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Carbon Dioxide
Section 1. Identification
GHS product identifier : Carbon Dioxide
Chemical name : Carbon dioxide
Other means of : Carbonic, Carbon Dioxide, Carbonic Anhydride, R744, Carbon Dioxide USP
identification
Product use : Synthetic/Analytical chemistry.
Synonym : Carbonic, Carbon Dioxide, Carbonic Anhydride, R744, Carbon Dioxide USP
SDS # : 001013
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 1/11
Carbon Dioxide
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 2/11
Carbon Dioxide
Specific hazards arising : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst or explode.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 3/11
Carbon Dioxide
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Keep container tightly closed and sealed until
ready for use. Cylinders should be stored upright, with valve protection cap in place,
and firmly secured to prevent falling or being knocked over. Cylinder temperatures
should not exceed 52 C (125 F).
Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 4/11
Carbon Dioxide
Odor : Odorless.
Odor threshold : Not available.
pH : Not available.
Flash point : [Product does not sustain combustion.]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : 830 (psig)
Vapor density : 1.53 (Air = 1) Liquid Density@BP: Solid density = 97.5 lb/ft3 (1562 kg/m3)
Specific Volume (ft /lb) 3
: 8.7719
Gas Density (lb/ft ) 3
: 0.114
Relative density : Not applicable.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : 0.83
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
SADT : Not available.
Viscosity : Not applicable.
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 5/11
Carbon Dioxide
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 6/11
Carbon Dioxide
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Carbon Dioxide 0.83 - low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 7/11
Carbon Dioxide
Packing group - - - - -
Environment No. No. No. No. No.
Additional Limited quantity Product classified as - - Passenger and Cargo
Yes. per the following AircraftQuantity
information sections of the limitation: 75 kg
Packaging instruction Transportation of Cargo Aircraft Only
Passenger aircraft Dangerous Goods Quantity limitation: 150
Quantity limitation: 75 Regulations: 2.13-2.17 kg
kg (Class 2).
Passenger Carrying
Road or Rail Index
75
Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.
Special precautions for user : Transport within users premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 8/11
Carbon Dioxide
State regulations
Massachusetts : This material is listed.
New York : This material is not listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
California Prop. 65
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
Carbon dioxide No. No. No. No.
International regulations
International lists
National inventory
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.
Japan : This material is listed or exempted.
Malaysia : Not determined.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.
Republic of Korea : This material is listed or exempted.
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 9/11
Carbon Dioxide
Flammability 0
Physical hazards 3
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
0 Flammability
Health 2 0 Instability/Reactivity
SA
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
Press. Gas Liq. Gas, H280 Expert judgment
History
Date of printing : 2/11/2016
Date of issue/Date of : 2/11/2016
revision
Date of previous issue : No previous validation
Version : 0.01
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 10/11
Carbon Dioxide
Date of issue/Date of revision : 2/11/2016 Date of previous issue : No previous validation Version : 0.01 11/11