Vidyamandir Classes

Solutions JEE Advanced-4/JEE-2017

CHEMISTRY PAPER-2

SINGLE CORRECT ANSWERS TYPE

1.(A) As the acid being titrated becomes weaker (pKa becomes larger), the pH change around the equivalence point
decreases significantly.
2.(B) Mg reacts with both O2 and N2 when heated in air. So some of the magnesium is used for formation of Mg3N2.
3.(C) Order of entropy is gas > liquid > solid.
4.(A) NH4Br and NaI also possess ionic bond and Al is metallic solid having metallic bond.
5.(C)

Methoxy group is more activating than methyl group.

6. (B) Rydbergs equation is applicable for one electron system i.e. H, He+ D and T.
Hydride ion (H) is two electron species.

MULTIPLE CORRECT ANSWERS TYPE

7.(BC) In this silicate repeating unit is Si 4 O116 and it is double chain silicate. In all silicate coordination number of
silicon is four.
8.(BCD)Refer theory
During reaction of N2, NO2 cant be formed, because G for formation of NO2 from N2 and O2 is always positive.

9.(ABC)

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10.(BC)

11.(AD)

Compound should have only one terminal C = C bond.

12.(ABD) Achiral due to plane of symmetry.

13.(ABC) As given compound is aromatic ketone and it is prepared by Friedel craft acylation reaction.

Benzophenone produce meta substituted product.

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14.(ABC)

LINK COMPREHENSION TYPE

15-16. 15.(B) 16.(C)

Formation of (Y) is intramolecular F.C. alkylation reaction.

17-18. 17.(C) 18.(B)

Para-formaldehyde is polymer of formaldehyde hence reaction is : n CH 2 O
(CH 2 O) n

1. nCH 2 O
(CH 2 O) n r H 72kcal

2. CH 2 O O 2
CO 2 H 2 O H 134 kcal

3. (CH 2 O) n nO 2
nCO 2 nH 2 O H 732 kcal
H3 n H 2 H3
72 134 n (732)
134n 72 732
804
n 6
134

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Solutions JEE Advanced-4/JEE-2017

PHYSICS PAPER-2

SINGLE CORRECT ANSWERS TYPE

1. (C) m1 v 1 = m2 v 2 = P (from conservation of momentum)
P 2
P P m1 m2
2 2
E
2m1 2m2 2m1m2

2.(D) No change in velocity along tangent.

V sin V1 sin 90
tangent
V
90
V1 V tan (i)
V1
P Q
V1 cos 90 V sin O
e 1 tan 2
V cos V cos

2 .5
3.(A) F 2 s 2 0.072 N 3.6 103 N
100
4. (A) q = 4C
dq
I 5A
dt
q2 1 42 1
5
2
So E UC U L LI 2 4 8 10 18 J
2C 2 2 1 2
qm2 qm2
So E 18 J (conservation of energy) 18 J qm 6 C
2C 2 1
20
5.(A) P.D. across capacitor = 10V
2
Hence current will not flow after the switch is closed

6. (D) The blocks will accelerate in left direction.

a
2F F F
a
2m 2m
For right block 2f
N
2 F N sin 30 ma 30
30
m
N F
2F N = 3F
2 2

MULTIPLE CORRECT ANSWERS TYPE

7.(BCD)(B) Refers to conservation of angular momentum under central force.
(C) Conservation of energy (D) increases from 90 , so modulus increases.

8.(ABCD)
D = 96 cm
I1
4 ; O I1 I 2 I1 I 2 O 2
I2
O2 O
I 22 2 (ratio of length of object to shorter image)
4 I2

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O 1

I1 2
D u2 1 96 u2 1
u2 64
u2 2 u2 2
D u1 96 u2
2 2 u1 32 u2 u1 32 cm
u1 u1
D 2 2 962 322 64
f cm
4D 4 96 3
For shorter image u = u2 = 64
D u2 96 64 32 cm

9.(AD) Let charge on innermost and outermost shell be x and y respectively. y x 2Q

2Q x
Charge on middle shell will not change.
x 2Q
x + y = Q + 5Q (charge conservation) (i) x
x 2Q y x y 2Q x
(ii) (V1 = V2)
4 0 R 4 0 2 R 4 0 3R 4 0 3R O

Solving we get : x Q / 2 ; y 11Q / 2

Final charge distribution is as shown
Q 3Q
Charge on the inner surface of outermost shell= 2Q x 2Q
2 2
a
Charge on inner surface of middle shell x
2
10.(AB) 20 K 45 20 [If temp is constant at 45 ]
4
K
5
Rate of heat loss R k 20
4
25C , R 25 20 4w
5
4
45C , R 45 20 20 w
5
560 q 560 c
560 q q q
11.(BC) + +
4 2 1
q 80 c

q q

+ + 2 F 1 F
12.(ABC) For each chamber
PV constant
P V
P V 1 V V P 0 P
V
P A x P A x 2P A x
Force for SHM = kx
0 0 0
M M 0
T 2 2
2 P A 2 P A 0K
K
0
13.(ABCD)

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14.(BCD) T 2 r3
T12 r13 322 x3 1 x3
r2 = 4x
T22 r23 2562 r23 82 r23
GmM
Total energy = r2 r1 E2 E1
2r
GmM
Kinetic energy = r2 r1 k2 k1
2r
LINK COMPREHENSION TYPE
15-16. 15.(B) 16.(C)
Equation of motion are
T f 3a (i)
2 3kg
fR 3 R2 (ii)
5 T a
40 f T 5a (iii)
For rolling without slipping. f
R a a
R 2 a (iv) f
T 5 kg 40 N
25
Solving a m / s2
8 a
f 7.5 N
17-18. 17.(B) 18.(D)
Let r be the distance of a point from axis.
r
r
For r R , B . 2 r 0 J 0 1 R 2 r d r [using amperes Law]
0
r r2
B 0 J 0
2 3 R
R
r 0 J 0 R 2
For r > R, B . 2 r 0 J 0 1 R 2 r d r B
6r
0
dB 1 2r 3R
B will be maximum at inside point where 0 0 r
dr 2 3R 4
3R 9 R 3 J 0 R
Bmax 0 J 0
8 48 16

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Solutions JEE Advanced-4/JEE-2017

MATHEMATICS PAPER-2
SINGLE CORRECT ANSWERS TYPE
1.(B) Roots of equation ax3 x 1 a 0, (a 1, 0) are 1, ,
1 a
1 and
a

lim
(1 a ) x3 x 2 a
lim

( x 1) (1 a) x 2 ax a
x
1 (e1x 1)( x 1) x 1 (e1x a )( x 1)

ax ax a
2
lim
x
1 (e1x 1)

a (1 x)(1 x) a ( )
lim lim a(1 x) k 1 & l 1
x
1 1 x x
1

So kl 1
1
2.(C) z i (1 i 3) i2
2
z101 i
( z101 i109 )106 (i2 )106 2
2 (i2 ) n i n 2 n
2 n 2i n 1
This is possible only when n 4r 2 and 2n 2 is a multiple of 3
i.e. 2(4r 2) 2 is a multiple of 3
r2 R 10
2
R4
5
3.(A) f ( x) is an even function
f (cos( x)) f ( cos x) f (cos x)
/2
I1 2 f (cos x) dx
0
/2

I1 2 f cos x dx
2
0
/2
I1 2 f (sin x) dx
0

I1 2 I 2
I1
2
I2

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4.(B) f ( x) f '( x) f ( x) f '( x)

f '( x) f '( x)

f ( x) f ( x)
f '( x) f '( x)
f ( x)
dx f ( x)
dx

ln f ( x) ln f ( x) c
At x 0 f ( x) 1 c 0
ln f ( x) ln f ( x) 0 f ( x) f ( x) 1
2
dx
Let I 1 f ( x) ..(1)
2
2
dx
I 1 f ( x)
2
2
f ( x) dx
I f ( x) 1
(2)
2

Adding (1) & (2)

2
2I dx I=2
2

5.(B) | a b | 3

| a |2 | b |2 2 a . b 3
1
a .b
2

c a 2b 3a b

k | (a b ) c | | (c . b )a (c . a )b |
1 5
c .b 2
2 2

c .a 1 1 2
5 1
k a 2b | 5a 4b | | 5a 4b |2 25 | a |2 16 | b |2 40 a . b 25 16 20 21
2 2

| 5a 4b | 21
1
21
2
[k ] 2
{x}, [ x] is odd
6.(B) f ( x)
1 {x}; [ x] is even
1
Required area 2 2 1 = 2 sq. units
2

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MULTIPLE CORRECT ANSWERS TYPE

7.(AC) Since a, b, c, d are in A.P.
(b a ) (c b) d c D
a d 3 D , b d 2 D , c a 2 D
Given equation becomes.
2 D xD 2 8D 3 6 D 4 D 2 D 3 9 D 2 ( x 4) D 4 0
Since D is real
( x 4) 2 4.9.4 0
( x 16)( x 8) 0
x 16 or x 8
8.(AC) cos(cos 1 1) 1 cos(cos(cos 1 1)) cos1
sin(sin 1 (sin( 1))) sin1
cos 1 (cos(2 2)) cos 1 (cos 2) 2 sin(cos 1 (cos(2 2))) sin 2
tan(cot 1 (cot1)) tan1
Also cos1 sin1 sin 2 tan1
(A) is correct.
cos 1 cos x is periodic & even
cos 1 cos(2t 1) cos 1 (cos1) 1
cos 1 cos(2t 1) 5000
Similarly cot 1 cot(t 1) 1

9.(BC) Shifting origin to point P by putting

1
x X 2, y Y
2
Equation of ellipse becomes
X2 1
Y2 X 2Y 0
4 2
Let equation of AB is AX BY 1
Homogenising
X2 X
Y2 2Y ( AX BY ) 0
4 2
Since AP BP
Coefficient of X 2 coefficient of Y 2 0
A 5
2B 0
2 4
4 4 2
A B 1 AB passes a fixed point.
5 2 5
4 4 2
,
5 2 5

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4 4 2 1 6 3
Shifting back 2, ,
5 2 5 2 5 2 5 2
6 3
a , b
5 2 5 2
36 9 9 m
a 2 b2
50 10 n
10.(ABC)
/2
I1 cos( sin
2
x) dx
0
/2
I1 cos( cos
2
x) dx
0
/2
2 I1 (cos( sin 2 x) cos( cos 2 x) )dx
0
/2
(sin 2 x cos 2 x)
2 I1 2 cos cos
2 2
dx

0

2 I1 0 I1 0
/2 /2 /2
1 2
I2 cos((1 cos 2 x))dx cos( cos 2 x)dx
20
cos( cos t )dt
2 cos( cos t )dt
0 0 0
/2
cos( sin t )dt
0

I 2 I3
I 2 I3 0
11.(ABC)
f ( x) x3 F ( x)
f '( x) x3 F '( x) 3x 2 F ( x)
f '(1) F '(1) 3F (1)
F '(1) 0 ( F '( x) 0 )
f (2) 8 F (2) 0 ( F (2) 0 & F '( x) 0 )
Now f '( x) x3 F '( x) 3x 2 F ( x)
For x (1, 3)
x3 F '( x) 0 and 3 x 2 F ( x) 0
f '( x) 0 for x (1, 3)
x2 y 2 x2 y2
12.(ABCD) For ellipse 1 and 1
16 7 (144 / 25) (81 / 25)
144 81 144 2
16 7 16e12 and e2
25 25 25
3
e1
4

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15 5
e2
12 4
Foci = (3, 0)
For point of intersection of hyperbola and ellipse
x2 y 2 1

144 63 9
x2 y 2 1 1 1 1 1 16
y2
144 81 25 63 81 9 25 9 25
3 7
y
5
16
x
5
16 3 7
Point of intersection ,
5 5
3
Equation of asymptote y x
4
16 12
Point P ,
5 5
256 144
Sum of square of co-ordinates of P 16
25
x 2 y 2 16 a 2
P lies on auxiliary circle
13.(AC) f x tan 1 cot x
Periodic with periods
(f (x) is not differentiable at x , 99 , 100 , as it is discontinuous at x n , n I , but x n is not in the
domain of the function)
f x 1 , for 2n x 2n 1

14.(BC)Let h( x) 3 f ( x) 2 g ( x)
h(2) h(0) h(1)
According to Rolles theorem for some x (2, 0)
h '( x) 0 and for some x (0, 1) h '( x) 0 but h ''( x) 0 .
h '( x) 0 has exactly one solution in (2, 0) and exactly one solution in (0, 1)

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LINK COMPREHENSION TYPE

15.(D) Let f ( x) F ( x) x 2
Where F ( x) is a polynomial of degree 5.
Now F (1) F (2) F (3) F (4) F (5) 0
f ( x) ( x 1)( x 2)( x 3)( x 4)( x 5) x 2
f (6) 156

16.(B) Sum of the roots of f ( x) 15

1
17.(B) Let L x ae 3 1
3
x 2 y 2 a 2 b 2 x 2 y 2 17 y 2 16, y 4

18.(B) Chord of contact of any point (1, ) w.r.t. ellipse and parabola respectively are
x y
1
9 8
x
y 8 1 ..(1)
9
x 1
and y 4
2
y 2( x 1) .(2)
From (1) & (2)
x
8 1 2( x 1) x9
9

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