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78, 335356
Research Article
DOI: 10.2110/jsr.2008.039
ABSTRACT: Quartz-rich sedimentary rocks are commonly assumed to be the eroded products of cratons or recycled orogens.
However, active or eroded acidic volcanic regions can also be an important, but commonly overlooked, source of quartz.
Cenozoic sandstones from East Java, Indonesia, illustrate this point. They are rich in quartz, and it has long been assumed that
they are the product of erosion of a continental source. However, new work using a variety of provenance indicators shows that
the sandstones contain a significant, previously overlooked, volcanic component. A number of factors have contributed to their
character: quartz-rich source regions, eruptive volcanic processes, and tropical weathering. Ternary discriminant diagrams,
such as QFL plots which use the ratios of quartz, feldspars, and lithic grains to interpret provenance from cratonic, volcanic,
and recycled orogen hinterland, may mislead, particularly in tropical volcanic settings. The quartz from acidic volcanic sources
is commonly overlooked because it is commonly assumed that quartz has a continental crustal source. Volcanic eruptive
processes can lead to crystal enrichment in rapidly eroded ash and sediments. Intense chemical weathering can have
considerable impact on the composition of sedimentary rocks by selectively removing labile minerals and lithic grains. The
resulting deposits may be texturally immature but compositionally mature, and rich in resistant minerals such as quartz and
zircon. In tropical settings the widely held view that quartz-rich sandstones are mature sediments representing multiple phases
of recycling may in many cases be incorrect.
INTRODUCTION
the equatorial belt, as they were throughout the Cenozoic (Hall 2002).
Therefore, the influence of tropical weathering must be considered
because of its well-documented effects on sandstone composition (e.g.,
Dosseto et al. 2006; Suttner et al. 1981).
This paper briefly summarizes the characteristics that allow different
types of quartz to be distinguished, drawing on published literature (e.g.,
Ingersoll 1984; Basu et al. 1975; Bernet and Basset 2005; Gotte and
Richter 2006) and studies of quartz from different rock types in the region
(Table 1). The Cenozoic quartz-rich sandstones of East Java are then
described. This is followed by a discussion of potential continental,
metamorphic, volcanic, and sedimentary source areas with consideration
of transport mechanisms, transport distances, and paleogeographical
barriers.
BACKGROUND TO THE STUDY AREA, EAST JAVA, INDONESIA
1527-1404/08/078-335/$03.00
Miocene Southern
Mountains
Eocene Southern
Mountains
Setting
Id. Code
i
ii
iii
iv
vi
Type(s)
1 + 3
Jaten
Kresek
Cakaran,
Wungkal-Gamping
Sermo, ?Nanggulan?
Lukulo,
Karangsambung
Member, Formation
Latitude,
Longitude
Type Section
Early Miocene
Road cut near to 8.13847S,
19 6 1 Ma (zircon the village of
111.26913E
U-Pb SHRIMP)
Tulukan, Pacitan
District, East
Java Province
?Middle Eocene?
?Middle Eocene?
Middle Eocene
(NP16)
Probably Middle
Sermo Reservoir, 7.826S,
Eocene
Yogyakarta
110.108E
(, 56.1 Ma zircon
U-Pb SHRIMP)
Middle Eocene
(P10-11)
Age
Location Information
A series of
quartz-rich
sandstones and
muddy interbeds,
which overlie basal
polymict
conglomerates. Up
section the
sandstones become
increasingly arkosic.
Quartz-rich, yellow,
laminated,
occasionally
channelized
sandstones.
Interbedded with
organic-rich muds,
containing abundant
plant fragments.
Quartz-rich
sandstones and
conglomerates with
abundant plant
fragments and coal
interbeds.
Granular, yellow,
quartz-rich
sandstones
interbedded with
channelized
polymictic
conglomerates.
Crystal-rich quartz
sandstones with
tuffaceous interbeds.
Outcrop
Environment of
Deposition
Thinly laminated
Air fall deposition or
bands of euhedral and
epiclastic
bipyramidal volcanic quartz reworking of
crystals and shards.
volcanic deposits
on a shallow
marine shelf.
Sandstones are
Close to an active
dominated by volcanic
and/or eroding
quartz with pumice,
acidic volcanic
volcaniclithic fragments,
source in a
and plagioclase. Quartz
terrestrial setting
types include faceted
possibly on a
bipyramidal crystals,
floodplain or
skeletal or embayed,
mangrove swamp.
shards, and
Primary air fall and
microcrystalline
epiclastic
aggregates.
reworking.
Quartz arenites to
Terrestrial to deltaic.
sublitharenites rich in
Gradual increase in
metamorphic and volcanic material of
quartz. Abundant fresh
volcanic source up
laths of plagioclase, and
section.
volcanic lithic fragments.
Sublitharenites, composed Terrestrial setting.
of metamorphic and vein
No
quartz and lithic fragments contemporaneous
of chert, basalt, and schist. volcanic activity.
Dominated by
metamorphic and vein
quartz. These are
texturally and
compositionally mature
quartz arenites.
Description
TABLE 1.Description of the Cenozoic quartz-rich sandstones of East Java, Indonesia. Type 1 contain metamorphic quartz, Type 2 volcanic quartz, and Type 3 have a mixed-provenance metamorphic,
volcanic and recycled sedimentary quartz (van Bemmelen 1949; Sartono 1964; Sumarso 1975; Ardhana 1993; Lunt et al. 1998; Lelono 2000; Smyth 2005).
336
H.R. SMYTH ET AL.
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Lodan Quarry,
6.834272S,
Rembang Hills, 111.67713E
East Java
Middle Miocene
(N8-9)
viii
3
Miocene Shelf Edge
Ngrayong
vii
3
Miocene Kendeng
Depocentre
Lutut
Member, Formation
337
Setting
Location Information
TABLE 1. Continued.
Outcrop
Description
Environment of
Deposition
338
JSR
FIG. 1. Simplified geological map of East Java, showing the main geological subdivisions and stratigraphic units (adapted from Smyth 2005). Inset shows current
plate-tectonic setting and location of Sundaland.
1988; Johnsson et al. 1991; Suttner et al. 1981). The following section
provides an overview of some of the most important processes; the reader
is referred to the references cited for more detailed discussion.
Chemical Weathering
Sediment maturity is mainly acquired through chemical weathering, as
chemically unstable minerals are eliminated (e.g., Salano-Acosta and
Dutta 2005). Therefore, in most cases the daughter product of recycled
sandstone should be mineralogically more mature than its parent source
rock. In a few rare cases the daughter sediment may be mineralogically
less mature owing to the breakdown (physical or chemical) of lithic
fragments or large unstable grains (Friis 1978; Solano-Acosta and Dutta
2005). There are a number of important controls on rates of chemical
weathering, such as residence time, climate, and presence and thickness of
a soil profile. It is generally accepted that tropical climatic settings have
higher rates of chemical disaggregation of source rocks and the resultant
daughter sediment than high-latitude settings.
Topographic Relief and Single-Cycle Sediments
Johnsson et al. (1991) describe the impact that topographic relief can
have on the sediment produced by chemical weathering based on a case
study from the Orinoco River drainage basin. In this example, sediments
produced within areas of high, often steep, relief, such as orogenic
terranes or parts of the elevated shield, are not as compositionally mature
as sediments produced in areas of low, flat-lying topography. Johnsson et
al. (1991) explain this in terms of sediment residence time and
transportation efficiency. In the areas of high relief, sediment transpor-
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339
FIG. 2.Stratigraphy of East Java showing the distribution of quartz-rich sandstones (adapted from Smyth 2005); inset map shows the geographic locations. Codes (i
to viii) are explained in Table 2.
340
of the character of the erupted material and the sorting efficiency of the
eruption mechanism. Quartz-rich ash deposits formed by Plinian
eruptions may be abundant even at considerable distances from the
erupting volcano (e.g., Rose and Chesner 1987; Carey and Sigurdsson
2000). They are unstable and rapidly eroded (unwelded loose deposits
which commonly lack vegetation cover), and the non-quartzose material
is rapidly destroyed by weathering and transport. Thus, volcanism can
lead to the formation of quartz-rich sandstones during a single cycle by
providing a volumetrically significant source in a very short time.
It is clear that a number of processes could have contributed to the
formation of the tropical quartz-rich sandstones of East Java. However,
characteristics of the grains, such as shape, internal structure, and
alteration would be expected to be distinctive and aid discrimination
between them. In order to assess the sources and processes that formed
the sandstones it is therefore important to identify the types of quartz
they contain. The following section summarizes the basis for distinguishing different quartz types.
VARITIES OF QUARTZ
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equilibrium between the crystal and the melt (McPhie et al. 1993). As a
quartz phenocryst bearing magma rises, SiO2 solubility in the melt
increases as pressure decreases and quartz that was previously in
equilibrium with the melt is partially resorbed (McPhie et al. 1993).
Embayments are due to unstable growth, dissolution in the melt, or gas
bubble drilling, which is a reaction with the melt as gas bubbles
approach the crystal (Donaldson and Henderson 1988). Embayments are
distinguished by their rounded shape from etching caused by corrosive
formation waters or pitting because of transportation. Volcanic quartz
grains may also develop a skeletal shape if the crystal edges form first,
generating a framework or skeleton outline (Spry 1969); the faces between
the edges form more slowly and in some cases are infilled by other
minerals or can remain as voids.
Melt inclusions are diagnostic of a volcanic origin and can readily be
distinguished from fluid inclusions (Fig. 3C.9). Fluid inclusions are
commonly small, , 5 mm (Shepherd et al. 1985), and form strings
parallel to fractures within the grains. Melt inclusions, however, form at
the time of mineral growth, can be much larger, up to 200 mm (Shepherd
et al. 1985), and may be arranged along growing faces so that they are
parallel to zonation in the crystal.
Metamorphic Quartz
Quartz of metamorphic origin (Fig. 3D) has several diagnostic
characteristics including undulose extinction angles, healed fractures,
indistinct mottling under cathodoluminescence, strings of fluid inclusions
(often needle-like), and anhedral, sutured or irregular grain shapes and
contacts (Basu et al. 1975; Donaldson and Henderson 1988; Demars et al.
1996; Peppard et al. 2001; Boggs et al. 2002). Metamorphic quartz is more
commonly polycrystalline than plutonic quartz and the straining of the
lattice during metamorphism and deformation results in higher angles of
undulose extinction (. 5u) compared to plutonic quartz (Fig. 3D).
Impurities and abundant fluid inclusions may cause metamorphic quartz
to be milky white. Mortar texture, in which large strained quartz grains
are surrounded by finely crystalline new quartz (Spry 1969), is commonly
observed in quartz from metamorphic rocks. SEM-CL images of
metamorphic grains are commonly mottled or patchy (Table 2). Shearing
during metamorphism results in the alignment of crystal units and the
development of foliation in polycrystalline or composite quartz grains.
Pressure fringes, commonly composed of fibrous quartz, calcite, chlorite,
or muscovite, are abundant in low-grade metamorphic rocks, and their
shape is related to the original crystal around which they formed. Fringes
may resemble the ocellar texture common in volcanic rocks but are rarely
preserved after erosion and transportation (Spry 1969).
Hydrothermal Vein Quartz
Vein quartz commonly has a milky white color due to fluid inclusions
(e.g., Tucker 2001). The crystal faces may be clear but can be
distinguished from volcanic quartz by the abundance of fluid inclusions
341
and lack of concentric zoning. The crystals are in many cases elongate
and columnar, in as much as they grow from a fixed point, often a
fracture wall, into an open space or vug, a texture known as comb
structure (Spry 1969). Crystal terminations at either end of the column
are different, and if there is limited space within the fracture, the quartz
may form equant crystals.
Chert
Chert is cryptocrystalline or microcrystalline quartz formed either by
siliceous organisms such as radiolaria, diatoms, and sponges, or by
secondary replacement, usually of limestones (Adams et al. 1984). In
radiolarian and other biogenic cherts spherical and elongate skeletons can
sometimes be distinguished, which allows easy identification (Fig. 3E).
However, when the chert is fine grained or cryptocrystalline and does not
contain any visible biogenic structures, it may be difficult to determine the
original nature of the grain. When the chert forms as secondary
replacement, it commonly has a radial fibrous growth texture,
chalcedonic quartz (Adams et al. 1984), which may be very similar to
spherulites which form in devitrified siliceous volcanic glass (Fig. 3E, F).
The spherulites are radiating arrays of crystal fibers (McPhie et al.
1993), which consist of feldspar and quartz, and the staining of thin
sections for feldspar and examination using SEM can assist with the
distinction of from other varieties of quartz.
Recycled Sedimentary Quartz
Detrital quartz that has been through multiple cycles of erosion is
commonly rounded and pitted, and may have brown corrosion rims
(Fig. 3H). The grains usually lack the crystal faces common in hypabyssal
and volcanic quartz. They may have quartz overgrowths, or a fringe of
other minerals such as calcite. Fractures which formed during transportation are likely to be angular or irregular, and are open, in contrast to the
curved fractures which occur in volcanic quartz or the healed fractures in
plutonic quartz. Diagenetic quartz formed as overgrowths on grains may
contain fluid inclusions which are very small, , 5 mm (Shepherd et al.
1985), and are readily distinguishable from the much larger melt
inclusions found within volcanic quartz.
CHARACTER OF THE QUARTZ-RICH SANDSTONES OF EAST JAVA
The Eocene and Miocene quartz-rich sandstones from East Java in this
study plot within the recycled orogen field on a standard Dickinson
plot. They have been reexamined and subdivided on the basis of the types
of quartz that they contain (Tables 1, 3). Fine to coarse sandstones were
selected for point counting using the Gazzi-Dickinson method (Gazzi
1966; Dickinson 1970; Ingersoll et al. 1984), and the quartz types were
identified using the criteria discussed above. A minimum of 300 grains
were counted from each sample. Where the quartz variety could not be
determined the grains were assigned to an unknown category (up to 2%
R
FIG. 3.Characteristics of quartz types commonly found in sedimentary rocks. Examples selected from Sumatra and Java, Indonesia, Tasmania, and Luzon. The scale
bar is 1 mm unless stated otherwise. A) Plutonic: 1. Anhedral grain with melt inclusion, strings of fluid inclusions, and slightly undulose extinction. 2. Large late-stage
filling grain with healed fractures. 3. The individual crystals within this composite grain have variable size, orientation, and extinction. B) Hypabyssal: euhedral quartz
phenocrysts from a high level intrusion. C) Volcanic: 1. Top left and right sketches of bipyramidal quartz. Lower sketch, bipyramidal grain with additional trigonal faces
formed during cooling. 2. Photograph of a bipyramidal quartz. 3. SEM image of bipyramidal quartz. 4. Bipyramidal grains in a crystal-rich dacitic ash. 5. SEM image of
embayed quartz. 6. SEM-CL image showing concentric zoning within a large quartz phenocryst. 7. Ocelli texture and rounded fractures. 8. SEM image of a shard of
quartz. 9. Melt inclusions in quartz. D) Metamorphic and sheared: 1. Polycrystalline grains with numerous crystal units, and monocrystalline grains with undulose
extinction and strings of fluid inclusions. 2. Sheared quartz. E) Chert: 1. Radiolarian chert. 2. Authigenic chert with radial fibrous growth pattern. F) Volcanic sphericules
(McPhie et al. 1993) formed in devitrified siliceous volcanic glass. G) Volcanic quartz aggregates easily confused with chert in thin section. The grains in the
photomicrograph of the left appear chert-like, but examination under SEM on the right shows the grains are aggregates of bipyramidal quartz grains. H) Recycled
sedimentary: rounded grains, with etched surfaces and alteration halos. The grains contain numerous strings of fluid inclusions.
342
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343
Chert
Hydrothermal
Metamorphic
Volcanic
Plutonic
(Hypabyssal)
Plutonic
Quartz type
Colour
Polycrystalline
Undulosity is
weak, , 5u
Undulosity
Inclusions
Zoning
Fracture
SEM-CL textures
(and panchromatic
colors)
Symmetry
Other common
textures
Fluid
Well
Healed
Blue-red,
Randomly
Trigonal
Mineral inclusions,
inclusions developed fractures
may overlap oriented
melt reaction
common
with
microcracks or
textures,
volcanic
healed cracks
granophyric
are observed in
growth with
all types of
feldspar.
plutonic quartz.
Light gray CL.
Rare zoning.
weak, , 5u to
May be
Common Healed
Blue
Trigonal
Melt reaction, will
nonundulose
free
fractures
(potential
depend upon depth
from
preservation and cooling
inclusions
of hexagonal history.
symmetry)
Euhedral,
Clear
Microcrystalline
Commonly
Melt
Present
Curved
Blue
Concentric
Hexagonal
Skeletal grains, melt
monocrystalline,
aggregates may
nonundulose and inclusions
leading to
zoning is very
with possible reactions leading to
composite and
appear to be
clear. Grains
are
crackedcommon in
addition of rounding of crystal
aggregate grains also
polycrystalline
may have strong diagnostic
tile pattern
volcanic quartz. trigonal
faces, melt
present, as are shards
undulosity in
Homogeneous
faces during embayments,
with a distinctive
case of lattice
CL is also
cooling
ocellular texture
cuspate shape.
imperfection.
commonly
and bipyramidal
obseverd in
grain shape.
volcanic quartz.
CL light gray to
black.
Anhedral, sutured or
Milky white to . 3 crystal units
Undulosity is
Fluid
Absent
Angular
Blue-brown, Inhomogeneous
____
Mortar texture,
irregular.
translucent
per grain. Most
. 5u
inclusions
healed and may overlap patchy or
pressure fringes,
abundant in lowcommon,
open
with
mottled CL
foliations in
grade metamorphic
often
fractures
plutonic
polycrystalline and
rocks
needlecomposite grains.
like.
Euhedral
Milky white to
___
Undulose
Fluid
Not
May be
Variable in
Trigonal
Grains are commonly
translucent
inclusions concentric present
some case
elongate, comb
common
green
texture.
Commonly rounded or Variable
___
___
___
___
___
May be non- Black CL not
___
If radiolarian,
anhedral in form. The
luminescent easily identified
spherical and
quartz can be
using SEM-CL
elongate skeleton
cryptocrystalline,
may be visible.
microcrystalline, or
Radial fibrous
fibrous
growth. May be
confused with
volcanic
sphericules or
microcrystalline
aggregates of
bipyramidal
quartz.
Anhedral (space
Milky white to , 3 crystal units
filling) + euhedral.
translucent
per grain
Can be mono-,
polycrystalline, or
composite. Grain
boundaries generally
straighter than in
metamorphic rocks
Euhedral,
Clear
Not
monocrystalline grains
common
Grains
SEM-CL
colours
TABLE 2.Types of quartz found in sedimentary rocks and their distinguishing characteristics (Spry 1969; Basu et al. 1975; Leeder 1982; Adams et al. 1984; Roedder 1984; Shepherd et al. 1985;
Donaldson and Henderson 1988; McPhie et al. 1993; Demars et al. 1996; Seyedolali et al. 1997; Peppard et al. 2001; Boggs et al. 2002; Bernet and Bassett 2005).
344
H.R. SMYTH ET AL.
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Etching + surface
alteration is a
common feature of
recycled grains. Pits
can easily be
distinguished from
melt embayments.
___
Undulose with
Strings of Lost due to Commonly Variable, can Grain
variable angles
very small diagenetic seen and
be nonshattering
depending on
fluid
overprint are
luminescent
history
inclusions
angular or if diagenetic
, 5 mm
irregular
common
open
fractures
Rounded, pitted
Brown corrosion Depends on
overgrowths may be
rim
original source
observed. Lack of
preserved crystal faces.
345
of grains counted). In addition to thin-section analyses, SEM examination was used was used to identify unknown minerals and grain surface
textures. Additional analysis of polished thin sections by panchromatic
SEM-CL and back-scatter imaging was also undertaken which aided the
identification of grains by optical techniques.
There are three types of sandstone:
Recycled
sedimentary
Inclusions
Undulosity
Polycrystalline
Colour
Grains
Quartz type
TABLE 2. Continued.
Zoning
Fracture
SEM-CL
colours
SEM-CL textures
(and panchromatic
colors)
Symmetry
Other common
textures
N
N
Type 1: Quartz and other fractions (minerals, lithics, and matrix clays)
are almost entirely metamorphic.
Type 2: Quartz and other fractions are entirely volcanic.
Type 3: Quartz and other fractions have a mixed provenance. These
sandstones are essentially a mix of Types 1 and 2, with the addition of
varying volumes of recycled sedimentary and plutonic quartz. A
proportion of the plutonic quartz is considered to be hypabyssal.
346
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FIG. 4.Methods of distinguishing plutonic and metamorphic quartz. A) Classification of source by examining polycrystallinity and undulosity (redrawn from Basu et
al. 1975). B) Distribution of true angles of undulosity in detrital quartz from plutonic and low-rank metamorphic sources (redrawn from Basu et al. 1975).
grains with a clear volcanic origin are also present, and their abundance
increases up section from 14 to 35%. There are also some volcanic lithic
grains that contain quartz. CL imaging confirms that many of the quartz
grains are fragments of much larger zoned volcanic grains (Fig. 7G). In
addition to these quartz types plutonic and detrital grains with quartz
overgrowths have been identified using SEM-CL images, but these are
present only in the lowermost parts of the formation. The sandstones also
contain feldspar, predominantly fresh plagioclase with a small number of
altered microcline grains. Schists make up the majority of the lithic
grains; they are commonly small (, 0.5 mm) and well rounded.
Zircons are the most common heavy mineral. The zircon population
includes fresh euhedral grains, elongated prisms, and broken prisms with
sharp terminations. SHRIMP U-Pb dating of grains yielded ages of
41.7 6 1 Ma and 42 6 0.9 Ma (P.J. Hamilton, personal communication 2005), similar to the middle Eocene (49 to 37 Ma) biostratigraphic
age for the formation. The remaining zircon grains are anhedral and
rounded with some evidence of zoning; these grains yielded much older
U-Pb SHRIMP ages. This indicates reworking of some older igneous
material but shows that at least some of the volcanic material was erupted
contemporaneously.
The identification of quartz types and the other provenance techniques
indicate that the middle Eocene quartz-rich sandstones of the Southern
Mountains contain predominantly two types of material: an older
metamorphic component and a contemporaneous volcanic component.
There is a clear increase up section in the percentage of volcanic quartz as
metamorphic quartz decreases (Table 3, Fig. 8), indicating a change in
the sediment supply. In addition there is igneous and recycled
sedimentary material (average 31%).
Miocene Quartz-Rich Sandstones of the Kendeng Basin.The Miocene
quartz-rich sandstones of the Lutut Beds (vii), Semarang (Fig. 1), are not
shown on the geological map for the area (Thaden et al. 1975) because
they are exposed only in small outcrops. They are interpreted to have
been deposited on the southern margin of the Kendeng Basin, and have
subsequently been deformed and moved northwards to their present-day
position by thrusting (Smyth 2005).
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347
TABLE 3. Summary of the average percentages of each quartz type found within the quartz-rich sandstones of East Java.
ID
Sample
QFL
Q (% of QFL total)
F (% of QFL total)
L (% of QFL total)
Quartz counts QMNU nof
QMU nof
QM , 5%
QM . 5%
PC , 4
PC . 4
Chert
Volcanic*
Detrital
VolLithic
Metalithic
SedLithic
Unknown**
Number
Quartz types
Metamorphic
from optical, Volcanic
SEM, and
Recycled sedimentary
SEM-CL
Plutonic
imaging
Unknown
Quartz
Metamorphic
categories
Volcanic
chosen (%)
Recycled sedimentary and
plutonic
ID
Sample
QFL
Q (% of QFL total)
F (% of QFL total)
L (% of QFL total)
Quartz counts QMNU nof
optical (300 QMU nof
were possible) QM , 5%
QM . 5%
PC , 4
PC . 4
Chert
Volcanic*
Detrital
VolLithic
Metalithic
SedLithic
Unknown**
Quartz types
Metamorphic
from optical, Volcanic
SEM, and
Recycled sedimentary
SEM-CL
Plutonic
imaging
Unknown
Quartz
Metamorphic
categories
Volcanic
chosen (%)
Recycled sedimentary and
plutonic
I
Jhs2KK2
I
Jhs2KW1
I
Jhs2KW2
I
Jhs2KK38
71.0
4.1
24.9
5
0
6
101
5
57
49
3
3
0
70
1
0
300
76.0
2.7
17.7
3.7
0.0
76.0
2.7
21.3
77.5
6.9
15.6
2
0
1
93
5
59
86
3
11
0
9
31
0
300
53.7
1.7
42.7
2.0
0.0
53.7
1.7
44.7
44.1
39.9
16.0
2
0
0
110
4
92
73
0
3
1
7
8
0
300
69.7
1.0
28.0
1.3
0.0
69.7
1.0
29.3
68.9
7.6
23.5
26
0
13
7
6
1
2
59
0
34
2
1
0
151
6.6
78.8
2.0
12.6
0.0
6.6
78.8
14.6
87.4
3.8
8.8
12
1
15
114
10
54
4
0
7
0
83
0
0
300
84.0
4.0
3.7
8.3
0.0
84.0
4.0
12.0
81.1
8.7
10.9
31
0
11
46
7
96
60
11
13
2
6
17
0
300
49.3
14.7
30.0
6.0
0.0
49.3
14.7
36.0
56.5
19.7
23.8
57
2
39
111
11
22
16
14
5
1
20
2
0
300
51.7
24.0
7.7
16.7
0.0
51.7
24.0
24.3
54
19
23
39
0
56
42
7
13
12
35
35
31
19
11
0
300
24.7
35.0
19.3
21.0
0.0
24.7
35.0
40.3
78.5
0.5
21
1
0
1
37
4
122
65
0
10
0
19
41
0
300
59.3
0.3
38.7
1.7
0.0
59.3
0.3
40.3
VI
Jhs2Pac21
VII
Jhs2Lutut11
VIII
Jhs1-012
VIII
Jhs1-006
VIII
Jhs1-008
VIII
Jhs2Ngr5
82.5
10.5
7
2
0
0
0
0
7
0
219
0
69
0
0
0
2.4
97.6
0.0
0.0
0.0
2.4
97.6
0.0
64.6
0
35.4
22
0
10
99
16
47
26
13
9
10
20
28
0
55.3
15.0
21.0
8.7
0.0
55.3
15.0
29.7
83.2
13.1
3.7
64
3
61
74
12
10
2
16
17
0
4
1
0
34.5
30.3
7.6
27.7
0.0
34.5
30.3
35.2
81.7
10.1
8.2
19
1
14
59
34
82
9
22
37
0
16
7
0
52.7
13.7
17.7
16.0
0.0
52.7
13.7
33.7
96
1
2
53
1
20
77
20
60
9
9
33
0
15
3
0
51.0
20.7
15.0
13.3
0.0
51.0
20.7
28.3
95.5
2.2
2.3
29
0
35
42
14
81
9
12
32
0
30
16
0
51.0
13.7
19.0
16.3
0.0
51.0
13.7
35.3
IV
V
VI
Jhs2Pendul1 Jhs2Kresek Jhs2Pac17A
81.1
0.5
18.4
16
0
23
79
19
69
10
1
6
3
72
1
1
73.3
6.7
5.7
14.0
0.3
73.6
6.7
19.7
40.4
53.4
5.6
32
97
0
0
2
1
0
162
0
1
0
0
5
32.7
65.0
0.0
0.7
1.7
33.2
66.1
0.7
95
0
5
0
0
0
0
0
20
0
214
0
66
0
0
0
6.7
93.3
0.0
0.0
0.0
6.7
93.3
0.0
II
III
III
III
IV
Jhs2Sermo1 Jhs2NKS10 Jhs2NKS17 Jhs2NKS26 Jhs2JC5
Q (Quartz), F (feldspar), L (lithics), QMNU (quartz, monocrystalline, non-undulose extinction, no other features), QMU (quartz monocrystalline, undulose
extinction, no other features and angle of extinction cannot be measured), QM , 5% (quartz monocrystalline , 5% undulose extinction), QM . 5% (quartz
monocrystalline . 5% undulose extinction), QPC , 4 (quartz, polycrystalline , 4 crystal units), QPC . 4 (quartz, polycrystalline , 4 crystal units).
bioclastic, and abundant volcanic rocks (Fig. 7). The bioclastic lithic
clasts contain fragments of reworked Eocene and Oligocene fossils.
These sandstones contain three components: recycled Cenozoic
sedimentary rocks, fresh contemporaneous acid volcanic rocks, and
metamorphic rocks. These are the only quartz-rich sandstones on land in
East Java which contain clear evidence of reworking of older Cenozoic
sedimentary sequences (Smyth 2005).
348
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This study indicates that there were three main sources of quartz for the
Cenozoic quartz-rich sandstones of East Java: metamorphic rocks, acid
volcanic material, and recycled sedimentary rocks. There were also
contributions from plutonic sources.
Metamorphic Source Rocks
The most likely source areas of metamorphic material are the (1) Upper
Cretaceous and older basement of East Java and (2) basement rocks on
the edge of Sundaland such as those exposed in southeast Kalimantan
and along the Karimunjawa Arch (van Bemmelen 1949).
In East Java the basement rocks are observed only in small exposures
in the western part of the study area at Karangsambung and Jiwo
(Fig. 1). At these locations the lithologies exposed include mica and
quartz-mica schists, basalts, cherts, serpentinites, metasediments, and a
range of high pressure low temperature metamorphic rocks including
eclogites, garnet amphibolites, and jadeitequartzglaucophane rocks
(Wakita and Munasri 1994; Miyazaki et al. 1998). The rocks are thought
to be the metamorphosed equivalents of ophiolites and arc rocks (Wakita
and Munasri 1994; Miyazaki et al. 1998) accreted during Cretaceous
349
r
FIG. 5.Character of Type 1 quartz-rich sandstones. A) Photomicrograph of metamorphic grains from iv (Cakaran Member of the WungkalGamping Formation)
(scale: 1 mm). B) Photomicrograph showing metamorphic grains from basal i (Lukulo Member, Karangsambung Formation) (scale: 1 mm). C, D) BS (back scatter) and
CL images of polycrystalline grains (Cakaran Member of the WungkalGamping Formation) (scale: 200 mm). E) QFL plot showing the Type 1 sandstones. F) Triangular
plot showing metamorphic, volcanic, and recycled sedimentary and plutonic quartz of the Type 1 sandstones.
350
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351
Today, and throughout the Cenozoic, the source regions that provided
sediment to East Java were located close to the equator (Hall 2002) and as
r
FIG. 6.Character of Type 2 sandstones. A) Bipyramidal grain (scale: 1 mm). B) Photomicrograph showing poorly sorted sandstone of v (Kresek Member, Wungkal
Gamping Formation). Note the two large clear, euhedral grains in the top right of the image (scale each box: 1 mm). C) Photomicrograph showing melt embayments from
vi (Jaten Formation) (scale: 500 mm). D) Quartz shard (scale: 1 mm). E, F) SEM-BS and SEM-CL images of a grain showing melt embayments and concentric zoning
(Jaten Formation) (scale: 700 mm). G) QFL plot showing the Type 2 sandstones. H) Triangular plot showing metamorphic, volcanic, and recycled sedimentary and
plutonic quartz of the Type 2 sandstones.
352
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353
increase in quartz (Schulz and White 1999). This enrichment is the result
of the selective removal of kaolinite. Unconsolidated volcanic deposits
and sediments which are subject to tropical weathering are expected to
break down much more rapidly than in lithified sediments or in granitic
rocks.
Tropical Weathering
Discriminant Diagrams
r
FIG. 7.Character of Type 3 sandstones. A) Photomicrograph showing a bipyramidal quartz grain in the center bottom left (scale: 1 mm). B) Photomicrograph of the
angular, clear quartz grains and opaque mineral grains (scale: 500 mm). C) Elongate volcanic zircons from viii (Ngrayong Formation) (scale: 100 mm). D) Quartz lithics
from the vii (Lutut Formation) (scale: 1 mm). E) Weathered volcanic lithics from vii (Lutut Formation) (scale: 1 mm). F, G) SEM-BS and SEM-CL images of a quartz
grain exhibiting incomplete concentric zoning, indicating that it is a fragment of a much larger grain (200 mm) (Nanggulan Formation). H) QFL plot showing the Type 3
sandstones. I) Triangular plot showing metamorphic, volcanic, and recycled sedimentary and plutonic quartz of the Type 3 sandstones.
354
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information from Indonesia, despite the size and the high sediment yields
of this region at present (e.g., Milliman and Syvitski 1992; Milliman et al.
1999), and its importance as a region of abundant volcanic and tectonic
activity throughout the Cenozoic (e.g., Hall and Smyth 2008). The
abundance of volcanic quartz in East Java suggests that more data are
needed from tectonically and volcanically active tropical regions such as
Indonesia, and that discriminant plots should be considered in the light of
climate at the time the sediment was eroded and deposited, as well as the
present day.
CONCLUSIONS
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