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Rate of mass
output from the
=
++
controlled
volume at time,
t+t
Rate of mass
input into the
controlled
volume at time,
t+t
Rate of mass
disappearance +due
to
chemical
reaction
in
controlled
volume at time,
t+t
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Rate of mass
accumulation
within
the
controlled
volume
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Mt = Mt+t + t( )Tr+ t( )P + t( )S
(1)
Where: Mt = Mass in volume element at the beginning of time t., M t+t = Mass in
volume element at the end of time t+t., ( )Tr= change in volume element by
process and ( )S= change in volume element by sources (e.g waste load, river
discharges).
Changes by transport include both advective and dispersive transport.
Equation (1) can be rearranged as;
| |+
= ( )Tr + ( )p + ( )s
(2)
Model Formulation
Model for Transport of Contaminant
To model the transport of contaminant (pollutant) over a space, a water system is
divided in small segment or volume elements. Each volume elements is defined by its
volume and its dimensions in one, two or three directions (x, y, and z) depending
on the nature of the schematization (1D, 2D, or 3D).
Advective Transport
The advective transport, 0
( ) of a constituent at site x0 is the product of the
average water velocity, 0 ( ), at that site, the surface or cross sectional area A (2 ),
through which advection takes place at the site and the average concentration ( 3 )
of the constituent.
0
= 0 0
(3)
Dispersive Transport
The dispersive transport, 0
( ), across a surface area is assumed to be proportional
0
=0 y=y0
(4)
Dispersion is done according to Ficks Law of diffusion. The minus sign originate from
the fact that dispersion causes net transport from higher to lower concentrations and
so in opposite direction of the concentration gradient. The concentration gradient is
the difference of concentration per unit length over a very small distance across the
cross section.
+
x= lim0
(5)
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(7)
= Ay0 Vy0 Cy0 Ay0+y Vy0+y Cy0+y + Dy0+y Ay0+y 0+ Dy0 Ay0 0 0 ( )p
+ ( )s
(8)
Assuming a zero order reaction for the rate of change of volume element by physical,
biochemical or biological process, and also knocking out the term for the rate of
change in volume element by sources, gives
| |+
= Ay0 Vy0 Cy0 Ay0+y Vy0+y Cy0+y + Dy0+y Ay0+y 0+ Dy0 Ay0 0 0 kp
(9)
Where kp is the rate constant due to chemical reaction.
Expressing eqn. (9) in terms of concentration and dividing throughout by the
elemental volume ((V=Ay), result in a one dimensional equation as shown below
| |+
0+
0+
0 0 0+ 0+
kp
(10)
= ( ) (VC) kp
(11)
Clearing the negative sign on the L.H.S and opening the bracket gives,
2
2
+ kp
(12)
0 = 2 + V + kp
2
If we let 2 = 2 ,
(13)
= ,
(14)
Suction pipe
Meter rule
Soil
environment
Fig.2a: Experimental
contaminant in water
Contaminate
Water
environment
Set-up to investigate
environment.
the
diffusion
process
of effluent
Sample Collection
Five water samples were collected from stagnant water in the neighborhood of the
Asphalt Company Nigeria Limited located at Enito 3, a village located between Ahoada
and Mbiama in Ahoada West Local Government Area of River State. The study
distance is about 65metres from the company and samples were collected on a weekly
basis. The analysis of the sample covers the following parameters: pH, Hardness and
Conductivity. Samples were collected with the aid of a capillary tube and the depth at
which each samples were collected is determined using a meter rule. Thereafter,
samples were transported to the research laboratory of the department of chemical
science, Niger Delta University for onward analysis.
Materials: TDS/Turbidity meter, Burette and Pipettes, Beaker 10ml and 250ml,
volumetric flask 50, 100, 250ml and 500ml
Determination of Nitrate (NO3)
The wagtech water kit was used to determine the anions namely NO3 , NO2 , SO4 and
chlorides.
The appropriate tablet is grinded and dissolved in 10ml sample. Left to stand for ten
minutes (10min) and read at the appropriate wavelength on the wagtech
spectrophotometer 5000. The reading is read from a table supplied by the company.
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15
30
45
60
WHO
Parameters
units
Standard
Nitrate (NO3)
mg/L
0.218
0.289
0.236
0.307
0.226
10.0
Sulfate(SO4)
mg/L
5.36
5.70
4.65
7.54
4.38
250
NO3-(Experimented)
NO3-(Theoretical)
NO3-(Validated)
0.00
0.22
0.23
0.25
15.00
0.29
0.27
0.25
30.00
0.24
0.28
0.25
45.00
0.31
0.27
0.25
60.00
0.23
0.24
0.25
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SO4-(Experimented)
SO4-(Theoretical)
SO4-(Validated)
0.00
5.36
5.11
5.55
15.00
5.70
5.76
5.55
30.00
4.65
5.96
5.55
45.00
7.54
5.74
5.55
60.00
4.38
5.07
5.55
0.35
0.30
y = 0.000x + 0.248
R = 0.018
0.25
0.20
NO3-
0.15
Linear (NO3-)
0.10
0.05
0.00
0.00
10.00
20.00
30.00
40.00
50.00
60.00
70.00
NO3-(Experimented)
NO3-(Theoritical)
NO3-(Validated)
0.15
0.10
0.05
0.00
0.00
20.00
40.00
60.00
80.00
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Theoretical,
and
Validated
Nitrate
(NO3-)
Figure 4 is the relationship obtained for the experimental, theoretical, and validated
model. The relationship presents a good match which indicates the reliability of the
developed model when compared with the experimental model. Points of intersection
were obtained for the three models at various concentrations such as 0.25mg/l.
8.00
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00
y = -0.000x + 5.55
R = 0.000
SO4
Linear (SO4)
0.00
10.00
20.00
30.00
40.00
50.00
60.00
70.00
SO4-(Experimented)
SO4-(Theoritical)
SO4-(Validated)
0.00
20.00
40.00
60.00
80.00
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