another name for CO and H2 mixture due to Hydroformylation
On the basis of origin

1. CO and H2 mixture Obtained from coal and steam can be called as water gas
2. Gas(CO+H2) produce from steam cracking of methane CH4 is called as Crack gas
Various raw Material which can be use for generation of Synthesis gas are :
Hard Coal
Brown Coal
Natural Gas
Mineral Oil Fractions
Petroleum Gas
Biomass
Heavy Oil
Light oil fractions and Natural gas is most suitable for production of synthesis gas since they
contain high fraction of H2.
Revival of coal gasification is in progress by now in some part of world due to increasing oil
crisis and shortage
Synthesis gas can also be made from plastics using chemical recycling process which are use
to convert plastics to gaseous raw material (synthesis gas ) and liquid
1.2 Synthesis Gas: A Historical Overview:

The synthesis gas production history date back to long time ago in 1800s. In times date back to
1800s town gas was produce by gasification of coal, prior to the extensive availability of natural
gas and electricity. The town gas was then used for various purposes like residential cooking,
Chapter 1
Introduction
for lightening street lights and for industrial heating. With time the increasing demand for
chemicals and energy developed interest in field of synthesis gas technology. The main reason
for this was:
1. Due to high flexibility, synthesis gas can be used in variety of process like fuel
production, power generation, chemical manufacturing.
2. Synthesis gas provide better opening to use renewable fuels and low cost fuel as it
can be produce from multiple kind of solid fuel.
Below we will look into some historical development in the field of Synthesis gas:
1804: Coal Gas use for lighting was first patented

1813: Westminster Bridge which is in London was first light up with use of town gas on the
eve of New Year with help of wooden pipe for delivery of gas.
1816: Town gas was use for first time to Light up streets light in Baltimore Maryland, US
1800s: Town gas was use to replaces lanterns and candle in factories which lead to
possibility of night shift and evolution of industrial age.
1.2.1 Historical Terminology Related to Different types of Synthesis gas:

Water Gas: It is type of syn gas which is produce by reaction of steam with hot coke which
results in gaseous mixture containing Hydrogen and Carbon Monoxide in equal volume.
Producer gas: Reaction of coke with humid air produce syngas which contain nitrogen
diluent in significant amount, such gas is called producer gas
Town gas: It is a type of synthesis gas which is produced from coal. In 1800s it was basically
used for lighting. To create yellow flame for purpose of lighting, heavy hydrocarbons were
added.
Blast Furnace Gas: It is the product gas which is obtained from blast furnace where iron
oxide reduces using coke to produce iron. This process produces gas which contains
nitrogen in large amount.
Chapter 1
Introduction
1.2.2 From Feedstock to Synthesis Gas: A brief over view:

Synthesis Gas is normally yield from process of gasification in which the feed stock containing
carbon is process in the presence of high temperature and pressure depending on the
composition of feed stock normally temperature range is from 800 to 1500 degree Celsius . The
heat required for the process can be obtained from external heat source or by the process of
partial oxidation in which a portion of feed stock is reacted with oxygen to release the heat
required.
The next stage in production of synthesis gas is the called as reaction phase. In this phase the
feed stock react with oxygen, water vapors and carbon dioxide in case of oxygen rich material
the reaction is initiated by thermal decomposition.
The next stage in processing of synthesis gas is the purification stage. The gas produce in
previous steps is raw synthesis gas which is not very clean to be use in further process. In
purification process impurities like carbon dioxide, tar, ash, sulfur compound, methane, water
vapors is removed. After completion of purification process the ratio of carbon monoxide and
hydrogen is also adjusted depending on the product for which production this synthesis gas will
be use further. This synthesis gas is now ready for further use
When synthesis gas is brought in contact with different catalyst which mostly contain
compound of metal like copper, iron, Manganese, cobalt then new complex molecules are
formed. Now a days scientist working on finding new ways of creating already discovered
molecular combination by experimenting synthesis gas with different catalysts This is how
environmental friendly fuel can be made now a days.
1.3 Need of Purification of Synthesis Gas:

The synthesis gas obtained as result of gasification is cleaned or purify from sulfur bearing acid
gases like Carbonyl sulphide and Hydrogen disulphide to make them according to
environmental emission regulation or to save the downstream catalyst from poisoning or both.
According to The environmental regulation the sulfur contents in product syn gas should be less
than 30 parts per million by volume (ppmv) in order to meet the stack gas emission target of 4
parts per million by volume of sulfur dioxide. The synthesis should be purify to meet emission
standard set by global regulatory authority and also to meet the desires standard for
downstream use or applications.
When synthesis gas is used for combustion process or applications then it should be purify to
meet the required standard of atmospheric emission by keeping emission like SOx and NOx in
control. To determine the amount of purity of synthesis gas required for combustion process
we take help of material balances involve in combustion and assuming in what way synthesis
Chapter 1
Introduction
gas will be oxidized in the furnace or combustor(for calculation and estimation is considered
appropriate to assume impurities like NH3 and H2S are all converted into NOx and SO2 stack
emission ). The process where flue gases are scrubbed with the help of selective catalytic
reduction the sulfur removal from synthesis gas is also required to keep NOx under control.
In case of particulate the level of tolerance is negligible because downstream applications
cannot let particulate or fine ash to accumulate over extended operations thats why the gas
purification methods currently use reduce particulate level to below all environmental
standard.
In the chemical or fuel production process the purity of synthesis gas is determined by catalyst
requirements. In some cases even small amount of impurities can damage or poison whole
catalyst so purification requirements in case of catalyst are quite strict and stringent. For
example Van Der Burgt and Higman (2003 ) showed that catalyst which is used in FischerTropsch(FT) for production of liquid fuel requires that the syn gas use as raw material should
contained combined HF+HCl+HBr less than 10 ppb. Now a day such techniques are use which
purify gas to such level that it can be used in FT process. So before using syngas as raw material
it is necessary to purify it to meet downstream applications. Below we will see in table the
purification level of synthesis gas required for different downstream applications
Chapter 1
Introduction
TABLE 1.1 Synthesis Gas Purification Requirements1

Impurity
Turbines
Chemical
Fuel Cell
Environmental
Production
Particulate
Typical: <1ppmv in fuel, wide

range possible((Stringer, 1989;
Wenglarzet al., 1986; Bossart et
al.,1990; GE Power Systems, 1999)
Process requirements often

exceed environmental;
typical stack range (see
notes)PM10 < 0.015 lb/10
BTU (Rataa-Brown et al.,
2002)
Total Sulphur
Environmental or maybe set by

SCR catalyst (~10 ppmv H2S fuel
gas )(DeBiasi, 2005)
Turbine stack SO2 range

6
0.030.2 lb/10 BTU
(Rataa-Brown et al., 2002)
Total Nitrogen
Compound
Environmental
Stack NOx limit, typical

range 2 ppm25 ppm.
Traces Impurities
Halides
Set by material corrosion limits;

typical range 0.40.6 ppm
(Takematsu and Maude, 1991).
Alkali (Na,K)
Vendor specs, typical range 0.021

ppmw fuel (GE Power Systems,
1999).
Metal (Hg,Cd,Se, V etc. )
Environmental and vendor specs.
Catalyst
and
process
specic
See
notes
See
notes
for
molten
for molten
carbonate and
carbonate
solid oxide fuel
and solid
oxide fuel
cell below
Recent IGCC permits: Hg

6
stacks emission~0.5 lb/10
BTU (WePower SCPC and
IGCC Information, 2003).
Produce in-situ;
controlled to avoid turbine
material deposits
Carbonyl
Carbon dioxide
Environmental
No standard to date
Fuel Cells: For molten carbonate fuel cells (MCFCs), earlier studies and requirements are
summarized by Thambimuthu (1993). For solid oxide fuel cells (SOFCs), recent studies have
established the required purity for multiple trace species; see papers by Gemmen and Trembly
(2006) and Trembly et al. (2007a, 2007b, 2007c).2
PM10: The particulate material lesser than 10 microns
Chapter 1
Introduction
1.4 Application of Synthesis Gas:

1. Power Generation:
Synthesis gas is a combustible material and can be used in various combustion processes as
fuel. It can also be used to produce steam which in turn can be used to produce electricity from
steam cycle using prime mover, gas engines, turbine as well as fuel cell.
In the big scale project that used coal gasification for the operation of gas turbine to produce
electricity using combined cycle technology, it is possible to operate that gas turbines on syngas
with combined cycle. This will provide opportunity to implement the idea of large scale
electricity production using syngas (biomass) without actually employing much effort on small
scale technologies of biomass gasification. Eventually by using this idea we can convert coal
fired power plant into biomass plant (bio syngas) for short term, it will help us to produce large
amount of green (environmental friendly) electricity. Implementation of this short term
possibility is more beneficial to produce large amount of clean, environmental friendly
electricity than relying just on those small scale green electricity production facilities. In this
way national governments and environmental authorities stringent emission limits can also be
met. This idea is already implemented in many facilities around the world For example, 253
Mega Watt coal fired entrained flow (IGCC) plant in Netherlands (Buggenum) is about 18 % by
weight biomass (bio syngas ) co fired.
1. Automobile Fuels:
It is widely expected that in future syngas will be used to produce large amount of Ultra clean
Transportation duel from process like GTL. Methanol/ DME and Fischer-Tropsch Diesel are the
prominent example of this idea.
Methanol:
Methanol can be produce by using syngas. It can be produce by catalytic reaction of hydrogen
and carbon monoxide and some amount of carbon Dioxide. These reactions proceed with the
contraction of volume and both are exothermic in nature. This presence of small amount of
Carbon Dioxide keep the reaction in optimum zone in other words it enhance the reaction, As
these reaction are exothermic and proceed with reduction in volume so higher pressure and
lower temperature are favorable condition for reaction to occur.
It Important to keep an eye on side reaction of this process as those side reaction are also
highly exothermic and lead to the formation of many by product like that of methane DME
(Dimenthyl ether ) and higher alcohols. Now a days all over the world Methanol on Industrial
Chapter 1
Introduction
scale is produce by conversion of Syn Gas in the presence of desire catalyst. The process of
production of methanol is divided into three types on the basis of pressure used:
1. Lower pressure process using conditions of 50-100 bar
2. Medium pressure process employing 100-250 bar
3. Higher pressure process using 250-300 bar
Synthesis of Methanol from synthesis Gas involve following main reactions:
CO + 2H2
CH3OH
CO2 + 3H2
CH3OH + H2O
Both high and low pressure processes mainly differ on the basis of reactor design, operating
conditions and catalyst employed. Low pressure process are largely used in world now a
days due to their several advantages which includes better flexibility in the selection of
plant size, lower investment, better operational reliability , production cost.
Fischer- Tropsch Synthesis:

In this process two moles H2 react with one mole CO to produce mostly straight chain
hydrocarbon (paraffin CxH2x) and primary alcohols with small quantity of unsaturated
hydrocarbon and branched hydrocarbon. The side reaction of FT Process includes coke
deposition, carbid formation, methanation, oxidation of catalyst.
Optimum operating condition for Fischer-Tropsch Synthesis include pressure in range of 25-60
bar and temperature should be in range of 200-350oC. Almost 20% of chemical energy is
dissipated in form of heat due to exothermic nature of this reaction. Following chemical
reaction take place:
CO + 2H2
H2O + -(CH2)-
Various types of synthetic fuel can be produce from synthesis gas by using Fischer-Tropsch
process. These product include light olefins, synthetic crude (light synthetic crude oil ), heavy
waxy hydrocarbons. Then further treatment of synthetic crude can produce high quality lube
oils, diesel fuel, naptha, aromatic liquid product. Fischer-Tropsch process can be operated on
various operating conditions to produce various types of product for example Fischer-Tropsch
synthesis process is carried out at high temperature of 330-350oC for direct production of light
olefins and gasoline similarly FT process is carried out at low temperature of 220-250oC for
production of diesel fuel and waxes.
Chapter 1
Introduction
2. Chemical Synthesis:
Ammonia :
Large amount of ammonia (85% ) produce world wide is used in the synthesis of fertilizers
while the remaining amount of ammonia is use in other useful application. Every nitrogen
atom which is used in industry in various application is obtained somehow (indirectly or
directly) from ammonia or nitric acid (derivative of ammonia). NH3 is used in the synthesis of
plastics, explosives, fibers for used in polyamides, polyurethane, polyacronitril, fertilizers,
animal feed. Ammonia production process required two main thing firstly nitrogen
concentration should be high and secondly the amount of CO and CO 2 should be limited to less
than 20 ppmV.3 So before using synthesis gas amount of CO and CO2 should be controlled by
using various CO and CO2 removal process. Ammonia production is carried out at temperature
of 350-550oC and at a pressure of 100-250 bar in the presence of suitable catalyst. :
N2 + 3H2
2NH3
Hydroformylation of olefins :
This process is also called as Roelen reaction or oxo-synthesis process for the manufacturing
of aldehydes on commercial scale. It is a catalytic reaction in which reaction take place
between synthesis gas (containing hydrogen and carbon monoxide) and olefins to form
aldehydes. These aldehydes contains additional carbon atom. The reactions occur as shown
below. In this reaction CO and H2 is added catalytically into olefins which result in aldehydes.
H2 + CO + R-CH=CH2
R-CH(CH3)-CHO + R-CH2-CH2-CHO
Alcohols and aldehydes are produce on industrial scale through Hydroformylation reaction.
The most significant products of oxo synthesis are C3-C19. Out of these butanal is one of the
most important product. Most used olefin is propene. The Products of oxo-synthesis is further
converted into aldol-condensation products, carboxylic acid, alcohols, primary amine.
Hydrogen in refineries:
In refineries main source of hydrogen is synthesis gas. Synthesis gas is obtained from heavy oil
through gasification and mainly from natural gas through steam reforming. This hydrogen is
used in refinery for purpose of hydro-treating and in other hydro-processing process.
Hydrogenation of olefins and removal of impurities (nitrogen and desulphurization) is
accomplished by using hydro treating. There are many hydro-treating units in refinery for
hydro treatment of several product fractions which includes heating oil, gasoline, kerosene,
Chapter 1
Introduction
diesel etc and also for pretreatment of feedstock which is used in catalytic cracking process.
On the other hand transportation fuels can by produce from the products obtained as a result
of hydro processing operation. Hydro processing operation basically involves the production of
lighter products from heavy oil fractions. The feed stock requirement for hydro cracking is 4 :
sum of CO2 And CO should be less than or equal to 10-15ppmV, H2 should be more than or
equal to 98% by volume, O2 should be less than or equal to 100 ppmV, inert gas should be less
than 2% by volume.
1.5 Principal Gas Phase Impurities:

The principal gas phase impurities that must be removed by gas purification processes are listed
in Table.
Acid Gas:
It is a gas containing acidic components such as CO2, H2S,COS (carbonyl sulphide), CS2(carbon
sulphide) RSH that can form acidic solutions when mixed with water.
Composition:
Mainly contains of CO2 and H2S gases. Both gases can cause corrosion. These gases are obtained
after a sweetening process applied to a sour gas.
Chapter 1
Introduction
1.6 Gas purification:

It involves the removal of vapor-phase impurities from gas streams. The processes which have
been developed to accomplish gas purification vary from simple once-through wash operations
to complex multiple-step recycle systems.
The primary operation of gas purification processes generally falls into one of the following five
categories:
Chemical
Absorption in to a
liquid
Physical
Adsorption on a
solid
Gas Purification
Permeation through
a membrane
Chemical conversion
to another
compound
Condensation
10
Chapter 1
Introduction
1.6.1 Absorption:
It refers to the transfer of a component of a gas phase to a liquid phase in which it is soluble.
Stripping is exactly the reverse-the transfer of a component from a liquid phase in which it is
dissolved to a gas phase. Absorption is undoubtedly the single most important operation of
gas purification processes.
Chemical Absorption
It is a type of separation process in which absorbent solution (solvent) reacts chemically with
acid gases presence in natural gas to produce compounds. E.g. Gas Sweetening process
The compounds can be dissociated by heating or operating at low pressure of stripping.
Used solvent is regenerated and re-use again
I.
Amine solutions
Amines are of three types.
Primary Amines:
Amines which have two hydrogen atoms directly attached to a nitrogen atom, such as
monoethanolamine(MEA) and 2-(2-aminoethoxy) ethanol (DGA), are called primary
amines and are generally the most alkaline.
Secondary Amines:
Diethanolamine(DEA) and Diisopropanolamine(DPA) have one hydrogen atom directly
attached to the nitrogen atom andarecalled secondary amines.
Primary and secondary amines are known for their non-selectivity, and can remove
comparatively more CO2than H2S from the feed syngas stream.
Tertiary Amines:
Triethanolamine (TEA) and Methyldiethanolamine (MDEA) represent completely substituted
ammonia molecules with no hydrogen atoms attached to the nitrogen, and are called tertiary
amines.
In comparison, a tertiary amine process such as MDEA and physical solvent systems of Selexol
and Rectisol can selectively remove first H2S then CO2
from a feed gas stream, and thus in principal, has a higher degree of control with meeting the
needed clean syngas specification. Also, MDEA has a lower circulation rate and regeneration
energy requirement than primary and secondary amine processes of MEA and DEA
respectively.
11
Chapter 1
Introduction
Table 1.2 Approximate Guidelines for Amine Process5
NOTES:
1. These data alone should not be used for specific design purposes. Many design factors must be considered for actual plant
design.
2. Dependent upon acid gas partial pressures and solution concentrations.
3. Dependent upon acid gas partial pressures and corrosiveness of solution. Might be only 60% or less of value shown for
corrosive systems.
4. Varies with stripper overhead reflux ratio. Low residual acid gas contents require more stripper trays and/or higher reflux
ratios yielding larger
reboiler duties.
5. Varies with stripper overhead reflux ratios, rich solution feed temperature to stripper and reboiler temperature.
6. Maximum point heat flux can reach 20,00025,000 Btu/hr-ft2at highest flame temperature at the inlet of a direct fired fire
tube. The most satisfactorydesign of firetube heating elements employs a zone by zone calculation based on thermal efficiency
desired and limiting the maximum tube wall temperature as required by the solution to prevent thermal degradation. The
average heat flux, Q/A, is a result of these calculations.
7. Reclaimers are not used in DEA and MDEA systems.
8. Reboiler temperatures are dependent on solution conc. flare/vent line back pressure and/or residual CO2content required. It
is good practice to operatethe reboiler at as low a temperature as possible.
9. According to Total.
10. B.L. Crynes and R.N. Maddox, Oil Gas J., p. 65-67, Dec. 15 (1969). The heats of reaction vary with acid gas loading and
solution concentration. Thevalues shown are average
12
Chapter 1
Introduction
Applications of Amine Solutions

a) MEA
Advantages:
used in solution of 15-18 wt%, to avoid corrosion.

Low solvent cost.
Good thermal Stability.
reacts strongly with CO2 and H2S.
High solution capacity at moderate concentrations typically acid gas. Pickup 0.330.40,
mols/mol amine,
contaminated solution can be easily reclaimed.
recommended for treatment of natural gas with low acid gas content (<10%)
enables compliance with strict acid gas specifications.
Disadvantages:
Operation energy consuming.
Required very careful operation of unit.
High corrosion potential than any other alkanolamines.
Non selective removal in a mix acid gas system.
High vapor pressure causes high vaporization losses in low-pressure operation.
easily degraded.
by oxidation
by reaction of COS and CS
by overheating the solution
13
Chapter 1
Introduction
b) DEA
Advantages:
used in 15-20 wt% solution but upgraded from 25-40 wt% solution
reduced in solution circulation flow rate and energy consumption
Greater resistance to degradation than MEA
Low in vapor pressure make DEA losses are reduced
Effective in simultaneously remove CO2 and H2S
Preferable to replace MEA for treatment of natural gas with low acid gas
content
Disadvantages:
Operation energy consuming.

Required very careful operation of unit.
The reclaiming of contaminated solutions is more complex since vacuum distillation may
be required6
14
Chapter 1
Introduction
c) MDEA
Advantages:
used in 35 50 wt% solution.

Selective removal of H2S
it can be partially regenerated ina simple flash
for extraction of H2S and leaving some CO2in treated gas
For production of CO2 with little H2S to enhance oil recovery fluid.
H2S enrichment of acid gas before treatment in Claus unit.
not behave in the same way as MEA and DEA
rate of reaction for MDEA-H2S extremely fast
rate of reaction for MDEA-CO2involves formation of carbonic acid and slow
Lower corrosion rates.
Lower heat of reaction results in lower regeneration energy.
It is more economical with respect to rates of solvent circulation and requirements for
energy7
Disadvantages:
Contact time is too short for absorption of all CO2.

For enhancing CO2 absorption some promoters should have to be added.
Cannot be reclaimed by conventional reclaiming techniques.
15
Chapter 1
Introduction
Reaction of H2S & CO2 with Amine8

Beside the type of amine (primary, secondary. tertiary), a common mechanism applies for the
reaction of H2S.
Reaction 2 is instantaneous; the rate of diffusion of H2S from vapor to liquid phase controls the
rate of absorption of H2S.
For CO2, rate of absorption proceeds by two parallel chemical reaction schemes.
16
Chapter 1
Introduction
Hydration of CO2 to carbonic acid which is then neutralized by amine to give

bicarbonate salt. The absorption of CO2 is limited by usually carbonic acid mechanism.
The second mechanism consists of direct reaction of the amine and CO2 to form a
zwitterionic intermediate which reacts with a second mole of amine to form the amine
carbamate.Only primary and secondary amines such as MEA, DEA, and DGA can react
via the carbamate mechanism. With these classes of amines, carbamate formation is
rapid and the bulk of the CO2 is absorbed in this way.In the carbamate mechanism, two
moles of amine are consumed for each mole of CO2absorbed. Thus, primary and
secondary amines have a maximum practical CO2 loading of 0.5mole/mole.
17
Chapter 1
II.
Introduction
Potassium Carbonate Solutions

specific feature is absorption takes place at high temperature(110-120C)
frequent use of term is hot carbonate
same operating principle as amine process
absorber and regenerator at similar temperatures
has different flow scheme where heat recovery is concerned
performance of conventional process with respect to sales
gas specifications greatly improves by used of additives
known commercial processes are:
Catacarb
Benfield
Giammarco-Vetrocoke
18
Chapter 1
Introduction
PHYSICAL ABSORPTION:
In this process an organic solvent is used to remove the acid gases from syngas. The process is
carried out at low temperatures and high pressures. In physical absorption the loading capacity
of the solvent is mathematically described by Henrys law which states that the absorption is
directly proportional to the partial pressure of the acid gas component in the syngas. Hence the
more the volume of the syngas to be processed, the more is the solvent rate required for the
desired absorption. This is shown in the fig below. During solvent regeneration reboiling is used
along with flashing and stripping which raises the temperature and reduces the solubility of
absorbed aid gases.
Loading Capacity of Solvent Vs Partial Pressure9
Characteristics:
Acid gases dissolve in the solution under pressure and temperature

Favoured by high acid gas partial pressure concentrations (contributed by both pressure
of CO2 and/or H2S) and low temperature
Use solvent is an operating parameter that will dictate the degree of efficiency of
absorption
Solvent is regenerated by low pressure expansion of solution rich in dissolved acid gases
Involves no chemical reaction between acid gases and the solvent
19
Chapter 1
Introduction
Principle Physical Solvents:10
Properties of solvents:
For industrial used, properties of solvents should have:
high solubility with respect to acid gases
low viscosity at operating temperature to facilitate solvent circulation
resistivity to corrosion of carbon steel
high thermal stability, i.e. not degraded under operating conditions (T, P, reaction)
low vapor pressure at operating conditions to minimize solvent loss
reasonable price
20
Chapter 1
Introduction
1.6.2 Adsorption:
It is the selective concentration of one or more components of a gas at the surface of a micro
porous solid. The mixture of adsorbed components is called the adsorbate, and the micro
porous solid is the adsorbent. The attractive forces holding the adsorbate on the adsorbent are
weaker than those of chemical bonds, and the adsorbate can generally be released (desorbed)
by raising the temperature or reducing the partial pressure of the component in the gas phase
in a manner analogous to the stripping of an absorbed component from solution. When an
adsorbed component reacts chemically with the solid, the operation is called chemisorption
and desorption is generally not possible.
Although adsorption can be practiced with many solid compositions, the great majority ofgaspurification and dehydration adsorbents are based on some
form of silica, alumina (including bauxite), carbon, or certain silicates, the so-called molecular
sieves. The silica and alumina-base adsorbents are primarily
used for dehydration, while activated carbon has the specific ability of adsorbing organic vapors
and is very important for this purpose. The molecular sieves have very unusual properties with
regard to both dehydration and the selective adsorption of other compounds.
21
Chapter 1
Introduction
Physical Properties Of Desiccant Materials:11
1.6.3 Membrane Permeation:

It is a relatively new technology in the field of gas purification. Permeation is
a technique that used in separating He and H2from other gases
develop extensively for natural gas treatment
based on difference in permeation rate that characterizes the speed of diffusion of various
constituents through membrane
separation takes place through very fine hollow fibers of micro porous membrane.
fast gases like H2, He He and less content of CO2 and H2S are diffused through membrane
slow gases cannot pass through membrane, only constitute residual gas
22
Chapter 1
Introduction
Permeation rates of Gases12:
Advantages:
Operational simplicity. The one-stage systems have no moving parts. For the two-stage
systems, the addition of the recycle adds some complexity.
Reduced space requirements
Ideal for remote locations
Can be used to debottleneck existing solvent-based plant. In such cases, the membrane
is used for bulk acid gas removal, and the existing solvent-based system is used for the
final cleanup.
contains little or no H2S.
in treating NG very rich in CO2(over 20%)
use lower CO2content to around 2%
Disadvantage:
cannot be widely used until improve in permeability and selectivity of membrane and
resistance to deterioration.
Because membranes use pressure as the driving force of the process, there may be a
considerable energy requirement for gas compression.
23
Chapter 1
Introduction
1.6.4 Chemical conversion:

It is the principal operation in a wide variety of processes, including catalytic and non-catalytic
gas phase reactions and the reaction of gas phase components with solids. The reaction of
gaseous Species with liquids and with solid particles suspended in liquids is considered to be a
special case of absorption and is discussed under that subject.
1.6.5 Condensation:
As a means of gas purification is of interest primarily for the removal of volatile organic
compounds(VOCs) from exhaust gases. This process consists of simply cooling the gas stream to
a temperature at which the Organic compound has a suitably low vapor pressure and collecting
the condensate.
24
Chapter 2
Process Selection
Chapter 2
Process Selection
2.1 PROCESS SELECTION:

Method used for gas treatment has various effects on the overall gas processing process and
facility. It usually affects the methods which are selected for various other processes like acid
gas removal, liquids fractionation, sulfur recovery, liquid product treatment and liquid recovery.
Following points designer must keep in mind while selecting any process for treatment of
gas13:
1. Designer must know the acid gas specifications.
2. The composition of hydrocarbon in gas should be considered.
3. The quantity (concentration ) and types of impurities which are present in the sour gas
must be consider
4. Concentration should be paid to the pressure and temperature of sour gas entering the
system and the required pressure and temperature of sweet gas which should be
obtained after treatment.
5. Residue gas specification should be noted
6. Volume of sour gas which should be treated
7. Selectivity needed for removal of acid gas
8. The environmental authorities regulations and limits regarding air pollution( emission
limits )
9. Operating and capital cost.
10. Specifications of liquid product
11. Selected process royalty cost.
Selection of the process can be done quite easily by examining the chart below shown14:
In our process the the partial pressure of acid gas of the feed (syngas ) is 71.355 psia while
the partial pressure of acid gas in the product is 7.178 psia. By comparing these values on
the chart above shown we get the following result
25
Chapter 2
Process Selection
Our process lies in the region where physical or amine system is feasible. We have to make now
selection between the amine or physical system.
The physical absorption process has draw back compare to other process that it is economically
less feasible when partial pressure of acid gas is low because capacity of physical solvent is
function of partial pressure.
According to Stupin, partial pressure of acid gas above 200 psia is suitable for physical
absorption whereas low partial pressure of acid gas is suit able for alkaline solution absorption.
Schaaf and Tennyson (1977) indicated that chemical solvents are use at partial pressure
between (60-100psia)and above this pressure range physical solvent is used15
From the discussion above made, chemical absorption would be our choice. In chemical
absorption we have different types of amines. We have selected a tertiary amine (Methyl di
ethyl Amine) due to the following distinctions over primary and secondary amines 16.
MDEA serves saving of energy from reduced reboiler duties (reflux ratio 0.5 to 1.0) and
lower overhead condenser duties. Highly selective towards H2S when compared with
CO2, resulting in lower circulation rates and recycling higher quality of acid gas to
sulphur recovery unit.
MDEA can be used in greater concentration thus a greater capacity to react with acid
gas
26
Chapter 2
Process Selection
Usually the concentration 30-50% and 0.4-0.5 moles acid gas pick up per mole of MDEA
has increased the capacity of existing unit and allowed the equipment to be to be
considerably smaller for newer units. High pick up rate and high concentration reflects
lower solvent circulation rates for equivalent capacities
MDEA has less heat of reaction with CO2 and H2S as compared with DEA and MEA
The ranking of corrosivity of amines are as follows

MEA >> DEA >> MDEA
27
Chapter 2
Process Selection
2.2 Process Description:

The synthesis gas first enters the knock out drum followed by absorber in which most of the
absorption takes place. The solvent which is used for extraction of acid gas enters from top of the
absorber.
After the absorption of acid gases in absorber the solvent leaves the absorber from the bottom
and this solvent is called as Rich solvent (contain absorbed acid gases). This rich solvent then
passes through heat exchanger after which its temperature raises. In heat exchanger this rich
solvent exchanges heat with lean solvent coming from the stripper.
This rich solvent then enters in stripper where acid gases and some amount of water vapors are
removed from it and this mixture of water vapor and acid gases passes through the condenser and
then enters separator where water vapors are separated from acid gases. The water which left the
separator from bottom is the pump back to top of stripper column
The solvent which leaves from bottom of stripper is now called as lean solvent as acid gases are
removed from it. This solvent then passes through the heat exchanger where heat exchange takes
place between lean and rich solvent. Then this solvent enters the absorber from its top at
temperature and pressure of 110oF and 432psia respectively.
The typical synthesis gas production required for methanol production17:
The treated gas having H2S content of about 2ppmv is then sent to the ZnO bed to meet the
desired concentration of H2s of 10-5mol % to synthesize methanol
28
Chapter 2
Process Selection
2.3 EQUIPMENTS USED IN THIS PROCESS:

I. Inlet Separator:
The characteristic, objective and alternative equipment of inlet separator are mentioned below :
Objectives:
The main objective of inlet separator is to prevent liquid contaminants from entering in amine
system. These liquid contaminates are mostly hydrogen condensate, water or mist.
Characteristic:
Inlet separator is basically employ demister pad which remove liquid contaminates from carrying
over to amine system. It is a demister containing vertical drum.
Alternatives Equipment:
The equipment which can be used as replacement of inlet separator is Cartridge filter separator
II. Absorber:
The characteristic, objective of Absorber are mentioned below:
Objective:
The main application of absorber is to remove acid gas from the feed.
Characteristic:
There are about to 2 or 3 packing bed or about 20 trays in fractionation column.

To check the level at bottom of column there are three level gasses at bottom.
One other thing which is necessary is this that there should be pressure differential
measuring instruments in column to keep close eye on pressure differential. The slow
pressure differential shows that there is some kind of fouling on bed or tray and the sharp
difference in pressure indicates that there is foaming.
To avoid condensation of hydrocarbon the inlet temperature of lean solution should be
about 5 degree C higher than temperature of feed gas. On the other end if the
temperature of lean solution is much higher then there will be decrease in the amount of
acid gas picked by it and will result in higher loss of water as well
29
Chapter 2
Process Selection
III. Amine Flash Drum:

The characteristic, objective of Amine flash drum are mentioned below:
Objective:
The primary objective of Amine flash drum is to remove entrained liquid hydrocarbon and
dissolved gas prior to sending them to amine/amine heat exchanger& stripper for recovery of
amine solution.
Characteristics:
It basically a three phase horizontal drum.

To obtain good degassing the amine flash drum must be operated at low pressure
The retention time of liquid in the amine flash drum is about 10 to 20 minutes.
Alternative Equipment:
Hydraulic turbine can be used in place of flash drum. Through the use of hydraulic turbine we can
produce power to drive circulation pumps.
IV. Amine/ Amine Heat Exchanger:

The characteristic, objective and alternative equipment of amine/amine heat exchanger are
mentioned below:
Objective:
The function of amine/amine heat exchanger is to heat the rich solution ( acid gas containing
solution ) before sending it to stripper ( regenerator). This reduces the heating load on stripper to
some extent.
Characteristics:
It is shell and tube exchanger having lean solution on shell side whereas rich solution is in
tube side.
To minimize the chances of erosion or corrosion as a result of mix flow, vaporization
should be as minimum as possible in exchanger.
Maximum 1m/s velocity should be allowed.
If more than one exchanger is to be used then exchangers will be installed one above the
other vertically. Rich solution will then enter the bottom exchanger from its lower part
and any released gas will flow out by moving upward alone amine solution.
The inlet temperature of lean solution is about 110-130 degree C
The outlet temperature of rich solution is about 90-110 degree C
30
Chapter 2
Process Selection
Alternative:
The alternative equipment for this purpose is plate frame exchanger . This exchanger offer high
heat transfer rates and larger surface area but are more prone to fouling.
V. Regenerator:
The characteristic, objective of Regenerators are mentioned below:
Objective:
The function of regenerator is to remove acid gases from rich solution by stripping so that rich
amine solution is regenerated.
Characteristics:
There are about to 2 or 3 packing bed or about 20 trays in fractionation column.

One other thing which is necessary is this that there should be pressure differential
measuring instruments in column to keep close eye on pressure differential. The slow
pressure differential shows that there is some kind of fouling on bed or tray and the sharp
difference in pressure indicates that there is foaming.
To prevent loss of amine due to physical entrainment at the tower of regenerator there is
demister pad is installed.
VI. Reboiler:
The objectives, characteristics of Reboiler are shown below:
Objectives:
The main purpose of Reboiler is to add heat to the acid gases containing rich solution to generate
energy for moving the chemical reaction in backward direction which will result in stripping of acid
gases from rich solution and reboiler also produce steam required to remove acid gases. The
overhead reflux ratio governed the efficiency of stripping.
Characteristics:
The reboiler mostly use is kettle type. The recommended tube pitch is square.
The outlet temperature of the regenerated solution depends on amine strength and
operating pressure.
The heating medium rate controls the duty of reboiler.
The prevent amine degradation the temperature of less than 145 degree C is
recommended for tube skin.
31
Chapter 2
Process Selection
To enhance the good natural circulation, space should be left below the bundle. This space
will also provide place for sludge deposition.
To avoid overheating and localized drying the layer of liquid should be high enough that it
totally covers the tube bundle.
Vapor volume should be high enough to prevent solution entrainments.

VII. Reflux Drum:
The objectives, characteristics of Reflux drum are shown below:
Objective:
The purpose of refuel drum is to recover the condensed water in condenser as stripper reflux and
also to remove any condensed hydrocarbon.
Characteristics:
It is a demister pad containing horizontal or vertical drum.

The temperature in the reflux drum should be as low as possible to prevent or
minimize concentration of water entrainment and amine to downstream facilities.
The facilities of oil skimming should be provided.

VIII. Surge Tank:
The objectives, characteristics of surge tank are shown below:
Objectives:
Surge tank has spare capacity equal to that of amine solution hold up for maintenance unloading
or emergency
Characteristics:
This is a cone roof or fixed roof Atmospheric storage tank.

To prevent degradation of amine with oxygen blanketing is done with treated gas or
nitrogen.
The operating temperature in surge tank should be higher than the freezing point of
solution.
32
Chapter 2
Process Selection
2.4 Process Flow Diagram for Amine Sweetening Process:
33
Chapter 3
Material Balance
Chapter 3
Material Balance
3.1 Introduction:
A mass balance (also called material balance) is an application of law of conservation of mass to
the analysis of physical systems. By accounting for material entering and leaving the system,
mass flows c a n b e identified which might have been unknown or difficult to measure without
this technique. The exact conservation law used in the analysis of system depends on the
context of problem but all revolve around mass conservation. That is that matter cannot
disappear or be created spontaneously.
The general form quoted for a mass balance is the mass that enters a system must, by
conservation of mass, either leave the system or accumulate within the system.
Mathematically the mass balance for a system within the system without chemical reaction is
as follows.
Input = Output + Accumulation

Strictly speaking the above equation holds also good for systems with chemical reactions if the
terms in the equation are taken to refer to total mass i-e the sum of chemical species of the
system. In the absence of chemical reactions the amount of any chemical species flowing in and
out will be same; This gives rise to an equation for each species in the system. However if this is
not the case then the mass balance equation must be amended t0 allow for the generation or
depletion (consumption) of each chemical species. Some use one term in this equation to
account for chemical reactions, which will be negative for depletion and positive for generation.
However, the conventional form of this equation is written to account for both a positive
generation term (i.e. product of reaction) and a negative consumption term (the reactants used
to produce the products). Although overall one term will account foi the total balance on the
system, if this balance equation is to be applied to an individual species and then the entire
process, both terms are necessary. This modified equation can be used not only for reactive
systems, but for population balances such as occur n particle mechanics problems. The
equation is given below; Note that it simplifies to the arlier equation in the case that the
generation term is zero.
Input + Generation = Output + Accumulation + Consumption

In the absence of a nuclear reaction the number of atoms flowing in and out are the same, even
in the presence of a chemical reaction. To perform a balance the boundaries of the system
must be well defined Mass balances can be taken over physical systems at multiple scales. Mass
balances can be simplified with the assumption of steady state, where the accumulation term is
zero 1>5.
34
Chapter 3
Material Balance
Here an assumption is taken that there is no chemical reaction is taking place and our system is
steady state process. Hence
Mass in = Mass out
3.2 Synthesis Gas Composition:18

Design Basis: 208mmscfd =22167
Component
H2
CO2
CO
H2O
CH4
C2H4
C2H6
C6H6
C10H8
NH3
H2S
N2
Mole %
0.3198
0.1658
0.1462
0.3541023
0.01316
8.35E-5
1.65E-5
2.54E-5
7.05E-7
7.696E-5
0.000336
0.000379
Molar Flow
lbmole/hr
7089
3675.648
3242.0364
7849.63
291.4674
1.86654
0.373308
0.563
0.01563
1.706
7.46616
8.32764
35
Chapter 3
Material Balance
3.3 Inlet Gas Separator:

Vapor (V)
300
Feed (F)
205
Condensate Liquid (L)

301
Our inlet gas separator has a temperature of 110 F, so those components which have critical
temperature less than 110 F will remain in gas phase. Otherwise they will be in liquid phase.
Gaseous Phase Components
Liquid Phase Components
H2
H2O
Co2
NH3
CO
C6H6
CH4
C10H8
C2H4
C2H6
H2S
N2
36
Chapter 3
Material Balance
Hydrogen Sulfide has not critical temperature less than 110 F but it has a very high vapor
pressure so that at this temperature of inlet gas separator, H2S will be present in gas phase.
According to Roult,s Law,
Ya = Mole fraction of component in vapor

Xa= Mole fraction of component in liquid
Pva= vapor pressure of component
P= Total pressure (in PSI)
Antoine Equation,
Where A,B and C are constants

T = Temperature in kelvin K
P*= Saturated vapor pressure in mmHg
Inlet gas separator temperature = 110F =316.33K
Component
ln(P*)
(P*)psi
(P*)mmHg
H2O
18.3036
3816.44
-46.13
4.179
1.263
65.30
NH3
16.9481
2132.50
-32.98
9.42
238.52
4536.9
C6H6
15.9008
2788.51
-52.36
5.33
4.02
206.44
C10H8
16.1426
3992.01
-71.29
-0.06
.0182
0.94
37
Chapter 3
Material Balance
Vapor pressure determination using Antoine Eq. is given as follows.

P = 429.5psi
Using Roult,s Law,
1. For Water:
XH2O = 2.9406 x 10-3 XH2O
YH2O =
(1)
2. For Ammonia:
YNH3 =
XNH3 = 0.555 XNH3
(2)
3. For Benzene:
XC6H6 = 9.35 x 10-3 XC6H6
YC6H6 =
(3)
4. For Naphthalene:
YC10H8 =
XC10H8 = 4.23 x 10-5 XC10H8
(4)
Overall material Balance on Inlet gas Separator

Using Component Balance
I.
For H2:
7089.5 = XH2L + YH2V
As it is only present in Vapor phase, so XH2L = 0
7089.5 = YH2V
YH2 =
II.
For CO2:
3674.73 = YCO2 V
YCO2 =
III.
(7)
For CH4:
291.69 = YCH4 V
YCH4 =
V.
(6)
For CO:
3241.36 = YCO V
YCO =
IV.
(5)
(8)
For C2H4:
1.86 = YC2H4 V
38
Chapter 3
Material Balance
YC2H4 =
VI.
(9)
For C2H6:
0.367 = YC2H6 V
YC2H6 =
VII.
(10)
For H2S:
7.44= YH2S V
YH2S =
Viii.
(11)
For N2:
8.39 = YN2 V
YN2 =
IX.
(12)
For H2O:
7849.39 = XH2O L + YH2O V
From Eq.1
7849.39 = YH2O/2.9406 x 10-3 L + YH2O V
7849.39 = YH2O { L (340.136) + V }
YH2O =
X.
For NH3:
1.706 = XNH3 L + YNH3 V
From Eq.2
1.706 = YNH3/0.555 L + YNH3 V
1.706 = YNH3 {1.80 L +V}
YNH3 = *
XI.
(14)
For C6H6:
2.44 = XC6H6 L + YC6H6 V
From Eq.3
2.44 = YC6H6/9.35 x 10-3 L + YC6H6 V
2.44 = YC6H6 {106.95 L + V}
YC6H6 =
XII.
(13)
(15)
For C10H8:
0.0156 = X C10H8 L + YC10H8 V
From eq.4
0.0156 = YC10H8/4.23 x 10-5 L + YC10H8 V
0.0156 = YC10H8 {23640.6L + V}
YC10H8 = *
(16)
39
Chapter 3
Material Balance
Now , we know that
Adding all the mole fractions (adding eq. 5 to eq.16)

1=
+
*
+
+
+*
+*
Multiplying by V on both sides

V=V[
+*
+*
+*
We know that
L = 22167 V
Putting this value in above Equation and solving by computer program
V = 14358
L = 22167 14358
L = 7809
By putting the value of V in Eq. (5 to 16) , we get
Composition of stream 300:
YH2
0.494
YC02
0.256
YCO
0.2258
YCH4
0.0203
YC2H4
0.00013
YC2H6
0.000026
YH2S
0.00052
YN2
0.00058
YH2O
0.00294
YC6H6
2.87 x 10-6
YNH3
6.0 x 10-5
YC10H8
8.5 x 10-11
40
Chapter 3
Material Balance
3.4 Mass Balance on Absorber:

302
H2S 4ppm
CO2 2 mole%
311
Amine recirculation rate
300
V = 14358
303
E
For stream 300:
Component
H2
CO2
CO
H2O
CH4
C2H4
C2H6
C6H6
C10H8
NH3
H2S
N2
Mole %
0.494
0.256
0.2258
0.00294
0.0203
0.00013
0.000026
0.00000287
8.5E-11
0.00006
0.00052
0.00058
Molar Flow
7092.852
3675.648
3242.0364
42.21252
291.4674
1.86654
0.373308
0.04120746
1.22043E-06
0.86148
7.46616
8.32764
41
Chapter 3
Material Balance
Amine Circulation rate:

For MDEA,
(
GPM =
Where Gas Flow = 135mmscfd

H2S = mole % of H2S to be removed = 0.0518%
CO2 = mole % of CO2 to be removed = 23.6%
M.wt = molecular weight of amine = 119.16
ML = acid gas loading i-e
= 0.40
Wt = amine solution weight percent re-circulated = 50%

So,
(
GPM =
GPM = 3919
Solution density at standard state = 8.68
Then ,
3919
x 8.68
= 2041015.2
Using recommended 15% safety factor, lean amine flow rate = 2041015.2
x 1.15
= 2347167.48
We know , re-circulated MDEA contains
. We assume that H2S is completely
stripped off, so only CO2 is present in re-circulated amine.

Amine present in solution = 0.50 x 2347167.48
= 1173583.74
42
Chapter 3
Material Balance
= 9848.80
So,
Acid gas present (CO2)
= 49.24
= 2166.689
Water present in solution = 0.50 x 2347167.48

= 1173583.74
Moles of water
=
= 65200
Lean amine re-circulation rate (including acid gas) = 65200 + 9848.589 + 49.24
= 75098
We can write,
D = 10680.037 + 0.02D + 4 x 10-6
D = 10680.037 + 0.0200D
D = 10898
In D stream,
CO2 = 10898 x 0.02
CO2 = 217.96
= 9590.24
H2S = 10898 x 4 x 10-6

H2S = 0.0218
= 0.7412
In E stream,
CO2 = 161728.5 + 2166.689 9590.24
43
Chapter 3
Material Balance
CO2 = 154304.95
= 3507.28
H2S = 253.844 0.7412

H2S = 253.1028
= 7.44
H2O = 759.834 + 1173583.74 759.834

H2O = 1173583.74
= 65200
308
MDEA = 9848.589
3.5 Mass balance on Stripper:

306
312
305
309
307
Inlet stream 305:
Out Stream 307:
MDEA = 1173583.74
MDEA = 1173583.74
Water = 1173583.74
Water = 1173583.74
44
Chapter 3
Material Balance
H2S = 254.218
CO2 = 2166.68
CO2 = 154308
CO2 in C stream would be as = 154308 2166.68

= 152141.32
H2S in C stream would be as = 254.218 0
= 254.218
Usually 0.8% water is lost in c stream
So, = 0.8% x 1173583.74 = 9388.66
Make up water is added usually to replenish this loss
So, make up water = 9388.66
C stream would be as:
CO2 = 152141.32
H2S = 254.218
H2O = 9388.66
Total flow rate of C stream = sum of all = 161784.198
45
Chapter 3
Material Balance
3.6 Balance across over-head separator:

308
313
312
309
Inlet stream 313:
Outlet stream 308:
CO2 =?
CO2 = 152141.31
H2S =?
H2S = 254.218
H2O =?
H2O = 9388.66
Reflux stream 309 = D=?
Stream C = makeup water
Our reflux drum has a temperature of 130 F , so those components which have a critical
temperature less than 130 F will remain in gaseous phase otherwise they would remain in
liquid phase.
Gaseous phase components
Liquid phase components
CO2
H2O
H2S
So feed stream contain same CO2 and H2S as in the vapor phase.i-e
CO2 = 152141.32
and H2S = 254.214
46
Chapter 3
Material Balance
It is reported that reflux ratios between
to mole of water per mole of acid gas are generally
used to make the process work properly.19

Moles of acid gas above reflux drum
= 3548 + 7.447
= 3465.477
Taking reflux ratio as
Reflux 309 stream (D) would be
= 1.26 x 3465.477
= 4366.501
= 78597
of water
3.7 Balance across the overhead reflux drum:

Water:
AH2O + 9388.66 = 9388.66 + 78597
AH2O = 78597
Stream A will now become
CO2 = 152141.31
H2S = 254.218
H2O = 78597
Total flow = 230992.33
3.8 Overall material balance:

Feed + makeup water = sweet gas + condensate + acid gas
413207 + 9388.66 = 120291.5 + 140568 + 161784.198
422595.66
= 422643.7
47
Chapter 4
Energy Balance
Chapter 4
Energy Balance
4.1 Introduction:
As with mass, energy can be considered to be separately conserved in all but nuclear process.
The conservation of energy, however differ from that of mass in that energy can be generated
(or consumed) in a chemical process. Material can change form, new molecular species can be
formed by chemical process, but total mass flow into a process unit must be equal to flow out
at the steady state. The same is not true of energy. The total enthalpy of outlet streams will not
equal to that of inlet streams if energy is generated or consumed in the process; such as that
due to heat of reaction. Energy can exist in several forms: heat, Mechanical energy, electrical
energy, and these are the total energy that is conserved. In process design, energy balance are
made to determine the energy requirements of the process: heating, cooling and power
required. In plant operation, energy balance (energy audit) on the plant will show the pattern
of the energy usage, suggest areas for conservation and savings.
4.2 Conservation of Energy:

As for material, a general equation can be written for the conservation of energy:
Energy out = energy in + generation consumption accumulation
It is the statement of first law of thermodynamics. An energy balance can be written for any
process step. Chemical reaction will evolve energy (exothermic) or consume energy
(endothermic). For steady state processes, the accumulation of both mass and energy will be
zero. Energy can exist in many forms and this, to some extent, makes an energy balance more
complex than material balance.
In our project we are using the steady state energy balance i.e
Amount of heat in = Amount of heat out
As we are using the relation given below for the calculation of heat
Q= m Cp T
Where
Q = Amount of heat
M = mass
Cp = specific heat
T = Given Temperature reference temperature
48
Chapter 4
Energy Balance
4.3 Forms of Energy:

i.
Potential energy:
Energy due to position;

Potential energy = gz
Where z = height above some arbitrary datum, m
G = gravitational acceleration (9.8 m/s2)
ii.
Kinetin energy:
Energy due to motion;

Kinetin energy = u2/2
Where u = velocity, m/s
iii.
Internal energy:
The energy associated with molecular motion. The temperature T of the material is a measure
of its internal energy U;
U = f(T)
iv.
Work:
Work is done when a force acts through a distance;

W = FD
Where F = force
D = Distance
v.
Heat:
Energy is transferred either as heat or work. A system does not contain Heat but the transfer
of heat or work to a system changes its internal energy. Heat taken in by a system from its
surrounding is conventionally taken as positive and that given out as negative.
vi.
Electrical energy:
Electrical and mechanical forms of energy are included in the work term in an energy balance.
Electrical energy will only be significant in an energy balance on electrochemical processes.
49
Chapter 4
Energy Balance
4.4 Inlet Separator:

300
205
Syn gas
301
General Energy Balance Equation:Q- s =H+Ex+Ep
(1)
Assumption:Negligible effect of Ep and Ex so we take

Ex=0 ; Ep=0
No moving parts , Hence
s=0
Equation (1) reduces to
Q = H
(2)
Energy balance on different streams link with Inlet Separator:

Reference temperature is 77F
For Stream No 205 :

Components:
50
Chapter 4
I.
Energy Balance
Hydrogen:
Formula used is Q = oCpT

o(Molar flow rate )=7093.44
Cp= 6.9
Q= o x Cp x T
Q= 7093.44 x6.9x33
Q=1615176.288
II.
Carbon Dioxide CO2:

Cp=9.12
Cp= 6.97
Q= o x Cp x T
Q=3657.555x9.12 x33
Q=1100777.753
III.
Carbon Monoxide CO:

Q= o x Cp x T
Q=3236.382 x 6.97 x 33
Q=744400.2238
IV.
Water H2O

Cp=17.98
Q= o x Cp x T
Q= 7862.6349 x 17.98 x33
Q=46611`5215.792
51
Chapter 4
V.
Energy Balance
Methane CH4:

Cp=8.7
Q= o x Cp x T
Q= 288.171 x 8.7 x 33
Q= 82733.8941
VI.
Ethylene C2H4:

Cp= 10.7
Q= o x Cp x T
Q= 1.8575 x 10.7 x 33
Q=655.91665
VII.
Ethane C2H6:

o(Molar flow rate )= 0.36
Cp= 13.09
Q= o x Cp x T
Q= 0.3657 x 13.09 x 33
Q= 157.9954
VIII.
Benzene C6H6:

Cp= 21.13
Q= o x Cp x T
Q= 0.563 x 21.13 x 33
Q= 392.60
52
Chapter 4
IX.
Energy Balance
Tar C10H8:

Cp=33.88
Q= o x Cp x T
Q= 0.01562 x 33.88 x 33
Q= 17.47
X.
Ammonia NH3:

Cp= 8.63
Q= o x Cp x T
Q= 1.76 x 8.63 x 33
Q= 502.5100184
XI.
Hydrogen Sulphide H2S:

Cp=8.63
Cp= 6.97
Q= o x Cp x T
Q= 7.448112 x 8.63 x 33
Q= 2022.832738
XII.
Nitrogen:

Q= o x Cp x T
Q= 8.401x 6.97 x 33
Q=1932.381403
53
Chapter 4
Energy Balance
Total heat (Q) of this stream is = 8213985.662
For Stream No 301:

Components:
I.
Water H2O

Cp=17.98
Q= o x Cp x T
Q= 7808.2191 x 17.98 x33
Q=4632928.721
II.
Benzene C6H6:

Cp= 21.13
Q= o x Cp x T
Q= 0.05356974 x 21.13 x 33
Q= 37.353644
III.
Tar C10H8:

Cp=33.88
Q= o x Cp x T
Q= 0.01562 x 33.88 x 33
Q= 17.47
IV.
Ammonia NH3:

Cp= 8.63
54
Chapter 4
Energy Balance
Q= o x Cp x T
Q= 0.843372 x 8.63 x 33
Q=240.1839119
Total Heat for Stream 301 is 4633223.702
For Stream 300:

Components:
I.
Hydrogen:

Cp= 6.9
Cp=9.12
Q= o x Cp x T
Q= 7092.852 x6.9x33
Q=1615042.4
II.
Carbon Dioxide CO2:

Q= o x Cp x T
Q=3675.648 x 9.12 x33
Q=1106223.022
III.
Carbon Monoxide CO:

Cp= 6.97
Q= o x Cp x T
Q=3242.0364 x 6.97 x 33
Q=745700.7924
55
Chapter 4
IV.
Energy Balance
Water H2O

Cp=17.98
Cp=8.7
Q= o x Cp x T
Q= 42.21252 x 17.98 x33
Q=25046.37662
V.
Methane CH4:

Q= o x Cp x T
Q= 291.4674 x 8.7 x 33
Q= 83680.29054
VI.
Ethylene C2H4:

Cp= 10.7
Q= o x Cp x T
Q= 1.86654 x 10.7 x 33
Q=659.075274
VII.
Ethane C2H6:

Cp= 13.09
Q= o x Cp x T
Q= 0.373308 x 13.09 x 33
Q= 161.2578568
56
Chapter 4
VIII.
Energy Balance
Benzene C6H6:

Cp= 21.13
Q= o x Cp x T
Q= 0.041 x 21.13 x 33
Q= 28.73354978
IX.
Tar C10H8:

o(Molar flow rate )= 1.22043E-06
Cp=33.88
Q= o x Cp x T
Q= 1.22043E-06x 33.88 x 33
Q= 17.47
X.
Ammonia NH3:

Cp= 8.63
Q= o x Cp x T
Q= 0.86148 x 8.63 x 33
Q= 245.34
XI.

Cp=8.23
Q= o x Cp x T
Q= 7.46616 x 8.63 x 33
Q= 2027.734394
57
Chapter 4
XII.
Energy Balance
Nitrogen:

Cp= 6.97
Q= o x Cp x T
Q= 8.32 x 6.97 x 33
Q=1915.440476
Total Q for stream 300 is 3580730.466

So Over all on Inlet Separator Heat IN= Heat out
3580730.466
=(4633244.686+8213985.662)
58
Chapter 4
Energy Balance
4.5 Absorber:
302
311
300
303
(1)
Assumption:1. Negligible effect of Ep and Ex so we take

Ex=0 ; Ep=0
2. No moving parts , Hence
s=0
Q = H
(2)
59
Chapter 4
Energy Balance
Energy Balance on different streams related to Absorber

Reference Temperature = 77F
For Stream 300 :

Components:
I.
Hydrogen:

Cp= 6.9
Cp=9.12
Q= o x Cp x T
Q= 7092.852 x6.9x33
Q=1615042.4
II.
Carbon Dioxide CO2:

Q= o x Cp x T
Q=3675.648 x 9.12 x33
Q=1106223.022
III.
Carbon Monoxide CO:

Cp= 6.97
Q= o x Cp x T
Q=3242.0364 x 6.97 x 33
Q=745700.7924
60
Chapter 4
IV.
Energy Balance
Water H2O

Cp=17.98
Cp=8.7
Q= o x Cp x T
Q= 42.21252 x 17.98 x33
Q=25046.37662
V.
Methane CH4:

Q= o x Cp x T
Q= 291.4674 x 8.7 x 33
Q= 83680.29054
VI.
Ethylene C2H4:

Cp= 10.7
Q= o x Cp x T
Q= 1.86654 x 10.7 x 33
Q=659.075274
VII.
Ethane C2H6:

Cp= 13.09
Q= o x Cp x T
Q= 0.373308 x 13.09 x 33
Q= 161.2578568
61
Chapter 4
VIII.
Energy Balance
Benzene C6H6:

Cp= 21.13
Q= o x Cp x T
Q= 0.041 x 21.13 x 33
Q= 28.73354978
IX.
Tar C10H8:

Cp=33.88
Q= o x Cp x T
Q= 1.22043E-06x 33.88 x 33
Q= 0.00136449
X.
Ammonia NH3:

Cp= 8.63
Q= o x Cp x T
Q= 0.86148 x 8.63 x 33
Q= 245.34
XI.

Cp=8.23
Q= o x Cp x T
Q= 7.46616 x 8.63 x 33
Q= 2027.734394
62
Chapter 4
XII.
Energy Balance
Nitrogen:

Cp= 6.97
Q= o x Cp x T
Q= 8.32 x 6.97 x 33
Q=1915.440476
For Stream 302 :

Components:
I.
Hydrogen:

Cp= 6.9
Q= o x Cp x T
Q= 7092.852 x6.9x33
Q=1615042.4
II.
Carbon Dioxide CO2:

Cp=9.12
Q= o x Cp x T
Q=217.96 x 9.12 x33
Q=655597.2416
III.
Carbon Monoxide CO:

Cp= 6.97
63
Chapter 4
Energy Balance
Q= o x Cp x T
Q=3242.0364 x 6.97 x 33
Q=745700.7924
IV.
Water H2O

Cp=17.98
Cp=8.7
Q= o x Cp x T
Q= 42.21252 x 17.98 x33
Q=25046.37662
V.
Methane CH4:

Q= o x Cp x T
Q= 291.4674 x 8.7 x 33
Q= 83680.29054
VI.
Ethylene C2H4:

Cp= 10.7
Q= o x Cp x T
Q= 1.86654 x 10.7 x 33
Q=659.075274
VII.
Ethane C2H6:

Cp= 13.09
Q= o x Cp x T
64
Chapter 4
Energy Balance
Q= 0.373308 x 13.09 x 33
Q= 161.2578568
VIII.
Benzene C6H6:

Cp= 21.13
Q= o x Cp x T
Q= 0.041 x 21.13 x 33
Q= 28.73354978
IX.
Tar C10H8:

Cp=33.88
Q= o x Cp x T
Q= 1.22043E-06x 33.88 x 33
Q= 0.00136449
X.
Ammonia NH3:

Cp= 8.63
Q= o x Cp x T
Q= 0.86148 x 8.63 x 33
Q= 245.34
XI.

Cp=8.23
Q= o x Cp x T
65
Chapter 4
Energy Balance
Q= 0.0218 x 8.63 x 33
Q= 5.920662
XII.
Nitrogen:

Cp= 6.97
Q= o x Cp x T
Q= 8.32 x 6.97 x 33
Q=1915.440476
For Stream 303 :

Components:
I.
Carbon Dioxide CO2:

o(Molar flow rate )=3507
Cp=9.38
Q= o x Cp x T
Q=3507 x 9.38 x75
Q=2467174.5
II.
Water H2O

Cp=18.02
Q= o x Cp x T
Q= 65602 x 18.02 x75
Q=88117800
66
Chapter 4
III.
Energy Balance

Cp=8.3
Q= o x Cp x T
Q= 7.477232968x 8.3 x 75
Q= 4654.577523
IV.
MDEA:

o (Molar flow rate )=9849
lbmol/hr ,
Cp= 69.04
Q= o x Cp x T
Q= 9849 x 69.04 x 75
Q=
50998122
For Stream No 311:

Components:
I.
Carbon Dioxide CO2:

Cp=9.12
Cp=18.02
Q= o x Cp x T
Q=49.24 x9.12 x33
Q=`14819.2704
II.
Water H2O

67
Chapter 4
Energy Balance
Q= o x Cp x T
Q= 65602 x 18.02 x33
Q=38771832
III.
MDEA:

o(Molar flow rate )= 9849
Cp= 65.33
Q= o x Cp x T
Q= 9849 x 65.33 x 33
Q=
21233360.61
Total Heat for Stream 306 is 60020011.88

For Absorber Heat of reaction = Heat out Heat in= Stream(300 +306 )Stream (302-307)= -80525091.6
68
Chapter 4
Energy Balance
4.6 Lean Solvent Exchanger:
310
311
E-1
For stream 310:

Temperature = 177F
Difference in temperature is =T= 100F
QMDEA= oCpT= 9849 x 71.25 x 100 =70174125
Qwater= oCpT =65200 x 18.07 x 100 = 117816400
QCarbon Dioxide= oCpT = 49.24 x 9.53 x 100 = 46925.72
Heat In = 70174125+117816400 +46925.72

Heat in = 188037450.7
For stream 311:

Temperature = 110 F
Difference in temperature = T= 33F
QMDEA= oCpT=9849 x 64 x 33= 20801088
Qwater = oCpT= 665200x 17.5 x 33 = 37653000
Qcarbon Dioxide = oCpT= 4924 x 912 x 23 = 14819.27
Heat Out = 20801088+37653000 +14619.27

Heat Out= 5846890
QDuty = Heat in - Heat Out
= 129568543.4 BTU/hr OR 129.568
69
Chapter 4
Energy Balance
4.7 Lean/Rich amine exchanger:
(1)

Ex=0 ; Ep=0
s=0
Q = H
(2)
Difference in temperature is =T= 99 F

QMDEA= oCpT= 9849 x 73.28 x 99 =71448756
Qwater= oCpT =65200 x 18.13 x 99 = 117025524
QCarbon Dioxide= oCpT = 49.24 x 9.65 x 99= 47041
Heat out = 71448756+117025524 +47041

Heat out = 188521321
70
Chapter 4
Energy Balance
Difference in temperature is =T= 181F

QMDEA= oCpT= 9849 x 73.28 x181=130628533
Qwater= oCpT =65200 x 18.13 x 181 = 213955756
QCarbon Dioxide= oCpT = 49.24 x 9.65 x 181 =160602.17
Heat In = 130628533+213955756+160602.17
Heat in = 344744891
QDuty = Heat in - Heat Out
= 156223570 BTU/hr OR 156.22
4.8 Over head Stripper Condenser:
306
313
Energy balance on streams Linked with Stripper Condenser

For Stream 306
I.
Carbon dioxide CO2

Cp= 9.67
Q= o x Cp x T
Q= 3457.757 x 9.67 x 126
Q= 4213000.284
II.
Hydrogen Sulphide H2S
71
Chapter 4
Energy Balance
Cp= 8.4
Q= o x Cp x T
Q= 7.477 x 8.4 x 126
Q=7913.6568
III.
Water H2O

Cp= 18.14
Q= o x Cp x T
Q= 4366.5 x 18.14 x 126
Q= 9980247.06
Total Heat (Q) for stream IN = 14201161
For stream 313:

I.
Carbon dioxide CO2

Cp= 9.25
Q= o x Cp x T
Q= 3457.757 x 9.25 x 53
Q= 1695165
II.
Water H2O

Cp= 17.99
Q= o x Cp x T
Q= 4366.5 x 17.99 x 53
Q=3273.281
72
Chapter 4
III.
Energy Balance

Cp= 8.26
Q= o x Cp x T
Q= 7.477 x 8.26 x 53
Q= 4163327
Total Heat (Q) for stream OUT = 5861765

Heat IN Heat OUT = -8339395.6
73
Chapter 4
Energy Balance
4.9 Stripper:
306
309
305
307
Energy balance on different streams linked with stripper
(1)

Ex=0 ; Ep=0
s=0
Q = H
(2)
74
Chapter 4
Energy Balance
Reference Temperature = 77F
For Stream 305

Components:
I.
MDEA

Cp= 0.615
Cp= 1.007
Q= o x Cp x T
Q= 1173584 x 0.615 x 123
Q= 88775742
II.
Water H2O

Q= o x Cp x T
Q= 1173584 x 1.007 x 123
Q= 145361256
III.

Cp= 0.219
Q= o x Cp x T
Q= 254.218 x 0.219 x 123
Q= 6847.8703
IV.
Carbon Dioxide CO2

Cp= 0.246
75
Chapter 4
Energy Balance
Q= o x Cp x T
Q= 154308 x 0.246 x 123
Q= 238812897
Total Heat (Q) for stream A = 23812897
For Stream 307:

I.
MDEA

Cp= 0.658
Cp= 1.018
Q= o x Cp x T
Q= 1173584 x 0.658 x 181
Q= 139771476
II.
Water H2O

Q= o x Cp x T
Q= 1173584 x 1.018 x 181
Q= 216242193
III.
Carbon Dioxide CO2

o (Molar flow rate) = 2166.68
Cp= 0.226
Q= o x Cp x T
Q= 2166.68 x 0.226 x 181
Q=356102299
Total Heat (Q) for stream B = 356102299
76
Chapter 4
Energy Balance
For stream 306:

Components
I.
Carbon dioxide CO2

Cp= 0.22
Q= o x Cp x T
Q= 152141.3 x 0.22 x 126
Q= 4217357.4
II.
Water H2O

Cp= 1.007
Q= o x Cp x T
Q= 78597 x 1.007 x 126
Q=9972544.6
III.

Cp= 0.246
Q= o x Cp x T
Q= 254.218 x 0.246 x 126
Q= 7879.7411
Total Heat (Q) for stream D = 14197782
For (309) Reflux Stream:
77
Chapter 4
Energy Balance
Components
I.
Water H2O

Cp= 0.999
Q= o x Cp x T
Q=78597 x 0.999 x 53
Q= 4161475
Heat of Reaction =-80525091.6

Reboiler heat Hb
= (Total Q for stream B + Total Q for stream D)-(Total Q for stream A+ Heat of
reaction+ Total Q for reflux stream)
=207850800
78
Chapter 4
Energy Balance
4.10 Energy Balance across Hydraulic Turbine:

303
152 F
445 Psia
304
30 Psia
T= ?
(1)
Assumption:3. System is perfectly insulated (no heat loss ) i.e Q=0

4. Negligible effect of Ep and Ex so we take
Ex=0 ; Ep=0
- s = H
(2)
5. Assuming that the volume remain constant ( i.e process streams are liquid )
Calculation of the shaft work:W= v.dp + P.dv
dv = 0 according to condition (3)
So
W= v(P2 P1)
(3)
Density of rich MDEA = 30.896
79
Chapter 4
Energy Balance
Average Molecular weight of rich MDEA = 31.86

Molar flow rate (inlet & outlet) = o= 78563.47
Volume of inlet and outlet stream
V= 78563.471 lbmol/hr x 31.86 lbm/lbmol x ft3/30.896 lbm
V= 81014.76521 ft3/hr
(4)
Putting Eq (4) in Eq (3)

W= V (P2 P1)
=81014.765 ft3/hr x (445 -30)psia x (1m3/(3.28)3ft3) x (101325 pa/14.7psia)
= 6567347847
Converting to horse power:=656734784 J/hr x 1BTU/1055J x 1 hp/2544.433

s =2446.50 hp
Assuming 50% (Adiabatic Efficiency ):s = 1223.25 hp

Putting this in equation (2)
- s = H
-1223.25= oCp(T2-T1)
Let Cp be constant
o= 78563.471
Average Cp= 25.67
Now putting these values
= -1223.25hp x 760 watts/1hp x ((1J/s)/1 watts) x (1 BTU/1055J) x
(1lbmol
F/2567BTU) x (hr/ 78563.467 lbmol) x (3600s / 1hr )

-1.573 = T2-T1
-1.573 + T1=T2
-1.573 + 152 = T2
150.42 F= T2
80
Chapter 5
Equipment Design
Chapter 5
Equipment Design
5.1 Inlet Separator:

Design of Separator:
Here we will read about following topics:
Basic Function of separators.

Different types of separators.
Criteria for selecting separator.
Method for designing separator.
Basic Principle:
The main purpose of separator is to separator liquid from vapor and vice versa. This separation
is accomplished by providing velocity low enough so that vapor get separated from liquid.
Gravity plays vital role in this separation along with density difference.
Different types of separators:

Basically there are three different types of liquid vapor separator:
Horizontal vapor liquid separator.

Vertical vapor liquid separator.
Knock-out drums.
a) Horizontal vapor liquid separator:

This type of separator is used when liquid contents are sufficiently high and when L/D (length to
diameter ratio) is great than 5.
b) Vertical vapor-liquid separator:

This type of separator is used when liquid contents are low and when L/D (length to diameter
ratio) is great than 3 and less than 5.
c) Knock-out drums:
This type of separator is used when very low liquid content are present in inlet stream. Due to
this reason Knock out drum is mostly installed on compressor inlet stream to stop liquid from
going in the compressor and damaging it.
81
Chapter 5
Equipment Design
Criteria for selecting separator:

Knock out drum is mostly installed on compressor inlet stream to stop liquid from going in the
compressor and damaging it. So this cannot be included in selection criteria.
As far as vertical and horizontal separator are concerned both have same designing procedure
and have same design calculations but they only differ in one parameter that is value L/D ratio.
If L/D ratio is greater than 5 than Horizontal is use if it is between 5 and 3 than vertical is used .
Method for designing separator:

Vapor volumetric rate = 1.58
Liquid volumetric rate =0.01784
Density of vapor= 1.353
= 21.67
Density of liquid = 62.2
= 996.348
1. Calculation of settling velocity of liquid droplets:

(
20
= Liquid density,
= vapour density,
= settling velocity,
(
2. Calculation of maximum superficial vapor velocity given by following

equation:
= Maximum velocity
82
Chapter 5
Equipment Design
= Liquid density,
= vapour density,
= 1.97 or 0.602
3. Calculation of minimum vessel diameter:
= minimum vessel diameter

= settling velocity, if demister pad is used
= gas or volumetric flow
= 2.06 m
4. Calculation of liquid depth:
Holding time for natural gas- condensate separator = 2-6 mints21

Taking holding time = 6 mints
= 1.928 m
83
Chapter 5
Equipment Design
5. Calculation of vessel length:
22
L =2.0D + Ld + Thickness of demister pad

L = 2.0 x 2.06 + 1.928m + 0.3048 m =6.34845045 m
Checking
If
ratio:
, then resize the tank 23
84
Chapter 5
Equipment Design
5.2 Plate Heat Exchanger:

Basically a plate heat exchanger is used to achieve the desired flow pattern by using corrugated
plates in addition to gasket and corner ports. In plate exchanger fluid pattern is such that fluid
goes through alternate channels. Plates are provided with connection for fluid and are held in a
frame. Plate heat exchanger in which gasket is used as sealing element are also know gasketed
exchanger.
The plate spacing in plate exchanger is normally in the range of 1.3 to 6.4 mm. There are certain
factors which determine the size and numbers of plates, these factors are pressure drop, fluid
physical properties, temperature program and flow rates. The main function of plate
corrugation is to give enough strength to plate to overcome differential pressure and also
introduce fluid turbulence. All plates are then composed in frame by using pressure
arrangement.
85
Chapter 5
Equipment Design
Useful data on PHE24

Unit
Size
1540-2500m
Number of plates
Port size
Up to 700
Up to 39cm
Plates
Thickness
0.5-1.2 mm
Size
Spacing
Corrugation depth
0.03-2.2 m
1.5-5.0 mm
3-5 mm
Standard Performance Limits:25
Maximum operating pressure 25 bar

With special construction 30 bar
Maximum temperature 160oC
With special gaskets 200oC
Maximum flow rate 3600m3/h
Heat transfer coefficient 3500-7500 W/m2 oC
Heat transfer area 0.1 2200m2
Maximum connection size 450mm
Temperature approach as low as 1 oC
Heat recovery as high as 93 %
Heat transfer coefficient 3000-7000 W/m2 oC
NTU 0.3-4.0
Pressure drop 30 kpa per NTU
Advantages of Plate heat exchanger

1.
2.
High heat transfer and high turbulence:

Different plate patterns and corrugation in plate heat exchanger induces high heat
transfer and high turbulence. For example the use of embossed plate pattern results in
high turbulence when fluid velocities are low on other hand plate having herringbone
pattern are arrange in such a way that their corrugation are in alternative direction ,
this causes swirling motion of fluid which ultimately results into high heat transfer
coefficient.
Reduced fouling:
Due to the presence of uniform flow pattern, high turbulence, smooth plate surface
and absence of stagnant area the fouling in plate heat exchanger is much less and
frequent cleaning can be avoided.
86
Chapter 5
3.
4.
5.
6.
7.
8.
9.
10.
Equipment Design
True Counter Flow:

In PHE greater temperature difference can be achieved by making fluid to move in
opposite direction.
Close temperature approach:
In PHE due to presence of true counter flow, efficient heat transfer and better flow
characteristics it is possible to achieve temperature approach as low as 1-2 oF
Multiple duties:
PHE has advantage that two or more than fluids can be heated or cooled in the same
unit by using intermediate divider section between heat transfer plates.
Easy maintenance:
It is easy to clean and inspect PHE because of configuration of PHE. PHE can be easily
opened by removing the bolts and then sliding away the end frame. In similar way
gasket of PHE can be replaced easily.
Lightweight:
PHE employs less surface area and has less liquid volume space. These features make
PHE lighter that other types of exchangers.
High Viscosity application:
PHE can handle high viscosity fluid because In PHE turbulence can be induce at low
velocities
Saves Servicing time and space:
It takes half time to open PHE for rebuilding, maintenance and inspection than shell
and tube exchanger. Also PHE requires about one half to one fifth area compare shell
and tube exchanger using for same application.
Less operational problems and lower cost:
In PHE erosion- corrosion, noise, flow induced vibration are not present which are
usually present in shell and tube exchange due to impingement attack. These
exchanger have low manufacturing cost and high thermal efficiency due to which they
are more economical as compare to exchangers of other type having same heat duty .
87
Chapter 5
Equipment Design
Construction features of PHE26:

Feature
PHE concept
Modular construction
Fixed frame and movable
press plates
Metallic contact between
plates
Bearing boxes on tightening
bolts
One- step plate pressing
Glue-free gaskets
Two-components ovencured epoxy on glued
gaskets
Advantages
Efficient heat transfer, low
weight
Flexibility
Easily accessible heat
transfer area
Minimized vibration
Reduced friction
High dimensional tolerances
Simplified regasketing while
still in frame
Superior bonding
Benefits
Reduced capital cost, smaller
foundation
Easy to modify for altered
duties
Reduced shutdown time
Longer life time greater
reliability
Easy opening and closing,
reduced maintenance
Improved performance
Reduced shut-down time,
reduced maintenance cost
Greater reliability
Construction of Plate Heat exchanger:

Plate
The plates use in PHE are available in wide variety of embossed and corrugated
patterns. The main reason of using corrugation to produce high turbulence which
ultimately results in high heat transfer than the heat transfer achieve in shell and tube
exchanger of same duties. The advantages of using embossed pattern is this that these
pattern provide more strength to plates and also enhance the effective surface area.
The most frequently used corrugation are wash board or intermating troughs and the
herringbone or chevron patterns.
Plate Material:
Carbon steel is used rarely due to poor corrosion resistance.
Commonly used PHE Materials:
27
88
Chapter 5
Equipment Design
Stainless steel AISI 304

Stainless steel AISI 316
Avesta SMO 254
Titanium, titanium-0.2%
(Palladium stabilized )
Tantalum
Inconel 600
Inconel 625
Incoloy 825
Monel 400
Hastelloy B
Hastelloy C-276
Aluminum brass 76/22/2
Cupronickel (70/30)
Cupronickel (90/100)
Diabon F 100
Gasket selection:
The main points which should be consider while selecting any gasket are shape, good
sealing ability, temperature and chemical resistance. Different gaskets and their
respective operating temperature are shown in below:
28
Styrene butadiene rubber (80 oC)

Nitrile rubber ( 140 oC)
Ethylene propylene rubber (150 oC)
Resin- cured butyl rubber (140 oC)
Fluorocarbon rubbers (180 oC)
Fluoroelastomer (100 oC)
Compressed asbestos fiber (260 oC)
Silicon elastomers ( low temperature application )

Tie bolts:
The tie bolts use in PHE are mostly made from 0.5%Mo-1%Cr low alloy steel. Different
types of tightening devices (pneumatic, hydraulic or electric) can by use for packing
large units.
89
Chapter 5
Equipment Design
Comparison between Shell & tube heat exchanger and Plate heat exchanger:29
Features
Multiple duty
Piping connection
Heat transfer ratio
Operating weight ratio
Hold-up volume
Space ratio
Welds
Sensitivity to vibrations
Gaskets
Detection of leakage
Access for inspection
Time required for opening
Repair
Modification
Fouling
Traditional PHE
Possible
From one direction(on frame
plate)
3-5
1
Low
1
None
Not sensitive
On every plate
Easy to detect on the exterior
On each side of plate
15 min with pneumatic
tightener
Easy to replace plate and/or
gasket
Easy by adding and removing
plates
10-25% that of STHE
STHE
Impossible
From several directions
1
3-10
High
2-5
Welded
Sensitive
On each flanged joint
Difficult to detect
Limited
60-90 min
Requires tube plugging (
decreased capacity)
Impossible
-----------
Plate heat exchanger design calculation

1. Heat Transfer Area:
Physical properties of hot fluid (Lean Amine)
= 938.4618
=0.0003018 Pa-sec
K=0.3443
Cp=110684
90
Chapter 5
Equipment Design
Physical properties of cold fluid (Rich Amine)

= 921.3411
=0.0005557 Pa-sec
K=0.3350
Cp=101919
The heat duty of Lean/Rich Exchanger as calculated before is
=156.231
Tlm=
or 45784.3 kW
) (
(
(
)
)
= 38.6
NTU is based on maximum temperature difference.

NTU=
= 1.16
FT factor calculated from graph for 1:1 pass is =0.975
30
As in this exchanger both stream are light organic liquid so the value of overall coefficient (U)
31
taken from table is 2200

Q=UAT
A( total heat transfer area )=
= 548.763 m2
Assumptions (some typical dimensions) 32

Effective plate area = 2.2 m2
Effective length = 1.5 m
Width = 0.5 m
Plate spacing = 5mm
Channel cross-sectional area= (5x10-3) x 0.5 = 2.5x10-3 m2
Hydraulic mean diameter= 2x (5x10-3) = 0.01 m
Plate thickness = 0.75mm
91
Chapter 5
Equipment Design
Number of plates =
Plates per pass =
= 125
2. Hp calculation for Lean Amine

(
Channel velocity=
=
x(
=1.02
Re(Reynoldss No)=
=
= 31789
Pr (Prandtl No) =
=
= 97
Nu (Nuesselt No) = 0.26 x (Re)0.65 x (Pr)0.4

= 0.26 x (31789)0.65 x (97)0.4 = 1368
Hp = Nu x
= 471128 Wm-2 oC
= 1368
3. Hp calculation for Rich Amine

(
Channel velocity=
=
x(
x
=1.03
Re(Reynoldss No)=
=
= 17240
Pr (Prandtl No) =
92
Chapter 5
Equipment Design
=
= 169
Nu (Nuesselt No) = 0.26 x (Re)0.65 x (Pr)0.4

= 0.26 x (17240)0.65 x (169)0.4 = 1147
Hp = Nu x
= 38453 Wm-2 oC
= 1147
4. Overall Coefficient:
Fouling factor for rich and lean amine (light organic) is
33
= 10000 Wm-2 oC-1
We Take plate thickness as 0.75 mm and we use titanium material which has thermal
conductivity of 21 Wm-1 oC-1
=
=
= 2.829x10-4
U= 3524 Wm-2 oC-1
The value of overall coefficient is much above the supposed value so the calculated number of
plate per pass is satisfactory
5. Pressure Drop
For Lean amine
Jf = 0.60 x (Re)-0.3
= 0.60 x (31789)-0.3
= 0.0267
Path length = plate length x number of passes = 1.5 x 1 = 1.5 m
Plate pressure drop
Pp=8 x Jf x
x density x
93
Chapter 5
Equipment Design
Pp= 8 x 0.0267 x
x 938 x
= 15655
Port pressure drop

We take port dia as 39 cm =0.39 m
Then area of the port is = 0.119 m2
(
Velocity through port=

=
=2.67
Ppt= 1.3 x
= 4351
Total Pressure drop = 15655 +4351 = 20000
=0.2 bar
For rich amine

Jf = 0.60 x (Re)-0.3
= 0.60 x (17240)-0.3
= 0.032
Path length = plate length x number of passes = 1.5 x 1 = 1.5 m
Plate pressure drop

Pp=8 x Jf x
Pp= 8 x 0.032 x
x density x
x 921x
= 18848
94
Chapter 5
Equipment Design
Port pressure drop

We take port dia as 39 cm =0.39 m
Then area of the port is = 0.119 m2
(
Velocity through port=

=
=2.72
Ppt= 1.3 x
= 4437
Total Pressure drop = 18848 +4437 = 23285
=0.23 bar
The pressure drop is well between the limits so the design of exchanger and number
of plates is good. So plate heat exchanger can be considered for this duty
95
Chapter 5
Equipment Design
5.3 Absorber Design:

Absorber
The removal of one or more selected components from a mixture of gas by absorption into a
suitable solvent.
Choice between Plate & Packed column:

Vapor liquid mass transfer operation may be carried either in plate or packed column. These
two types of operation are quite different. The relative merits of plate over packed column are
as follows:
1. Plate column are designed to handle wide range of liquid flow rates without flooding.
2. If a system contains solid contents; it will be handled in plate column, because solid will
accumulate in the voids, coating the packing materials and making it ineffective.
3. Dispersion difficulties are handled in plate column when flow rate of liquid are low as
compared to gases.
4. For large column heights, weight of the packed column is more than plate column.
5. If periodic cleaning is require, man holes will be provided for cleaning. In packed columns
packing must be removed before cleaning.
6. For non-foaming systems the plate column is preferred.
7. Design information for the plate column is more readily available and more reliable than
that for packed column.
8. Inter stage cooling can be provided to remove heat of reaction or solution in plate column.
9. When temperature change is involved, packing may be damaged.
Choice of Plate Type34:

There are three main types of plate, sieve plate, bubble cap and value plate. We have selected
sieve plate because:
1.
2.
3.
4.
5.
They are lighter in weight and less expensive. It is easier and cheaper to install.
Pressure drop is low as compared to valve and bubble cap plates.
Peak efficiency is generally high.
Maintenance cost is reduced due to the ease of cleaning.
In case of capacity rating, sieve plate has high rank as compared to valve and bubble plates.
Sieve plate:
Sieve plate is simplest type of cross-flow plate. Vapor passes up through perforations in the
plate; and the liquid is retained on the plate by vapour flow. The perforations are usually small
96
Chapter 5
Equipment Design
holes, but larger holes and slots are used. The arrangement, number and size of the holes are
design parameters.
Because of their efficiency, wide operating range, ease of maintenance and cost factors, sieve
and valve trays have replaced the once highly thought of bubble cap trays in many applications.
Factors affecting the absorption Column :

Vapor Flow Conditions:
1.
2.
3.
4.
Foaming
Entrainment
Weeping/dumping
Flooding
Foaming:
Foaming refers to the expansion of liquid due to passage of vapor or gas. Although it provides
high interfacial liquid-vapor contact, excessive foaming often leads to liquid buildup on trays. In
some cases, foaming may be so bad that the foam mixes with liquid on the tray above.
Whether foaming will occur depends primarily on physical properties of the liquid mixtures, but
is sometimes due to tray designs and condition. Whatever the cause, separation efficiency is
always reduced.
Entrainment:
Entrainment refers to the liquid carried by vapor up to the tray above and is again caused by
high vapor flow rates. It is detrimental because tray efficiency is reduced: lower volatile
material is carried to a plate holding liquid of higher volatility. It could also contaminate high
purity distillate. Excessive entrainment can lead flooding.
Weeping/Dumping:
This phenomenon is caused by low vapor flow. The pressure exerted by the vapor is insufficient
to hold up the liquid on the tray. Therefore, liquid starts to leak through perforations. Excessive
weeping will lead to dumping. That is the liquid on all trays will crash (dump) through to the
base of the column (via a domino effect) and the column will have to be re-started. Weeping is
indicated by a sharp pressure drop in the column and reduced separation efficiency.
97
Chapter 5
Equipment Design
Flooding:
Flooding is brought about by excessive vapor flow, causing liquid to be entrained in the vapor
up the column. The increased pressure from excessive vapor also backs up the liquid in the
down comer, causing an increase in liquid holdup on the plate above. Depending on the degree
of flooding, the maximum capacity of the column may be severely reduced. Flooding is
detecting by sharp increases in column differential pressure and significant decrease in
separation efficiency.
State of trays & Packing:

Remember that the actual number of trays required for a particular separation duty is
determined by the efficiency of the plate. Thus, any factors that cause a decrease in tray
efficiency will also change the performance of the column. Tray efficiencies are effected by
fouling, wear and tear and corrosion and the rates at which these occur depends upon the
properties of the liquids being processed. Thus appropriate materials should be specified for
tray construction.
Column Diameter:
Vapor flow velocity is dependent on column diameter. Weeping determines the minimum
vapor flow required while flooding determines the maximum vapor flow allowed, hence column
capacity. Thus, if the column diameter is not sized properly, the column will not perform well
Standard Design steps:

1)
2)
3)
4)
5)
6)
7)
8)
Calculation of theoretical number of stages.

Calculation of actual number of stages.
Calculation of diameter of column.
Calculation of weeping point.
Calculation of pressure drop.
Downcomer design.
Entrainment calculations.
Calculation of height of column.
98
Chapter 5
Equipment Design
ABSORBER DESIGN
Flow rate = 10898 Ibmole/hr
Pressure = 422 psia
Temperature = 110 F
302
CO2 = 217.96 Ibmole/hr
Pressure = 429.5 psia
H2S = 0.0218 Ibmole/hr
Temperature = 110 F
Density = 21.47 kg/m
H2 = 7092.85 Ibmole/hr
CO = 3242.036 Ibmole/hr
Avg. wt = 18.9985 Ib/Ibmole
CH4 = 291.467 Ibmole/hr
C2H4 = 1.866 Ibmole/hr
H2 = 7092.85 Ibmole/hr
CO = 3242.036 Ib mole/hr
C10H8 = 1.22 x 10-6 Ibmole/hr
CH4 = 291.467 Ibmole/hr
NH3 = 0.8615 Ibmole/hr
N2 = 8.3276 Ibmole/hr
300
H2O = 42.2125 Ibmole/hr

C10H8 = 1.22 x 10-6 Ibmole/hr
NH3 = 0.8615 Ibmole/hr
N2 = 8.3276 Ibmole/hr
Density = 1001.48 kg/m3
311
Avg. wt = 31.2969 Ib/Ibmole

Pressure = 432 psia
Temperature = 110 F
303
MDEA = 9848.8 Ibmole/hr

H2O = 65200 Ibmole/hr
Flow rate = 78563.309 Ibmole/hr

Pressure = 445 psia
Temperature = 152 F
99
Chapter 5
Equipment Design
1. Calculation of theoretical number of stages:35

The main component which we want to be absorbed in MDEA is H2S.so, we take it as a
reference.
H2S:
In = 3.73
Out = .0109
Moles of H2S absorbed = 3.719
Eai =
= 0.997
or
99.7%
Minimum for H2S.

(
) min = Ki Eai
L =
lean oil entering absorber.
Vn+1 =
rich gas entering absorber.
Value of K depends on T & P.

So, average tower conditions for ki:
T = 110 F
P=
= 433psia.
36
Ki = 1.6
So, (
)min = 1.6 x 0.997

= 1.5952.
Operating (
) = 1.25 (1.5952)
= 1.994.
100
Chapter 5
Equipment Design
Operating absorption factor

Aio = (
) .
=
= 1.246.
Theoretical stages at operating conditions.
Eai = AioN+1 Aio / AioN+1 1
0.997 = (1.246)N+1 1.246 / (1.246)N+1 1
(N+1) log 1.246 = log (
(N+ 1)(0.0995) = 1.919

N = 19.09.
It means 19 theoretical trays are needed.
2. Calculation of Actual Number of stages:

We take 70% efficiency.
So,
Actual number of stages =
= 27 stages.
3. Calculation of Diameter of Column:37

Flooding velocity is given by
Uf = K1
Where,
Uf = Flooding vapor velocity in m/s , base on net column cross-sectional area.
K1 = Constant obtained from figure 11.27 vol.6 Coulson & Richardson .
FLV =
101
Chapter 5
Equipment Design
Where,
Lw =Liquid mass Flow rate ,
Vw = Vapour mass Flow rate ,
In this Case,
Lw = 148.045
Vw = 17.18
Pv = 21.47
PL = 1001.48
FLV =
= 1.26
We use Plate Spacing 700mm.
38
K1 = .034
Then, UF = 0.034
= 0.23
We take actual velocity as 85% of flooding velocity
So, Uv = 0.85 x 0.23
= 0.20
Maximum volumetric vapor flow rate =
=0 .80
Net area required = An =
= 4 m2
102
Chapter 5
Equipment Design
We take downcomer area as 12% of total area

Column cross sectional area = Ac =
= 4.55 m2
Down comer area = Ad = 4.55 -4 = .55m2
Active area , bubbling area = Aa= Ac 2 Ad
= 4.55 2(0.55)
= 3.45 m2
Total hole area as 10% of active area , so
Hole area = AH = 0.10 x 3.45 = 0.345 m2
Column diameter = Dc =
=
= 2.40 m.
4. Calculation of Weeping Point:

For the calculation of weeping point, hole diameter must be selected so that at lowest
operation rate, the vapor flow velocity is still above weeping point.
Maximum liquid flowrate = 148.045
Minimum liquid rate , at 70% turn down = 0.70 x 148.045
= 103.631
x 100 =
39
x 100 = 12%
= 0.77
lw = 0.77 x 2.40 = 1.85m

we know
103
Chapter 5
Equipment Design
+ 2/3
how = 750 *
Lw = weir length, m
how = height over weir , mm liquid
Lw = liquid flow rate
] 2/3
Minimum how = 750 [

= 109mm.
We take , hw = 50mm
hw + how = 109 + 50 = 159mm.
40
K2 = 31.2
Uh(min) = [
(
)
Uh = minimum vapor velocity through holes, m/s

Dh = hole diameter, mm
Uh =
(
)
Uh = 0.77m/s
Actual minimum vapor velocity =
=
= 1.62 m/s.
So, minimum operating rate will be well above weeping point.
5. Calculation of Pressure drop:

= 9.81 x 10-3 ht PL
= total pressure drop , Pa (N/m2)
104
Chapter 5
Equipment Design
ht = total pressure drop , mm liquid

Total pressure drop is giver by
ht = hd + (hw + how) + hr
ht = total plate pressure drop
hd = dry plate pressure drop
hr = residual head
hw = height of weir
how = weir crest, mm liquid
hd = 51 [ ]2
Co = Orifice coefficient
Uh = Vapor velocity through holes , m/s
Uh =
= 2.32 m/s.
We take carbon steel plate, so

plate thickness = 5mm
hole diameter = 5mm
so,
41
Co = 0.84
hd = 51 [
]2 [
= 8.34 mm
hr =
= 12.48mm
105
Chapter 5
Equipment Design
ht = 12.48 + 8.34 + 50 + 109

= 179mm liquid
= 9.81 x 10-3 x 179 x 1001.48
= 1757 Pa
= 0.26 Psia (per plate)
6. Down comer Design:

The downcomer area and the plate spacing must be such that the level of the liquid and froth in
the downcomer is well below the top of outlet weir on the plate above. If the liquid rises above
the outlet weir the column will flood.
hb = (hw + how) + ht + hdc
Where,
hb = downcomer backup, measured from plate surface, mm
hdc= head loss in downcomer, mm
hdc = 166 [
]2
where,
hdc = head loss in downcomer, mm
Lwd = liquid flowrate in downcomer, kg/s
Am = Either downcomer area or clearance area under the downcomer Aop which is smaller.
Aop = hop Lw
Where, hop = height of bottom edge of apron above plate
Lw = length of weir
hop = hw 10
= 50 10 = 40mm
So, Aop= 0.040 x 1.85m
106
Chapter 5
Equipment Design
= 0.074m
]2
hdc = 166 [
= 6.62mm
So, backup in downcomer = hb= (50 +109) +6.62 + 179

= 34..62mm = 0.33462m
Then , backup in downcomer < (plate spacing + weir height)
0.33462 < (0.700 + 0.50)
0.33462 < 0.375
So, plate efficiency is acceptable.
7. Entrainment Calculation:
For checking entrainment , we calculate
Uv =
Uv =
= 0.2 m/s
% flooding =
=
= 86%
We already know FLV

FLV = 1.26
42
It is well below 0.1, so there is no chance of entrainment and process is satisfactory.
8. Calculation of Height of Column:

No. of plates = 27
Tray spacing = 0.700m
107
Chapter 5
Equipment Design
Tray thickness = 0.005m

Total thickness of trays = 0.135m
Top clearance = 1m
Bottom clearance = 1m
Total height = 20m
108
Chapter 5
Equipment Design
5.4 Stripper Design:

Stripper:
It is a counter current multi-stage separation column, with liquid feed at top and vapor feed at
the bottom stage.
Stripping Phenomenon:
Stripping is a mass transfer operation that involves the transfer of a solute (as H2S & CO2 in our
case) from the liquid phase to the gas phase.
Stripping Agents:
Air
Stream
Inert gas
Hydrocarbon gases
Reboiled vapors (as in our case)
Types of Stripper:
i.
Refluxed Stripper:
It is employed if simple stripping is not sufficient to achieve the desired separation and
contacting trays are needed above the feed tray.
ii.
Reboiled Stripper:
If the bottom product from a stripper is thermally stable, it may be Reboiled at the bottom of
the column.
iii.
Open steam/Air stripper:

Direct steam may also be used. Sometimes air or inert gases may also be used
(Combination of above can be made based on systems requirement)
Principle of separation: difference in volatilities
Created or added phase: vapor
Separating agent: stripping vapor
109
Chapter 5
Equipment Design

Pressure = 25 psia
Density = 935.24 kg/m
308
3
Avg. wt = 31.7742 Ib/Ibmoe

Temperature = 200 F

Pressure = 21.4 psia
Density = 1.96 kg/m3
305
Avg. wt = 40.59 Ib/Ibmoe

Temperature = 203 F
307


Pressure = 30 psia
Temperature = 258 F
110
Chapter 5
Equipment Design
Standard Design Steps:

Calculation of
1)
2)
3)
4)
5)
6)
7)
8)
Theoretical number of stages.

Actual number of stages.
Diameter of column.
Weeping point.
Pressure drop.
Downcomer design.
Entrainment calculations.
Height of column
1. Calculation of theoretical number of stages:43

The main component which we want to be stripped from MDEA is H2S. So, we take it as a
reference.
Let us suppose that 100% of H2S is not stripped and very minute quantities remains in the lean
MDEA coming back from Stripper.
Fraction of H2S stripped = Esi = 0.998
Minimum V/L for H2S = ( )min =
Value of K depends on T & P.
So, average tower conditions for value of ki:
T = 230 F
P = 26psia.
36
Ki = 35
So, ( )min =
=
= 0.0285
Operating ( ) = 1.25 (0.0285)

= 0.0356.
111
Chapter 5
Equipment Design
Operating stripping factor

Si = ( ) . Ki = 0.0356 x 35
= 1.246.
Theoretical stages at operating conditions.
ESi = SiN+1 Si / SiN+1 1
0.998 = (1.246)N+1 1.246 / (1.246)N+1 1
(N+1) log 1.246 = log (
(N+ 1)(0.0955) = 2.0969

N = 20.78
It means 21 theoretical trays are needed.
2. Calculation of Actual Number of stages:

We take 70% efficiency.
So,
Actual number of stages =
= 30 stages.
3. Calculation of diameter of column:37

Flooding velocity is given by
Uf = K1
Where,
Uf = Flooding vapor velocity in m/s , base on net column cross-sectional area.
K1 = Constant obtained from figure 11.27 vol.6 Coulson & Richardson .
FLV =
112
Chapter 5
Equipment Design
Where,
Lw =Liquid mass Flow rate ,
Vw = Vapour mass Flow rate ,
In this case,
In this Case,
Lw = 315
Vw = 20.38
Pv = 1.96
PL = 935.24
FLV =
= 0.71
We use Plate Spacing 800mm.
38
K1 = .054
Then, UF = 0.054
= 1.18
We take actual velocity as 85% of flooding velocity
So, Uv = 0.85 x 1.18
= 1.00
Maximum volumetric vapor flow rate =
=10.4
Net area required = An =
113
Chapter 5
Equipment Design
= 10.4 m2
We take downcomer area as 12% of total area

Column cross sectional area = Ac =
= 11.82 m2
Down comer area = Ad = 11.82 10.4 = 1.42m2
Active area , bubbling area = Aa= Ac 2 Ad
= 11.82 2(1.42)
= 8.98 m2
Total hole area as 10% of active area , so
Hole area = AH = 0.10 x 8.98 = 0.898 m2
Column diameter = Dc =
=
= 3.88 m.
4. Calculation of Weeping Point:

For the calculation of weeping point, hole diameter must be selected so that at lowest
operation rate, the vapor flow velocity is still above weeping point.
Maximum liquid flowrate = 315
Minimum liquid rate , at 70% turn down = 0.70 x 315
= 220.5
x 100 =
39
x 100 = 12%
= 0.77
lw = 0.77 x 3.88 = 2.99m

we know
114
Chapter 5
Equipment Design
+ 2/3
how = 750 *
Lw = weir length, m
how = height over weir , mm liquid
Lw = liquid flow rate
] 2/3
Minimum how = 750 [

= 138mm.
We take , hw = 50mm
hw + how = 138 + 50 = 188mm.
40
K2 = 31.2
Uh(min) = [
(
)
Uh = minimum vapor velocity through holes, m/s

Dh = hole diameter, mm
Uh =
(
)
Uh = 6.17m/s
Actual minimum vapor velocity =
=
= 8.11 m/s.
So, minimum operating rate will be well above weeping point.
5. Calculation of Pressure drop:

= 9.81 x 10-3 ht PL
= total pressure drop , Pa (N/m2)
115
Chapter 5
Equipment Design
ht = total pressure drop , mm liquid

Total pressure drop is giver by
ht = hd + (hw + how) + hr
ht = total plate pressure drop
hd = dry plate pressure drop
hr = residual head
hw = height of weir
how = weir crest, mm liquid
hd = 51 [ ]2
Co = Orifice coefficient
Uh = Vapor velocity through holes , m/s
Uh =
= 11.6 m/s.
We take carbon steel plate, so

plate thickness = 5mm
hole diameter = 5mm
so,
41
Co = 0.84
hd = 51 [
]2 [
= 20 mm
hr =
= 13mm
116
Chapter 5
Equipment Design
ht = 188 + 13 + 20
= 221mm liquid
= 9.81 x 10-3 x 221 x 935.24
= 2027.6 Pa
= 0.29 Psia (per plate)
6. Downcomer Design:
The downcomer area and the plate spacing must be such that the level of the liquid and froth in
the downcomer is well below the top of outlet weir on the plate above. If the liquid rises above
the outlet weir the column will flood.
hb = (hw + how) + ht + hdc
Where,
hb = downcomer backup, measured from plate surface, mm
hdc= head loss in downcomer, mm
hdc = 166 [
]2
where,
hdc = head loss in downcomer, mm
Lwd = liquid flowrate in downcomer, kg/s
Am = Either downcomer area or clearance area under the downcomer Aop which is smaller.
Aop = hop Lw
Where, hop = height of bottom edge of apron above plate
Lw = length of weir
hop = hw 10
= 50 10 = 40mm
So, Aop= 0.040 x 2.99m
117
Chapter 5
Equipment Design
= 0.120m
]2
hdc = 166 [
= 13.07mm
So, backup in downcomer = hb= (50 +138) +13.07 + 221

= 422.07mm = 0.422m
Then , backup in downcomer < (plate spacing + weir height)
0.422 < (0.800 + 0.50)
0.422 < 0.425
So, plate efficiency is acceptable.
7. Entrainment Calculation:
For checking entrainment , we calculate
Uv =
Uv =
= 1 m/s
% flooding =
=
= 85%
We already know FLV

FLV = 0.71
42
It is well below 0.1, so there is no chance of entrainment and process is satisfactory.
8. Calculation of Height of Column:

No. of plates = 30
Tray spacing = 0.800m
118
Chapter 5
Equipment Design
Tray thickness = 0.005m

Total thickness of trays = 0.15m
Top clearance = 1m
Bottom clearance = 1m
Total height = 25m
5.5 MDEA Surge Drum:

Flow rate of MDEA = 2349334.04 Ib/hr
Density of MDEA at 160oF = 64.6 Ib/ft3
Basis 24 hours
Vol. of MDEA for 24 hr = 2349334.04 x 24/64.6 = 872817.6 ft3
Total vol. of vessel = vol. of MDEA + 10% allowance
= 872817.6 x 1.10 = 960099.36 ft3
Let us suppose that 0.3% of MDEA solution is slipped in the surge tank
=960099.36 *0.03=2858.29 ft3=81m3
V = d2h/4
Let, h/d = 3
or h = 3d
3
V = 3 d /4
From here, d = 3.25m so, h=9.75 m
[1]
Design Specifications
Time of operation = 24hr
Dia. Of vessel = 3.25m
Height of Vessel = 9.75m
Recommended material of instruction is carbon steel
119
Chapter 6
Instrumentation & Process Control
Chapter 6
6.1 Amine Plant Control

Optimal amine control will reduce corrosion, energy consumption, improved treated gas
quality, reduce hydrocarbon load to sulphur recovery unit and improve H2S/CO2 ratio to
Sulphur recovery unit.
In Amine contactor bottom section most of the heat of reaction44 is released. If there is high
amine loading then it will lead towards corrosion. In the following control scheme we have used
the temperature near the middle of the amine absorber to reset the control the amine flow. By
controlling the amine flow rate the chances of corrosion due to temporary overloading of rich
amine solution is reduced. Level is controlled in the absorber by using Proportional controller.
Sweet gas pressure is maintained by using Proportional Integral Controller.
In Regenerator section we have used flow ratio control45 to set the reboiler heat medium mass
flow at a fixed value in relation to the rich amine and second control method on regenerator
uses the temperature between the top tray and overhead condenser to reset the reboiler heat
medium flow.
In lean/rich MDEA Exchanger, the rich MDEA is more important because it after the exchanger
it leads to Regenerator column. Any change in its dynamic can alter the dynamics of the whole
column. Hence the lean MDEA stream is manipulated to keep the temperature of rich MDEA
constant.
Further in Lean MDEA cooler, the lean MDEA stream is the key stream because it then flows to
absorber and hence failure to meet the required temperature will affect the absorber
performance. Hence the speed of the fan of Air Fin Fan Cooler Is varied to meet the constant
lean MDEA temperature. The control action is simple, since the temperature usually has a
sluggish response so a PID controller is more suitable.
120
Chapter 6
6.2 Process Instrumentation Diagram for Amine plant:
121
Chapter 7
Cost Estimation
Chapter 7
Cost Estimation
7.1 Plant Cost Estimation:

As the process design is completed it becomes possible to make accurate cost estimation
because detailed specification can thus be obtained from various manufactures. However
no design project should proceed to the final stages before costs are considers and the cost
estimation should be made throughout all the early stages of the design when complete
specifications are not available. Evaluation of costs in the preliminary design is said pre
design cost estimation. Such estimation should be capable of providing a basis for company
management to decide whether or not further capital should be invested in the project.
An evaluation of costs in the preliminary design phase is sometimes called as guess
estimation and often rule of thumb are used. A plant design obviously must present a
process that is capable of operating under conditions which will yield a profit.
A capital investment is required to any industrial process, and determination of necessary
investment is an important part of plant design project. The total investment for any
process consists of physical equipment and facilitates in the plant plus the working capital
for money which must be available to pay salaries. Keep raw materials and products on
hand and handle other special items requiring a direct cash layout.
7.2 Capital Investment:

Before industrial plant can be put into operation, large amount of money must be supplied
to purchase and install the necessary machinery and equipment, land services facilitates
must be obtained and plant must be erected, complete with all pipe control services. In
addition it is necessary to have money available for payment of expenses involved in plant
operation.
The capital needed to supply the necessary manufacturing and plant facilities is called fixed
capital. Fixed cost capital investment while necessary for the operation of the plant termed
as Working Capital. The sum of fixed capital investment and the working capital is known as
total capital investment.
Fixed capital investment classified into two subdivisions: namely
Direct costs
Indirect costs
7.2.1 Direct costs:

The direct cost items are incurred in the construction of planet in addition to the cost of
equipment:
Purchase equipment
Purchase equipment installation
Instrumentation
122
Chapter 7
Cost Estimation
Piping
Electrical Equipment and materials
Building (including services)
Service facilities
Taxes
7.2.2 Indirect costs:

These include:
Design and engineering

Contractors expanses
Contractors fee
Contingency
7.3
Types of Cost Estimation:
Various methods are employed for estimating capital investment are as follows:
Preliminary estimate
Definitive estimate
Detailed estimate
In choosing the method for cost estimation following factors are considered:
Amount of detailed information available

Accuracy desired
Time spent on estimation
7.4
Methods of Estimating Capital Investment:
Seven methods of estimating capital investment are outlined below:
Detailed item estimate

It cost estimate
Percentage of delivered equipment cost
Lang factor for approximation of capital investment
Power factor applied to plant capacity ratio
Investment cost per capacity
Turnover ratio
7.5 Percentage of Delivered Equipment Cost:

This method for estimating the fixed or total capital investment requires determination of
the delivered equipment cost. The other items included in the total direct plan cost are then
estimated as Percentage of Delivered Equipment Cost.
123
Chapter 7
Cost Estimation
The percentage used in making an estimation of this type should be determined on the basis
of type of process involved, design complexity required, material of construction, location of
the plant, past experiences, and other items depend on the particular unit under
consideration.
Purchased equipment cost for common plant equipment
= Ce = E
Ce= a + b (S)n
Where a & b are cost constants
S = size parameter
n = exponent for that type of equipment
(these all above values have been obtained from table # 6.6, Coulson vol.6, Ed.5. for year
2007 )
1. Cost of Absorber:
We know that
C= a+b(S)n
Diameter of Absorber = 2.4 m
sizing factor (S) = 2.4
a = 110, b = 380, n= 1.8
46
(for year 2007)
so,
C = 110+380(2.4)1.8
= $1947
( Cost/Tray)
Total cost of one absorber = 1947 x 27

= $52569
As we have used two absorber, so
Cost of both Absorbers = $52569 x 2
124
Chapter 7
Cost Estimation
= $105138
This cost is for year 2007, so by applying inflation rate of 3.3% per year, we can find cost in
2013.
C = 105138(1.033)6 = $127750.21
2. Cost of Exchanger:
We know
C= a+b(S)n
Sizing parameter of exchanger (S) = 584 m2
a = 1350, b = 180, n = 0.9547
(for year 2007)
so,
C = 1350+180(584)0.95
= $73313
2013.
C = 73313(1.033)6 = $89080.
3. Cost of Inlet Gas Separator:

Diameter = D = 2.06 m
Length = L = 6.34 m
From Graph48
C = 22000
Pressure Factor = 1.4 (at 30 psia)
So,
C = 22000 x 1.4 = $30800
2013.
C = 30800(1.033)9 = $41253.
125
Chapter 7
Cost Estimation
4. Cost of Lean Solvent pump:

Capacity of Pump = 3919 GPM
From Graph
C = $25000
2013.
C = 25000(1.033)21 = $49436.
5. Cost of MDEA Surge Tank:

Capacity of tank = 81 m3
We know that
C = C= a+b(S)n
a = 5000, b = 1400, n = 0.7 (cone roof)49
(for year 2007)
C = 5000+1400(81)0.7
so,
= $35343
2013.
C = 35343(1.033)9 = $47337.
E = $354856
7.6 Direct Cost: 50

Component
% of E
Cost ($)
Purchased Equipment Installation

Instrumentation installation
Piping
Electrical
Building
Yard improvement
Service facilities
Land
Total direct cost = D = 241262
0.25E
0.07E
0.08E
0.05E
0.05E
0.02E
0.15E
0.01E
88714
24840
28388
17723
17723
7097
53228
3549
126
Chapter 7
Cost Estimation
7.7 In-Direct cost:

Engineering & Supervision
0.33E = $117102
(1)
Construction Expenses
0.41E = $145490
(2)
Total in-direct Cost
$262592
Total Cost
direct Cost + indirect cost
$503855
Contactors Fee
X = 0.05 (D+I) = $12063
Contingency
Y = 0.10 (D+I) = $24126
Fixed Capital Investment
(D+I+X+Y) = $540043
Working Capital Investment =
0.15(D+I+X+Y) = $81006
127
Chapter 8
HAZOP Study
Chapter 8
HAZOP Study
8.1 HAZOP study:

A Hazard is something which may cause harm and is an undesired event. The word HAZOP
refers to the detail study regarding operability and hazards. Its a formal procedure to identify
hazards in a chemical process facility. This systematic study is used to find out operability
problems and equipment hazards or all plant hazards. The method for doing HAZOPS study
involves detail examination of each equipment (instruments, piece of equipment, pipeline) and
the finding out all possible deviation from normal operating conditions. Before the HAZOP
study is started, detailed information on the process must be available. This includes up-to-date
process flow diagrams (PFDs), process and instrumentation diagrams (P&IDs), detailed
equipment specifications, materials of construction, and mass and energy balances.
A HAZOP study is conducted in the following steps
Specify the purpose, objective, and scope of the study. The purpose may be the analysis of a yet
to be built plant or a review of the risk of unexisting unit. The scope of the study is the
boundaries of the physical unit, and also the range of events and variables considered. The
initial establishment of purpose, objectives, and scope is very important and should be precisely
set down so that it will be clear, now and in the future, what was and was not included in the
study. These decisions need to be made by an appropriate level of responsible management.
HAZOP team is selected.

For the collection of data following materials are needed:
Process description
Process flow sheets
Data on the chemical, physical and toxicological properties of all raw materials,,
intermediates, and products.
Piping and instrument diagrams (P&IDs)
Equipment, piping, and instrument specifications
Process control logic diagrams
Layout drawings
Operating procedures
Maintenance procedures
Emergency response procedures
Safety and training manuals
128
Chapter 8
HAZOP Study
8.1.1 Objectives of HAZOP study:
To find out those areas in design which can have significant hazard potential.
To study and find out those aspect of design that effects the occurrences of hazardous
incidence.
To make study team familiar with design information.
To make sure that systematic study of areas involving hazard potential is made.
To provide a mechanism for feedback to the client of the study team's detailed
comments
8.1.2 HAZOP Team:

HAZOP studies are carried out using a `brainstorming' approach by a team, chaired and
coordinated by a qualified person experienced in Team leadership Following are the members
of HAZOP team:
Team Secretary
Process Engineer
Mechanical Engineer
Commissioning/Operations
Engineer/Manager
Instrument Engineer
8.1.3 Strength of HAZOP:
HAZOP is a systematic, reasonably comprehensive and flexible.
It gives good identification of cause and excellent identification of critical deviations.
The use of keywords is effective and the whole group is able to participate.
HAZOP is an excellent well-proven method for studying large plant in a specific manner.
8.1.4 Weakness of HAZOP:
HAZOP is very time consuming and can be laborious with a tendency for boredom for
analysts.
It tends to be hardware-oriented and process-oriented, although the technique should

be amenable to human error application.
HAZOP does not identify all causes of deviations and therefore omits many scenarios.
129
Chapter 8
HAZOP Study
8.1.5 Responsibility of HAZOP Team Members:
Plan sessions and timetable
Control discussion
Limit discussion
Encourage team to draw conclusion
Ensure secretary has time for taking note
Keep team in focus
Encourage imagination of team members
Motivate members
Discourage recriminations
Judge importance issues
8.1.6 Guide Words:

Guide Words
No or Not
More
Less
As well as
Meaning
Negation of intention
Quantitative increase
Quantitative decrease
Quantitative increase
Part of
Quantitative decrease
Reverse
Logical opposite of intention
Other than
Compete substitution
Comments
No flow of A
Flow of A greater than design flow
Flow of A less than design flow
Transfer of some component
additional to A
Failure to transfer all components of
A
Flow of A in direction opposite to
design direction
Transfer of some material other than
A
130
Chapter 8
HAZOP Study
8.2 HAZOP Study of storage Tank for MDEA:

A HAZOP study is to be conducted on MDEA storage tank, as presented by the piping and
instrumentation diagram show below.
In this scheme, MDEA is unloaded from tank trucks into a storage tank maintained under a
slight positive pressure until it is transferred to the process. Application of the guide words to
the storage tank is shown in Table (8.1) along with a listing of consequences that results from
process deviation.
Piping & instrumentation Diagram of MDEA storage Tank51
131
Chapter 8
HAZOP Study
Table 8.152
Equipment
reference
and
operating
conditions
Deviations
from operating
conditions
What event
could cause
conditions this
deviation?
Consequences
of
this deviation
on
item of
equipment
under
consideration
Pump
cavitates
Additional
implications of
this
consequence
Process
indications
Notes and questions
MDEA
Storage
tank
Level
1. Tank runs dry
Damage to
pump,
LIA-1,
FICA-1
2. Rupture 4-in.
discharge
Reagent
released
Potential fire
LIA-1,
FICA-l
3. V-3 open or
broken
4. V-l open or
broken
5. Tank rupture
Reagent
released
Reagent
released
Reagent
released
Tank overfills
Potential fire
LIA-1
Potential fire
LIA-1
Potential fire
LIA-1
Reagent
released
via RV-1
LIA-1
7. Reverse flow
from process
Tank overfills
Reagent
released
via RV-1
LIA-1
Composition
Other than
8. Wrong
reagent
Possible
reaction
Possible tank
rupture
As well as
9. Impurity in
reagent
Pressure
Less
10. Break l-in.

line to flare or lin nitrogen line
If volatile,
possible
overpressure
Reagent
released
Can reagent
react/explode if overheated in pump?
Estimate release
quantity. Consider
second LAL
shutdown on pump.
Estimate release
quantity.
Consider V-l
protection
What external events
can cause rupture
Is RV-1 designed to
relieve liquid
atloading rate?
.Consider secondhigh
level shutoff.
Consider check
valvein pump
discharge line.
Consider second LAH
shutdown on feed
lines.
Consider
samplingbefore
unloading.
Are other
materialsdelivered in
trucks?
Consider PAL to
PICA- 1. Consider
independent
PAL.
Consider vacuumbreak
Valve.
consider PAL on
PICA-l
Tank not designed
for vacuum.
Less
More
6. Unload too
much from tank
truck
Potential fire
PICA-l
11. Lose nitrogen
Tank implodes
Reagent
released
PICA-l
12. PV-2 fails

closed
13. PICA-1 fails,
closing PV-2
Tank implodes
Reagent
released
Reagent
released
PICA-l
Tank implodes
PICA-l
132
Chapter 8
HAZOP Study
More
14. PICA-l fails

closing PV-1
Reagent
released
via RV-1
Reagent
released
via RV-1
Reagent
released
via RV-1
Tank rupture if
RV-1 fails
PICA-l
Tank rupture if
RV-1 fails
PICA-l
Tank rupture if
RV-1 fails
PICA-l
17. Overfill tank
See Event 6
Tank rupture if
RV-1 fails
PICA-l
18. Temperature
of
inlet is hotter
than normal
Reagent
released
via RV-1
Tank rupture if
RV-1 fails
PICA-l
15. PV-1
failsclosed
16. V-7 closed
What is capacity of
PV-l? RV-l? Consider
independent PAH.
Consider
independent PAH.
Is V-7 locked open?
Is V-S locked open?
Consider
independent PAH.
Consider second
High-level shutoff.
What prevents high
Temperature of
inlet?
133
Chapter 9
Operational Problems
Chapter 9
9.1
Problems occurring during operation:
One of the reasons that alkanolamine processes have become the predominant choice for both
refinery gas treating and natural gas purification is their comparative freedom from operating
difficulties. Nevertheless, several factors can result in undue expense and cause difficulties in
the operation of alkanolamine units. Chief among these, from an economic standpoint are
corrosion and amine loss. Other operating difficulties, which occasionally limit the capacity of
plant for gas purification, include foaming and plugging of equipment. In many cases, operation
can be significantly improved by daily monitoring of key plant operating variables and by proper
control and design of treating plant.
9.2
Foaming53:
Foaming of alkanolamine solution is probably the most common operating problem in amine
treating units. It is most frequently encountered in contractor, but may also occur in the
stripping column.
Causes of Foaming:
Specific cause of foaming includes the following:
Water soluble surfactants in the feed gas (e.g. well treating compounds, pipeline corrosion
inhibitors) which lowers the amine solutions surface tension. Excessive antifoam can also
cause foaming.
Liquid hydrocarbons e.g. entrained compressor lubricating oils in the feed gas or
hydrocarbons condensation within the amine absorber.
Particulate contaminants (e.g. mill scale, FeS correction products, rust contained in the feed
gas or produced within amine treating units. Solids such as FeS do not cause foaming but
concentrate at liquid/gas interface and stabilize the foam by increasing the surface viscosity
retarding film drainage.
Oxygen contamination of feed gas or amine unit (usually at the amine sump or amine
storage tank) and reaction of amine heat stable salts. Dissolved iron can catalyze the
reaction of amine with oxygen to foam carboxylic acid.
Feed gas contamination such as carboxylic acid, which react with amine to form heat stable
salts.
Contamination of amine unit with gases and oils during a turnaround.
Amines filter elements that have been washed with surfactants or contaminated with oils
during manufacture.
Contaminants in the amine plant makeup water such as boiler feed water treating
chemicals and corrosion inhibitors.
134
Chapter 9
Prevention of Foaming:
Foaming can be reduced or controlled by proper care of the amine solution. The following
techniques reduce the amine solution contamination and minimize foaming:
A properly designed feed gas inlet separator and filter should be provided. A feed gas
coalscer should be considered for feed gas stream contaminated with compressor
lubricating oils and other finally dispersed aerosols. A properly size slug catcher should be
provided if slugs can accumulate in the feed gas line.
A feed gas water wash should be considered when the feed gas streams is severely
contaminated with carboxylic acid or water soluble, surface active contaminates. A feed gas
water wash can also remove aerosols and ultra fine chemicals.
Onsite of offsite amine solution reclaiming to remove heat stable salts and amine
degradation products. No more than 10% of the amine should be tied up as stable salts.
Caustic addition to neutralize heat stable salts to mitigate corrosion and thereby reduce
iron sulfite formation.
A properly sized rich amine flash drum remove entrained and dissolved hydrocarbons.
Liquid skimming facilitate in the absorber sump, the rich amine flash drum, the regenerator
sump and the amine regenerator overhead accumulator.
New plants and old plants that have undergone a major turnaround or often contaminated
with oils, greases welding fluxes and corrosion inhibitors. A hot caustic wash (2-5 wt%
caustic soda) followed by a hot condensate wash can remove these impurities and help to
prevent foaming.
Addition of antifoam is carried out.
9.3 Corrosion:
By far the most serious operating problem encountered with amine gas purification process
is corrosion as would be expected this problem has been given widest attention. Generally,
it occurs in regenerator heat exchanger and pumps. The extent and type of corrosion has
been observed to depend upon such factors as the amine used, the presence of
contaminants in the solution leading with acid gas, the temperature and pressure,
prevailing in various part of the plant, the velocity with which the solution flows and others.
However, it appears that the principal corroding agents are the add gases. The rate of
corrosion increases with increase acid gas concentration n solution.
Corrosion due to hydrogen sulfide and carbon dioxide is frequently observed a filter shell
and the hot end heat exchanger tubes. To minimize corrosion by hydrogen sulfide and
carbon dioxide, the acid gases must be held in a relatively corrosive form until regeneration
of amine solution is stripping still.
135
Chapter 9
Overloading the amine solution will increase the chance for corrosion due to pressure
reduction or high temperature in the heat exchanger. This danger can be remedied
bymaintaining sufficient pressure on the foul amine solution and by operating the unit at as
low and acid gas alkanolamine ratio as possible. This ration should not exceed 0.05 moles of
acid gas per mole of alkanolamine and should be event less of condition permits.
Mechanism of Corrosion:
It is known that free or aggressive carbon dioxide causes severe corrosion particularly at
elevated temperature and in the presence of water.
It is believed that the metallic iron with carbonic acid which results in the formation of stable
iron bicarbonate. Further heating of solution may cause the release of carbon dioxide and the
precipitate of the iron as the relatively insoluble carbonate.
Hydrogen sulfide attacks steel as an acid with the subsequent formation of insoluble ferrous
sulfite. This compound forms a coating on the metal surface which does not adhere tightly and
therefore affords little protection from further corrosion. There is no satisfactory correlation
available for carbon dioxide, hydrogen sulfide mixture, which relates the corrosive attacks to be
expected with any given ratio of hydrogen sulfide to sulfur dioxide.
However, certain generalized observation has been made. It appears that in plant handling
predominantly carbon dioxide, very small quantity of hydrogen sulfide may actually reduce
corrosion. On the other hand, each of the acid gases increases the corrosive attacks of the
other.
Methods of Minimizing Corrosive Attacks:

Corrosion can be reduced by various methods, including certain protection in the operation and
process design of purification plants. Use of more expensive corrosion resistant material and
continues or periodic removal of corrosion promoting agent from the solution. A combination
of several of these measures usually leads to most satisfactory and economical to reduce
corrosion attacks;
The temperature of the solution in the reboiler and the temperature of the steam used in
the reboiler should be kept as low as possible.
Use of high temperature heat carrying media, such as oil, should be avoided to maintain the
lowest possible skin temperature of metal.
Pressure regenerator with its accompanying high temperatures results in severe corrosion
of reboiler tubes; it is, therefore, good practice to maintain the lowest possible pressure on
the stripping column and reboiler.
To prevent oxygen from entering the system, it is advisable to maintain a blanket of inlet
gas over all portion of the solution, which could be exposed to atmosphere and to ensure
the pressure the suction side of all pumps.
136
Chapter 9
Continuous removal of suspended solids (by nitration) and the decomposition product (by
distillation of a side stream) generally helps to reduce corrosion.
9.4
Chemical Losses54:
The loss of a solvent can be a serious operating difficulty in alkanolamine gas purification
plants. Corrosion can be incurred by entrainment of the solution in the gas stream vaporization
or chemical degradation of the amine. Loss of the solvent by entrainment or vaporization is
undesirable not only because of the cost of chemicals but also because of the contamination of
the pipelines by liquid deposited on the walls. In addition when alkanolamine solution are used
to purify the gas to be used in catalytic process, entrainment by vaporization of solvent result in
a serious poisoning of the catalyst.
9.5
Losses due to Volatility:
Glycol volatility losses are usually significant in ethylene glycol, di-ethylene glycol but very less
in tri-ethylene and higher glycols, which have very high boiling points. Hence usually a very
small amount of glycol is lost by vaporization into gas stream in absorbers and also in
regenerators.
Prevention from Volatility Losses:

Volatility losses can be prevented by following methods:
9.6
A cold water flux is provided at the top plate of regenerating column.

Normally absorbers are operated at lower temperatures (80-1100F recommended) to
avoid losses.
Entrainment:
In many cases most of the glycol loss occurs as carry over of solution with the product gas.
Entrainment losses are caused either by inefficient mist extraction or by foaming and
subsequent carry over solution. Entrainment losses from glycol absorber vary considerably
depending on the mechanical design of both the upper solution of absorber and mist
elimination devices.
Prevention from Entrainment Losses:

Entrainment can be mi minimized by the following techniques:
Using efficient mist elimination equipment.

Application of the foam inhibitor.
137
BIBLOGRAPHY
BIBLOGRAPHY
1- TIM C.LIEUWEN & VIGOR YANG & RICHARD YETTER, Synthesis Gas Combustion
Fundamentals and Applications, Page 19, Table 1.5
2- TIM C.LIEUWEN & VIGOR YANG & RICHARD YETTER, Synthesis Gas Combustion
Fundamentals and Applications,Table 1.5
3- PETER HAUSSINGER & REINER LOHMULLER & ALLAN M. WATSON,
UllmannsEncyclopaedia of Industrial Chemistry, Page 340
4- PETER HAUSSINGER & REINER LOHMULLER & ALLAN M. WATSON, Ullmanns
Encyclopaedia of Industrial Chemistry, Page 345.
5- GAS PROCESSORS SUPPLIERS ASSOCIATION, Engineering Data Book, page 21-5,
Volume 2, Edition 12th.
Volume 2, Edition 12th
7- ARTHUR KOHL & RICHARD NELSON , Gas Purification , Page 53, Edition 5 th .
8- ARKEMA, MDEA Proven Technology For Gas Treating Technology, Page 3.
9- Adapted from DOE / NETL (Department of Energy / National Energy Technology
Laboratory), (2011), Advanced Carbon Dioxide Capture R&D Program: Technology
Update, U.S
10- ARTHUR KOHL & RICHARD NELSON , Gas Purification , Page 1202, Table 14-1, Edition
5th
5th
5th
13- LUDWIG, Applied Process Design for Chemical and Petrochemical Plants, Page 303,
14- TENNEYSON, R.N. & SCHAAF, R.P, "Guidelines Can Help Choose Proper Process for Gas
Treating Plants", Oil and Gas Journal, January 10, 1977, page 78.
138
BIBLOGRAPHY
15- ARTHUR KOHL & RICHARD NELSON , Gas Purification , Page 4, Edition 5th. 1979
16- Amine & Plasticizers limited,AN ISO 9001:2008 CERTIFIED COMPANY.
17- A.A.C.M BEENACKERS, Methanol production from wood-Results of the EEC Pilot
Programme, ,page 7, Table 1.1
18- NREL(national renewable energy laboratory),task 2:Gas cleanup design and cost
estimates-Wood Feedstock.
19- TOTAL FINAELF, Oil and Gas processing plant Design and operation training course,
Gas sweetening process, Page 9, 2002
20- SCHEIMAN A.D, Horizontal Vapor and Liquid Separators, Hydrocarbon Processing &
Petroleum Refinery, Page 155, May 1964.
21- GAS PROCESSORS SUPPLIERS ASSOCIATION, Engineering Data Book, Fig 7-20, Volume
1&2, Edition 12th .
22- http://www.amistco.com/spanish/tech105.htm
23- STANLEY M . WALAS, Chemical Process Equipment , page 649, edition 2nd .
24- T.KUPPAN, Heat Exchanger Design Handbook, page 351, Table 2.
25- T.KUPPAN, Heat Exchanger Design Handbook, page 351.
26- T.KUPPAN, Heat Exchanger Design Handbook, Page 349, Table 1
28- T.KUPPAN, Heat Exchanger Design Handbook , Page 356, Table 5
30- R.K SINNOTT ,Coulson & Richardson`s Chemical Engineering , Page 760, Figure 12.62,
volume 6 ,edition 4th.
31- R.K SINNOTT, Coulson & Richardson`s Chemical Engineering , Page 637 , Table 12.1,
volume 6 ,edition 4th.
32- T.KUPPAN,Heat Exchanger Design Handbook, page 368, Table 2.
33- R.K SINNOTT, Coulson & Richardson`s Chemical Engineering , Page 757 table 12.9,
Volume 6 , Edition 4th.
139
BIBLOGRAPHY
34- R.K SINNOTT, Coulson & Richardsons Chemical Engineering page 558-561, Volume 6,
Edition 4th.
35- ERNEST E. LUDWIG, Applied Process Design for Chemical & Petrochemical Plants, page
109, Volume 2, Edition 3rd.
Volume 1&2, Edition 12th.
37- R.K SINNOTT, Coulson & Richardsons Chemical Engineering page 567-579, Volume 6,
Edition 4th.
38- R.K SINNOTT, Coulson & Richardsons Chemical Engineering, Figure 11.27, page 568,
43- ERNEST E. LUDWIG, Applied Process Design for chemical & petrochemical plants, page
110, Volume 2, Edition 3rd.
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48- R.K SINNOTT, Chemical Engineering Design, page 256, Figure 6.5a,b.
140
BIBLOGRAPHY
50- MAX S.PETERS & KLAUS D.TIMMERHAUS, Plant Design & Economics For Chemical
Engineer, page 167, Table 4, Edition 4th.
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Engineers, page 63, Edition 4th.
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Engineers, page 64, Edition 4th.
54- ARTHUR KOHL, Gas Purification. Page 231, Edition 5th
141

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A PLANT DESIGN PROJECT ON

PURIFICATION OF SYNTHESIS GAS (208MMSCFD): REMOVAL OF ACID

Ahmad Riaz Khan

Institute Of Chemical Engineering and Technology

It is certified that this report is submitted by the following students.

Ahmad Riaz Khan

Ahmad Riaz Khan

1.2 Synthesis Gas: A Historical Overview

1.2.1 Historical Terminology Related to Different types of Synthesis gas

1.2.2 From Feedstock to Synthesis Gas: A brief over view

1.3 Need of Purification of Synthesis Gas

1.4 Application of Synthesis Gas

1.5 Principal Gas Phase Impurities

1.6 Gas purification

1.6.3 Membrane Permeation

1.6.4 Chemical conversion

2.2 Process Description

2.3 Equipments used in The Process

2.4 Process Flow Diagram for Amine Sweetening Process

3.2 Synthesis Gas Composition

3.3 Inlet Gas Separator

3.4 Mass Balance on Absorber

3.5 Mass balance on Stripper

3.6 Balance across over-head separator

3.7 Balance across the overhead reflux drum

3.8 Overall material balance

4.2 Conservation of Energy

4.3 Forms of Energy

4.4 Inlet Separator

4.6 Lean Solvent Exchanger

4.7 Lean/Rich amine exchanger

4.8 Over head Stripper Condenser

4.10 Energy Balance across Hydraulic Turbine

5.2 Plate Heat Exchanger

5.3 Absorber Design

5.4 Stripper Design

5.5 MDEA Surge Drum

6. INSTRUMENTATION & PROCESS CONTROL

6.2 Process Instrumentation Diagram for Amine plant

7.2 Capital Investment

7.2.1 Direct costs

7.2.2 Indirect costs

7.3 Types of Cost Estimation

7.4 Methods of Estimating Capital Investment

7.5 Percentage of Delivered Equipment Cost

7.6 Direct Cost

7.7 In-Direct cost

8.1.1 Objectives of HAZOP study

8.1.2 HAZOP Team

8.1.3 Strength of HAZOP

8.1.4 Weakness of HAZOP

8.1.5 Responsibility of HAZOP Team Members

8.1.6 Guide Words

8.2 HAZOP Study of storage Tank for MDEA

9.4 Chemical Losses

9.5 Losses due to Volatility

1.1 Synthesis Gas:

On the basis of Application

On the basis of origin

1.2 Synthesis Gas: A Historical Overview:

1804: Coal Gas use for lighting was first patented

1.2.1 Historical Terminology Related to Different types of Synthesis gas:

1.2.2 From Feedstock to Synthesis Gas: A brief over view:

1.3 Need of Purification of Synthesis Gas: