Академический Документы
Профессиональный Документы
Культура Документы
2.217E+007 7.346
1.789E+007 7.253 B' A'
1.474E+007 7.169 906.306208 4.001
1.237E+007 7.092 37.867 0.118
1.054E+007 7.023 0.971 0.044
9.116E+006 6.960 572.833 17.000
7.990E+006 6.903 1.108 0.033
7.087E+006 6.850
6.358E+006 6.803
5.763E+006 6.761 B' A'
5.274E+006 6.722 906.306 4.001
4.870E+006 6.688 37.867 0.118
4.536E+006 6.657 0.971 0.044
4.257E+006 6.629 572.833 17.000
4.026E+006 6.605 1.108 0.033
3.835E+006 6.584
3.676E+006 6.565
3.547E+006 6.550
3.443E+006 6.537
Amount Volume
g l or ml
1.008 0.000 ml
33.068 0.000 ml
g l or ml
34.076 0.000 ml
K Log(K)
3.201E+013 13.505
2.198E+013 13.342 B' A'
1.527E+013 13.184 2462.0669 4.62828699
1.074E+013 13.031 14.8828026 0.04655969
7.653E+012 12.884 0.9993792 0.01728549
5.521E+012 12.742 27367.1931 17
4.033E+012 12.606 8.17699334 0.0050794
2.983E+012 12.475
2.233E+012 12.349
1.692E+012 12.228
1.296E+012 12.113
1.005E+012 12.002
7.871E+011 11.896
6.232E+011 11.795
4.984E+011 11.698
4.025E+011 11.605
3.281E+011 11.516
2.699E+011 11.431
2.240E+011 11.350
Amount Volume
g l or ml
1.008 0.000 ml
32.060 0.000 ml
g l or ml
33.068 0.000 ml
K Log(K)
6.344E+009 9.802
4.384E+009 9.642
3.104E+009 9.492 B' A'
2.246E+009 9.351 2036.68222 2.40424639
1.658E+009 9.220 33.3182055 0.10423341
1.246E+009 9.096 0.99547108 0.03869711
9.523E+008 8.979 3736.6579 17
7.392E+008 8.869 5.59552046 0.02545693
5.821E+008 8.765
4.647E+008 8.667
3.757E+008 8.575
3.075E+008 8.488
2.544E+008 8.406
2.128E+008 8.328
1.798E+008 8.255
1.534E+008 8.186
1.320E+008 8.121
1.147E+008 8.059
1.004E+008 8.002
Amount Volume
g l or ml
1.008 0.000 ml
26.018 0.000 ml
g l or ml
27.026 0.000 ml
1.- Del sistema Me(+2) -H2O calcular sus diagramas de Solubilidad Predominancia y Bjer
Considere como especie slida solamente al MeO y entre las especies acuosas considere
y cuando la base de datos cuente con esta especie.
2.- Determinar los diagramas de solubilidad del MeCO3 y MeS corresponientes a 5C,25
concentracion totla de CO3(2-)=10^(-3) M y S(2-)=10^(-3) M respectivamente, se rec
PH de 0 a 14, pero en algunos casos puede ser mejor extenderlo de -4 a 20.
3.- De acuerdo al ECA del MINAM, sealar para los tres solidos considerados si cumplen c
segn los LMP para las A1 y A3.
olubilidad Predominancia y Bjerrum a 5c, 25C y 95C.
las especies acuosas considere el MeO(a) siempre
B' A'
-2696 -0.2726
1.631 0.0051
1 0.002
### 18
11.12 7E-005
Para
Logk1
k1= A' + Sabiendo
B'*(1/T) que A' -0.2726278 B' -2695.861
Para
Logk1
k2= A' + Sabiendo
B'*(1/T) que A' -0.2040572 B' -3247.206
Para
Logk1
k3= A' + Sabiendo
B'*(1/T) que A' -4.7783978 B' -1206.53
B' A'
-3247.206 -0.20405724
7.638732 0.0237376131
0.9999 0.009450143
180707.9 18
16.13816 0.0016074936
k2 k3
1.30E-012 7.61E-010
7.93E-012 1.49E-009
9.38E-010 8.77E-009
Reaccin 3: k3
FeO(a) + H2O(l) = HFeO2(-a) + H(+a)
Log(K) 1/T T deltaH deltaS
K kJ J/K
-11.898 0.00359518 278.150 22.610 -93.225
-11.684 0.0035317 283.150 22.853 -92.360
-11.478 0.00347041 288.150 23.041 -91.701
-11.281 0.00341122 293.150 23.182 -91.213
-11.092 0.00335402 298.150 23.284 -90.870
-10.909 0.0032987 303.150 23.351 -90.649
-10.733 0.00324517 308.150 23.386 -90.532
-10.564 0.00319336 313.150 23.393 -90.509
-10.400 0.00314317 318.150 23.375 -90.568
-10.243 0.00309454 323.150 23.331 -90.704
-10.090 0.00304739 328.150 23.263 -90.913
-9.943 0.00300165 333.150 23.169 -91.196
-9.801 0.00295727 338.150 23.055 -91.537
-9.663 0.00291418 343.150 22.917 -91.940
-9.530 0.00287233 348.150 22.758 -92.402
-9.400 0.00283166 353.150 22.575 -92.923
-9.275 0.00279213 358.150 22.369 -93.502
-9.154 0.00275368 363.150 22.140 -94.138
-9.036 0.00271628 368.150 21.885 -94.833
-8.921 0.00267989 373.150 21.605 -95.589
B' A'
-1206.52982 -4.77839781
2.05606462 0.00638929
0.99994773 0.00254363
344351.995 18
2.22797514 0.00011646
deltaG K Log(K)
kJ
48.541 7.650E-010 -9.116
49.004 9.100E-010 -9.041
49.464 1.078E-009 -8.967
49.922 1.271E-009 -8.896
50.377 1.491E-009 -8.827
50.831 1.741E-009 -8.759
51.284 2.024E-009 -8.694
51.736 2.341E-009 -8.631
52.189 2.697E-009 -8.569
52.642 3.091E-009 -8.510
53.096 3.528E-009 -8.452
53.551 4.009E-009 -8.397
54.008 4.535E-009 -8.343
54.467 5.109E-009 -8.292
54.928 5.732E-009 -8.242
55.391 6.404E-009 -8.194
55.857 7.126E-009 -8.147
56.326 7.898E-009 -8.102
56.798 8.721E-009 -8.059
57.274 9.592E-009 -8.018
C K
5 278
25 298
95 368
pH H
0.0 1
0.5 0.316227766
1.0 0.1
1.5 0.0316227766
2.0 0.01
2.5 0.0031622777
3.0 0.001
3.5 0.0003162278
4.0 0.0001
4.5 3.1622776602E-005
5.0 0.00001
5.5 3.1622776602E-006
6.0 0.000001
6.5 3.1622776602E-007
7.0 0.0000001
7.5 3.1622776602E-008
8.0 0.00000001
8.5 3.1622776602E-009
9.0 0.000000001
9.5 3.1622776602E-010
10.0 1E-010
10.5 3.1622776602E-011
11.0 1E-011
11.5 3.1622776602E-012
12.0 1E-012
12.5 3.1622776602E-013
13.0 1E-013
13.5 3.1622776602E-014
14.0 1E-014
14.5 3.1622776602E-015
15.0 1E-015
15.5 3.1622776602E-016
16.0 1E-016
16.5 3.1622776602E-017
17.0 1E-017
17.5 3.1622776602E-018
18.0 1E-018
Diagrama de Predominancia a T = 5C
1/T Logk1 Logk2 Logk3
0.0035971223 -9.9699705677 -11.8846549889 -9.1184331417
0.0033557047 -9.3191421957 -11.1007222541 -8.8271556024
0.0027173913 -7.5983378317 -9.0279870612 -8.0570114565
1*([H+]^2) + [H+]^3
ma de Predominancia a T = 5C
[Fe2+]/[Fe2+]total
[FeOH+]/[Fe2+]total
[FeO(a)]/[Fe2+]total
[HFeO2-]/[Fe2+]total
k1 k2 k3
1.0715919251E-010 1.3042024481E-012 7.6131933271E-010
4.7957640115E-010 7.9300832382E-012 1.4888275533E-009
2.5215185546E-008 9.3758993985E-010 8.7697768659E-009
[Fe2+]total 0.001
[HFeO2-]/
Log([Fe2+]) Log([FeOH+] Log[FeO(a)]
[Fe2+]total
1.0639992006E-031 -3 -12.9699705677 -24.8546255566
3.3646609017E-030 -3.0000000001 -12.4699705678 -23.8546255567
1.0639991996E-028 -3.0000000005 -11.9699705681 -22.854625557
3.3646608914E-027 -3.0000000015 -11.4699705691 -21.854625558
1.0639991893E-025 -3.0000000047 -10.9699705723 -20.8546255612
3.3646607888E-024 -3.0000000147 -10.4699705824 -19.8546255713
1.0639990867E-022 -3.0000000465 -9.9699706142 -18.8546256031
3.3646597626E-021 -3.0000001472 -9.4699707148 -17.8546257037
1.0639980605E-019 -3.0000004654 -8.969971033 -16.854626022
3.3646495011E-018 -3.0000014717 -8.4699720393 -15.8546270282
1.0639877991E-016 -3.0000046538 -7.9699752215 -14.8546302104
3.3645468893E-015 -3.0000147166 -7.4699852842 -13.8546402731
1.0638851955E-013 -3.0000465362 -6.9700171039 -12.8546720928
3.3635211114E-012 -3.0001471438 -6.4701177115 -11.8547727004
1.0628602333E-010 -3.0004651434 -5.9704357111 -10.8550907
3.3532972012E-009 -3.0014692552 -5.4714398229 -9.8560948118
1.0527167893E-007 -3.0046297523 -4.97460032 -8.8592553089
3.2543260614E-006 -3.0144802376 -4.4844508052 -7.8691057941
9.6080373910E-005 -3.0443066172 -4.0142771849 -6.8989321738
0.0025041585 -3.1282794833 -3.598250051 -5.9829050399
0.0485408276 -3.3408341251 -3.3108046928 -5.1954596817
0.4262793359 -3.8972470212 -3.3672175889 -4.7518725778
0.8902759797 -5.0774166458 -4.0473872134 -4.9320422023
0.9856856288 -6.5332028771 -5.0031734447 -5.3878284336
0.9976753727 -8.0279520498 -5.9979226174 -5.8825776064
0.9994838876 -9.5271655043 -6.997136072 -6.3817910609
0.9998585883 -11.0270027204 -7.996973288 -6.8816282769
0.9999574576 -12.526959778 -8.9969303457 -7.3815853346
0.9999867644 -14.0269470499 -9.9969176176 -7.8815726065
0.9999958363 -15.52694311 -10.9969136777 -8.3815686666
0.9999986855 -17.0269418726 -11.9969124403 -8.8815674292
0.9999995845 -18.5269414821 -12.9969120498 -9.3815670387
0.9999998686 -20.0269413588 -13.9969119264 -9.8815669153
0.9999999585 -21.5269413197 -14.9969118874 -10.3815668763
0.9999999869 -23.0269413074 -15.9969118751 -10.881566864
0.9999999958 -24.5269413035 -16.9969118712 -11.3815668601
0.9999999987 -26.0269413023 -17.9969118699 -11.8815668588
-33.9730586983
-32.4730586984
-30.9730586988
-29.4730586998
-27.9730587029
-26.473058713
-24.9730587448
-23.4730588455
-21.9730591637
-20.47306017
-18.9730633521
-17.4730734149
-15.9731052345
-14.4732058421
-12.9735238417
-11.4745279535
-9.9776884506
-8.4875389359
-7.0173653155
-5.6013381816
-4.3138928234
-3.3703057195
-3.0504753441
-3.0062615754
-3.0010107481
-3.0002242026
-3.0000614187
-3.0000184763
-3.0000057482
-3.0000018083
-3.0000005709
-3.0000001804
-3.000000057
-3.000000018
-3.0000000057
-3.0000000018
-3.0000000006
Log[HFeO2-]
[Fe2+]total 0.001
C K 1/T Logk1 Logk2
5 278 0.0035971 -9.9699705677 -11.884654989
25 298 0.0033557 -9.3191421957 -11.100722254
95 368 0.0027174 -7.5983378317 -9.0279870612
[Fe2+]/ [FeOH+]/
pH H n
[Fe2+]total [Fe2+]total
0.0 1 1 1.071592E-010
0.5 0.316228 0.0316228 0.9999999985 3.388671E-010
1.0 0.1 0.001 0.9999999952 1.071592E-009
1.5 0.031623 3.16E-005 0.9999999848 3.388671E-009
2.0 0.01 0.000001 0.999999952 1.071592E-008
2.5 0.003162 3.16E-008 0.9999998483 3.388671E-008
3.0 0.001 1.00E-009 0.9999995204 1.071591E-007
3.5 0.000316 3.16E-011 0.9999984834 3.388666E-007
4.0 0.0001 1.00E-012 0.9999952043 1.071587E-006
4.5 3.2E-005 3.16E-014 0.9999848347 3.388620E-006
5.0 0.00001 1.00E-015 0.9999520446 1.071541E-005
5.5 3.2E-006 3.16E-017 0.9998483672 3.388157E-005
6.0 0.000001 1.00E-018 0.9995206497 0.0001071078
6.5 3.2E-007 3.17E-020 0.9984857046 0.000338354
7.0 1.0E-007 1.00E-021 0.9952267433 0.0010664769
7.5 3.2E-008 3.21E-023 0.9850571562 0.0033380348
8.0 1.0E-008 1.05E-024 0.9541972595 0.0102251008
8.5 3.2E-009 3.64E-026 0.867893779 0.0294100666
9.0 1.0E-009 1.49E-027 0.6715729037 0.0719652101
9.5 3.2E-010 8.64E-029 0.3658130356 0.12396201
10.0 1E-010 1.18E-029 0.0844722763 0.0905198091
10.5 3.2E-011 6.29E-030 0.005024597 0.0170267072
11.0 1E-011 5.75E-030 0.0001739397 0.0018639234
11.5 3.2E-012 5.68E-030 5.568385E-006 0.0001886943
12.0 1E-012 5.67E-030 1.764784E-007 1.891129E-005
12.5 3.2E-013 5.66E-030 5.583726E-009 1.892141E-006
13.0 1E-013 5.66E-030 1.765999E-010 1.892431E-007
13.5 3.2E-014 5.66E-030 5.584841E-012 1.892519E-008
14.0 1E-014 5.66E-030 1.766107E-013 1.892547E-009
14.5 3.2E-015 5.66E-030 5.584948E-015 1.892555E-010
15.0 1E-015 5.66E-030 1.766118E-016 1.892558E-011
15.5 3.2E-016 5.66E-030 5.584959E-018 1.892559E-012
16.0 1E-016 5.66E-030 1.766119E-019 1.892559E-013
16.5 3.2E-017 5.66E-030 5.584960E-021 1.892559E-014
17.0 1E-017 5.66E-030 1.766119E-022 1.892559E-015
17.5 3.2E-018 5.66E-030 5.584960E-024 1.892559E-016
18.0 1E-018 5.66E-030 1.766119E-025 1.892559E-017
[Fe2
[FeO
[FeO
[HFe
Logk3 k1 k2 k3
-9.1184331417 1.071592E-010 1.3042024E-012 7.6131933E-010
-8.8271556024 4.795764E-010 7.9300832E-012 1.4888276E-009
-8.0570114565 2.521519E-008 9.3758994E-010 8.7697769E-009
[Fe2+]total
[FeO(a)]/ [HFeO2-]/
Log([Fe2+]) Log([FeOH+]) Log([FeO(a)])
[Fe2+]total [Fe2+]total
1.397573E-022 1.063999E-031 -3.0000000002 -12.9699705679 -24.8546255568
1.397573E-021 3.364661E-030 -3.0000000007 -12.4699705683 -23.8546255572
1.397573E-020 1.063999E-028 -3.0000000021 -11.9699705697 -22.8546255586
1.397573E-019 3.364661E-027 -3.0000000066 -11.4699705742 -21.8546255632
1.397573E-018 1.063999E-025 -3.0000000208 -10.9699705885 -20.8546255774
1.397573E-017 3.364660E-024 -3.0000000659 -10.4699706335 -19.8546256224
1.397572E-016 1.063999E-022 -3.0000002083 -9.9699707759 -18.8546257648
1.397571E-015 3.364656E-021 -3.0000006586 -9.4699712263 -17.8546262152
1.397566E-014 1.063994E-019 -3.0000020828 -8.9699726504 -16.8546276393
1.397552E-013 3.364610E-018 -3.0000065863 -8.4699771539 -15.8546321428
1.397506E-012 1.063948E-016 -3.0000208273 -7.9699913949 -14.8546463838
1.397361E-011 3.364151E-015 -3.0000658583 -7.4700364259 -13.8546914148
1.396903E-010 1.063489E-013 -3.0002082291 -6.9701787968 -12.8548337857
1.395456E-009 3.359566E-012 -3.0006581486 -6.4706287162 -11.8552837051
1.390902E-008 1.058920E-010 -3.0020779623 -5.97204853 -10.8567035189
1.376689E-007 3.314383E-009 -3.0065385696 -5.4765091372 -9.8611641262
1.333560E-006 1.015265E-007 -3.0203618351 -4.9903324027 -8.8749873916
1.212945E-005 2.920168E-006 -3.0615334246 -4.5315039923 -7.9161589812
9.385720E-005 7.145530E-005 -3.1729068349 -4.1428774026 -7.0275323915
0.0005112504 0.0012308368 -3.4367408227 -3.9067113903 -6.2913663792
0.0011805616 0.0089878434 -4.0732858028 -4.0432563705 -5.9279113594
0.000702224 0.0169060651 -5.2988987648 -4.7688693325 -6.1535243214
0.0002430933 0.0185071666 -6.7596013662 -5.7295719338 -6.6142269227
7.782224E-005 0.0187357275 -8.2542707397 -6.7242413074 -7.1088962963
2.466414E-005 0.0187772901 -9.7533083869 -7.7232789545 -7.6079339434
7.803664E-006 0.0187873462 -11.2530758624 -8.7230464301 -8.107701419
2.468113E-006 0.0187902179 -12.7530094849 -9.7229800526 -8.6076350415
7.805222E-007 0.0187910952 -14.2529892089 -10.7229597766 -9.1076147655
2.468264E-007 0.0187913695 -15.7529828685 -11.7229534361 -9.607608425
7.805371E-008 0.018791456 -17.2529808706 -12.7229514383 -10.1076064272
2.468279E-008 0.0187914833 -18.7529802395 -13.7229508072 -10.6076057961
7.805386E-009 0.0187914919 -20.25298004 -14.7229506077 -11.1076055966
2.468280E-009 0.0187914947 -21.752979977 -15.7229505446 -11.6076055335
7.805388E-010 0.0187914955 -23.252979957 -16.7229505247 -12.1076055136
2.468280E-010 0.0187914958 -24.7529799507 -17.7229505184 -12.6076055073
7.805388E-011 0.0187914959 -26.2529799487 -18.7229505164 -13.1076055053
2.468280E-011 0.0187914959 -27.7529799481 -19.7229505157 -13.6076055046
[Fe2+]/[Fe2+]total
[FeOH+]/[Fe2+]total
[FeO(a)]/[Fe2+]total
[HFeO2-]/[Fe2+]total
Log([HFeO2-])
-33.9730586985
-32.473058699
-30.9730587004
-29.4730587049
-27.9730587191
-26.4730587642
-24.9730589066
-23.4730593569
-21.9730607811
-20.4730652846
-18.9730795255
-17.4731245566
-15.9732669274
-14.4737168469
-12.9751366606
-11.4795972679
-9.9934205334
-8.5345921229
-7.1459655332
-5.909799521
-5.0463445011
-4.7719574631
-4.7326600645
-4.727329438
-4.7263670852
-4.7261345607
-4.7260681832
-4.7260479072
-4.7260415668
-4.7260395689
-4.7260389378
-4.7260387383
-4.7260386752
-4.7260386553
-4.726038649
-4.726038647
-4.7260386464
um a T=25C
Log[FeO(a)] Log[HFeO2-]
C K 1/T Logk1
5 278 0.00359712 -9.9699705677
25 298 0.0033557 -9.3191421957
95 368 0.00271739 -7.5983378317
[Fe2+]/
pH H n
[Fe2+]total
0 1 1.00000003 0.9999999748
0.5 0.31622777 0.03162278 0.9999999203
1 0.1 0.001 0.9999997478
1.5 0.03162278 3.1623E-005 0.9999992026
2 0.01 0.000001 0.9999974785
2.5 0.00316228 3.1623E-008 0.9999920263
3 0.001 1.0000E-009 0.9999747854
3.5 0.00031623 3.1625E-011 0.9999202687
4 0.0001 1.0003E-012 0.9997479093
4.5 3.162E-005 3.1648E-014 0.9992032375
5 0.00001 1.0025E-015 0.9974845881
5.5 3.162E-006 3.1875E-017 0.9920870025
6 0.000001 1.0252E-018 0.9753822928
6.5 3.162E-007 3.4152E-020 0.9259427392
7 0.0000001 1.2547E-021 0.7969884442
7.5 3.162E-008 5.7793E-023 0.5471740478
8 0.00000001 3.9653E-024 0.2521899981
8.5 3.162E-009 5.6587E-025 0.0558838259
9 1.000E-009 2.5719E-025 0.0038882153
9.5 3.162E-010 2.1736E-025 0.0001454857
10 1E-010 2.0995E-025 4.76308374E-006
10.5 3.162E-011 2.0810E-025 0.000000152
11 1E-011 2.0757E-025 4.81765988E-009
11.5 3.162E-012 2.0741E-025 1.52468191E-010
12 1E-012 2.0735E-025 4.82266147E-012
12.5 3.162E-013 2.0734E-025 1.52517853E-013
13 1E-013 2.0733E-025 4.82315697E-015
13.5 3.162E-014 2.0733E-025 1.52522805E-016
14 1E-014 2.0733E-025 4.82320648E-018
14.5 3.162E-015 2.0733E-025 1.52523300E-019
15 1E-015 2.0733E-025 4.82321143E-021
15.5 3.162E-016 2.0733E-025 1.52523349E-022
16 1E-016 2.0733E-025 4.82321192E-024
16.5 3.162E-017 2.0733E-025 1.52523354E-025
17 1E-017 2.0733E-025 4.82321197E-027
17.5 3.162E-018 2.0733E-025 1.52523355E-028
18 1E-018 2.0733E-025 4.82321198E-030
Diagrama de Predominancia
Logk2 Logk3 k1 k2
-11.8846549889 -9.1184331417 1.07159193E-010 1.304202448E-012
-11.1007222541 -8.8271556024 4.79576401E-010 7.930083238E-012
-9.0279870612 -8.0570114565 2.52151855E-008 9.375899399E-010
+ [H+]^3
[Fe2+]/[Fe2+]total
[FeOH+]/[Fe2+]total
[FeO(a)]/[Fe2+]total
[HFeO2-]/[Fe2+]total
Log([Fe2+]) Log([FeO
k3
7.613193327E-010
1.488827553E-009
8.769776866E-009
[Fe2+]total 0.001
1.5
1.0
0.5
0.0
-1.0
-1.5
H 2 O L im its
-2.0
0 2 4 6 8 10 12 14
C:\HSC6\EpH\Fe5.iep pH
1.5
1.0
0.5
0.0
-1.0
-1.5
H 2O L im its
-2.0
0 2 4 6 8 10 12 14
C:\HSC6\EpH\Fe5.iep pH
1.5
1.0
0.5
0.0
2.0
1.5
1.0
0.5
0.0
-1.0
-1.5
H 2 O L im its
-2.0
0 2 4 6 8 10 12 14
C:\HSC6\EpH\Fe5.iep pH
H 2 O L im its
12 14
pH
FeO2(-a)
H 2O L im its
12 14
pH
(-a)
H 2 O L im its
12 14
pH