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(a) pressure, volume, temperature using the expression W pex dV . The work can also be calculated
Vt
(b) temperature, amount, pressure
from the pV plot by using the area under the curve within the
(c) amount, volume, temperature
specified limits. When an ideal gas is compressed
(d) pressure, volume, temperature, amount (a) reversibly or (b) irreversibly from volume Vi to Vf .choose the
4. The volume of gas is reduced to half from its original volume. The correct option.
specific heat will be ______. (a) w (reversible) = w (irreversible)
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(b) w (reversible) < w (irreversible) (a) is always negative (b) is always positive
(c) w (reversible) > w (irreversible) (c) may be positive or negative (d) is never negative
(d) w (reversible) = w (irreversible) + pex. V
13. Enthalpy of sublimation of a substance is equal to
9. The entropy change can be calculated by using the expression S =
(a) enthalpy of fusion + enthalpy of vapourisation
qrev/T. When water freezes in a glass beaker, choose the correct
statement amongst the following : (b) enthalpy of fusion (c) enthalpy of vapourisation
(a) S (system) decreases but S (surroundings) remains the (d) twice the enthalpy of vapourisation
(b) S (system) increases but S (surroundings) decreases. (a) G is zero for a reversible reaction
(c) S (system) decreases but S (surroundings) increases. (b) G is positive for a spontaneous reaction
(d) S (system) decreases and S (surroundings) also decreases. (c) G is negative for a spontaneous reaction
10. On the basis of thermochemical equations (a), (b) and (c), find out (d) G is positive for a non-spontaneous reaction
which of the algebric relationships given in options (i) to (iv) is 15. Thermodynamics mainly deals with
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Cp [H2O(l)] = 75.3 J mol-1 K-1
Cp [H2O(s)] = 36.8 J mol-1 K-1
(a) -6.415 KJ (b) -5.145 KJ (c) -7.258 KJ (d) -8.753 KJ
29. Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol-1.
Calculate the heat released upon formation of 35.2 g of CO2 from
carbon and dioxygen gas.
(a) -485 KJ (b) -753 KJ (c) -315 KJ (d) -951 KJ
30. Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are MATHS
-110, 393, 81 and 9.7 kJ mol-1respectively. Find the value of rH
Time : 1 Hour M.M.120
for the reaction: N2O4(g) + 3CO(g) ! N2O(g) + 3CO2(g)
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(a) -576 KJ (b) -778 KJ (c) -856 KJ (d) -475 KJ
Point & Straight line ,Circle, & Binomal
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CHEMISTRY 1. The intercept made by a line on y-axis is double to the intercept
Q. 1 2 3 4 5 6 7 8 9 made by it on x-axis. If it passes through (1, 2) then its equation
10 A. C C D C C B C B -
C C (a) 2x + y = 4 (b) 2x + y + 4 = 0
Q. 11 12 13 14 15 16 17 18 (c) 2x y = 4 (d) 2x y + 4 = 0
19 20 2. Orthocentre of the triangle whose sides are given by 4x 7y +
A. C C A B AB AB CD CD B 10 = 0, x + y 5 = 0 & 7x + 4y 15 = 0 is -
C (a) ( 1, 2) (b) (1, 2) (c) ( 1, 2) (d) (1, 2)
3. If the point (5, 2) bisects the intercept of a line between the
Q. 21 22 23 24 25 26 27 28
axes, then its equation is -
29 30
(a) 5x + 2y = 20 (b) 2x + 5y = 20 (c) 5x 2y = 20 (d) 2x 5y =
A. B C A D A B D A C
20
B 4 Equation of the line passing through the point (1, 1) and
perpendicular to the line 2x 3y = 5 is
(a) 3x + 2y 1 = 0 (b) 2x + 3y +
1=0
(c) 3x + 2y 3 = 0 (d) 3x + 2y +
(17) 'Satyam ', 1 1th Pal Road, N ear 1 2th Road C ircle (18) 'Satyam ', 1 1th Pal Road, N ear 1 2th Road C ircle
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