Jeeadvsolutions16 PDF

Sri Chaitanya IIT Academy.
,India [P-2]_Question Paper,Key and Solutions
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2016 JEE-ADVANCED_CODE-4 Page 2

Sri Chaitanya IIT Academy.,India [P-2]_Question Paper,Key and Solutions
PART I: PHYSICS
SECTION 1 (Maximum Marks: 18)
This section contains SIX questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four
options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS
For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If only the bubble corresponding to the correct option is
darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : -1 In all other cases.
Q1. A small object is placed 50 cm to the left of a thin convex lens of focal length 30cm.
A convex spherical mirror of radius of curvature 100 cm placed to the right of the lens
at a distance of 50 cm. The mirror is tilted such that the axis of the mirror is at an
angle 300 to the axis of the lens, as shown in the figure
If the origin of the coordinate system is taken to be at the centre of the lens, the
coordinates (in cm) of the point (x, y) at which the image is formed are
f=30 cm

(-50,0) (0,0) x
50 cm
R=
10
0cm
50 50 3, 50
A) 125 / 3, 25 / 3 B) 0, 0 C) 50 25 3, 25 D) 25, 25 3
KEY: D

Q2. There are two Venire calipers both of which have 1 cm divided into 10 equal divisions
on the main scale. The Venire scale of one of the calipers C1 has 10 equal divisions
that correspond to 9 main scale divisions. The venire scale of the other caliper C2
has 10 equal divisions that correspond to 11 main scale divisions. The readings of the
two calipers are shown in the figure. The measured values (in cm) by calipers C1 and
C2 , respectively, are
2 3
4
C1
0 5 10
2 3
4
C2
0 5 10
A) 2.87 and 2.87 B) 2.85 and 2.82 C) 2.87 and 2.83 D) 2.87 and 2.86
KEY: C
Q3. A gas is enclosed in a cylinder with a movable frictionless piston. Its initial
thermodynamic state at pressure P1 105 Pa and volume Vi 103 m3 changes to final
1
state at Pf 105 pa & V f 8 103 m3 in an adiabatic quasi-static process, such that
32
P3V 5 constant. Consider another thermodynamic process that brings the system form
the same initial state to the same final state in two steps: an isobaric expansion at Pi
followed by an isochoric (is volumetric) process at volume V f . The amount of heat
supplied to the system in the two-step process is approximately
A) 112 J B) 294 J C) 588 J D) 813 J
KEY: C
Q4. An accident in a nuclear laboratory resulted deposition of a certain amount of
radioactive material of half-life 18 days inside the laboratory. Tests revealed that the
radiation was 64 times more than the permissible level required for safe operation of
the laboratory. What is the minimum number of days after which the laboratory can be
considered safe for use?
A) 64 B) 90 C) 108 D) 120
KEY: C
Q5. The ends Q and R of two thin wires, PQ and RS, are soldered (joined) together.
Initially each of the wires has a length of 1 m at 100 C . Now the end P is maintained at
100 C , while the end S is heated and maintained at 4000 C . The system is thermally
insulated from its surroundings. If the thermal conductivity of wire PQ is twice that of
the wire RS and the coefficient of linear thermal expansion of PQ is1.2 105 K 1 , the
change in length of the wire PQ is
A) 0.78 mm B) 0.90 mm C) 1.56 mm D) 2.34 mm
KEY: A

Q.6 The electrostatic energy of Z protons uniformly distributed throughout a spherical

3 Z Z 1 e
2
nucleus of radius R is given by E The measured masses of the neutron,
5 4 0 R
1 15 15
1 H 7 N and 8 O are 1.008665 u, 1.007825 u, 15.000109 u and 15.003065 u,
respectively. Given that the radii of both the 157 N and 158 O nuclei are same,
1U 931.5 MeV / c 2 (c is the speed of light) and e2 / 4 0 1.44 MeV fm. Assuming that
the difference between the binding energies of 157 N and 158 O is purely due to the
electrostatic energy, the radius of either of the nuclei is 1 f m 1015
A) 2.85 fm B) 3.03 fm C) 3.42 fm D) 3.80 fm
KEY: C
This section contains EIGHT questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN
ONE of these four options (s) is (are) correct.
For each question, darken the bubble (s) corresponding to all the correct option (s) in
the ORS.
Full Marks : +4 If only the bubble (s) corresponding to all the correct option (s)
is (are) darkened.
Partial Marks :+1 For darkening a bubble corresponding to each correct option,
provided NO incorrect option is darkened
For example, if (A), (C) and (D) are all the correct options for a question, darkening
all these three will result in +4 marks; darkening only (A) and (D) will result in +2
marks; marks; and darkening (A) and (B) will result in -2 marks, as a wrong option is
also darkened.
Q7. A block with mass M is connected by a massless spring with stiffness constant k to a
rigid wall and moves without friction on a horizontal surface. The block oscillates
with small amplitude A about an equilibrium position x0 . Consider two cases: (i) when
the block is at x0 ; and (ii) when the block is at x x0 A . In both the cases, a particle
with mass m M is softly placed on the block after which they stick to each other.
Which of the following statements(s) is (are) true about the motion after the mass m is
placed on the mass M
M
A) The amplitude of oscillation in the first case changes by a factor of ,
mm
whereas in the second case it remains unchanged
B) The final time period of oscillation in both the cases is same
C) The total energy decreases in both the cases
D) The instantaneous speed at x0 of the combined masses decreases in both the cases
KEY: ABD

SOL: When block is placed at a poison x0

From LCL n MV m M V 1
MAW mA K
V1
mM mM M
K MA K
A1
M m mM M
M A1 M
AA 1

mM A mM
When block is placed at extreme position amplitude does not change fince at extream position M is
at rest F0 initial and final momentums are not changed
M
B) Tinitial 2
K
mM
After block is placed T final 2
K
1 1
C) Total energy E mA w mVmean
2 2 2
2 2
Before block is placed
1
At x0 : E1 MV 2
2
1
At x0 A E2 MV 2 E1 energy constant
2
After block is placed
2
1 MV
E3 m M
m M
At x0 :
2
1 M
MV 2
2 m M
At x0 A E4 E3 [energy constant]
M
As 1 so energy decreases
mM
D) When block is placed at x0
M
V1 V
m M
V1 V
When block is placed at x0 A velocity of system at its mean position
K
V 1 Aw1 =A V1 V
M m

Q8. In an experiment to determine the acceleration due to gravity g, the formula used for
7R r
the time period of a periodic motion is T 2 . The values of R and r are
5g
measured to be 60 1 mm and 10 1 mm, respectively. In five successive
measurements, the time period is found to be 0.52s, 0.56s, 0.57s, 0.54s and 0.59s. The
least count of the watch used for the measurement of time period is 0.01 s. Which of
the following statements (s) is (are) true
A) The error in the measurement of r is 10%
B) The error in the measurement of T is 3.57%
C) The error in the measurement of T is 2%
D) The error in the determined value of g is 11%
KEY: ABD
r 1
SOL: 100 100 10%
r 10
T 0.01 0.01
100 100 100
T T 0.56
= 0.0178 100
=0.02
=2%
Rr
g
T2
g R r T
100 2 100
g Rr T
2
50 2 0.02 100
= 0.04 0.04 100
=8%

Q9. In the circuit shown below, the key is pressed at time t 0 . Which of the following
statement (s) is (are) true
40 F
25k
-
V
+
50k 20 F
A
+ -
Key
5V
A) The voltmeter displays -5V as soon as the key is pressed, and displays +5V after a
long time
B) The voltmeter will display 0 V at time t 1n 2 seconds
C) The current in the ammeter becomes 1/e of the initial value after 1 second
D) The current in the ammeter becomes zero after a long time
KEY: ABCD
SOL: Let VB 0 VA 5V
Voltmeter is ideal
A) At t 0 q=0 in both the capacitor VC VB 0 and VA VD 5V
VC VD 5V but the voltmeter cannot read this negative value
At t : I 0 V 0 across both resistors VA VC 5V VD VB 0V VC VD 5V
This can be shown by voltmeter
q1
B) VA VD 5 1 e t / R1C1 5 1 e t
C1
1 5
At t ln2, VA VD 5 1 V
2 2
t
5
VA VC E e 5e t V
R2C2
2
1 2 VC VD 0 reading of voltmeter
C) I I1 I 2
1 1

E e t I 0e t
R1 R2
At t=I &, I= I 0 / e
D) At t , I I 0 / 0

Q10. A rigid wire loop of square shape having side of length L and resistance R is moving
along the x-axis with a constant velocity v0 in the plane of the paper. At t 0, the right
edge of the loop enters a region of length 3L where there is a uniform magnetic field
B0 into the plane of the paper, as shown in the figure. For sufficiently large v0 , the loop
eventually crosses the region. Let x be the location of the right edge of the loop. Let
v(x), I(x) and F(x) represent the velocity of the loop, current in the loop, and force on
the loop, respectively, as a function of x. Counter-clockwise current is taken as
positive.
+ + ++
+ + ++
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R
L
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V0
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x
0 L 2L 3L 4L
Which of the following schematic plot(s) is (are) correct? (Ignore gravity)

F(x)
V(x)
V0
x
0 L 2L 3L 4L
x
0 L 4L
A) B) 2L 3L
I(x)
I(x)
3L 4L
L
x
0 2L
L 4L
x
3L
D) D) 0 2L
KEY: BC

SOL: For O L
e BL
BL
i
R
B 2 L2
F BiL
R
B L
2 2
B 2 L2 B 2 L2 B 2 L2 BL
a Vd V dx x V0 i
V
x V0
mR 0
mR mR mR 2 R
BL B 2 L2
Force F BL V0 2
x
R mR
2 2
B L 3 3
BL enet 0
F V0 x From L to 3L
R mR 2 i 0 F 0 V constant
From 3L to 4L: Direction of induced current will be reversed, sot e conductions are just opp to
thenof 0 to L
Q11. While conducting the youngs double slit experiment, a student replaced the two slits
with a large opaque plate in the x-y plane containing two small holes that act as two
coherent point sources (S1, S2 ) emitting light of wavelength 600nm. The student
mistakenly placed the screen parallel to the x-z plane (for z>0) at a distance D=3 m
from the mid-point of S1S2 , as shown schematically in the figure. The distance between
the sources d=0.6003mm. The origin O is at the intersections of the screen and the line
joining S1S2 , which of the following is(are) true of the intensity pattern on the screen?
Screen
z
o
S1 S2 y
d x
D
(A) Semi circular bright and dark bands centered at point O

(B) Straight bright and dark bands parallel to the x-axis
(C) The region very close to the point O will be dark
(D) Hyperbolic bright and dark bands with foci symmetrically placed about O in the
x-direction
KEY: AC

SOL: Locus of points p such that S1P S2 P constant is a circle. Can the given screen, only
semicircle is formed. Hence caption s(B) (D) are wrong
(C) path difference at O is x=d
= 6.003 104 m
x 6.003 104
1000.5
6 107
x
1000 dark is formed at O
2
Q12. Consider two identical galvanometers and two identical resistor with resistance R. If
the internal resistance of the galvanometers RC R / 2, Which of the following
statement (s) about any one of the galvanometers is (are) true?
(A) The maximum voltage range is obtained when all the components are connected
in series
(B) The maximum voltage range is obtained when the two resistors and one
galvanometer are connected in series, and the second galvanometer is connected in
parallel to the first galvanometer
(C) The maximum current range is obtained when all the components are connected in
parallel
(D) The maximum current range is obtained when the two galvanometers are
connected in series and the combination is connected in parallel with both the resistors
KEY: AC
SOL: For A
VA ig 29 2R
For B
VB ig 9 2ig 2R
ig G 2R 2R
As G < R So VB VA
For C ic 2ig i1 i2
G G 2G
2ig 2ig 2ig 1 For D i0 ig i1 i2 ig 2i
R R R
1 2G G G 1
2ig 2ig 1 As G < R/2 ic iD
2 R R R 2

Q13. Light of wavelength ph falls on a cathode plate inside a vacuum tube as shown in the
figure. The work function of the cathode surfaces is and the anode is a wire mesh of
conducting material kept at a distance d from the cathode. A potential difference v is
maintained between the electrodes. If the minimum de Broglie wavelength of the
electrons passing through the anode is e , Which of the following statement(s)
is(are)true?
Light
Electrons
V
- +
(A) e increases at the same rate as ph for ph hc /
(B) e decreases with increases in and ph

(C) e is approximately halved, if d is doubled
(D) For large potential difference (v / e), e is approximately halved if V made
four times
KEY: D
SOL: Can reacting anode, maximum kinetic energy of electrons is KEmax 47 w0 Ve
h
minimum de Broglie wavelength e
2 KEmax m
h
e
2 ve h w0 m
Given that Ve W0 (h is also small for visible light)
1
e
V
when V is made 4 times, e will be doubled

Q14. Two thin circular discs of mass m and 4m, having radii of and 2 , respectively,
are rigidly fixed by a massless, rigid rod of length l 24 through their centers. This
assembly is laid on a firm and flat surface, and set rolling without slipping on the
surface so that the angular speed about the axis of the rod is . The angular
momentum of the entire assembly about the point O is L ( see the figure). Which of
the following statement(s) is (are)true?
4m
z
m
l
2a
l a
(A) The Magnitude of the z-component of L is 55m 2

(B) The center of mass of the assembly rotates about the z-axis with an angular speed
of / 5
(C) The magnitude of angular momentum of center of mass of the assembly about the
point O is 81m 2
(D) The magnitude of angular momentum of the assembly about its center of mass is
17m 2 / 2
KEY: B


This section contains TWO questions.
Based on each paragraph, there are TWO questions.
options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
Full Marks : +3 If only the bubble corresponding to all the correct option is
darkened.
Zero Marks : 0 In all other cases.
PARAGRAPH-1
A frame of reference that is accelerated with respect to an inertial frame of reference
is called a non-inertial frame of reference. A coordinate system fixed on a circular disc
rotating about a fixed axis with a constant angular velocity is an example of a non-
inertial frame of reference. The relationship between the force F rot experienced by the
particle in an inertial frame of reference is F rot Fin 2m vrot m r , where
urot is the velocity of the particle in the rotating frame of reference and r is the
position vector of the particle with respect to the centre of the disc
Now consider a smooth slot along a diameter of a disc of radius R rotating counter-
clockwise with a constant angular speed about its vertical axis through its center.
We assign a coordinate system with the origin at the center of the disc, the x-axis
along the slot, the y-axis perpendicular to the slot and the z-axis along the rotation axis
k . A small block of mass m is gently placed in the slot at r R / 2 i at t 0 and
is constrained to move only along the slot

m
R/2
Q15. The distance r of the block at time t is

R R t t R R 2t 2t
A) cos 2t B) (e e ) C) cos t D) (e e )
2 2 2 2
KEY: B

SOL: F in 0 (Resultant of weight and normal force from f(or0 2m V rot w will be 1r to the
wall of solt and is balanced by its normal force

F net m w r w mrw2 i

V r
dv
a rw V 2
rw2 vdr w2 rdr
dr 0 R
2
2 R2
2
R
V w r V w r 2
2 2
4 2
dr Vdt
2
R
r t
dr
dr w r dt w dt
2
2 2
R R 0
r2
2
2
r
2r 2r
cosh wt cosh 1 cosh 1 1 wt
1
R R R
2
2r 2r
cosh 1 wt cosh wt
R R
R R
r= e wt +e-wt = e wt +e-wt
2 4
Q16. The net reaction of the disc on the block is
1
(A) m 2 R sin t j mgk (B)) m 2 R(e2t e2t ) j mgk
2
1
(C) m 2 R(et et ) j mgk (D) m 2 R cos tj mgk
2
KEY: C
SOL: R=R graound +R wall + = mg k+2 m v w j
2 R 2 2 R 2 wt -wt 2 R 2 w 2R 2 2wt -2wt
V w r w
2 2
e +e - =
4 16

e +e +2-4
4 16
V
wR 2 wt
4
e e2 wt 2
wR wt
4
e e wt 2mvw
= 2mw
wR wt
4
e e
wt mw2 R wt
2
e e wt From-
(1), R mgk
mw2 R wt
2

e w wt

PARAGRAPH-2
Consider an evacuated cylindrical chamber of height h having rigid conducting plate
at the ends and an insulating curved surface as shown in the figure. A number of
spherical balls made of a light weight and soft material and coated with a conducting
material are placed on the bottom plate. The balls have a radius r h . Now a high
voltage source HV is connected across the conducting plates such that the bottom
plate is at V0 and the top plate at V0 . Due to their conducting surface, the balls will
get charged, will become equipotentail with the plate and are repelled by it. The balls
will eventually collide with the top plate, where the coefficient of restitution can be
taken to be zero due to the soft nature of the material of the balls. The electric field in
the chamber can be considered to be that of a parallel plate capacitor. Assume that
there are no collisions between the balls and the interaction between them is negligible
(Ignore gravity)
A
-
HV
Q17. Which one of the following statements is correct?

(A) The balls will execute simple harmonic motion between the two plates
(B) The ball will stick to the top plate and remain there
(C) The balls will bounce back to the bottom plate carrying the same charge they
went up with
(D) The balls will bounce back to the bottom plate carrying the opposite charge they
went up with
KEY: D
SOL: When they collide and stick to upper place, they come to the potential of upper plate
acquiring ve charge, same amount as initial +ve charge in a very short time internal
Q18. The average current in the steady state registered by the ammeter in the circuit will be
(A) proportional to V02
(B) Zero
(C) proportional to the potential V0
(D) proportional to V01/2
KEY: A

SOL: Acceleration a
Eq 2V0 q

2h

2h hm h2m
time of journey t
m h m a 2V0 q V0 q
Nq Vq
Average current I Nq 20
t hm
1
I q V0
3/2 2
But q CV0 4 0rV0 q V0

From 1, 2 I V0
2
PART II: CHEMISTRY
This Section Contains SIX questions.

Each question has FOUR options (A), (B), (C) and (D) . ONLY ONE of those
four options is Correct
For each question ,darken the bubble corresponding to the correct option in the
ORS.
For each question ,marks will be awarded in one of the following categories:
Full Marks : +3 If only the bubble corresponding to the correct option in
darkened .
Zero Marks : 0 If none of the bubbles is darkened .
Negative Marks: -1 In all other cases
19. The geometries of the ammonia complexes of Ni 2 , Pt 2 , and Zn2 , respectively, are
A) Octahedral, square planar and tetrahedral
B) Square planar, octahedral and tetrahedral
C) tetrahedral, Square planar and octahedral
D) octahedral , tetrahedral and Square planar
Key: A
2 2 2
Sol: Ni NH 3 6 , Pt NH 3 4 , Zn NH 3 4

20. The correct order of acidity for the following compounds is

CO 2 H
CO 2 H
CO 2 H CO 2 H
HO
OH OH
OH
OH
I II III IV
A) I II III IV B) III I II IV
C) III IV II I D) I III IV II
Key: A
Sol: I II III IV
21. For the following electrochemical cell at 298K,
pt (s) H 2 ( g ,1bar ) H (aq,1M ) M 4 (aq), M 2 (aq) pt (s)
M 2 (aq)
Ecell 0.092V when 10 x .
M (aq)
4
RT
Given: EM0 4
/ M 2
0.151V ; 2.303 0.059V The value of x is
F
A) -2 B) -1 C) 1 D) 2
Key: D
Sol: Pt , H 2 1 bar H 1M M 4 M 2 Pt
H 2 2H 2e , E 0 0
M 4 2e M 2 , E 0 0.151
H 2 M 4 aqu 2H M 2 aqu ; E 0 0.151
H 2 M 2
log 4
2.303RT
EE 0
F M

M 2 M 2
log 4
2.303RT aqu 2.303RT
0.092 0.151 0.059

log
2F M 4 2F M
aqu
M 2 M 2
log 4 4 102 10 x x 2
0.059
0.059
2F M M


22. In the following reaction sequence in aqueous solution , the species X , Y and Z ,
respectively, are
Ag Ag with time
2
S 2O 3 X Y Z
white
clear precipitate black
solution precipitate
A) Ag (S2O3 )2 , Ag2 S2O3 , Ag2 S B) Ag (S2O3 )3 , Ag2 SO3 , Ag2 S
3 5
C) Ag (SO3 )2 , Ag2 S2O3 , Ag D) Ag (SO3 )3 , Ag2 SO4 , Ag

3 3
Key: A
3
Ag S 2 O3
2

Ag 2 S 2 O3 Ag 2 S
Ag Ag
S 2 O3
2
(white ppt) (Black ppt)

(Soluble complen)
Sol:
23. The qualitative sketches I, II and III given below show the variation of surface
tension with molar concentration of three different aqueous solutions of KCl , CH3OH
and CH3 (CH 2 )11 OSO3 Na at room temperature. The correct assignment of the sketches
is
I II
III
S u rfa c e te n s io n
S u rfa c e te n sio n
S u rfa c e te n sio n
Concentration Concentration Concentration
A) I: KCl II:CH 3OH III: CH3 (CH 2 )11 OSO3 Na

B) I:CH3 (CH 2 )11 OSO3 Na II:CH 3OH III:KCl
C) I: KCl II: CH3 (CH 2 )11 OSO3 Na III: CH3OH
D) I:CH3OH II:KCl III: CH3 (CH 2 )11 OSO3 Na
Key: D
Sol: Surface tension deepens on attractive forces holding the size together
I CH3OH H 2O ve deviation sol ' s
II KCl H 2 monovolatile solution
III micelle formation

24. The major product of the following reaction sequence is

O
i) HCHO (excess)/ NaOH, heat
+
ii) HCHO/H (catalytic amount)
O OH
O O O O OH O O
HO
A) B) C) D) OH
Key: A
Sol:
O
O
H
O O
HO
H C H
O
O OH OH O
H C H
C OH H C OH
H +
O O cromecl
H commizora

SECTION 2 (Maximum Marks :32)

This Section Contains EIGHT questions .
Each question has FOUR options (A),(B),(C) and (D). ONE OR MORE THAN
ONE of
these four options (s) is (are) correct .
For each question, darken the bubble(s) corresponding to all the correct options (s) in
the ORS.
For each question , marks will be awarded in One of the following categories:
Full Marks : +4 If only the bubble(s) corresponding to all the correct
options(s), Is (are) darkened .
Partial Marks : +1 For darkening a bubble corresponding to each correct
option, Provided NO incorrect option is darkened.
For example , if (A),(C)and (D) are all the correct options for a question , darkening
all these three will result in +4 marks ; darkening only (A) and (D) will result in +2
marks ; and darkening (A) and (B) will result in -2 marks, as a wrong option is also
darkened.
25. According to Molecular Orbital Theory,
A) C22 is expected to be diamagnetic
B) O22 is expected to have a longer bond length than O2
C) N 2 and N 2 have the same bond order

D) He2 has the same energy as two isolated He atoms
Key: AC
Sol: a) C22 =14 electrons
b) O22
Band order-3, O2 Band order-2
c) N 2 , N 2 have same number of electrons

d) He2 has 0.5 Bond order, which has dissociation energy
26. The nitrogen containing compound produced in the reaction of HNO with P O
3 4 10
A) can also be prepared by reaction of P and HNO
4 3
B) is diamagnetic
C) contains one N-N bond
D) reacts with Na metal producing a brown gas

Key: BD
HNO P O N O HPO
3 4 10 2 5 3
Sol:
P HNO H PO
3 4 NO
a) 4 3 2
N O
2 5
b) is diamagnetic
O O
N O
2 5 N O N
c) O
d) Na N O Na O NO
2 5 2 2
Browngas
27. Extraction of copper from copper pyrite (CuFeS ) involves

2
A) crushing followed by concentration of the ore by froth-flotation
B) removal of iron as slag
C) self-reduction step to produce blilster copper following evolution of SO
2
D) refining of blister copper by carbon reduction
Key: ABC
Sol: Cu is refined by cupellation and electrolightic refining
28. Reagent(s) which can be used to bring about the following transformation is (are)
O O O O
C C
O
H H
O O
COOH COOH
A) LiAlH in C2 H5 O B) BH in THF
4 2 3
C) NaBH in C H OH D) Raney Ni / H in THF
4 2 5 2
Key: C
Sol: LAH reduces acid m Ester and aldehyde BH 3 / THF reduces acid, ester and aldehyde
NaBH 4 reduces only aldehyde group
0
29. Mixture(s) showing positive deviation from Raoults law at 35 C is (are)
A) carbon tetrachloride+methanol B) carbon disulphide+acetone
C) benzene+toluene D) phenol+aniline
Key: AB

Sol: A, B shows +ve deviation C shows ideal nature d shows ve deviation

30. The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure
is (are)
A) The number of the nearest neighbours of an atom present in the topmost layers is
12
B) The efficiency of atom packing is 74%
C) The number of octahedral and tetrahedral voids per atom are 1 and 2, respectively
D) The unit cell edge length is 2 2 times the radius of the atom
Key: BCD
Vol .ofatom
Sol: Packing fraction 100
Vol .of unit cell
4
4 r 3
3 100
a 3
4
4 r 3
3 100

3
2 2r
=74%
Total no.of octahedral and tetrahedral voids 4 and 8 respectively
31. For invert sugar, the correct statement(s) is (are)
(Given: specific rotations of (+)-sucrose, (+)-maltose, L (-)-glucose and L(+)-fructose
0 0 0 0
in aqueous solutions are 66 , 140 , 52 and 92 , respectively)
A)invert sugar is prepared by acid catalyzed hydrolysis of maltose
B) invert sugar is an equimolar mixture of D-(+)-glucose and D-(-)-fructose
0
C) specific rotation of invert sugar is 20
D) on reaction with Br water, invert sugar forms saccharic acid as one of the
2
products
Key: BC
Sol: invert sugar is equimolar mixture of D-(+)-glucose and D-(-)- fructose specific
0
rotation of invert sugar is 20 .

32. Among the following, reaction(s) which gives(give) tert-butyl benzene as the major
product is(are)
Br
Cl
NaOC H AlCl
2 5 3
A) B)
OH
H SO BF OEt
C) 2 4 D) 3 2
Key: BCD
AlCl
3
AlCl
3
Cl
NH
Sol:
BF
3
no
OH O t
2 , rearrangement happens,as BF is weak lewis acid
3


This section contains TWO questions .
Based on each paragraph ,there are TWO questions .
Each questions has FOUR options (A),(B),(C)and (D).ONLY ONE of these four
options is correct.
For each question , darken the bubble corresponding to the correct integer in the ORS.
For each question ,marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases
PARAGRAPH-1
Thermal decomposition of gaseous X to gaseous X at 298 K takes place according
2
to the following equation: X

2
g 2X g
0
The standard reaction Gibbs energy, G , of this reaction is positive. At the start of
r
the reaction, there is one mole of X and no X. As the reaction proceeds, the number
2
of moles of X formed is given by . Thus, is the number of moles of
equilibrium
X formed at equilibrium . The reaction is carried out at a constant total pressure of 2
1 1
bar. Consider the gases to behave ideally. (Given : R=0.083 L bar K mol )
33. The equilibrium constant K for this reaction at 298 K, in terms of , is

P equilibrium
8 2equilibrium 8 2equilibrium
A) B)
2 equilibrium 4 2equilibrium
4 2equilibrium 4 2equilibrium
C) D)
2 equilibrium 4 2equilibrium
Key: B
Sol: X 2 2 x, ve
1 0

1
2


1
Px2 2 x2 2 2
2
1
2
4
Px .2
2
1
2
2
4
2 16 2 2
kp
2 2 22
2
2 .2

8 2

4 2
34. The INCORRECT statement among the following , for this reaction, is
A) Decrease in the total pressure will result in formation of more moles of gaseous X
B) At the start of the reaction, dissociation of gaseous X takes place spontaneously
2
C) =0.7
equilibrium
D) K 1
c
Key: C
Sol: value cannot be calculated
PARAGRAPH-2

Treatment of compound O with KMnO / H gave P, which on heating with
4
ammonia gave Q. The compound Q on treatment with Br / NaOH produced R. On
2
strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in
the presence of KOH followed by acidification, gave a compound T.
(O)

35. The compound R is

O
Br
NH
2
Br
A)
NH
2 B) O
O O
NHBr
NBr
NHBr
C) O D) O
Key: A
Sol:
COOH
KMnO4
H
COOH
(O) (P)
NH 3
O O
C NH 2
strong
NH heating NH 2
C
O O
O (Q)
Gabriel OH &
phthalimide
synthesis CH 3 CH C O
Br2 / KOH
Br
O
CH 3
NH 2
N CH COO t (R)
NH 2
O
H / H 2O
COOH
CH 3 CH COOH
Alanine
COOH NH 2
(T)

36. The compound T is

A) glycine B) alanine C) valine D) serine
Key: B
Sol:
COOH
KMnO4
H
COOH
(O) (P)
NH 3
O O
C NH 2
strong
NH heating NH 2
C
O O
O (Q)
Gabriel OH &
phthalimide
synthesis CH 3 CH C O
Br2 / KOH
Br
O
CH 3
NH 2
N CH COO t (R)
NH 2
O
H / H 2O
COOH
CH 3 CH COOH
Alanine
COOH NH 2
(T)

MATHEMATICS
This section contains SIX questions.
options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS
Full Marks : +3 If only the bubble corresponding to the correct option is
darkened.
Q37. Area of the region x, y 2 : y x 3 ,5 y x 9 15 is equal to
1 4 3 5
A) B) C) D)
6 3 2 3
KEY: C
SOL:
3 1
x9
1
Area 4 5 dx 4 x 3 dx 3 x 3dx
3
1 x2
1
2 3
2 3 1

9 x x 3 2 x 3 2
5 2 4 3 4 3 3
1 19 2 2
28 0 1 8
5 2 3 3
19 28 3
6
20 5 2
13
1
Q38. The value of is equal to
k 1 k 1 k
sin sin
4 6 4 6
A) 3 3 B) 2 3 3 C) 2 3 1 D) 2 2 3
KEY: C
SOL:
k sin
sin k 1
4 6 4 6
13
1
k sin
sin k 1 sin k 1
6 4 6 4 6
1 13
cot
4
6
cot
sin 4
6

2 1 2 3
2 3 2

Q39. Let bi 1 for i 1, 2,..,101 . Suppose loge b1 , loge b2 ,.., loge b101 are in arithmetic progression
(A.P). With the common difference loge 2 . Suppose a1 , a2 ,...., a101 are in A.P such that
a1 b1 and a51 b51 .If t b1 b2 ..... b51 and s a1 a2 .... a51, then
A) s t and a101 b101 B) s t and a101 b101
C) s t and a101 b101 D) s t and a101 b101
KEY: B
SOL:
b1 , b2 , b3 .....b101 in GP with common ratio 2
= a1 , a2 , a3 ,...a101 in A.P
a51 b51 a1 50d a1.250
t b1 1 2 22 ....250 a1 251 1
a1 a51 a1 1 250
51 51
s
2 2
t r
a101 a1 100d a1 2 250 1 a1 251 1
b101 a1 2100
Clearly b101 a101
Q40. Let P be the image of the point (3, 1, 7) with respect to the plane x y z 3 . Then
x y z
the equation of the plane passing through P and containing the straight line
1 2 1
is
A) x y 3z 0 B) 3x z 0 C) x 4 y 7 z 0 D)
2x y 0
KEY: C
SOL: Let h k l be image of 317 in x y z 3
h 3 k 1 l 7 6
2 4
1 1 1 3
h k l 1,5,3
p 1,5,3 now plane three P containing
x y z
is
1 2 1
x 1 y 5 z 3
1 5 3 0
1 2 1
x 4 y 7z 0

1 0 0
Q41. Let P 4 1 0 and I be the identity matrix of order 3. If Q qij is a matrix such
16 4 1
q q
that p50 Q 1, then 31 32 equals
q21
A) 52 B)103 C) 201 D) 205
KEY: B
SOL:

1 0 0

Pn 4n 1 0
n n 1
16 4n 1
2
1 0 0 1 0 0

P I 200
50
1 0 0 1 0 Q
20400 200 1 0 0 1
q31 q32 20400 200
103
q21 200

2
x 2 cos x
Q42. The value of
1 ex
dx is equal to
2

2 2
A) 2 B) 2 C) 2 e 2 D) 2 e 2
4 4
KEY: A
SOL:

2
2
x cos x 2
x 2 cos x
I 1 ex
dx 1 e x

2 2

2 2
2I x 2 cos xdx I x 2 cos xdx
0

2

2
I x 2 sin x 2 2sin xdx
0
0

2
2 2
2
2 x cos x 2 cos x dx 2
4 0 0
4

SECTION 2 (Maximum Marks :32)

This Section Contains EIGHT questions .
Each question has FOUR options (A),(B),(C) and (D). ONE OR MORE THAN
ONE of
these four options (s) is (are) correct .
For each question, darken the bubble(s) corresponding to all the correct options (s) in
the ORS.
For each question , marks will be awarded in One of the following categories:
Full Marks : +4 If only the bubble(s) corresponding to all the correct
options(s), Is (are) darkened .
Partial Marks : +1 For darkening a bubble corresponding to each correct
option, Provided NO incorrect option is darkened.
For example , if (A),(C)and (D) are all the correct options for a question , darkening
all these three will result in +4 marks ; darkening only (A) and (D) will result in +2
marks ; and darkening (A) and (B) will result in -2 marks, as a wrong option is also
darkened.
x
n n n
n x n x .... x
n
.Q43. Let f x Lt 2 n
for all x 0 . Then
n n 2 n2
2 2
n ! x n x .... x 2
2
2
4 n
A) f f 1 B) f f
1 1 2
2 3 3
f 3 f 1 2
1
C)
f 1
2 0 D) 1 1
f 3 f 2
KEY: ABCD
SOL:

x
n n n n x 2 x 3x nx n
n .n. . .... 1 1 1 .... 1
2 3 n n n n n
f x lim
x 00 x 4 x n 2 x 2
2 n n n
2 2 2 2 2
n !n 2 1 2 1 2 .... 1 2
4 9 n n n n
x
lim x
1 1 2 3....n
e x00 n 1
1 2 1 2 ....n
2
n x 2 2
n
lim
x00 n n 1 6
e 1
n n 1 2n 1
and a2 b2 0. suppose S z C : z
1
Q44. Let a, b , t , t 0 , where i 1. If
a ibt
z x iy and z S , then x, y lies on
and center , 0 and a 0, b 0

1 1
A) the circle with radius
2a 2a
and center , 0 a 0, b 0
1 1
B) the circle with radius
2a 2a
C) the x-axis for a 0, b 0
D) the y-axis for a 0, b 0
KEY: ACD
SOL:
1
z , t R, t 0
a bit
a bit
z 2 x iy
a b 2t 2
x a ay
t
y bt bx
x a x2 y2
x
x2 y2
a
centre , 0
1 1
Circle with radius
2a 2a
1
Also if b 0, a 0 z purely real lies on x-axis
a
1
if b 0, a 0 z purely imaginary lies on y-axis
bit
Q45. Let f : 0, and g : be twice differentiable functions such that f 11 and g11

Are continuous functions on . Functions on . Suppose f 1 2 g 2 0 , f 11 2 0

f x g x
and g ' 2 0. If lim 1 , then
x 2 f ' x g' x
A) f has a local minimum at x 2
B) f has a local maximum at x 2
C) f '' 2 f 2
D) f x f '' x 0 For at least one x R
KEY: AD
SOL:
f x g x
lim 1
x 2 f ' x g' x
f ' x g x f x g' x
lim '' 1
x 2 f x g ' x f ' x g '' x
f 2 g ' 2
'' 1 f '' 2 0 range of f is 0, 00
f 2 g 2
'
f has minimum
Q46. Let P be the point on the parabola y 2 4 x which is at the shortest distance from the
centre S of the circle x2 y 2 4 x 16 y 64 0 . Let Q be the point on the circle dividing
the line segment SP internally. Then
A) SP= 2 5
B) SQ : QP 5 1 : 2
C) the x-intercept of the normal to the parabola at P is 6
1
D) the slope of the tangent to the circle at Q is
2
KEY: ACD
x 2 y 8 4
2 2
SOL:
y2 4x
Normal to
y xt 2t t 3
If it passes through(2,8) then 8+2t=2t+ t3
t 2
P(4,4) eq to SP is 2 x y 12
S(2,8) SP 4 16 2 5

2 4 8 4 2 4
Then Q ,
4 , 4
1 1 1 1
Q lie, on the circle
2 2
2 4
2 4 4
1 1
2
1
4 16 1 4
1
5 1
2
1 1
1
1 5 4
Let Q is (2-t,8+2t)
2
t 2 4t 2 4 t
5
8 8 2t t 5 1
Ratio
8 2t 4 t 2 4
X-intercept of normal=6
1
Slope of tangent to circle at Q=
2
Q47. Let a, b and f : be defined by f x a cos x3 x b x sin x3 x . Then f is
A) Differentiable at x 0 if a 0 and b 1
B) Differentiable at x 1 if a 1 and b 0
C) NOT differentiable at x 0 if a 1 and b 0
D) NOT differentiable at x 1 if a 1 and b 1
KEY: AB
SOL: A)
f x x sin x x 3 x
f x f 0
lim lim sin x3 x 0
x 0 x0 x 0
f x f 0
lim lim sin x3 x 0
x 0 x0 x 0

f x f 1 cos x3 x
lim lim 0
x 1 x 1 x 1 x 1
B)
f x f 1 sin x3 x
lim lim 0
x 1 x0 x 1 x 1
f x f 1 cos x x 1
3
lim lim 0
x 0 x x 0 x
C)
f x f 0 sin x x3 1
lim lim 0
x 0 x x 0 x
f x f 1 cos x x3 x sin( x3 x) 1 sin x

lim lim 0
x 1 x 1 x 1 x 1
D) Are equal
f x f 1 cos x x3 x sin x( x3 x) 1 sin x
lim lim 0
x 1 x 1 x 1 x 1
Q48. Let u u1 i u2 j u3 k be a unit vector in 3

and 1 i j 2k . Given that three
6
exists a vector v in 3

such that u v 1 and u v 1 which of the following
statement(s) is (are) correct?

A) There is exactly one choice for such v
B) There are infinitely many choices for such v
C) if u lies in the xy plane then u1 u2
D) if u lies in the xz plane then 2 u1 u3
KEY: BC
SOL:
u 1, w 1, u v 1 v sin u, v 1
w. u v 1 w u v cos w, u v 1
sin u, v cos , u v v 1
cos , u v 1
Infinite choices for v and u.w=0

Q49. Let a, , . Consider the system of linear equation ax 2 y , 3x 2 y
Which of the following statement(s) is (are) correct?
A) If a 3, then the system has infinitely many solutions for all values and

B) If a 3, then the system has a unique solutions for all values and
C) If 0 then the system has infinitely many solutions for a 3
D) If 0, then the system has no solution for a 3
KEY: BCD
SOL: a) 3 equations are
3 x 2 y
3x 2 y
3 x 2 y
3x 2 y
Will have infinite solutions only, when not for all &
hence option
b) 3 Then 2 6 0
Q50. Let f : , 2 and g : , 2

1 1
be functions defined by f x x 2 3 and
2 2
g x x f x 4 x 7 f x , where [y] denotes the greatest integer less than or equal to
y for y .Then
A) f is discontinues exactly at three points in , 2

1
2
B) f is discontinues exactly at four points in , 2
1
2
C) g is NOT differentiable exactly at four points in , 2
1
2
D) g is NOT differentiable exactly at five points in , 2
1
2
KEY: BC
SOL:
1
f x x 2 3 , x , 2
2 Is discontinuous at x 1, 2, 3 , 2
g x x f x 4 x 7 f x is not differentiable at x 0,1, 2, 3

1
7 5 x x 3 , 2 x 0
2

7
g x 7 3x x 2 3 , 0 x
4
7
5 x 7 x 3 , 4 x 2
2


This section contains TWO questions.
Based on each paragraph, there are TWO questions.
options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
Full Marks : +3 If only the bubble corresponding to all the correct option is
darkened.
Zero Marks : 0 In all other cases.
Paragraph-1
Football teams T1 and T2 have to play two games against each other. It is assumed
that the outcomes of the two games are independent. The probabilities of T1 winning,
1 1 1
drawing and losing a game against T2 are , and , respectively .Each team gets 3
2 6 3
points for a win, 1 point for a draw and 0 point for a loss in a game. Let X and Y
denote the total points scored by teams T1 and T2 respectively, after two games
Q51. P ( x Y ) is
1 5 1 7
A) B) C) D)
4 12 2 12
KEY:B
SOL:
p x y T1 : W T1 : W T1 : D T1 : W T1 : W T2 : D
1 1 1

4 12 12 12
Paragraph-2
x2 y 2
Let F1 x1 ,0 and F2 x2 , 0 , for x1 0 and x2 0 , be the foci of the ellipse 1.
9 8
Suppose a parabola having vertex at the origin and focus at F2 intersects the ellipse at point M in the
first quadrant and at point N in the fourth quadrant.
Q52. P(X=Y) is
11 1 13 1
A) B) C) D)
36 3 36 2
KEY:C

SOL:
p x y T1 : W T1 : L T1 : L T1 : W T1 : D T2 : D
1 1 1 13

6 6 36 36
Q53. The orthocenter of triangle F1MN is
A) , 0 B) , 0 C) , 0 D) , 6
9 2 9 2
10 3 10 3
KEY: A
SOL:
F1 1, 0 F2 1, 0
parabola y 2 4 x
3 3
M & N are M , 6 N , 6
2 2
9
orthocenter is , 0
10
Q54.If the tangents to the ellipse at M and N meet at R and the normal to the parabola at M
meets the x-axis at Q, then the ratio of area of the triangle MQR to area of the
quadrilateral MF1 NF2 is
A) 3:4 B) 4:5 C) 5:8 D) 2:3
KEY: C
SOL: tangent at M&N
x 64
1
6 8
x 64
1
6 8
Ris 6,0
7
Normal to parabola at M is 6 x 24 6
2
5 6
7 Area of MQR 5
Q , 0 4
2 Area of Qual MF1 NF2 2 6 8

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Sri Chaitanya IIT Academy.

,India [P-2]_Question Paper,Key and Solutions

OPTICAL RESPONSE SHEET:

16. Darken the bubble COMPLETELY.

2016 JEE-ADVANCED_CODE-4 Page 2

2016 JEE-ADVANCED_CODE-4 Page 3

2016 JEE-ADVANCED_CODE-4 Page 4

Q.6 The electrostatic energy of Z protons uniformly distributed throughout a spherical

2016 JEE-ADVANCED_CODE-4 Page 5

SOL: When block is placed at a poison x0

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Which of the following schematic plot(s) is (are) correct? (Ignore gravity)

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(A) Semi circular bright and dark bands centered at point O

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2016 JEE-ADVANCED_CODE-4 Page 11

(A) e increases at the same rate as ph for ph hc /

(B) e decreases with increases in and ph

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(A) The Magnitude of the z-component of L is 55m 2

2016 JEE-ADVANCED_CODE-4 Page 13

SECTION 3 (Maximum Marks: 12)

Q15. The distance r of the block at time t is

2016 JEE-ADVANCED_CODE-4 Page 14

2016 JEE-ADVANCED_CODE-4 Page 15

Q17. Which one of the following statements is correct?

2016 JEE-ADVANCED_CODE-4 Page 16

But q CV0 4 0rV0 q V0

PART II: CHEMISTRY

SECTION 1 (Maximum Marks: 15)

This Section Contains SIX questions.

2016 JEE-ADVANCED_CODE-4 Page 17

20. The correct order of acidity for the following compounds is

2016 JEE-ADVANCED_CODE-4 Page 18

C) Ag (SO3 )2 , Ag2 S2O3 , Ag D) Ag (SO3 )3 , Ag2 SO4 , Ag

(white ppt) (Black ppt)

Concentration Concentration Concentration

A) I: KCl II:CH 3OH III: CH3 (CH 2 )11 OSO3 Na

2016 JEE-ADVANCED_CODE-4 Page 19

24. The major product of the following reaction sequence is

i) HCHO (excess)/ NaOH, heat

2016 JEE-ADVANCED_CODE-4 Page 20

SECTION 2 (Maximum Marks :32)

2016 JEE-ADVANCED_CODE-4 Page 21

27. Extraction of copper from copper pyrite (CuFeS ) involves

2016 JEE-ADVANCED_CODE-4 Page 22

Sol: A, B shows +ve deviation C shows ideal nature d shows ve deviation

2016 JEE-ADVANCED_CODE-4 Page 23

2016 JEE-ADVANCED_CODE-4 Page 24

SECTION 3 (Maximum Marks: 15)

to the following equation: X

33. The equilibrium constant K for this reaction at 298 K, in terms of , is

2016 JEE-ADVANCED_CODE-4 Page 25

2016 JEE-ADVANCED_CODE-4 Page 26

35. The compound R is

2016 JEE-ADVANCED_CODE-4 Page 27

36. The compound T is

2016 JEE-ADVANCED_CODE-4 Page 28

2016 JEE-ADVANCED_CODE-4 Page 29

2016 JEE-ADVANCED_CODE-4 Page 30

2016 JEE-ADVANCED_CODE-4 Page 31