Model Paper-7 (B) PDF

1
AITS-CRT-III (Paper-2)-PCM(Sol)-JEE(Advanced)/14
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ANSWERS, HINTS & SOLUTIONS

CRT III
(Paper-2)
PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
Q. No.
1. C B A
2. D B C
3. A B C
4. A A C
5. D B B
6. C B B
7. C D B
8. B C D
9. A, B, C, D A, B A, B, C
10. A, C A, C A, B, C, D
11. A, D A, B, C A, B, C, D
12. A, B, C A, D B, C
(A) (q) (A) (p, s) (A) (t)
(B) (q) (B) (p, r, s, t) (B) (r)
1.
(C) (r) (C) (p, r, s) (C) (q)
(D) (s) (D) (r) (D) (s)
(A) (q), (s) (A) (q, s) (A) (s)
(B) (p), (s) (B) (q, r) (B) (t)
2.
(C) (p), (s) (C) (p) (C) (r)
(D) (p), (r) (D) (s) (D) (s)
1. 2 9 4
2. 2 3 7
3. 5 6 4
4. 5 7 5
5. 2 4 4
6. 1 5 9
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2
Physics PART I
1. In first case, 3 = k (2 0 ), If 0 is natural length of the spring

In second case 4 = k( 1 0 ), 1 is the length of the spring in second case
By solving the equations we have 0 = 8 3 1
but 0 is always greater than zero.
8 3 1 > 0
8
1 so it cannot be 2.7 m.
3
2. U = 2x + 4y
U U U
F= i j k 2 i 4 j N
x y z
At t = 0, at (4, 4), P = 24 J
Kinetic energy K = 0

Total energy, E = P + k + 24J and acceleration a i 2j m / s2

1 1
To cross x-axis, along y, 4 = a y t12 2t12 t1 = 2sec
2 2
1 1
To cross y-axis, along y, 4 = a x t 22 .1.t 22 t2 = 2 2 sec
2 2
1
Also, Crossing the x-axis co-ordinates are 4 ax t12 ,0 2,0
2
P = 4J K = E P = 20 J.
1
Crossing the y-axis co-ordinates are 0,4 a y t 22 0, 4
2
P = 16J, K = E P = 40 J
m
3. If at t = t0 container is empty then the rate by which water comes out is . At any t, total mass
t0
mt
m1 = m + m -
t0
dv
F m 1g = m 1a = m 1
dt
v t0 0 t
F
dv
0
0 m1 0 gdt
dt
t0
F t 0F
v= gt 0 . n2 gt 0
mt m
0 2m
t0
mv = t0 [F n2 mg]
mv
t0 correct coice is (A)
F n2 mg
3
K PV
4. V= ,T= is put then PV3 = constant (say k1)
T nR
k nRT 5RT
W = PdV = 13 dv
v 2 2
3R 5R 19
U = nCvT = (n1Cv1 + n2Cv2)T = 3 x 2x T RT
2 2 2
14R T
Q = U + W = 7RT
2
Q 7RT 7R
C(process) =
n T 5 T 5
Q 1
5. Total flux coming out of the sphere is and conductivity at that point, =
0
The relation current density, J = E
dQ
rate of change of charge, J. A E A = [Total flux]
dt
dQ Q Q
.
dt 0 0
Q/ 4 t
dQ 1 dt t
Hence, n4 1 t1 = 0 n4 2 0 n2
Q
Q 0 0 0
6. If the loop is completed by wire of length 2R along y-axis i.e. the diametre of the semicircle

then B.d I [Amperes law]. And due to the diameter wire only,
0
0I 0I 30I
B at all point on the circle 3x 2 + 3z2 = R2, is sin 1 sin 2 sin60o sin60o
4r R 4R
4
3
3 0I R 3
B.d (due to diameter wire only) = 4R
2
3

2
0I
30I
2 3 0I
Hence, B.d due to semicircle = I 0
2

2

7. Intesnity, I = 4I0 cos2
2
Imax = 4I0, For I to be 2I0.

Phase diff. 2n 1 , n = 0, 1, 2, 3......
2
hd
Path diff. = 2n 1 ; 2n 1
4 D 4
2

4hd 4hd

2n 1 D odd int eger xD
b t2
8. P = at + dt 3
c
-1
[P] = [m.v] = [MLT ]
4
[a] =
P MLT 2
t
2 o o 2
[b] = [t ] = M L T
t2 t 2
P c M1L1T 3
c
P
P
[d] = 3 MLT 4
t
11. To have max. M.E. on ground spring should be detached at a point where spring have minimum
energy.
mR 2 tan
12. If I= , min
K 1 K
tan 1
K is minimum for cylindrical shell min tan is maximum
1 2 2
If shell can roll then other will also roll.
Force of frictional is static hence work done by force will zero w.r.t. ground.
SECTIONB
1. Length of wire (Youngs modulus Y2). Cos 600 = length of wire (Youngs modulus Y1)
By symmetry and small deformation
Elongation in wire (Youngs modulus Y2) = Elongation in wire (Youngs modulus Y1).cos 600
4*Strain in wire (Youngs modulus Y2) = strain in wire (Youngs modulus Y1)
2. Degree of freedom f = 3
U = fnR(T2 T1) = f(P2V2 P1V1) = fP1V1{(V2/V1)1-n 1} ; > 0 for n < 1 and < 0 for n > 1
W = (P1V1 P2V2)/(n-1) = P1V1{1 - (V2/V1)1-n}/(n-1) ;
Q = U + W = P1V1{(V2/V1)1-n - 1}{ f - 1/(n-1)} ;
SECTIONC
1. About O N O

N + centrifugal + mg o = 0
2
About O

N + centrifugal + mg o = 0
2
N
m 2 1
centrifugal = xdx m 2 o (anticlockwise) O
0 2 0 4
1
N + m2 o mg o = 0
4 2
1
and N m2 o mg o = 0
4 2
1
When N = 0, m2 o mg o = 0
4 2
2g
=

5
1 1
2. 2T cos gh
r1 r2
Cp Q U
3. =
Cv
Cp T , Cv T

Fm
4. 2T sin = Bi (R)
2
T = IRB
2
also, T = r
2
r T T
B=
IR
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Chemistry PART II
SECTION A
1. HCl NaOH
NaCl H2 O
H OH
H2 O; x kJ
CH3 COOH NaOH
CH3 COONa H2 O
CH3 COOH OH CH3 COO H2 O; y kJ
Required equation:
CH3 COOH CH3 COO H
H y x kJ
2. Because it has one d and one centre.
4.
O OH OH
H3C O NaOH H3C O

HCl
H3C H3C A
O HO O HO
K sp
5. Solubility of Ag2CrO4 S1 = 3
4
= 6.5 10 5 M
Solubility of AgBrS2 = K sp
7
= 7.07 10 M
S 6.5 105 M
Ratio = 1
S2 7.07 10 7
= 91.9
6. (B) O
Zn Hg

HCl

HO Cl
7. 12 coordination (f.c.c.) : 8 coordination (b.c.c.)

4 Mx 2 Mx
: Ratio of density
Nav a3 Nav a3
4r
For f.c.c. lattice, a
2
4r
For b.c.c. lattice, 4r 3a a
3
7
4 2
Mx Mx
Nav Nav
Ratio of density = 3
: 3
4r 4r

2 3
3 3
=2 2 : 3
ze2 ze2 ze2
9. Because magnitude of KE , PE and TE
2r r 2r
10. According to Le Chateliers principle.
11. A is present at corners and face centres and B in the tetrahedral voids.
So, along one axis two face centred atoms will be and if they are removed then A are present in
the corner and centre of four faces.
So, total no. of atoms of A = 1 + 2 = 3
total no. of atoms of B = 4
Formula is A3B4
12. Ba2+ ions produce yellow ppt. with CrO24 , which is not soluble in CH3COOH.
BaCO3 dissolves in CH3COOH and produces Ba2+ ion which gives yellow ppt. with CrO24 which is
insoluble in CH3COOH.
SrCO3 is soluble in CH3COOH and produces Sr2+ ion which does not give yellow ppt. of SrCrO4
in CH3COOH.
SECTION C
10 103 58 103 T2 274

1. log 3

4.5 10 2.303 8.314 274T2
T2 = 283 K = 10oC
Rise in temperature = 10 1 = 9oC
2. CH3COCHO, OHCCH2CH2CHO
10 10 5
4. H 108
10,000
H 108 from H2SO 4 10 7 from water
total
-7
= 1.1 10
pH = 7 log 1.1 = 6.94 7
8a a
5. Tc ,Vc 3b,Pc
27Rb 27b2
PV 3 1.5
Zc c c
RTc 8 4
6. Black sulphides are Hgs, PbS, CuS, NiS, CoS.
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Mathematics PART III
SECTION A
0 ln 2 ln 3
e x 1 dx
e x dx e 2 dx
x
1. I

0 ln 2
On solving = 3 + ln 2 2 ln 3
2. z 4 i 1 63 16i
z = 4(i 1) (1 8i)
z = 5 12i, 3 + 4i
0 0 1
1 1
Hence area (oz1z2) = 5 12 1 56 28
2 2
3 4 1
h 2 5 2 cos
3.
3 3
k 4 5 2 sin
and
3 3
A(5, 5)
Orthocenter 2 1 Circumcentre
H(h, k) G (0, 0)
(0, 0)
5 7 5 2 cos 5 1 5 2 sin
, B(7, 1) C 5 2 cos , 5 2 sin
3 3
On eliminating , we get (x 2)2 + (y 4)2 = 50
x2 + y2 4x 8y 30 = 0
22 12 3 y=x
4. k
2 2

sin x dx sin xdx 2

0

0
1 2
2 2
5. h + 16 = (h 8) (0, 4)
h2 + 16 = h2 16h + 64
h=3
(8, 0)
So centre is (3, 0) and r = 5
2 2 (h, 0)
equation of circle (x 3) + y = 25
Let C(3 + 5 cos , 5 sin )
0 4 1
1
8 0 1 .10 2 sin cos 1
2
3 5cos 5 sin 1
A max 10 5 1
9
3
6. Slope of given line =
2
First of all we try to locate points on the curve at which tangents are parallel to given line
On differentiating 3x2 4y2 = 72 w.r.t. x
dy 3x 3 x
(Given) 2
dx 4y 2 y
2 2
Put x = 2y in 3x 4y = 72
11 13
We get (6, 3) and (6, 3) and their distances from line are and respectively
13 13
So (6, 3) is nearest
So x0 = 6 y0 = 3 and (x0 + y0) = 3
7. y2 = (x2 1)2
So y = x2 1 or y = 1 x2
1
(1, 0)
1
x3 8 (0,0)
So required area = 4 1 x 2 dx = 4 x

0
3 0 3
10
8. Given limit = 0 + (22 1) + (32 1) + ..... + (102 1) = n
n2
2
1
10 11 21
= 1 9 375
6
9. Circle on PQ as diameter p(t1)

x t12 x t 22 y 2t1 y 2t2 0
x 2 y 2 t12 t 22 x 2 t1 t 2 y t12 t 22 4t1t 2 0 45
t t
Put 1 2 1 and t1t2 = 1
2
Hence equation of circle become a(t2)
x2 + y2 6x 4y 3 = 0 ..... (1)
With centre (3, 2) and radius 4
Equation (1) is not orthogonal to x 2 + y2 + 2x 6y + 3 = 0
10. Three planes meet at two points it means they have infinite many solution, so
2 1 1
1 1 1 0 on solving = 4
1 3
P1 : 2x + y + z = 1
P2 : x y + z = 2
P3 : 4x y + 3z = 5
P on XOY plane (1, 1, 0) (Which can be obtained by putting z = 0 in any two equations)
1 3
Q on YOZ plane 0, , (By putting x = 0 in any two equations)
2 2
10
11. N : y + tx = 2at + at3 2

(at , 2at)
L : y = 2at P
On solving together 2at + tx = 2at + at3
2
x = at + 4a
2
Hence h = at + 4a ..... (1)
k = 2at ..... (2)
2
So y = 4a(x 4a) (eliminating t)
Now verify alternatives y = 2at G(h, k)
2
(at , 2at)
12. 4x2 + 2x 1 = 0
2 4 16
x=
8
2 2 5 1 5
x=
8 4
5 1
If sin18
4
5 1
cos36
4
= cos 36 = sin[90 36] = sin 54 = 4 sin3 18 3 sin 18 = 43 3
= cos 36 = 2 cos2 18 1 = 22 1
SECTION B
1. (A) lim f x 4
x 3
(B) x2 + 6x + 9 + y2 = 9 + 4
(x + 3)2 + y2 = 9 + 4
(x + 3)2 = 9, y2 = 4 or (x + 3)2 = 4, y2 = 9
(C) Draw graph and check
(D) Let 2 95 and be other root
As + = a (Given)
= a = a 2 + 95
Also = b
2 95 a 2 95 b
But b < 0 (Given)
a 2 95 0
So a 95 2
Hence max of a = 7
2. (A) cos x + cos 3x = cos 2x

2 cos 2x cos x cos 2x = 0
cos 2x (2 cos x 1) = 0
1 5
cos x x or or cos 2x = 0
2 3 3
3 3
2x or x ,
2 2 4 4
Roots are ,
5
3 3
2 roots
11
a
(B) f ' x 2x
x2
a
f ' 2 4
0
4
a = 16 so a1 = 16
2a
Also f(x) = 2 3
x
Also f(1) = 2 + 2a = 0
a = 1 so a2 = 1
a a2 15
Hence 1 5
3 3
(C) Check by graph
x
t2

0
at
dt
(D) We have lim 1
x 0 x sin x 3
x
x3
x2 1 2
6. lim 1 = 1 so a = 4
x 0 ax 3x 2 a
SECTION C
9 5!
1. C3 3C2
2!2!1!
2 18
20 x x x
2. f x 1 x 1 ......
1 x 1 x 1 x
19
1 x 21 1 x 1 x 21 1 x 2 x19
1 x
Coefficient of x18 in f(x) = Coefficient of x18 in (1 + x)21 = 21C18 = 1330
3. Let 2x = t (for x < 0, t < 1 and for x > 0, t > 1)

Now g(t) = t2 + 2(1 b)t + b = 0
Unity must be between the roots of this equation g(1) < 0
1 + 2(1 b) + b < 0 b > 3
Possible values of b in [1, 20] are 4, 5, 6, ..... 19, 20
So p = 204 = 4
1
4. Area of ABC = a b b c c a
2

Now given 2a 3b 6c 0

Cross with a , 3a b 6a c 0

or a b 2 c a ..... (1)

Again cross with b

2a b 6c b = 0

or a b 3 b c
1
Area of OAB = a b
2
12
1 1 1
a b 1
Area of ABC 2 2 3 11

Area of AOB 1 6
ab
2
So m = 11, n = 6 (m n) = 5
5. x2 + (2 tan )x (1 + tan ) = 0
+ = tan 2 ..... (1)
= tan 1 ..... (2)
From equation (1) + (2)
+ + = 3
( + 1)( + 1) = 2
Hence either + 1 = 2 and + 1 = 1
then = 3, = 0
or + 1 = 1 and + 1 = 2
= 2 and = 1
If = 3, = 0 then tan = 1
3 7
,
4 4
If = 2, = 1 then tan = 1
5
,
4 4
3 7 5
Sum = 4 = 4
4 4 4 4
9
p C 1C1 18 C9 9 10
6. 1 108 19 1
q C9 C9 19 19
So q p = 19 10 = 9

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ANSWERS, HINTS & SOLUTIONS

PHYSICS CHEMISTRY MATHEMATICS

1. In first case, 3 = k (2 0 ), If 0 is natural length of the spring

2. Because it has one d and one centre.

7. 12 coordination (f.c.c.) : 8 coordination (b.c.c.)

10. According to Le Chateliers principle.

10 103 58 103 T2 274

6. Black sulphides are Hgs, PbS, CuS, NiS, CoS.

Mathematics PART III

9. Circle on PQ as diameter p(t1)

11. N : y + tx = 2at + at3 2

2. (A) cos x + cos 3x = cos 2x

3. Let 2x = t (for x < 0, t < 1 and for x > 0, t > 1)

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