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SKEMA PEMARKAHAN KERTAS 2

NO SCHEMES MARKS
1.a. i. (solid drawing) 2
ii.

70

61
25

-correct curve 1
-label 1
iii. molecule 1
b. i.Total no of proton and neutron in the nucleus of an atom 1
ii.12 1
iii.2.8.6 1
iv. -Q and R 1
-it have same proton no which is 16 1
2.a Zinc (any reactive metal) and hydrochloric acid ( any strong acid) 2
b To dry H2 gas 1
c
Cu O
Mass/g 1.92 0.48
Mole 0.03 0.03 1
Ratio 1 1 1

Empirical formula of copper(II) oxide is CuO 1

d Repeat process of heating, cooling and weighing until constant mass 1


is obtain
e i. No 1
ii. Mg is more reactive than H 1
3.a A > B (mark on diagram) 1
b To allow the movements of ions 1
c i. Colourless to reddish brown 1
ii. 2 I- I2 + 2e 1
iii. oxidation 1
d i. +3 to +2 1
ii. Test with excess sodium hydroxide solution 1
e i. Purple to colourless 1
ii. MnO4= -1
Mn + 4 (-2) = -1 1
Mn = -1 +8 = +7 1
4.a i. Mg + 2HCl MgCl2 + H2 1
ii. -correct axis and label 1
-correct data 1
-correct shape 1
iii. average rate of reaction = 96cm3/ 270 s = 0.356cm3s-1 2
b i. -Exp I use bigger size of reactants while Exp II use small size of 1
reactants
-the smaller the size of reactants, the larger the total surface area of 1
reactants that collide with each other
-frequency of collision between particles increase, frequency of 1
effective collision between particles also increase, thus rate of
reaction for Exp II is higher than I.

ii. use higher concentration of HCl/ use higher temperature 1


5.a Heat change when 1 mole of water is formed when 1 mole of acid 1
and alkali is reacted.
b i. H = mc
= (100) (4.2) (13) 1
= 5460 J 1

ii.n=(2)(50) / 1000 =0.1 mole 1

iii. Heat = (5.46kJ)/0.1 mol x 1 = 54.6 kJmol-1


heat of neutralization= -54.6 kJmol-1 1
c -correct shape + label (exothermic) 1
-correct equation and H 1
d -NaOH is a strong alkali that ionize completely in water to form OH- 1
while NH3 is a weak alkali that ionize partially in water to form OH- 1
- some heat is used to dissociate NH3 molecule, thus heat of
neutralization become low
6.a -correct label 1
-functional diagram 1
b C6H13OH + 9O2 6CO2 + 7H2O
-correct reactants and products 1
-balanced equations 1
c i. H = (200) (4.2) (31) = 26040 J 1
ii. n= 0.002 mole 1
iii. Heat = 13000 kJmol-1 1
Heat of combustion = - 13000 kJmol-1 1
iv. -correct shape + label (exothermic) 1
-correct equation and H 1
d Use copper can/ use wind shield 1
7.a Speed of reactants convert into products 1
b i. 15cm3min-1 1
ii. 22.5 cm3min-1 1
iii. 7.5 cm3min-1 1
c i. CaCO3 + H2SO4 CaSO4 + CO2 +H2O
-correct reactants and products 1
-balanced equations 1

ii. n (CaCO3) = 0.002 mol


1
1 mole CaCO3 = 1mol CO2
n = 0.002 mol CO2
1
1
volume CO2 at s.t.p = 0.0448 dm3 1
d i. -rate of reaction Exp II is higher than Exp I 1
- Exp II use higher concentration of sulphuric acid than Exp I 1
-the higher the concentration of acids, the more the volume per unit H + 1
- the more the collision between particles, 1
- the higher the effective collision berween particles, the higher the rate of
1
reactions

ii. -rate of reaction Exp I is higher than Exp III 1


- Exp I use higher temperature than Exp III 1
-the higher the temperature, the higher the kinetic energy between particles 1
- the more the collision between particles, 1
- the higher the effective collision berween particles, the higher the rate of 1
reactions
8. a X=2.4 1
Y=2.6 1
Z=2.8.1 1
b i. Covalent compound 1
ii.Ionic compound 1
c i.- X have valence electron 4 and it need to share 4 electron to achieve octet 1
electron arrangement
-Y have valence electron 6 and it need to accept 2 electron to achieve octet 1
electron arrangement
- 1 atom X share its valence electron with 2 atom Y to form XY 2 1+1
- drawing 1

ii. Z have 1 valenece electron and it need to donate 1 electron to achieve 1


octet electron arrangement
- Y have valence electron 6 and it need to accept 2 electron to achieve octet 1
electron arrangement
- 2 atom Z donate 1 electron to 1 atom Y to form Z2Y 1+1
-drawing 1
d -It cannot conduct electricity in molten and aqueous state 1
-It exist as molecule and does not have free moving ions 1
- It has low melting points 1
- It have weak Van der Waals forces 1
- Low heat energy required to overcome the forces of attraction between 1
particle
9.a heat change when 1 mole of metal is displace from its salt solution by more 2
electropositive metal.
b -magnesium is more electropositive than zinc 1
-the more the electropositive the metal that displace a metal from its salt
solution 1
-the more the heat release and the higher the heat of displacement
1
c Substances: 50 cm3 1.0 moldm-3 of copper (II) sulphate solution, zinc 2
powder
and magnesium powder 2
Materials: polystyrene cup, thermomether, measuring cylinder, spatula

Procedures: 1
1. Measure 25 cm3 1.0 moldm-3 of copper (II) sulphate solution by 1
measuring cylinder and pour into polystyrene cups 1
2. Measure the initial temperature of the solutions 1
3. Add zinc powder using spatula into the polystyrene cup 1
4. Stir using thermometer and record the final temperature. 1
5. Step 1-4 is repeated by replacing zinc powder with magnesium powder 1
7.All the data are recorded

Calculations:
1
H = mc
= (25) (4.2) ()
=x J
1
n=(1)(25) / 1000 =0.025 mole
1
Heat = H kJ /0.025 x 1 = y kJmol-1
1
Heat of displacement = - y kJmol-1

10.a Is a chemical reaction where oxidation and reduction that occur 1


simultaneously
b Oxidation = hydrogen 1
Reason = it obtain oxygen 1
Reduction = CuO 1
Reason = it loss oxygen 1
c Substances: Nail, Magnesium strip, Copper strip, Zinc strip, Jelly 2
solution containing potassium hexaxianoferrate(III) solution and
phenopthalein, Sand paper
Materials: Petri dish 1

Procedures:
1. Nail, Mg strip, Cu strip and Zn strip is clean with sand paper. 1
2. In 4 petri dish, a nail is preparing as below:
Test tube A (nail only) 1
Test tube B (nail coiled with magnesium strip) 1
Test tube C (nail coiled with copper strip) 1
Test tube D (nail coiled with zinc strip) 1
3. A jelly solution containing potassium hexaxianoferrate(III) solution
1
and phenopthalein is poured into every petri dish.
4. The petri dish is left for a few days
1
5. All the observation are recorded. 1

Diagram: (all test tube) 4


(must fuctional and label) (1 test tube-1
mark)

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