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org/wiki/Hydrophilic-lipophilic_balance
Hydrophilic-lipophilic balance
From Wikipedia, the free encyclopedia
Griffin's method
Griffin's method for non-ionic surfactants as
described in 1954 works as follows:
The HLB value can be used to predict the surfactant properties of a molecule:
Davies' method
In 1957, Davies suggested a method based on calculating a value based on the chemical groups of the molecule.
The advantage of this method is that it takes into account the effect of stronger and weaker hydrophilic groups.
The method works as follows:[3]
where:
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Hydrophilic-lipophilic balance - Wikipedia, the free encyclopedia https://en.wikipedia.org/wiki/Hydrophilic-lipophilic_balance
-COOK+ 21.1
-COONa+ 9.4
N (tertiary amine) 9.4
Ester (sorbitan ring) 6.8
Ester (free) 2.4
-COOH 2.1
Hydroxyl (free) 1.9
-O- 1.3
Hydroxyl (sorbitan ring) 0.5
References
1. Griffin, William C. (1949), "Classification of Surface-Active Agents by 'HLB' " (PDF), Journal of the Society of
Cosmetic Chemists 1 (5): 311-26
2. Griffin, William C. (1954), "Calculation of HLB Values of Non-Ionic Surfactants" (PDF), Journal of the Society of
Cosmetic Chemists 5 (4): 249-56
3. Davies JT (1957), "A quantitative kinetic theory of emulsion type, I. Physical chemistry of the emulsifying agent"
(PDF), Gas/Liquid and Liquid/Liquid Interface (Proceedings of the International Congress of Surface Activity),
pp. 42638
Categories: Surfactants
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