Jiara Laine Montao

21
Experiment no. 5: %NaOH and Dichromate
24 2016

June

Sample Calculations
1. Volume of HCl dispensed
Volume dispensed=final readinginitial reading
34.75 mL0.00 mL

34.75

mL

2. Buret Correction
y=0.0014 x0.0673, 25 mL x 35 mL
y=0.0008 x +0.0087, 35 mL< x 45 mL

Buret CorrectionPart I
0.0014(34.75)0.0673

0.0014 x0.0673

0.01865 mL
3. Corrected Volume
Corrected Volume=Volume dispensed + Buret correction
34.75 mL0.01865 mL

34.73135 mL = 0.03473135 L

4. Moles HCl
Since the HCl, utilized in the experiment has previously been
standardized in experiment 4 the value of the Molarity of HCl as
been determined to be 0.092528308 M. Thus from the formula below
the moles of HCl can now be determined.
mol
Moles HCl
Molarity HCl(
)=
L
Volume HCl ( L)
Molarity HCl

0.092528308

( molL ) x Volume HCl ( L )=Moles HCl

mol
[ 0.03473135 L ]=Moles HCl
L

0.003213633 moles=Moles HCl

5. Weight / Volume NaOH
The following equation has to be taken into account before
calculating for the moles of sodium hydroxide:
Equation A.
HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l).
From this equation we can see that there is a 1:1 stoichiometric
ratio between HCl and NaOH. Thus, we can say that the number of

moles of HCl is equivalent to the number of moles of NaOH.

Therefore,
Moles HCl=M ol es NaOH=0.003213 633 moles
To determine the wt/vol of NaOH, the moles of NaOH must first be
converted to mass. This is done by using the formula:
39.9971 g NaOH
Mass NaOH =Moles NaOH MW NaOH (
)
1 mole NaOH
Mass NaOH =0.003213633 moles NaOH

g NaOH
( 39.9971
1 mole NaOH )

Mass NaOH =0.1285360

Now that the mass of NaOH is determined. The wt/vol can now be
calculated by using the formula:
Wt g NaOH
=
=
Vol mL soln
Wt
=
Vol

g NaOH
25.1211 mL
Pipetted Volume
250. mL

0.1285360 g NaOH
25.1211 mL
25.1211 mL
250.mL

Wt
g
=0 .050919894
Vol
mL

6. Moles of HCl for Na2CO3

In part II, both NaOH and Na2CO3 are considered to be reacting with
HCl titrated. Thus, the moles HCl that reacted with the moles NaOH
must be removed to determine the moles of HCl that actually
reacted with Na2CO3.
Moles for Na2 CO3=moles HClMean moles of HCl for NaOH
Moles for Na2 CO3=0.004124266 moles HCl0.0031300009 moles
M oles for Na2 CO3=0.000994257 moles HCl
7. Weight/Volume Na2CO3
The following equation has to be taken into account before
calculating for the moles of sodium hydroxide:
Equation B.
2HCl(aq) + Na2CO3(aq) 2NaCl(aq) + H2O(l) + CO2(g)
From this equation we can see that there is a 1:2 stoichiometric
ratio between HCl and NaOH. Thus, we can say that the for every
mole of sodium carbonate there are two moles of HCl. Hence, half
the value of moles of HCl is equivalent to the number of moles of
Na2CO3. Therefore,
1 Moles HCl=2 Moles Na 2 CO 3

1
Moles HCl=Moles Na2 CO 3
2
0.00099 4257
=0 .0004971 28=Moles Na2 CO3
2
To determine the wt/vol of Na2CO3, the moles of Na2CO3 must first be
converted to mass. This is done by using the formula:
105.988 g Na2 CO 3
Mass Na2 CO3=Moles Na2 CO3 MW Na CO (
)
1 mole Na2 CO 3
2

Mass Na2 CO3=0.000497128 =moles Na2 CO3

105.988 g Na2 CO3

1 mole Na2 CO3

Mass Na2 CO3=0.05268 9644

Now that the mass of Na2CO3 is determined. The wt/vol can now be
calculated by using the formula:
0.052689644 g Na2 CO 3
Wt g Na2 CO3
=
=
Vol
mL soln
25.1211 mL
Pipetted Volume
250. mL
Wt
=
Vol

0 .052689644 g NaOH
25.1211 mL
25.1211 mL
250.mL

Wt
g
=0 .02087 315
Vol
mL

8. Mean Percent Wt/vol

xi
Average =

0.02087 315 +0.02029086 +0.02145544

3

0.020873149

9. Standard Deviation
2

x iave .

s=

2
2
2
( 0.0 2087 315 0.02087 3149 ) + ( 0.0 2029 0860.02087 3149 ) + ( 0.0 2145 5440.02087 3149 )

2
0.000582288

10.

Percent Relative Standard Deviation

s
RSD=
100
average

0.000582288
100
0.02087 3149
2. 78965 =2.8

Data and Results

Run

Corr Vol
Pipet (mL)

1
2
3
4

25.1211
25.1211
25.1211
25.1211

Initial
Volume
(mL)
0
0.01
0
5.8

Final
Volume
(mL)
34.75
34.7
33.65
38.1

Buret
Correction
(mL)
-0.01865
-0.018734
-0.02019
-0.02208

Molarity
HCl (M)
0.092528308
0.092528308
0.092528308
0.092528308

Table 1 Experimental Data from the First Part / Titration of the Experiment

Ru
n
1

Volume
Dispense
d (L)
0.0347313
5

0.0346712
66

0.0336298
1

0.0322779
2

Corr Vol
(mL)

Moles
HCl

Moles
NaOH

0.003213

0.00321363

633

0.03467126

0.003208

0.00320807

074

0.003111

0.00311170

709

0.002986

0.00298662

621

0.03473135

0.03362981
0.03227792

Mass
NaOH (g)

Weight/Vol
(g/mL)

0.128536002

0.050919894

0.12831364

0.050831805

0.124459353

0.049304918

0.119456192

0.047322902

Table 2 Derived Data from the First Part / Titration of the Experiment

Mean Wt/Vol:

0.04959488

Run

Corr Vol
Pipet (mL)

Initial
Volume
(mL)

Final
Volume
(mL)

Buret
Correction
(mL)

25.1211

44.6

25.1211

44.3

25.1211

44.9

Molarity
HCl (M)

0.0925283
08
0.0925283
-0.02674
08
0.0925283
-0.02722
08
Standard Deviation:
0.001686377 = 0.0017
-0.02698

Relative Standard
Deviation: 3.40 =3.4

Table 3 Experimental Data from the Second Part / Titration of the Experiment

Ru
n

Volume
Dispens
ed (L)

0.2311

0.2088

0.2109

Corr Vol
(mL)
0.04457
302

0.04427
326

0.04487
278

Moles
HCl
0.00412
4266
0.00409
653
0.00415
2002

Moles
HCl for
Na2CO3
0.000994

0.000497

Mass
Na2CO
3 (g)
0.05268

257

0.02087314

128

9644

0.000966

0.000483

0.05121

0.02029086

52

26

9787

0.0010219

0.000510

0.05415

0.02145543

93

997

9501

Moles
Na2CO3

Weight/V
ol (g/mL)

Table 4 Derived Data from the Second Part / Titration of the Experiment

Mean Wt/Vol:
0.020873149

Standard Deviation:
0.000582288 = 0.00058

Relative Standard
Deviation: 2.78965 =
2.8