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Strea

m
Numb
er
1

Temperature
Justification

Pressure Justification

25

15

Assumed pipeline
delivers gaseous
feed at ambient
temperature.

Literature suggested
pipeline pressure in this
area between 10-100 bar

400

14.2
5

Literature suggested
desulfurization unit
works at a range
between 300 and
550
Journal article based
on experimental
results suggested
approximate
complete conversion
of 400 ( )
Exothermic reaction
therefore
temperature
increased.

403

12.8
3

403

12.8
3

403

28.4
2

Assumed adiabatic
reactor where Q=0,
goal seek.
Temperature =
stream 3
Assume temperature
increase is
negligible.
Assume more than
one compressor
gives a smaller T
increase.

500

27

Adiabatic
compression
calculation
suggested a
temperature leaving
the compressor of
525. Need to look
into whether or not
we need E102.
Temperature will

Dr Dupont
The unit is not affected by
pressure.
5% pressure drop was
assumed across the HX.

10% pressure drop across


major units.

Assumed 10% pressure


drop caused by splitter.
Pressure increases
following compressor.
Assuming a 5% drop
across HX unit and that 27
bar was the required
condition for the reformer,
this value was calculated.

Required Pressure.

195

14

8
9

228
800

27
27

10

350

25.6
5

increase to reaction
temperature in the
reactor using the
heat released in the
burner.
Steam tables.
Elementary
Principles book ()
Steam Tables.
Required reformer
condition.
Reduced to
temperature of HT
shift unit.
350 is the ideal
temperature, low
enough to favor the
direction of the
products at a high
enough rate. (Kinetic
and thermodynamic
condition).

IP steam pressure found


onsite
Required Pressure.
Required reformer
condition.
Journal Article
(Ratnasamy).
Suggested pressure of 2030.
Pressure drop across heat
exchanger.

Hydrogen fuel
production transport
and storage. 340360.
Catalyst, IronChromium based
catalyst. Suggested
from literature.
Calculated Kp= 21.2
11

472

23.0
9

12

250

21.9
3

Exothermic reaction
in HT reactor.
Q=0 Goal seek
method.
250 required for LT
shift reactor.
Decreasing T
increases Kp and
therefore CO
conversion
increases. (Graph,
Demirel. E 2012)

10% pressure drop across


large unit.
5% pressure drop.

Calculated Kp=237
13

259

19.7
4

14

50

17.7
6

15

50

17.7
6

16

25

10

17

25

170

18

25

10

19

25

20

403

21
22

?
25

12.8
3
?
6

23

24

800

27

25

Exothermic reaction.
Q=0 Goal seek
method.
Use a series of
condenser units that
decrease the T to 50;
the ideal conditions
of the PSA.
Other outlet stream
producing water (l)
at same conditions.
PSA produces
product at ambient
T.
Intercooler after
each compressor
which counteracts
temperature
increase caused by
increase in pressure.
Without intercoolerAdiabatic
compression
calculation suggests
T=679K.
Ambient
Temperature.
Ambient
Temperature.
Temperature =
stream 3
Assume Ambient T
air flow feed.
Required reformer
condition.

10% pressure drop.


10% pressure drop

Dr Dupont

Dr Dupont
Assumed 10% pressure
drop across pump.
Assume pressure drop of
5%.
Available pipeline feed of 6
bar.
Available pipeline feed of 6
bar.
Required reformer
condition.

Conversion Justifications:
PSA
Desulfurization: <90% Karim H. Hassan. Journal. 2008
All other units, calculated using kp calculations.