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Solar Energy 108 (2014) 576591
www.elsevier.com/locate/solener
Received 17 May 2014; received in revised form 21 July 2014; accepted 28 July 2014
Abstract
A new multigeneration system based on an ocean thermal energy conversion system and equipped with at plate and PV/T solar col-
lectors, a reverse osmosis desalination unit to produce fresh water, a single eect absorption chiller and a PEM electrolyzer is proposed
and thermodynamically assessed. Energy and exergy analyses are employed to determine the irreversibilities in each component and
assess system performance. A multi-objective optimization method based on a fast and elitist non-dominated sorting genetic algorithm
(NSGA-II) is applied to determine the best design parameters for the system. The two objective functions utilized in the optimization are
the total cost rate of the system, which is the cost associated with fuel, component purchasing and environmental impact, and the system
exergy eciency. The total cost rate of the system is minimized while the cycle exergy eciency is maximized using an evolutionary algo-
rithm. To provide further insight, the Pareto frontier is shown for a multi-objective optimization. In addition, a closed form relation
between exergy eciency and total cost rate is derived, and a sensitivity analysis is performed to assess the eects of several design param-
eters on the system total exergy destruction rate, total cost rate and exergy eciency.
2014 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.solener.2014.07.022
0038-092X/ 2014 Elsevier Ltd. All rights reserved.
P. Ahmadi et al. / Solar Energy 108 (2014) 576591 577
Nomenclature
generate a vapor, which rotates a turbine to generate elec- making it non-viable commercially today. In order to
tricity. The working uid then is condensed back to a liquid improve the eectiveness and economics of OTEC cycles,
in a continuous process. 80% of the energy that is received it is proposed to integrate them with industrial operations
from the sun by the earth is stored in the worlds oceans so that, apart from generating electricity, they can be used
(Tchanche et al., 2011; Faizal and Rauddin Ahmed, for fresh water production, air conditioning and refrigera-
2011), and many regions of the world have access to this tion, and hydrogen production (Tchanche et al., 2011).
OTEC resource. OTEC can produce fuels by using the gen- Potential sites for OTEC have been identied, mainly in
erated electricity to produce hydrogen, which can be used the Pacic ocean, and about 50 countries are examining
in hydrogen fueled cars as well as in the development of its implementation as a sustainable source of energy and
synthetic fuels. For a small city, millions of tons of CO2 fresh water, including India, Korea, Palau, Philippines,
are generated annually through fossil fuel use while with the U.S. and Papua New Guinea (Meegahapola et al.,
OTEC the value is zero or almost zero, during the opera- 2007). In 2001, as a result of cooperation between Japan
tion of devices. OTEC has the potential to replace some and India, a 1-MW OTEC plant was built in India
fossil fuel use, perhaps via OTEC ships travelling the seas (Meegahapola et al., 2007), and others are planned to be
of the world. constructed in the near future (Esteban and Leary, 2012).
An OTEC system utilizes low-grade energy and typically Some research has been directed to the development of
has a low energy eciency (approximately 510%). There- OTEC recently. Uehara (Uehara and Nakaoka, 1984;
fore, achieving a high electricity generating capacity with Uehara and Ikegami, 1990; Uehara et al., 1996) conducted
OTEC requires the use of large quantities of seawater numerous theoretical and experimental studies on the
and, correspondingly, a high pumping power. These fac- major components of an OTEC plant, and showed that
tors detract from the cost-eectiveness of this technology, ammonia is a suitable working uid for an OTEC plant
578 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
employing a closed organic Rankine cycle (ORC). The recovery unit, an organic Rankine cycle, an ejector refriger-
energy eciency of the Rankine cycle in an OTEC plant ation cycle, a domestic water heater and a proton exchange
is usually no more than 5%, due to the small temperature membrane (PEM) electrolyzer, and the application was a
dierences between surface waters and deep waters of the two-story residential detached house in Brampton,
ocean. Thus, in order to improve the eciency of OTEC, Ontario, Canada. Ozturk and Dincer (2013) performed a
other thermodynamic cycles are being considered such as thermodynamic assessment of an integrated solar power
the Kalina and Uehara cycles, which use an ammonia tower and coal gasication system for multigeneration,
water mixture as the working uid (Yamada et al., 2009); including a parametric study to determine the eect of
these cycles are reported to have higher energy eciencies design parameters on energy and exergy eciencies of the
than a Rankine cycle operating with the same temperature system.
dierence (Yamada et al., 2009). Increasing the tempera- The main purposes of using multigeneration often are to
ture dierence between the heat source and the colder heat increase eciency and sustainability and to reduce environ-
sink can improve the eciency of OTEC plants, as can the mental impact (including global warming) and cost, and
integration of OTEC with other energy technologies. Sai- the research reported to date suggests that multigeneration
toh and Yamada (Yamada et al., 2009) proposed a concep- can support these purposes.
tual design of a multiple Rankine-cycle system using both The primary objective of the present research is to
solar thermal energy and ocean thermal energy in order improve understanding of multigeneration, by performing
to improve eciency. thermodynamic modeling and exergy and economic analy-
The overall eciency of conventional power plants that ses, of an integrated solar and OTEC based multigenera-
use a fossil fuel with a single prime mover is usually less tion system based on at plate and PV/T solar collectors,
than 40%, although advanced plants can achieve higher a reverse osmosis (RO) desalination unit to produce fresh
values. That is, more than 60% of the heating value of water, a single eect absorption chiller, an OTEC cycle
the fuel entering a conventional power plant is lost. Multi- and a PEM electrolyzer that produces hydrogen. Such mul-
generation energy systems, which in general produce sev- tigeneration system can be complicated and expensive, but
eral useful outputs from one or more kinds of energy it may nevertheless be benecial for a coastal area where
inputs, can provide many benets, including increased e- the needs of several useful commodities exist simulta-
ciency and correspondingly reduced thermal losses and neously largely because it is based on renewable energy.
wastes, reduced greenhouse gas emissions, reduced operat- Therefore, considering environmental costs is necessary
ing costs, shorter transmission lines, fewer distribution when comparing this integrated energy system with a nat-
units, multiple generation options, increased reliability, ural gas red combined cycle power plant. In addition,
and reduced likelihood of grid failure. the exergy eciency of this system is higher than that for
Ahmadi et al. (2012) carried out an exergy-based optimi- the natural gas-based system, as it generates electricity with
zation of a multigeneration energy system, containing a gas a low temperature. As a consequence, this study stresses
turbine as a prime mover, for electricity generation, heat- the importance of integrated renewable-based energy sys-
ing, cooling and domestic hot water production. They tems for sustainable development. The main steps of this
applied a multi-objective evolutionary based optimization study are:
to nd the best design parameters of the system, consider-
ing exergy eciency and total system cost as the two objec- To thermodynamically model this integrated energy
tive functions. Dincer and Zamrescu (2012) performed system.
energy and exergy analyses of renewable energy-based mul- To conduct exergy and exergoeconomic analyses of
tigeneration, considering several options for such products this integrated system.
as electricity, heat, hot water, cooling, hydrogen and fresh To apply a multi-objective optimization technique
water. Ozturk and Dincer (2012) conducted a thermody- based on a code developed in the Matlab software
namic analysis of a solar-based multigeneration system program using an evolutionary algorithm.
with hydrogen production. The solar-based multigenera- To propose a new closed-form expression for the
tion considered for this analysis consists of four main exergy eciency in terms of total cost rate at the
sub-systems: Rankine cycle, organic Rankine cycle, optimal design point.
absorption cooling and heating, and hydrogen production To derive an equation for the Pareto optimal points
and utilization. The exergy eciencies and destructions for curve that can serve as an aid for designing optimal
the subsystems and the overall system show that parabolic multigeneration plants.
dish collectors have the highest exergy destruction rate of To perform sensitivity analyses of the variation of
the components of the solar-based multigeneration system. each objective function with the main design param-
Ahmadi et al. (2013) assessed and optimized a novel eters of the system.
integrated multigeneration system for residential buildings. To select the nal optimum design point using a
The proposed multigeneration system included a heat decision-making method.
P. Ahmadi et al. / Solar Energy 108 (2014) 576591 579
Fig. 1. Schematic of renewable energy-based multigeneration system for the provision of heating, cooling, electricity, hydrogen, fresh water and hot water.
Table 1
2. System description Properties of ammonia (working uid for OTEC cycle).
Parameter Value
Fig. 1 shows a schematic of an integrated OTEC system Chemical formula NH3
equipped with at plate and PV/T solar collectors, a Molar mass (kg/kmol) 17
reverse osmosis (RO) desalination unit, a single eect Boiling temperature (C) 33.2
absorption chiller and a PEM electrolyzer. This integrated Density (kg/m3) 225
Freezing temperature (C) 77.7
system uses the warm surface seawater to evaporate a
working uid (ammonia in this study, with the thermody-
namic properties listed in Table 1), which drives an ORC
absorbing the suns heat on its panels. Hot air leaves the
turbine to produce electricity, which in turn is used to drive
PV/T solar panel at point 40 and enters the absorption chil-
a PEM electrolyzer to produce hydrogen. The processes
ler generator to drive the chiller. The electricity generated
comprising the OTEC system are shown on a TS diagram
by the PV/T unit is directed to a RO desalination plant
in Fig. 2. After passing through the turbine, the vapor is
to produce fresh water. In this multigeneration system,
condensed in a heat exchanger that is cooled by cold deep
electricity generated by the OTEC plant is used to produce
seawater. The working uid is then pumped back through
hydrogen using a PEM electrolyzer at point 22. The pro-
the warm seawater heat exchanger, and the cycle is
duced hydrogen is stored in a hydrogen storage tank for
repeated continuously. Warm surface water is pumped
later usage.
from the ocean surface at point 1. A warm surface pump
increases the pressure where the high pressure warm water
enters a at plate collector at point 2 to increase its temper- 3. Thermodynamic modeling and analysis
ature. Water enters an evaporator at point 3 and, after heat
exchange with the ORC uid, leaves the evaporator at For thermodynamic modeling, the multigeneration sys-
point 4 where it is released back to the ocean surface. A tem considered here (Fig. 1) is divided into ve sub-sys-
PV/T solar panel satises the cooling load of the system. tems: (1) OTEC system, (2) solar systems, (3) single-eect
Air enters the PV/T panel at point 41 and is warmed by absorption chiller, (4) proton exchange membrane (PEM)
580 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
electrolyzer, and (5) reverse osmosis desalination unit. We where (DHWS)SP is the friction loss of the straight pipe and
determine the temperature prole in the multigeneration (DHWS)B is the bending loss on the warm seawater pipe,
plant, input and output enthalpies, exergy ows, destruc- which are given as (Nihous and Vega, 1993):
tions and eciencies, and environmental impacts. The rel- 1:85
evant energy balances and governing equations for the LWS V WS
DH WS SP 6:82 1:17 ; C WS 100 6
main sections of the multigeneration plant in Fig. 1 are d WS C WS
described in the following subsections. X V2
DH WS B km WS 7
2g
3.1. Ocean thermal energy conversion (OTEC)
Here, LWS is the length of the warm seawater pipe, dWS is
As shown in Fig. 1, the electricity production unit is the warm seawater inner pipe diameter and VWS is the
based on an organic Rankine cycle which is suitable for velocity of warm seawater inside the pipe. Also, (DHWS)E
low-grade heat. The net power output of the system is is the pressure dierence of warm seawater in the evapora-
expressible as tor, expressible as
W_ net W_ G W_ WS W_ CS W_ WF 1
V 2WS LE
DH WS E kE 8
where W_ G is the turbine generator power, W_ WS and W_ CS are 2g Deq W
the warm and cold seawater pumping powers, and W_ WF is
where LE is the length of the evaporator plate (4 m in this
working uid pumping power.
study) and kE is 0.068, as reported in reference (Nihous and
Turbine generator power
Vega, 1993). Also, Deq is the equivalent diameter, which is
The turbine output power, determined via an the energy
calculated as
balance for a control volume around the turbine, is the
product of working uid mass ow rate, m_ F and the adia- Deq 2d 9
batic heat loss rate between the evaporator and the con-
where d is the clearance.
denser, as follows:
Cold seawater pumping power
W_ G m_ F gT gG h5 h6 2 The cold seawater pumping power can be expressed as
Here, gT and gG are the turbine isentropic eciency and m_ CS DH CW g
generator mechanical eciency, respectively. W_ CS 10
gCSP
Warm seawater pumping power
The warm seawater pumping power can be written as where gCSP is the cold seawater pump eciency and DHCW
is the total pump head of the cold seawater piping, given as
m_ WS DH WS g
W_ WS 3
gWSP DH CS DH CS P DH CS C DH CS d 11
where DHWS is the total pump head dierence of the warm Here, (DHCS)P is the pump head of the cold seawater pipe
seawater piping (Nihous and Vega, 1993): (Nihous and Vega, 1993):
DH WS DH WS P DH WS E 4
DH CS P DH CS SP DH CS B 12
Here, (DHWS)P is the pump head of the warm seawater
pipe, which can be expressed as: These two terms are similar to the terms in Eqs. (6) and (7).
Also, (DHCS)C is the cold seawater pressure dierence in
DH WS P DH WS SP DH WS B 5 the condenser, expressible as
P. Ahmadi et al. / Solar Energy 108 (2014) 576591 581
Q_ u AP F R saI QL 16 T air;in 4
air Cp air
5 23
bU L L
m_ air Cpair
Here, FR is heat removal factor, dened as:
" n o# The thermal eciency of the PV/T collector is dened as
F 0 U l AP
_ p
mC mC
Q_
_ p
FR 1e 17
U l AP gth 24
_
IbL
Here, F0 is the collector eciency factor, which is approxi- Here, I_ is the solar intensity and b and L are the width and
mately 0.914 for this case (Farahat et al., 2009), and Ul is length, respectively, of the PV/T panel.
the overall collector loss coecient, obtained from
Farahat et al. (2009). In Eq. (16), (sa) is optical eciency 3.4. Absorption chiller
and I is solar radiation intensity. Also, QL is dened as:
The principle of mass conservation and the rst and sec-
QL U l T in T 0 18
ond laws of thermodynamics are applied to each compo-
The energy eciency of the solar at plate collector is nent of the single-eect absorption chiller. In our
expressed as analysis, each component is considered as a control volume
with inlet and outlet streams as well as heat and work inter-
Q_ u
g 19 actions. Mass balances are applied for the total mass and
IAP each material of the working uid solution. The governing
and conservation equations for total mass and each mate-
3.3. Solar PV/T system rial of the solution for a steady state and steady ow case
follow (Farshi et al., 2012):
In this integrated multigeneration energy system, a PV/ X X
m_ i m_ o 25
T solar panel is considered as shown on the left side of
Fig. 1. To model the PV/T system, we consider the
X X
approach used by Joshi et al. (2009). The power produced mx
_ i mx
_ 0 26
by the PV module is calculated as
Here, m_ is the working uid mass ow rate and x is mass
W_ gc Ib
_ c sg A 20
concentration of Li-Br in the solution. For each compo-
where gc is the solar cell eciency, equal to 0.38 in this nent of the absorption system, a general energy balance is
study, bc is the packing factor of solar cell (0.83 here based written:
582 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
X X
Q_ W_ m_ o ho m_ i hi 27 DP m_ 13
W_ pump 30
gpump q13
The cooling load of the absorption chiller is dened as
DP m_ 16 gturbine
W_ turbine 31
q16
Q_ cooling mh
_ 28 h27 28
where DP is the trans-membrane pressure and gpump and
Further information about the thermodynamic modeling gturbine are the RO pump and hydro-turbine isentropic e-
and energy balances for each component is given in ciencies respectively. The target fresh water ow rate m_ 15 is
Palacios-Bereche and Gonzales (2012). dependent on the electricity driving the RO and the recov-
ery ratio RR, which is a technical characteristics of the
3.5. PEM electrolyzer membrane, as follows:
m_ 13
The PEM electrolyzer for H2 production is illustrated m_ 15 32
RR
on the right side of Fig. 1. During electrolysis, electricity
and heat are both supplied to the electrolyzer to drive The trans-membrane pressure can be expressed as follows:
the electrochemical reactions. As shown in Fig. 1, liquid
DP J w k m Dd 33
water at the ambient temperature enters a heat exchanger
and is heated to the PEM electrolyzer temperature before where km is the membrane permeability resistance, which
it enters the electrolyzer. Leaving the cathode, the H2 pro- 2s
has a value of 8:03 1011 kgm Pa and Jw is volumetric perme-
duced dissipates heat to the environment and cools to the ate ow rate, expressible as
reference environment temperature. The oxygen gas pro-
duced at the anode is separated from the water and oxygen m_ 15
Jw 34
mixture and then cooled to the reference environment tem- q15 nAmem
perature. The remaining water is returned to the water
supply stream for the next hydrogen production cycle. Here, n is the total number of membranes (600 in this
The overall PEM electrolysis reaction is water splitting, study), q15 is the density at point 15 and Amem is the area
i.e., electricity and heat are used to separate water into of the membrane. Also, Dd is the trans-membrane osmotic
hydrogen and oxygen. Hydrogen is stored in a tank for pressure, which can be expressed as follows:
later usage. More details about the thermochemical mod-
Dd 805:1 105 C w R 35
eling of the PEM electrolyzer are given elsewhere
(Ahmadi et al., 2012). Here, Cw is the membrane wall concentration, which can be
determined as
3.6. Reverse osmosis (RO) desalination unit jw
eK mass x39
A typical seawater reverse osmosis-desalination plant Cw jw 36
eK mass 1 R R
r r
consists of three major processes: seawater intake, pre-
treatment and RO (in which the main separation process where Rr denotes the membrane rejection coecient
occurs). The RO system includes a high pressure pump, a (0.9975 in this study, based on Salcedo et al. (2012)). Also,
membrane separation unit and an energy recuperation sys- Kmass is the mass transfer coecient, expressible as follows:
tem. The raw water is pressurized by a high pressure pump
and then supplied to the membranes where seawater desa- Ds
K mass 0:04Re0:75 Sc0:33 37
lination occurs. Here, a standard RO unit based on a typ- d
ical seawater RO plant consisting of a single RO stage of b
where Ds is the diusivity and d is the feed channel thick-
trains is considered, according to Salcedo et al. (2012). The 2
ness (1:45 7 ms and 0.71 mm respectively). The Reynolds
rejected brine is pressurized at the outlet of the RO stage
number is determined as
and then passes through a hydro-turbine in order to
recover part of the energy consumed by the high pressure m_ 13
Re13 38
pump. In order to model the RO desalination unit, mass N ch W m l13 N P
and energy balances are used as follows:
where Nch and NP denote the number of feed channels and
W_ net bn W_ pump W_ turbine 29 the number of pressure vessels respectively, l13 is the
dynamic viscosity of the water and Wm is the RO mem-
brane with (0.243 m in this study). Also, in Eq. (37), Sc
Here, bn is the number of trains (7 in our study) and W_ pump is the Schmidt number, dened as
and W_ turbine are the work rate interactions required by the
RO pump and the hydro-turbine respectively, expressible l13
Sc 39
as: q13 Ds
P. Ahmadi et al. / Solar Energy 108 (2014) 576591 583
Extending this equation for the LiBr water solution we The renewable energy-based multigeneration system in
obtain: Fig. 1 has various components. In this section, the pur-
" # chase cost functions of each subsystem is explained.
y H2 O ex0H2 O y LiBr ex0LiBr
exch 1M sol 41
RT 0 y H2 O lnaH2 O y LiBr lnaLiBr 5.1. Subsystem costs
Here, aH2 O is water activity dened as vapor pressure of
water in the mixture divided by vapor pressure of pure PV/T solar collector
water and aLiBr is the LiBr activity dened as the vapor The purchase cost of PV/T solar collector is a function
pressure of LiBr in the mixture divided by the vapor pres- of the collector area and can be expressed as follows (Al-
sure of LiBr. This equation consists of two parts, the stan- Alili et al., 2012):
dard chemical exergy of a pure species and the exergy due
Z PV =T $ 310nx ny Lb 52
to the dissolution process, dened as follows:
1 where nx and ny is the number of PV/T collectors in series
ex0ch y H2 O ex0H2 O y LiBr ex0LiBr 42 and parallel respectively, and L and b are the PV/T length
M sol
and width respectively.
RT 0
exdis y H O lnaH2 O y LiBr lnaLiBr 43
ch
M sol 2 Flat plate solar collector in OTEC cycle
where yi is the molar fraction dened as As shown in Fig. 1, a at plate solar collector is used
with the OTEC system to increase the eciency of the sys-
1 x1w M LiBr tem. The purchase cost of the solar at plate collector can
y H2 O 44
1 x1w M LiBr x1w M H2 O be expressed as
y LiBr 1 y H2 O 45
Z FPC $ 235AFPC 53
Here, x1w is dened as
Here, AFPC is the at plate collector area, in m2.
xLiBr
x1w 46 OTEC cycle
100
The OTEC cycle has four major components, for each
where xLiBr is the LiBr water solution concentration in per- of which the cost is described as follows:
cent and M LiBr and M H 2 O are 86.85 kg/kmol and 18.02 kg/
kmol respectively. OTEC turbine and generator
584 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
The cost function of the ORC turbine can be calculated 5.2. Capital recovery factor (CRF)
as follows (Peters et al., 1968):
0:75 0:95
A capital recovery factor is the ratio of a constant annu-
Z T $ 4750W_ T 60W_ T 54 ity to the present value of receiving that annuity for a given
Here, W_ T is the power generated by the turbine in kW. length of time (Bejan and Moran, 1996). Using an interest
rate i, the capital recovery factor is dened as
OTEC evaporator n
The purchase cost of OTEC evaporator can be calcu- i 1 i
CRF n 61
lated as follows (Peters et al., 1968): 1 i 1
Q_ EVP Here, i denotes the interest rate and n the total operating
Z EVP $ 276AEVP 0:88 ; AEVP 55 period of the system in years.
U EVP DT ln
Here, UEVP is the overall heat transfer coecient for the
5.3. Cost rate
evaporator, which is taken to be 4:39 mkW2 K (Peters et al.,
1968).
Since each device in a system is expected to be working
Condenser in a specic time frame, the cost rate of each device is a
The purchase cost of an OTEC condenser can be calcu- good indicator of the cost rate in $/s represented by Z. _
lated as follows (Uehara and Nakaoka, 1984; Peters et al., The cost rate of each device is determined as
1968): Z k CRF U
Z_ 62
Q_ Cond N 3600
Z Cond $ 150ACond 0:8 ; ACond 56
U Cond DT ln where Zk is the purchase cost of the kth component, and
Here, UCond is the overall heat transfer coecient for the CRF is the capital recovery factor (Eq. (61)). Also, N is
the annual number of operation hours for the unit, and
evaporator 4:69 mkW2K (Uehara and Nakaoka, 1984).
u is the maintenance factor, which is often 1.06 (Bejan
Pumps and Moran, 1996).
The following expression is used to calculate the cost of
the OTEC pumps (Uehara et al., 1988): 6. Multi-objective optimization
0:41
Z Pump $ 3500W_ P 57
A multi-objective optimization method based on an evo-
Here, W_ P is the pump work rate in kW. lutionary algorithm is applied to the multigeneration sys-
Absorption chiller tem for heating, cooling, electricity, hot water, fresh
The purchase cost of the absorption chiller is a function water and hydrogen to determine the best design parame-
of all design parameters for the chiller, but can be com- ters for the system. Objective functions, design parameters
pactly approximated as a function of the cooling load of and constraints, and overall optimization are described in
the chiller as follows (Lian et al., 2010): this section.
0:67
Z chiller $ 1144:3Q_ EVP 58
6.1. Denition of objectives
Here, Q_ EVP is the cooling load of the absorption chiller in
kW, which can be calculated with an energy balance for Two objective functions are considered here for multi-
the control volume around the evaporator shown in Fig. 1. objective optimization: exergy eciency (to be maximized)
PEM electrolyzer and total cost rate of product (to be minimized). Conse-
The purchase cost of the electrolyzer is a function of the quently, the objective functions in this analysis can be
inlet electricity to split water, which can be expressed as expressed as follows:
(Genc et al., 2012):
6.2. Exergy eciency
Z PEM $ 1000W_ PEM 59
Here, W_ PEM is the electrical power required to split water in W_ net;ORC W_ PV =T Ex
_ cooling Ex
_ H2 Ex
_ 22
the electrolyzer. Wmulti 63
_ in;WS Ex
Ex _ in;CS Ex
_ Sun
Reverse osmosis desalination unit
The cost of the RO desalination unit in this multigener-
ation system can be expressed as follows (Bruno et al., 6.3. Total cost rate
2008):
Z RO $ 0:98m3 60 X
where m is the fresh water mass in kg. C_ tot Z_ k C_ env 64
k
P. Ahmadi et al. / Solar Energy 108 (2014) 576591 585
where the cost rates of environmental impact and fuel are 7. Results and discussion
expressed as
The genetic algorithm optimization is performed for 300
C_ env C Co2 m_ Co2 and C_ f cf m_ f LHV 65 generations, using a search population size of M = 100
individuals, a crossover probability of pc = 0.9, a gene
Here, Z_ K is the purchase cost of each component, as mutation probability of pm = 0.035 and a controlled elitism
explained in the previous section. value c = 0.55. The results of the optimization are given
and described below.
6.4. Decision variables
7.1. Optimization results
The following decision variables (design parameters) are
selected for this study: warm surface mass ow rate m_ WS , Fig. 3 shows the Pareto frontier solution for this multi-
OTEC evaporator pinch point temperature (PP) dierence, generation system with objective functions indicated in
OTEC turbine isentropic eciency (gT), pump isentropic Eqs. (63) and (64) for the multi-objective optimization. It
eciency (gp), absorption chiller evaporator temperature can be seen in this gure that the total cost rate of products
(TEVP), PV/T inlet air mass ow rate m_ air , PV/T collector increases moderately as the total exergy eciency of the
length (L), PV/T collector width (b) and OTEC condenser cycle increases to about 45%. Increasing the total exergy
temperature (TCond). Although the decision variables may eciency from 45% to 70% increases the cost rate of the
be varied in the optimization procedure, each is normally product signicantly. The results of optimum exergy e-
required to be within a reasonable range. Such constraints, ciency and total cost rate for all points evaluated over
based on earlier reports are listed in Table 3. 300 generations are shown in Fig. 4. The Pareto-optimal
curve (best rank) is clearly visible in the lower part of the
6.5. Evolutionary algorithm: genetic algorithm gure (red line) which is separately shown in Fig. 3. As
shown in that gure, the maximum exergy eciency exists
Genetic algorithms apply an iterative, stochastic search at design point C (73.63%), while the total cost rate of
strategy to nd an optimal solution and imitate in a simpli- products is the greatest at this point (161.58 $/hr).On the
ed manner principles of biological evolution (Srinivas and other hand, the minimum value for the total cost rate of
Deb, 1994; Ghaarizadeh et al., 2011; Deb et al., 2002). A product occurs at design point A which is about 143.7 $/
characteristic of an evolutionary algorithm is a population hr. Design point A is the optimal situation when the total
of individuals, where an individual consists of the values of cost rate of the product is the sole objective function, while
the decision variables (structural and process variables design point C is the optimum point when exergy eciency
here) and is a potential solution to the optimization prob- is the sole objective function. In multi-objective optimiza-
lem (Srinivas and Deb, 1994). More details about genetic tion, a process of decision-making for selection of the nal
algorithms and their procedure are given elsewhere (Deb optimal solution from the available solutions is required.
et al., 2002; Zitzler et al., 2000). The process is usually performed with the aid of a hypo-
thetical point in Fig. 3 (the ideal point), at which both
objectives have their optimal values independent of the
Table 2 other objectives. It can be clearly seen that it is not feasible
Expressions for exergy destruction rates for components of the system. to have both objectives at their optimum point simulta-
Component Exergy destruction rate expression
Warm sea water pump _ D;WSP Ex
Ex _ 1 W_ P Ex_ 2
Cold sea water pump _ D;CSP Ex
Ex _ 9 W_ P Ex_ 10
Flat plate solar collector _ D;FP Ex
Ex _ 2 Ex
_ sun Ex_ 3
Turbine _ D;T Ex
Ex _ 5 W_ T Ex_ 6
Condenser _ D;Cond Ex
Ex _ 6 Ex
_ 10 Ex_ 7 Ex
_ 11
WF pump _ D;P Ex
Ex _ 7 W_ P Ex_ 8
Solar PV/T _ D;PV =T Ex
Ex _ 41 Ex_ sun Ex
_ 40
Absorption condenser _ D;Cond Ex
Ex _ 39 Ex_ 26 Ex
_ Q
Absorption expansion _ D;EXV Ex
Ex _ 26 Ex_ 27
valves
Absorption evaporator _ D;EVP Ex
Ex _ 27 Ex_ 28 Ex
_ Q
Absorber _ D;Abs Ex
Ex _ 28 Ex_ 38 Ex
_ 31 Ex_ 32 Ex_ 33
Absorption pump _ D;P Ex
Ex _ 33 W_ P Ex _ 34
Absorption heat exchanger _ D;HEX Ex
Ex _ 34 Ex_ 36 Ex
_ 35 Ex_ 37
Absorption generator _ D;Gen Ex
Ex _ 35 Ex_ 40 Ex_ 41 Ex_ 39 Ex
_ 36
PEM electrolyzer _ D;PEM Ex
Ex _ 24a W_ PEM Ex _ 22 Ex
_ 21
RO pump _ D;ROPump Ex
Ex _ 13 W_ P Ex _ 14
RO desalination unit _ D;ROdesalination Ex
Ex _ 14 Ex
_ 16 Ex_ 15
RO hydraulic turbine _ D;hturbine Ex
Ex _ 16 W_ T Ex _ 17
Fig. 3. Pareto Frontier: best trade o values for the objective functions.
586 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
Table 3
Optimization constraints and their rationales.
Constraint Rationale
100 kg/s < m_ WS < 150 kg/s Due to pump required work limitation
3 C < PP < 6 C Due to heat transfer limit
0.5 kg/s < m_ air < 2 kg/s Due to commercial availability
0.8 m < L < 2 m Due to heat transfer limit
gT < 0.9 Due to commercial availability
gp < 0.9 Due to commercial availability
3 C < TEVP < 7 C Due to cooling load limitation
0.4 m < b < 0.7 m Due to commercial availability
5 C < TCond < 9 C Due to heat transfer limit
Fig. 5. Scattered distribution of decision variables with population in Pareto frontier: (a) PV/T length, (b) warm surface mass ow rate, (c) pinch point
temperature, (d) turbine isentropic eciency.
eect on total cost rate and to increase the system exergy on both objective functions. An increase in this parameter
eciency. An increase in PV/T length leads to an increase reduces the system exergy eciency because the higher
in collector electricity production and heat input to the sin- the pinch point temperature, the lower the energy utilized
gle eect absorption chiller, resulting in an increase in the in the evaporator, leading to a reduction of OTEC tur-
system useful outputs and eciency. But, an increase in bine power output. However, an increase in pinch point
this parameter correspondingly increases the purchase cost temperature when other design parameters are xed
of the PV/T collector, aecting the total cost rate of the sys- decreases the heat transfer area for the evaporator and
tem. Since an increase in PV/T length has both positive and correspondingly the total cost rate for the system.
negative eects on objective functions, its variation has a Fig. 11 shows the eect of varying turbine isentropic e-
scattered distribution (see Fig. 5a). ciency (gT) on both objective functions. An increase in gT
Fig. 9 shows the eect of variation in the mass ow results in an increase in system exergy eciency, because
rate of warm surface water on both objective functions. of the increase in the turbine power output, and system
Specically, an increase in this parameter raises the total total cost. Fig. 11 also shows that increasing this param-
cost rate and lowers the exergy eciency. The latter eect, eter leads to an increase in turbine purchase and mainte-
as previously noted, occurs because of the way an nance cost. Since an increase in this parameter has
increase in this parameter increases the net power output positive and negative eects on both objective functions,
while increasing the exergy input to the system. An the variation of this design parameter within its allowable
increase in warm surface mass ow rate raises the pur- range exhibits a scattered distribution as shown in
chase cost of the OTEC turbine and OTEC pumps, Fig. 5d. Fig. 12 shows that pump isentropic eciency
increasing the total cost of the system. Fig. 10 shows does not have a signicant eect on either objective func-
the eect of evaporator pinch point temperature variation tion, as its purchase cost is relatively insignicant.
588 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
Fig. 6. Scattered distribution of decision variables with population in Pareto frontier: (a) pump isentropic eciency, (b) chiller evaporator temperature, (c)
condenser temperature, (d) PV/T mass ow rate.
Table 5
Thermodynamic characteristics of three points on the Pareto frontier.
Point W_ net (kW) W _ D;tot (kW)
Ex Q_ cooling (kW) C_ tot ($/h) m_ H 2 (kg/h) m_ fresh (kg/h)
A 29 0.28 1242 40 143.8 0.10 312
B 52.5 0.60 1277 140.5 153.7 0.18 584.7
C 66.6 0.73 1248 146.54 161.6 0.23 720
Fig. 8. Eects of PV/T length on both objective functions. Fig. 10. Eects of OTEC evaporator pinch point temperature on both
objective functions.
mainly because it raises the cooling load of the system, eects on both objective functions, the variation of this
which in turn increases the system purchase cost. Since design parameter within its allowable range exhibits a scat-
an increase in this parameter has positive and negative tered distribution as shown in Fig. 7. In order to enhance
eects on both objective functions, the variation of this understanding of system performance, the cost of useful
design parameter within its allowable range exhibits a scat- outputs is calculated for the worst case in the optimization
tered distribution as shown in Fig. 6d. Fig. 16 shows the study, for which the total cost of the system is highest. To
eect of PV/T width on both objective functions. An determine the cost of the useful out puts, the total cost of
increase in PV/T collector width is observed to increase the plant is divided by the summation of output power
the system exergy eciency, mainly due to an increase in and cooling load of the system (i.e., the main two outputs).
collector area, which increases the electricity generated by The results for point C show that the cost of the useful out-
the PV/T and increases in the absorption chiller energy puts are 0.01 $/kWh, which is reasonable for such a com-
input. An increase in this parameter also raises the PV/T plex system. In addition, this multigeneration energy
purchase cost, which is a function of collector area. Since system has the possibility of increasing the eciency of
an increase in this parameter has positive and negative the system compared to a single generation plant.
590 P. Ahmadi et al. / Solar Energy 108 (2014) 576591
Fig. 12. Eects of pump isentropic eciency on both objective functions. Fig. 15. Eects of PV/T inlet air mass ow rate on both objective
functions.
important eects on the trade-o between exergy eciency Farahat, S., Sarhaddi, F., Ajam, H., 2009. Exergetic optimization of at
and total cost rate. Other concluding remarks follow: plate solar collectors. Renewable Energy 34, 11691174.
Farshi, L.G., Mahmoudi, S.S., Rosen, M.A., Yari, M., 2012. Use of low
grade heat sources in combined ejectordouble eect absorption
Exergy eciency and total system cost rate rise with refrigeration systems. Proc. Inst. Mech. Eng. Part A J. Power Energy
increasing PV/T collector length, turbine isentropic e- 226, 607622.
ciency, pump isentropic eciency, absorption chiller Genc, G., C elik, M., Serdar Genc, M., 2012. Cost analysis of wind-
evaporator temperature and PV/T collector inlet air electrolyzer-fuel cell system for energy demand in Pnarbas-Kayseri.
Int. J. Hydrogen Energy 37 (17), 1215812166.
mass ow rate. Ghaarizadeh, A., Ahmadi, K., Flann, N.S., 2011. Sorting unsigned
An increase in pinch point temperature results in a permutations by reversals using multi-objective evolutionary algo-
decrease in system exergy eciency and, when other rithms with variable size individuals. In: Evolutionary Computation
design parameters are xed, also results in a decrease (CEC), 2011 IEEE Congress. IEEE. pp. 292295.
in heat transfer area for the evaporator, reducing the Joshi, A., Tiwari, A., Tiwari, G., Dincer, I., Reddy, B., 2009. Performance
evaluation of a hybrid photovoltaic thermal (PV/T) (glass-to-glass)
total cost rate of the system. system. Int. J. Therm. Sci. 48, 154164.
The best optimized point from the multi-objective opti- Kotas, T.J., 1986. Exergy method of thermal and chemical plant analysis.
mization has the exergy eciency of 60% while the total Chem. Eng. Res. Des. 64, 212229.
cost rate of the system at this point is 154 $/h. Lian, Z., Chua, K., Chou, S., 2010. A thermoeconomic analysis of
biomass energy for trigeneration. Appl. Energy 87, 8495.
Martinot, E., Dienst, C., Weiliang, L., Qimin, C., 2007. Renewable energy
futures: targets, scenarios, and pathways. Annu. Rev. Environ.
Acknowledgement Resour. 32, 205239.
Meegahapola, L., Udawatta, L., Witharana, S., 2007. The ocean thermal
The authors acknowledge the support provided by the energy conversion strategies and analysis of current challenges. In:
Natural Sciences and Engineering Research Council of Industrial and Information Systems, 2007 ICIIS 2007 International
Conference. IEEE. pp. 123128.
Canada. Nihous, G., Vega, L., 1993. Design of a 100 MW OTEC-hydrogen
plantship. Mar. Struct. 6, 207221.
References Ozturk, M., Dincer, I., 2012. Thermodynamic analysis of a solar-based
multi-generation system with hydrogen production. Appl. Therm. Eng.
Ahmadi, P., Rosen, M.A., Dincer, I., 2014. Thermoeconomic multi- 51 (1), 12351244.
objective optimization of a novel biomass-based integrated energy Ozturk, M., Dincer, I., 2013. Thermodynamic assessment of an integrated
system. Energy 68, 958970. solar power tower and coal gasication system for multi-generation
Ahmadi, P., Dincer, I., Rosen, M.A., 2012. Energy and exergy analyses of purposes. Energy Convers. Manage. 76, 10611072.
hydrogen production via solar-boosted ocean thermal energy conver- Palacios-Bereche, R., Gonzales, R., Nebra, S.A., 2012. Exergy calculation
sion and PEM electrolysis. Int. J. Hydrogen Energy 38 (4), 17951805. of lithium bromidewater solution and its application in the exergetic
Ahmadi, P., Dincer, I., Rosen, M.A., 2013. Performance assessment and evaluation of absorption refrigeration systems LiBrH2O. Int. J.
optimization of a novel integrated multigeneration system for residen- Energy Res. 36, 166181.
tial buildings. Energy Build. 67, 568578. Peters, M.S., Timmerhaus, K.D., West, R.E., Timmerhaus, K., West, R.,
Ahmadi, P., Dincer, I., Rosen, M.A., 2013a. Thermodynamic modeling 1968. Plant Design and Economics for Chemical Engineers. McGraw-
and multi-objective evolutionary-based optimization of a new multi- Hill, New York.
generation energy system. Energy Convers. Manage. 76, 282300. Salcedo, R., Antipova, E., Boer, D., Jimenez, L., Guillen-Gosalbez, G.,
Ahmadi, P., Dincer, I., Rosen, M.A., 2013b. Development and assessment 2012. Multi-objective optimization of solar Rankine cycles coupled
of an integrated biomass-based multi-generation energy system. with reverse osmosis desalination considering economic and life cycle
Energy 56, 155156. environmental concerns. Desalination 286, 358371.
Al-Alili, A., Hwang, Y., Radermacher, R., Kubo, I., 2012. A high Srinivas, N., Deb, K., 1994. Muiltiobjective optimization using nondom-
eciency solar air conditioner using concentrating photovoltaic/ inated sorting in genetic algorithms. Evol. Comput. 2, 221248.
thermal collectors. Appl. Energy 93, 138147. Tchanche, B.F., Lambrinos, G., Frangoudakis, A., Papadakis, G., 2011.
Bejan, A., Moran, M.J., 1996. Thermal Design and Optimization. Wiley. Low-grade heat conversion into power using organic Rankine cycles
com. a review of various applications. Renew. Sustain. Energy Rev. 15,
Bruno, J.C., Lopez-Villada, J., Letelier, E., Romera, S., Coronas, A., 39633979.
2008. Modelling and optimisation of solar organic rankine cycle Uehara, H., Ikegami, Y., 1990. Optimization of a closed-cycle OTEC
engines for reverse osmosis desalination. Appl. Therm. Eng. 28, 2212 system. J. Solar Energy Eng. (USA), 112.
2226. Uehara, H., Nakaoka, T., 1984. OTEC using plate-type heat exchanger
Deb, K., Pratap, A., Agarwal, S., Meyarivan, T., 2002. A fast and elitist (using ammonia as working uid). Trans. JSME 50, 13251333.
multiobjective genetic algorithm: NSGA-II. Evolut. Comput. IEEE Uehara, H., Dilao, C.O., Nakaoka, T., 1988. Conceptual design of ocean
Trans. 6, 182197. thermal energy conversion (OTEC) power plants in the Philippines.
Dincer, I., Rosen, M.A., 2013. Exergy: Energy, Environment and Sol. Energy 41, 431441.
Sustainable Development, second ed. Elsevier Science. Uehara, H., Miyara, A., Ikegami, Y., Nakaoka, T., 1996. Performance
Dincer, I., Zamrescu, C., 2012. Renewable-energy-based multigeneration analysis of an OTEC plant and a desalination plant using an integrated
systems. Int. J. Energy Res. 46 (15), 14031415. hybrid cycle. J. Sol.Energy Eng., 118.
Dresselhaus, M., Thomas, I., 2001. Alternative energy technologies. Yamada, N., Hoshi, A., Ikegami, Y., 2009. Performance simulation of
Nature 414, 332337. solar-boosted ocean thermal energy conversion plant. Renewable
Esteban, M., Leary, D., 2012. Current developments and future prospects Energy 34, 17521758.
of oshore wind and ocean energy. Appl. Energy 90, 128136. Zitzler, E., Deb, K., Thiele, L., 2000. Comparison of multiobjective
Faizal, M., Rauddin Ahmed, M., 2011. On the ocean heat budget and evolutionary algorithms: empirical results. Evolut. Comput. 8, 173
ocean thermal energy conversion. Int. J. Energy Res. 35, 11191144. 195.