Gas State

Level 1
Q No: 1
Three flasks of equal volumes contain CH 4, CO2 and Cl2 gases respectively. They will
contain equal number of molecules if (1) the mass of all the gases is same
(2) the moles of all the gas is same but temperature is different
(3) temperature and pressure of all the flasks are same
(4) temperature, pressure and masses same in the flasks
Correct Answer: 3 Status: unattempted
[X]
Avogadro's Law
Otherwise think in terms of n =
Avogadro's Law : "At same condition of temperature and pressure, equal volumes of
different gases contains equal number of molecules."
Q No: 2
At 0C, the density of a gaseous oxide at 2 bar is same as that of nitrogen at 5 bar. What
is the molecular mass of the oxide ?
(1) 70
(2) 210
(3) 35
(4) 52
[X]
Solve for unknown M
Q No: 3
8.2 L of an ideal gas weight 9.0 gm at 300 K and 1 atm pressure. The molecular mass of
gas is(1) 9
(2) 27
(3) 54
(4) 81
[X]
Ideal gas equation
Q No: 4
A gas 'A' having molecular weight 4 diffuses thrice as fast as the gas B. The molecular
weight of gas B is(1) 36
(2) 12
(3) 18
(4) 24
[X]
rA = 3 r B
Grahams Law of effusion or diffusion
Q No: 5
Equal volumes of two gases A and B diffuse through a porous pot in 20 and 10 seconds
respectively. If the molar mass of A be 80, find the molar mass of B.
(1) 80 g mol1
(2) 20 g mol1
(3) 40 g mol1
(4) 160 g mol1
Correct Answer: 2
Status: unattempted
[X]
t1 = t2 (same time interval)
Q No: 6
Which is not correct in terms of kinetic theory of gases(1) Gases are made up of small particles called molecules
(2) The molecules are in random motion
(3) When molecules collide, they lose energy
(4) When the gas is heated, the molecules moves faster
Kinetic Theory of Gases's postulates
Elastic collisions.
According to K.T.G., collision of gaseous molecules is elastic collision.
Q No: 7
The average speed of an ideal gas molecule at 27C is 0.3 m sec1. Calculate average
speed at 927C.
(1) 0.15 m/sec
(2) 1.2 m/sec
(3) 2.4 m/sec
(4) 0.6 m/sec
[X]
Q No: 8
Critical temperature of the gas is the temperature(1) Below which it cannot be liquified
(2) Above which it cannot be liquified
(3) At which it occupies 22.4 L of volume
(4) At which one mole of it occupies volume of 22.4 L
Definition of Critical temp.
Critical Temperature (TC) : The temperature above which liquification of gas cannot take
place however high pressure is applied on it.
NA
Q No: 9
The compressibility factor for an ideal gas is :
(1) 1.5
(2) 1.0
(3) 2.0
For ideal gas PV = nRT
PV = nRT for ideal gas
Q No: 10
(4)
One litre of an unknown gas weighs 1.25 gm at N.T.P. which of the following gas
pertains to the above data (1) CO2
(2) NO2
(3) N2
(4) O2
[X]
N.T.P. (22.4 L
1 mole gas)
M.W. (weight of 22.4 L)
Decide from options.
Weight of 1 L gas at N.T.P. = 1.25 g.
M.W. = weight of 22.4 L = 1.25 22.4

= 28 g.
from option N2 (M.W. = 28)
Q No: 11
V versus T curves at constant pressure P1 and P2 for an ideal gas are shown in fig. Which
is correct -
(1) P1 > P2
(2) P1 < P2
(3) P1 = P2
(4) All
Correct Answer: 2
Status: unattempted
Higher slope, lower pressure.

Otherwise at same temperature
Higher volume Lower pressure (from Boyle's Law)
Q No: 12
If a gas is expanded at constant temperature(1) Number of molecules of the gas decreases
(2) The kinetic energy of the molecule decreases
(3) The kinetic energy of the molecules remains the same
(4) The kinetic energy of the molecules increases
Kinetic Energy is function of temperature only for ideal gas
K.E. of a gas is function of temperature only.

Q No: 13
A box of 1L capacity is divided into two equal compartments by a thin partition which
are filled with 2g H2 and 16gm CH4 respectively. The pressure in each compartment is
recorded as P atm. The total pressure when partition is removed will be (1) P
(2) 2P
(3) P/2
(4) P/4
Does by opening door between two rooms, pressure of each room becomes 2 atm? or remains
1 atm?
after removing partition pressure will be same in both sides.

NA
Q No: 14
Helium atom is twice times heavier than a hydrogen molecule. At 25C the average K.E.
of helium atom is (1) Twice that of hydrogen
(2) Same as that of hydrogen
(3) Four times that of hydrogen
(4) Half that of hydrogen
K.E. of gas does not depends upon M.W.

K.E. of gas function of temperature only
Q No: 15
Which of the following molecule has the lowest average speed at 273 K ?
(1) CO
(2) CH4
(3) CO2
(4) C2H6
Choose higher M.W. from options.
Q No: 16
A real gas is expected to exhibit maximum deviations from ideal gas laws at (1) Low T and High P
(2) Low T and Low P
(3) High T and High P
(4) High T and Low P
At high temperature force of attraction deceases i.e. 'a' becomes very small.
At low pressure, molecular volumes becomes insignificant i.e.
b << v
Real gas at high temperature, low pressure
At high temperature and low pressure real gases behaves as ideal gas.
Q No: 17
Which of the following expressions between the van der Waals constant b and the radius
r of spherical molecules is correct (1)
(2)
(3)
(4)
Correct Answer: 4
b = 4 NAV
Status: unattempted
Volume of sphere
b = 4 NAV Volume of one molecule
= 4. NA
Q No: 18
The units of the van der Waal's constant 'b' are (1) atmosphere
(2) joules
(3) L mol1
(4) mol L1
Dimensional analysis
In addition or subtraction of two Quantity dimensions must be same.
Dimension of V and nb are same
(V nb)
unit of b = (L mole1)
Q No: 19
At 100 C a gas has 1 atm. pressure and 10 L volume. Its volume at NTP would be (1) 10 litres
(2) Less than 10 litres
(3) More than 10 litres
(4) None
Charle's Law
Compare T1 and T2.
At 100C (= 373 K) V = 10 L
at cont P V T
at 273 k
V < 10 L.
Level 2
[X]
Avogadro's Law
Otherwise think in terms of n =
Avogadro's Law : "At same condition of temperature and pressure, equal volumes of
different gases contains equal number of molecules."
Level 2
Q No: 1
An open flask containing air is heated from 300 K to 500 K. What percentage of air will
be escaped to the atmosphere, if pressure is kept constant ?
(1) 80
(2) 40
(3) 60
(4) 20
Open vessel heating
Apply n1T1 = n2T2
P,V const.
Q No: 2
Pressure of gas contained in a closed vessel is increased by 0.4%, when heated by 1C.
Calculate its final temperature. Assume ideal nature.
(1) 251 K
(2) 502 K
(3) 250 K
(4) 400 K
[X]
If P1 = P then P2 = 1.004 P
Q No: 3
A rigid container containing 5 mole H2 gas at same pressure and temperature. The gas
has been allowed to escape by simple process from the container due to which pressure
of the gas becomes half of its initial pressure and temperature become (2/3) rd of its
intitial. The mass of gas remaining is :
(1) 7.5 g
(2) 1.5 g
(3) 2.5 g
(4) 3.5 g
[X]
Write initial and final n, T and P in appropriate terms.
Convert mole into mass
No: 4
821 mL N2(g) was collected over liquid water at 300 K and 1 atm. If vapour pressure of
H2O is 30 torr then moles of N2(g) in moist gas mixture is :
(1) 0.39
(2) 0.032
(3) 0.96
(4) 0.0013
[X]
Use partial pressure of N2 only
Q No: 5
Equal masses of SO2, CH4 and O2 are mixed in empty container at 298 K, when total
pressure is 2.1 atm. The partial pressures of CH4 in the mixture is (1) 0.5 atm
(2) 0.75 atm

(3) 1.2 atm
(4) 0.6 atm
Correct Answer: 3
Status: unattempted
cv
Q No: 6
At what temperature will average speed of the molecules of the second member of the
series CnH2n be the same of Cl2 at 627C ?
(1) 259.4 K
(2) 400 K
(3) 532.4 K
(4) None of these
[X]
Q No: 7
Compressibility factor(Z) for N2 at 50C and 800 atm pressure is 1.95 Calculate mole of
N2 gas required to fill a gas cylinder of 100 L capacity under the given conditions.
(1) 2.24 103
(2) 22.4
(3) 44.8
(4) 2296
[X]
Convert all terms in approperiate units

Determine moles.
8. The behaviour of a real gas is usually depicted by plotting compressibility factor Z

versus P at a constant temperature. At high temperature and high pressure, Z is
usually more than one This fact can be explained by van der Walls' equation when :
1
The constant a is negligible and not b
)
2
The constant b is negligible and not a
)
3 Both the constant a and b are negligible
)
4
Both the constants a and b are not negligible
)
Write vander wall's equations (for 1 mole)
at high pressure a/v2 << P
Z=
Q No: 9
What will be the pressure exerted by a mixture of 3.2 g of methane and 4.4 g of carbon
dioxide contained in a 9 dm3 flask at 27C ?
(1) 8.31 104 bar
(2) 8.31 104 Pa
(3) 8.31 106 Pa
(4) 4.15 104 Pa
alton's Law of Partial Pressure
nT = nA + nB
Ideal gas equation (PV = nRT)
Q No: 10
The root mean square velocity of hydrogen is

temperature of the gas, then :
(1)
(2)
(3)
(4)
Correct Answer: 3
times than that of nitrogen. If T is the
Status: unattempted
[X]
Take ratio of Vr.m.s. of H2 to N2

Obtain relationship in
Q No: 11
Calculate relative rate of effusion of O 2 to CH4 through a container containing O2 and
CH4 in 3 : 2 mass ratio.
(1)
(2)
(3)
(4) none of these
Convert mass ratio to mole ratio
Take mole ratio = Pressure ratio
Use graham's Law of diffusion
No: 12
Calculate the number of moles of gas present in the container of volume 10 L at 300 K.
If the manometer containing glycerin shows 5 m difference in level as shown diagram.
(Given : dglycrin = 2.72 g/mL; dmercury = 13.6 g/mL)
(1) 0.94 mole

(2) 0.49 mole
(3) 0.64 mole
(4) none of these
Determine Pressure in terms of Height of mercury column.
haag = hbbg
Determine Pressure of gas and use ideal gas equation
haag = hbbg
(5) (2.72) = (h) (13.6)
Q No: 13
At what temperature will most probable speed of the molecules of the second member of
homologous series CnH2n2 be the same as that of SO2 at 527C.
(1) 500C
(2) 727C
(3) 227C
(4) None of these
Correct Answer: 3
Status: unattempted
Q No: 14
Two flask A and B of equal volumes maintained at temperature 300 K and 700 K contain
equal mass of He(g) and N2(g) respectively. What is the ratio of total translational kinetic
energy of gas in flask A to that of flask B ?
(1) 1 : 3
(2) 3 : 1
(3) 3 : 49
(4) None of these
Q No: 15
4 gm of sulphur dioxide gas diffuses from a container in 8 min. Mass of helium gas
diffusing from the same container over the same time interval is :
(1) 0.5 gm
(2) 1 gm
(3) 2 gm
(4) None of these
[X]
Convert moles of He to mass.
Q No: 16
Two closed vessel A and B of equal volume of 8.21 L are connected by a narrow tube of
negligible volume with open valve. The left hand side container is found to contain 3
mole CO2 and 2 mole of He at 400 K, what is the partial pressure of He in vessel B at
500 K ?
(1) 2.4 atm

(2) 8 atm
(3) 12 atm
(4) none of these
[X]
Use ideal gas equation.
Q No: 17
Two flasks X and Y have capacity 1L and 2L respectively and each of them contains 1
mole of a gas. The temperature of the flask are so adjusted that average speed of
molecules in X is twice as those in Y. The pressure in flask X would be (1) Same as that in Y
(2) Half of that in Y
(3) Twice of that in Y
(4) 8 times of that in Y
Q No: 18
Temperature at which most probable speed of O2 becomes equal to root mean square
speed of N2 is [Given : N2 at 427C]
(1) 732 K
(2) 1200 K
(3) 927 K
(4) 800 K
[X]
Equate these two
Q No: 19
The density of gas A is twice that of B at the same temperature the molecular weight of
gas B is thrice that of A. The ratio of pressure of gas A and gas B will be
(1) 1 : 6
(2) 7 : 8
(3) 6 : 1
(4) 1 : 4
Take ratio of dA and dB from hint (1).
Q No: 20
Compressibility factor (z) for real gas at very high pressure is
(1)
(2) 1
(3)
1+
(4)
1
Correct Answer: 3
Status: unattempted
Write vander waals equation for 1 mole

At high P
P >>
Z=
Q No: 21
At 0C and 1 atm pressure, volume occupied by one mole of a gas is greater than 22.4L.
Compressibility factor (z) for the gas is
(1) greater than 1
(2) less than 1
(3) equal to 1
(4) can be greater or less than on
For ideal gas PVm = RT

Zreal < Zideal
Compare (Vm)real and (Vm)ideal.
For ideal at 0C and 1 atm Vm = 22.4 L
for real gas if Z > 1, Vm > 22.4 L. if Z < 1, Vm < 22.4 L
Level 3
Q No: 1
A mixture of hydrogen and helium is prepared such that the number of wall collisions
per unit time by molecules of each gas is the same. Which gas has the higher
concentration?
(1) He
(2) H2
(3) Both
(4) None of these
Number of molecuels colliding at wall/time =
NA
Q No: 2
For a gaseous reaction,
2A(g) 3B(g) + C(g)
Whose extent of dissociation depends on temperature is performed in a closed container,
it is known that extent of dissociation of A is different in different temperature range.
With in a temperature range it is constant. (Temperature range T0 T1, T1 T2, T2 T).
A plot of P v/s T is drawn under the given condition.
Given : tan55 = 1.42, tan50 = 1.19, tan60 = 1.73
If
(1)
(2)
(3)
(4)
is the degree of dissociation of A then in the temperature range Ti Ti + 1
Correct Answer: 1
Status: unattempted
V = constant P Vs T is straight line and passes from origin.

tan = n (Number of moles)
Q No: 3
For a gaseous reaction,
2A(g) 3B(g) + C(g)
Whose extent of dissociation depends on temperature is performed in a closed container,
it is known that extent of dissociation of A is different in different temperature range.
With in a temperature range it is constant. (Temperature range T0 T1, T1 T2, T2 T).
A plot of P v/s T is drawn under the given condition.
Given : tan55 = 1.42, tan50 = 1.19, tan60 = 1.73
If initially 1 mole of A is taken in a 0.0821 l container then [R = 0.0821 atm lit/k]

(1)
(2)
(3)
(4)
Correct Answer: 1,3 Status: unattempted
tan 50 = 1.19 = 1 +
= 0.19
tan 55 = 1 +
1.42 = 1 + ; = 0.42.
NA
Q No: 4
Select the correct option(s) for an ideal gas
(1) Most probable speed increases with increase in temperature
(2) Fraction of particles moving with most probable speed increases with increase in
temperature
(3) Fraction of particles moving with most probable speed are more for Cl 2 than H2
under similar condition of T, P & V.
(4) Most probable speed is more for Cl2 than H2 at same temperature
Correct Answer: 1,3 Status: unattempted
Q No: 5
For two gases A and B, P v/s V isotherms are drawn at T K as shown. T A & TB are
critical temperatures of A & B respectively
Which of following is true?

(1) TA < T < TB
(2) TA > T > TB
(3) TA > TB > T
(4) none of above
[X]
Experiment Temp > TC then gas cannot be liquified.
TA > T < TB
NA
Q No: 6
For two gases A and B, P v/s V isotherms are drawn at T K as shown. T A & TB are
critical temperatures of A & B respectively
The correct statement(s) is/are

(I) Pressure correction term will be more negligible for gas B at T K.
(II) The curve for gas 'B' will be of same shape as for gas A if T > TB
(III) Gas 'A' will show same P v/s V curve as of gas 'B' if T > TA
(1) III only
(2) II and III
(3) II only
(4) All
Correct Answer: 3
Status: unattempted
If a = 0 then attraction is zero so gas can not be liquified.

T > (TC)B so gas show that graph.
TA is critical point of A and above TC gas can not be liquified.
Q No: 7
On the recently discovered 10th planet it has been found that the gases follow the
relationship PeV/2 = nCT where C is constant other notation are as usual (V in lit., P in
atm and T in Kelvin). A curve is plotted between P and V at 500 K & 2 moles of gas as
shown in figure
The value of constant C is

(1) 0.01
(2) 0.001
(3) 0.005
(4) 0.002
Applying PeV/2 = nCT.
NA
Q No: 8
shown in figure
Find the slope of the curve plotted between P Vs T for closed container of volume 2 lit.
having same moles of gas
(1)
(2) 2000 e
(3) 500 e
(4)
Correct Answer: 4
Status: unattempted
NA
NA
Q No: 9
shown in figure
If a closed container of volume 200 lit. of O2 gas (ideal gas) at 1 atm & 200 K is taken to
planet. Find the pressure of oxygen gas at the planet at 821 K in same container
(1)
(2)
(3) 1 atm
(4) 2 atm
Correct Answer: 1
Status: unattempted
NA
NA
Q No: 10
The molar volume of He at 10.1325 MPa and 273 K is 0.011075 of its molar volume at
101.325 KPa at 273 K.Calculate the radius of helium atom. The gas is assumed to show
real gas nature. Neglect the value of a for He.
(1) r = 1.33 108 cm
(2) r = 2.33 108 cm
(3) r = 1.33 106 cm
(4) r = 5.23 103 cm
For He a = 0
NA
Q No: 11
Sign of initial slope of compressibility factor (z) versus P curves is ________ if a gas is
below its Boyle's temperature and ________ if it is above its Boyle's temperature.
(1) +ive, +ive
(2) ive, +ive
(3) ive, ive
(4) +ive, ive
For He a = 0
NA
Q No: 12
A commercial cylinder contains 6.91 m3 of O2 at 15 M Pa and 21C. the critical
constants for O2 are TC = 126C, PC = 50 bar. Determine the reduced pressure and
reduced temperature for O2 under these conditions.
(1) PR = 3, TR = 2
(2) PR = 2, TR = 3
(3) PR = 5, TR = 2
(4) PR = 3, TR = 5
[X]
Put in the same unit.

NA
Q No: 13
Calculate the number of moles of gas present in the container of volume 10 lit at 300 K.
If the manometer containing glycerin shows 5m difference in level as shown in diagram.
Given : dglycerin = 2.72 gm/ml, dmercury = 13.6 gm/ml.
(1) 0.94 mole

(2) 0.93 mole
(3) 0.84 mole
(4) 0.90 mole
eight is determine for glycerin.
h1d1 = h2d2
hHg = 1M = 100 cm
Q No: 14
A manometer attached to a flask contains NH 3 gas have no difference in mercury level
initially as shown in diagram. After the sparking into the flask, it have difference of 19
cm in mercury level in two columns. Calculate % dissociation of ammonia.
(1) 21%
Correct Answer: 4
P1M1 = P2M2
76 17 = 95 M2
M2 = 13.6
Q No: 15
(2) 22%
Status: unattempted
(3) 24%
(4) 25%
1.0 102 kg of hydrogen and 6.4 102 kg of oxygen are contained in a 10 103 m3
flask at 473 K. Calculate the total pressure of the mixture. If a spark ignities the mixture.
What will be the final pressure.
(1) Ptotal = 27.54 105 N/m2, Pfinal = 19.66 105 N/m2
NA
Q No: 16
Calculate relative rate of effusion of SO2 to CH4 under given condition
(i) Under similar condition of pressure & temperature
(ii) Through a container containing SO2 and CH4 in 3 : 2 mass ratio
(iii) If the mixture obtained by effusing out a mixture
three effusing steps.
(1)
(i) ; (ii) ; (iii)
(2)
(i) ; (ii) ; (iii)
(3)
(i) ; (ii) ; (iii)
(4) None of these
for
Q No: 17
Find the number of diffusion steps required to separate the isotopic mixture initially
containing some amount of H2 gas and 1 mol of D2 gas in a container of 3 lit capacity
maintained at 24.6 atm & 27 C to the final mass ratio
(1) 1
(2) 2
(3) 3
X Number of effusion steps
.
(4) 4
Q No: 18
Calculate the fraction of N2 molecules at 101.325 kPa and 300 K whose speeds are in the
range of ump 0.005 ump to ump + 0.005 ump.
(1) 8.303 103
(2) 7.303 103
(3) 8.501 103
(4) 5.323 103
U2 U1 = Ump + 0.005Ump Ump + 0.005Ump = 0.01 Ump

f = 0.01
0.01 Ump
Q No: 19
One mole of an ideal gas is subjected to a process in which P (in atm) =

V (in Litre).
If the process is operating from a initial pressure 1 atm to final pressure 10 atm (no
higher pressure achieved during the process) then what would be the maximum
temperature obtained & at what instant will it occur in the process.
(1) 10,000 K
(2) 20,000 K
(3) 15,000 K
(4) 19,000 K
Moles remains constant.
NA

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Level 1

Solve for unknown M

t1 = t2 (same time interval)

PV = nRT for ideal gas

M.W. = weight of 22.4 L = 1.25 22.4

Higher slope, lower pressure.

Kinetic Energy is function of temperature only for ideal gas

K.E. of a gas is function of temperature only.

after removing partition pressure will be same in both sides.

K.E. of gas does not depends upon M.W.

Choose higher M.W. from options.

Convert mole into mass

Use partial pressure of N2 only

(2) 0.75 atm

Convert all terms in approperiate units

8. The behaviour of a real gas is usually depicted by plotting compressibility factor Z

The root mean square velocity of hydrogen is

times than that of nitrogen. If T is the

Take ratio of Vr.m.s. of H2 to N2

(1) 0.94 mole

Convert moles of He to mass.

(1) 2.4 atm

Use ideal gas equation.

Equate these two

Take ratio of dA and dB from hint (1).

Write vander waals equation for 1 mole

For ideal gas PVm = RT

Number of molecuels colliding at wall/time =

is the degree of dissociation of A then in the temperature range Ti Ti + 1

V = constant P Vs T is straight line and passes from origin.

If initially 1 mole of A is taken in a 0.0821 l container then [R = 0.0821 atm lit/k]

Which of following is true?

The correct statement(s) is/are

If a = 0 then attraction is zero so gas can not be liquified.

The value of constant C is

Applying PeV/2 = nCT.

Put in the same unit.

(1) 0.94 mole

X Number of effusion steps

U2 U1 = Ump + 0.005Ump Ump + 0.005Ump = 0.01 Ump

One mole of an ideal gas is subjected to a process in which P (in atm) =

Moles remains constant.

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