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3+[1]
3++ Cr
6+ Fe
Fe0 +Cr
1,5:3
3:3
3:9
3:18
mortio
2.1
1.9
1.7
1.5
0 30 60 90 120
Tiempo (min)
1
1
=kt+
[2]
2
2 [ A] t=t
2[ A ]2t =0
v =k [ A]x [3 ]
Adems segn la ecuacin para una reaccin de tercer orden, se
determin la su constante de velocidad como se muestra en la
Tabla3
Tabla2. Ecuacin de tercer orden, constante de velocidad, y
velocidad de reaccin en las diferentes proporciones Fe:Ext y
una solo con mortio
Cte de
Vel de la
Fe:Ext
Ecuacin
velocidad reaccin (v)
(k)
(ppm/min)
1,5:3 y = 0.0006x + 0.1086
0.0006
0.0096
3:3
y = 0.0002x + 0.0897
0.0002
0.0032
3:9
3:18
morti
o
y = 0.0005x + 0.1027
y = 0.0005x + 0.1010
0.0005
0.0005
y = 0.0004x + 0.0794
0.00004
0.0006
f(x)
= 170.85x
- 308.57
Linear
(1,5:3)
R = 1
50.000
Linear (1,5:3)
c/q
3:3
45.000
Linear ( 3:3)
40.000
Linear ( 3:3)
35.000
3:9
30.000
Linear ( 3:9)
Linear ( 3:9)
25.000
20.000
3:18
Linear
( 3:18)
1.700 1.800
2.100
2.200
R = 11.900 2.000
Linear ( 3:18)
C(ppm)
0.55
-2.6
1,5:3
-2.7
0.65
0.7
0.75
0.8
f(x)
= (1,5:3)
- 2.33x - 1.27
Linear
3:3
R = 1 f(x)
f(x)== - -2.84x
2.96x- -0.96
0.89
-2.8
ln(q)
0.6
R
R==11
-2.9
Linear (-33:3)
-3.1
-3.2
3:9
Linear ( 3:9)
-3.3
3:18-3.4
=1
Linear R
( 3:18)
ln(c)
0,9993
0,9991
-0,8151
-0,5536
3:9
3:18
0.0080
0.0080
0,0226
0,0058
0,999
0,9999
-0,7119
-0,7263
0,0160
0,017
[3]
[4]
[5]
[6]
[7]
id=S4bjFOEXRzMC&printsec=frontcover&source=gbs_
ge_summary_r&cad=0#v=onepage&q&f=false. [ltimo
acceso: 20 08 2016].
Agencia para Sustancias Toxicas y registro de
enfermedades (ATSDR), Resea Toxicologica del
Cromo, 2008. [En lnea]. Available:
http://www.atsdr.cdc.gov/es/phs/es_phs7.html. [ltimo
acceso: 24 8 2016].
W.-x. Zhang, Nanoscale Iron Particles for
Environmental Remediation: An Overview, [En lnea].
Available: http://link.springer.com/article/10.1023%2FA
%3A1025520116015. [ltimo acceso: 20 08 2008].
S. G. Y. W. Raimondi F, Nanoparticles in energy
technology: examples from electrochemistry and
catalysis., 2005. [En lnea]. Available:
http://www.ncbi.nlm.nih.gov/pubmed/15776488. [ltimo
acceso: 20 08 2016].
BMRB, Nanotechnology and Nanoscience, [En lnea].
Available: http://www.nanotec.org.uk/. [ltimo acceso:
20 08 2016].
E. D, Materials conservation: Not-so-new technology,
2006. [En lnea]. Available:
http://www.nature.com/nmat/journal/v2/n8/abs/nmat951.
html. [ltimo acceso: 20 08 2016].
[8] S. H. H. W. y. W. M. Chang MC, Using Nanoscale ZeroValent Iron for the Remediation of Polycyclic Aromatic
Hydrocarbons Contaminated Soil. Air & Waste Manage
Assoc 55: 1200 1207, 2003. [En lnea]. Available:
http://www.ncbi.nlm.nih.gov/pubmed/16187589. [ltimo
acceso: 24 08 2016].
[9] Z. W. Li XQ, Iron Nanoparticles: the CoreShell
Structure and Unique Properties for Ni(II) Sequestration.
Langmuir 22: 4638-4642., 2006. [En lnea]. Available:
http://www.ncbi.nlm.nih.gov/pubmed/16649775.
[10] E. Murgueitio, A. Debut y L. Cumbal, Synthesis of Iron
Nanoparticles through Extracts of Native Fruits of
Ecuador, as Capuli (Prunus serotina) and Mortio
(Vaccinium floribundum), 2016. [En lnea]. Available:
http://www.biolmedonline.com/Articles/Vol8_3_2016/B
M_Vol8_3_synthesis-of-iron-nanoparticles-usingextracts-of-native-fruits-of-ecuador-as-capuli-prunusserotina-and-mortio-vaccinium-floribun-0974-8.pdf.