Fiitjee: JEE (Advanced) - 2017

1
AITS-FT-I-(Paper-2)-PCM (Sol)-JEE(Advanced)/17
In JEE Advanced 2016, FIITJEE Students bag 36 in Top 100 AIR, 75 in Top 200 AIR, 183 in Top 500 AIR. 3541 Students from Long Term Classroom/ Integrated
FIITJEE JEE(Advanced)-2017
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

School Program & 4423 Students from All Programs have qualified in JEE Advanced, 2016
ALL INDIA TEST SERIES
1. C C A
2. D D A
3. C D D
4. B B C
5. D B A
6. C A B
7. AB BCD CD
8. BD AB ABC
9. BCD AB BC
10. C C C
11. B B B
12. B D D
13. B A B
14. B B C
(A) q, (A) s, t, (A) s,
(B) s, (B) p, q, (B) q, r,
1. (C) p, (C) p, q, r, (C) t,
(D) r (D) p, q (D) p
(A) p, s, t, (A) r, (A) r,
(B) q, r, (B) t, (B) q,
2.
(C) q, r, (C) p, s, (C) p, t,
(D) p, s, t (D) q (D) p, q, s
1. 8 6 2
2. 9 0 3
3. 9 8 0
4. 2 3 3
5. 2 6 2
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2
Physics PART I
SECTION A
1. C
Balance the force in vertical direction
N N

N
mg
T becomes zero when

2Ncos mg ...... 1
1
mgR 1 cos mv 2 .... 2
2
mv 2
mgcos N ..... 3
R
From equation (1), (2) & (3) we get
6m cos2 4mcos m 0
1 1 3M
cos 1
3 3 2m
2. D
Let vy be the velocity along the plane in the y-direction
v y v sin , 30o
2v y 2v sin
T
gsin gsin
1
2 9.8
sin 2 1 30o
9.8 2 2
3. C
MV 2
qVB
R
mV
R
qB
2R 2 mV 2m
t , t
V V qB qB
V cos T 0.01
n t T
n 32
3
4. B
PV1 P1 V1 Ax
P Ax
P1 P 1
Ax V1
1
V1
PV2 P2 V2 Ax
P Ax
P2 P 1
A x V2
1
V2

F A P1 P2
1 1
F PA 2 x
V1 V2
M
T 2
K
MV1V2
T 2
PA 2 V1 V2
5. D
Use dimensional analysis
KE
a b r c h d
kg
a b
L2 M M c b
L L
T 2 L3 LT 2
Solving, b = 1, a = -1, c = -d. It is not possible to resolve d by dimensional analysis but it can be
reasoned out that if we double the thickness of the disk the maximum possible rotation speed
before it disintegrates wont change so we will have twice the energy and twice the mass.
So, d = 0
6. C
Let M be the mass of uncut sphere and M1 be the mass of carved out to from the cavity then
M
M1
8
M
G
GM 8
g 2
2
2R 3 R

2
7 GM
g
36 R 2
7. A
Saturation current is independent from frequency and wavelength of light used.
8. BD
t
I I0 e
RC
4
1 t
e
4 RC
1
t 2sec C
10ln2
1 1 2
H 100 J
2 10ln 2
H I2
RC
thermal power in the resistance will decrease with a time constant .
2
9. BCD
1
qV mu2
2
2qV
u
m
R
mu mvR
2
u
v
2
1 1
mu2 mv 2 qVf
2 2
qV
qVf qV
4
3V
Vf
4
Using principle of conservation of angular momentum and energy, we get angle of deviation
3
2 tan1
4
o
74
3
Magnitude of change in momentum is 2mv sin where sin1
2 2 5
2qV 3
P 2m
m 5
6
2qmV
5
Q2 3 KQ 9 V 2R3
U , V U
2C 4 R 32 40 3
10. C
P0 V0
P0 V0 nRT0 n
RT0
PV cons tan t

V
P0 V0 Pf 0 Pf 8P0
4
So final pressure in both the compartments is Pf 8P0
5
Compartment I Compartment II
PV nRT PV f
Tf T
T PV PV i 0
PV f V
Tf T 8P0 0 T0
PV i i 4

7 P0 V0
8P0 V0
4 T Tf 2T0
0
P0 V0
Tf 14T0
Ans 14T0, 2T0
11. B
R
CV
1
R
2R
3
1
2
dU nCV dT
P V
0 0 2R 14T0 T0 26P0 V0
RT0
12. B

N E
2
fr N m g

E m g
2
2mg
E

13. B
dE
E
dt
E E0 et
2mg
E0

When rope starts slipping frictional force becomes equal to the gravitational force.
2mg t
So, e . m g

1
et
2
ln2
t

14. B
6
t
SECTION B
1. A q , B s, C p, D r
for cylinder
aC

mg
I
aC g
2g
&
R
For plank
2
mg
mg g
aP
2m 2
At the moment slipping stops
V1 t V2 t
VC R ap t
2g g 2v 0
v 0 gt R t t t
R 2 7g
g 2V V
VP 0 0
2 7g 7
1 V2 mV02
(A) KEP . 2m . 0
2 49 49
2V 5
For cylinder Vcm V0 g 0 V0
7g 7
2g 2V0 4V0
t .
R 7g 7R
2 2
1 5 1 4V
(B) KE of cylinder = m V0 mR2 0
2 7 2

7R
33
mV02
98
1 mV0 83
(C) Wf mV02 mV02
2 49 98
7
14mV02
Wf
98
5 V 4
(D) VCP v 0 0 V0
7 7 7
2 2

1 4 1 R2 4 V0
KEcy /Plank m V0
2 7 2 2 7 R
24
mV02
98
2. A pst, B qr, C qr, D pst

If f is positive, power is positive.
SECTION C
1. 8
At t = 0 current will flow only in 12 resistance
1 mH

2 mH
S 5V
5
Imin
12
At t , L1 and L2 both behave as conducting wire
Reff = 3/2
10
Imax
3
Imax
8
Imin
2. 9
MeV
Q value = 12.014U 12U 0.4041 2 C2
c
Q 0.014U 931.5 MeV 4.041 MeV
= 9 MeV
Hence particle will have a maximum KE of 9 MeV.
3. 9
1 1 1 1

f f1 f2 f3
8
1 2 3
+ +
3
1
1 1 1 1 2 1 1

f1 1 R1 R 2 1 12 12

f1 12cm f3
4
3 1 1 1 1 1
f2
1 12 12 3 6

f2 18
1 1 1 1 1

f 12 18 12 9
f 9 cm
4. 2
2T
h
gr
Rise in potential energy
U

2
mgh r h gh 2T 2

2 2 g
Work done by tension
4T 2
WT 2r Th
g
2T 2 2
Q W U 2J
g g
5. 2
37
o B
V = 3R
3R
4R O
A
V
fB f0 o
V VS cos37
V 5v 5V
f0 , f f , f f0
12R B 0 5V 12R A 5V 12R

V
5
9
Chemistry PART II
1. C
H2S 2H S 2
2 2
1021 H S 2 103 S 2

S 2 1016 M

2. D
n2 0.693
t1/2 13.86 min
K 1 K 2 0.02 0.03
3. D
O OH
H2N OH - +
O NH2 OH HO NH
H+
+
H
+ OH
H + H H 2O NH
O OH
N - H+ N
-H2 O
H 2O + OH
OH 2 OH +
N HN
N
+
N - H2 O + H+ - H+
4. B
In blast furnace,
In combustion zone, CO is produced ultimately which reduce Fe2O3 to Fe3O4 in reduction zone,
which is uppermost zone.
5. B
r r
Either octahedral void 0.414 or tetrahedral voids 0.225 are occupied by interstitial
r r
sites in FCC.
10
4r 2 a
2
r a
4
& r 0.414r
2r 2 0.414r
2 0.414 2 a
146.35pm
4
6. A
22
Binding energy of He+ = 13.6 3.4eV
42
-
Total K.E of e = 3.4 1.4 + 4 eV = 6 eV
h h 0
5A
2meV 2me 6
7. BCD
CH2OH
CH2OH
OH O
H O OH
OHOH H O OHH H
OH H
O H
H OH
H OH
8. AB
NOCl +
H3C C CH2 Ph H3C C CH Ph H3C C CH Ph
O OH OH NO
+
-H
LiAlH4 H3C C CH Ph
H3C CH CH Ph H3C C C Ph
OH NH2 O N OH O NO
(Y) (X)
0
0-5 C NaNO 2 + HCl
+
H3C CH CH Ph H3C C CH2 Ph
OH O
(Z)
9. AB
(A) NH4NO3 NaOH NH3 NaNO3 H2 O
7NaOH NaNO3 4Zn 4Na2 ZnO 2 NH3 2H2 O
(B) NH4NO 2 NaOH NaNO2 NH3 H2 O
3Zn 5NaOH NaNO2
3Na2 ZnO2 NH3 H2 O
11
10. C
1 YA YB

P PA0 PB0
PA0 PB0 5400
P

PA0 PB0 PA0 YA 60 30YA
0 0
P 60 & P 90 mm Hg
A B
11. B
When YA = 0.4, P = 75
PY 75 0.4
X A 0A 0.5
PA 60
XB 1 XA 0.5
12. D
Same wittig product may be obtained through two pathways.
13. A
CH3 CH3
O O
Ph
O + P
- PPh
3
P Ph + Ph
Ph
Ph
Ph
14. B
A R A O
R R' - A R R'
C C
+ B
C C
B
C C + Ph
P
Ph
O PPh3 O PPh3 R' B Ph
4 membered cyclic
intermediate called
oxaphosphetane
SECTION B
1. A st, B pq, C pqr, D pq

For Ideal gas, Z = 1
At low pressure and high temperature, real gas behave as an ideal gas.
For real gas, Z 1
At Boyle temperature in a certain pressure range, real gas behave as an idea gas.
TB = a/Rb
2. A r, B pq, C ps, D q
(A) sandmeyer reaction operated via free radical mechanism.
(B) addition of Br2 to olefins in presence of CCl4 occurs through bromonium ion complex
(C) both carbocation intermediate & carbene (:CCl2) involved.
(D) bimolecular nucleophilic aromatic reaction involves carbanion intermediate.
SECTION C
12
1. 6
The geometrical isomers of a complex type [M ABCDEF] = 15 & all these structures exhibit
optical isomerism. So, total stereoisomers x = 30.
2. 0
c 50
0.2
0 250
3
C 2 10 0.2 0.2
Ka 5 105
1 0.8
xy 0
3. 8
COOH

+ P4O 10 3C3O 2 + 4H3PO 4
COOH (A)
(X)
200 C
C3O 2 CO 2 + 2C
(B) (C)
COOH

+ 2NaOH CH4 + 2Na2CO 3
CaO
COOH (Y)
(X)
4. 3
BaCrO4 yellow, soluble in dil. HNO3
Hg2CrO4 red, soluble in conc. HNO3
ZnS white, soluble in conc. HNO3
BaSO4 white, insoluble in all mineral acid
BaS2O3, CH3COOAg or AgNO2 all are white solid and are soluble in dilute HNO3 solution.
5. 6
Cl
Except and Cl
All gives white ppt. with AgNO3.
13
Mathematics PART III

SECTION A
1. A
ab bc c a
2s
2 2 2
2 2 2
2s
1 1 1 1 1 1

a b b c c a
2s 2s
AM HM
abc
So, triangle is equilateral
2. A
a b e x
a b ex
3. D
If z = n + 1; x, y can be choosen in n2 ways
z = n; x, y can be choosen in (n 1)2 ways
z = 1; x, y can be choosen in 12 ways

so, total n numbers of ways 12 + 22 + + n2
4. C
a2 a1 a1a2 d
.
.
.
a100 a99 a99 .a100 d
99
a100 a1 d ai ai 1 aaa1a100 d
i 1
5. A
Put x = 0 and expand; differentiate and put x = 0 and expand.
6. B
perpendicular
7. CD
r must be an even integer because two decreasing function are required to make it increasing
function.
Let y = r(n r)
n 1 n1
When n is odd r or for maximum value of y.
2 2
14
n
Similarly n is even r =
2
n2 1
y n is odd
4
n2
n is even
4
8. ABC
S S'
H'
9. BC
Un 1

Un 1 2
1
So, GP with common ratio
2

U1
4
n 1
1
Un
4 2 2n 1

U100 101
2
10. D
Let f x sin x
g x cos x
sin sin cos
So, cot
cos cos sin
11. B
Let g(x) = x3
f x f a f c
So,
b3 a3 3c 2
12. D
Let x and y denotes the time of arrival of Ranchod and Chatur respectively.
15
Meeting happens if |x - y| 10
y F
C (0, 60) B (60, 60)
H E
G
I
x
O D (10, 0) (30, 0) A (60, 0)
(0, 0)
The shaded area indicates (x, y) where the meeting happens.
shaded area
Probability =
area of square OABC
11
36
13. B
1 11
Since the probability that Ranchod gets a job is . Probability that the meeting happens =
2 72
14. C
area of quadrilateral GDIH
P1 (meeting between 5:10 PM to 5:30 PM) =
area of square OABC
area of pentagon DEBFG
P2 (meeting after 5:10 PM till 6:00 PM) =
area of squareOABC
P1 400 8
conditional probability =
P2 950 19
SECTION B
1. A s, B qr, C t, D p

a b c d 1 d

a b c d 1 a

1 d 1 a
1
d a
1
1
abc a
1
1
1 a b c 0 a, b, c are coplanar but according to question it is so,
1

abc d 0.
16

ab 1

ab ab 1
2 2
a b 2 a b cos 1
1
cos
2
2

3

(C) a b 1

(D) a b c
2 2
ab c
2 2
a b 2 a.b 1
1
a.b
2
1
cos
2
2

3
2. A r, B q, C pt, D pqs
(A) a2 b2 + c2 = 0 and a2 2bd + c2 = 0
b
b2 2bd 2
d
(B) x = 2r + 1, y = 3r 2, z = - 6r + 3
2 2 2
9 11 15
Distance = 1 2 3 1
7 7 7
(C) K = 0 or 3
(D) cos2 cos2 cos2 1
cos2 cos 2
cos 2 0
0 cot 1
SECTION C
1. 2
A.A T I
2. 3
2
sin cos sin
2 2 2
2 d
3 2
cos cos cos cos
2
Let cos t
3. 0
17
y y1 x12 x x1
y 2 y1 x12 x 2 x1
3
x32 1 x1 1

x12 x 2 x1
3 3

x 32 x13 3x12 x 2 x1
x 22 x1x 2 x12 3x12
x 22 x1x 2 2x12 0
x 2 2x1
x 3 2x 2 4x1 22 x1
n1
xn 1 2n 1 x1
4. 3
Let f x 7 2xln 25 5 x 1 52 x
f x 0 at x = 2
r = 1/3
2
s 3
1
1
3
5. 2
2x x
x x
x
Let x = I + f
1
Will give f = 0,
2
If f = 0, I = 0 which is not possible
1 1
x 1 , 1
2 2

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1

Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES

T becomes zero when

2. A pst, B qr, C qr, D pst

At t , L1 and L2 both behave as conducting wire

1. A st, B pq, C pqr, D pq

All gives white ppt. with AgNO3.

Mathematics PART III

z = 1; x, y can be choosen in 12 ways

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