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4. 2.8 gm of Fe displaces 3.2 gm of Cu from a solution of copper sulphate. If equivalent mass of iron is 28,
then equivalent mass of copper will be :
(A) 16 (B) 32 (C) 48 (D) 64
5. If the theory of resonance is not considered, then which of the following will have different strength of
- bonds ?
(A) CO2 (B) SO2 (C) XeO3 (D) N O2
6. If a balloon filled with CO is pierced and kept in a tank filled with N 2 gas at same P and T, the volume of
balloon will :
(A) Increase (B) Decrease (C) Remain same (D) Cant say
9. Which hydrogen like species will have same radius as that of first Bohr orbit of hydrogen atom ?
(A) n = 2, Li2+ (B) n = 2, Be3+ (C) n = 2, He (D) n = 3, Li2+
10. What volume of 1M NaOH solution should be added to 12g NaH2PO4 to convert it into Na2HPO4?
(A) 100 ml (B) 200 ml (C) 300 ml (D) None of these
11. Molality (m) of a solution whose density is d g/L and molarity is M is given by :
1000M 1000M M
(A) (B) (C) (D) None of these
1000d MM B d MM B 1000d MM B
13. One mole of ice is converted into water at 273 K. The entropies of H2O(s) and H2O(l) are 38.20 and
60.01 J mole1 K1 respectively. The enthalpy change for the conversion is :
(A) 59.54 J mol1 (B) 5954 J mole1 (C) 594.5 J mole1 (D) 320.6 J mole1
15. For a certain temperature the chemical reaction represented by the following equation has an equilibrium
constant of 4.
CO 2 (g) H 2 (g)
CO(g) H 2 O(g)
A mixture initially containing one mole of each of CO and steam is allowed to reach equilibrium.
How many moles of CO are now present?
(A) 1/4 (B) 1/3 (C) 1/2 (D) 2/3
16. When a certain volume, V1 of a gaseous hydrocarbon is exploded with excess of oxygen and the products
were cooled to room temperature. The observed contraction in volume was 1.5V1. A further contraction of
2V1 was observed on exposure of the product gases to alkali. Formula of hydrocarbon is :
(A) C2H4 (B) C2H2 (C) C2H6 (D) C3H4
17. One mole of non-ideal gas undergoes a change of state (1.0 atm, 3.0L, 200 K) to (4.0 atm, 5.0L, 250 K)
with a change in internal energy (U) 40 L-atm. The change in enthalpy of the process in L-atm :
(A) 43 (B) 57 (C) 42 (D) None of these
18. Which of the following ions has the highest magnetic moment ?
(A) Fe3+ (B) Mn2+ (C) Cr3+ (D) V3+
19. Which of the following pairs contain both species as planar in all possible forms ?
(A) C2 (CN) 4 H 2 C CH CH CH 2 (B) O C C C O , H 2C C O
(C) H 2 C C CH 2 , H 2 C C C CH 2 (D) CO 2 H 2 O 2
20. Assuming the overlap direction to be z-axis, which of the given overlappings of atomic orbitals of two
atoms (A) and (B) will result in bond formation ?
I. s-orbital of A and p x - orbital of B II. s-orbital of A and p z - orbital of B
III. py-orbital of A and p z - orbital of B IV. s-orbitals of both (A) and (B)
The correct choice is :
(A) I, II only (B) I, III only (C) II, IV only (D) I, II, IV
4 2
22. 2 NO 2 (g) whose K p
Consider the following equilibrium in a closed container N 2 O 4 (g) P.
1 2
At a fixed temperature, the volume of the reaction container is halved. For this change, which of the
following statements holds true regarding the equilibrium constant ( K p ) and degree of dissociation ( ) :
(A) Neither K p nor changes (B) Both K p and increase
(C) K p increases but decreases (D) K p does not change but decreases
23. How much water must be added to 300 mL of 0.2 M solution of CH3COOH for the degree of
dissociation of the acid to double? K a for the acetic acid 1.8 105 .
(A) 900 mL (B) 1000 mL (C) 500 mL (D) 300 mL
24. Which of the following will produce a buffer solution when mixed in equal volumes ?
(A) 0.1mol dm 3 NH 4 OH and 0.1mol dm 3 HCl
(B) 0.05mol dm 3 NH 4 OH and 0.1mol dm 3 HCl
(C) 0.1mol dm 3 NH 4OH and 0.05 mol dm 3 NH 4Cl
(D) 0.1mol dm 3 CH 3COONa and 0.1mol dm 3 NaOH
25. To a 20ml 0.1 M solution of BOH (K b 106 ) , 10 ml of 0.2 M HA is added. If the pH of resulting
solution is 6.2, Then Ka of acid is :
(A) K a 106 (B) K a 106 (C) K a 106 (D) Data insufficient
[Cu 2 ] yM solution loses 5 L of water due to evaporation at constant temperature. At new equilibrium :
(A) [Cu 2 ] 2y ; [Fe 2 ] 2x (B) [Cu 2 ] 2y ; [Fe 2 ] 2x
(C) [Cu 2 ] 2y ; [Fe 2 ] 2x (D) Data insufficient
27. Which of the following equilibrium is unaffected by addition of inert gas at constant pressure ?
(A) H 2 (g) I 2 (g)
2HI(g) (B) 2H(g)
H 2 (g)
30. Ag is added into a solution containing Cl 0.1M , Br 0.1M , I 0.1M . In what order the salts will
precipitate out ?
K sp (AgCl) 1015 , K sp (AgBr) 1020 , K sp (AgI) 1023
(A) AgCl, AgI, AgBr (B) AgBr, AgCl, AgI
(C) AgI, AgBr, AgCl (D) AgBr, AgI, AgCl
1. Let O 0, 0 , P 3, 9 , Q 6, 5 be the vertices of the triangle OPQ. The point R inside the triangle OPQ
such that the triangles OPR, PQR and OQR are of equal area. The coordinates of R are :
3 4 9
(A) 4, 4 (B) (3, 2) (C) 3, 3 (D) 2, 2
2. If T 0 , T1 , T 2 , T 3 ,....., T n represents the terms in the expansion of x a n , x, a R , then the value of
T 0 T 2 T 4 T 6 ..... T1 T 3 T 5 .....
2 2
equals to :
x x 2a
n n/2 n
(A) n (B) 2
a2 (C) 2
a2 (D) 2
x2
4. If A 3, 2 and B(2, 1) are the two points in the Cartesian plane, which of the following line divides
externally the line segment AB in the ratio 1 : 2 ?
(A) 6x 3y 2 (B) 3 y 3 x 9 0 (C) x y 13 0 (D) 2 x y 18
6
5. The coefficient of x7 in the expansion of 1 x x 2 x3 is :
(A) 132 (B) 144 (C) 132 (D) 144
256
6. The number of integral terms in the expansion of 385 is :
(A) 32 (B) 33 (C) 34 (D) 35
50
8. The sum of coefficients of integral powers of x in the binomial expansion of 1 2 x is :
3 2 3 3
1 1 1 1
(A) 50
1 (B) 50
1 (C) 50
1 (D) 50
250
2 2 2 2
9. 4 buses runs between Bhopal and Gwalior. If a man goes from Gwalior to Bhopal by a bus and comes back
to Gawalior by another bus, then the total possible ways are:
(A) 12 (B) 16 (C) 4 (D) 8
10. The number of ways in which four cards can be selected from a pack of 52 cards such that there is exactly
one pair (pair has same number or alpha weights) is :
(A) 13 48
C2 4 C2 (B) 13 4C2 12
C2
(C) 13 C2
4 12
C2 4 2
(D) 13 12 11 4C2
11. A number of 5 digits telephone numbers having at least one of their digits repeated is:
(A) 90000 (B) 100000 (C) 30240 (D) 69760
1 1
12. In an A.P., let an denote nth term, let a p , aq , then a p q
q p q p p q
1 1 1
(A) (B) (C) (D) None of these
pq p q 2 2
pq
13. Given that x, y, z are positive reals such that xyz = 32. The minimum value of x 2 4 xy 4 y 2 2 z 2 is equal
to :
(A) 64 (B) 256 (C) 96 (D) 216
15.
Let , be real roots of quadratic equation x 2 kx k 2 2k 4 0 , then maximum value of 2 2
is equal to : k R
4 16 8
(A) 12 (B) (C) (D)
9 9 9
1
16. If sin x cos x , then tan x is equal to :
5
1 1 3
(A) (B) (C) (D) None of these
6 2 4
a b 1 1 1
17. Let a sin10, b sin 50, c sin 70 , then 8abc
c a b c
(A) 1 (B) 3 (C) 6 (D) None of these
18. All possible 720 permutations of MANDIR are arranged in dictionary order, what is the position (rank) of
MANDIR in that dictionary ?
(A) 372 (B) 373 (C) 374 (D) 375
2 2
20. If cos i sin , 1 then 1 2 3 2 4 3 . . . . n n 1
n n
n n n n
(A) (B) (C) (D)
1 1
4 sin 2 4 sin 2
n n
SPACE FOR ROUGH WORK
1 1
21. Let x 2i, i 1 , then x 2187 2187
x x
1
(A) 2i (B) 2i (C) 2 (D) i
2
2
22. If z 2 1 z 1 , then z lies on :
(A) real axis (B) imaginary axis (C) a circle (D) None of these
24. Area of the quadrilateral formed by the roots of equation z 4 z 2 1 0 plotted in an argand plane is :
3
(A) (B) 3 (C) 2 3 (D) 4 3
4
25. A value of K for which the equations x 2 Kx 1 0 and x 2 x K 0 have one root common is :
(A) 2 (B) i 3 (C) i 5 (D) 2
26.
All values of k such that x 2 8kx 16 k 2 k 1 0 has real and distinct roots and both roots have values
at least 2 is :
(A) 1, (B) 2, (C) R (D) 1,
SPACE FOR ROUGH WORK
28. Let
P : sin cos 2 cos
and Q : sin cos 2 sin
then :
(A) P Q and Q P (B) QP
(C) PQ (D) P=Q
1
29. If af x 1 bf x, x 1, a b . Then f 2 is equal to :
x 1
2a b a a 2b
(A) (B) (C) (D) None of these
2 a b 2 2
a b2 2
a 2 b2
1
30. Let f x x12 x9 x 4 x 1 2
. The domain of the function is :
3. A particle has an initial velocity of 9 m/s due east and a constant acceleration of 2m / s 2 due west.
The distance covered by the particle in the 5th second of its motion is :
(A) Zero (B) 0.5 m (C) 2m (D) None
4. Rain is falling vertically with a velocity of 25ms 1 . A person rides a bicycle with a speed of 10 ms 1 in
the north to south direction. What is the direction (angle with vertical) in which he should hold his
umbrella to save himself from the rain ?
(A) tan 1 0.4 (B) tan 1 1 (C) tan 1 3 (D) tan 1 2.6
8. In the given situation, what is the minimum mass of block A so that the
block B remains stationary with respect to the wall? The coefficient of
friction is between wall and block. All others surface are smooth.
M m M
(A) (B)
1 1
M m M m
(C) (D)
1
Parabolic Curve
If particle has a mass = 1 kg. Find the magnitude of force acting on particle.
(A) 1N (B) 2N (C) 3N (D) 0.5N
11. A particle of mass m is moving in a circular path of constant radius r such that its centripetal
acceleration aC is varying with time as aC = k2rt2, where k is a constant. The power delivered to the particle
by the force acting on it is :
mk 4 r 2t 5
(A) 2 mk 2 r 2t (B) mk 2 r 2t (C) (D) Zero
z
12. A man of mass 100 kg having a bag of mass 1 kg slips over the roof of a tall building of height 50m and
starts falling vertically. When at a height 18m from the ground, he notices that the ground below him is
pretty hard, but there is a pond at a horizontal distance of 10m from the line of fall. In order to save himself
he throws the bag horizontally (w.r.t himself) in the direction opposite to the pond. What is the minimum
velocity imparted to bag, so that the man lands in the water :
(A) 250 g (B) 500 g (C) 1000 g (D) 2000 g
13. A mass m is thrown as a projectile. The magnitude of its angular momentum about the highest point of
trajectory above the ground:
(A) Is zero (B) Remains constant
(C) First decreases and then increases (D) Goes on decreasing
14. A mass of 2 kg hangs from a string, which is wound over a pulley of mass
5 kg and radius 2m. Initially they are at rest. The mass begins to fall as the string
unrolls over the pulley. Find speed of mass when it falls a distance of 5m.
(Assume string doesnt slip on pulley, and pulley is a solid cylinder)
20
(A) 10 m/s (B) m/s
3
200
(C) m/s (D) None of these
7
Paragraph for Questions 15 - 17
An object has a flat rectangular handle of mass m
and length l and a flat circular disc of radius r and
mass m attached to the handle.
15. The moment of inertia of the object about an axis perpendicular to its plane and passing through its centre
of mass is :
ml 2 mr 2 ml 2 3mr 2
(A) (B)
12 2 3 2
2
l ml 2
mr 2 m
(C) 2m r (D) (l 2r ) 2
2 12 2 8
16. In previous question, if m = 1 kg, l = 12m and r = 2m, and a
force of 10N starts acting at the end of handle of object, such
that it is always perpendicular to handle. Find time after
which object completes one complete revolution, if the
object is fixed at its centre of mass.
46 46 46
(A) s (B) s (C) s (D) None of these
50 25 100
17. In previous question, find kinetic energy possessed by the object after one complete revolution.
(A) 200 J (B) 400 J (C) 100 J (D) None of these
25. 1 kg of ice at 0C is mixed with 500 gm of steam at 100C. The amount of water formed in thermal
equilibrium is: [Given L f 3.36 105 J / kg and LV 2.26 106 J / kg and S 4200 J / kg ].
(A) 335 gm (B) 1kg (C) 1.5kg (D) 1.335kg
26. Heat flows from one end of a rod of varying cross section to another in steady state 2 1
27. What is the density of lead under a pressure of 2.0 108 N / m 2 , if the bulk modulus of lead is
8 109 N / m 2 and initially the density of lead is 11.4 g / cm3 ?
(A) 11.7 g / cm3 (B) 11.8 g / cm3 (C) 11.9 g / cm3 (D) 12 g / cm3
28. A wire is bent to form a ring of radius 1m. The density of wire is 7 103 kg / m3 and Youngs modulus
7 108 N / m 2 . The ring is rotated with an angular velocity 10 rad / s in horizontal plane. The small
increase in radius of the ring is :
(A) 0.1 m (B) 1m (C) 0.1 cm (D) 1 cm
29. The time taken by a block of iron to cool from 50C to 45C is 6 min. Then the taken by the same block to
cool from 45C to 40C is : [Given room temperature 25.5C]
3 1
(A) 7 min (B) 7 min (C) 8 min (D) 8 min
4 4
30. The specific heat of a metal at low temperature varies according to S 2 T 3 J / gmC where T is in Kelvin.
The heat energy needed to raise temperature of a unit mass of metal from T 1 k to T 3 k is :
(A) 81J (B) 80 J (C) 40 J (D) 1J