BUTADIENE dagah ren UNIT e Ra Be aa CHEMICAL CLEANING PROTOCOL LOOP 1-2 CC-121CHEMICAL CLEANING REPORT OF BdEU & AU AREA _ LOOP 1-2 CC- 121 GS Om Es CHEMICAL CLEANING OF BUTADIENE EXTRACTION UNITS & AU AREA PROJECT: OPaL DFCU AND AU UNITS, CLIENT: ONGC Petro additions Limited Contractor: SAMSUNG ENGINEERING CO, LTD Sub — Contractor: ARUDRA ENGINEERS PVT LTD CHENNAI INDIA Page 1 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 A DESCRIPTION PAGE SYSTEM IN OPERATION CIRCUIT LOOP 1-2 CC - 121 ACTIVITY REPORTS ANALYTICAL REPORT NEUTRALIZATION TEST REPORT BY THIRD PARTY 10 7 CORROSION RATE 18 CONSUMPTION OF CHEMICALS , WATER& DIESEL, 19 GRAPH — ACID & IRON CHART 20& 24 10 ‘TUBE SAMPLE BEFORE CHEMICAL CLEANING 2 TUBE SAMPLE AFTER PASSIVATION STEEL WOOL TEST - INITIAL STAGE 23 4 1 12 STEEL WOOL TEST - FINAL STAGE | PROTOCOL 25 26 Page 2 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 7 EE ~ 130 A to D, EE - 110, ‘COLUMN / VESSELS EE ~111,VV-110,EE = 142 /EXCHANGERS cC-121 A&B, EE - 120 A&B, EE - 121A&B, EE - 193A&B PUMPS SUCTION & DISCHARGE OF PUMPS 13-PC-122 13-PC - 133 13-PC-121 Page 3 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 SANGIN ENGINERING >- ACTIVITY REPORTS LOOP 1 ~2 CC - 121 DATE & " "TIME (Hrs) ACTIVITIES 12.04.2016 | PRESSURE TEST O} PORARY PIPING ‘System involved: Supply and Return lines of temporary system up to Loop 1- 1 permanent system hook up points: Suction & discharge of pump 13 PC 122, PC 133, PC 121. 17.00 | Pump started for filling with fire water. 17.20 __| System filling completed and press raised 12 Kg/ ent 17.55 Hydro test start — 10 Kg/ om’ 18.10 | Hydro test end —10 Kg/ em"No leakages found. — 13.04.2016 | COLD WATER FLUSHING 00.55 | System filling started with fire water through 122 Pump discharge line and suction line full open. 02.00 122 Pump suction valve closed and filling started for VV — 110, EI —110, 03.50 110, FE— 111 filling completed and flushing started 05.00 | VV—110, EE— 110, EE— 111 isolated and filling started for EE 120 A, EE — 120B 08.00 __| Flushing stopped and filling started. EE 120 A, EE — 120 B valve closed. 12.15 122 Pump return valve 20% open, 121Pump return valve 50% close, EE 120 as A & B 20% open flushing started. Bottom pressure 5.8 Kg/em” - 14.25 _ | Fire water filling stopped and draining started 15.00 _ | Filling started through 133 pump discharge through 130 A, 130 B, 130 C, 130 D, EE 142 A & B, EE 193, BE 131, BE 110, BE 120 A & Ball line taken in __| the circuit and open flushing started. 20.15 | System filling started with fire water through 122 pump discharge full open, 133 pump discharge 30 % open. 14.04.2016 03.00 | System CC - 121 filling completed and recirculation started. 122 pump discharge full open, VV ~ 110, EE — 110, EE ~ 111, return 10% open, CC 121 over flow line to EE — 121A, EE — 121B, VV ~ 121 20% open, CC — 121 to EE 120A & EE — 120B line 3” line full open 133 pump supply & return closed. During the processpH, conductivity, turbidity is tested and results are tabulated in Annexure — A Page 4 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 AW sa VA AGEING LL HOT WATER FLUSHING Steam charged to raise the temperature to bringing 65°C. Draining started for Exchanger. Draining completed. [ Fire water filling started. System filling completed and recirculation established. During the process pH, conductivity, turbidity and temperature is tested and results are tabulated in Annexure ~B aot LLAS Water coming from VV 121 & EE 121 A& B 13.30 Steam charged to raise the temperature. _| 17.00 NOTE: Visually the water sample appears pale yellow in colour. This is due to the oxidation of iron which reflects in the slight higher value of turbidity. The total iron was Analysed was 2.7 ppm. This is agreed upon mutually between Opal, Samsung and Arudra and Hot water flushing declared completed. DE-GREASING _ 19.50 Caustic soda flakes addition started 20.30 Caustic soda flakes addition completed — 4300 kgs 20.45 Non ionic wetting agent added — 200 kgs. 15.04.2016 00.15 133 pump supply and return closed. co 01.00 ‘Steam charged to raise the temperature. CC — 121 filling completed. 122 pump discharge full open, VV — 110, 110, EE — 111, 10% open CC — 121 over flow line to El 121A & B, VV — 121 40% open, CC — 121 to EE 120 A & B, VV — 181 3” line 10% open. 01.25 Caustic soda flakes addition started 02.00. Caustic soda flakes addition completed — 2700 kgs 02.10 Non ionic wetting agent added — 150 kgs. cet 06.00. VV — 110, BE — 110, BE ~ 111 line closed 06.45 Caustic soda flakes added — 500 kgs. 07.00 VV — 181 3” line closed. 11.00to | All exchanger by pass valve open in circulation, During the process pH, Total | 11.30 alkalinity as NaOH %, oil and grease and temperature is tested and results 7 are tabulated in Annexure — C Total chemicals were consumed: | 1. Caustic soda flakes — 7500 kgs. (For making 1 % solution) _| 2. Non — ionic wetting agent — 350 kgs.(For making 0.05 % solution) 12.05 System draining started under plant air.(CC ~ 121, VV — 110, EE — 110,111 & EE ~ 121A & B, VV ~ 121) 16.04.2016 00.15 System draining started under plant air (EE — 130 A,B,C,D & EE - 142 A&B, and EE ~ 193, BE ~ 131, EE — 110, EE~— 120 A & B) Page 5 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 SAMSUNG EAGNEEIG 04.30 __ | System draining completed. The spent alkaline solution is neutralized COLD WATER FLUSHING - 1 05.00 | System CC - 121 filling started with fire water through PC 122 pump discharge& supply line full open. And flushing started. [05.40 | Flushing stopped and CC — 121 through PC 122 return Tine 06.00 | VV 110, EE ~ 110,11 filling completed and open flushing started, 06.45 _| Flushing stopped and CC ~ 121 filling started. 08.30 | CC— 121 Bottom pressure 5.0 Kg/em’ 10.15 | System filling completed and recirculation established and open flushing started for CC — 121, BE~121 A&B EE — 130 A,B,CD open flushing started, CC — 121 main return open & supply valve close, VV ~ 110 & EE ~ 110, BE ~ 111 return line open to temporary drain valve in open , PC 121 return close. During the processpH, conductivity, turbidity,Total alkalinity and oil and grease is tested and results are tabulated in Annexure ~D [15.20 Pump stopped and system draining started. 17.04.2016 03.55 _| System draining completed, cH zi COLD WATER FLUSHING — 2 04.00 | System CC — 121filling started with fire water through PC pump discharge and supply line full open and flushing started. 05.00 Flushing stopped and CC — 121 filling started 7 05.20 'V — 110, EE ~ 110, FE— 111 flushing started. 05.55__ | VV— 110, EE— 110, EE — 111 flushing stopped and CC — 121 filling started. 09.00 __ | System filling completed and water coming from EE ~ 121 and VV - 121 09.15 ~ 121 and VV — 12Ifilling completed and open flushing started. 10.45 | VV—110,BE — 110, EE — 111 return valve 20% open. 12.15 | Filling started through 131 pump discharge to BE ~ 130 A,B,C,D and 142 A.B, EE~193 and EE - 120 A.& B 13.10 | Filling completed and open flushing started. During the processpH, conductivity, turbidity,Total alkalinity and oil and grease is tested and results are tabulated in Annexure ~ E _[ System draining started System draining completed. INHIBITED CITRIC ACID PICKLING 02.15 | System CC — 121 filling started with DM water through PC pump discharge and supply line full open and flushing started. 03.30 | VV—110, EE — 110, EE — 111 filling completed. 07.45 | CC—121 to EB — 120 A & B filling completed and open flushing started. (09.00 | 133 pump supply open automatically filling started 09.45, — 130 A to D and EE - 120 A & B filling completed and open flushing Page 6 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 SWUSUNG ENGINEERING started H a 10.20 | Open flushing stopped and recirculation established. 10.30 | Loop EE — 130 A to D isolated PC 133 supply closed, CC = 121 taken in circulation and Steam charged to raise the temperature bringing 70°C MP steam valve closed due to steam line tripped. Pump stopped due to steam problem Pump started for recirculation established. Steam charged (o raise the temperature CC=121, VV = 121 and EE — 121 A & B loop return temperature 50.9 °C Inhibitor Coronil 92 B additions started. Inhibitor Coronil 92 B additions completed — 1410 k; 133 pump discharge valve closed, Citric acid addition started Citric acid addition completed — 17500 kgs and Ammonia 800 kgs added. ‘Ammonium bi fluoride added — 600 kgs. 19.04.2016 01.05 __| Citric acid ~ 1250 kgs and Ammonia ~ 100 kgs added. 04.40 110, EE ~ 111 taken in circulation. 05.50 | Citric acid — 1250 kgs, Ammonia — 100 kgs and Ammonium bi fluoride — 50 kgs added, 06.00__| EE— 130 A,B,C,D to EE — 120 B taken in circulation. 07.30 __| Citric acid — 1250 kgs, Ammonia ~ 100 kgs added, 09.40] VV 110, BE~ 110, EE ~ 111 taken in circulation. During the process Acidity, pH, Fe**, Fe*’,Total Fe temperature and steel wool test is tested and results are tabulated in Annexure ~ F Total chemicals were consumed: 1, Inhibitor Coronil 92 B— 1410 kgs. (For making 0.02 % in solution) 2. Citric acid ~ 21250 kgs (For making 3 % in solution 3. Ammonia — 1100 kgs (For pH boost up in solution) 4, Ammonium bi fluoride ~ 650 kgs.(For making 0.1 % in solution) 11.00 | Pump stopped and system draining started under Nitrogen blanketin; 20.04.2016 02.00 __| System draining completed. The spent acid solution is neutralized. DM WATER FLUSHING - 1 03.05 | System CC — 121 filling started with DM water through PC pump discharge __| and supply line full open and flushing started. 04.45 | VV—110, EE — 110, EE — 111 flushing started. (05.15 | Flushing stopped and CC — 121 filling started. iz 09.20 | Water coming from CC — 121 vent line 09.30 | Water coming from ventEE — 121 A,B and VV — 121 and recirculation , open flushing started fe 11.45 | Water coming from vent EE — 130 A to D and CC — 121 hold up supply and Page 7 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 A return close. EE — 130 A to D circulation and open flushing started. results are tabulated in Annexure ~G During the process Total Fe, pH , conductivity, and turbidityis tested and 21.04.2016 15.50 __ | Pump stopped and system draining started under Nitrogen blanketing. 06.00__| System draining completed. DM WATER FLUSHING - 2 06.45 | System CC - 121 filling started with DM water through PC pump discharge and supply line full open and flushing started. 07.45 __| Flushing stopped and filling started. 08.15 | EE — 110 open flushing started 08.45 | EE— 110 open flushing stopped and CC — 121 filling started. 09.50 | Steam charged to raise the temperature brining 55°C 11.45 | CC— 121 filling completed. VV — 121 ,EE — 121 A & B also filling flushing started. 12,00 | PC 133 supply line 10% open for filling EE ~ 130 A to D. completed water coming from vent line and recirculation established & open 12.50 | EE—130.A to D filling completed and kept in hold up. 13.00 | CC~ 121 Recirculation established During the process Total Fe, pH, conductivity, and turbidi 14.20 | CC~ 121 loop temperature 50 °C 14.30 | Citric acid addition started 14.50 _| Citric acid addition completed — 1400 kgs and Ammonia added ~ 150 kgs. 18.00 VV — 110 return line 10% open and PC 133supply line 10% open and EE — 130 A to D return 20% open. | 22.04. 20.15 Return line temperature 58 °C 20.30 Ammonia addition started to raise the pH 9.5 to 10.0 20.40 _| System CC = 121, VV — 110, VV — 121 circulations taken. 01.30 | Ammonia addition completed ~ 5400 kgs. 02.00 __| pH, Inlet — 9.82 Outlet 9.55 tested and results are tabulated in Annexure ~ HI | CITRIC ACID RINSE AND NEUTRALIZATION & PASSIVATION 02.15 | Sodium Nitrite addition started. 03.00 Sodium Nitrite addition completed — 6000 Kgs. 13.00 | EE~ 130 A to D supply and return line 20% open, VV — 110, EE~ 110 and EE — 111 return line 10% open. 13.15 ‘Ammonia added — 600 kgs. 14.00 EE — 130 A to D and VV ~ 110, EE — 110, EE — 111 recirculation started. 14.30 | Sodium Nitrite added — 1000 Kgs. results are tabulated in Annexure ~I Total chemicals were consumed: During the process Acidity, total iron ,pH and temperature is tested and Page 8 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA A LOOP 1-2 CC- 121 i Om 1. Citric acid — 1400 Kgs (For making 0.2 % in solution) 2. Liquor Ammonia - 6150 Kgs (For pH boost up in solution) 3._Sodium Nitrite — 7000 kgs (For making 1 % in solution) 16.10 Passivation process declared completed and system draining started under Nitrogen blanketing, (EE ~ 130 A to D and VV ~ 110, EE~ 110, BE~111) 22.45 | CC—121 draining started 23.04.2016 10.10 | System draining completed. ‘The spent alkaline solution is neutralized. ANALYTICAL REPORT Page 9 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC-121 SHUSING ENGINEERING COLD WATER FLUSHING Annexure — A Date /Time | Pump pressure pH | Conductivity | Turbidity | Remarks (Hrs) Kg/em? (wis) (NTU) Inlet Outlet 13.04.2016 O15 40 0.0 851 3774 19.1 01.40 4.0 0.0 8.46 362.2 113 02.15 4.0 0.0 8.40 362.1 7.6 02.30 4.0 0.0 8.46 368.2 10.5 04.45 4.0 0.0 8.36 345.3 58 07.00 5.0 0.0 6.73 403.5 45.4 07.30 5.0 0.0 6.79 348.5 16.1 08.00 6.0 0.0 7.04 329.1 144 08.30 65 1.0 7.05 292.5 67 09.00 67 15 7.16 296.8 4 09.30 65 4.0 7.24 296.8 12.2 10.00 65 35 7.21 299.8 118 10.30 65 1.0 7.25 332.4 28.1 11.00 6.7 15 7.25 336.6 271 11.30 65 1.0 7.27 325.7 144 12.00 65 0.0 7.29 321.6 14.9 [12.30 65 18 721 310.5 11.6 13.00 65 2.0 7.27 297.5 17.1 13.30 6.0 1s | 7.23 312.8 14.7 staal 14.00 6.0 15 721 3119 14.1 18.00 3.0 1.0 771 333.7 14 19.00 3.0 1.0 7.69 325.9 42 19.45 3.0 1.0 7.92 334.9 5.8 21.15 40 35 8.22 304.2 6.0 Page 10 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 A a SAMSUNG FNGNEERNG HOT WATER FLUSHING Annexure ~ B declared completed serene aes Temperature | yy Conductivity Turbidity Homans irs) Kelem? eC) (ws) | TU) In | Out | In | Out 14.04.2016 = 05.30 7.0 25 54 35 7.72 40.5 06.00 | 7.0 | 4.0 | 5&8 | 35 | 7.74 37.2 _| 06.30 | 7.0 | 35 | 58 | 35 | 7.78 39.4 o7.00 | 7.0 [35 | 58 | 35 | 7.82 40.3 7 0730 | 7.0 [35 | 61 | 38 | 7.81 54.1 08.00, 7.0 0.5 66 44 7.84 62.3 0830 | 7.0 [1.5 | 80 | 46 | 7.86 64.2 is | 67 [2.0 7.45 88.4 12.00 | 6.7 | 2.0 739 94.1 13.00 67 2.0 735 > 100 14.00 | 7.0 | 25 | 65 | 60 | 7.42 > 100 15.00 | 68 | 25 | 70 | 58 | 737 "> 100 16.00 | 65 [3.0 | 76 | 60 | 7.42 100 17.00 | 65 | 40 | 78 | 62 | 738 > 100 18.00 6.5 25 88 7 731 > 100 19.00 | 65 | 25 | 87 | 79 | 739 > 100 NOTE: Visually the water sample appears pale yellow in colour This is due to the oxidation of iron which reflects in the slight higher value of turbidity. After removing the interference of iron, again when checked for the turbidity the value drops to the acceptable limit of < 10 NTU.The | uults was observed to drop from 100 NTU to 2.5 NTU. Total Iron analyzed was 2.7 ppm his is agreed upon mutually between Opal, Samsung and Arudra and Hot water flushing Annexure —C Page 11 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 A a DE — GREASING tenho jem Temp Total Ol & 2 co pH Alkalinity as | Grease | Remarks in) Rote NaOH (%) | (ppm) In_| Out | In | Out | _ 14.04.2016 = 20.45 67 | 28 | 79 | 79 | 1234 1.792 Eee 21.45 67 3.2 71 | 76 12.46 3.04 12.0 22.45 67 32 BB 74 12.60, 2.30 = 23.45 67 3.2 7B 72_| 12.54 2.08 12.4 15.04.2016 : oo4s | 7.0 | 15 | 53 | 51 | 1239 | 03 Ect 01.45, 7.0 2.0 69 56 | 12.26 0.2 13.2 02.45, 7.0 17 70_ | 58 12.28 0.24 03.45, 70 is 70 58 12.34 0.22 18.0 04.45, 7.0 | 2.5 67 58 12.26 0.14 it |___ 05.45 7.0. 3.0 67 59 12.54 0.54 oo 06.45 | 60 | 3.3 | 75 | 65 | 12.61 118 19.5 07.45, 7.0 3.0 77 66 12.63 1.22 08.45, 7.0 | 3.0 B 66 12.60 118 19.8 09.30 7.0 3.0 B 66 12.65 1.16 19.6 10.30 7.0 | 3.0 7B 67 12.63 1,024 11.30 7.0 3.0 77 66 12.64 1.04 19.0 Annexure Page 12 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA : LOOP 1-2CC-121 A MS las BASEN COLD WATER FLUSHIN Pump a aasial Total | O11& D came ven pH Sr r ae Alkalinity as | Grease Ta | Out NaOH (ppm) | (ppm) 16.04.2016 : 40 | 00 | 12.60 | _17380 $100 3040 45 | 00 | 1257| 16354 38.8 2016 | 72 “09.30 | 5.0 | 0.0 | 12.50 | 12800 > 100 2000 8.6 1115 | 70 | 3.5 | 10.45 | 428.9 84 80 Nil 12.15 | 7.0 | 35 | 10.04 | 384.7 10 40 13.50 | 70 | 3.5 | 12.78 | 38580 38.2 6520 96 1515 | 70 | 35 | 12.71] 19850 B2 3680 34 16.15 | 5.0 | 5.0 | 1159 | 1054 17.6 220 08 Annexure —E COLD WATER FLUSHING - 2 Pump ; i a Total | O& Date/Time | pressure | yy | Conductivity Twehit | ana a | Grease In | Out NaOH (ppm) | (ppm) 17.04.2016 E a [044s | 45 | 20 | 10.01 390 38.1 40 Nil 05.45 | 45 | 21 | 8.79 356 518 2 Nil 10.15, 65 3.5 9.58 328.6 23.3 24 11.00 | 65 | 3.5 | 957 356 23.2 16 1130 | 65 | 35 | 9.50 317 176 2 1330 | 35 | 35 | 12.19 | 4580 47 696 ais | 35 | 3.5 | 11.28 876 25 120 _| 15.00 | 50 | 25 | 10.12 387 45 40 Nil 1530 | 5.0 | 25 | 9.80 385 72 28 16.00 | 50 | 25 | 950 | 479 88 70 16.30, 5.0 2.5 947 375 5.0 24 | _ Nil Page 13 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 Annexure —F INHIBITED CITRIC ACID PICKLIN Pump Citric | 5.3 | pe2 | Total Steel Date /Time | pressure ae acid | S| xe Fe | pH | wool (Hrs) Kg/em? eo) (%) (ppm) | (ppm) (ppm) test In | Out | In | Out 18.04.2016 ‘ 23.30 | 40 | 77| 69 | 082 | 163 | 593 | 756 | 3.52 | Ok 19.04.2016 00.00 [7.0] 4.0 | 76 | 70 | 3.36 | 163 | 2627 | 2790 | 3.58 00.30 [| 7.0| 40 [77] 71 | 3.32 167 | 2654 | 2817 | 3.55 | Ok 01.00 [7.0 | 4.0 | 77 | 70 | 3.26 167_| 2678 | 2845 | 3.62 01.30 [7.0] 4.0 [77 | 71 | 3.20 167 | 2738 | 2905 | 3.57 | Ok 02.00 | 7.0 | 4.0 | 76 | 71 3.17__|_167 | 2762 | 2929 | 3.55 02.30 [7.0 | 4.0 | 76 | 70 | 3.15 167_| 2790 | 2957 | 3.54 | Ok 03.00 [7.0 | 4.0 | 76 | 70 | 3.22 | 167 | 2804 | 2971 | 3.63 03.30 [7.0 | 4.0 | 75 [70 | 3.23 167 | 2818 | 2985 | 3.60 | Ok 04.00 | 7.0 | 4.0 [75 | 70 [3.23 167 | 2818 | 2985 | 3.61 04.30 [7.0 | 4.0 | 75 | 72 | 3.23 167_| 2818 | 2985 | 3.60 | Ok 05.00 3 [73 | 70 | 2.59 iit_| 1676 | 1787 | 3.26 0530 [65] 35 [73] 70 | 252 1] 1648 | 1759 | 3.23 | Ok 06.30 [5.5/3.5 | 73 | 7 | 2.54 167 | 1116 | 1283 | 3.09 07.00 [5.5 | 3.5 | 73 | 71 2.59 167 | 1283 | 1450 | 3.05 | Ok 08.00 [5.5/3.5 | 74 | 70 | 3.22 | 167 | 2995 | 3162 | 3.59 08.30 [5.5 | 3.5 | 74[ 70 | 3.15 167 | 2904 | 3071 | 3.57 | Ok 09.00 [5.5 | 3.5 | 74 | 71 3.15 167_| 2932 | 3099 | 3.56 0930 [5.5| 3.5 [74] 70 | 3.15 167 | 2932 | 3099 | 3.54 | Ok 1o10 [55] 35 [73 [ 70 | 3.11 167 | 2793 | 2960 | 3.55 10.40 [55/35 [73 | 70 | 3.11 167 | 2793 | 2960 | 3.52 | Ok Annexure ~G Page 14 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC - 121 BR Ox, Gs TS acts | a DM WATER FLUSHIN' 1 Pump - Date /Time pressure Conductivity | Turbidity Total Fe dirs) | _Kgyem’ | PA | (us) @xru) | (pm | Remarks Tn | Out F 20.04.2016 a 04.10. 40 | 2.0 3.67 867, 23.8 307 05.10 4.0 2.0 3.75 344 15 167 10.15 7.0 2.5 4.26 208 38.6 195 15 | 7.0 25 4.93 138 33.2 125 iz 12.30 5.0 3.0, 3.76 656 30.8 223 |__13.30 5.0 3.0 3.60 976 35.2 335 __ 14.30 5.0 3.0 3.70 869 17.10 268 15.15, 5.0 0 | 3.96 415 1.6 7 Annexure —H DM WATER FLUSHING - 2 Pump Date /Time pressure Turbidity Total Fe (Hrs) Kg/em* pH (NTU) co | In Out 21.04.2016 0730 | 40 | 15 | 448 46.26 125 i0 : 08.30 40 LS 493 26.41 8.6_ 5.0 12.00 7.0 3.5 5.36 18.0 318 5.5 12.30 7.0 3.0 5.91 M2 21.6 4.18 Annexure I Page 15 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC-121 A SWuSUNG las a7 CITRIC ACID RINSE AND NEUTRALIZATION& PASSIVATIO! Pump Temp Date/Time | pressure °c) Citric 7 Total Fe | Remarks (Hrs) Kg/em? i acid (%) | (ppm) In_| Out | In_| Out 21.04.2016 16.00 | 7.0 | 3.0 | 75 | 53 7 1630 | 7.0 | 3.0| 74 | 58 | 007 | 407 335 1730 | 70 | 3.0 | 75 | 59 | 023 | 351 | 670 18.00__| 7.0 | 3.0 | 75 | @ | 028 | 3.56 89.3 1830 | 7.0 | 35 | 72 | 60 | 025 | 3.61 106 19.00 | 7.035) 70 | 58 | 032 | 3:58 112 1930 | 7.0 | 3.5 | 68 | 58 | 028 | 3.55 122 22.04.2016 02.00 7.0. 68 64 Z _3.55 03.00 | 7.0 ~67_| 64 9.85 04.00 7.0 65 65 10.30 a 05.00__|7.0 65_|_65 10.31 06.00__|7.0 64 | 65 1033 | __ 07.00 | 7.0 | 1.0 | 63 | 64 7 10.35 08.00 | 7.0 | 1.0 | 62 | 63 10.17 09.00 | 7.0 | 1.0 | 63 | 62 10.20 10.00 | 7.0 | 3.0 | 63 _| 62 10.20 11.00_|7.0 | 3.0 | 61 | 60 | _ 10.14 12.00 | 7.0 | 3.0 | 60 | 58 10.02 14.00 7.0 3.0 59 57 9.97 1430 7.0 | 3.0 | 58_| 58 10.07 15,00_| 7.0_| 3.0 | 58 | 57 10.04 1530 | 7.0 | 3.0. | 57 | 55 9.97 [ Page 16 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC-121 Sau ENGINEERING »- NEUTRALIZATION TEST REPORT BY THIRD PARTY Page 17 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2CC- 121 = ‘a SAMSUNG ENGINEERING CORROSION R. DESCRIPTION COUPON NOT COUPON NO2_ METAL LOss Initial weight (gm) _ 97.2724 98.9346 Final weight (gm) —97.1519 98.8191 Metal loss (gm) 0.1205 0.1155 AREA 7 7 _| OD (em) 5.860 5.880 1D (em) 5.145 3.142 H (cm) 1.980 1.972 2n (K+) [h+(R-H] é ‘Area in(cm”) 80.7838 81.0198 Area in (m’) 0.00807838 0.00810198 Corrosion rate (gm/m”) 14.91 14.25 ‘Average corrosion rate (gm/m’) _| 14.58 ‘Total quantity of oxides removed ‘Total Iron removed from the system Loop I — 2 (Ct Total volume considered — 700 M' ~ 121) ~ 2960 ppm. 2Fe 112 Fe03160 —1.43(factor) As Fe 2960 ppm x 700 M* 1000 x 1000 2.072 MT or 2072 kgs as Fe _ As FeO; 2072 kgs as Fe x 1.43 2962.96 kgs as FexO3 ‘Amount of iron oxide removed as Fe,Osfrom the Loop 1 — 2 (CC — 121) during chemical cleaning process=2962.96kgs Page 18 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA _ LOOP 1-2 CC- 121 SMS ENGINEER UANTITY OF CHEMI SI. | Process ‘Chemicals Purity | Cone | Quantity No Step_ (%) | (%) used | [1 Caustic soda flakes - NaOH 98.1 1.0 | 7500 kgs 2_| De -Greasing | Non — Tonic wetting agent 99.4 | 0.05 | 350 kgs 3 ‘Anti-foaming agent 99.0 _| Asrewird | 50 kgs 4 Citric acid — CgHsO7 99.93 | 3.0 | 21250kgs | 5_| Inhibited [Inhibitor Coronil 92 B 99.2 | 02 | 1410kgs 6 | Citric acid [Ammonium bi fluoride—NFGFHF [98.8 | 0.1 | 650 kgs T pickling [Liquor Ammonia - NH OH 25 pH | 1100 kgs 8 ‘Anti-foaming agent 99.0 | Atewied 9 | Mild Rinse, | Citric acid — CoHyO> 99.93 | 0.2 [10 | Neutralization | Liquor Ammonia - NHy OH 25 pH | 6150 kes 11_| &Passivation | Sodium Nitrite —NaNOo 99.3 | 1.0 | 7000 kgs FIRE WATER, DM WATER& DIESEL CONSUMPTION FOR THE ENTIRE PROCESS SI.No Description Fire water DM water DIESEL (acu cw) a) (Liters) 1__| Cold water flushing 900 - ~2__| Hot water flushing 900 = 3__| De~Greasing - : 4 _| Cold water flushing - 1 900 = 5__| Cold water flushing - 2 800 = | 6 Inhibited Citric acid pickling : 800 7__| DM water flushing - 1 Tithe 800 8 | DM water flushing - 2 - 300 9 | Citric acid rinse and passivation ~ = ‘Total quantit: 3500, 2400 4800 Page 19 of 26szsoozates [se [sve ere enz sz ese] oot |eve lee eve exe sve ave] ce lace wee see wo vmo——| G06 |0€ 008 007 0€5 [oF |ovs|oev oo ore ove oe aoz ver |oot ceo ovo eee o ST : st F ’ LYWH) ALICGIOV BOVIS ONT Told GIoV ORAL GALANT SHAVED IOLA TVNV Izi-99 7-1 dO0OT Vaud AV 8 NaPa AO LAOdTA ONINVATO TVOINGHDszso weateg BOVIS ONT DOld lV ONLI) CALIENTE LYWH NOU! 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(wid) 03CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 SANSING ENGINEERING BEFORE CHEMICAL CLEANING T { SAMPLE Page 22 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA _LOOP 1-2 CC- 121 SWUNG ENGINEERING ee »- AFTER PASSIVATIONTUBE SAMPLE Page 23 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC- 121 >> STEEL WOOLTEST- INITIAL STAGE Page 24 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1-2 CC-121 A STEEL WOOL TEST- FINAL STAGE Page 25 of 26CHEMICAL CLEANING REPORT OF BdEU & AU AREA LOOP 1~—2 CC - 121 A @Q oz PROJECT: OPaL, DUAL FEED CRACKER UNIT & ASSOCIATED UNITS PROTOCOL: CHEMICAL CLEANING OF BdEU & AU AREA LOOP 1-2 (CC- 121) COLUMN/EXCHANGERS/ EE- 130 A to D, EE ~ 110, — aoa ee 121A&B, EE - 193A&B Suction & discharge of PUMPS pumps 13-PC- 122 13-PC-133 13-PC- 121 CONCLUT! ‘The Pre— Commissioning Chemical Cleaning of BUTA DIENE EXTRACTION UNIT (ASSOCIATED UNIT) for LOOP 1 ~ 2 (CC — 121) was successfully declared completed. ‘Test coupon (kept inside pipeline) inspection was done jointly by M/s. OPaL, M/s. SECL and M/s, Arudra on 25.04.2016, and. Quality of passivation (Magnetite layer) formation was found uniform and satisfactory. Mis, Arudra Engineers Mis, Samsung Mis. ONGC Petro | Pvt Ltd Engineering co, Ltd_| _ additions Limited wen] Pye | ee? | OF ae Name | Gt. CHEPHIYAN FZ WCe, leas Date | 26/64/2616 DL/ou / 266 Page 26 of 26