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FIITJEE - JEE (Main)

SAMPLE TEST - 1
Time Allotted: 3 Hours

Maximum Marks: 360

Do not open this Test Booklet until you are asked to do so.
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

Important Instructions:
1.

Immediately fill in the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen. Use of
pencil is strictly prohibited.

2.

The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out
the Answer Sheet and fill in the particulars carefully.

3.

The test is of 3 hours duration.

4.

The Test Booklet consists of 90 questions. The maximum marks are 360.

5.

There are three sections in the question paper I, II, III consisting of Physics, Chemistry and Mathematics
having 30 questions in each section of equal weightage. Each question is allotted 4 (four) marks for correct
response.

6.

Candidates will be awarded marks as stated above in instruction No.5 for correct response of each question.
(one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from
the total score will be made if no response is indicated for an item in the answer sheet.

7.

There is only one correct response for each question. Filling up more than one response in any question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6
above.

8.

Use Blue / Black Ball Point Pen only for writing particulars / marking responses on Side-1 and Side-2 of the
Answer Sheet. Use of pencil is strictly prohibited.

9.

No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. except the Admit Card inside the examination hall / room.

10. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room / Hall. However, the candidates are allowed to take away this Test Booklet with them.
11. Do not fold or make any stray marks on the Answer Sheet.

Name of the Candidate (in Capital Letters) :_____________________________________


Enrolment Number :_________________________________________________________
Batch :________________________ Date of Examination : ________________________

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JEE-MAIN -SAMPLE TEST -1-PCM-2

Useful Data Chemistry:


= 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987 2 Cal K1 mol1
Avogadro's Number Na
= 6.023 1023
Plancks Constant h
= 6.626 1034 Js
-27
= 6.25 x 10 erg.s
1 Faraday
= 96500 Coulomb
1 calorie
= 4.2 Joule
-27
1 amu
= 1.66 x 10 kg
1 eV
= 1.6 x 10-19 J
Atomic No :
H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses:
He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Gas Constant

Useful Data Physics:


Acceleration due to gravity g = 10 m / s2

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JEE-MAIN -SAMPLE TEST -1-PCM-3

Section I (Physics)
1.

A particle is projected vertically upwards with a velocity of 20 m/sec. Find the time at which the
distance travelled is twice the displacement

1.
Sol.

(A) 2 + 4 / 3 sec.
A
For AB

(B) 1 sec.

s/2

3s
0 20 20 2 10 .
2
20 20 40
S

10 3
3
1 2
Now, s ut gt
2
40
1

20t 10t 2
3
2
4
On solving t 2
3
2.

(D) 3 sec

2s
v u 2 g
2
2

3/4

(C) 2 +

C
s
A

Two men who can swim with a speed v 1 in still water start from the middle of a river of width d
and move in opposite directions always swimming at an angle with the banks. What is the
distance between them along the river when they reach the opposite banks, if the velocity of the
river is v2
(A)

2.

Sol.

t1

dv 1
cot
dv 2

3.

3.
Sol.

dv1 cos
v1 v 2

(C)

dv 2
tan
v1

(D)

v2 d
v1 sin

d /2
v1 sin

Distance =

(B)

v1 cos v2 v1 cos

d
2v1 sin

v2 d
v1 sin

A uniform chain of mass m hangs from a light pulley, with unequal lengths of the chain hanging
from the two sides of pulley the force exerted by moving chain on the pulley is
(A) = mg
(B) > mg
(C) < mg
(D) either b or c depending upon acceleration of
chain
C
Force is less than mg as it is accelerated

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JEE-MAIN -SAMPLE TEST -1-PCM-4

4.

In the figure ball A is released from rest, when the spring is at its natural
length. For the block B of mass M to leave contact with the ground at
some stage, the minimum mass of A must be
(A) 2M
(B) M
(C) M/2
(D) a function of M and force constant of spring.

4.
Sol.

C
For B
Just to loose contact

Mg Kx x

Kx

Mg
K

Applying WET

WDg WDs KE

1
Kx 2 mgx 0
2
M
m
2
5.

5.
Sol.

N
Mg

A system is shown in figure pulleys and strings are ideal system


is released from rest
a1 acceleration of 2 kg, a2 = acceleration of 3 kg
(i) a1 = 2a2
(ii) a2 = 2a1
(iii) a1 = a2 = 0
s = 3 / 2 2 kg
(iv) Tension T in the string = 15 N
(v) frictional force between 2 kg & incline = 5N
300
(vi) frictional force between 2 kg & incline = 15N
(A) (ii), (iv) & (vi) are correct
(B) (iii), (v) are correct
(C) (iii), (iv) & (v) are correct
(D) (i), (iv) & (vi) are correct
D
Using constraint

a1 0
a2
2
a1 2a2 .(1)
Applying Newtons law and
solving

T f 15 N

3 kg

a1

3
N

2 g sin

a2

2 g cos
3g

6.
6.
Sol.

A bullet of mass 10 gm is fired from a rifle with a velocity of 800 m/s. After passing through a mud
wall 180 cm thick, the velocity drops to 100 m/s. The average resistance of the wall is
(A) 750 N
(B) 1250 N
(C) 1750 N
(D) 2250 N
C
Using Kinematics find time taken by bullet
Then,

7.

7.

P
F 1750 N
t

A body is gently dropped on a conveyor belt moving 3 m/s. If


2
relative to the belt before coming to rest? (g = 10m/s )
(A) 0.3 m
(B) 0.6 m
(C) 0.9 m

= 0.5 how far will the body move


(D) 0.8 m

C
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JEE-MAIN -SAMPLE TEST -1-PCM-5

Sol.

With respect to belt

v 2 u 2 2as
0 32 2 g s
s 9m
8.

Consider the disc kept on a rough horizontal surface as


shown in the diagram. If a horizontal force F has to be
applied such that the disc starts pure rolling, what
should be the value of h ?

8.
Sol.

(A) R
(C) R / 2
h
C
For Pure rolling

F
h
R

(B) R/3
(D) Body cant start pure rolling for any value of

aCM Rh
F R.F h R

mR 2
m
3
2
R
On solving, h
2
9.

Moment of inertia of a half shell of mass M about an


axis tangential to it, as shown, would be

R
O

(A)
9.
Sol.

2
MR 2
3

(B)

1
MR 2
3

(C) MR2

(D) none of these

B
Applying parallel axis theorem

1
I MR 2
3
10.

Consider 3 bodies namely a disc A, a sphere B and a hollow cylinder all


with same mass and radius being released from top of fixed inclined plane.
If tA, tB & tc be the time they take to reach the bottom, find the correct
alternative for each of given situations.

In absence of any friction


(A) tC > tA > tB
(B) tC < tA < tB

10.
Sol.

(C) tC = tA = tB

(D) none of these

C
In absence of friction only mg is acting through COM.
So, this case of sliding in all cases and time taken will be same as aCM is same.

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JEE-MAIN -SAMPLE TEST -1-PCM-6

11.

A small ball starts rolling on an inclined track which


becomes loop if radius R in vertical plane.

h=2R

11.
Sol.

(A) speed of the ball at highest point is zero but and highest point is 2R above the ground.
(B) speed of the ball at highest point is non zero but highest point is 2R above the ground
(C) speed of the ball is along horizontal at highest point and highest point is less than the 2R
above the ground.
(D) speed of the ball is along horizontal at highest point but height of highest point above the
ground can not be calculated.
C
In Pure rolling, energy is conserved

PE T .KE R. KE
12.

A double star consists of two stars having mass M and 2M. The distance between their centre is
equal to r. They revolve under their mutual gravitational interaction. Then which of the following
statements is/are correct.
(A) heavier star revolves in orbit of radius r/3
(B) kinetic energy of heavier star is twice of that of the other star.
(C) lighter star revolves in orbit of radius

12.
Sol.

2r
5

(D) all above are correct.


A
Taking M as origin applying COM

M 0 2m r 2
r
3M
3
r
So, from heavier black
3
xCM

13.

Three small identical bodies each of mass m are moving in circular orbit around a fixed point with
same angular velocity under their gravitational interaction. If the separation between any two
bodies is R, the total energy possessed by the system is given by
(A)

3GM2
2R

(B)

13.

Sol.

Total potential energy =


Total K.E. =

3GM2
4R

2R cos 30

(D)

3GM2
R

3 GM 2
2 R
3 GM 2
2 R

A man of mass M stands at one end of a plank of length L which lies at rest on a frictionless
surface. The man walks to the other end of the plank. If the mass of the plank is M/3, the
distance that the man moves relative to the ground is
(A)

14.

3GM2

3GM 2
R

So, total energy = KE P.E


14.

(C)

3L
4

(B)

4L
5

(C)

L
4

(D)

L
3

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JEE-MAIN -SAMPLE TEST -1-PCM-7

Sol.

Let the distance moved by plank be x.


Now, there is no external force so COM
Will not move

m1n1 m2 n2
m1 m2
M
M L x x
3
0
4M
3
Mx
ML Mx
3
44
ML Mx.
3
3L
x
4
xCM

So, distance moved by person wrt.

15.

L
4

The centre of mass of a half disc shown is at C while O is the centre. Thus OC
is
(A) R/2
(B) 2R/
(C)

15.

4R
3

(D) none of the above


O

Sol.

16.

16.
Sol.


4 R sin
2
COM of sector =
3
Here
4R
r
3
If the tension in a stretched string fixed at both ends in changed by 20%, the fundamental
frequency is found to change by 15 Hz. Then the
(A) original frequency is 150 Hz
(B) velocity of propagation of the transverse wave along the string changes by 5 %
(C) velocity of propagation of the transverse wave along the string change by 10 %
(D) fundamental wavelength on the string does not change.
B

T2' 1.2T

v
17.

Beats are produced by two progressive waves. Maximum loudness at the waxing is x times the
loudness of each wave. The value of x is

17.
Sol.

(A) 1
(B) 2
D
At maximum net amplitude = 2A
Loudness A

(C) 2

(D) 4

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JEE-MAIN -SAMPLE TEST -1-PCM-8

18.

A thermodynamic system undergoes a cyclic


process as shown in the figure. The cycle
consists of two closed loops. Over one
complete cycle, the system performs
(A) positive work
(B)negative work
(C) zero work
(D) nothing can be predicted

18.
Sol.

B
Area under PV graph is greater is anticlockwise direction.
So, net W.D. is negative

19.

A half ring of radius R is charged with a linear charged density . The field at the centre is
(A) 0
(B) k/R
(C) 2k/R (D)
k/R
C

19.
Sol.

20.

dl Rd
dq .R
K . dq
dE
R2
/2
dq
2K
E K . 2 cos
R
R
/2

The maximum electric field strength E due to a uniformly charged ring of radius r, happens at a
distance x, where value of x is (x is measured from the centre of the ring)
(A) x = R

(B) x = R/2

(C) x =

(D) x = 2 R

2
20.

Sol.

KQx

x2

For maximum
So, x

21.

3/ 2

dE
0
dx

R
2

Two charges +q and q are placed fixed on the corner of a


massless rigid rod of length 2L.Calculate the potential energy of
the dipole thus formed.
2

(A)

1 q
4 o 4L2

21.

Sol.

PE =

(B)

1 q
4 o 2L

+q

q
2L

(C)

1 q
2 o 2L

(D) None of these.

KqV
1 q2

r
4 0 2 L

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JEE-MAIN -SAMPLE TEST -1-PCM-9

22.

If the above discussed dipole is placed in a uniform electric field E as shown,


calculate the proper potential energy of the dipole.
(A)

1 q2
4 o 2L

(B) 4qLE

1 q2
(C) 2qLE
4 o 2L
22.
Sol.

+q

1 q2
4 o 2L

2L

1 q2
(D) 4qLE
4o 2L

D
Net PE = PE due to EF + PE of system

4qLE

1 q2
4 0 2 L

In the shown network current through 20 resistor equals

23.

3
(A) A
2

10 V

9
(B) A
2
2
(D) A
3

(C) 1A

20 V

10
20

23.
Sol.

A
Applying KVL

I
24.

3
A
2

Equivalent resistance between the points A and B is


(A) 1
(B) 2
(C) 3
(D) 4

3
3

3
3

3
3

24.
Sol.

D
Using node removal method

Req h
25.

The two rails of a railway track; insulated from each other and the ground, are connected to
millivoltmeter. What is the reading of the millivoltmeter when a train passes at a speed of 180
km/hr along the track, given that the horizontal component of earths magnetic field is
0.2 10-4 wb/m2 and rails are separated by 1 metre
(A) 10-2 V
(B) 10 mV
(C) 1 V
(D) 1 mV
D

25.
Sol.
26.
26.
Sol.
27.

27.


dl . B v 1mV

In an R-L-C circuit v = 20 sin (314 t + 5/6) and i = 10 sin (314 t + 2/3)


The power factor of the circuit is
(A) 0.5
(B) 0.966
(C) 0.866
C
Conceptual based

(D) 1

A circular current carrying coil has a radius a. The distance from the centre of coil, on its axis,
where the magnetic induction will be 1/8 th of its value at centre of coil is
(A) 3a
C

(B) + 3a

(C) 3a

(D) 2a / 3

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JEE-MAIN -SAMPLE TEST -1-PCM-10

Sol.

0 IR 2
2 R2 x

2 3/ 2

0 I
B
2R

x 3a
28.

28.
Sol.
29.

29.
Sol.

In photoelectric effect, the photo current


(A) increases with increase of frequency of incident photon
(B) decreases with increase of frequency of incident photon
(C) does not depend on the frequency of the photon but depends only on intensity of incident
light.
(D) depends both on intensity and frequency of photon.
C
Conceptual based
If refractive index of water is 4/3 and glass is 5/3 then critical angle so that light travelling form
glass to water is completely reflected is
(A) sin-1 (4/5)
(B) sin-1 (5/4)
(C) sin-1 (3/5)
(D) sin-1 (5/3)
A
Applying 1 sin i 2 sin r

sin
30.
30.
Sol.

4
5

When a ray of light enters a glass slab from air


(A) its wavelength decreases
(B) its wavelength increases
(C) its frequency increases
(D) neither wavelength nor frequency changes
A

vf
f req remains constant
Here volume increases, so

decreases
space for rough work

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JEE-MAIN -SAMPLE TEST -1-PCM-11

Section II (Chemistry)
1.

For the equations


C diamond 2 H 2 g CH 4 g ; H1
C graphite 2H 2 g CH 4 g ; H 2
Predict whether
(A) H1 H 2

1.
Sol.

(B) H1 H 2

(C) H1 H 2
(D) H1 H 2 H vap 3 H diss H 2
B
This is because diamond is more stable than graphite and has more energy content.

2.

Which of the following can behave as both electrophile and nucleophile?


(A) CH 3 C N
(B) CH 3OH
(C) CH 2 CH CH 3
(D) CH 3 NH 2

2.
Sol.

A
CH 3CN can behave as both electrophile and nucleophile.

3.

Steam reacts with iron at high temperature as follows:


3Fe s 4 H 2 O g Fe3O4 s 4 H 2 g
The correct expression for the equilibrium constant (KP) is:
4

(A)

pH

(B)

pH 2O

p
p
H2

(C)

H 2O

p Fe O
p Fe
H2

H 2O

3.
Sol.

B
Molar concentration or partial pressure of solid = 1.

4.

In which of the following solvents, AgBr has the maximum solubility?


(A) 10-3 M NaBr
(B) 10-3 M NH4OH
(C) Pure water

(D)

Fe3O4
Fe

(D) 10 3 M HBr

4.
Sol.

B
AgBr reacts with NH4OH to form a soluble complex.
AgBr 2 NH 4OH Ag NH 3 2 Br 2 H 2 O.

5.

The electrode potential of a copper wire dipped in 0.1 M CuSO4 solution at 250C (the standard
reduction potential of copper is 0.34V):
(A) 0.34V
(B) 0.31V
(C) 0.349 V
(D) 0.28 V

5.
Sol.

B
The electrode reaction written as reduction reaction is
Cu 2 2e Cu n 2
0.0591
1
Applying Nernst equation, E = E 0
log
2
Cu 2

Cu s 1

0.0591
1
log
2
0.1
0.34 0.0295 1 0.3105V
0.34

6.

The strongest reducing agent among the following is


(A) F(B) Cl(C) Br-

6.
Sol.

D
I- can losses electrons easily (undergoes oxidation easily). So strong reducing agent

(D) I-

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JEE-MAIN -SAMPLE TEST -1-PCM-12

7.

Diazonium salt decomposes as:


C6 H 5 N 2 Cl C6 H 5Cl N 2

7.

At 00 C , the evolution of N2 becomes two times faster when the initial concentration of the salt is
doubled., Therefore, it is
(A) a first order reaction
(B) a second order reaction
(C) independent of the initial concentration of the salt
(D) a zero order reaction.
A

Sol.

Because rate conc

8.

If 2.68 10 mole of a solution containing an ion A

the oxidation of A
(A) 3
8.

requires 1.61 10

mole of MnO4 for

to AO3 in an acidic medium, then what is the value of n?


(B) 2
(C) 5
(D) 4

An

Sol.

MnO4

AO3 Mn 2

1.61103
2.68 103 5 n 1.61 103 5
5n 3
n2

mole 2.68 10

9.

The equivalent weight of MnSO4 is half its molecular weight when it is converted to
(A) Mn2O3

(B) MnO2

(C) MnO4

(D)

MnO42

9.

Sol.

Mn 2 Mn 4 2e
nf 2
M .wt
E.wt
2

10.

The largest number of molecules is in


(A) 36 g of H2O
(B) 28 g of CO
(C) 46 g of CH3CH2OH
(D) 54 g of N2O5
(Use atomic weight: O = 16, C = 12, N = 14, H = 1)

10.

Sol.

N H 2O

11.

Consider a titration of K 2Cr2O7 with acidified Mohrs salt solution FeSO4 . NH 4 2 SO4 .6 H 2O

36
N AV 2 N AV
18
28
N CO
N AV N AV
28
46
N C2 H5OH
N AV N AV
46
54
N N 2O5
N AV 0.5 N AV
28 80

using diphenylamine as indicator. The number of moles of Mohrs salt required per mole of
dichromate is

H
Fe2 Cr2O72
Fe 3 Cr 3

(A) 3

(B) 4

(C) 5

(D) 6

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JEE-MAIN -SAMPLE TEST -1-PCM-13

11.

Sol.

neq Mohr salt = neq Cr2 O7

1 6

n 1
n6

The normality of 0.3 M phosphorus acid H 3 PO3 is

12.

(A) 0.1
12.
Sol.

(B) 0.9

(C) 0.3

(D) 0.6

D
O
HO

OH

nf 2
N 0.3 2 0.6

13.

The energy of hydrogen atom in the ground state is 13.6 eV. Its energy corresponding to the
quantum number n = 5 is
(A) 0.54eV
(B) 5.40 eV
(C) 0.85eV
(D) 2.72eV ]
A

Sol.

En

14.

14.

If r1 is the radius of first orbit of hydrogen atom, then the radii of second, third and fourth orbit in
terms of r1 are
(A) 8r1 , 27 r1 , 64r1
(B) 2r1 , 6r1 ,8r1
(C) 4r1 ,9r1 ,16r1
(D) r1 , 2r1 ,3r1
C

Sol.

rn r1 n 2

15.

If kinetic energy of an electron is increased nine times, the de-Broglie wavelength associated with
it would become

13.

13.6
n2

(A) 3 times

(B) 9 times

(C)

1
times
3

(D)

1
times
9

15.

Sol.

16.

Which electronic level allows the hydrogen atom to absorb a photon but not emit a photon?
(A) 2s
(B) 2p
(C) 1s
(D) 3d
C
1s is the lowest energy level

16.
Sol.

1
KE

CH3
17.

Br

NaOMe

CH 3OH

E2

Product. Product of the reaction is:

reaction

CH3

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JEE-MAIN -SAMPLE TEST -1-PCM-14

(A)

(B)

(C)

(D)

No reaction

OMe

17.
Sol.

D
Since there is no

H present anti to Br, hence E2 doesnt occur.

CH3

18.

Major product of the reaction is:

NaOEt

Cl

CH3

CH3

(A)

18.

CH3

CH3

(B)

(C)

(D)

B
CH3

CH3

and

Sol.

The product obtained are:

(major)

19.

(minor)

Which of the given options best describes the product of the following reaction?
CH3

Ph
(A)
(B)
(C)
(D)
19.
Sol.

K t BuO

Product
E2

CD3
Br
Absolute configuration has been inverted
Absolute configuration has been retained
Racemisation (loss of absolute configuration)
Loss of chirality has occurred (the product is achiral)

D
CH3

CH2

Ph

CD3
Br

K t BuO

Ph
E2

CD 3

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JEE-MAIN -SAMPLE TEST -1-PCM-15

20.

Which one of the following undergoes nucleophlic aromatic substitution at the fastest rate?
Cl

(A)

(B)

Cl

(C)

NO 2
20.
Sol.

Cl

Cl

(D)

CH3

Cl

OMe

A
The electron withdrawing groups make nucleophilic aromatic substitution proceed at the fastest
rate.
Br
NO 2

21.

OH

Product of the following reaction is:

Br
Br

OH

Br
Br

NO 2

NO 2

(A)

HO

(B)

NO 2

(C)

NO 2

(D)
HO

OH
21.
Sol.

Br

Br

B
The electron-withdrawing groups at ortho or para position to the leaving group help nucleophilic
aromatic substitution proceed at a faster rate.
OH

OH
Ph

22.

H 2 SO4

Ph
(A)

The product (P) is:

99% yield

(B)

Ph

Ph

(C)

OH

(D)

Ph

C
C

Ph
Ph

Ph

Ph
Ph

22.

A
OH

Ph

Sol.

Ph

H 2O

Ph

Ph

23.

OH

OH

Ph

An organic compound B is formed by the reaction of ethyl magnesium iodide CH 3CH 2 MgI
with a substance A, followed by treatment with dil. aqueous acid. Compound B doesnot react
with PCC. Identify A?
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Ph

JEE-MAIN -SAMPLE TEST -1-PCM-16

(A)

O
H3C

23.

(B)

CH3CH2

(C)

(D)

CH 2 O

O
CH2

CH3

CH2

B
O
CH3 CH2

Sol.

OH

O(MgI)
CH3

EtMgI
CH3 CH2 C

dil aq

CH3 CH2 C
acid

CH3

Et

Et

CH3

PCC
No reaction
O
18

24.

Ph

OH H3C

H
X H 2 O.

Identify

O
(A)

X Ph

CH3

(Esterification)

CH3

(Esterification)

O
(B)

18

X Ph

O
(C)

18

X Ph

CH3 (Saponification)

CH3

O
(D)

24.

X Ph

(Hydrolysis)

18

Ph

OH2

OH

OH
OH

H3C

Ph
H

18

Ph
CH3

18

CH3

OH

OH H
Sol.
O

18

Ph

CH3

X
25.

SOCl2
O3 / Zn
CH 2 CH CH 2 CH 2 CH 2OH

A
pyridine
H 2O

C4 H 7ClO

Compound (B) is

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JEE-MAIN -SAMPLE TEST -1-PCM-17

(A)

O
H3C

CH2

CH2
CH3

(B)

O
CH2

CH2

CH2

(C)

HC
O
HC

CH2

CH2

CH2

CH2

Cl

Cl
(D)

O
HC

CH2

CH

CH3

Cl
25.
Sol.

C
O3 / Zn
CH 2 CH CH 2 CH 2 CH 2Cl
HCHO CHO CH 2 CH 2 CH 2Cl
H 2O

26.

Equimolar solutions of two non electrolytes in the same solvent have


(A) same b.pt but different f.pt
(B) same f.pt but different b.pt
(C) same b.pt and same f.pt
(D) different b.pt and different f.pt

26.
Sol.

27.

The degree of dissociation

T f and Tb are constant for a solvent.

of weak electrolyte Ax B y is related to vant Hoffs factor (i) by

the expression:
(A)

i 1
x y 1

(B)

27.

Sol.

Ax By
xA y yB x

x
1
i 1 x y
i 1 x y 1

i 1
x y 1

(C)

x y 1
i 1

(D)

x y 1
i 1

i 1
x y 1

When 20 gm of naphthoic acid C11 H 8O2 is dissolved in 50 gm of benzene k f 1.72 , a

28.

freezing point depression of 2k is observed. The vant Hoff factor (i) is


(A) 0.5
(B) 1
(C) 2
28.
Sol.

(D) 3

T f K f molality i

2 1.72

20 1000

i
172 50

i 0.5
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JEE-MAIN -SAMPLE TEST -1-PCM-18

A 0.004 M solution of Na2 SO4 is isotonic with a 0.01 M solution of glucose at same temperature.

29.

The apparent degree of dissociation of Na2 SO4 is


(A) 25%
(B) 50%
(C) 75%
29.
Sol.

(D) 85%

Na2 SO4 Glu cos e


CRT 1 2 CRT
0.004 1 2 0.01

0.75
75%
If equal volumes of BaCl2 and NaF solutions are mixed, which of these combination will not

30.

give a precipitate. K sp of BaF2 1.7 10


2

(A) 10 M BaCl2 and 2 10 M NaF


2

(C) 1.5 10 M BaCl2 and 10 M NaF


30.
Sol.

(B) 10 M BaCl2 and 1.5 10 M NaF


2

(D) 2 10 M BaCl2 and 2 10 M NaF

C
For precipitation Qsp K sp

pace for rough work

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JEE-MAIN -SAMPLE TEST -1-PCM-19

Section III (Mathematics)


n

n 1

r 1r

1.

r 1

Cr
n1

equals to

1
n 1
(n 2)
(C)
n1
B

n
n 1
1
(D)
n 1

(A)

1.

(B)

n n 1
n 1
n Cr
Cr 1 n1Cr
Cr
=

n 1
n 1
r 1 n 1
r 1 r 1
1
n
1 n n 1
=
( Cr 1 n 1Cr ) =
(1 n 1)
.
n 1 r 1
n 1
n1
n

Sol.

Statement -1: If a, b, c are distinct and x, y , z are not all zero, then

2.

ax by cz 0
bx cy az 0
cx ay bz 0
Gives a + b + c 0
Statement 2: a 2 b 2 c 2 ab bc ca if a, b, c are distinct.
(A) Statement-1 is true, Statement-2 is true, but Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is true, Statement-2 is true, but Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is true, Statement-2 is false.
(D) Statement-1 is false, Statement-2 is true.
2.

a b
Sol.

Let D = b

c
a = a 3 b3 c3 3abc

c a b

a b c a 2 b 2 c 2 ab bc ca
Now a 2 b 2 c 2 ab bc ca 0

the given system of equations can have non-zero solution (x, y, z are not all zero)
If D = 0, i.e. If a b c 0
Statement -1 is false.
Again a 2 b 2 c 2 ab bc ca

1
2a 2 2b 2 2c 2 2ab 2bc 2ca
2
1
2
2
2
a b b c c a 0

a, b, c are all different


2

a b c ab bc ca
Statement-2 is true.
D holds.
3.

If f x is an odd periodic function with period 2, then f 4 equals


(A) 0
(B) 2
(C) 4

(D) - 4

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JEE-MAIN -SAMPLE TEST -1-PCM-20

3.

Sol.

f 4 f 2 f 0 0
The solution of the differential equation 2 x

4.

(A) straight lines


4.

dy
y 3 represents
dx

(B) circle

(C) parabola

(D) ellipse

Sol.

dy y
3

dx 2 x 2 x
1
I .F .
x
y 3 c x
5

5.

If [x] denotes the greatest integer less than or equal to x, then the value of

x 3 dx is
1

(A) 1
5.

(B) 2

(C) 4

(D) 8

Sol.

x 3 dx

x dx

2 x dx
0

A tower AB leans towards west making an angle with the vertical. The angular elevation of B,
the top most point of the tower, is , as observed from a point C due east of A at a distance d
from A. If the angular elevation of B from a point due east of C is at a distance 2d from C is ,
then
(A) 2 tan 2cot cot
(B) 2 tan 3cot cot

6.

(C) tan cot cot


6.
Sol.

(D) None of these

B
B

Let h be height of tower then

tan 90

... 1

h
... 2
xd
h
tan
... 3
3d x
tan

West

h
x

90

East

Solve (1), (2) and (3)


d

2d

2 tan 3cot cot

7.

Let f x x3 ax 2 bx 5sin 2 x be an increasing function in the set of real number R. Then

7.

(A) a 2 3b 15 0
C

(B) a 2 3b 15 0

(C) a 2 3b 15 0

(D) a 0 and b 0

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JEE-MAIN -SAMPLE TEST -1-PCM-21

Sol.

dy
3 x 2 2ax b 10 sin x cos x
dx
and discriminant < 0
n

If a1 , a2 , a3 ,... are in H.P. and f k

8.

ak , then

r 1

(A) A.P.
8.

Sol.

Let

(B) G.P.

a
a
a1
a
, 2 , 3 ,..., n are in
f 1 f 2 f 3
f n

(C) H.P.

(D) None of these

Sn

r 1

1 1 1
1
, , ,....
in A.P.
a1 a2 a3
an
S n Sn Sn
S
, , ,....., n in A.P.
a1 a2 a3
an
Sn
S
S
1, n 1, n 1... in A.P.
a1
a2
a3
1
1
1

,
,
...... H.P.
Sn
Sn
Sn
1
1
1
a1
a2
a3
a
a
a
1 , 2 , 3 ,..... in H.P.
f 1 f 2 f 3
9.

A problem in mathematics is given to 3 students whose chances of solving individually are

1 1
,
2 3

1
. The probability that the problem will be solved atleast by one is
4
1
1
23
3
(A)
(B)
(C)
(D)
4
24
34
4
and

9.
Sol.

D
1 Nobody solves the problem

1 1 1
1 1 1 1
2 3 4
10.

If a I and the equation x a x 10 1 0 has integral roots, then the values of a are
(A) 6, 8
(B) 8, 10
(C) 10, 12
(D) 8, 12

10.

Sol.

x a x 10 11
so either x a 1 and x 10 1
or x 10 1 and x a 1

11.

If 2 x 6 y 2 touches the hyperbola x 2 2 y 2 4 , then the point of contact is


(A)

11.

2, 6

(B)

5, 2 6

1 1

2 6

(C) ,

(D)

4, 6

D
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JEE-MAIN -SAMPLE TEST -1-PCM-22

2 6y
in equation of hyperbola
2
y 6 x4

Sol.

Put x

12.

Consider a circle with its centre lying on the focus of the parabola y 2 px such that it touches
the directrix of the parabola. Then a point of intersection of the circle and the parabola is

p
p

, p or , p
2
2

p
(C) , p
2

p p
,
2 2
p p
(D) ,
2 2

(A)

(B)

12.
Sol.

A
If focal chord is diameter of the circle then it touches the directrix of the parabola

13.

If a, a

falls inside the angle made by the linear equations

x
y , x 0 and y 3x, x 0 , then
2

a belongs to

1
2

(A) 3,
13.
Sol.

1
2

1
2

(C) 3,

(B) 0,

(D) ,3

D
Locus of point a, a 2 is y x

y x2

y 3x

y x 2 and y

(3, 9)

x
2

x
2

1
2
y x 2 , y 3x
x 0,3
1
a3
2
x 0,

1 1
,
2 4

The straight lines whose direction cosines satisfy al bm cn 0, fmn gnl hlm 0 are
perpendicular if

14.

(A)
(C)

af bg ch 0

(B)

f g h
0
a b c

14.

Sol.

Put l

a 2 b2 c2
0
f
g
h

(D) a 2 f b 2 g c 2 h 0

bm cn
in the another equation,
a
bm cn
fmn gn hm
0
a

2
bhm mn bg ch af cgn 2 0

m1m2 n1n2
ll

12
g /b h/c f /a
15.

Domain of derivative of the function f (x) = |sin (2x 1)| is

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JEE-MAIN -SAMPLE TEST -1-PCM-23

1
(B) [1, 1] ~ 0,

1
(D) [1, 1] ~

(A) [1, 1]
(C) [1, 1] ~ {0}
15.

Sol.

y = |sin1 (2x2 1)|

sin1 (2x 2 1)
y =

4x

sin (2x 1) | 2x | 1 x 2
1

x 0 and sin (2x 1) 0 and |2x 1| 1 |x| 1

x 0, x

tan1 r 2 5r 7 equals to

16.

r 1

(A) tan1 3
(C) sin1

(B)

(D) cot1 2

10

16.

Sol.

an = tan1

1 (n 3) (n 2)
tan

1 (n 3)(n 2)
1 (n 3)(n 2)

= tan1 (n + 3) tan1 (n + 2)
Sn = tan1 (n + 3) tan1 3
S =

1
tan1 3 cot 1 3 sin1
.
2
10

17.

If P1, P2, P3 be the lengths of perpendiculars from the vertices of the triangle ABC to the opposite
sides, then
(A) P1P2P3 = abc
(B) P1P2P3 = 8R3
a2b2c 2
a2b2c 2
(C) P1P2P3 =
(D)
P
P
P
=
1
2
3
R3
8R 3
(where R is circumradius of triangle ABC).

17.

Sol.

P1 = c sin B, P2 = a sin C, P3 = b sin A


P1P2P3 = abc sin A sin B sin C =

a2 b 2 c 2
.
8R3

18.

A unit vector is orthogonal to 5i 2j 6k and is coplanar to 2i j k and i j k , then the


vector is
3j k
2i 5j
(A)
(B)
10
29
6i 5k
2i 2j k
(C)
(D)
3
61

18.
Sol.

Let a be the unit vector

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JEE-MAIN -SAMPLE TEST -1-PCM-24

a 2i j k i j k

| a | = 1 (2 + )2 + ( )2 + ( + )2 = 1
62 + 4 + 32 = 1

a is orthogonal to 5i 2j 6k so, 5(2 + ) + 2( ) + 6( + ) = 0


18 + 9 = 0 2 =
62 82 + 122 = 1
102 = 1
1
2
=
=
10
10

3j k
a
.
10
2
If the curve y = x + bx + c touches the straight line y = x at the point (1, 1), then b and c are given
by
(A) 1, 1
(B) 1, 2
(C) 2, 1
(D) 1, 1

19.

19.
Sol.

A
y = x touches y = x2 + bx + c
1=1+b+cb+c=0

(1)

dy
2x b (1, 1) 2 b 1 b 1 , c = 1.
dx
(b, c) = (1, 1).
20.

In the sequence 1, 2, 2, 3, 3, 3, 4, 4, 4, 4 ....... , where n consecutive terms have the value n, the
150th term is
(A) 17
(B) 16
(C) 18
(D) none of these

20.
Sol.

1, 22, 333, 4444,........


1 2 3 4 .......
when last time 16 will appear that will be

16 17
th
= 136 term
2

so after that 17 will repeat from 137th term to 153th term


Ans is 17

5 2n
, n N where {.} denotes the fractional part of x, is
24

21.

The value of
(A) 5/24

21.

24 1

(D) None of these

24
If z1 and z2 are two complex numbers satisfying the equation
which is
(A) Positive real
(C) Zero or purely imaginary

22.

(C) 1/24

Sol.

22.

(B) 9/24

z1 z 2
z
1 , then 1 is a number
z2
z1 z2

(B) Negative real


(D) None of these

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JEE-MAIN -SAMPLE TEST -1-PCM-25

Sol.

23.

z1
t 1
t,
1 t 1 t 1
z2
t 1
locus of t is line y axis

Let

The number of ways of switching the network such that the bulb glows is
(A) 61
(B) 60
(C) 63
(D) None of these

23.

Sol.

24.

If 2 sin .sec 3 = tan 3 -tan , then 2[sin .sec 3+sin 3.sec 32 +..+sin 3n 1 .sec 3n] =
1
(A) tan 3n -tan
(B) tan 3n -ntan
(C) tan 3n -tan 3n 1 (D) (tan 3n -tan )
2

24.
Sol.

A
2
2
Using method of difference, 2sin 3 sec 3 tan 3 tan 3 and so on.

25.

The determinate sin B

C0 3C1 3C2 3C3 3 1 3 1 1 3 61

cos C tan A
0
0
tan A has the value where A, B, C are angles of a triangle
0

(A) 0
25.
Sol.

sin B

cos C

(B) 1

(C) sinA. sinB

(D) cosA cosB cosC

A
Expand along the 1st row

cos C tan A sin B tan A sin B cos C


26.

The equation of the image of the circle x2 y 2 16 x 24 y 183 0 by the line mirror 4 x 7 y 13 0 is
(A) x2 y 2 32 x 4 y 235 0
(B) x2 y 2 32 x 4 y 235 0
(C) x2 y 2 32 x 4 y 235 0
(D) None of these

26.
Sol.

A
Radius will remain same, image of center (-8, 12) is (-16, -2) w.r.t. line 4 x 7 y 13 0

27.

For hyperbola

27.
Sol.

B
eccentricity = sec
so foci are constant

x2
y2

1, which of the following remains constant with change in ' ' ?


cos 2 sin 2
(A) abscissae of vertices
(B) abscissae of foci
(C) eccentricity
(D) directrix

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JEE-MAIN -SAMPLE TEST -1-PCM-26

sin x
,

If f x x
0,

28.

x 0
x 0

Where, [x] denotes the greatest integer less than or equal to x, then

lim f x equals:
x0

(A) 1
28.

(B) 0

(C) -1

(D) None of these

Sol.

sin x
,

f x x
0
,

lim f x 0

x 0
x 0

x 0

lim f x

x 0

29.

sin 1
sin1
1

For a real number y, let [y] denote the greatest integer less than or equal to y. Then the function

f x

tan x
2

1 x

is:

(A) discontinuous at some x


(B) continuous at all x, but the derivative f ' x does not exist for some x
(C) f ' x exists for all x, but the derivative f '' x does not exist for some x
(D) f '' x exists for all x
29.

Sol.

It is a zero function, f x 0

30.

1 (sin x)2 / 3
d(sin x)1/ 3 is equal to
4/3
1 (sin x)
2/ 3

sin x 2 / 3 1
1
tan1
c
2 sin x 1 / 3
2

(A)

1 sin x 1
c
1/ 3
2 2 sin x

(B)

(C)

sin x 1 / 3 1
1
tan1
c
2 sin x 2 / 3
2

(D) none of these

30.

Sol.

Let sin x

1/3

t d sin x 3 dt

1
d t
t
Using algebraic twins,
2
1
t

2
t
space for rough work

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