Downloaded From www.rejinpaul.com Reg. No. ; I Question Paper Code : 77103 B.EB.Tech. DEGREE EXAMINATION, APRIL/MAY 2015. First Semester Civil Engineering CY 6151 — ENGINEERING cauestetee, (Common to all branches except Marine < (Regulation 2013) C NX : ' ‘Time : Three hours Y Maximum : 100 marks Answor ALL me’ PART A — (100220 fiprks) oY 1.” What is the finetionality ofteypPrytewé (b) Phenol towards polymerisation? 2 Define polvdisnersity inde? eX 3. What happens to exttropy of the following? (@) A gaseous nitrog@t is converted to liquid nitrogen. () Solid jodive is Sublimed to its vapour. 4. CalcigaenPWe, otropy change iuveivel im conferting oneliie! water at 373 Kito its vapour at the same temperature. (Molar heat of vaporisation of waters 40.66 kd k mole»). a \ State Stark-Binstein law of photochemistry. 6) “eatin the possible electronic transitions that can occur in organic molecules. 7. What do you understand by reduced phase rule? 8 What is hardening of etee!? Mention its purpose. 9. Mention the difference between a nanorod and a nanowire, 10. | Write any two applications of carbon nanotubes. . © ee Grow With Usi 12. 12. as tans @ @ Gi) ® @ @® @ @ @ di) o® @ @ Pea) mL wo @ @) Downloaded From www.rejinpaul.com PART B— ( x 16 = 80 marks) Explain the mechanism of polymerization through free radicals. (8) What aro tho different typos of molocular mass of polymers? Explain each type with significance. ® Or a What are the differences between thermoplastic << ‘thermosetting polymers? 8) ‘Explain the following : wt (1) Emulsion polymerisation. ‘~ 4) (@): Bellution poleaiattecn —y ey ; Derive Gibb's ~Helmholtz equations, ® Define free encrgy. Explain ite signigcinde ON At what temperature will waved ic 528 mm He? Latont hodt oA o # Y AY Derive glen (any four) ® j ey ce AG? =-RT In Ke, Caloulate the standard entropy, change for the reaction, A == B, if the value of al = 28.4 kJ/mol and equilibrium constant is 1.8 x 107 at 298 K. ® shen the atmospheric pressure jsation of water is 545.5 cal/g. (4) Explain the instramentation of a uv-visible spectrophotometer. (8) What is quantum efficiency? How is it determined? ® or Explain the following : (2) Flourescence. (4) (@) Phospherescence. w State Lambert - Beer Law. Derive its mathematical form. What are ite limitations? (24442) 2 rN oo. Grow With Us14. @) (o) (a) ©) Gi) @ @) @ Gi) @ a Downloaded From www.rejinpaul.com Apply phase rule to water system and explain the characteristics. (8) What are the purposes of alloy making? Illustrate with suitable examples. ara Or Discuss the phase diagram of silver-lead system and explain the eutectic mixture, characteristics and uses. Re alloys: (1) Brass € : wat (2) Bronze bs e AY ON What are the properties that change frémts bullk form to nano size form? Explain each with example. (8) Give the composition and applications (two each) of the co (4x (3) Nichrome (4) Stainless steel. Explain chemical ae my technique of synthesis of nano particles. ®@ Diseuss the ao and laser ablation methods of synthesis of nano mat ® Comparedho properties of molecules, narioparticles and bulk materials. ® \ @ Grow With Us rejingiel.com