CHEMISTRY

31. The correct statement with respect to CO is

1) It combines with H2O to give carbonic acid

2) It reacts with hemoglobin in RBC

3) It is a powerful oxidising agent
4) It is used to prepare aerated drinks
32. Which of the following statements is correct?

1) Graphite is thermodynamically more stable than diamond

2) Diamond is thermodynamically more stable than graphite

3) Graphite has such a high thermodynamical stability that diamond spontaneously

Changes into graphite under ordinary conditions.

4) Graphite and diamond have equal thermodynamic stability

33. When oxalic acid is heated with concentrated H2SO4 it produces

1) Only CO2 2) both CO2 and SO2 3) Only CO 4) both CO and CO2

34. Silicones are a group of organosilicon polymers containing

1) Si-O-Si linkages 2) Si-Si linkages 3) Si-C-Si linkages4) O-Si-Si-O linkages

35. H2SO4 is not used for preparation of CO2 from marble chips because

1) It does not react

2) Huge amount of heat is evolved
3) The reaction is vigorous
4) Calcium sulphate formed is sparingly soluble and gets deposited on marble chips
which stops further reaction.
36. Which one of the following allotropic forms of carbon is isomorphous with crystalline
silicon ?
1) Graphite 2) Coal 3) Coke 4) Diamond
37. A meal, M forms chlorides in its +2 and +4 oxidation states. Which of the following
statements about these chlorides is correct?
1) MCl2 is more ionic than MCl4
2) MCl2 is more easily hydrolysed than MCl4
3) MCl2 is more volatile than MCl4
4) MCl2 is more soluble in anhydrous ethanol than MCl4
38. The stability of dihalides of Si, Ge, Sn and Pb increases steadily in the sequence
1) GeX2 < SiX2 < SnX2 < PbX2 2) SiX2 < GeX2 < PbX2 < SnX2
3) SiX2 < GeX2 < SnX2 < PbX2 4) PbX2 < SnX2 < GeX2 < SiX2
39. On heating potassium ferrocyanide with conc. H2SO4 produces a neutral gas A. The
gas A on treatment with caustic soda under high pressure produced B. What are A
and B respectively.
1) CO2, Na2CO3 2) SO2, Na2SO4 3) CO, HCOONa 4) NO2, NaNO3
40. Man dies in an atmosphere of carbon monoxide, because it:
1) Combines with the O2 present in the body to form CO2
2) Reduces the organic matter of tissues
3) Combines with haemoglobin of blood, making it incapable of absorbing O2
4) Dries up the blood
41. Which statement is correct with respect to the property of the elements with increase
in atomic number in the carbon family:
1) Their metallic character decreases 2) The stability of + 2 o s increases
3) Their ionisation energy increases 4) Their atomic size decreases
42. C and Si belong to IV group (or 14th gp). The maximum co-ordination number of
carbon in commonly occurring compounds is 4, whereas that of silicon is 6. This is
due to:
1) Large size of silicon
2) Availability of vacant dorbitals in silicon
3) More electropositive nature of silicon
4) Silicon being vulnerable to attack by nucleophilic reagents
43 A silicate anion in a mineral is a linear chain of three silicate tetrahedral units that

share at corners. The silicate mineral contains and ions. The formula of the
mineral is
1) A2 B2 Si3O10 2) A2 B Si3O9 3) A B2 Si3O9 4) A B Si3O8

44. Which halide is least stable and has doubtful existence:

1) Cl4 2) GeI4 3) SnI4 4) PbI4

45. R3SiCl on hydrolysis followed by heating forms:

1) R3SiOH 2) R3Si O SiR3 3) R2Si = O 4) linear silicones

46. If carbon dioxide is passed in excess into limewater the milkiness first formed
disappears due to:
1) Reversal of the original reaction
2) Formation of volatile calcium derivatives
3) Formation of water soluble calcium bicarbonate
4) The solution gets heated by exothermic reaction
47. .is the compound which can remove both oxygen and nitrogen of the air

when passed over it at 1000oC.

1) CaC2 2) CaCl2 3) CaCN2 4) Ca(CN)2

48. Carbon cannot be used in the reduction of Al2O3 because:
1) It is expensive
2) The enthalpy of formation of CO2 is more than that of Al2O3
3) Pure carbon is not easily available
4) The enthalpy of formation of Al2O3 is too high
49. Select incorrect statement
1) Mellitic acid is benzene hexa-carboxylic acid
2) Pb reacts with HI and forms PbI4
3) Pb dissolves in acid as well as in base
4) Diamond is unreactive but graphite forms (CF )n with F2
50. The correct order of decreasing ionic nature of lead dihalides is:

1) PbF2 > PbCl2 > PbBr2 > PbI2 2) PbF2 > PbBr2 > PbCl2 > PbI2

3) PbF2 < PbCl2 < PbBr2 < PbI2 4) PbI2 < PbBr2 < PbCl2 < PbF2

51. Carbogen is:

1) Mixture of 9095% O2 + 5 10% CO2
2) Used by pneumonia patients for respiration
3) Used by victims of CO for respiration
4) All the above

52. Which of the following statements is incorrect?

 1) Thermal conductivity of Graphite is more than diamond

2) -graphite has layers arranged as ABAB sequence

3) -graphite has layer arranged as ABCABC sequence

4) The number of C-atoms per unit lattice of diamond is 8.

53. C60 (Fullerene) has the shape of a soccer ball, consider the following statements

(I ) Fullerene is an allotrope of carbon (II) Fullarene has 5 and 6 membered

rings

(III) All carbons in fullerene are sp2 hybridised

Identify the correct statement

1) I, II, and III 2) I only 3) III only 4) I, II

54. The carbide Mg2C3 upon hydrolysis gives

1) C3H8 2) C3H4 3) C3H6 4) none of these

55. Which of the following statement is incorrect?

1) Silicates are wide spread in the earth crust because they are very insoluble in water
 2) The Si O , bonds are weaker than C O bonds because of bigger size of silicon
atom
3) Zeolites are used as ion exchange materials, and as molecular sieve
4) Sharing of all four corners of a SiO4 tetrahedron results in a three dimensional
lattice of formula SiO2 .
56. Pyroxenes and amphiboles cleave readily parallel to the chains forming fibers because
1) the Si O bonds in the chains are strong and directional
2) the adjacent chains are held together by the metal ions present
3) pyroxene is single chain silicate while amphibole is a double chain silicate
4) (1) and (2) both
57. Which is incorrect statement about silicones?

1) they are repeating units ( SiO4 ) in silicates

2) they are synthetic polymers containing repeated R2 SiO2 units

3) They are formed by hydrolysis of R2 SiCl2

4) silicones are used as a lubricants

58. Which of the following silicate units are present in the mineral Beryl

1) Si4O11
6
2) SiO32 3) 12
Si6O18 4) Si2O76
59. Dimethyldichloro silane cannot be obtained by

1) 2)

3) 4)

60. Which is not a use of a silicone polymer?

1) Lubricant 2) Insulator 3) Paints and emulsions 4) Frothing agents

MATHEMATICS
1
3
61. sin 2 tan

4
 1 1 1 1 1 1 1 1
1) sin 4 tan 2) sin 2 tan 3) cos 2 tan 4) cos 4 tan
3 3 7 7

62. If tan 1 2, tan 1 3 are two angles of a triangle, then the third angle is

1) 300 2) 450 3) 600 4) 750

1 1
a b
63. If in ABC , C is a right angle, then tan tan
b c c a
5
1) 2) 3) 4)
6 4 3 2

64. tan 2 tan tan 1/ 3 tan if tan is equal to

1 2 1

1) 2 2)-1 3) 2/3 4)2

1 ab x
65. 2 tan tan
ab 2

1 b a cos x
1 b a cos x
1 b a cos x
1 b a cos x

1) cos 2) cos 3) cos 4) cos
a b cos x a b cos x a b cos x a b cos x

1 1 2 a 1 1 1 a
2
66. tan sin cos
2 1 a2 2 1 a 2

2a 2a a a
1) 2) 3) 4)
1 a2 1 a2 1 a2 1 a2

1 1 1
b
67. The value of tan tan tan 2 is
a b a ab 1
 1) a 2) 1/a 3) b 4) 1/b
1 1 a 1 a
68. tan cos tan 1 cos 1
4 2 b 4 2 b

1) b/a 2) a/b 3) 2a/b 4) 2b/a

1 ab 1 1 bc 1
1 ca 1
69. If a,b,c have the same sign, then cot cot cot =
a b b c c a

1)0 2) 3) 4) 2
2

1 1 c x y1 2 c c
1 3 1c c 1
70. tan c y x tan 1 c c tan 1 c c .....tan c
1 2

1 2 1 3 2 n

1) tan 1 2 x / y 2) tan 1 xy 3) tan 1 x / y 4) none of these

1 1 1 1 1 1 1 11
71. If tan 1 2 tan 1 2 3 tan 1 3 4 ....tan 1 n n 1 tan , then =

n n 1 n n 1
1) 2) 3) 4)
n 1 n2 n2 n2

72. If a1, a2 , a3 ,...., an is an A.P with common different d, then

d 1 d 1 d
tan tan 1 tan

....tan
1 a1a2 1 a2a3 1 an1 an

n 1 d n 1 d nd an a1
1) 2) 3) 1 a a 4) a a
a1 an 1 a1an 1 n n 1
73. If x1, x2 , x3 , x4 are the roots of the equation x 4 x3 sin 2 x 2 cos 2 x cos sin 0 then

tan 1 x1 tan 1 x2 tan 1 x3 tan 1 x4 is equal to

1) 2) / 2 3) 4)
n
2m
74. tan 1 m4 m2 2
m 1

1) tan n n 1 2) tan n n 1
1 2 1 2 n2 n
3) tan 1 4) none of these
n2 n 2

1 xy 1 yz
1 xz
75. If x 2 y 2 z 2 r 2 , then tan tan tan
zr xr yr

1) 2) / 2 3) 0 4) none

1 x 1 x 1 1 2 x 3 3 x 2
76. If y sec sin 1 and z cosec cos 1 then y z
x 1 x 1 3 x 2 2 x 3

1) 0 2) 3) x 1 / x 1 4) 3x 2 / 2 x 3

1 1
77. If
4
A
2
then tan tan 2 A tan cot A tan cot A
2
1 1 3

1) 0 2) 3) / 2 4) / 4

3 100 100 100 9

78. If sin 1 x sin 1 y sin 1 z , then value of x y z 101 101 101 is
2 x y z
 1) -1 2) 0 3)1 4) 3

1 2a 2b
79. If sin 2
sin 1
2
2 tan 1 x, then x =
1 a 1 b

ab a b ab 1 ab 1
1) 2) 3) 4)
1 ab 1 ab ab a b

80. The greatest and least value of sin 1 x cos 1 x are

3 3

3 3 7 3 3
1) , 2) , 3) , 4) none
2 2 8 8 8 32

2
2a 1 1 b 2x
81. The solution of sin 1 2
cos 2
tan 1 is
1 a 1 b 1 x2

ab a b ab 1 ab 1
1) 2) 3) 4)
1 ab 1 ab ab a b

1 2
82. The domain of cos in 0,2 is
2 sin x

1) 0, 2) 0, / 2 3) / 2, 4) none

1 1 2 3 1 12 1
83. The value of sin cot sin cos sec 2 is
4 4


1) 0 2) 3) 4)
4 6 2

84. The value of x satisfying the equation

1 1 1
3 tan 1 tan 1 tan 1 is
2 3 x 3

1 1
1) x 2 2) x 3) x 4) none of these
2 2 3

5 2
85. If tan 1 x cot 1 x
2 2
then x equal to
8

1) -1 2) 1 3) 0 4) none of these

x y
86. If cos 1 cos 1 then 9 x 2 12 xy cos 4 y 2
2 3

1) sin 2 2) 9sin 2 3) 16sin 2 4) 36sin 2

1 1 y 3
87. The +ve integral solution of tan x cos sin 1
1 y2 10 is

1) x 1, y 2; x 2, y 7 2) x 1, y 3; x 2, y 4

3) x 0, y 0; x 3, y 4 4) none of these

1
88. tan 1 1 r r 2
......
r 1
 2
1) 2) 3) 4) none of these
2 4 3

89. The number of real solutions of tan 1 x x 1 sin 1 x 2 x 1 / 2 is

1) zero 2) one 3) two 4) infinite

1 x 2 x3 x 4 x6
90. If sin x ... cos 1 x 2 ... for 0 x 2 , then x equals
2 4 2 4 2

1)1/2 2) 1 3) -1/2 4) -1