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Syllabus for Bachelor of

Science
Under Choice Based Credit
System
Chemistry Core Course
(Honours)
2015

Department of Chemistry
College of Basic Science &
Humanities

Orissa University of Agriculture and


Technology

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Bhubaneswar - 751003

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Content
Year
First

Semeste Course Opted


r
I

Core Course - I
Core Course - I Practical
Core Course - II
Core Course - II Practical

II

Core Course - III


Core Course - III
Practical
Core Course - IV

Secon
d

III

Core Course - IV
Practical
Core Course - V
Core Course - V
Practical
Core Course - VI
Core Course - VI
Practical
Core Course - VII

IV

Core Course - VII


Practical
Skill Enhancement
Course I
Core Course - VIII
Core Course - VIII
Practical
Core Course - IX
Core Course - IX
Practical
Core Course - X

Third

Core Course - X
Practical
Skill Enhancement
Course II
Core Course - XI
Core Course - XI
Practical
Core Course - XII
Core Course - XII

Course
Code

Course Title

Page
No.

CHC(T)110
1
CHC(P)110
1
CHC(T)110
2
CHC(P)110
2
CHC(T)120
3
CHC(P)120
3
CHC(T)120
4
CHC(P)120
4
CHC(T)230
5
CHC(P)230
5
CHC(T)230
6
CHC(P)230
6
CHC(T)230
7
CHC(P)230
7
CHS2301

Physical Chemistry I

Physical Chemistry Lab


I
Inorganic Chemistry
I
Inorganic Chemistry
Lab I
Physical Chemistry II

5
6
7
10

Physical Chemistry Lab


II
Organic Chemistry I

11

Organic Chemistry Lab


I
Physical Chemistry III

13

Physical Chemistry Lab


III
Inorganic Chemistry
II
Inorganic Chemistry
Lab II
Organic Chemistry II

17

Organic Chemistry Lab


II
Pesticide Chemistry

21

CHC(T)240
8
CHC(P)240
8
CHC(T)240
9
CHC(P)240
9
CHC(T)241
0
CHC(P)241
0
CHS2402

Physical Chemistry IV

23

Physical Chemistry Lab


IV
Inorganic Chemistry
III
Inorganic Chemistry
Lab III
Organic Chemistry
III
Organic Chemistry Lab
III
Fuel Chemistry

24

CHC(T)351
1
CHC(P)351
1
CHC(T)351
2
CHC(P)351

Inorganic Chemistry
IV
Inorganic Chemistry
Lab IV
Organic Chemistry
IV
Organic Chemistry Lab

31

12

16

17
19
19

21

25
26
27
28
29

32
33
35

College of Basic Sciences & Humanities


Honours

VI

Practical
Discipline Specific
Elective Course I
Discipline Specific
Elective Course I
Practical
Discipline Specific
Elective Course II
Discipline Specific
Elective Course II
Practical
Core Course - XIII
Core Course - XIII
Practical
Core Course - XV
Core Course - XIV
Practical
Discipline Specific
Elective Course III
Discipline Specific
Elective Course III
Practical
Discipline Specific
Elective Course IV

Bachelor of Science Syllabus In Chemistry

2
CHD(T)350
1
CHD(P)350
1

IV
Polymer Chemistry

35

Polymer Chemistry Lab

37

CHD(T)350
2
CHD(P)350
2

Industrial Chemicals
and Environment
Industrial Chemicals
and Environment Lab

38

CHC(T)361
3
CHC(P)361
3
CHC(T)361
4
CHC(P)361
4
CHD(T)360
3
CHD(P)360
3

Physical Chemistry V

42

Physical Chemistry Lab


V
Organic Chemistry V

43

Organic Chemistry Lab


V
Analytical Methods in
Chemistry
Analytical Methods in
Chemistry Lab

45

CHD3604

Dissertation

50

39

44

46
48

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

First Year
Semester I
Course outline and Credit
structure
Course Opted
Core Course - I
Core Course - I
Practical
Core Course - II
Core Course - II
Practical
Total

Course
Code
CHC(T)11
01
CHC(P)11
01
CHC(T)11
02
CHC(P)11
02

Course Title
Physical Chemistry I
Physical Chemistry Lab
I
Inorganic Chemistry
I
Inorganic Chemistry
Lab I

Credit
s
4

Mark
s
75

25

75

25

12

200

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course I


Course Code: CHC(T)1101
Course Title: Physical Chemistry I
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
The Gaseous State (14 Periods)
Average kinetic energy of gas molecules. Principle of equipartition of
energy, specific heat of gases, Cp/ Cv ratio for monatomic gases. MaxwellBoltzmann distribution of molecular velocities ( qualitative treatment only),
nature of distribution curve and effect of temperature on distribution, root
mean square, most probable and average velocities, Relation between
them, Collision number, mean free path, collision diameter, Behaviour of
real gases and van der Waals equation of state, Critical phenomena and
critical constants, law of corresponding states, liquefaction of gases(based
on Joule-Thomson effect)

UNIT 2
Liquid State (8 Periods)
Structure of liquids ( qualitative description only) Structural difference
between solid, liquid and gas; Vapour Pressure, Surface tension, parachor
and its applications, viscosity; Liquid crystals, difference between liquid
crystal, solid and liquid; classification.
Colligative Properties (8 Periods)
Lowering in vapour pressure, Raoults law, Osmotic pressure and the
laws of osmotic pressure, lowering of freezing point and elevation of
boiling point of solution,thermodynamic derivations of colligative
properties determination of molecular weight by these methods,
anomalous molecular weight of solutes due to dissociation and
association. Isotonic solutions.

UNIT 3
Solid State (10 Periods)
The Study of crystal, types of crystal, space lattice, unit cell, crystal systems;
laws of crystallography, law of constant interfacial angle, law of rational
indices, law of symmetry, symmetry elements in crystal; Lattice planes and
dimension, X-ray diffraction by crystal, Braggs equation; crystal structure
of NaCl, KCl ionic solids ( AB type), lattice energy and its calculation.
Qualitative treatment of Band theory of solids, Point defects in solids
(Frenkel and Schottky defects).

UNIT 4
Chemical Kinetics (14 Periods)
Rate of a reaction, factors affecting rate of a reaction, order and
molecularity, Kinetics of Zero, 1st and 2nd order reaction, radioactive decay
as a 1st order reaction, pseudo first order, half life period, determination of
order of reaction- differential method, method of integration, fractional
6

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

change method and Ostwalds isolation method. Arrhenius equation,


concept of activation energy, qualitative treatment of collision theory
andtransition state theory, Expression for rate constant based on
equilibrium constant and thermodynamic aspects; Simple opposing
reaction of the type A B .

Books Recommended
1.
2.
3.
4.
5.
6.
7.

Principles of Physical Chemistry, Revised Edition, Puri, Sharma and


Pathania, Shobanlal Naginchand & Co.
Text Book of Physical Chemistry, S. Glasstone, McMillan
Modern College Chemistry, Physical, Achraya and Sharma,
Kalyani Publisher.
Physical Chemistry Bahl, Tuli & Soni, S.Chand & Co
Physical Chemistry, Atkins; Oxford University Press
Physical Chemistry through Problems, S. K. Dogra and S. Dogra,
Wiley Eastern Ltd.
Physical Chemistry, W.J. Moore; University Press (5th Edition)

Course Opted: Core Course I Practical


Course Code: CHC(P)1101
Course Title: Physical Chemistry Lab I
Credits: 2Full Mark: 25
General Experiments
15
1. Determination of rate constant for acid hydrolysis of ethyl acetate.
2. Determination of energy of activation of acid catalysed hydrolysis of
methyl acetate.
3. Comparison of strength of HCl and H 2SO4 by studying the kinetics of
hydrolysis of methyl acetate.
4. Determination of viscosity of aqueous solutions of polymer at room
temperature.
5. Determination of viscosity of ethanol at room temperature.
6. Determination of viscosity of sugar at room temperature.
7. Preparation of buffer solutions of different pH of sodium acetate-acetic
acid.
8. Preparation of buffer solutions of different pH of ammonium chlorideammonium hydroxide.
9. pH metric titration of strong acid vs. strong base.
10.
pH metric titration of weak acid vs. strong base.
Record
Viva

5
5

Books Recommended
1.
2.
3.
4.

Modern approach to practical chemistry, Y.R.Sharma,


A complete paper in Practical Chemistry, Acharya, Mohapatra,
Mishra and Sharma.
Practical Physical Chemistry, 8th Edition, B. D. Khosla, V. C. Garg
and A. Gulati.
Experiments in Physical Chemistry, 8th Ed.; C. W. Garland,; J. W.
Nibler and D. P. Shoemaker.
7

College of Basic Sciences & Humanities


Honours

5.

Bachelor of Science Syllabus In Chemistry

Experimental Physical Chemistry 3rd Ed, A. M. Halpern, and G. C.


McBane.

Course Opted: Core Course II


Course Code: CHC(T)1102
Course Title: Inorganic Chemistry I
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Atomic Structure (14 Periods)
Bohr's theory, its limitations and atomic spectrum of hydrogen atom.
Wave mechanics: de Broglie equation, Heisenberg's Uncertainty
Principle and its significance, Schrdinger's wave equation, significance
of & 2 . Quantum numbers and their significance. Normalized and
orthogonal wave functions. Sign of wave functions. Radial and angular
wave functions for hydrogen atom. Radial and angular distribution curves.
Shapes of s, p, d and f orbitals. Contour boundary and probability
diagrams. Pauli's Exclusion Principle, Hund's rule of maximum multiplicity,
Aufbau's principle and its limitations, Variation of orbital energy with
atomic number.

UNIT 2
Periodicity of Elements (14 Periods)
s , p, d, f block elements, the long form of periodic table. Detailed
discussion of the following properties of the elements, with reference to s
& p-block.
(a) Effective nuclear charge, shielding or screening effect, Slater rules,
variation of effective nuclear charge in periodic table.
(b) Atomic radii (van der Waals)
(c) Ionic and crystal radii.
(d) Covalent radii (octahedral and tetrahedral)
(e) Ionization enthalpy, Successive ionization enthalpies and factors
affecting ionization energy. Applications of ionization enthalpy.
(f) Electron gain enthalpy, trends of electron gain enthalpy.
(g) Electronegativity, Pauling's/ Mulliken's/ Allred Rachow's/ and
Mulliken-Jaff's electronegativity scales. Variation of electronegativity
with bond order / partial charge, hybridization, group electronegativity.
Sanderson's electron density ratio.

UNIT 3
Chemical Bonding (18 Periods)
(i) lonic bond: General characteristics, types of ions, size effects,
radius ratio rule and its limitations. Packing of ions in crystals. BornLand equation with derivation and importance of
Kapustinskii
expression for lattice energy. Madelung constant, Born-Haber cycle
and its application, Solvation energy.
(ii) Covalent bond: Lewis structure, Valence Bond theory (HeitlerLondon approach). Energetics of hybridization, equivalent and nonequivalent hybrid orbitals. Bent's rule, Resonance and resonance
8

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

energy, Molecular orbital theory. Molecular orbital diagrams of


diatomic and simple polyatomic molecules N 2, O 2, C 2, B 2, F 2, CO,
NO, and their ions; HCl, BeF 2, CO 2, (idea of s-p mixing and orbital
interaction to be given). Formal charge, Valence shell electron pair
repulsion theory (VSEPR), shapes of simple molecules and ions containing
lone pairs and bond pairs of electrons, multiple bonding (" and # bond
approach) and bond lengths.Covalent character in ionic compounds,
polarizing power and polarizability. Fajan's rules and consequences of
polarization. consequences of polarization. Ionic character in covalent
compounds: Bond moment and dipole moment. Percentage ionic
character from dipole moment and electronegativity difference.
(iii) Metallic Bond: Qualitative idea of valence bond and band theories.
Semiconductors and insulators, defects in solids.
(iv) Weak Chemical Forces: van der Waals forces, ion-dipole
forces, dipole-dipole interactions, induced
dipole
interactions,
Instantaneous dipole-induced dipole interactions. Repulsive forces,
Hydrogen bonding (theories of hydrogen bonding, valence bond
treatment) Effects of chemical force, melting and boiling points,
solubility energetic of dissolution process.

UNIT 4
Oxidation Reduction (6 Periods)
Redox equations, Standard Electrode Potential and use of redox potential
data. Its application to inorganic reactions. analysis of redox cycle, redox
stability in water Frost Latimer and Pourbaix diagrams. Principles
involved in the extraction of the metals.

Books Recommended
1.
2.
3.
4.
5.

Concise Inorganic Chemistry, J.D. Lee.


Concepts & Models of Inorganic Chemistry, B.E. Douglas, and
D.H.Mc Daniel.
Concepts & Models of Inorganic Chemistry, P.W. Atkins and J.
Paula. Physical Chemistry,
Theoretical Inorganic Chemistry, M.C. Day and J. Selbin.
Use of redox potential data analysis of redux cycle, redox
stability in water Frost Latimer and Pourbaix diagrams.
Principles involved in the extraction of the metals.

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course II Practical


Course Code: CHC(P)1102
Course Title: Inorganic Chemistry Lab I
Credits: 2Full Mark: 25
General Experiments
15
1. Preparation of solutions of different molarity/Normality of titrants
2. Determination of the amount of Na2CO3 and NaHCO3 present in
the given mixture.
3. Estimation of carbonate and hydroxide present in mixture.
4. Estimation of oxalic acid and sodium oxalate in a given mixture
5. Standardization of H2SO4 and estimation of ammonia in
ammonium chloride.
6. Estimation of calcium using standard KMnO4 solution.
7. Estimation of calcium in chalk by EDTA.
8. Standardization of thiosulphate solution using standard K 2Cr2O7
solution.
9. Estimation of copper iodometrically using standard thiosulphate
solution.
10.
Estimation of Fe+2 using standard K2Cr2O7 solution.
11.
Estimation of Fe(II) and oxalic acid using standardized
KMnO4 solution.
12.
Estimation of free alkali in different soap/ detergents
Record

Viva

Books Recommended
1. Vogels Text Book of Quantitative Inorganic Analysis, A. I. Vogel.
2. Vogels Text Book of Quantitative Organic Analysis, A. I. Vogel.
3. Practical Chemistry, Sharma and Acharya.

10

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

First Year
Semester II
Course outline and Credit
structure
Course Opted
Core Course - III
Core Course - III
Practical
Core Course - IV
Core Course - IV
Practical
Total

Course
Code
CHC(T)12
03
CHC(P)12
03
CHC(T)12
04
CHC(P)12
04

Course Title

Credit
s
4

Mark
s
75

Physical Chemistry Lab


II
Organic Chemistry I

25

75

Organic Chemistry Lab


I

25

12

200

Physical Chemistry II

11

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course III


Course Code: CHC(T)1203
Course Title: Physical Chemistry II
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Chemical Equilibrium (11 Periods) (3 Periods)
Thermodynamic derivation of the expression for the equilibrium constant;
Le- Chateliers principle; Application of law of mass action and LeChateliers principle to some simple gaseous reactions; Le-Chateliers
principle and physical equilibria; Equilibrium constant and free energy ;
vant Hoff Reaction isotherm; Effect of temperature on equilibrium,
vant Hoff equation and its integration.
Catalysis (3 Periods)
Characteristics of catalyzed reactions, types of catalysis, kinetics of
homogeneous catalysis: Acid-Base catalysis.

UNIT 2
Thermodynamics I (10 Periods)
Definition of thermodynamic terms; System, surrounding, extensive and
intensive properties, state and path functions and their differentials;
Thermodynamic processes, concept of heat, work, zeroth law of
thermodynamics; 1st law of thermodynamics; statement and scope, heat
content, internal energy and heat capacity; Isothermal and adiabatic
changes; Calculation of w, q, dU and dH in the expansion of ideal gas
under isothermal and adiabatic condition; Adiabatic relations; JouleThomson effect, Joule- Thomson coefficient for an ideal and real gas.
Thermochemistry (5 Periods)
Heat changes in chemical reactions, heat of formation, heat of
neutralization, laws of thermochemistry, Hesss law of constant heat
summation, bond energy, Kirchoffs equation.

UNIT 3
Thermodynamics II (12 Periods)
2nd law of thermodynamics; statement, scope, Carnot theorem, Carnot
cycle, efficiency of heat engine, thermodynamic scale of temperature,
concept of entropy, entropy change in reversible and irreversible
processes, entropy change in an ideal gas, variation of entropy with
temperature, pressure and volume, free energy and work function,
conditions of equilibrium, Gibbs- Helmholtz equation, Maxwells
relations, Clapeyron Clausius equation.

12

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

UNIT 4
Surface Chemistry (6 Periods)
Adsorption and its types, factors affecting adsorption, Freundlichs
adsorption isotherm, Langmuir adsorption isotherm, Gibbs adsorption
isotherm. Introduction to BET theory of multilayer adsorption (derivation
not required).
Colloidal State (5 Periods)
Definition of colloids, classification of colloids, Solids in liquids (sols)properties-kinetic, optical and electrical; stability of colloids, protective
action, Hardy-Schulze rule, gold number and its significance.

Books Recommended
1. Principles of Physical Chemistry, Revised Edition, Puri, Sharma and
Pathania.
2. Modern College Chemistry, Physical ,Achraya and Sharma
3. Thermodynamics by Glasstone.
4. Physical Chemistry, Atkins

Course Opted: Core Course III Practical


Course Code: CHC(P)1203
Course Title: Physical Chemistry Lab II
Credits: 2Full Mark: 25
General Experiments
15
1.
Study of the adsorption of acetic acid from aqueous solution by
animal charcoal.
2.
Study of the adsorption of oxalic acid from aqueous solution by
animal charcoal.
3.
Determination of critical solution temperature of phenol water
system.
4.
Determination of temperature dependance of solubility of benzoic
acid in water.
5.
Determination of heat capacity of a calorimeter.
6.
Determination of enthalpy of neutralisation of HCl with NaOH.
7.
Calculation of enthalpy of ionization of acetic acid.
8. pH metric titration of strong acid vs. weak base.
9.
pH metric titration of weak acid vs. weak base.
10. Determination of surface tension of a detergent by drop number
method.
Record
5
Viva
5

Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra, Mishra
and Sharma.
2. An advanced course of Practical Chemistry, Nad, Ghoshal&Mohapatra

13

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course IV


Course Code: CHC(T)1204
Course Title: Organic Chemistry I
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Basics of Organic Chemistry (14 Periods)
Classification, Nomenclature of acyclic compounds with multifunctional
groups, alicyclic, aromatic, spirocyclic, bicyclo and simple heterocyclic
compounds. Influence of hybridization on bond properties. Inductive,
electromeric, resonance and mesomeric effects, hyperconjugation and
their applications; Dipole moment; Organic acids and bases; their relative
strength.
Homolytic and Heterolytic fission with suitable examples. Curly arrow rules,
formal charges;Electrophiles and Nucleophiles; Nucleophlicity and basicity;
Types, shape and their relative stability of Carbocations, Carbanions, Free
radicals and Carbenes. Introduction to types of organic reactions and their
mechanism: Addition, Elimination and Substitution reactions.

UNIT 2
Stereochemistry (14 Periods)
Configurational analysis: Fischer Projection, Newmann and Sawhorse
Projection formulae and their interconversions; Geometrical isomerism:
cistrans and, syn-anti isomerism E/Z notations with C.I.P
rules.Geometrical isomerism in Oximes, Alicyclic, Dienes and Conjugated
dienes. Optical Isomerism: Optical Activity, Specific Rotation,
Chirality/Asymmetry, Enantiomers, Molecules with two or more chiralcentres, Distereoisomers,Threo and Erytro compounds meso compounds,
Racemic mixture and resolution. Relative and absolute configuration: D/L
and R/S designations.
Confirmational analysis: Conformation analysis of alkanes: Relative
stability: Energy diagrams of cyclohexane: Chair, Boat and Twist boat
forms; Relative stability with energy diagrams.

UNIT 3
Aliphatic HydrocarbonsI (Carbon-Carbon sigma bonds) (4 Periods)
Chemistry of alkanes: Formation of alkanes, Wurtz Reaction, Wurtz-Fittig
Reactions, Free radical substitutions: Halogenation -relative reactivity and
selectivity.
Chemistry of cycloalkanes: Types of cycloalkanes and their relative stability,
Baeyer strain theory
Aliphatic Hydrocarbons II (Carbon-Carbon pi bonds) (10 Periods)
Formation of alkenes and alkynes by elimination reactions, Mechanism of
E1, E2, E1cb reactions. Saytzeff and Hofmann eliminations. Electrophilic
additions their mechanisms in alkene; Markownikoff and Anti
Markownikoff addition, mechanism of oxymercuration-demercuration,
hydroborationoxidation, ozonolysis, catalytic and chemical reduction, syn
14

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

and anti-hydroxylation oxidation. 1,2-and 1,4-addition reactions in


conjugated dienes and, Diels-Alder reaction; Allylic and benzylic
bromination and mechanism, e.g. propene, 1-butene, toluene, ethyl
benzene. Acidity, Electrophilic and Nucleophilic additions. Hydration to
form in alkyne, carbonyl compounds, Alkylation of terminal alkynes.

UNIT 4
Aromatic Hydrocarbons (9 Periods)
Aromaticity, Hckels rule, aromatic character of arenes, cyclic
carbocations / carbanions and heterocyclic compounds with suitable
examples. Electrophilic aromatic substitution: halogenation, nitration,
sulphonation and Friedel-Crafts alkylation/acylation with their
mechanism. Directing effects of the groups.

Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.

Advanced Organic Chemistry, B.S. Bahl and Arun Bahl.


Organic Chemistry Vol- I.II& III, S.M.Mukherji, S.P. Singh and
R.P.Kapoor.
Organic Chemistry, P. Y. Bruice.
Organic Chemistry, R.K. Bansal.
Organic chemistry,Reaction and reagents, O.P Agarwal
Organic Chemistry; F.A Carey
Organic Chemistry; Wade
Organic reaction and their mechanism; P.S. Kalsi
Stereo Chemistry confirmations and Mechanism, P. S. Kalsi.
Stereo Chemistry of carbon compounds, D. NashiPuri
Text Book of Organic Chemistry, Morison & Boyd.
Text Book of Organic Chemistry, Vol I, I. L. Finar.

Course Opted: Core Course IV Practical


Course Code: CHC(P)1204
Course Title: Organic Chemistry Lab I
Credits: 2Full Mark: 25
Organic qualitative analysis

15

1. Basic laboratory Techniques in Organic chemistry


(a) Purification of organic compounds by crystallization using the
following solvents:
(i)
Water
(ii)
Alcohol
(iii)
Alcohol-Water
(b) Determination of the melting points of above compounds and
unknown organic compounds (electrically heated melting point
apparatus)
(c) Determination of boiling point of liquid compounds. (boiling
point lower than and more than 100 C by distillation method
2. Identification of Organic compounds containing C, H, O & C, H, N,
halogens and sulphur (Confirmation through the preparation of
derivative is included)
15

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Record
Viva

5
5

Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra,
Mishra and Sharma.
2. A Text Book of Practical Organic Chemistry (Qualitative); I. Vogel.
3. Modern approach to practical chemistry, Y.R.Sharma.
4. Hand book of Organic Analysis-Qualitative & Quantitative; H.
Clarke, Adward Arnold.

16

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Second Year
Semester III
Course outline and Credit
structure
Course Opted
Core Course - V
Core Course - V
Practical
Core Course - VI
Core Course - VI
Practical
Core Course - VII
Core Course - VII
Practical
Skill Enhancement

Course
Code
CHC(T)23
05
CHC(P)23
05
CHC(T)23
06
CHC(P)23
06
CHC(T)23
07
CHC(P)23
07
CHS2301

Course Title
Physical Chemistry III
Physical Chemistry Lab
III
Inorganic Chemistry
II
Inorganic Chemistry
Lab II
Organic Chemistry
II
Organic Chemistry Lab
II
Pesticide Chemistry
17

Credit
s
4

Mark
s
75

25

75

25

75

25

50

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course I
Total

20

350

Course Opted: Core Course V


Course Code: CHC(T)2305
Course Title: Physical Chemistry III
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Electrochemistry I (14 Periods)
Specific, equivalent and molar conductance ; Variation of specific and
equivalent conductance with dilution; Kohlrauschs law of independent
migration of ions; Applications of conductance measurementdetermination of degree of dissociation and dissociation constant of weak
monobasic acid; Solubility and solubility product of sparingly soluble salts,
degree of hydrolysis of salts, ionic product of water, conductometric
titration.

UNIT 2
Electrochemistry II (14 Periods)
Arrhenius theory of electrolytic dissociation; Ostwalds dilution law;
Strong and weak electrolytes; Interionic attraction theory; Onsagers
conductance equation and its validity (derivation not required); DebyeHuckel limiting law (derivation not required); Activity coefficient; Transport
number and its determination by Hittorf and Moving boundary method.

UNIT 3
Electrochemistry III (18 Periods)
Galvanic cell and cell reaction; Types of reversible electrodes and electrode
reaction; emf of reversible cells; Relation between cell emf, H, G, S
and expression for single electrode potential, Polarization and over voltage
(elementary idea); Reference electrodes; Standard oxidation potential,
electrochemical series; Concentration cells with and without transference;
Application of emf measurement- determination of transport number,
valency of ions, activity coefficient, solubility of sparingly soluble salts, heat
of reaction ; pH; Hydrogen, Quinhydrone and glass electrode; Dissociation
constant of weak monobasic acids; Ionic product of water, degree of
hydrolysis.
18

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

UNIT 4
Ionic equilibrium (10 Periods)
Acid and bases: theory of acids and bases, relative strengths, solvent and
substituent effect on strength; Dissociation constant of acids and bases.
pH.Salt hydrolysis, degree of hydrolysis. Buffer solutions, action, range,
capacity; Hendersons equation; Buffers in the body- buffer of tissue
fluids and carbonate-bicarbonate buffer. Theory of acid and base
indicators, range, choice of indicators; Neutralization curves, elementary
knowledge about other types of indicators.

19

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Books Recommended
1. Physical Chemistry, Atkins; Oxford University Press
2. A text book of Electro Chemistry, S. Glassstone.
3. The Elements of Physical Chemistry, P.W. Atkins.

Course Opted: Core Course V Practical


Course Code: CHC(P)2305
Course Title: Physical Chemistry Lab III
Credits: 2Full Mark: 25
General Experiments
15
1. Determination of solubility and solubility products of PbSO 4
conductometrically.
2. Determination of solubility and solubility products of BaSO 4
conductometrically.
3. Determination of the strength of strong acid by titration with a strong
base conductometrically.
4. Determination of the strength of strong acid by titration with a weak
base conductometrically.
5. Determination of the strength of weak acid by titration with a strong
base conductometrically.
6. Determination of the strength of a weak acid by titration with a weak
base conductometrically.
7. Potentiometric titration of strong acid vs. strong base.
8. Potentiometric titration of weak acid vs. strong base.
9. Potentiometric titration of Dibasic acid vs. strong base.
10. Potentiometric titration of Potassium dichromate vs. Mohr's salt.
Record
5
Viva
5

Books Recommended

1. A complete Course in Pratical Chemistry, Acharya, Mohapatra,


Mishra and Sharma.
2. An
advanced
course
of
Practical
Chemistry,
Nad,
Ghoshal&Mohapatra

Course Opted: Core Course VI


Course Code: CHC(T)2306
Course Title: Inorganic Chemistry II
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Chemistry of s and p Block Elements (14 Periods)
Inert pair effect, relative stability of different oxidation states, diagonal
relationship and behaviour of first member of each group. Allotropy and
catenation, Complex formation tendency of s and p block elements.
Hydrides and their classifications: ionic, covalent and interstitial, basic
beryllium acetate and nitrate. Study of compounds (Preparation,
properties, uses, structure and bonding): Boric acids and borates, boron
20

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

nitrides, borohydides (diborane), carboranes, graphitic compounds,


silanes, Oxides and oxoacids of nitrogen, phosphorous and chlorine.
Peroxo acids of sulphur, Interhalogen compounds, polyhalide ions,
pseudohalogens and basic properties of halogens.

UNIT 2
Non Aqueous Solvents (8 Periods)
The properties of non- aqueous solvent, classification of solvents; Liquid
NH3; solution of metal in liquid NH 3, Reaction in liquid NH3: metathetical
reaction, ammonation reaction, acid base reactions and ammonolysis.
Advantages and disadvantages of liquid ammonia as solvent. Liquid SO 2:
auto ionisation, solvolytic reaction, precipitation reaction and acid base
reaction.
General Principles of Metallurgy (6 Periods)
Use of redox potential data - analysis of redox cycle, redox stability in
water - Pourbaix diagrams, Principles involved in the extraction of
elements.General principles of metallurgy, occurrence of metals with
special emphasis on mineral wealth of India, calcination, roasting,
smelting, bessemerization, various methods of concentration, purification
and refining (such as parting process, zone refining, oxidation refining,
electrolytic refining and solvent extraction) metallurgy of important metals
like Ag, Au, Zn, Cu, Ni.

UNIT 3
Principles in qualitative analysis (14 Periods)
Theory of precipitation: ionic product, solubility product, co-precipitation,
post-precipitation, purification of precipitates.Chemistry of analysis of
various groups of basic and acidic radicals, chemistry of identification of
acid radicals in typical combinations.Chemistry of interferences of acid
radicals such as fluoride, borate, oxalate and phosphate and their removal
in the analysis of basic radicals.Choice of group reagents for analysis of
cations.

UNIT 4
Nuclear Chemistry (8 Periods)
Nature of radiation from radioactive substances, Composition of Nuclei,
structure of nucleus, forces operative within nucleus, nuclear stability and
mass energy equivalence (binding energy). Radioactive disintegration
series, kinetics of radioactive disintegration. Nuclear reactions: Types of
nuclear reactions, thermonuclear reactions including fusion and fission
reactions, radiation detection and measurement, semi-conductors
detectors. Artificial transmutation of elements, Radio-carbon dating,
synthetic elements. Activation analysis, isotopic dilution and radioactive
titration.

Books Recommended
1.
2.

Principle of Inorganic Chemistry, Puri, Sharma and Kalia,


ShobanLal & Nagin Chand & Co.
Text Book for Inorganic Chemistry, Satyaprakesh, Tuli
and
Madan; Sultan Chand & Co
21

College of Basic Sciences & Humanities


Honours

3.
4.
5.
6.
7.
8.
9.
10.

Bachelor of Science Syllabus In Chemistry

Modern College Chemistry, Inorganic, Guru, Mohapatra, Mishra


and Sharma, Kalayani Publisher.
Concise Inorganic Chemistry, J.D.Lee; Wiley India PVT. Ltd.
Comprehensive Inorganic Chemistry, Cotton & Willkinson; Wiley
India PVT Ltd
Basic Inorganic Chemistry, Cotton Willkinson; Wiley India PVT Ltd
Inorganic Chemistry, Huheey; Pearson Education
Chemistry of the Elements; N. N. Greenwood and A. Earnshow;
Pergamon
Selected Topics in Inorganic Chemistry, W. U. Malik, G. D. Tuli, R.
D. Madan; S Chand and Company Ltd.
Qualitative Inorganic Analysis; A. I. Vogel, John Wiley.

Course Opted: Core Course VI Practical


Course Code: CHC(P)2306
Course Title: Inorganic Chemistry Lab II
Credits: 2Full Mark: 25
Inorganic quanlitative analysis
15
Qualitative analysis of mixtures containing 3 anions and 3 cations.
CO32-, NO2-, S2-, S2O32-, CH3COO-, F-, Cl-, Br-, I-, NO3-, BO33-, C2O42-, PO43-,
NH4+, K+, Pb2+, Cu2+, Cd2+, Bi3+, Sn2+, Sb3+, Fe3+, Al3+, Cr3+, Zn2+, Mn2+, Co2+,
Ni2+, Ba2+, Sr2+, Ca2+, Mg2+
Mixtures should preferably contain one interfering anion or insoluble
componenet (BaSO4, SrSO4, PbSO4, CaF2 or Al2O3) or combination of
anions e.g. CO32- and SO32-, NO2- and NO3-, Cl- and Br-, Cl- and I-, Br- and I-,
NO3- and Br-, NO3- and I-.
Record
5
Viva
5

Books Recommended
1. Vogel, A.I. A text book of quantitative inorganic analysis, ELBS
1978.

Course Opted: Core Course VII


Course Code: CHC(T)2307
Course Title: Organic Chemistry II
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Halogen Compounds (11 Periods)
Methods of preparation, nucleophilic substitution reactions SN1, SN2
and SNi mechanisms with stereochemical aspects and effect of solvent
etc.; nucleophilic substitution vs. elimination. Preparation of aryl halides,
including preparation from diazonium salts. nucleophilic aromatic
substitution; SNAr, Benzyne mechanism. Relative reactivity of alkyl,
allyl/benzyl, vinyl and aryl halides towards nucleophilic substitution
22

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

reactions. Organometallic compounds of Mg and Li Use in synthesis of


organic compounds.

UNIT 2
Alcohols, Phenols, Ethers and Epoxides (12 Periods)
Alcohols: preparation, properties and relative reactivity of 1, 2, 3
alcohols, Bouvaelt-Blanc Reduction; Preparation and properties of glycols:
Oxidation by periodic acid and lead tetra acetate, Pinacol-Pinacolone
rearrangement; Phenols: Preparation and properties; Acidity and factors
effecting it, Ring substitution reactions, ReimerTiemann and
KolbesSchmidt Reactions, Fries and Claisen rearrangements with
mechanism; Ethers and Epoxides: Preparation and reactions with acids.
Reactions of epoxides with alcohols, ammonia derivatives, LiAlH4 Grignard
and Organolithium reagents.

UNIT 3
Carbonyl Compounds (14 Periods)
Structure, reactivity and preparation; Nucleophilic additions, Nucleophilic
addition-elimination reactions with ammonia derivatives with mechanism;
Mechanisms of Aldol and Benzoin condensation, Knoevenagel
condensation, Claisen-Schmidt, Perkin, Cannizzaro and Wittig reaction,
Beckmann and Benzil-Benzilic acid rearrangements, haloform reaction and
Baeyer Villiger oxidation, -substitution reactions, oxidations and
reductions: Clemmensen, Wolff-Kishner, LiAlH4, NaBH 4, MPV, PDC and
PGC; Addition reactions of unsaturated carbonyl compounds: Michael
addition. Active methylene compounds: Keto-enol tautomerism.
Preparation and synthetic applications
of diethyl malonate and ethyl acetoacetate

UNIT 4
Carboxylic Acids and their Derivatives (12 Periods)
Preparation, physical properties and reactions of monocarboxylic acids:
Typical reactions of dicarboxylic acids, hydroxy acids and unsaturated acids:
succinic/phthalic, lactic, malic, tartaric, citric, maleic and fumaric acids;
Preparation and reactions of acid chlorides, anhydrides, esters and amides;
Comparative study of nucleophilic sustitution at acyl group -Mechanism of
acidic and alkaline hydrolysis of esters, Claisen condensation, Dieckmann
and Reformatsky reactions, Hofmann bromamide degradation and Curtius
rearrangement.
Sulphur containing compounds (3 Periods)
Preparation and reactions of thiols, thioethers and sulphonic
acids.Mustard gas:Preparation from ethylene,Oxidation and chlorination of
mustard gas.

Books Recommended
1.
2.
3.
4.
5.
6.

Advance Organic Chemistry, B.S. Bahl and Arun Bahl.


Organic Chemistry Vol- I.II& III, S.M.Mukherji, S.P. Singh and
R.P.Kapoor.
Organic Chemistry, P. Y. Bruice.
Organic Chemistry, R.K. Bansal.
Organic chemistry,Reaction and reagents, O.P Agarwal
Organic Chemistry; F.A Carey
23

College of Basic Sciences & Humanities


Honours

7.
8.
9.

Bachelor of Science Syllabus In Chemistry

Organic Chemistry; Wade


Text Book of Organic Chemistry, Morison & Boyd.
Text Book of Organic Chemistry, Vol I, I. L. Finar.

24

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course VII Practical


Course Code: CHC(P)2307
Course Title: Organic Chemistry Lab II
Credits: 2Full Mark: 25
Organic Preparations

15

1.
2.
3.
4.
5.
6.
7.

Picric Acid
Nitrobenzene
Ethyl Benzoate
Aspirin
Methyl orange
Acetylation of one of aniline/ p-toluidine by conventional method
Benzolyation one of aniline/ p- toluidine by Schotten-Baumann
reaction
8. Hydrolysis of amides and esters.
The solid samples must be collected and may be used for recrystallization,
melting point and TLC.
Record
5
Viva
5

Books Recommended
1. Small Scale Organic preparations; P. J. Hill
2. Organic Synthesis, Vol. III; Clarke.

Course Opted: Skill Enhancement Course I


Course Code: CHS2301
Course Title: Pesticide Chemistry
Credits: 2Full Mark: 50 (External: 40 and Internal: 10)
(Each unit carries equal mark)
UNIT 1
Basic Concept (3 Periods)
General introduction to pesticides (natural and synthetic), benefits and
adverse effects; Changing concepts of pesticides, structure activity
relationship.

UNIT 2

Synthesis and Uses I (4 Periods)


Synthesis and technical manufacture and uses of representative pesticides
in
the following
class:
Organochlorines: DDT,
Gammexene;
Organophosphates: Malathion, Parathion.

UNIT 3

Synthesis and Uses II (5 Periods)


Synthesis and technical manufacture and usages of representative
pesticides in the following class: Carbamates: Carbofuran and Carbaryl;
Quinones: Chloranil; Anilides: Alachlor and Butachlor.

Book Recommended

1. R. Cremlyn: Pesticides, John Wiley


25

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Second Year
Semester IV
Course outline and Credit
structure
Course Opted
Core Course - VIII
Core Course - VIII
Practical
Core Course - IX
Core Course - IX
Practical
Core Course - X
Core Course - X
Practical
Skill Enhancement
Course II
Total

Course
Code
CHC(T)24
08
CHC(P)24
08
CHC(T)24
09
CHC(P)24
09
CHC(T)24
10
CHC(P)24
10
CHS2402

Course Title

Credi
ts
4

Mark
s
75

Physical Chemistry Lab


IV
Inorganic Chemistry
III
Inorganic Chemistry
Lab III
Organic Chemistry III

25

75

25

75

Organic Chemistry Lab


III
Fuel Chemistry

25

50

20

350

Physical Chemistry IV

26

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course VIII


Course Code: CHC(T)2408
Course Title: Physical Chemistry IV
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Phase Equilibrium (3 Periods) (8 Periods)
Terms-phase, component, degree of freedom, Gibbs phase rule and its
derivation, one component system; water system, sulphur system and CO 2
system. Two component system, Solid- liquid equilibria, simple eutectic
PbAg system, Freezing mixture, CuSO4.5H2O system.
Distribution law (4 Periods)
Distribution law-thermodynamic derivation, applications:
associate ion and solvent extraction association.

degree

of

UNIT 2
Photochemistry (12 Periods)
Difference between thermal and photochemical reaction; Laws of
photochemistry; Grotthus Draper law; Stark- Einstein law; Beer
Lamberts law; Quantum yield and its determination-actinometry,
mechanism and kinetics of decomposition of HI; Photochemical
combination of hydrogen and bromine & hydrogen and chlorine reactions;
Jablonski diagram; Radiative and non-radiative processes; Fluorescence,
phosphorescence,
resonance
fluorescence,
chemiluminescence,
bioluminescence,
photosensitization and photosynthesis (elementary
idea).

UNIT 3
Elementary Quantum Mechanics (14 Periods)
Black body radiation, Plancks radiation law, photoelectric effect, heat
capacity of solids, Bohrs model of hydrogen atom (derivation not
required) and its limitations, Compton effect , de-Broglie equation,
Heisenbergs uncertainty principle, Hamiltonian operator, Schrodinger
wave equation and its derivation, physical interpretation of the wave
function, Postulates of quantum mechanics (Problems based on algebra of
operators excluded), Schrodinger wave equation for H-atom, separation
into three equations (derivation not required), quantum numbers and their
importance, Hydrogen like wave functions, elementary idea on radial and
angular wave functions (derivation not required).

UNIT 4
Molecular Spectroscopy (10 Periods)
Scope; Molecular spectra; Born- Oppenheimer approximation ; Brief idea
about various types of molecular spectra; Rotational( Micro wave) spectra
of diatomic molecules, energy levels of a rigid rotator, selection rules ,
spectral intensities, vibrational spectra (IR) of diatomic molecules, energy
levels of a simple harmonic oscillator; Anharmonicity; Electronic spectra of
diatomic molecules; FranckCondon principle.
27

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Books Recommended
1.
2.
3.
4.

Introduction to Quantum Chemistry, A.K.Chandra.


Quantum Chemistry, Ira N. Levine
Fundamental of Molecular Spectroscopy, Colin N. Banwell.
Fundamentals of Photochemistry, K.K.Rohtagi and S.M.Mukherji.

Course Opted: Core Course VIII Practical


Course Code: CHC(P)2408
Course Title: Physical Chemistry Lab IV
Credits: 2Full Mark: 25
General Experiments
15
1. Study the 200-500 nm absorbance spectra of KMnO 4 and determine
the max value.
2. Study the 200-500 nm absorbance spectra of K 2Cr2O7 (in 0.1 M
H2SO4) and determine the max value.
3. Verify Lambert-Beers law and determine the concentration of CuSO 4
of unknown concentration.
4. Verify Lambert-Beers law and determine the concentration of KMnO4
of unknown concentration.
5. Verify Lambert-Beers law and determine the concentration of K 2Cr2O7
in a solution of unknown concentration.
6. Study of distribution equilibrium of acetic acid between water and
cyclohexane at room temperature.
7. Study of distribution equilibrium of benzoic acid between water and
cyclohexane at room temperature.
8. Calibration of spectrophotometer by KMnO4 solution and
determination of unknown concentration of KMnO 4.
9. Calibration of spectrophotometer by K 2Cr2O7 solution and
determination of unknown concentration of K2Cr2O7.
10. Determination of energy of activation of acid catalyzed hydrolysis of
methyl acetate.
Record
5
Viva
5

Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra, Mishra
and Sharma.
2. An advanced course of Practical Chemistry, Nad, Ghoshal&Mohapatra

28

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course IX


Course Code: CHC(T)2409
Course Title: Inorganic Chemistry III
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Noble gases (12 Periods)
Occurrence and uses, rationalization of inertness of noble gases,
clathrates, preparation and properties of XeF 2, XeF4 and XeF6, Oxides and
oxofluorides of Xenon (XeO 4, XeO3, XeOF4, XeO2F4, XeO3F3, XeO2F2,
XeOF2). Nature of bonding in noble gas compounds (Valence bond
treatment and molecular orbital treatment for XeF 2). Molecular shapes of
noble gas compounds (in light of VSEPR Theory).

UNIT 2
Chemistry of Transition elements (12 Periods)
General group trends with special reference to electronic configuration,
colour, variable valency, magnetic and catalytic properties, and ability to
form complexes. Stability of various oxidation states and e. m. f.
Comparison of properties between first, second and thirdrow transition
series.
Chemistry of Ti, V, Cr, Mn and Co in various oxidation states (excluding
metallurgy).

UNIT 3
Coordination Chemistry (14 Periods)
Werners theory, experimental verification of Werners theory,
coordination number, IUPAC nomenclature, factors influencing the
formation of complexes, valence bond interpretation of common
octahedral, tetrahedral and square planar complexes; electricalneutrality
principle and back bonding. Limitationsof VBT, Crystal field theory,
splitting of d-orbitals in octahedral and tetrahedral fields. CFSE in weak
and strong fields.Ligand field theory.
Isomerism in coordination compounds, stereochemistry of complexes with
4 and 6 coordination umbers, chelate effect, polynuclear complexes.
Elementary idea about labile and inert complexes.

UNIT 4
Chemistry of Inner Transition Elements (10 Periods)
Lanthanides: electronic configuration, oxidation states and ionic radii and
lanthanide contraction, complex formation, occurrence and separation of
lanthanides (ion-exchange method only).
Actinides: electronic configuration and oxidation states, separation of Np,
Pu and Am from U, comparison between properties of actinides and
lanthanides.

Books Recommended
29

College of Basic Sciences & Humanities


Honours

1.
2.
3.
4.
5.
6.
7.
8.
9.

Bachelor of Science Syllabus In Chemistry

Principle of Inorganic Chemistry, Puri, Sharama and Kalia,


ShobanLal&Nagin Chand & Co.
Text Book for Inorganic Chemistry, Satyaprakesh, Tuli
and
Madan; Sultan Chand & Co
Modern College Chemistry, Inorganic, Guru, Mohapatra, Mishra
and Sharma, Kalayani Publisher.
Concise Inorganic Chemistry, J.D.Lee; Wiley India PVT. Ltd.
Comprehensive inorganic Chemistry, Cotton &Willkinson; Wiley
India PVT Ltd
Basic Inorganic Chemistry, Cotton Willkinson; Wiley India PVT Ltd
Inorganic Chemistry, Huheey; Pearson Education
Chemistry of the Elements; N. N. Greenwood and A. Earnshow;
Pergamon
Selected Topics in Inorganic Chemistry, Mallick, Madan, Tuli, S
Chand Publications

Course Opted: Core Course IX Practical


Course Code: CHC(P)2409
Course Title: Inorganic Chemistry Lab III
Credits: 2Full Mark: 25
Inorganic quantitative analysis
15
1. Estimation of arsenite in tartar emetic iodimetrically
2. Estimation of antimony in tartar emetic iodimetrically
3. Estimation of available chlorine in bleaching powder iodimetrically.
4. Estimation of copper iodometrically using standard thiosulphate
solution.
5. Estimation of MnO2 in pyrolusite
6. Estimation of barium as barium sulphate gravimetrically.
7. Estimation of Ni(II) using dimethylglyoxime gravimetrically
8. Estimation of iron as Fe2O3 by precipitating iron as Fe(OH)3
gravimetrically.
9. Estimation of copper as CuSCN gravimetrically.
10.
Estimation of Al(III) by precipitating with oxine and weighing
as Al(oxine)3 gravimetrically
Record
5
Viva
5

Books Recommended
1. Vogel, A.I. A text book of quantitative analysis, ELBS 1986.

30

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course X


Course Code: CHC(T)2410
Course Title: Organic Chemistry III
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Nitrogen Containing Functional Groups (10 Periods)
Preparation and important reactions of nitro and compounds, nitriles and
isonitriles; Amines: Effect of substituent and solvent on basicity;
Preparation and properties: Gabriel phthalimide synthesis, Carbylamine
reaction, Mannich reaction, Hoffmanns exhaustive methylation,
Hofmann-elimination reaction; Distinction between 1, 2 and 3amines
with Hinsberg reagent and nitrous acid. Diazonium Salts: Preparation and
their synthetic applications.

UNIT 2
Heterocyclic Compounds (14 Periods)
Classification and nomenclature, Structure, aromaticity in 5-numbered and
6-membered rings containing one heteroatom; Synthesis, reactions and
mechanism of substitution reactions of Furan, Pyrrole Paal-Knorr
synthesis, Knorr pyrrole synthesis, Hantzsch synthesis, Thiophene, Pyridine
Hantzsch synthesis), Pyrimidine, Structure elucidation of indole, Fischer
indole synthesis and Madelung synthesis), Structure elucidation of
quinoline and isoquinoline, Skraup synthesis, Friedlanders synthesis,
Knorr quinoline synthesis, DoebnerMiller synthesis, Bischler-Napieralski reaction, Pictet-Spengler reaction,
Pomeranz-Fritsch reaction; Derivatives of furan: Furfural and furoic acid.

UNIT 3
Alkaloids (10 Periods)
Natural occurrence, General structural features, Isolation and their
physiological action, Hoffmanns exhaustive methylation, Emdes
modification, Structure elucidation and synthesis of Hygrine and Nicotine.
Medicinal importance of Nicotine, Hygrine, Quinine, Morphine, Cocaine,
and Reserpine.
Terpenes (3 Periods)
Occurrence, classification, isoprene rule; Elucidation of stucture and
synthesis of Citral, Neral and -terpineol.

UNIT 4
Polynuclear Hydrocarbons (7 Periods)
Reactions of naphthalene phenanthrene and anthracene Structure,
Preparation and structure elucidation and important derivatives of
naphthalene and anthracene; Polynuclear hydrocarbons.
Phase Transfer Catalyst (6 Periods)
31

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Principle and advantages, application in organic synthesis: Nucleophillic


substitution reaction, Elimination reaction, C-alkylation at -carbon. Crown
Ether Complexes: Charateristics and nomenclature, synthesis of [12]
crown 4, synthetic application of crown ether in Aliphatic. Cryptands

Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.

Advance Organic Chemistry, B.S. Bahl and Arun Bahl.


Chemistry of Natural products; O.P Agarwal
Heterocyclic chemistry; Gupta,Kumar,Gupta
Heterocyclic chemistry;T.L Gilchrist
Organic Chemistry Vol- I.II& III, S.M.Mukherji, S.P. Singh and
R.P.Kapoor.
Organic Chemistry, R.K. Bansal.
Text Book of Organic Chemistry, Morison & Boyd.
Text Book of Organic Chemistry, Vol I, I. L. Finar.

Course Opted: Core Course X Practical


Course Code: CHC(P)2410
Course Title: Organic Chemistry Lab III
Credits: 2Full Mark: 25

Chromatography
1. Separation of a mixture of two amino acids by ascending and
horizontal paper chromatography
2. Separation of a mixture of two sugars by ascending paper
chromatography
3. Separation of a mixture of o-and p-nitrophenol or o-and paminophenol by thin layer chromatography (TLC)
Isolation of natural products
1. Isolation of caffeine from tea leaves.
2. Isolation of casein from milk.
3. Isolation of lactose from milk.
Record
Viva

5
5

Books Recommended
1. A complete Course in Pratical Chemistry, Acharya, Mohapatra,
Mishra and Sharma.
2. Hand book of Organic Analysis-Qualitative & Quantitative; H.
Clarke, Adward Arnold.
3. Vogels Text Book of Quantitative Chemical Analysis;
J.Mendham, R. C Denney, J. D. Barnes, M. J. K. Thomas; Pearson
Education Publishers, 6th Edition.
4. Vogels Text Book of Quantitative Organic Analysis, A. I. Vogel.

32

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Skill Enhancement Course II


Course Code: CHS2402
Course Title: Fuel Chemistry
Credits: 2Full Mark: 50 (External: 40 and Internal: 10)
(Each unit carries equal mark)
UNIT 1
Basic Concept (4 Periods)
Review of energy sources (renewable and non-renewable). Classification
of fuels and their calorific value. Lubricants: Classification of lubricants,
lubricating oils(conducting and non-conducting)Solid and semisolid
lubricants, synthetic lubricants.

UNIT 2
Solid Fuel Coal (6 Periods)
Uses of coal (fuel and nonfuel) in various industries, its composition,
carbonization of coal. Coal gas, producer gas and water gas- composition
and uses. Fractionation of coal tar, uses of coal tar bases chemicals,
requisites of a good metallurgical coke, Coal gasification (Hydro
gasification and Catalytic gasification), Coal liquefaction and Solvent
Refining.

UNIT 3
Liquid Fuel Petroleum (8 Periods)
Composition of crude petroleum, Refining and different types of
petroleum products and their applications. Fractional Distillation
Principle and process, Thermal and catalytic cracking, Reforming
Petroleum and non-petroleum fuels: LPG, CNG, LNG, Bio-gas, fuels
derived from biomass, fuel from waste, synthetic gaseous and liquids fuels,
clean fuels. Petrochemicals: Vinyl acetate, Propylene oxide, Isoprene,
Butadiene, Toluene and its derivatives Xylene.

Books Recommended
1. E. Stocchi: Industrial Chemistry, Vol-I,Ellis Horwood Ltd.UK
2. P.C. Jain, M.Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi.
3. B.K.Sharma: Industrial Chemistry, Goel Publishing House, Meerut.

33

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Third Year
Semester V
Course outline and Credit
structure
Course Opted
Core Course - XI
Core Course - XI
Practical
Core Course - XII
Core Course - XII
Practical
Discipline Specific
Elective Course I
Discipline Specific
Elective Course I
Practical
Discipline Specific
Elective Course II
Discipline Specific
Elective Course II
Practical
Total

Course
Code
CHC(T)35
11
CHC(P)35
11
CHC(T)35
12
CHC(P)35
12
CHD(T)35
01
CHD(P)35
01

Course Title

CHD(T)35
02
CHD(P)35
02

Inorganic Chemistry
IV
Inorganic Chemistry
Lab IV
Organic Chemistry IV

Credi Mark
ts
s
4
75
2

25

75

Organic Chemistry Lab


IV
Polymer Chemistry

25

75

Polymer Chemistry Lab

25

Industrial Chemicals and


Environment
Industrial Chemicals and
Environment Lab

75

25

24

400

34

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course XI


Course Code: CHC(T)3511
Course Title: Inorganic Chemistry IV
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Acids and Bases (8 Periods)
Bronsted-Lowry Concept of acid-base relations, solvated proton, relative
strength of acids, type of acid-base reactions, levelling solvents, Lewis acidbase concept, classificationofLewis acids, Hard and Soft Acids and Bases,
application of HSAB principle.
Inorganic polymers (6 Periods)
Types of inorganic polymers, comparison with organic polymers, synthesis,
structural aspects and applications of silicones and siloxanes.Borazines,
silicates, phophazenes and polysulphtes.

UNIT 2
Organometallic Chemistry (14 Periods)
Definition and classification of organometallic compounds on the basis of
bond type, concept of hapticity of organic ligands. Metal carbonyls: 18
electron rule, electron count of mononuclear, polynuclear and substituted
metal carbonyls of 3d series. General methods of preparation (direct
combination, reductive carbonylation, thermal and photochemical
decomposition) of mono and dinuclear carbonyls of 3d series. Structures
of mononuclear and binuclear carbonyls of Cr, Mn, Fe, Co and Ni using
VBT.Pi-acceptor behaviour of CO (in light of MO of CO), back bonding of
metal-CO. Elementary idea of metal alkyls and ferrocene.

UNIT 3
Catalysis (4 Periods)
Catalysis
by
organometallic
compounds:
Wilkinsons
hydroformyltion, Wacker process and Fischer Tropsch reaction.

catalyst,

Bioinorganic Chemistry (8 Periods)


Metal ions present in biological system, sodium and potassium pump,
carbonic anhydrase and carboxypeptidase, iron and its application in biosystems, haemoglobin: storage and transfer of iron.
Excess and deficiency of some trace metals, toxicity of metal ions (Hg, Pb,
Cd, and As) and reasons.

UNIT 4
Group Theory (8 Periods)
Basic idea about group and classes, symmetry elements, symmetry
operations present in a molecule, point groups.

35

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.

Principle of Inorganic Chemistry, Puri, Sharama and Kalia,


ShobanLal&Nagin Chand & Co.
Text Book for Inorganic Chemistry, Satyaprakesh, Tuli
and
Madan; Sultan Chand & Co
Modern College Chemistry, Inorganic, Guru, Mohapatra, Mishra
and Sharma, Kalayani Publisher.
Concise Inorganic Chemistry, J.D.Lee; Wiley India PVT. Ltd.
Comprehensive inorganic Chemistry, Cotton & Willkinson; Wiley
India PVT Ltd
Basic Inorganic Chemistry, Cotton Willkinson; Wiley India PVT Ltd
Inorganic Chemistry, Huheey; Pearson Education
Chemistry of the Elements; N. N. Greenwood and A. Earnshow;
Pergamon
Selected Topics in Inorganic Chemistry, Mallick, Madan, Tuli, S
Chand Publications
Application of Group Theory; F A Cotton
Symmetry and Spectroscopy of Molecules, K Verra Reddy; New
Age Publishers
Bioinorganic chemistry by Bartini
Environmental chemistry, A. K. Dey; New Age Publication

Course Opted: Core Course XI Practical


Course Code: CHC(P)3511
Course Title: Inorganic Chemistry Lab IV
Credits: 2Full Mark: 25
Preparations
15
1. Preparation of Cuprous Chloride, Cu2Cl2.
2. Preparation of Manganese (III) Phosphate, MnPO4. H2O.
3. Preparation of Aluminium potassium sulphate KAl(SO4)2.12H2O
(Potash alum)
4. Preparation of acetylacetanato complexes of Cu2+ and
determination of max.
5. Preparation of ammine complexes of Ni(II) and its ligand exchange
reactions by substitution method.
6. Preparation of Tetramminecopper (II) sulphate, [Cu(NH3)4]SO4.H2O
7. Preparation of Cis and trans K[Cr(C2O4)2.(H2O)2] Potassium
dioxalatodiaquachromate(III).
8. Preparation of Potassium tris(oxalate)ferrate(III)
9. Preparation of sodium tetrathionate.
10.
Preparation of Al(oxine)3
Record
Viva

5
5

Books Recommended
1. Vogel, A.I. A text book of quantitative inorganic analysis, ELBS
1978.
36

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

2. Practical Chemistry, Sharma and Acharya.

Course Opted: Core Course XII


Course Code: CHC(T)3512
Course Title: Organic Chemistry IV
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Nucleic Acids (4 Periods)
Components of nucleic acids, Nucleosides and nucleotides; Structure,
synthesis and reactions of: Adenine, Guanine, Cytosine, Uracil and
Thymine;
Amino Acids, Peptides and Proteins (4 Periods)
Amino acids, Peptides and their classification. -Amino Acids - Synthesis,
ionic properties and reactions. Zwitterions, pKa values, isoelectric point .
Lipids (2 Periods)
Introduction to oils and fats; common fatty acids present in oils and fats,
Hydrogenntion of
fats and oils, Saponification value, acid value, iodine number..
Pharmaceutical Compounds: Structure and Importance (4 Periods)
Classification, structure, synthesis and therapeutic uses of antipyretics:
Paracetamol; Analgesics: Ibuprofen; Antimalarials: Chloroquine. An
elementary treatment of Antibiotics and detailed study of
chloramphenicol.

UNIT 2
Pericyclic Reactions (10 Periods)
Classification of pericylic reactions, Woodward- Hoffmann correlation
diagram.FMO treatment. Electrocyclic reactions:Conrotatory and
disrotarory reactions. 4n, 4n+2 and allyl system. Cycloadditions
antaraficial and suprafacial addition. 4n, 4n+2 system, 1,3 dipolar
cycloaddition and cheleotropic reactions.
Photochemistry (6 Periods)
Principles of organic photochemistry,Photochemical reactions of carbonyl
compounds (Norrish type-I and II reaction,Paterno-buchi reaction),di methane rearrangement.

UNIT 3
Name Reactions (12 Periods)
Principle, mechanism and applications: Michael condensation,
Reformatsky reaction, Benzidine rearrangement, Wagner-Meerwien
rearrangement. Houben-Hoesch reaction, Vilsmeier-Haack reaction,
Lossen rearrangement, Sharpless epoxidation,Demjanov rearrangement
and Favorskii rearrangement.
Synthetic Reagents (4 Periods)
37

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Synthesis and application: Aluminium t-butoxides, DCC, OsO 4, HlO4,


diazomethane, PCC, diborane, selenium dioxide.

UNIT 4
Protection and deprotection techniques in organic synthesis (4 Periods)
Protection and deprotection of carbonyl groups, Amino groups and
double bonds
Oxidation and Reduction methods (10 Periods)
Oxidations with Chromium(VI),Manganese(VII) ,Peroxides and Peracids,
Ozone , DMSO, NBS and DDQ
Reductions: Catalytic hydrogenation, hydrides transfer reaction, Dissolving
metal reduction.

Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.

Advance Organic Chemistry, B.S. Bahl and Arun Bahl.


Chemistry of Natural products; O.P Agarwal
Frontier orbitals and symmetry controlled reaction;R.K.Kar
Organic chemistry,Reaction and reagents, O.P Agarwal
Organic Chemistry; F.A Carey
Organic Chemistry; Wade
Organic photochemistry;Gurdeep,Chatwal
Organic reaction and their mechanism; P.S. Kalsi
Pericyclic reaction and photochemistry;A.M.Arora
Pericyclic reaction;S.M.Mukherjee
Synthetic approaches in organic synthesis;R.K.Bansal
Text Book of Organic Chemistry, Morison & Boyd.
Text Book of Organic Chemistry, Vol I, I. L. Finar.

38

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course XII Practical


Course Code: CHC(P)3512
Course Title: Organic Chemistry Lab IV
Credits: 2Full Mark: 25
One step Organic Synthesis
1. Benzene Benzophenone
2. Benzophenone Benzpinacol
3. Benzpinacol Benzpinacolone
4. Benzophenone Benzophenoneoxime
5. Benzophenoneoxime Benzanilide
6. Benzoin Benzil
7. Benzil Benzilic acid
8. Nitrobenzene m-dinitrobenzene
9. m-dinitrobenzene m-nitroaniline
10. Phthalicacid phthalic anhydride
11. phthalic anhydride phthalimide
12. phthalimide Anthranilic acid
Record
Viva

15

5
5

Books Recommended
1. Macroscale and Microscale Organic Experiments;
Williamson, D. C. Heath.
2. Small Scale Organic preparations; P. J. Hill

K.

I.

Course Opted: Discipline Specific Elective Course I


Course Code: CHD(T)3501
Course Title: Polymer Chemistry
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Introduction and history of polymeric materials (5 Periods)
Different schemes of classification of polymers, Polymer nomenclature,
Molecular forces and chemical bonding in polymers, Texture of Polymers.
Functionality and its importance (7 Periods)
Criteria for synthetic polymer formation, classification of polymerization
processes, Relationaships between functionality, extent of reaction and
degree of polymerization. Bi-functional systems, Poly-functional systems.

UNIT 2
Kinetics of Polymerization (8 Periods)
Mechanism and kinetics of step growth, radical chain growth, ionic chain
(both cationic and anionic) and coordination polymerizations, Mechanism
and kinetics of copolymerization, polymerization techniques.
39

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Crystallization and crystallinity (4 Periods)


Determination of crystalline melting point and degree of crystallinity,
Morphology of crystalline polymers, Factors affecting crystalline melting
point.

UNIT 3
Nature and structure of polymers (12 Periods)
Structure Property relationships; Determination of molecular weight of
polymers (Mn, Mm, etc.) by end group analysis viscometry, light scattering
and osmotic pressure methods. Molecular weight distribution and its
significance; Polydispersity index; Glass transition temperature (Tg)and
determination of Tg, Free volume theory, WLF equation, Factors affecting
glass transition temperature(Tg).

UNIT 4
Properties of Polymers (12 Periods)
Brief introduction to preparation, structure, properties and application of
the following polymers: polyolefins, polystyrene and styrene copolymers,
poly vinyl chloride and related polymers, poly vinyl acetate and related
polymers, acrylic polymers, fluoro polymers, polyamides and related
polymers. Phenol formaldehyde resins Bakelite, Novalac, polyurethanes,
silicone polymers, polydienes. Polycarbonates, Conducting Polymers
polyacetylene, polyaniline, poly para phenylene sulphide, polypyrrole,
polythiophene.

Books Recommended
1. Malcohm P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed.
2. Harry R. Allcock, Frederick W. Lampe and James E. Mark,
Contemporary Polymer Chemistry, 3rd ed. Prentice_Hall (2003)
3. Feed W. Billmeyer, Textbook of Polymer Science, 3rd ed. WileyInterscience (1984)
4. Joel R. Fried, Polymer Science and Technology, 2nd ed. Prentice-Hall
(2003)
5. Petr Munk and Tejraj M. Aminabhavi, Introduction to
Macromolecular Science, 2nd ed, ;John Wiley & Sons (2002)
6. L.H. Sperling, Introduction to Physical Polymer Science, 4th ;ed. John
Wiley & Sons (2005)
7. Malcolm P. Stevens, Polymer Chemistry: An Introduction, 3rd ed.
Oxford Univesity Press(2005)
8. Seymour/ ;Carrahers Polymer Chemistry, 9th ed. By Charles E.
Carraher, Jr. (2013)

40

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Discipline Specific Elective Course I


Practical
Course Code: CHD(P)3501
Course Title: Polymer Chemistry Lab
Credits: 2Full Mark: 25
General Experiments
15
1. Synthesis of Methyl Methacrylate
2. Preparation of nylon 6,6.
3. Redox polymerization of acrylamide
4. Precipitation polymerization of acrylonitrile.
5. Preparation of urea-formaldehyde resin
6. Estimation of the amount of HCHO in the given solution by sodium
sulphite method
7. Testing of mechanical properties of polymers.
8. Determination of molecular weight by end group analysis:
Polyethylene glycol (PEF) (OH group).
9. Determination of hydroxyl number of a polymer using colorimetric
method.
10.
Determination of molecular weight by viscometry of
polyacrylamide- aq. Sodium nitrite solution.
11.
FTIR analysis of polymers.
Record
5
Viva
5

Books Recommended
1. Malcohm P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed.
2. Harry R. Allcock, Frederick W. Lampe and James E. Mark,
Contemporary Polymer Chemistry, 3rd ed. Prentice_Hall (2003)
3. Feed W. Billmeyer, Textbook of Polymer Science, 3rd ed. WileyInterscience (1984)
4. Joel R. Fried, Polymer Science and Technology, 2nd ed. PrenticeHall (2003)
5. Petr Munk and Tejraj M. Aminabhavi, Introduction to
Macromolecular Science, 2nd ed, ;John Wiley & Sons (2002)
6. L.H. Sperling, Introduction to Physical Polymer Science, 4th ;ed.
John Wiley & Sons (2005)
7. Malcolm P. Stevens, Polymer Chemistry: An Introduction, 3rd ed.
Oxford Univesity Press(2005)
8. Seymour/ ;Carrahers Polymer Chemistry, 9th ed. By Charles E.
Carraher, Jr. (2013)

41

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Discipline Specific Elective Course II


Course Code: CHD(T)3502
Course Title: Industrial Chemicals and Environment
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Industrial Gases and Inorganic Chemicals (12 Periods)
Industrial Gases: Large scale production, uses, storage and hazards in
handling of oxygen, nitrogen, argon, neon, helium, hydrogen, acetylene,
carbon monoxide, chlorine, fluorine, sulphur dioxide and phosgene.
Inorganic Chemicals: Manufacture, application, analysis and hazards in
handling hydrochloric acid, nitric acid, sulphuric acid, caustic soda,
common salt; borax, bleaching powder, sodium thiosulphate, hydrogen
peroxide, peroxide, potash alum, chrome alum, potassium dichromate and
potassium permanganate.

UNIT 2
Industrial Metallurgy (3 Periods)
Preparation of metals (ferrous and nonferrous) and ultrapure metals for
semiconductor technology.
Energy & Environment (6 Periods)
Sources of energy: Coal, petrol and natural gas. Nuclear Fusion / Fission,
Solar energy, Hydrogen, geothermal, Tidal and Hydel, etc. Nuclear
Pollution: Disposal of nuclear waste, nuclear disaster and its management.
Biocatalysis (3 Periods)
Introduction to biocatalysis: Importance in Green Chemistry and
Chemical Industry

UNIT 3
Environment and its segments I Air Pollution (14 Periods)
Ecosystems. Biogeochemical cycles of carbon, nitrogen and sulphur. Major
regions of atmosphere. Chemical and photochemical reactions in
atmosphere. Air pollutants: types, sources, particle size and chemical
nature; Photochemical smog: its constituents and photochemistry.
Environmental effects of ozone, Major sources of air pollution.
Pollution
by SO2, CO2, CO, NOx, H2S and other foul smelling gases. Methods of
estimation of CO, NOx, SOx and control procedures. Effect of air pollution
on living organisms and vegetation. Greenhouse effect and Global
warming, Ozone depletion by oxides of nitrogen, chlorofluorocarbons and
Halogens, removal of sulphur from coal. Control of particulates.

42

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

UNIT 4
Environment and its segments II Water Pollution (14 Periods)
Hydrological cycle, water resources, aquatic ecosystems, Sources and
nature of water pollutants, Techniques for measuring water pollution,
Impacts of water pollution on hydrological and ecosystems. Water
purification methods. Effluent treatment plants primary, secondary and
tertiary treatment. Industrial effluents from the following industries and
their treatment: electroplating, textile, tannery, dairy, petroleum and
petrochemicals, agro, fertilizer, etc. Sludge disposal. Industrial waste
management, incineration of waste. Water treatment and purification
(reverse osmosis, electro dialysis, ion exchange). Water quality parameters
for wastage water; industrial water and domestic water.

Books Recommended
1. E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd.UK
2. R.M. Felder, R.W. Rousseau: ;Elementary Principles of Chemical
Processes, Wiley Publishers, New Delhi.
3. J.A. Kent: Riuegels Handbook of Industrial Chemistry, CBS
Publishers, New Delhi.
4. S. S. Dara: A Textbook of Engineering Chemistry, S. Chand &
Company Ltd. New Delhi.
5. K. De, Environmental Chemistry: New Age International ;Pvt., Ltd,
New Delhi
6. S. M. Khopkar, Environmental Pollution Analysis: Wiley Eastern Ltd.,
New Delhi
7. S.E. Manahan, Environmental Chemistry, CRC Press (2005)
8. G.T. Miller, Environmental Science 11th edition. Brooks/ Cole (2006)
9. A. Mishra, Environmental Studies. Selective and Scientific Books,
New Delhi (2005).

Course Opted: Discipline Specific Elective Course II


Practical
Course Code: CHD(P)3502
Course Title: Industrial Chemicals and Environment Lab
Credits: 2Full Mark: 25
General Experiments

15

1.
2.
3.
4.
5.

Determination of dissolved oxygen in watger


Determination of Chemical Oxygen Demand (COD)
Determination of Biological Oxygen Demand (BOD)
Percentage ;of available chlorine in bleaching powder.
Measurement of chloride, sulphate and salinity of water samples by
simple titration method (AgNO3 and potassium chromate)
6. Estimation of total alkalinity of water samples (CO32-, HCO3-) using
double titration method.
7. Measurement of dissolved CO2.
43

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

8. Preparation of borax.
9. Estimation of SPM in air sample.
10.
Study of some common bio-indicators of pollution.
Record
Viva

5
5
Books Recommended

1. E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.


2. R.M. Felder, R.W. Rousseau: Elementary Principles of Chemical
Processes, Wiley Publishers, New Delhi.
3. J. A. Kent: Riegels Handbook of Industrial Chemistry, CBS
Publishers, New Delhi.
4. S. S. Dara: A Textbook of Engineering Chemistry, S. Chand &
Company Ltd. New Delhi.
5. K. De, Environmental Chemistry: New Age International Pvt., Ltd,
New Delhi.
6. S. M. Khopkar, Environmental Pollution Analysis: Wiley Eastern Ltd,
New Delhi.

44

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Third Year
Semester VI
Course outline and Credit
structure
Course Opted
Core Course - XIII
Core Course - XIII
Practical
Core Course - XV
Core Course - XIV
Practical
Discipline Specific
Elective Course III
Discipline Specific
Elective Course III
Practical
Discipline Specific
Elective Course IV
Total

Course
Code
CHC(T)36
13
CHC(P)36
13
CHC(T)36
14
CHC(P)36
14
CHD(T)36
03
CHD(P)36
03

Course Title

Credit
s
4

Mark
s
75

Physical Chemistry Lab


V
Organic Chemistry
V
Organic Chemistry Lab
V
Analytical Methods in
Chemistry
Analytical Methods in
Chemistry Lab

25

75

25

75

25

CHD3604

Dissertation

100

24

400

Physical Chemistry V

45

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course XIII


Course Code: CHC(T)3613
Course Title: Physical Chemistry V
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Thermodynamics III (6 Periods)
3rd law of thermodynamics; Nernst heat theorem; Statement and concept
of residual entropy; Evaluation of absolute entropy from heat capacity
data.
System of variable compositions (6 Periods)
Partial molal quantities, their physical significance, chemical potential,
Gibbs-Duhem equation. Chemical potential of ideal mixtures, change in
thermodynamic function- entropy of mixing of ideal gases.

UNIT 2

Solutions of Non electrolytes (10 Periods)


Liquid- Liquid mixtures, Concentration units, ideal mixtures (derivations for
thermodynamic properties are not required); Raoults law; Vapour
pressure of ideal solution, Activity and chemical potentials of ideal and
non-ideal solutions; Non ideal liquid mixtures, azeotropes, HCl H 2O
system.

UNIT 3
Statistical Thermodynamics (14 Periods)
Phase space, unit cells, micro and macro state. Statistical weight factor,
configuration, distribution, distribution number, complexion and
combination. System, assembly and ensemble- Canonical, grand canonical
and micro canonical ensembles. Concept of distribution, thermodynamic
probability and most probable distribution. Most probable distribution and
Maxwell- Boltzmann distribution law of energy.

UNIT 4
Kinetics of Fast Reactions (4 Periods)
General features of fast reactions. Study of fast reactions by flow and
relaxation method.
Macromolecules (4 Periods)
Types of polymers, mechanism of polymerization, kinetics of addition
polymerization.
Micelles (4 Periods)
Surface active agents, classification of surface active agents, micellization,
critical micellar concentration (CMC), factors affecting the CMC of
surfactants.

Books Recommended
1. Modern College Chemistry, Physical by Achraya and Sharma
2. Thermodynamics by Glasstone.
46

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

3. Principles of Physical Chemistry, Revised Edition, Puri, Sharma and


Pathania.
4. Physical Chemistry, Atkins

Course Opted: Core Course XIII Practical


Course Code: CHC(P)3613
Course Title: Physical Chemistry Lab V
Credits: 2Full Mark: 25
General Experiments
15
1. Determination of partial molar volume of solute (NaCl) and solvent
(water) in a binary mixture.
2. Determination of partial molar volume of solute (KCl) and solvent
(water) in a binary mixture.
3. Study of kinetics of saponification of ethyl acetate conductometrically.
4. Estimation of available chlorine in bleaching powder iodometrically.
5. Verify the Freundlich isotherm for adsorption of acetic acid on activated
charcoal.
6. Verify the Langmuir isotherms for adsorption of acetic acid on activated
charcoal.
7. Verify the Freundlich isotherm for adsorption of oxalic acid on activated
charcoal.
8. Verify the Langmuir isotherms for adsorption of oxalic acid on activated
charcoal.
9. Study the variation of viscosity of sucrose solution with the
concentration of solute.
10. Study the kinetics of iodination of propanone in acidic medium.
Record
Viva

Books Recommended

5
5

1. A complete Course in Practical Chemistry, Acharya,


Mohapatra, Mishra and Sharma.
2. Volgels TextBook of Qualitative Inorganic Chemistry
Analysis, Revised, J.Bassett, R.C. Denney, G.H.Jeffery and
J.Mendham.
3. An advanced course of Practical Chemistry, Nad, Ghoshal &
Mohapatra

47

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Core Course XIV


Course Code: CHC(T)3614
Course Title: Organic Chemistry V
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Electromagnetic Radiation (2 Periods)
General principles Introduction to absorption and emission spectroscopy.
Ultraviolet Spectroscopy (5 Periods)
Types of electronic transitions, max, Chromophores and Auxochromes,
Bathochromic and Hypsochromic shifts, Intensity of absorption;
Application of Woodward Rules for calculation of max for the following
systems: , unsaturated aldehydes, ketones, carboxylic acids and esters;
Conjugated dienes: alicyclic, homoannular and heteroannular; Extended
conjugated systems (aldehydes, ketones and dienes); distinction between
cis and trans isomers.
Infrared Spectroscopy (5 Periods)
Fundamental and non-fundamental molecular vibrations; IR absorption
positions of O, N and S containing functional groups; Effect of H-bonding,
conjugation, resonance and ring size on IR absorptions; Fingerprint region
and its significance; application in functional group analysis.

UNIT 2
NMR Spectroscopy (6 Periods)
Basic principles of Proton Magnetic Resonance, chemical shift and factors
influencing it; Spin Spin coupling and coupling constant; Anisotropic
effects in alkene, alkyne, aldehydes and aromatics, Interpetation of NMR
spectra of simple compounds.
Mass Spectroscopy (8 Periods)
The molecular ion and determination of molecular mass. Recognition of
the parent peak. Fragmentation ions. Metastable ions. MacLaffertys
rearrangement. Important features of the mass spectra of the following
organic compounds: n-Dodecane, n-Propyl cyclohexane, Pentene,
cyclohexene, acetylene, Benzene, n- Butanol, sec- Butyl alcohol, Phenol,
Ethyl amine, Ethyl chloride.

UNIT 3
Application of spectroscopy (4 periods)
Combined problems using UV, IR, PMR and mass spectral data, for the
structure elucidation of simple organic compounds
Dyes (8 Periods)
Classification, Colour and constitution; Mordant and Vat Dyes; Chemistry
of dyeing; Synthesis and applications of: Azo dyes Methyl Orange and
Congo Red (mechanism of Diazo Coupling); Triphenyl Methane Dyes
-Malachite Green, Rosaniline and Crystal Violet; Phthalein Dyes
48

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Phenolphthalein and Fluorescein; Natural dyes structure elucidation and


synthesis of Alizarin and Indigotin; Edible Dyes with examples.

UNIT 4
Carbohydrates (14 Periods)
Occurrence,
classification
and
their
biological
importance.
Monosaccharides: Constitution and absolute configuration of glucose and
fructose, epimers and anomers, mutarotation, determination of ring size
of glucose and fructose, Haworth projections and conformational
structures; Interconversions of aldoses and ketoses; Killiani-Fischer
synthesis and Ruff degradation; Disaccharides Structure elucidation of
maltose, lactose and sucrose. Polysaccharides Elementary treatment of
starch, cellulose and glycogen.

Books Recommended
1.
2.
3.
4.
5.
6.
7.
8.
9.

Advance Organic Chemistry, B.S. Bahl and Arun Bahl.


Analytical chemistry;U.N Das
Elements
of
Analytical
chemistry;Gopalan,Subramanian,Rengarajan
Elements of Organic spectroscopy;Y.R.Sharma
Organic Chemistry Vol- I.II& III, S.M.Mukherji, S.P. Singh and
R.P.Kapoor.
Organic Chemistry; Wade
Organic spectroscopy;P.S.Kalsi
Text Book of Organic Chemistry, Morison & Boyd.
Text Book of Organic Chemistry, Vol I, I. L. Finar.

Course Opted: Core Course XIV Practical


Course Code: CHC(P)3614
Course Title: Organic Chemistry Lab V
Credits: 2Full Mark: 25

Organic Quantitative analysis


15
1. Estimation of Phenol
2. Estimation of Aniline
3. Estimation of Glucose.
4. Determination of acetic acid content in commercial vinegar using
NaOH.
5. Determination of ascorbic acid in citrus fruits.
6. Analysis of fat in a butter sample
7. Determination of the saponification value of a given oil.
8. Estimation of glycine by Sorensons formalin method
9. Study of the action of salivary amylase on starch at optimum
conditions
10.
Effect of temperature on the action of salivary amylase
11.
Study of the titration curve of glycine.
Record
5
Viva
5

Books Recommended
49

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

1. Experiments and Techniques in Organic Chemistry; D. Pasto, C.


Johnson & M. Miller; Prentice-Hall.
2. Macroscale and Microscale Organic Experiments; K. I. Williamson,
D. C. Heath.
3. Organic Synthesis, Vol. III; Clarke.
4. An advanced course of Practical Chemistry, Nad, Ghoshal &
Mohapatra

Course Opted: Discipline Specific Elective Course III


Course Code: CHD(T)3603
Course Title: Analytical Methods in Chemistry
Credits: 4Full Mark: 75 (External: 60 and Internal: 15)
(Each unit carries equal mark)
UNIT 1
Qualitative and quantitative aspects of analysis (9 Periods)
Sampling evaluation of analytical data, errors, accuracy and precision,
methods of their expression, normal law of distribution if indeterminate
errors, statistical test of data; F, Q and t test, rejection of data and
confidence intervals.
Thermal methods of analysis (3 Periods)
Theory of thermogravimetry (TG), basic principle of instrumentation.
Techniques for quantitative estimation of Ca and Mg from their mixture.

UNIT 2
Optical methods of analysis I (12 Periods)
Origin of spectra, interaction of radiation with matter, fundamental laws
of spectroscopy and selection rules, validity of Beer-Lamberts law. UVVisible Spectrometry: Basic principles of instrumentation, choice of source,
monochromator and detector for single and double beam instrument;
Basic principles of quantitative analysis: estimation of metal ions from
aqueous
solution,
geometrical
isomers,
keto-enol
tautomers.
Determination of composition of metal complexes using ;Jobs method
of continuous variation and mole ratio method. Infrared Spectrometry:
Basic principles of instrumentation, choice of source, monochromator &
detector for single and double beam instrument; sampling techniques.
Structural illustration through interpretation of data Effect and importance
of isotope substitution.

UNIT 3
Optical methods of analysis II (10 Periods)
Flame Atomic Absorption and Emission Spectrometry: Basic principles of
instrumentation (choice of source, monochromator, detector, choice of
flame and Burner designs. Techniques of atomization and sample
introduction Method of background correction, sources of chemical
interference and their method of removal. Techniques for the quantitative
estimation of trace level of metal ions from water samples.
Electroanalytical methods (4 Periods)
50

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Classification of electroanalytical methods, basic principle of pH metric,


potentiometric and conductometric titrations. Techniques used for the
determination of equivalence points. Techniques used for the
determination of pKa values.

UNIT 4
Separation techniques (14 Periods)
Solvent extraction: Classification, principle and efficiency of the technique.
Mechanism of extraction extraction by salvation and chelation. Technique
of extraction: batch, continuous and counter current extractions.
Qualitative and quantitative aspects of solvent extraction: extraction of
metal ions from aqueous solution, extraction of organic species from the
aqueous and nonaqueous media. Chromatography: Classification,
principle and efficiency of the technique. Mechanism of separation:
adsorption, partition & ion exchange. Development of chromatograms:
frontal, elution and displacement methods. Qualitative and quantitative
aspects of chromatographic methods of analysis: IC, GLC, GPC, TLC and
HPLC. Stereoisometic separation and analysis: Measurement of optical
rotation, calculation of Enantiomeric Excess (ee)/diastereometic excess
(de) ratios and determination of enantiomeric composition using NMR,
Chiral solvents and chiral shift reagents. Chiral chromatographic
techniques using chiral columns in GC and HPLC

Books Recommended
1. Vogel, Arthur I: A Test book of quantitative Inorganic Analysis (Rev.
by G.H. Jeffery and others) 5th Ed. The English Language Book
Society of Longman.
2. Willard, ;Hobert H.et.al.: Instrumental Methods of Analysis, 7 th Ed.
Wardsworth Publishing Company, Belmont, California, USA, 1988
3. Christ ian, Gary D; Analytical Chemistry, 6 th Ed. John Wiley & Sons,
New York, 2004.
4. Harris, Daniel C: Exploring Chemical Analysis, Ed. New Yord,
W.H.Freeman,2001.
5. Khopkar, S.M. Basic Concepts of Analytical Chemistry. New Age,
International Publisher, 2009.
6. Skoog, D.A., Holler F.J. and Nieman, T.A. Principles of Instrumental
Analysis, ;Thojmson Asian Pvt. Ltd. Singapure.
7. Mikes, O. & Chalmes, R.A. Laboratory Hand Book of
Chromatographic & Allied Methods, Elles Harwood Ltd. London.
8. Ditts, R.V. Analytical Chemistry - ;Methods of separation.

51

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Discipline Specific Elective Course III


Practical
Course Code: CHD(P)3603
Course Title: Analytical Methods in Chemistry Lab
Credits: 2Full Mark: 25
General Experiments
15
1. Separation and identification of glucose & fructose present in the
given mixture by paper chromatography. Reporting the R f values.
2. Separation of Ni2+ & Fe2+ in a mixture by complexation with DMG
and extracting the Ni2+ - DMG complex in chloroform, and
determine its concentration by spectrophotometry.
3. Determination of pH of soil.
4. Estimation of calcium, magnesium, phosphate, nitrate in soil.
5. Separation of metal ions from their binary mixture.
6. Separation of amino acids from organic acids by ion exchange
chromatography.
7. Determine the composition of the Ferric-salicylate/ ;ferricthiocyanate complex by jobs method.
8. Chromatographic separation of Fe+3, Al+3 and Cr+3 using paper
chromatography.
9. Chromatographic separation of active ingredients of plant, flowers
and juices.
10.
Determination of Na in coca cola drinks and fruit juices by
flame photometric methods.
11.
Determination of pH of aerated drinks, juices, shampoos and
soaps.
Record
5
Viva
5

Books Recommended
1. Vogel, Arthur I: A Test book of Quantitative Inorganic Analysis (Rev.
by G.H. Jeffery and others)5th ;Ed. The English Language Book
Society of Longman.
2. Willard, Hobert H.et.al: Instrumental Methods of Analysis, 7th Ed.
Wardsworth Publishing Company, Belmont, California, USA,1988.
3. Christan, Gary D; Analytical Chemistry, 6th Ed. John Wiley & Sons,
New ;York, 2004.
4. Harris, Daniel C: Exp[loring Chemical Analysis, Ed. News York, W.H.
Freeman, 2001.
5. Khopkar, S.M. Basic Concepts ;of Analytical Chemistry. News Age,
International Publisher, 2009.
6. Skoog, D.A. ;Holler F.J. and Nieman, T.A. P:rinciples of Instrumental
Analysis, Thomson Asia Pvt. Ltd. Singapore.
7. Mikes, O.& Chalmes, R.A. Laboratory ;Hand Book of
Chromatographic & Allid ;Methods, Elles Harwood Ltd. London.

52

College of Basic Sciences & Humanities


Honours

Bachelor of Science Syllabus In Chemistry

Course Opted: Discipline Specific Elective Course IV


Course Code: CHD3604
Course Title: Dissertation
Credits: 6Full Mark: 100
The Topic for Dissertation will be assigned to the students by
the concerned guide at the beginning of the 6th Semester.

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