EXAMPLES OF UNCERTAINTY BUDGET TABLES

AIR DENSITY
SOP 2

BUOYANCY CORRECTIONS (NISTIR 6969)

Equation 1. OIML R 111

u 2 u 2

x
u a [m s (a n )]2 4s 4x
u m s s
s
s x
x

2
bc

Equation 2. SOP 2 Magnitude of Air Buoyancy Correction

MABC m0 (

)( a n )

Component
Description
Standard uncertainty for air density
ua
ue
Standard uncertainty for air density
equation
ut
Standard uncertainty for temperature
urh
up
us
ux

Reference

CIPM Air density paper,

e.g., 0.0012 mg/cm3
HB 143 accuracy guideline,
0.5 C; SOP 2 (NISTIR 6969)
Standard uncertainty for relative humidity HB 143 accuracy guideline,
5 %; SOP 2 (NISTIR 6969)
Standard uncertainty for pressure
HB 143 accuracy guideline,
65 Pa; SOP 2 (NISTIR 6969)
Calibration report, e.g., 0.008 %
Standard uncertainty for density of
(0.00064 g/cm3)
standard (s)
Standard uncertainty for density of
Mfg. estimate, 0.05 g/cm3
unknown (x)

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Page 1 of 11

MASS
SOP 3 (DOUBLE SUBSTITUTION, EQUAL ARM) (NISTIR 6969)
SOP 4 (DOUBLE SUBSTITUTION) (NISTIR 6969)
SOP 5 (THREE IN ONE) (NISTIR 6969)
SOP 6 (TRANSPOSITION) (NISTIR 6969)
SOP 7 (SINGLE SUBSTITUTION) (NISTIR 6969)

Cx = Cs + d + disparity (bias/drift) + unrelated corrections

Mx = Ms + d + a (Vx Vs) + disparity (bias/drift) + unrelated corrections
Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process

ubc
ua
ue

ut
urh
up
us
ux
ud

uba
usens
uresol
uecc load
umag
uo

Reference
Calibration report, divide by k
Measurement assurance process;
control charts

Standard uncertainty for buoyancy

correction
Standard uncertainty for air density
Standard uncertainty for air density equation CIPM Air density paper
(Davis/Giacomo, 1992), e.g.,
0.0012 mg/cm3
Standard uncertainty for temperature
HB 143 accuracy guideline,
0.5 C; SOP 2 (NISTIR 6969)
Standard uncertainty for relative humidity
HB 143 accuracy guideline,
5 %; SOP 2 (NISTIR 6969)
Standard uncertainty for pressure
HB 143 accuracy guideline,
65 Pa; SOP 2 (NISTIR 6969)
Standard uncertainty for density of standard Calibration report, e.g.,
e.g., 0.008 % (0.00064 g/cm3)
(s)
Standard uncertainty for density of
Mfg. Estimate, 0.05 g/cm3
unknown (x)
Standard uncertainty for disparity due to
Rectangular distribution and
drift/bias
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
Standard uncertainty of the balance
Typically not used if sp is used.
Standard uncertainty due to sensitivity of
OIML R111-1
balance
Standard uncertainty due to digital
OIML R111-1
resolution of balance
Standard uncertainty due to eccentric
OIML R111-1
loading
Standard uncertainty due to magnetism
OIML R111-1
Standard uncertainty for other factors

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Page 2 of 11

SOP 8 (MODIFIED SUBSTITUTION) (NISTIR 6969)

Cx = Cs + d + disparity (bias/drift) + unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process
ubc
Standard uncertainty for buoyancy
correction
Standard uncertainty for air density
ua
ue
Standard uncertainty for air density equation

ut

Standard uncertainty for temperature

urh

Standard uncertainty for relative humidity

up

Standard uncertainty for pressure

us
ux
ud

uba
usens
uresol
uecc load
umag
uo

Standard uncertainty for density of standard

(s)
Standard uncertainty for density of
unknown (x)
Standard uncertainty for disparity due to
drift/bias
Standard uncertainty of the balance
Standard uncertainty due to sensitivity of
balance
Standard uncertainty due to digital
resolution of balance
Standard uncertainty due to eccentric
loading
Standard uncertainty due to magnetism
Standard uncertainty for other factors

Reference
Calibration report, divide by k
Measurement assurance process
Possibly: uncorrected systematic
error

CIPM Air density paper

(Davis/Giacomo, 1992), e.g.,
0.0012 mg/cm3
HB 143 accuracy guideline,
0.5 C; SOP 2 (NISTIR 6969)
HB 143 accuracy guideline,
5 %; SOP 2 (NISTIR 6969)
HB 143 accuracy guideline,
65 Pa; SOP 2 (NISTIR 6969)
Calibration report, e.g., 0.008 %
(0.00064 g/cm3)
Mfg. Estimate, 0.05 g/cm3
Rectangular distribution and
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
Typically not used if sp is used.
OIML R111
OIML R111
OIML R111
OIML R111

QUESTION: CAN ubc BE ASSUMED TO BE NEGLIGIBLE, AT THIS LEVEL?

OR IS IT SAFER TO EVALUATE IT AND THEN DECIDE THE
NEGLIGIBILITY OF IT AND HAVE IT DOCUMENTED?

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Page 3 of 11

SOP 28 (ADVANCED WEIGHING DESIGNS) (NISTIR 5672)

Mx = Ms + d + a (Vx Vs) + disparity (bias/drift) + unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process

ubc
ua
ue

ut
urh
up
uCO2
ucce
us
ux
ud

uba
usens
uresol
uecc load
umag
uo

Reference
Calibration report, divide by k
Measurement assurance process;
control charts

Standard uncertainty for buoyancy

correction
Standard uncertainty for air density
Standard uncertainty for air density equation CIPM Air density paper
(Davis/Giacomo, 1992), e.g.
0.0012 mg/cm3
Standard uncertainty for temperature
HB 143 accuracy guideline,
0.5 C; SOP 2 (NISTIR 6969)
Standard uncertainty for relative humidity
HB 143 accuracy guideline,
5 %; SOP 2 (NISTIR 6969)
Standard uncertainty for pressure
HB 143 accuracy guideline,
65 Pa; SOP 2 (NISTIR 6969)
Standard uncertainty for carbon dioxide
determination
Standard uncertainty for cubical coefficient
of expansion
Standard uncertainty for density of standard Calibration report, e.g., 0.008 %
(0.00064 g/cm3)
(s)
Standard uncertainty for density of
Mfg. Estimate, 0.05 g/cm3
unknown (x)
Standard uncertainty for disparity due to
Rectangular distribution and
drift/bias
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
Standard uncertainty of the balance
Typically not used if sp is used.
Standard uncertainty due to sensitivity of
OIML R111
balance
Standard uncertainty due to digital
OIML R111
resolution of balance
Standard uncertainty due to eccentric
OIML R111
loading
Standard uncertainty due to magnetism
OIML R111
Standard uncertainty for other factors

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Page 4 of 11

LENGTH
SOP 10 (RIGID RULE) (NBS Handbook 145)

Lx = Ls + d + disparity (bias/drift) + unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process

ugr
ud

Standard uncertainty for graduated reticle

Standard uncertainty for disparity due to
drift/bias

ures

Standard uncertainty due to resetting of the

rules
Standard uncertainty for other factors

uo

Reference
Calibration report, divide by k
Measurement assurance process;
range charts

Rectangular distribution and

reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)

SOP 11 (BENCH METHOD) (NBS Handbook 145)

SOP 23 (PI TAPES) (NBS Handbook 145)

Lx = Ls + d + Ln [(t 20) ( - )] + disparity (bias/drift) + unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process

ugr
utc
ut
ulce (,)
utw
ud

ures
uo

Standard uncertainty for graduated reticle

Standard uncertainty for temperature
correction
Standard uncertainty for temperature

Reference
Calibration report, divide by k
Measurement assurance process;
range charts

HB 143 accuracy guideline,

0.05 C

Standard uncertainty for linear coefficient of

expansion
Standard uncertainty for tension weights
Standard uncertainty for disparity due to
Rectangular distribution and
drift/bias
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
Standard uncertainty due to resetting of the
tape
Standard uncertainty for other factors

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Page 5 of 11

SOP 12 (TAPE TO TAPE)

Lx = Ls + d + disparity (bias/drift) + unrelated corrections

Component
us
sp
ugp
uss
ud

Description
Standard uncertainty for standards
Standard uncertainty for the process
Standard uncertainty for graph paper
Standard uncertainty for spring scales
Standard uncertainty for disparity due to
drift/bias

ures

Standard uncertainty due to resetting of the

tapes
Standard uncertainty for other factors

uo

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Reference
Calibration report, divide by k
Measurement assurance process

Rectangular distribution and

reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)

Page 6 of 11

VOLUME - GRAVIMETRIC
SOP 13 (MECHANICAL BALANCE)
SOP 14 (ELECTRONIC BALANCE)
SOP 15 (EQUAL ARM BALANCE)
1
1 (t t ref )
Vtref M F M E M S M R 1 a

s w
a

1
1 (t t ref )
Vtref O3 O2 O1 M S 1 a
s w a

Vx = d(F E) + a (Vx Vs) + [1 - (t tref)] + bias/drift + other corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the measuring
process to determine mass difference
between filled and empty container;
recorded in volume units on charts to be
converted to grams by dividing a Z constant
of 1.003; represents all weighing operations
ubc
Standard uncertainty for buoyancy
correction
Standard uncertainty for air density
ua
ue
Standard uncertainty for air density equation

us
ux
utc
ut

uw

ut

Standard uncertainty for temperature

urh

Standard uncertainty for relative humidity

up

Standard uncertainty for pressure

Standard uncertainty for density of standard
(s)
Standard uncertainty for density of
unknown (x)
Standard uncertainty for temperature
correction
Standard uncertainty for temperature

ucce (,) Standard uncertainty for cubical coefficient

of expansion
Standard uncertainty for density of water

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Reference
Calibration report, divide by k
Measurement assurance process;
control chart or range chart and
d2*

CIPM Air density paper

(Davis/Giacomo, 1992),
0.0012 mg/cm3
HB 143 accuracy guideline,
0.5 C; SOP 2 (NISTIR 6969)
HB 143 accuracy guideline,
5 %; SOP 2 (NISTIR 6969)
HB 143 accuracy guideline,
65 Pa; SOP 2 (NISTIR 6969)
Calibration report, e.g., 0.008 %
(0.00064 g/cm3)
Mfg. Estimate, 0.05 g/cm3

HB 143 accuracy guideline,

0.05 C
NBS Report 10 081,
5 x 10-6 /F (0.000009 / C)

Page 7 of 11

ue

ut

Standard uncertainty for water density

equation and uncorrected systematic error
due to air-free vs air-saturated water
densities
Standard uncertainty for temperature

uread men
ud

Standard uncertainty for reading meniscus

Standard uncertainty for disparity due to
drift/bias

uba

Standard uncertainty of the balance

Standard uncertainty due to sensitivity of
balance
Standard uncertainty due to digital
resolution of balance
Standard uncertainty due to eccentric
loading
Standard uncertainty due to magnetism
Standard uncertainty for other factors

usens
uresol
uecc load
umag
uo

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Metrologia, Patterson/Morris
(1994), 7 ppm (0.000007 g/cm3)

HB 143 accuracy guideline,

0.1 C, SOPs
(ASTM E694); GMP 3
Rectangular distribution and
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
Typically not used if sp is used.
OIML R111-1
OIML R111-1
OIML R111-1
OIML R111-1

Page 8 of 11

VOLUME TRANSFER
SOP 16 (FLASKS)

Vx = VsP + VsB + V [1 + ( - ) (t tref)] + disparity (bias/drift) + unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process

utc
ut

ud

Standard uncertainty for temperature

correction
Standard uncertainty for temperature

ucce (,) Standard uncertainty for cubical coefficient

of expansion
Standard uncertainty for disparity due to
drift/bias

uread men
udrain
utime piece
uo

Standard uncertainty for reading meniscus

Standard uncertainty due to drain time
Standard uncertainty for time piece
Standard uncertainty for other factors

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Reference
Calibration report, divide by k
Measurement assurance process;
control chart or range chart and
d2*

HB 143 accuracy guideline,

0.05 C; SOPs
NBS Report 10 081,
5 x 10-6 /F (0.000009 / C)
Rectangular distribution and
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
(ASTM E694)

Page 9 of 11

SOP 18 (GRADUATED NECK)

Vx = Vs + disparity (bias/drift) + unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for the process

ud

Standard uncertainty for disparity due to

drift/bias

uread men
udrain
utime piece
uo

Standard uncertainty for reading meniscus

Standard uncertainty due to drain time
Standard uncertainty for time piece
Standard uncertainty for other factors

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Reference
Calibration report, divide by k
Measurement assurance process;
control chart or range chart and
d2*
Rectangular distribution and
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
(ASTM E694); GMP 3

Page 10 of 11

SOP 19 (LARGE NECK)

Vx

w s Vs 1 t t ref
w x 1 t t ref

disparity (bias / drift ) unrelated corrections

Component
Description
us
Standard uncertainty for standards
sp
Standard uncertainty for standards
utc
Standard uncertainty for temperature
correction
ut
Standard uncertainty for temperature

uw

ucce (,) Standard uncertainty for cubical coefficient

of expansion
Standard uncertainty for density of water
ue
Standard uncertainty for water density
equation
ut
Standard uncertainty for temperature

ud

Standard uncertainty for disparity due to

drift/bias

uread men
udrain
utime piece
uo

Standard uncertainty for reading meniscus

Standard uncertainty due to drain time
Standard uncertainty for time piece
Standard uncertainty for other factors

SOP 29 Job Aid UNCERTAINTY BUDGET TABLE EXAMPLES.doc

Reference
Calibration report, divide by k
Measurement assurance process

HB 143 accuracy guideline,

0.05 C
NBS Report 10 081,
5 x 10-6 /F (0.000009 / C)
Metrologia, Patterson/Morris
(1994), 7 ppm (0.000007 g/cm3)
HB 143 accuracy guideline,
0.05 C
Rectangular distribution and
reasons, 0.577 d, 0.29 d;
SOP 29 (NISTIR 6969)
(ASTM E694)

Page 11 of 11