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Combustion-Drive Tests
W.E,
SHOWAI-TER
ABSTRACT
This paper discusses
some oi the results
of
cotnbu stron-drive tests which were made. in a test
cel[ using a sand bed 10 in. in diameter x 10.ft
long. The test method is illustrated
and described.
The relationship
between the API gravity of the
in situ oil and the amount of air required for combustion drive is discussed
in detail. other things
constant,
t be air requirement
for combustion
drive
increases
as the API gravity of the in situ oil
If the test results
apply to actual
decreases.
reserm irs, the lowest-priced
oils may cost the
most to recover by this method.
Irz/orma~ion is shown which indicates
that the
effect
of pressure
on the amount of bydrocarbofi
br.aned is not large. A method o/ predicting
air
requirements
from the API gravity of the in situ
oil is presented.
INTRODUCTION
Combustion drive is the term used to identify
the process of interstitial or in situ burning as an
oil recovery method. Part of the in situ oil is
burned to generate the energy needed to produce
the remainder of the oil.
Combustion drive as an oil recovery mechanism
remains an economic uncertainty
in spite of aH
the work that has been done by the industry in
both laboratory and field}-6 This paper will show
some of theresults of tests which were made in a
test cell fo~ the purpose of studying the nature of
the combustion-drive process. It will present data
which indicate that the API gravity of the in situ
oil is a significant indicator of the amount of air
required to drive a burning front through oil sand.
Air requirement varies inversely as the API gravity
of the in situ oil.
UNION
OIL
BRE&
CALIF.
CO,
OF
CALIFORNIA
fk%_M!wT
TH
ALVE
EXPERIMENTAL
The tests were performed in a cell which t&iIized
a cylindrical sand section 10 in. in diamerer x 104t
long, The thin-walled metal pipe which held the
sand waa wound with twenty external electrical
Originul
office
Psper
,
1962,
manuscript
Aw,
presented
in Lo e
lRef=en=es
-M +R CH .
received
3, 1962. Revised
at37th
in Societ y of Petroleum
manuscript
Annusl
Fsll
.%%eles, Calif.
given
at end of P-e.
received
Meeting
Jan.
EnKlneers
11, 1963.
of SP 1?. Oct.
7-10,
FIG.
SCHEMATIC
.
PRODUCTION WITHDRAWN
HERE
OF COMBUSTION-DRIVE
CELL,
.
TEST
63
1963
..
..m
TABLE
IN
U.
lSi
COMBIJa
,ALYSIS
, ,.. I+ DRIVE
OF
SAND
TEST
Weight
S, Screen
Held
Size
Per
30
0.04
0.04
50
0.36
70
0.84
100
5.44
140
29.75
200
42.80
270
12.72
*Of
Cent
on Screen
40
7.92*
Pan
was
USED
CELL
thin,
5L) par
largely
quartz.
cent
was
kaolin.
The
{emainder
tained approximately 18 per cent kaolin. The eftective air permeability y before ignition ior the individual
tests varied from 200 to 950 md.
Oil production from the cell was measured dry
after removing the water by di st ill ation,.
Exhaust gas from the cell was sampled periodically and tested (by mears of a mass spectrometer)
for its principal ingredients,
including C02, CO
and 02. The C02 content of the exhaust gas was
recorded continually by a C02 analyzer.
Burning was initiated by means of an electrical
heater. Tests were performed at pressures
up to
500 psig and at raies of burning as low as I ft/D of
flame-front advancement. Sixteen tests will be discussed.
The quantity of hydrocarbon burned (fuel con
sumption) was calculated pnly for a portion of the
sand section in which burning had been as uniform
as possible.
This was usually the 4 linear ft of
sand starting 4 ft from the upstream sand face and
ending 2 ft from the downstream sand face. Values
for the amount of hydrocarbon burned were calculated
from the volume of the oxides of carbon produced
while that section of sand was burning. This method
excluded the nonequilibrium
burning which took
place during and subsequent to ignition and in the
vicinity of the flanges around the downstream sand
face.
DISCUSSION
This discussion
is concerned principally
with
the relationship between the API gravity of the in
situ oil and the volume of air required co drive a
burning front through oiI sand. It is proposed that
the air requirement can be predicted. It depends
mainly on the quantity of the fuel for combustion;
the quantity of the fuel for combustion can be predicted from the API gravity of the in situ oiI. The
API gravity appears to be a satisfactory
indicator
of the fuel-for-combustion
content of the in situ oil.
Air requirement i:; also affected by the character of
the rock, but that was held constant for the oilgravity tests.
The discussion
of fuel consumption will be in
terms of 1 cu ft of oil sand because this unir can
be readily employed in reservoir calculations.
Fuel
consumption is defined as the quantity of the fuel
for combustion (quantity of hydrocarbon burned) per
5A
TABLE
DESCRIPTION
OF
CRUDE
OILS
USED
IN
-. -...,
Test
(API)
Source
Guodalupe,
3, 3A,
8.15
17.0
Stearns,
Brea.Olinda
25.0
Stearns,
Brea.01
30.0
.%msinena,
35.0
Bornsdall.ODee,
7.
40.0
Padelfwd,
SOCIETY
OF
South
PETROLEUM
of Oi I
11*O
12.5
Santa
Maria
Valley
Belridge
inda
Whittier
Resocrans
Rasecrans
ENGINEERS
JO URN AI.
TABLE
3-VARIATION
AIR REQUIREMENT
Oil
Gravity
VS
CONSUMPTION
OIL GRAVITY
Initfpl
REQUIREMENT
VS OIL
GRAVITY
of methene
woutd
welsht
be 12/4
ratio.
= 3.
Far
example,
the
C/H
Soo
:<:
400
300
3.0
*O
-t
200
1.0
00
,~
API
;0
GRAVITY
OF
FIG,
;0
IN
SITU
;0
AT
60
[00
.0
F,
OIL
2 COMBUSTION-DRXVE
FUEL CONSUMPTION
AND AIR REQUIREMENT VS OIL GRAVITY.
Test
FUEL
WITH
CONSUMPTION
OIL GRAVITY
Initial
(API)
FUEL
OF
(Nominal)
Product
011
Water
.
011
1 Lo
19* 1
20
60
12,5
16.5
30
50
17.0
16.6
20
60
3A
17,0
17.0
20
60
25.0
23.6
20
60
30.0
29.6
20
60
35,0
35.6
20
60
40.0
40.9
20
60
Average
Burning
Test
1
(%
Exhaust
a~a~~
( scf/mhr/f@)
Nominal
Pressure
During
%tura?lon
(percentage
of
pore space)
rest
(ISSIQ)
3s0
300
200
200
450
4s0
200
200
Exhaust
Gas
COmpasltion*
(.01
per
AND
Burning
Rate
(ft/D)
0.9
1.4
5*2
0.s
6,7
6.5
1.0
0,9
C@~~&.
Re~~r*
(1~%)
(s%%)
cent)
c~o~z
..
2
3
780
840
940
0.29
0.33
0.95
3.0
1.8
1.4
205
3A
730
0.13
14.0
1.7
1.5
1.4
250
780
0.95
10.8
2.8
3.5
1.2
240
830
O*88
11.4
2.5
3.5
1.0
195
670
0.11
13.8
1.5
0.7
0.94
170
650
0095
13.4
1.7
1.9
*Ccmmcted
for use in Eqs. 1 and
mass-spectrometer
test results.
2. Average
O*77
of ali
.510
350
140
sensible
.
M>\n CH,
.
1963
Ss
-.
PRESSURE
.
.
-
-.
...+
BURNING
RATE
CRUDE
OIL
TABLE
FUEL
4EFFECT
CONSUMPTION
Test
.
.-
200
300
TEST
PRESSURE,
400
500
. ..--
Water
..-.
(psig)
17
18.0
60
470
17
17.7
20
60
470
1.9
10
17
18.3
20
60
45
2.4
17.4
20
60
450
4.8
12*
:;
1 7*8
20
60
300
5.3
13*
14+
17
17
19.2
20
60
200
5.2
17*7
20
60
500
5.4
15*
17
18.6
20
60
330
6,0
CO O,
(lb/ft8)
11*
how:
%-
Burning
During
oil
.m
5.2
Exhaust
GOS FIOW
Tmr:
Rate
(scf/min/f#)
Test
CO,
(scf/ftg)
1,000
0.81
15.1
3,3
O*15
1,6
255
835
0,29
15.2
3.5t
0.01
1,5
225
10
830
0.27
15.3
3.5
0.23
1.2
180
11*
826
0.s3
10.0
3.4
5,5
1,4
290
12*
830
0.90
11.4
3,7
3.6
1.4
255
}3
815
0,92
14*
907
0.90
15*
883
0.94
10.9
2.8
4,3
Note:
Tests
11, 12 and
contain
clay.
* Adinbatic
** (&.ected
mass.
13 were
mnde
using
1.4
o sand
heaters
not used.
fOr use in Eqs. 1 and 2. Average
spec,!rometer
test
275
which
of all
did net
sensible
results.
t Assumed.
1
TABLE
5PRODUCTION
BELRIDGE
I
100
Pr#;cl
{Nominal)
ON
Nominal
rhs,r,~m
Initial
oil
10
EXPERIMENT
.--,
-0.
14
157
-o-
15
1s3
0.19
-o-
12
154
17.43
0.19
0.10
13
162
16.10
0.15
0.10
172
14,s9
0.19
0,21
173
6,90
0,07
1,8
378
0006
18.68
0.10
18,2S
D
E
DATASOUTH
RECOVERY
~-
18.32
WELL
TktERMAL
00
PRESSURE
REQUIREMENT
Initial
e- . . -------
-1
OF TEST
AND
AIR
0.26
7.64
2.1
10
258
PSIG
*These
FIG. 3 COMBUSTION-DRIVE
FUEL
AND AIR REQUIREMENT VS TEST
CONSUMPTION
PRESSURE.
reports
< are
exhaust
about
published
gas
the .%th
with
the
anal yses
Belr idge
eansent
were
thermal
of Mobil
taken
from
recovery
Oil
tmpubl i shed
experiment
and
CO.
I
SOCIETY
S6
.. .
I
OF
ENGINEERs
JO
IJRX,il,
&.COMBUSTION
RELATIONSHIPS
Mention
was
made earlier of three factors in
addition to the quantity of the fuel for combustion
(fuel consumption) which also affect air requirement.
These factors are the C/H ratio of the fuel for
combustion (hydrocarbon burned), the amount of CO
and C% in the exhaust gas, and the amount of 02
in the exhauat gas, The C/H ratio of the hydrocarbon ~
burned can be calculated from the results of exhaust
gas analyses using Eq. 1. This equation is derivable
from stoichiomeeric consideration.
A+B
R=
where
.(1)
. ..*
21 -L4+B+C)
2.37
+Ji
6
burned,
gas,
B = per cent CO in the exhaust gas, and
C = per cent 02 in the exhaust gas.
The volume of air required to burn 1 lb of hydrocarbon can be calculated using Eq. A This equation
is also derivable from stoichiometric considerations.
v=
( )1
R
2.667 (A +
R-PI
A4B
COMBUSTION-DRIVE
WELL
Table 5 shows data from an actual combu:tion&lve producing weI1. The exhaust gas ana[yses
from this well were corrected to a methane-free
basis nnd averaged, month by month. For each month
the CO + C02, the CO/CO z and the 02(C0 z were
calculated. Using curves developed from Eq, 1 and
2, rhe C/I-l ratio of ,the fuel for combustion and the
volume of air required to burn a pound of fuel were
determined
for each month. Examination of this
Iatter column of resuks
wilf show that, when
significant amounts of oxygen began to appear in
the gas from this well, the volume of injected air
required to bum a pound of fuel roughly doubled.
This means that for Months G and H on~half of the
gas production from the well represented
air that
was injected and subsequently
produced withoutbeneficial
effect beyond transferring
heat and
kinetic energy.
The over-all fuel consumption
for the South
Belridge thermal-recovery
experiment can be calcul ated from published information. s The value is
approximately
Fig. 2.
1.9 lb/cu
0.01873
. . . . . . . ..?..
AN. ACTUAL
PRODUCING
.,
(2)
gases.
Preliminary
estimates of air requirement which
are needed before a project is started could be made
from information like that shown in Fig, 2. When
the pro ject is underway and exhaust gas analyses
are available, the preliminary estimates could be
refined, if necessary, using Eqs. 1 and 2.
MA RCIi,
1963
o~
012345.6789104
DISTANCE
OF
UPSTREAM
FIG,
BURNING
SAND
FRONT
FACE
FROM
, FEET
TYPICAL
PLOT OF OIL AND WATER PRODUCTION FROM CELL (TEST 4),
s?
TABLE
Air R#ueyt,
Oil Sand
Tes~efibor
.
Ref.
9,0
9*O
805
9.6
12,3
13
14
1s
16
17
18
DISTANCE
FROM
UPSTREAM
SAND
FACE,
FEET
7
6
5
6
7
5
245
219
251
295
358
301
Eq,
2,
Fig.
243
228
235 :
255
345
230
method.
The API gravity of the in situ oil can be used
to predict fuel consumption
which, in turn, can
be used together with exhaust gas analyses to
to determine the
estimate
the air requirements,
volume of reservoir burned through at any time,
and to aid in day-to-day combustion-drive re servoir
engineering. This assumes that appropriate correlations are avaiIable,
REFERENCES
L
OF
PETROl.EllM
l?NC INltERS
JOURNAL