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Gould
1. System:
Chapter 2 Page 1
MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
bdry
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
A zero volume (no mass, not wall) surface, usually located at the interface
between two materials (or commonly between the system and surroundings)
The properties on a boundary are shared by both the system and the
surroundings (i.e continuous function).
(a) (b)
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
x x x x
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
5. Property :
Any measurable characteristic of a system.
Properties are point functions and thus do not depend on how the system
arrived at its condition.
a.) Extensive Property: (Depends upon the size of the system): add
1. Volume partition
2. Mass
3. Total energy, total enthalpy, total entropy,
4. All mass dependent properties
5. 1st and 2nd laws use extensive properties! (1) (2)
b.) Intensive Property: (Independent of system size):
1. Temperature
2. Pressure
3. Specific volume (v V/m)
4. Any specific extensive property (per unit mass or mole)
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
If, in addition, potential energy is active in your problem, you have one
additional work mode and will need to specify an additional variable, i.e.
E(T,v,z).
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
Qin
system boundary V
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
If at the conclusion of the process, the initial states of the system and
surroundings can be restored without leaving any net change at all elsewhere,
the process is reversible.
A reversible process must be a quasistatic process.
Reversible processes cannot involve such phenomena as solid or fluid friction,
electric resistance, inelastic deformation, and hysteresis in magnetization or
polarization.
Some debate on definitions
Old interpretation: quasistatic implies reversible
New interpretation: reversible process is more restrictive
If complete equilibrium is reached at each step along the path, then quasistatic
is also reversible.
If for example, the thermal diffusion time scale is different from the viscous
mixing time scale, this process may be quasistatic in terms of mixing, but may
not reversible.
15. Cycle:
A process whose initial and final states are identical
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MAE 501 course notes Spring 2013 Copyrighted by R. D. Gould
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