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  • Acetic Acid Production Process (Ct-Aceticatm) - Technology - Chiyoda Corporation

    Загружено:

    Fauzi Abdilah
    207 просмотров2 страницы
    The CT-ACETICATM process developed by Chiyoda Corporation produces acetic acid through the carbonylation of methanol. It uses a unique resin-supported rhodium catalyst and bubble column loop reactors. The resin support increases the catalyst quantity in the reactor, reduces rhodium loss, and decreases water usage and refining costs. The bubble column loop reactor efficiently contacts the three phases of gas, liquid, and solid catalyst while allowing for easy temperature control and reducing catalyst erosion.

    Исходное описание:

    acetic acid

    Оригинальное название

    Acetic Acid Production Process (Ct-Aceticatm) _ Technology _ Chiyoda Corporation

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    The CT-ACETICATM process developed by Chiyoda Corporation produces acetic acid through the carbonylation of methanol. It uses a unique resin-supported rhodium catalyst and bubble column loop reactors. The resin support increases the catalyst quantity in the reactor, reduces rhodium loss, and decreases water usage and refining costs. The bubble column loop reactor efficiently contacts the three phases of gas, liquid, and solid catalyst while allowing for easy temperature control and reducing catalyst erosion.

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    © All Rights Reserved
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    207 просмотров2 страницы

    Acetic Acid Production Process (Ct-Aceticatm) - Technology - Chiyoda Corporation

    Загружено:

    Fauzi Abdilah
    The CT-ACETICATM process developed by Chiyoda Corporation produces acetic acid through the carbonylation of methanol. It uses a unique resin-supported rhodium catalyst and bubble column loop reactors. The resin support increases the catalyst quantity in the reactor, reduces rhodium loss, and decreases water usage and refining costs. The bubble column loop reactor efficiently contacts the three phases of gas, liquid, and solid catalyst while allowing for easy temperature control and reducing catalyst erosion.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    из 2

    1/24/2017 AceticAcidProductionProcess(CTACETICATM)|Technology|CHIYODACORPORATION

    AceticAcidProductionProcess(CTACETICATM)

    TheCTACETICATMPROCESS,developedbyChiyodaCorporation,isaprocesstoproduceaceticacidby
    carbonylationofmethanol.Withauniquelineoftechnologiesincludinghighperformanceresin
    supportedrhodiumcatalystsandbubblecolumnloopreactors,TheCTACETICATMPROCESSstands
    outfromothersimilarprocesses.

    1.HighPerformanceResinSupportedRhodiumCatalyst

    Rhodiumcomplexisusedasacatalystforthecarbonylationreactionofmethanol.Conventionally,
    dissolvingtheRhcomplexinthereactorrequireslargequantitiesofwater.Consequently,theenergy
    requirementforseparationofwaterfromAceticacidproductalsogoesup.Toovercomethoseproblems,
    ChiyodaCorporationhasdevelopedathermostablevinylpyridineresinwhichcansupporttherhodium
    complex.
    Fixingtherhodiumcomplexcatalysttothevinylpyridineresinexhibitsthefollowingadvantages:

    Withoutthesolubilitylimitations,thequantityofcatalystinthereactorcanberaisedto
    enhancethespacetimeyield(STY)ofthecarbonylationreaction.

    Thelossofrhodiumbyprecipitationindistillationsectioncanbereduced,sincetheresin
    supportedrhodiumcatalystremainsinthereactor.

    Sincetheamountofwaterisreducedtoaminimumlevelasrequiredforthereaction,the
    refiningcostoftheproductaceticaciddecreases,inadditiontoreducedbyproductformation.

    2.BubbleColumnLoopReactorTechnology

    CTACETICATMPROCESSadoptsabubblecolumnloopreactordesignedforeffectiveusageofresin
    catalysts.Asthecarbonmonoxidereactantgasisintroducedanddispersedatthebottomofthe
    reactor,smallbubblesareformed.Thesebubblesefficientlycontactandreactwithmethanolandresin

    https://www.chiyodacorp.com/technology/en/gtl/acetica.html 1/2
    1/24/2017 AceticAcidProductionProcess(CTACETICATM)|Technology|CHIYODACORPORATION
    catalystsastheyrisethroughthereactor.
    Thebubblecolumnloopreactorhasthefollowingfeatures:

    Highcontactefficiencyamongthethreephases:gas,liquidandsolid

    Astherearenorotatingelements,highairtightnessisachieved.Resinerosionisalsoreduced.

    Reactionheatiseasilyremovedbyinstallingaheatexchanger,therebyachievingamoreprecise
    controlofreactiontemperature.

    https://www.chiyodacorp.com/technology/en/gtl/acetica.html 2/2

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