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IX


CHEMICAL ENGINEERS HANDBOOK

JOHN H. PERRY
Editor of First, Second and Third Editions

FOURTH EDITION

Prepared by a Staff of Specialists


under the Editorial Direction of

ROBERT H. PERRY

Professor of Chemical Engineering


University of Rochester

CECIL H. CHILTON

Editor-in-Chief, Chemical Engineering

SIDNEY D. KIRKPATRICK

Former Editorial Director,


Chemical Engineering and Chemical Week

McGRAW-HILL BOOK COMPANY


New York Toronto London Sydney
1963
.



. . .

.-. . .

"

1969
66.0(083)

. , -,. . 1.
. . . H. . .-.
. . , 1969,
. 640, . 397, . 332.


,
.
.

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- ,
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,
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: . . . 3.
(. VI); . . . . (. IVV III); .-.
. . (. V IX); . . . . (. I, III, IV, IX);
. . . . (. VI); . . . .
(. I); .-. . . POMAHKQB (. II, IV, VII, IX); . .
. . (. Ill, IV); . . . . (. II).

3 -1 4
6 5 68

-, .
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,
1937 . 30 .
,
Chemical En , ,
gineering .
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-

. (. . LiIey), . (Y. S. Touloukian),
. (W. R. Gambill)

. .
E

. . 9 ....................................... 74
. . . ................................................. 9 . . . . . . . 75
.................................................. 9
. . . . 10 . . . 75
...................... *.......................... 10 79
...................................................................... 13 82
........................................ 15
................................................................. 15 ..................................................................... 85
.................... 18
.............................. 18 ............................................ 86
............................................................ 19 . 86
........................................ 19 ...................................87
........................................ 20
...................... .............................. 21 ................................................. 87
............................................................ 25
...................................................................... 26
29 ..................................................................... 93
......................... ................................... 30
...................................................................... 30 .........................93
................................... 30
, , ...................................................... 94
0-41 , ,
7j>0 . .......................................................... 31 .........................94
. . 95
10 250 . . . . 32
........................................................... 98
10 360 . . . 32
33 ................................................ 99

............................................................ 34 . . .1 0 1
..................102
......................... . . . 46
................................... 58 .........................................................................102

15 .................................102
0 ................................................................. 58
....................... 103
....................... 103
16 0 .................................................. 58 ,
(, )............................105
0
IOO0C ............................................................ 58 .......................107
................................................................. 60
....................................................................109
. . . 60
........................................ 64 ............................110
......................... 64
( ).......................HO
. . ............................................. 64 111
.................... 66
.................... 67 . 112
............................................. 68 () . . .1 1 2
, . 113
. 68
. 69 .......................113
............................................. \ . . . 70 . 114
pv . . ......................... 70
pv .............................. 70 ..........................................................115
71
pv .............................. 72 .........................................................................115
pv .............................. 72 . .1 1 7
pv . . 72
pv . . . 72 ................................... 117
pv .............................. 72
pv ................................... 73 ...................................... 118
pv . . . . . 73 118
pv . . 73
v T . . . . 73 () . .1 1 9
pv ................................... 73 ....................................................................120

M

, , R d P

.
, , , R d P
,
. ,
,
, ( ) ................................ 2,418 9,2
, , H ................................ 1,100 15,41
, - C H 2- ................................................ 4,618 40,0
. ( ) 1,525 20
( ) . 1,643 20
. ( ) ................................ 2,211 39
F ................................................................ 0,952 25,5
C l ................................................................ 5,967 55
Br ............................................................ 8,865 69
I ................................................................ 13,900 90
N ( ).................... 2,$22 17,5
. N ( ) ................ 2,502 17,5
, N ( ).................... 2,840 17,5
[1] N ( ) .................................... 5,516 55,5
S ................................................................ C m. 3 50
P ................................................................ C m. 4 40,5
................................ C m. 4 C m. 5
:
3 - ........................................ 0 12,5
R d P 4 - ........................................
, 6
5 - ........................................ 3
. I-I [1, 2, 12]. 5 - ........................................
0,8
7 - ........................................ - 4 ,0
(. 1-2). T ........................................
(1-1): 2%, 7%. 1,733 19,0
. . . . 1,733 0
P . I-I ........................................
, 2,398 38
................................ - 9 ,5
.
-
[3]. . 1-3
, 16,4; 12,8;
19 (, 10; 12,5; (5,4.
) . 2 , ;
^ R d = 1,1.
P ~ 1,5% . 3 7,69 SH ; 7,97 RSR; 7,91 RSCN;
. I-I 8,11 RSSlR.
, , 4 .
R 8 As 54, Sb 68, S e '63, 21,5, Si 31,
Be 42, Al 55, Cr 58, Te 62, Sn 64,5, H g 69,
X: Bi 80.
+ 3 ;
3 RCHX2, RCOOH, RCOOR, RCOC1, R2CHX, 6 RCX3, R3CX, 101, C1S0C1, RSO2Cl, R3CR
R2CHR, RCONH2, -ROCOOR, R0C0C1, RSOOR, RSOOR, RSO2R, ROSO2OR1 R3N, NCl3, NO2Cl, PX3, R3P.
Ri NH, N0C1, NO2R1 NO2OR, N2O, RSeOOH; PO (O R )3, BX3, AsX3, SbX3 ClSeOCl;
10 . I. -

9 CX4, R4C, SCl4, SO2Cl2, NOCl3, POCl3, SiX4,


SnX4 CrO2Cl; .
12 SbCb PCU; ,
15 SCb. . [4],
1-2 (
(I-I) ~ 5 % ) :
0,04314
= (1-4)
(T kp - T ) 0 ,6 4 1

.
( )........................ 28000
(), , 16500 1
:
................................................ 6500 Tk
................................................. 2000
................................................ -3 0 0 0 [5]:
T1_ (5)
............................. 15000 1 Kp
2 a T-/100
................................ 30000
. . . . 4000 2
: , . 1-4;
........................ -5 0 0 T .
........................ -2 5 0 0 (1-5)
-2 5 0 0 239
............................ -4 5 0 0 23 .
........................................................ 15000
4000 1%.
........................................................ 20000
[6],

1*3 .
, 220 <
- < <780 , :
Ig Tk - 1,1836 + 0,2985 Ig + 0,62164 Ig (1-6)



59,1 G e . . 93,3 Te . . 104,6 -
. . 47,6 Be . :
H . . 24,7 . . 53,4 As . . 87,6 I . . 98,9
. . 36,2 He . 19,0 Se . . 81,9 Xe . . 93,2 -^2 2 -= 0 ,6 1 3 (1-7)
N . . 41,9 F . . 30,5 Br . . 76,1' Pb. . 113,8 7
S . . 67,7 Ne . 24,8 Kr . . 70,3 Bi . . 108,1
73,5 Sn . . 116,0 Po. . 102,4 ,
Cl . . 62,0 P . . 40 ,
Si . . 79,2 Ar . 56,3 S b . . 110,3 R h. . 90,9
Al . . 96,7 5% ( 17,6%).
\
To-
[7]

7 = 1 , 4 7 3 2 13 ( 1-8)
,
Tk .
ho
(1-2) 16 1,4%.
V \ )

, .
pi 2 t\
J2, 1: T,
[8] :

P i- (1 .3 )

2 (t2 ~ b ) 12 (1-9)
1 * :
2 * . I
i~ l
(1-2), . Xi , i
.
1 (1-2), (1-3),

* 1
% . , . %
Tl

1-4 P k
Ar [11],

FKp Ap (. 1-5):

104 (1-12)
, ,
(2 *)2
................................................................................ -55,32 1-5
H ................................................................................ 28.52 Ap
( ) ................................................ 1,59
N ( ) ....................................................... . 30,6
N ( ) ........................................................ -26,29
C l ................ ... ........................................................... 29,89
Br . ........................................................................ 31,15
F . . ........................................................................ 29,75
S .. ................................... 1,31 ............................................................................ -9 ,3 5
Si ( ) ........................................................ -54,00 ................................... ;....................................... 16,20
( ) ................................................ 31,63 ( )........................................................ 17,20
( ), 1 3 .................................... 65.62 N ............................................................................ 0,0
/ = 4 ........................................... 34.0 C l .................... . . . 48.0
5 ................................ 32,72 B r ................ 68,8
=6 .................................... 31,40 F . . . . . 39,9
=7 .................................... 30.1 S ................................................................................ 27.8
=8 .................................... 29 Si ( ) .................................................... 22.4
> 8 .................................... 28.52 - .................................................................... 23.7
31.63 ') 0 = 0 . 30.2
> - .....................................................
- C O O H .................................................................... 35,94 - C O O H ................................................................. 57.7
- C O O ( )............................ 4,12 -C = N . ......................................................... 52.5
-C = N .. . 33,83 (C )=(C ), 1= 2 .................................................... 28.6
(C )=(C ) = 3 .................................................... 27.9
............................................................ 56,61 = 4 .................................................... 25.2
(C)==(C) = 5 ................................................ ....
....................... . . . . 55,21 21.2
= 6 .................................................... 16.4
(C) = ( C ) ................................ ................................... 112,9 = 7 ....................................................
(N )-(C ) ( ) ............................................ -19,172 11.0
(N )-(H ) ( ) ............................................ -18,37
/2 = 8 ..................................................................................................... 5,3
> 8 .................................................................................................... 0,0
: (C) = (C) . .........................................................
5- . ........................ .... 54,28 51,1
53.52 (N )-(H ) ( ) ......................................... -3 ,1 5
6- ............................................................ :
.................................... 0,25
5-2 .................................................... 10.5
3 ................................................ -0 ,3 4 6-2 .................................................... 7,2
.................................................... 84.5
3 ............................................................ -1 ,4 2 3:
................ - 1,6
( ) 3 . . . -0 ,9 6 ( )
..................................... -4 ,7 5
1 .
2 , N - C . .
3 2 .
. 3
.
.


. .
- , 182
[9]: 23 , 3,7%.
^, 2 I ( F lO ) VKp,
P k
;; . ,
' [10]: [12]:
21,75
, FncKP= 105,5 + 5 ,421 (1*11) (3)
T 0K.
( I - I l ) , , Fkp ,
M 0K 3/.
16< <26. 20%.
12 . /. -

1-6
[13]:
V ( CM3/ )
^ ( . / ) 2
, CM = 9 P
1 + P (1-14)
[ 2 ^( , i/100)]s
, ,
. V



[8]:

X t P , / (1-15)
1=1 As . . . . 30,5 Cl (RCl) . . . . 21,6
B i ................ 48,0 Cl
X t ) Br . . . . 27,0 ( R - C H C l - R ) ................ 24,6
. ................ 14,8 N ( ) . . 15,6
[10]: Cr . . . . 27,4 N ( *
= 6895 (710 - 2,07) (1-16) F . . . . . 8,7 ) ................................ 16,3
Ge . . . . 34,5 N ( )'. . 10,5
/2. H ................ 3,7 N ( ) 12,0
(1-16) , Hg . . . . 19,0 N ( ) 10,8
M I ................ 37,0 (
16< <26 P ................ 27,0 ) .................................... 7,4
Pb . . . . 48,3 (
[14]: S ................ 25,6 ) ............................ 9,1
Sb . . . . 34,2 (
V kp - Vma (0,422 Ig P kp + 1,981) (1-17) S i ................ 3 ) ............................ 9,9
Vkp , Sn . . . . 4^3 (
3/\ Vimn T i ................ 35,7 ) . . . . 11,0
, 3/; P kp V ................ 32,0 ( ) .................... 12,0
, . Zn . . . . 20,4 ( S, , N) 8,3
Vkp : :
2,5%, 10%. 3- ........................ 6,0
Vkp 4-........................ 8,5
. 5- ........................ 11,5
6- ( ,
: ,
) ........................ 15,0
V Km = ~ - ( 8) . . . . 30,0
> ................ 47,5
,
; M M a c c a v

, . 1-6 [15].
, P kp , [18].
,
[16]. (), :

0 ,2 2 3 * 0 ,1 3 2
.-
P ^ = 4,3 - IO-3 ( 1-2 1 )
Zkp- - Af0,5*6
R T1

: , Fkp M .

1 FncKp = 20 P n = 9,42 10 /2.
- 5 (1-19)
3,43 + 0,0067L j [19] 11
,
Lu,
. 4% :
, (1-19)
4%. 9/ 16

( 40%) = 6,1 10~ ( 1-22)
Z kp . M1/3F ^5
P kp F kp
, ,
- (1-21).
[17]:
I g p KP
Z = 0,371 - 0,0343 (1-20) (. 1-11).
T/ F 1
P .
13

2,4% [20]:
$
7 , 112^ .
(1-23)
I1kP --------
1 KP

0K.
[21] ,
(1-23) ^ 7,7

6,5 62,1%.
(
4,6 34,2%)
:
6 1 ,6 ^ 1'
1* "\/ (1*24)

Vkp (
).
( t 15,6 U - / ; , Kt / J1

. 1-1. P
23% .
[14]:
. = (1,981 + 0,422 Ig ) (1-25) ,
P , . (1-18),

7 - /
. 1-2. .
14 T a . I. -

(. 1-6). - P2, [22]:


45%.
- _
Tu 2 ( T tp - T t Vh
(1-26)
, 1 pm U
V
kp - G /

0.1 0.2 0.4 0.6 0.6 1.0 4.0____ 6,0 8.0 10 20 30

. 1-3. Z P ap .

pni 2 [28] , [28]


, , [29]
. . ,

[23] ,
, .
( ) .
P .
,
(. I-I)', = ,
1 , [30]:
Py 1 P a e c = I ClT
[24]. Cp = 4190 (0,2 + 0,00088/ + 0,15:) \ (1-29)

, , V kp Z itpy t , 0C;
.
JIy (. 1-2) [25] (,
. , , )
, [31]:
:
K1 , - 4 1 9 [ , ,8 + .(|, + 3 2 ) ] ^ ^ - (1*30)
I l (1-27)
2
t , .
/Cl
Tnp P np 7=20
a K2 Tup P np 5% ( ~ 14% )
2. [32]
, (. 1-7).
, , .
. ,' Z kp > 0,24 1-7
~ 1 % ,
, ,~3% .
. ( 20 )

Pnp= 1
,
Pnp= 1. ')

:
CH3- ..................................................... 9,9
v^I L ( ) - C H 2- .................................................... 6.3
I
- C - H ........................ ............................ 5.4
Z , I
[26]. -C O O H .................................................... 19.1
C O O - ( ) ................ 14.5
, . 1-3 [16].
H2 He , 44C = O . ................................................. 14.7
Pnp>2,5. <2,5 H2 He ( /
Ne) - C s N .................................................... 13,9
Z- [27]. - ......................................................... 11,0
, - N H 2 ........................................................ 15.2
, - C l ............................................................ 8,6
(1-9) (1-15). . 1-3 - B r ............................................................ 3.7
Z ttp=0,27. - N O 2 ........................................................ 15.3
Zkp - - ................................................ . . 8.4
. -S - ........................................................ 10.6
C6H 5- . ............................................ 30,5
H ( ) 3,55 [33]
= C H - ( ) . . 5.4
,
, . VI. . .
/=*20 ,

[34]:
TpGT1 (1-31)
,
, )
. , [35]; ,
..
. I. -

- ,
(1-31) .
:
[38]:
^ 2'

, Tn ^ 0 ,6 5 10 , cPos (1*35)
6450
:
d t ,
= 0,1745 - 0,0838Fnp (1-33) (1-34).


. (1-35) ~ 2 % .
4%
[31]: :
* <*<350 ; 0,68<d<0,9.
4190 [,388 + 0,00045 ( | - 1 + 32 j j Cp C pICv

(1-34) [39].

d 15,6
; t
, .
(1-34)
: 0 < /< 2 0 5 ;
0,75<d<0,96.


(. 1-8) [36].
1-8

Cp



Cp 1,



. . . 7.4 5%
(3/ 4 ),
12%

2 . 9.6 15%

.................... 8,1 10%
(3/ 4 )

,
3 ................ 5.7 30%

,
* 6.5 30%
. 1-4: ACp
.
1 , . . ,

. Cp
(
). [40]:
2 , .
.
3
, ,
.
Sn 6 2 q, -i
+ vT S *1. 1 ( 36;
2 j4 i
[35]
[37]. Cpq - ,
, [( ) ; R
17

(1-36):
, );
, C n 2,24 + 61,47 HT3T - 20,44-IO-6T2 - )
(. . Po
; qt i; - , 700 C n = 3 5 ,2 6
Po
; yL qi ).
; Cv , i Ca, / 34,2 ). ,
~ 2 % .
i. Po
Cp0
,
. 1-9 [33],
v [.41], 300 IlOO0 K 5,5%,
, [42], 25%- ,
:
Cp0 = A + + CT2 (1-37) ,
(500 <
< 7 < 1 1 0 0 ),
(1-36) (1-37) .
. 1-9. 10%. ,

. C3H8
*=427 . 160
+-1650 [43].
= 11; ' = 2; ' - = # = 1 ,9 8 7 - );

- 6 qt . 1-4 [44].
, q = io, ---------------------------- = 1,5. 8 C - H 30%,
Ij q ~ 5 8%.
2 - . . 1-9, : >3,5 .
q.C . = 8 ( - 0 ,1 3 9 + 0 ,168-10 3 + 0,447- 6! 2) +
'l V, I Cp
+ 2 ( - 0,339 + 3,564* IO-3T - 1,449- IO-6T2) = Cvt
= - 1,789+ 8,471-IO-3T + 0,68-IO-6T2 ) Cp Cv - R . :
: Cp C y - R
(1-38)
2 Qi Cb i ~ 3,940 + 35,364 10~ 3 ~ 14,09-10-62 -)
($
\ ^ V / Cv

1-9




V, 1 , - 1
IO8 IO3 B - I O8 10

C -C 1 . . . . 910 -0,339 364 -1,4 4 9 650 0,343 2,707 -1 ,1 5 0


C -C 2 . . . . 1500 -0,836 3,208 -1,087 600 0,503 2,472 -1 ,0 5 8
C=C . . . . 1200 -0,740 3,730 -1,404 910 -0 ,3 3 9 3,564 -1 ,4 4 9
C= C . . . . 2080 -0,606 1,861 -0,306 375 1,268 1,244 -0 ,5 4 4
C -H . . . . 3000 -0,139 0,168 0,447 1050 -0 ,5 7 9 3,741 -1,471
. . . . 1030 -0,458 3,722 -1,471 1120 -0 ,665 3,754 -1 ,4 4 9
C=O . . . . 1740 -0,778 2,721 -0,7 5 9 780 -0,034 3,220 -1,341
C -N . . . . 1000 -0,501 3,695 -1,471 450 1,016 1,663 -0 ,7 2 3
C= N . . . . 2220 -0,525 1,528 -0,141 240 1,665 0,566 -0 ,2 4 9
C -C l . . . . 650 0,343 2,707 -1,1 5 0 260 1,613 0,656 -0 ,2 8 9
C -F . . . . 1050 -0,579 3,471 -1,471 1200 -0 ,7 4 0 3,730 -1 ,4 0 4
C -B r . . . . 610 0,471 2,519 -1,0 7 6 950 -0 ,4 1 5 3,630 -1 ,4 6 2
C -I . . . . 530 0,740 2,106 -0,908 880 -0 ,2 7 5 3,498 -1,431
O -H . . . . 3500 0,000 -0,240 0,560 1350 -0 ,8 1 9 3,563 -1 ,2 6 7
S -H . . . . 2570 -0,331 0,805 0,192 860 -0 ,2 3 0 3,450 -1 ,4 1 6
S=O . . . . 1250 -0,77*2 3,685 -1,363 520 0,774 2,051 -0 ,8 8 6
C -S . . . . 690 0,219 2,884 -1,218 280 1,558 0,750 -0 ,3 3 0
N -N 3 . . . . 1000 -0,501 3,695 -1,471 900 -0 ,3 2 0 3,547 -1 ,4 4 5
N -H . . . . 3300 -0 ,0 4 -0 ,1 2 0,53 1200 -0 ,7 4 0 3,730 -1 ,4 0 4
N -O . . . . 1270 -0,785 3,668 -1,3 4 7 660 0,311 2,754 -1 ,1 6 8
N=O . . . . 1470 -0,835 3,347 -1,125 650 0,343 2,707 -1 ,1 5 0

1 .
2 .
5 N^O NaO.
18 . I. -

Cv/Cv CTis <J2s


: .
, :
Cn
(1-39)
Cv Cp { Cv) aI - aI S - aU (U0)
(1-.40)
Cp Cv , R.
Oi 02, * ( 02 ).
. 1-5 [45].
, 100%. ,

Oi8 o2s,
15% ,
,
.

. ,


(1884 .):
^ n , 2 1 ( I -4 1 )

L a, , /;
T , .
(1-41)
30% .

,

.
0,04 Q M 0,4 0.6 0.8 1
[47]:
P/ ^tCP

In P
. 1-5. (1-42)
Cp - C v . ^ Tk
:
, 2,5%, 10%.
Lui
T
, 1 2 T2
. , [35]:

( Lu2 ( T T2 V
) (1-43)
. Lui \ Ti )

. (1*42)
: 1) (1*43) :
; 2) ( - T)038
40 .%, Lu R T KpTKKu In \ 11 38
(1-44)
/ T
K1 1 ;
.

Lu T
~ 4 % ,
( )
.
-
, .
P
. [46], Lu, ,
Oi , :
,
LnJ>x e LUIX1+ ^2*2 + + (**45)
. 19

Lni, Ln2, , Ln, AT=Tna- -298,


1, 2, . . . , \ \, 2, . * (LnafTna)''.
. / ^ Y
- ATt
\ ^ / * '

Ln, . 0 1,9
: 300 2,5
700 3,0
+ L Zlt TLj > 1200 3,2
, P T ' ^ni^l ^2^2 '(1-46)'

\, /2, . . . , , ,
1, 2, . . . , . LnafTna 13,5 /( ).
(1-45) (1-46) .
, ,

(, .
).

.
, Cpll
1 Pr - ^

. P r
Ln ,
[48]. [51]. ,
, P r =0,67 ( 5 % ),
, P r =0,73 (
= 1 , 15% ),
. 1-6 [49]. Pr=O ,79 ( 1 5 % ),
Pr=O ,86 (
8 % ),
P r = I ( 1 0 % ).
,

,
. Pr


C p ,
.
Pr

. , , ,

,
50 150 200 250 300 350 400 450 500 600 L
, 0C .

. 1-6.
(A PI
American Petroleum Institute).
. [52] ,
' An
. Lnn Ap

. , An = 0,6 (1-48)
LnaITn
~ 2 ,2 /( ),
57 /( ), ( ~ 2 % ).
9 14 /( ).
Lna ,
( 10%)
[50]:
.

(1-47)
' ( f e )
1 ,
T n a , 0K; - - , .
. , .
20 . 1. -

: )
2 I :
: (1-49)
( + 0,4)
.

-P ip ir (1-52)


: , . .
. / < /
\0,5
/ 2 R d + V \ (1-52)
(1-50) .
45% 3 0 < /< / .
(1-52) . [56]
R d ,
. 1-1; V , (. 1-7).
. 1-6.
P
400

~
( 350 -
23%)
[53, 54]: , /
300 - '" 40
t P 22 -1 1\4
\ 4
(1-51) 0.5
/
I V "2+ 2) F 50
;-0,6
R d, 250- 50- : 60
40- f -O J
(1-51), . 1-1. ?
P [55] V 0.8
b
(. 1-10). 20 h 0.9 96
200
* '-100
-
MO
W- -)
( ) 1
5 - > is
DZ
150

, , P 150 - - 200
Z 20
250
..................................................................... 4,8
17.1 300
H ( ) ............................
H ( ) ............................ 20,0 -3 4 0
( , ) 11.3 t- 400

0 ( ) ................................ 43,22
O2 ( , ) 60.02 0 J
F ............................................................. 25.7 . 1-7.
C l .......................... ............................... 54.3 [ (1-52)].
B r ............................................................ . 68,0 : A B C , CDE.
1 ........................ ............................ 91,0
N ( ) . . . . . . . . . . 12.5
N ( ) ............................ .... 29,13
S ........................................................ .... 48.2 /
37.7 ~ 5% [57]:
P ............................. ...........................................
: _ ^ , ,
3- .................................... 16.7 ---------- 364 ^T (1-53)
4- .................................... 11.6
5- .................................... 8,5 L n, / ,
6- .................... .... 6,1 / ; , /,
.................................... 23.2 /3.
.................................... 46,6

[58]:
1 (1-51). O2 ( T kp - T 2 - 2
2 .
8 . " W = T r ) (54)
, ,
, , -
M ( - .
T 21

(1-54)
0 2 / 0 1 (. 1-8) [59].
.
( ) - X /( - )
[60]. 5 10%
[63]:
* T9
10 2 ICTls (-L Y 9,7 - IO3Cnp2
62/ 6, \ /
500 : 80 = 2,61 10'
60 CpQ + - - ' (59)
400
40
300 30 20 T , 0K;
20 , \ C v
, /( ); , /\
200 10 30
M , /.
.
t S 40
4
3 50
100 2 60 . 1-9 [64].
80 1 80
60 100
50
40
30 200

20 300
400
500
10
. 1-8.
[ (1-54)].

(1-51) (1-52)

.
,

[54, 61]:

(1-55)

(1-56)

C M = 2 n Ix * (1-57)


.
.
[62]:
. 1-9.
.
!/4
X , -
^ 4 0 .%,
, , M m M a
( ). [65]:
[54]
= 1,73 IO- 3 P (0,1159 + 0,00233) + 0,0236 /( )
(1-60)
, /3; ,
( /= 2 0 ). .%.
22 . I. -

* > 4 0 % :
= 1,73 10 3 (0,1159 + 0,00316*) + 0,0236 ( ) a ^rb (1-66)
(1-61) 2 1 /

, L n,
, , /;
(, ), , .
. , ( 1-66 )
24 , 30 ,
. (, , )
Fk/2 . ,
( , ) ,
[66 ]: (1-66) /= 30 ,
, 1 Fkp.
+ I - 2/ ,
(1-62) 28 , ,
. v ( p 2/3- p ) + I - p 2/z + (1-65)
8,7%, 31,6%. '
A cm Ak
Anop , ,
; v = ----------- ~ 5 %
.
:

(); ( = </ (1-67)
).
,
: .

, ~~ ' (1-63) , (
~ Pr 13%, 50%)
[71]:
, v
, (1-62) : 1,294^3
= Al /3 --------T
(1-68)
(1-64)
. I P
,
(1-65).
(1-62)
(0 < < 1), .
. 35 .
, () .

15%, [72]:
6 %. , / A2 \ 2
(, ), (1-69)
(1-62) VA1 Zr E1
. , [67], Ei 82
,
. .
,
, Fnp, . 1- 11.
,
d < \ ,
, . ,
[67]. /=20
, [73]
[68 ]. Ac=0,136 ). , ,
. 13%. Acm
Bap- Kparo [74]:
[69] [70]:
0 117
Acm = ( 1 - 0,00054/) (1-70)
1,54 4 /3
A= (1-65)
1/ ' 4 - d Cyi 15,6
; /
Cp , .
, * ); , /*; M , 0,78<
, /; , <flfCM<0,95 0 < /< 2 0 0 .
. 12%, *39%.
T 23

M l ,
C v 0. ,
0
[80]:
Tn
0 = ( ^ + ^ ) (1-74)

0,4 0,5 0,6 0,7 0,8 0.9 0,96 1,0


p-

() ; C v
() ; R
; M
0 14,25 13,39 12,42 11,40 10,14 8,10 6,98 .
1 14,39 13,54 12,61 11,62 10,47 9,10 7,96 *7*1*0 (1-74) :
2 14,52 13,68 12,78 11,82 10,76 9,61 8,74 8,09
3 14,64 13,81 12,93 12,01 11,00 9,96 9,15 8,61
4 14,75 13,93 13,06 12,16 11,20 10,21 9,44 8,95 ^0 = ^ ( ^ + - - ) (-75)
5 14,85 14,04 13,19 12,31 11,38 10,43 9,67 9,18
6 14,95 14,15 13,30 12,45 11,53 10,61 9,85 9,38 C v
7 15,04 14,24 13,41 12,56 11,69 10,76 10,00 9,53 .
8 15,12 14,32 13,50 12,67 11,81 10,89 10,15 9,67 0 C v
9 15,20 14,41 13,59 12,77 11,92 11,00 10,28 9,79 , (1-75)
10 15,28 14,49 13,67 12,85 12,02 11,09 10,48 9,89 ~ 5 %
11 15,35 14,56 13,75 12,93 12,10 11,17 11,00 9,99 ~13% .
12 15,42 14,63 13,82 13,00 12,15 11,25 11,10 10,08 30%.
0
[81].
:
~ 2%
[75]: - ^ 2- = 2,4 + 0,0160"5 2 >5 (1-76)

Sh ( 1 0 0 S ) = 2 U s h (W i B ) (1 -7 1 ) :
J= I
Xi W t - ^ 2 - = 3,4+ 1,32 Cv - - j - (1-77)
Fo 7
/; ,
:
; ,
.
, 2- = 3,6 + 1, - 0,(> - - (1-78)
! Tn
,
X0
[76]: , / (* * ) ;
X xW\ - X2W2 0,72iffi-'2 (2 |) (1-72)
|0 , ,
,C v ,
Xi X2 /( ) ; Cir ,
1 2, 2>\; w x W2
. , /( ) ; ,
( / ( ) .
)
(1-62), . ,
. 1-12 .
:
[77],
[78]. , a= 8,75 1 ) (1-79)

, :
,
*1 _ 1 2+ 2 ( ) ^ , /3; Ln, /
~ 2+ + ( ) (73) , / ( ) ; R
, /( ) .
, (1-79) .
0 Cr ,
. X0
[79] , 4, 3,5 7,5%
( ,
) . .
. 20%
0 10%.
24 . 1. -

112
/, ) ( ),

CH3 CH2R I
I CH3 I CH2 I I R -C =
, C= O I I C H 3- C H 2- R -C -H R -C - R -C H = 1 R - C H = 2 = C H -C H = ^ c-C - I
I I CH2 I I
R CH2R I

200 1,79 1,4 2,24 2,64 1,74 1,76 1,60 2,02 1,48 2,09 0,81 1,91
298 1,52 1,35 2,33 3,18 2,10 2,12 1,99 2,02 1,26 3,02 0,92 2,15
400 1,32 1,25 2,26 2,74 2,17 2,19 2,18 1,82 1,16 3,25 0,76 2,10
500 1,24 1,20 2,09 2,39 2,09 2,12 2,23 1,65 1,11 2,96 0,60 1,95
600 1,18 1,18 1,91 2,12 1,96 2,00 2,18 1,50 1,07 2,67 0,48 1,79
700 1,10 1,16 1,71 1,90 1,82 1,82 2,08 1,40 1,05 2,44 0,39 1,65
800 1,09 1,15 1,66 1,73 1,69 1,71 1,96 1,32 1,04 2,44 0,35 1,54
900 1,08 1,14 1,55 1,60 1,59 1,62 1,85 1,26 1,03 2,09 . 0,32 1,46
1000 1,06 1,13 1,47 1,51 1,51 1,55 1,76 1,21 1,02 1,96 0,31 1,38

1 .
2 -2-.

Acm P0
, . ,

[82]: , -


= - ------------ (1-80)

I= 1

19 ,
273 < < 353 , ,
(1-80)
2,7%;
9,5%. ,
[83], , ,
,
. ...................


.
. ,
. 1-10 [84] (
20%) /0,

P T7 a Ao -
Pjip * / ^kp
1-13


V 106
V iV )

Hr2 . . . 584 102 6,79


CO . . . . 133 34,5 . 8,61
Cl2 . . . . 417 76,1 9,60 '
F 2 ................ 144 55,0 9,54
8,21 Pfi * PhPkp
HBr . . . . 363,2 84,0
HCl . . . . 324,6 81,5
HF . . . . . . 503,4 ' 94,5 26,0 . 1-10.
I2 . . . , . 785 116 6,33 .
NO . . . . 180 64 11,82 () () :
N2 . . . . 126,2 33,5 8,55 ;
O2 . . . . 154,8 50,1 10,40 ; , .
25

,
.

,
A0, , [85].

. 1-11. .

, . (1-80),
. 1-10,
T [86]:
(1-9) (1-15).

' = - ' (1' 81)

[19]. . I-Il , ,
Anp P np .
Fnp.
, , =230,
. M l ~1,4% N2 13,2%
. :
11 . 1-13 ,
> = Ig P n + f + 2 ( 1' 8 2 )
.
.[lg (PmfPu2)] (T 1 + 230) (F2 + 230) '
F 1- - F 2
(1-22).
(1-81)

P n
, Fnp=0,85.
, ,
, .
26 . I. -

(1-82) (1-83) 4
<250,
<0,65 [33]. [ (1-92)]
( ,
, NH3 H2O)
[87]: ,
, Jj ,
,

Ig = 0,118- 7 Ig Tnp + ( - 7) (0,0364 - Ig )


................ -0,462 ................. 0,043
(1-84) . . . . 0,249 C6H5 . . . 0,385
. . . . 0,054 0,478
.................... 0,340 CO (,
35 + 42 In T1np (1-85) .................... 0,326 ) . . . 0,105
........................ 0,335 CN () 0,381
,

d In P n
= - ( 1-86) ~20% , ~90% .
d in T

[88]: ( 1-2%)
[93]:
= 5,808 + 4,93 (1-87)
: -Aee lr (1-93)
:
Ig
CD = 1 ( 1-88) ,
7 (7/) ~ 1 . ,
(1-93),
.
, Ig \1 = f ("* j
[89]:
1 -3 ,7 2 Z KP (1-93)

= 7+- (89) ,
, ,
Z kp [ .
(1-19) (1-20)]. .
p-,

(. 1-12) [94],
. ,
, . ,
, .
~0,29 ( 25% ) [90].
, .
[91]: ,
<40 .
*0,275,5 (1-90) , ,
,
. ,
\i Po
, \ = 1,32, CH3O H ----- ,
, , Hp0
/3. Po
(1-90) ~ = IO7 ( -
~ 21% , ~ 5 2 % . Hp 0
, P = 11700 ,
, [92]: Ppo P 0 = 1 ).
(1-91) [95]
= 0,01675 IOv ,
. [96]
B ( I - T np) ,
Y= (1-92) 34
1
, 1.
,

(. 1-14). . Ho
(1-91) , .
<15 / ^ /- [97] -
27

, -, , [99];
: + 04
(1-94) 1 + 2,5 (1-96)
IiCM'- . ' + '
1/ 7 +
Ai A2 - ; pi Ph
2 ;
. .
(1-94) (1-96) ,

, , <0,03. ,
>0,03, [100]
[101]:

IaC (1-97)

(
) , ,
<0,5, [102, 103]:
I 0,5
(1-98)
( I )4
;
().
(1-98)
^ 0,1,

,
(,
, ).
, , , ,
,
, .

, [104].
, , ^ 0,3,
:
1)

------------------------------------------ (1-99)
1
0,460-0,00158 (/)0,469
2)
. 1-12. (, )
. (, )
0,403
(MOO)
(, 0,403 - 1
2 P i < 15 ). ,
3)

2 -3 % .
,
, ? , = 0,460 - 0,00158 f J 0,469 - 0,79 (M O l)
-a CM ~
\ R /
, Ta-
[98]: (1-99) (1-101) R =


A i P i ^ i + X2Q22 + 2 p i z ( ^ ^ ^ ) 00 (1-95) .
.
Oj 2 ;
Pi2 , ( 3%, 15%)
( [105],
[106], ,
).

(1-95) VKp. :
<10% ,
. 33,3 (MTkp) 1'*
() Po ~ ~ / (1,) (1-102)

28 . 1. -

Po () , :
; 7 , 0K; Vnp 3/2
, !\ /(1,33 Fnp) Ho = C 7 - (1-105)
F + 1,47 Fkhii
, . 1-15. :
1-15 .2 = / 3/2 F 1 + 1,47Fkiifi
(1-106)
P oi \ Fj / F2 + 1,47

(1-102) (1-107) IX02 Ji0I
F2 Fb
1,33 7, 1,33 7. /(1,33 7 ) 1,33 . f (1,33 Tnp)

0,30 0,1969 1,65 1,0174 4.0 2,0719


0,35 0,2252 1,70 1,0453 4.1 2,1090
0,40 0,2540 1,75 1,0729 4.2 2,1457
0,45 0,2834 1,80 1,0999 4.3 2,1820
0,50 0,3134 1,85 1,1264 4.4 2,2180
0,55 0,3440 1,90 1,1529 4.5 2,2536
0,60 0,3751 1,95 1,1790 4.6 2,2888
0,65 0,4066 2,00 1,2048 4.7 2,3237
0,70 0,4384 2,10 1,2558 4.8 2,3583
0,75 0,4704 2,2 1,3057 4.9 2,3926
0,80 0,5020 2.3 .1,3547 5.0 2,4264
0,85 0,5346 2.4 1,4028 6.0 2,751
0,90 0,5666 2.5 1,4501 7.0 3,053
0,95 0,5985 2.6 1,4962 8.0 3,337
1,00 0,6302 2.7 1,5417 9,0 3,607
1,05 0,6616 2.8 1,5861 10 3,866
1,10 0,6928 2,9 1,6298 20 6,063
1,15 0,7237 3.0 1,6728 30 7,880
1,20 0,7544 3.1 1,7154 40 9,480
1,25 0,7849 3.2 1,7573 50 10,958
1,30 0,8151 3.3 1,7983 60 12,324
1,35 0,8449 3.4 1,8388 70 13,615
1,40 0,8744 3.5 1,8789 80 14,839
1,45 0,9036 3.6 1,9186 90 16,010
1,50 0,9325 3.7 1,9576 100 17,137
1,55 0,9611 3.8 1,9962 200 26,80
1,60 0,9894 3.9 2,0343 400 41,90


-
[107]:
/( 1 ,3 3 ) = 1,058 645 - - 0,261 (1-103)

, Fnp>
>0,3.
Vkp ,
, . 1-13. - .
, :
[108, 109]: a -V -p jV -l = f (Pnp) Tap const; - / , - { (T v p )
Pnp = const.
27,0 M lh Tih
IA0 = - (1-104)
V ^ n {T + IA T T hm )
(1-102)
Vunn :
(1-18) / (1,33Fnp 2) , *
(. 1-6). , Iioi / (l,33Fn p ,)

(I-1Q4) 5%, 15%. (1-107) , -,
,
(1-104), , .
29

. 1-13,
(. 1-13) [HO]. Tucnp = TITncnp
Pncnp = PIPncnp-
P
~ 2% , 10%. (1-9) (1-15)


.
C a r n b i l l , C hem . E n g ., F eb r. 1957 J a n . I960 (se rie s ! 33
. , , a rtic le s). H i s h f I d , Curtiss, Bird, M o lec u la r
= 1,67 P np = T heory of G a se s a n d L iq u id s, N ew York, 1954. P a r t i n g t o n ,
= 23, . 1-13, An A dvanced T rea tise of P h y sic a l C h em istry , llo n d o n , vol. I, 1949;
fip/fii =23, Pnp = 1,6 Pnp =1,75 ( vol. 2, 1951. R e i d , S h e r w o o d , The P ro p e rtie s of G a se s
a n d L iq u id s, N ew York, 1958. S c h e i b e I, In d . E n g . C hem .,
1,67,
46, 1569 (1954). . ,
). ,
, . . . . , .
p-/ P np = 2 3
, 1966
. 1-13,6, Pnp = 1,67
\ipln 1, . .
P 1 .

I. M e i s s n e r , C hem . E ng. P r o g r., 45, 149 (1949). 2. G a m -


b i 11, C hem . E n g ., J u ly , 267 (1957). 3. M c G o w a n , C hem . a.
In d ., 495, M ay 31 (1952). 4. S m i t h , G r e e n b a u m, R u t
l e d g e , J. P h y s. C hem ., 58, 443 ( 1 9 5 4 ) .- 5 . G a m b i 1 1, C hem .
E n g ., J u n e 15, 182 ( 1 9 5 9 ) .- 6 . N k a y, C hem . E n g ., F e b r. 23,
146 ( 1 9 5 9 ) .- 7 . G a t e s , T h o d o s, Am. In s t. C hem . E n g rs J.,
6, 50 ( 1 9 6 0 ) .- 8 . K a y , In d . E ng. C hem ., 28, 1014 (1936).
9. E d m i s t e r, P e tro l. R efiner, S ept., 95 (1949). 10. E d m i -
s t e r, P e tro l. R efiner, A pril, 213 (1948).

II. G a m b i 11, C hem . E n g ., J u ly 13, 157, 160 (1959). 12. H e r*


z g, In d . E n g . C hem ., 36, 997 (1944). 13. B e n e d i c t (1939),
. no E d m i s t e r, P e tro l. R efiner, S ept., 95 (1949). 14. B e n-
s o n , J. P hys. a. C olloid. C hem ., 52, 1060 ( 1 9 4 8 ) .- 15. L e B a s .
The M o lec u la r V olum es of L iquid C h em ical C o m pounds, L ondon,
1915. 16. L d e r s e n, U niv. W isconsin E n g . E xpt. S ta . R ept
3 a. 4, 1955. 17. E d m i s t e r, P e tro l. R efiner, A pril, 178
. 1-14. ( 1 9 5 8 ) .-1 8 . O w e n s , T h o d o s, Am. In s t. C hem . E n g rs J., 3,
( ). 454 (1957). 19. S c h a e f e r , T h o d o s, Am. In s t. C hem . E n g rs
J., 5, 367 (1 9 5 9 ) .- 2 0 . B r e b a c h, T h o d o s, In d . E n g . C hem .,
50, 1095 (1958).
, . 1-14,

21 U y e h a r a, W a t s o n , N a tl. P e tro L N ew s (T ech. Sec.),
P np Pnp [111] 36, R-764 ( 1 9 4 4 ) .- 22. G o l d h a m m e r , Z. phys. C hem ., 71,
,
577 ( 1 9 1 0 ) .-2 3 . O t h m e r, J o s e f o w i t z, S c h m u t z l e r,
He, H2 D2. In d . E n g . C hem ., 40, 883 ( 1 9 4 8 ) .- 2 4 . N. G. S. M. A. D a ta Book,
6 ed., 1951. 25. L u . C hem . E n g ., M ay 4, 137 (1959). 26. N e 1-
s n, O b e t. C hem . E n g ., J u ly , 203 (1954). 27. M a s I a n,
[112]:
L i 11 m a n, In d . E n g . C hem ., 45, 1566 (1953). 28. W e n n e r,
T herm ochem ical C a lc u la tio n s , N ew York, 1941. 29. S a t h, J.
S W iMr Sei. Res. In s t. (T okyo), 43, 79 (1948), . no [33]. 30. C l e n -
d e n i n, P a . S ta te C ollege M in eral In d u s trie s E xptl S ta . Tech.
. = ~ ------------ (1-108) P a p e r 160, 1949.
2 Jli Af?-5
31. C r a g e, N BS M isc. P u b l. 97, 1929. 32. J o h n s o n ,
H u a n g . C an. J. T echnol., 33, 421 (1955). 33. R e i d , S h e r
w o o d , The P ro p e rtie s of G a se s a n d L iq u id s, N ew York, 1958.
, 34.C h o w , B r i g h t , C hem . E n g . P ro g r., 49, 175 (1953).
. 35. W a t s o n , In d . E n g . C hem ., 35, 398 (1943). 36. D o u g l a s ,
(1-108) ~ 2 % . T ran s. Am. Soc. M ech. E n g rs, 79, 23 (1957). 37. S a k i a d i s,
, [82]. C o a t e s , Am. In st. C hem . E n g rs J., 2, 88 (1 9 5 6 ) .- 3 8 . B a h l -
k e, K a y , In d . E ng. C hem ., 21, 942 (1 9 2 9 ) .- 3 9 . B r o o k s , O il
. G as J., M ay 4, 139 ( 1 9 5 3 ) .- 40. D b r a t z, In d . E n g . C hem .,
, , 33, 759 (1941).
, 10%.
H2>25%, 41. M e g h e b I i a n, J. Am. R ocket Soc., 21, 127 (1957).
[]. 42. G r a w f d, P a r r , J. C hem . P h y s , 16, 233 (1948).
43. Souders,M atthew;, H u r d , Ind. E ng. C hem ., 41,
(1-108) 1037 (1949), 44^ L d m i s t e r 1 P e tro l. E n g ., D ec., C-16 (1950).
30 . 1. -

45. E d m i s t e r f Petrol. Refiner, N ov., 613 (1 9 4 8 ).-4 6 . . . - , ., 6, 545 ( 1 9 4 0 ) .-7 8 . O r r , D a l l a V a l l e , Heat


, , 39, 342 (1907); , 5, 372 (1907). 47. G i - Transfer S tudies for 1954, Chem. Eng. Progr., Sym p. Ser., Ne 9,
1 n , G azz. chim . Italt 81, 180 ( 1 9 5 1 ) .- 4 8 . D o d g e , C he 50, 29 ( 1 9 5 4 ) .-7 9 . W a n g , K n u d s e n, Ind. E ng. Chem., 50,
mical E n gin eerin g Therm odinam ics, N ew York, 1944, p. 392. 1667 (1 9 5 8 ) .- 8 0 . E u c k e n, P h ys. Z., 14, 324 (1913).
49. H u g e n, W a t s o n , C hem ical P rocess Principles, part I,
New York, 1943, p. 337. 50. T u r k d o g a n, P e a r s o n , . 81. B r o m l e y , U niv. Calif. R adiation Lab. Rept UCRL-1852,
Appl. Chem., 3, 495 (1953). Jun e 12, 1952. 82. F r i e n d , A d l e r , Transport Properties in
G ases, E vanston, 111, 1958, p. 128. 83. L i n d s a y , Brom
51. G a m b 111, Chem. E ng., A ug. 25, 121 (1-958). 52. W a r d , l e y , Ind. E ng. Chem., 42, 1508 ( 1 9 5 0 ) .- 8 4 . L e n o i r , J u n k .
K u r t z . Ind. E ng. Chem., A nal. Ed., 10, 573 (1938); K u r t z Comings, Chem. Eng. Progr., 49, 539 ( 1 9 5 3 ) .- 8 5 . Gor-*
et al., Ind. E ng. Chem., 42, 174 ( 1 9 5 0 ) .- 5 3 . T I p a t h I, J. In d o n , Ind. Eng. Chem., 35, 851 (1943). 86. A n t o i n e , Compt.
dian Chem. Soc., 18, 411 (1 9 4 1 ) .- 5 4 . M e i s s n e r , M i c h a e l s , rend., 107, 681, 836 (1 8 8 8 ) .- 8 7 . R i e d e l , Chem. Ing. Techn.,
Ind. Eng. Chem., 41, 2782 (1 9 4 9 ) .- 5 5 . S u g d e n, The Parachor 26, 83 (1954). 88. H i r s c h f e l d e r et. al., Ind. E ng. Chem.,
and V alency, R outkedge, London, 1930. 56. J o h n s o n et al., 50, 375 (1 9 5 8 ) .-8 9 . R i e d e l , Chem. Ing. Techn., 26, 679
Chem. in C an., A ug., 28 ( 1 9 5 4 ) .- 57. W a l d e n , Z. E letrochem ., (1 9 5 4 ) .- 9 0 . G a m b i I, Chem. Eng., Jan. 12, 1130 (1959).
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(1 9 4 1 ) .- 5 9 . K h a r b a n d a. Ind. C hem ist, April, 187 (1955). 91. P t i n g t n, An A dvanced Treatise on P h ysical Che
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part II, 573 ( 1 9 4 6 ) .- 9 3 . A n d r a d e , N ature, 125, 309,v 582
61. H a m m f c k , A n d r e w , J. Chem. Soc., 754 (1929). (1 9 3 0 ) .- 9 4 . L e w i s , Squires, Oil Gas J., N ov. 15, 92
62. W e i n a u g, K a t z , Ind. Eng. Chem., 35, 239 (1943); R e n o , (1934). 95. A n d r a d e , Endeavour, 13, 117 (1954). 96. n d i,
Katz. Ind. E ng. Chem., 35, 1091 ( 1 9 4 3 ) .- 6 3 . Ewing, Petrol. Refiner, 25, 269 (1946). 97. K e n d a l l , M o n r o e , J.
W a l k e r , C r a n d, M i l l e r , Chem. E ng. Progr., Sym p. Ser., Am. Chem. Soc., 39, 1787 (1917); 43, 115 ( 1 9 2 1 ) .-9 8 . T a m u r a.
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Proc. Roy. Soc., 138A, 41 ( 1 9 3 2 ) .- 100. O l n e y, C a r l s o n ,
M ar. 9, 1951. 65. Forest Products Lab., U. S., D epartm ent of
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s e l . J. Am. Ceram . Soc., 18, I ( 1 9 3 5 ) .- 6 7 . L a u b i t z. Can. 101. A r r h e n i u s , Z. phys. Chem., 1, 285 ( 1 8 8 7 ) .- 102. K u
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(London, July, 1957), Institution of M echanical E ngineers, Lon tiss, B i r d , M olecular Theory of G ases and L iquids, N ew
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(1948). 1641 ( 1 9 5 1 ) .- 107. S c h e i b e i , Ind. E n g . Chem ., 46, 1574, 2007
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ternation al Critical T ables, vol. V, N ew York, 1929, p. 227. 111. R o s s , B r o w n , Ind. Eng. Chem., 49, 2026 (1957).
76. . . , H. . , . , 112. H e r n i n g, Z i p p e r e r, Gas u. W asserfach, 79, 49, 69
. .- , 10 (3), Ns 2, 37 ( 1 9 5 5 ) .- 7 7 . . . T . ( 1 9 3 6 ) .- 113. W i l k e , J. Chem. Ph ys., 18, 517 (1950)*

, . 1-16, 1-17, 1-18 1-19,


, Smithsonian Physical Tables, 9 ed.,
International Critical T ables1. Washington, 1954.

*.

1 International C ritical T ables, vol. I-V II, N ew York, 1926 1 W ADS-TR-59-598, 1599. H d g m a n (ed .), Handbook of
1933. C m. , , C hemistry and P h ysics, 40 ed. J o h n s o n (ed .). WADD-TR-
, . 1X, 19281936. 60-56, 1960.
31

1-16

( / ) , , 041 769 p m . c m .



1
0 1 2 3 4 5 7 8 9

0 0,999 8681 8747 8812 8875 8936 8996 9053 9109 9163 9216 59
1 9267 9315 9363 9408 9452 9494 9534 9573 9610 9645 41
2 9679 9711 9741 9769 9796 9821 9844 9866 9887 9905 24
3 9922 9937 9951 9962 9973 9981 9988 9994 9998 0000 8
4 1,000 0000 9999 9996 9992 9986 9979 9970 9960 9947 9934 -8

5 0,999 9919 9902 9884 9864 9842 9819 9795 9769 9742 9713 24
6 9682 9650 9617 9582 9545 9507 9468 9427 9385 9341 -3 9
7 9296 9249 9201 9151 9100 9048 8994 8938 8881 8823 -5 3
8 8764 8903 8641 8577 8512 8445 8377 8308 8237 8165 -6 7
9 8091 8017 7940 7863 7754 7704 7622 7539 7455 7369 -8 1

10 7282 7194 7105 7014 6921 6826 6729 6632 6 6432 -9 5


11 6331 6228 6124 6020 5913 5805 5696 5586 5474 5362 -1 0 0
12 5248 5132 5016 4898 4780 4660 4538 4415 4291 4166 -1 2 1
13 4040 3912 3784 3654 3523 3391 3257 3122 2986 2850 -1 3 3
14 2712 2572 2431 2289 2147 2003 1858 1711 1564 1416 -1 4 5

15 1266 1114 0962 0809 0655 0499 0343 0185 0026 9865 -1 5 6
16 0,998 9705 9542 9378 9214 9048 8881 8713 8544 8373 8202 -1 6 8
17 8029 7856 7681 7505 7328 7150 6971 6791 6610 6427 -1 7 8
18 6244 6058 5873 5686 5498 5309 5119 4227 4735 4541 -1 9 0
19 4347 4152 3955 3757 3558 3358 3158 2955 2752 2549 -2 0 0

20 2343 2137 1930 1722 1511 1301 1090 0878 0663 0449 -2 1 1
21 0233 0016 9799 9580 9359 9139 8917 8694 8470 8245 -2 2 1
22 0,997 8019 7792 7564 7335 7104 6873 6641 6408 6173 5938 -2 3 2
23 5702 5466 5227 4988 4747 4506 4264 4021 3777 3531 -2 4 2
24 3286 3039 2790 2541 2291 2040 1788 1535 1280 1026 -2 5 2

25 0770 0513 0255 9997 9736 9476 9214 8951 8688 8423 -2 6 1
26 0,996 8158 7892 7624 7356 7087 6817 6545 6273 6000 5726 -2 7 1
27 5451 5176 4898 4620 4342 4062 3782 3500 3218 2935 -2 8 0
28 2652 2366 2080 1793 1505 1217 0928 0637 0346 0053 -2 8 9
29 0,995 9761 9466 9171 8876 8579 8282 7883 7684 7383 7083 -2 9 8

30 6780 6478 6174 5869 5564 5258 4950 4642 4334 4024 -3 0 7
31 3714 3401 3089 2776 2462 2147 1832 1515 1198 0880 -3 1 5
32 0561 0241 9920 9599 9276 8954 8630 8304 7979 7653 -3 2 4
33 0,994 7325 6997 6668 6338 6007 5676 5345 5011 4678 4343 -3 3 2
34 4007 3671 3335 2997 2659 2318 1978 1638 1296 0953 -3 4 0

35 0610 0267 9922 9576 9230 8883 8534 8186 7837 7486 -3 4 7
36 0,993 7136 6784 6432 6078 5725 5369 5014 4658 4301 3943 -3 5 5
37 3585 3226 2866 2505 2144 1782 1419 1055 0691 0326 -3 6 2
38 0,992 9960 9593 9227 8859 8490 8120 7751 7380 7008 6636 -3 7 0
39 6263 5890 5516 5140 4765 4389 4011 3634 3255 2876 -377
40 2497 2116 1734 1352 0971 0587 0203 9818 9433 9047 -3 8 4
41 0,991 8661

i .
32 . 1. -

1*17
10 250 1

p, ,
t, *10, t, ,
!Mi { -106, t, ! Mi V' 106,
0C Mi IKz 0C Mi Im 0C Mi Im

-1 0 998,15 1001,86 20 998,23 1001,77 50 988,07 1012,07


-9 998,43 1001,57 21 998,02 1001,98 51 987,62 1012,54
-8 998,69 1001,31 22 997,80 1002,20 52 987,15 1013,01
-7 998,92 1001,08 23 997,57 1002,44 53 986,69 1013,49
-6 999,12 1000,88 24 997,33 1002,68 54 986,21 1013,98
-5 999,30 1000,70 25 997,08 1002,93 55 985,73 1014,48
-4 999,45 1000,55 26 996,82 1003,20 60 983,24 1017,05
-3 999,58 1000,42 27 996,55 1003,47 65 980,59 1019,79
-2 999,70 1000,31 28 996,27 1003,75 70 977,81 1022,70
-I 999,79 1000,21 29 995,98 1004,04 75 974,89 1025,76
0 999,87 1000,13 30 995,68 1004,34 80 971,83 1028,99
I 999,93 1000,07 31 995,37 . 1004,65 85 968,65 1032,37
2 999,97 1000,03 32 995,06 1004,97 90 965,34 1035,90
3 999,99 1000,01 33 994,73 1005,30 95 961,92 1039,59
4 1000,00 1000,00 34 994,40 1005,63 100 958,38 1043,43
5 999,99 1000,01 35 994,06 1005,98 110 951,0 1051,5
6 999,97 1000,03 36 993,71 1006,33 120 943,4 1060,1
7 999,93 1000,07 37 993,36 1006,69 130 935,2 1069,3
8 999,88 1000,12 38 993,00 1007,06 140 926,4 1079,4
9 999,81 1000,19 39 992,63 1007,43 150 917,3 1090,2
10 999,73 1000,27 40 992,25 1007,82 160 907,5 1101,9
U 999,63 1000,37 41 991,87 1008,21 170 897,3 1114,5
12 999,52 1000,48 42 991,47 1008,61 180 886,6 1127,9
13 999,40 1000,60 43 991,07 1009,01 190 875,0 1142,9
14 999,27 1000,73 44 990,66 1009,43 200 862,8 1159,0
15 999,13 1000,87 45 990,25 1009,85 210 850 1177
16 998,97 1001,03 46 989,82 1010,28 220 837 1195
17 998,80 1001,20 47 989,40 1010,72 230 823 1215
18 998,62 1001,38 48 988,96 1011,16 240 809 1236
19 998,43 1001,57 49 988,52 1011,62 250 794 1259

1 .

1-18
10 360 1

, , ,
t , KZl Mi
* 106, L K zl Mi *10, t , KefMi V *106,
0C M i JKS 0C M i I KZ 0C 1

-1 0 13619,8 73,4225 0 13595,1 73,5560 10 13570,4 73,6893


-9 13617,3 4358 1 13592,6 5694 11 13568,0 7030
-8 13614,8 4492 2 13590,1 5828 12 13565,5 7164
-7 13612,4 4626 3 13587,7 5961 13 13563,0 7298
-6 13609,9 4759 4 13585,2 6095 14 13560,6 7431
-5 13607,4 73,4893 5 13582,7 73,6228 15 13558,1 73,7565
-4 13605,0 5026 6 13580,3 6362 16 13555,7 7699
-3 13602,5 5160 7 13577,8 6496 17 13553,2 7832
-2 13600,0 5293 8 13575,4 6629 18 13550,7 7966
-1 13597,6 5427 9 13572,9 6763 19 13548,3 8100

* C m. A t a c k , H andbook of C hem ical D ata, N ew York, 1957, p. 14, - L u b s k , K a u f Ti a n, NACA Rept 1270,
1956. A m erican In stitu te of P h y sic s H andbook, N ew York, 1957.
33

, , ,
t , // - 106, t , /< *10, t, //3 V -106,
0C ^/ 0C ^/ 0C 31

20 13545,8 73,8233 40 13496,9 74,0910 240 13020,6 76,8017


21 13543,4 8367 50 13472,5 2250 250 12997,2 9402
22 13540,9 8501 60 13448,2 3592 260 12973,8 77,0900
23 13538,5 8635 70 13424,0 4936 270 12950,4 2182
24 13536,0 8768 80 13399,8 6282 280 12927,0 3579
25 13533,6 73,8902 90 13372,3 74,7631 290 12903,6 77,4979
26 13531,1 9036 100 13351,5 8981 300 12880,3 6385
27 13528,7 9170 110 13327,9. 75,0305 310 12856,9 7795
28 13526,2 9304 120 13304,0 1653 320 12833,6 9210
29 14523,8 9437 130 13280,1 3002 330 12810,2 78,0630
30 13521,3 73,9572 140 13256,3 75,4354 340 127869 78,2054
31 13518,9 9705 150 13232,6 5708 350 127635 3485
32 13516,4 9839 160 13209,0 7064 360 127402 4921
33 13514,0 9973 170 13185,3 8422
34 13511,6 74,0107 180 13161,7 9784
35 13509,1 74,0241 190 13138,1 76,1149
36 13506,6 0374 200 13114,5 2516
37 13504,2 0508 210 13091,0 3886 .
38 13501,8 0642 220 13067,7 5260
39 13499,4 0776 230 13044,0 6637

I -19
(0 , 1 )
: S c o t t , C ryogen ic E n g in e e
Z ring, P rin ceton , N ew York, 1959. . . ,
MZ , . II, , 1960. W e a t h e r f o r d
- - - Z T y l e r , Ku , WADS-TR-59-598, 1959.
(. 70). , , . A t k, H andbook of C hem ical D ata, New
, , , , , York, 1957. A m erican In stitu te of P h y sics H andbook, N ew York,
(WADD-TR-60-56, 1960). 1957.
,



, -103, , P -103,
/ ! I /

........................ N2 28,02 1,2507 . . . . CO 28,00 1,2501


.................... NH3 17,03 0,7708 ................ Cl2O 86,91 3,8874
........................ Ar 39,91 1,7828 . . H2Se 81,22 3,6134
................ C2H2 26,02 1,1708 . . SO2 64,06 2,9268
........................ Br2 159,83 7,1388 ................ H2S 34,08 1,5392
........................ C4H 10 58,08 2,5985 . . COS 60,06 2,7201
.................... H2 2,016 0,0898 . H2Te 129,52 5,8034
.................... 1,2928 ................................ F2 38,00 1,6354
........................ He *4,00 0,1769 . . HF 20,01 0,9218
CO2 44.00 1,9768 ................................ Cl2 70,91 3,2204
. . . N2O 44.02 1,9781 . . HCl 36,47 1,6394
HI 127,94 5,7245 . . . CH3Cl 50,48 2,3044
................ O2 32.00 1,4289 . . NOCl 65,47 2,9864
.................... Kr 82,90 3,6431 . . . . C2H5CI 64,50 2,8700
.................... Xe 130,20 5,7168 () . . . . C2N2 52,02 2,3348
........................ CH 4 16.03 0,7167 ................................ C2H6 30,05 1,3567
........................ Ne 20,40 0,8713 ............................ C2H 4 28,03 1,2644
. . . . NO 30.01 1,3401
34 . I. -

*
: *
; t ( 4 ).
1-20
Al2(SO 4) 3
d*
X4 %
60 80
X4 % 45 j X4 % 45 X4 % dK X4 % 4 O0C 10 25 40

I 1,00931 8 1,0837 16 1,1770 24 1,2803 12 1,0539 1,0515 1,0464 1,0400 1,0301 1,0181
2 1,0195 12 1,1293 20 1,2272 26 1,3079 16 1,0721 1,0691 1,0633 1,0565 1,0462 1,0342
4 1,0404] 20 1,0905 1,0870 1,0806 1,0734 1,0627 1,0506
24 1,1090 1,1051 1,0982 1,0907 1,0796 1,0673
1-21 28 1,1277 1,1234 1,1161 1,1082 1,0968 1,0844
NH3 30 1,1371 1,1327 1,1252 1,1171 1,1055 1,0931
40 1,1862 1,1810 1,1727 1,1640 1,1515 1,1385
d\ 50 1,2380 1,2320 1,2229 1,2136 1,2006 1,1868
U Xt % /*15 1-25
* , %
dK
U (NH4)2SO4
7 7 I Si I
CM ?
I 0,9943 0,9954 0,9959 0,9958 0,99551 0,9939 0,993 32 0,889 d \
2
0,9906 0,9915 0,9919 0,9917 0,9913 0,9895 0,988 36 0,877
4 0,9834 0,9840 0,9842 0,9837 0,9832] 0,9811 0,980 40 0,865 *, %
8 0.970 0,9701 0,9701 0,9695 0,9686 0,9677 0,9651 0,964 45 0.849 O0C 20 40 80 IOO0C
12 0,958 0,9576 0,9571 0,9561 0,9548 0,9534 0,9501 0,948 50 0,832
16 0,947 0,9461 0,9450 0,9435 0,9420 0,9402 0,9362 0,934 60 0,796
20 0,9353 0,9335 0,9316 0,9296 0,9275 0,9229 # 70 0,755
24 9 . 0,9249 0,9226 0,9202 0,9179 0,9155 0,9101 . . 80 0,711 1 1,0061 1,0041 0,9980 0,9777 0,9644
28 0.9150 0,9122 0,9094 0,9067 0,9040 0,8980 90 0,665 2 1,0124 1,0101 1,0039 0,9836 0,9705
30 , . 0,9101 0,9070; 0,9040 0,9012 0,89831 0,8920 . 100 0,618
4 1,0248 1,0220 1,0155 0,9953 0,9826
8 1,0495 1,0456 1,0387 1,0187 1,0066
1-22 12 1,0740 1,0691 1,0619 1,0421 1,0303
CH3COONH4 1 16 1,0980 1,0924 1,0849 1,0653 1,0539
20 1,1215 1,1154 1,1077 1,0883 1,0772
.25 24 1,1448 1,1383 1,1304 1,1111 1,4003
X4 % 4 , % 4
X4 % dA 28 1,1677 1,1609 1,1529 1,1338 1,1232
35 1,2072 1,2000 1,1919 1,1731 1,1629
1 0,9992 16 1,0294 35 I 1,0618 40
50
1,2350
1,2899
1,2277
1,2825
12196
1,2745
UOll
1,2568
1,1910
1,2466
2 1,0013 20 1,0368 40 1,0691
4 1,0055 24 1,0439 45 1,0760 1-26
8 1,0136 28 1,0507
NH4Cl
12 1,0216 ^30 1,0540 I
1 / 16 = 3-*-52 . A t a c k , Hand d*
book of Chemical Data, New York, 1957, p. 33.
X4 %
1-23 O0C IO0C 20 30 60 80 IOO0C
(NH 4) 2Cr2O7
1 1,0033 1,0029 1,0013 0,9987 0,9910 0,9749 0,9617
. % , % 12 X4 % 4* 2 1,0067 1,0062 1,0045 1,0018 0,9940 0,9780 0,9651
4 1 dA
0,9718
4 1,0135 1,0126 1,0107 1,0077 0,9999 0,9842
8 1,0266 1,0251 1,0227 1,0195 1,0116 0,9963 0,9849
1 1,0051 4 1,0223 16 1,0981 12 1,0391 1,0370 1,0344 1,0310 1,0231 1,0081 0,9975
2 1,0108 8 1,0463 20 1,1263 16 1,0510 1,0485 1,0457 1,0422 1,0343 1,0198 1,0096
1-24 20 1,0625 1,0596 1,0567 1,0532 1,0454 1,0312 1,0213
24 1,0736 1,0705 1,0674 1,0641 1,0564 1,0426 1,0327
NH4NO3
1-27
d* (NH 4)2CrO4
, %
0 10 25 40 60 80
X4 % /, 0C < R * % /. <
1 1,0043 1,0039 1,0011 1,9961 0,9870 0,9755
2 1,0088 1,0082 1,0051 1,0000 0,9908 0,9793
4 1,0178 1,0168 1,0132 1,0079 0,9985 0,9869 3,80 20 1,0219 19,75 13,7 1,1189
8 1,0358 1,0340 1,0297 1,0238 1,0142 1,0024 10,52 13 1,0627 Il 28,04 19,6 1,1707
* .
35

1-28 1-32
BaCl2 HCl

d * d*
JCf % X. %
CPC 20 40 60 80 IOOe C 5 CPC 10 20 40 60 80 IOOe C

1 1,0048 1,0052 1,0048 1,0052 0,9970 0,9881 0,9768 0,9636


2 1,0181 1,0159 1,0096 1,0004 0,9890 0,9755 2 1,0104 1,0106 1,0100 1,0082 1,0019 0,9930 0,9819 0,9688
4 1,0368 1,0341 1,0275 1,0181 1,0066 0,9931 4 1,0213 1,0213 1,0202 1,0181 1,0116 1,0026 0,9919 0,9791
8 1,0760 1,0721 1,0648 1,0551 1,0434 1,0299 6 1,0321 1,0319 1,0303 1,0279 1,0211 1,0121 1,0016 0,9892
8 1.0428 1,0423 1,0403 1,0376 1,0305 1,0215 1,0111 0,9992
12 1,1178 1,1128 1,1047 1,0948 1,0827 1,0692 10 1,0336 1,0528 1,0504 1,0474 1,0400 1,0310 1,0206 1,0090
16 1,1627 1,1564 1,1478 1,1373 1,1249 1,1113 12 1.0645 1,0634 1,0607 1,0574 1,0497 1,0406 1,0302 1,0188
20 1,2105 1,2031 1,1938 1,1828 1,1702 1,1563 14 1,0754 1,0741 1,0711 1,0675 1,0594 1,0502 1,0398 1,0286
16 1.0864 1,0849 1,0815 1,0776 1,0692 1,0598 1,0494 1,0383
24 1,2531 1,2430 1,2316 1,2186 1,2045 18 1,0975 1,0958 1,0920 1,0878 1,0790 1 0694 1,0590 1,0479
26 . . . 1,2793 1,2688 1,2571 1,2440 1,2298 20 1.1087 1,1067 1,1025 1,0980 1,0888 1,0790 1.0685 1,0574
22 1.1200 1,1177 1,1131 1,1083 1,0986 1,0886 1,0780 1,0668
24 1,1314 1,1287 1,1238 1,1187 1,1085 1,0982 1,0874 1,0761
26 1.1426 1,1396 1,1344 1,1290 1,1183 1,1076 1 0967 1,0853
1-29 28 1,1537 1,1505 1.1449 1,1392 1,1280 1,1169 1,1058 1,0942
30 1,1648 1,1613 1,1553 1,1493 1,1376 1,1260 1,1149 1,1030
HBr 32 1,1593
34 1,1691
36 1,1789
10 .25 10 .25 38 1,1885
JC, % < 4 dA X, % dA dA 40 1,1980

1 1,0073 1,0068 1,0041 20 1,1640 1,1615 1,1557


2 1,0146 1,0139 1,0111 22 1,1832 1,1806 1,1743
1-33
4 1,0295 1,0285 1,0255 24 1,2030 1,2003 1,1935
6 1,0448 1,0435 1,0402 26 1,2235 1,2206 1,2134 HCN
8 1,0604 1,0589 1,0552 28 1,2446 1,2415 1,2340
10 1,0764 1,0747 1,0707 30 1,2663 1,2630 1,2552 ^ 15
JC. % 15
12 1,0928 1,0910 1,0867 40 1,3877 1,3838 1,3736 4 JC. % d A5 j > dA
14 1,1097 1,1078 1,1032 50 1,5305 1,5257 1,5127
16 1,1272 1,1251 1,1202 60 1,6950 1,6892 1,6731
18 1,1453 1,1430 1,1377 65 1,7854 1,7792 1,7613 1 0,998 8 0,984 82 0,752
2 0,996 12 0,971 90 0,724
4 0,993 16 0,956 100 0,691
1-30
H2O2

,1 8 1 34
X, % JCf % JC, % 18
dA JCf % dA dA
N2H4

1 1,0022 14 1,0499 28 1,1040 J 55 1,2188 JC, % JC, % JC, % W15


d A JC, % 4 5
2 1,0058 16 1,0574 30 1,1122 60 1,2416
4 1,0131 18 1,0649 35 1,1327 70 1,2897
6 1,0204 20 1,0725 40 1,1536 80 1,3406
8 1,0277 22 1,0802 45 1,1749 90 1,3931 1 1,0002 16 1,0164 30 1,0305 70 1,046
10 1,0351 24 1,0880 100 2 1,0013 20 1,0207 40 1,038 80 1,040
50 1,1966 1,4465
4 1,0034 24 1,0248 50 1,044 90 1,030
12 1,0425 26 1,0959
j I 8 1,0077 28 1,0286 j 60 1,047 100 1,011
12 1,0121
I 31 Il
HF

1-35
, % JC, %
A t
(III) Fe(NO 3)3

5 1,020 1,017 60 1,235 JC, % ^ 18 ,J 8


4 JC, % Xt % dA , % 4
10 1,040 1,035 70 1,258
20 1,080 1,070 80 1,259
30 1,119 1,101 90 1,178
40 1,159 1,130 95 1,089 1 1,0065 4 1,0304 12 1,0989 20 1,1748
50 1,198 1,155 100 1,0005 2 1,0144 8 1,0636 16 1,1359 25 1,2281
36 . I. -

I 36 I-41
(II) FeSO4 KHCO3

^4 dtA d 4
X, % i, 1 0C
15 18 20
JXv 2% j 4% \% 2% 4%

0,2 1,00068 1,0002 0 1,0066 1,0134 1,0270 40 0,9990 1,0058 1,0195


0,4 . . 1,00275 1,0022 10 1,0064 1,0132 1,0268 50 0,9949 1,0017 1,0154
0,8 1,00645 1,0062 15 1,0058 1,0125 1,0260 60 0,9901 0,9969 1,0106
1,0 i ,0090 1,0085 1,0082 20 1,0049 1,0117 1,0252 80 0,9786 0,9855 0,9993
4,0 1,0380 1,0375 30 ,1,0024 1,0092 1,0228 . 100 0,9653 0,9722 0,9860
8,0 1,0790 1,0785
12,0 1,1235 1,1220 6% ^ 45 1,0396, 8 %
16,0 1,1690 1,1675
^45 = 1,534, 10% d xA = 1,0674.
20,0 1,2150 1,2135
1-37 1-42
(III) Fe2(SO 4) 3 K2Cr2O7

w20 ,2 0
X, % *17,5 .1 7 ,5 , % X, % , % 4
X. % 4 4

1 1,0052 4 1,0264 8 1,0554


1,0072 8 1,0670 20 1,1811 50 1,6127
2 1,0122 I 6 1,0408 10 1,0703
1,0157 12 1,1028 30 1,3073 60 1,7983
1,0327 16 1,1409 40 1,44871 1-43
KBr
1-38
(III) FeCl3 j 20
W20
X, % dA X, % dA * 4
ct.4 d A
1 1,0054 12 1,0903 30 1,2993
2 1,0127 20 1,1601 40 1,3746
O0 C 10 20 30 O0 C 10 20 30 6 1,0426 U
1-44
1 1,0086 1,0084 1,0068 1,0040 25 1,2400 1,2380 1,2340 1,2290 KOH
2 1,0174 1,0168 1,0152 1,0122 30 1,2970 1,2950 1,2910 1,2850
4 1,0347 1,0341 1,0324 1,0292 35 1,3605 1,3580 1,3530 1,3475
8 1,0703 1,0692 1,0669 1,0636 40 1,4280 1,4235 1,4175 1,4115
W15
12 1,1088 1,1071 1,1040 1,1006 45 1,4920 1,4850 X, % dI5 X, % 4 , % dA , % dI5
Ib 1,1475 1,1449 1,1418 1,1386 50 1,5610 1,5510
20 1,1870 1,1847 1,1820 1,1786 (I
1 1,00831 8 ' 1,0730 25 1,2387 45 1,4558
1-39 2 1,0175 10 1,0918 30 1,2905 50 1,5143
1 4 1,0359 15 1,1396 35 1,3440 51,7 1 1,5355
6 1,05441 20 1,1884 40 1,3991
.
W15 15 5
4 , % 4 , % dA 1-45
, %
K2CO3
2 1,0169 6 1,0520 10 1,0876 d 4
4 1,0345 8 1,0697 12 1,1060
J : CaOC l2 89,15%, CaCl2 - 7,31%, ( 3)2 0,26%, 0 10 I 20 40 60 80 I 100
C a(OH)2 -2 ,9 2 % .
1 1,0094 1,0089 1,0072 1,0010 0,9919 0,9803 0,9670
1-40 2 1,0189 1,0182 1,0163 1,0098 1,0005 0,9889 0,9756
4 1,0381 1,0369 1 0345 1,0276 1,0180 1,0063 0,9931
* Cd(NO3) 2 8 1,0768 1,0746 1,0715 1,0640 1,0538 1,0418 1,0291
12 1,1160 1,1131 1,1096 1,1013 1,0906 1,0786 1,0663
16 1,1562 1,1530 1,1490 1,1399 1,1290 1,1170 1.1049
W18 20 1,1977 1,1941 1,1898 1,1801 1,1690 1,1570 1,1451
X1 % , % j , % dI 8 Jj *. * 4 8 24 1,2405 1,2366 1,2320 1,2219 1,2106 1,1986 1,1869
28 1,2846 1,2804 1,2756 1,2652 1,2538 1.2418 1,2301
30 1,3071 1,3028 1,2979 1,2873 1,2759 1,2640 1,2522
2 1,0154 12 1,10611 25 1,2488 40 1,4590 35 1,3648 1,3600 1,3548 1,3440 1,3324 1,3206 1,3089
40 1,4244 1,4195 1,4141 1,4029 1,3913 1,3795 1.3678
4 1,0326 16 1,1468 30 1,3124 50 1,6356 45 1,4867 1,4815 1,4759 1,4644 1,4528 1,4408 1,4290
8 1,0683 II 20 1,1904 I 50 1,5517 1,5462 1,5404 1,5285 I 1,5169 1,5048 1,4928
37

1-46
KNO3 ^ 4
, %
d ^ IlO0 C I 120 j 130 I 140

O0 C 10 20 I 40 I 60 80 100 3,79 0,9733 0,9663 0,9583 0,9502


7,45 0,9978 0,9899 0.9827 0,9745
13,62 1,0388 1,0313 1,0238 1,0159
1 1,00654 1,00615 1,00447 0,99825 0,9890 0,9776 0,9641 1-51
2 1,01326 1,01262 I,(Jl 075 1,00430 0,9949 0,9834 0,9699 K2CrO4
4 1,02677 1,02566 1,02344 1,01652 1,0068 0,9951 0,9816
8 1,05419 1,05226 1,04940 1,04152 1,0313 1,0192 1,0056
12 1,08221 1,07963 1,07620 1,06740 1,0567 1,0442 1,0304 X, %
. 15
4
^ 8
dA X, % d1
A
5 W18
4
16 1,10392 1,09432 1,0831 1,0703 1,0562
20 1,13261 1,12240 1,1106 1,0974 0,0831
24 1,16233 1,15175| 1,1391 1,1256 1,1110 1 1,0073 1,0066 16 , 1,1366
2 1,0155 1,0147 20 1,1748
1-47 4 1,0321 1,0311 24 * 1,2147
8 1,0659 1,0647 28 1,2566
K2SO4 12 1,1009 1,0999 30 . . . 1,2784

X, % df j , %
.20
, %
.2
dA Ca(OH)2
1-52

W15
, % df
1 1,0063 4. 1,0310 8 1,0646 4

2 1,0145 I! 6 . 1,0477 I 10 1,0817


0,05 0,99979 0,99773
1-48 0,10 1,00044 0,99838
K2SO3 0,15 1,00110 0,99904
1-53

, % ./1 5
, %
Ab Ca(NO3) 2
.V, % d I5 dA dA

dt. dt.4
. , %
I 1,0073 8 1,0667 20 1,1793 %
2 1,0155 12 1,1026 24 1,2197 6 18 25 J 30 I 6 18 25 30
4 1,0322 16 1,1402 26 1,2404
2 1,0157 1,0137 1,0120 1,0105 I 25 1,2168 1,2106 1,2065 1,2032
1-49 4 1,0316 1,0291 1,0272 1,0256 30 1,260 . . .
8 1,0641 1,0608 1,0585 1,0565 35 . . . 1,311
KClO3 12 1,0979 1,0937 1,0911 1,0887 40 . . . 1,3.35
16 1,1330 1,1279 1,1250 1,1224 45 1,422 .
20 1,1694 1,1636 1,1602 1,1575 I 68 1 . . . 1,747 1,741 1,736

I, 0C 1 (
41,4 ).
1% 2% 3% 4%
1-54
CaCl2
0 1,0061 1,0124 1,0189 1,0256
. 10 1,0059 1,0122 1,0187 1,0254 cf.4
20 1,0045 1,0109 1,0174 1,0241 X,
30 1,0020 1,0085 1,0151 1,0218 %
I cO

- 5 |i 0 20 j 30 | 40 60 C 80 140

40 0,9986 1,0051 1,0116 1,0183


60 0,9895 0,9959 1,0024 1,0091 2 1,0171 1,0148 1,0120 1,0084 0,9994 0.9881 0,9748 0,9596 0,9428
80 0,9781 0,9845 0,9910 0,9977 4 1,0346 1,0316 1,0286 1,0249 1,0158 1,0046 0,9915 0,9765 0 9601
100 0,9646 0,9709 0,9774 0,9840 8 1*,0708 1,0703 1,0659 1,0626 1,0586 1,0492 1,0382 0,0257 1,0111 0,9954
12 1,1083 1,1072 1,1015 1,0978 1,0937 1,0840 1,0730 1,0610 1,0466 1,0317
1-50 16 1,1471 1,1454 1,1386 1,1345 1,1301 1,1202 1,1092 1,0973 1,0835 1,0691
20 1,1874 1,1853 1,1775 1,1730 1,1684 1,1581 1,1471 1,1352 1,1219 1,1080
KCl 25 . . 1,2376 1,2284 1,2236 1,2186 1,2079 1,1965 1,1846
30 1,2922 1,2816 1,2764 1,2709 1,2597 1,2478 1.2359
35 ,. 1,3373 1,3316 1,3255 1,3137 1,3013 1,2893
40 1 3957 1,3895 1,3826 1,3700 1,3571 1,3450
, %
1 .
O0 C 20 j 25 40 60 I 80 100
1-55
1,0 1,00661 1,00462 1,00342 0,99847 0,9894 0,9780 0,9646 ^ C r 2(SO 4) 4
2,0 1,01335 1,01103 1,00977 1-00471 0,9956 0,9842 0,9708
4,0
8,0
1 2 ,0
1,02690
1,05431
1,08222
1,02391
1,05003
1,07679
1,02255
1,04847
1,07506
1,01727
1,04278
1,06897
1,0080
1,0333
1,0592
0,9966
1,0219
1,0478
0,9834
1,0088
1,0350
, % ^15
4
X, % 18
4
X, % AS
dA Il ' % dA
16,0 1,11068 1,10434 1,10245 1,09600 1,0861 1,0746 1,0619 1 1,007 10 1,089 20 1,193 40 1,456
20.0 1,13973 1.13280 1,13072 1,12399 1,1138 1,1024 1,0897
24,0 . 1,16226 1,15995 1,15299 1,1425 1,1311 1,1185 2 1,016 14 1,129 30 1,315 50 1,615
28,0 . . . . 1,18304 1,1723 1,1609 1,1483 6 1,052
38 . /. -

1-56
HNO3

d \
X, %
QP 5 IOeC 15 20 25 30 ' 40 50 60* 80 IOO9

\ 1,0058 1,00572 1,00534 1,00464 1,00364 1,00241 1,0009 0,9973 0,9931 0,9882 0,9767 0,9632
2 1,0117 1,01149 1,01099 1,01018 1,00909 1,00778 1,0061 1,0025 0,9982 0,9932 0,9816 0,9681
3 1,0176 1,01730 1,01668 1,01576 1,01457 1,01318 1,0114 1,0077 1,0033 0,9982 0,9865 0,9730
4 1,0236 1,02315 1,02240 1,02137 1,02008 1,01861 1,0168 1,0129 1,0084 1,0033 0,9915 0,9779
5 1,0296 1,02904 1,02816 1,02702 1,02563 1,02408 1,0222 1,0182 1,0136 1,0084 0,9965 0,9829
6 1,0357 1,03497 1,03397 1,03272 1,03122 1,02958 1,0277 1,0235 1,0188 1,0136 1,0015 0,9879
7 1,0418 1,0410 1,0399 1,0375 1,0369 1,0352 1,0333 1,0289 1,0188 1,0188 1,0066 0,9929
8 1,0480 1,0471 1,0458 1,0443 1,0427 1,0409 1,0389 1,0344 1,0295 1,0241 1,0117 0,9980
9 1,0543 1,0532 1,0518 1,0502 1,0485 1,0466 1,0466 1,0399 1,0349 1,0294 1,0169 1,0032
10 1,0606 1,0594 1,0578 1,0561 1,0543 1,0523 1,0503 1,0455 1,0403 1,0347 1,0221 1,0083
11 1,0669 1,0656 1,0639 1,0621 1,0602 1,0581 1,0560 1,0511 1,0458 1,0401 1,0273 1,0134
12 1,0733 1,0718 1,0700 1,0681 1,0661 1,0640 1,0618 1,0567 1,0513 1,0455 1,0326 1,0186
13 1,0797 1,0781 1,0762 1,0742 1,0721 1,0699 1,0676 1,0624 1,0568 1,0509 1,0379 1,0238
14 1,0862 1,0845 1,0824 1,0803 1,0781 1,0758 1,0735 1,0681 1,0624 1,0564 1,0432 1,0289
15 1,0927 1,0909 1,0887 1,0865 1,0842 1,0818 1,0794 1,0739 1,0680 1,0619 1,0485 1,0341
16 1,0992 1,0973 1,0950 1,0927 1,0903 1,0879 1,0854 1,0797 1,0737 1,0675 1,0538 1,0393
17 1,1057 1,1038 1,1014 1,0989 1,0964 1,0940 1,0914 1,0855 1,0794 1,0731 1,0592 1,0444
18 1,1123 1,1103 1,1078 1,1052 1,1026 1,1001 1,0974 1,0913 1,0851 1,0787 1,0646 1,0496
19 1,1189 1,1168 1,1142 1,1115 1,1088 1,1062 1,1034 1,0972 1,0908 1,0843 1,0700 1,0547
20 1,1255 1,1234 1,1206 1,1178 1,1150 1,1123 1,1094 1,1031 1,0966 1,0899 1,0754 1,0598
21 1,1322 1,1300 1,1271 1,1242 1,1213 1,1185 1,1155 1,1090 1,1024 1,0956 1,0808 1,0650
22 1,1389 1,1366 1,1336 1,1306 1,1276 1,1247 1,1217 1,1150 1,1083 1,1013 1,0862 1,0701
23 1,1457 1,1433 1,1402 1,1371 1,1340 1,1310 1,1280 1,1210 1,1142 1,1070 1,0917 1,0753
24 1,1525 1,1501 1,1469 1,1437 1,1404 1,1374 1,1343 1,1271 1,1201 1,1127 1,0972 1,0805
25 1,1594 1,1568 1,1536 1,1503 1,1469 1,1438 1,1406 1,1332 1,1260 1,1185 1,1027 1,0857
26 1,1663 1,1638 1,1603 1,1569 1,1534 1,1502 1,1469 1,1394 1,1320 1,1244 1,1083 1,0910
27 1,1733 1,1707 1,1670 1,1635 1,1600 1,1566 1,1533 1,1456 1,1381 1,1303 1,1139 1,0963
28 1,1803 1,1777 1,1738 1,1702 1,1666 1,1631 1,1597 1,1519 1,1442 1,1362 1,1195 1,1016
29 1,1874 1,1847 1,1807 1,1770 1,1733 1,1697 1,1662 1,1582 1,1503 1,1422 1,1251 1,1069
30 1,1945 1,1917 1,1876 1,1838 1,1800 1,1763 1,1727 1,1645 1,1564 1,1482 1,1307 1,1122
31 1,2016 1,1988 1,1945 1,1906 1,1767 1,1829 1,1792 1,1708 1,1625 1,1542 1,1363 1,1175
32 1,2088 1,2059 1,2014 1,1974 1,1934 1,1896 1,1857 1,1772 1,1687 1,1602 1,1419 1,1228
33 1,2160 1,2131 1,2084 1,2043 1,2002 1,1963 1,1922 1,1836 1,1749 1,1662 1,1476 1,1281
34 1,2233 1,2203 1,2155 1,2113 1,2071 1,2030 1,1988 1,1901 1,1812 1,1723 1,1533 1,1335
35 1,2306 1,2275 1,2227 1,2183 1,2140 1,2098 1,2055 1,1966 1,1876 1,1784 1,1591 1,1390
36 1,2375 1,2344 1,2294 1,2249 1,2205 1,2163 1,2119 1,2028 1,1936 1,1842 1,1645 1,1440
37 1,2444 1,2412 1,2361 1,2315 1,2270 1,2227 1,2182 1,2089 1,1995 1,1899 1,1699 1,1490
38 1,2513 1,2479 1,2428 1,2381 1,2335 1,2291 1,2245 1,2150 1,2054 1,1956 1,1752 1,1540
39 1,2581 1,2546 1,2494 1,2446 1,2399 1,2354 1,2308 1,2210 1,2112 1,2013 1,1805 1,1589
40 1,2649 1,2613 1,2560 1,2511 1,2463 1,2417 1,2370 1,2270 1,2170 1,2069 1,1858 1,1638
41 1,2717 1,2680 1,2626 1,2576 1,2527 1,2480 1,2432 1,2330 1,2229 1,2126 1,1911 1,1687
42 1,2786 1,2747 1,2692 1,2641 1,2591 1,2543 1,2494 1,2390 1,2287 1 2 182 1,1963 1,1735
43 1,2854 1,2814 1,2758 1,2706 1,2655 1,2606 1,2556 1,2450 1,2345 1,2238 1,2015 1,1783
44 1,2922 1,2880 1,2824 1,2771 1,2719 1,2669 1,2618 1,2510 1,2403 1,2294 1,2067 1,1831
45 1,2990 1,2947 1,2890 1,2836 1,2783 1,2732 1,2680 1,2570 1,2461 1,2350 1,2119 1,1879
46 1,3058 1,3014 1,2955 1,2901 1,2847 1,2795 1,2742 1,2630 1,2519 1,2406 1,2171 1,1927
47 1,3126 1,3080 1,3021 1,2966 1,2911 1,2858 1,2804 1,2690 1,2577 1,2462 1,2223 1,1976
48 1,3194 1,3147 1,3087 1,3031 1,2975 1,2921 1,2867 1,2750 1,2635 1,2518 1,2275 1,2024
49 1,3263 1,3214 1,3153 1,3096 1,3040 1,2984 1,2929 1,2811 1,2693 1,2575 1,2328 1,2073
50 1,3327 1,3277 1,3215 1,3157 1,3100 1,3043 1,2987 1,2867 1,2748 1,2628 1,2377 1,2118
51 1,3391 1,3339 1,3277 1,3218 1,3160 1,3102 1,3045 1,2923 1,2802 1,2680 1,2425 1,2163
52 1,3454 1,3401 1,3338 1,3278 1,3219 1,3160 1,3102 1,2978 1,2856 1,2731 1,2473 1,2208
53 1,3517 1,3462 1,3399 1,3338 1,3278 1,3218 1,3159 1,3033 1,2909 1,2782 1,2521 1,2252
54 1,3579 1,3523 1,3459 1,3397 1,3336 1,3275 1,3215 1,3087 1,2961 1,2833 1,2568 1,2296
>
39

^4
X, %
O0C 5 IO0 15 20 25 30 40 50 60 80 100

55 1,3640 1,3583 1,3518 1,3455 1,3393 1,3331 1,3270 1,3141 1,3013 1,2883 1,2615 1,2339
56 1,3700 1,3642 1,3576 1,3512 1,3449 1,3386 1,3324 1,3194 1,3064 1,2932 1,2661 1,2382
57 1,3759 1,3700 1,3634 1,3569 1,3505 1,3441 1,3377 1,3246 1,3114 1,2981 1,2706 1,2424
58 1,3818 1,3757 1,3691 1,3625 1,3560 1,3495 1,3430 1,3298 1,3164 1,3029 1,2751 1,2466
59 1,3875 1,3813 1,3747 1,3680 1,3614 1,3548 1,3482 1,3348 1,3213 1,3077 1,2795 1,2507

60 1,3931 1,3868 1,3801 1,3734 1,3667 1,3600 1,3533 1,3398 1,3261 1,3124 1,2839 1,2547
61 1,3986 1,3922 1,3855 1,3787 1,3719 1,3651 1,3583 1,3447 1,3308 1,3169 1,2881 1,2587
62 1,4039 1,3975 1,3907 1,3838 1,3769 1,3700 1,3632 1,3394 1,3354 1,3213 1,2922 1,2625
63 1,4091 1,4027 1,3958 1,3888 1,3818 1,3748 1,3679 1,3540 1,3398 1,3255 1,2962 1,2661
64 . . . 1,4078 1,4007 1,3936 1,3866 1,3795 1,3725

65 1,4128 1,4055 1,3984 1,3913 1,3841 1,3770


66 1,4177 1,4103 1,4031 1,3959 1,3887 1,3814
67 1,4224 1,4150 1,4077 1,4004 1,3932 1,3857
68 1,4271 1,4196 1,4122 1,4048 1,3976 13900
69 1,4317 1,4241 1,4166 1,4091 1,4019 1,3942

70 1,4362 1,4285 1,4210 1,4134 1,4061 1,3983


71 1,4406 1,4328 1,4252 1,4176 1,4102 1,4023
72 1,4449 1,4371 1,4294 1,4218 1,4142 1,4063
73 1,4491 1,4413 1,4335 1,4258 1,4182 1,4103
74 1,4532 1,4454 1,4376 1,4298 1,4221 1,4132

75 1,4573 1,4494 1,4415 1,4337 1,4259 1,4180


76 1,4613 1,4533 1,4454 1,4375 1,4296 1,4217
77 1,4652 1,4572 1,4492 1,4413 1,4333 1,4253
78 1,4690 1,4610 1,4529 1,4450 1,4369 1,4288
79 1,4727 1,4647 1,4565 1,4486 1,4404 1,4323

80 1,4764 1,4683 1,4601 1,4521 1,4439 1,4357


81 1,4800 1,4718 1,4636 1,4555 1,4473 1,4391
82 1,4835 1,4753 1,4670 1,4589 1,4507 1,4424
83 1,4869 1,4787 1,4704 1,4622 1,4540 1,4456
84 1,4903 1,4820 1,4737 1,4655 1,4572 1,4487

85 1,4936 1,4852 1,4769 1,4686 1,4603 1,4518


86 1,4968 1,4883 1,4799 1,4716 1,4633 1,4548
87 1,4999 1,4913 1,4829 1,4745 1,4662 1,4577
88 1,5029 1,4942 1,4858 1,4773 1,4690 1,4605
89 1,5058 1,4970 1,4885 1,4800 1,4716 1,4631

90 1,5085 1,4997 1,4911 1,4826 1,4741 1,4656


91 1,5111 1,5023 1,4936 1,4850 1,4766 1,4681
92 1,5136 1,5048 1,4960 1,4873 1,4789 1,4704
93 1,5156 1,5068 1,4979 1,4892 1,4807 1,4722
94 1,5177 1,5088 1,4999 1,4912 1,4826 1,4741

95 1,5198 1,5109 1,5019 1,4932 1,4846 1,4761


96 1,5220 1,5130 1,5040 1,4952 1,4867 1,4781
97 1,5244 1,5152 1,5062 1,4974 1,4889 1,4802
98 1,5278 1,5187 1,5096 1,5008 1,4922 1,4835
99 1,5327 1,5235 1,5144 1,5056 1,4969 1,4881
100 1,5402 1,5310 1,5217 1,5129 1,5040 1,4952
40 . I. -

1-57 1-58
H2SiF6 H3AsO4

.17,5 jl5 j 15 jl5


JC, % d4 JC, % JC, % d4 JC , % d4 JC, % d4 Xt % d4 JC, % d4 JC, % d4
4
1 1,0080 8 1,0661 20 1,1748 30 1,2742 I 1,0057 10 1,0681 30 1,2331 60 1,6070
2 1,0161 12 1,1011 25 1,2235 34 1,3162 2 1,0124 16 1,1128 40 1,3370 70 ' 1,7811
4 1,0324 16 1,1373 6 1,0398 20 1,1447 50 1,4602

1-59
H3PO4

d^
t, 0C
2% 6% 14% 20% 26% 35% 50% 75% 100%

1,0113 1,0339 1,0811 1,1192 1,1567 1,221 1,341


10 1,0109 1,0330 1,0792 1,1167 1,1529 1,216 1,335 1,579 1,870
20 1,0092 1,0309 1,0764 1,1134 1,1484 1,211 1,329 1,572 1,862
30 1,0065 1,0279 1,0728 1,1094
40 1,0029 1,0241 1,0685 1,1048

1-60
H2SO4

d \J

0 C IQ- C 15 C 20 C 25 C 30 40 C 50 C 60 C 80 C 100 C

I 1,0074 1,0068 1,0060 1,0051 1,0038 1,0022 0,9986 0,9944 0,9895 0,9779 0,9645
2 1,0147 1,0138 1,0129 1,0118 1,0104 1,0087 1,0050 1,0006 0,9956 0,9839 0,9705
3 1,0219 1,0206 1,0197 1,0184 1,0169 1,0152 1,0113 1,0067, 1,0017 0,9900 0,9766
4 1,0291 1,0275 1,0264 1,0250 1,0234 1,0216 1,0176 1,0129 1,0078 0,9961 0,9827
5 1,0364 1,0344 1,0332 1,0317 1,0300 1,0281 1,0240 1,0192 1,0140 1,0022 0,9888
6 1,0437 1,0414 1,0400 1,0385 1,0367 1,0347 1,0305 1,0256 1,0203 1,0084 0,9950
7 1,0511 1,0485 1,0469 1,0453 1,0434 1,0414 1,0371 1,0321 1,0266 1,0146 1,0013
8 1,0585 1,0556 1,0539 1,0522 1,0502 1,0481 1,0437 1,0386 1,0330 1,0209 1,0076
9 1,0660 1,0628 1,0610 1,0591 1,0571 1,0549 1,0503 1,0451 1,0395 1,0273 1,0140
10 1,0735 1,0700 1,0681 1,0661 1,0640 1,0617 1,0570 1,0517 1,0460 1,0338 1,0204
11 1,0810 1,0773 1,0753 1,0731 1,0710 1,0686 1,0637 1,0584 1,0526 1,0403 1,0269
12 1,0886 1,0846 1,0825 1,0802 1,0780 1,0756 1,0705 1,0651 1,0593 1,0469 1,0335
13 1,0962 1,0920 1,0898 1,0874 1,0851 1,0826 1,0774 1,0719 1,0661 1,0536 1,0402
14 1,1039 1,0994 1,0971 1,0947 1,0922 1,0897 1,0844 1,0788 1,0729 1,0603 1,0459
15 1,1116 1,1069 1,1045 1,1020 1,0994 1,0968 1,0914 1,0857 1,0798 1,0671 1,0537
16 1,1194 1,1145 1,1120 1,1024 1,1067 1,1040 1,0985 1,0927 1,0868 1,0740 1,0605
17 1,1272 1,1221 1,1195 1,1168 1,1141 1,1113 1,1057 1,0998 1,0938 1,0809 1,0674
18 1,1351 1,1298 1,1271 1,1243 1,1215 1,1187 1,1129 1,1070 1,1009 1,0879 1,0744
19 1,1430 1,1375 1,1347 1,1318 1,1290 1,1261 1,1202 1,1142 1,1081 1,0950 1,0814
20 1,1510 1,1453 1,1424 1,1394 1,1365 1,1335 1,1275 1,1215 1,1153 1,1021 1,0885
21 1,1590 1,1531 1,1501 1,1471 1,1441 1,1410 1,1349 1,1288 1,1226 1,1093 1,0957
22 1,1670 1,1609 1,1579 1,1548 1,1517 1,1486 1,1424 1,1362 1,1299 1,1166 1,1029
23 1,1751 1,1688 1,1657 1,1626 1,1594 1,1563 1,1500 1,1437 1,1373 1,1239 1,1102
24 1,1832 1,1768 1,1736 1,1704 1,1672 . 1,1640 1,1576 1,1512 1,1448 1,1313 1,1176
25 1,1914 1,1848 1,1816 1,1783 1,1750 1,1718 1,1653 1,1588 1,1523 1,1388 1,1250
26 1,1996 1,1929 1,1896 1,1862 1,1829 1,1796 1,1730 1,1665 1,1599 1,1463 1,1325
27 1,2078 1,2010 1,1976 1,1942 1,1909 1,1875 1,1808 1,1742 1,1676 1,1539 1,1400
28 1,2160 1,2091 1,2057 1,2023 1,1989 1,1955 1,1887 1,1820 1,1753 1,1616 1,1476
29 1,2243 1,2173 1,2138 1,2104 1,2069 1,2035 1,1966 1,1898 1,1831 1,1693 1,1553
41

J 4
X, %
O0 C 15 20 25 30 40 50 60 80 100

30 1,2326 1,2255 1,2200 1,2185 1,2150 1,2115 1,2046 1,1977 1,1909 1,1771 1,1630
31 1,2409 1,2338 1,2302 1,2267 1,2232 1,2196 1,2126 1,2057 1,1988 1,1849 1,1708
32 1,2493 1,2421 1,2385 1,2349 1,2314 1,2278 1,2207 1,2187 1,2068 1,1928 1,1787
33 1,2577 1,2504 1,2468 1,2432 1,2396 1,2360 1,2283 1,2218 1,2148 1,2008 1,1866
34 1,2661 1,2588 1,2552 1,2515 1,2479 1,2443 1,2371 1,2300 1,2229 1,2088 1,1946

35 1,2746 1,2672 1,2636 1,2599 1,2563 1,2526 1,2454 1,2383 1,2311 1,2169 1,2027
36 1,2831 1,2757 1,2720 1,2684 1,2647 1,2610 1,2538 1,2466 1,2394 1,2251 1,2109
37 1,2917 1,2843 1,2805 1,2769 1,2732 1,2695 1,2622 1,2550 1,2477 1,2334 1,2192
38 1,3004 1,2929 1,2891 1,2855 1,2818 1,2780 1,2707 1,2635 1,2561 1,2418 1,2276
39 1,3091 1,3016 1,2978 1,2941 1,2904 1,2866 1,2793 1,2720 1,2646 1,2503 1,2361

40 1,3179 1,3103 1,3065 1,3028 1,2991 1,2953 1,2880 1,2806 1,2732 1,2589 1,2446
41 1,3268 1,3191 1,3153 1,3116 1,3079 1,3041 1,2967 1,2893 1,2819 1,2675 1,2532
42 1,3357 1,3280 1,3242 1,3205 1,3167 1,3129 1,3055 1,2981 1,2907 1,2762 1,2619
43 1,3447 1,3370 1,3332 1,3294 1,3256 1,3218 1,3144 1,3070 1,2996 1,2850 1,2707
44 1,3538 1,3461 1,3423 1,3384 1,3346 1,3308 1,3234 1,3160 1,3086 1,2939 1,2796

45 1,3630 1,3553 1,3515 1,3476 1,3437 1,3399 1,3325 1,3251 1,3177 1,3029 1,2886
46 1,3724 1,3646 1,3608 1,3569 1,3530 1,3492 1,3417 1,3343 1,3269 1,3120 1,2976
47 1,3819 1,3740 1,3702 1,3663 1,3624 1,3586 1,3510 1,3435 1,3362 1,3212 1,3067
48 1,3915 1,3835 1,3797 1,3758 1,3719 1,3680 1,3604 1,3528 1,3455 1,3305 1,3159
49 1,4012 1,3931 1,3893 1,3854 1,3814 1,3775 1,3699 1,3623 1,3549 1,3399 1,3253
50 1,4110 1,4029 1,3990 1,3951 1,3911 1,3872 1,3795 1,3719 1,3644 1,3494 1,3348
51 1,4209 1,4128 1,4088 1,4049 1,4009 1,3970 1,3893 1,3816 1,3740 1,3590 1,3444
52 1,4310 1,4228 1,4188 1,4148 1,4109 1,4069 1,3991 1,3914 1,3837 1,3687 1,3540
53 1,4412 1,4329 1,4289 1,4248 1,4209 1,4169 1,4091 1,4013 1,3936 1,3785 1,3637
54 1,4515 1,4431 1,4391 1,4350 1,4310 1,4270 1,4191 1,4113 1,4036 1,3884 1,3735
55 1,4619 1,4535 1,4494 1,4453 1,4412 1,4372 1,4293 1,4214 1,4137 1,3984 1,3834
56 1,4724 1,4640 1,4598 1,4557 1,4516 1,4476 1,4396 1,4317 1,4239 1,4085 1,3934
57 1.4830 1,4746 1,4703 1,4662 1,4621 1,4581 1,4500 1,4400 1,4342 1,4187 1,4035
58 1,4937 1,4852 1,4809 1,4768 1,4726 1,4685 1,4604 1,4524 1,4446 1,4290 1,4137
59 1,5045 1,4959 1,4916 1,4875 1,4832 1,4791 1,4709 1,4629 1,4551 1,4393 1,4240
60 1,5154 1,5067 1,5024 1,4983 1,4940 1,4898 1,4816 1,4735 1,4656 1,4497 1,4344
61 1,5264 1,5177 1,5133 1,5091 1,5048 1,5006 1,4923 1,4842 1,4762 1,4602 1,4449
62 1,5375 1,5287 1,5243 1,5200 1,5157 1,5115 1,5031 1,4950 1,4869 1,4708 1,4554
63 1,5487 1,5398 1,5354 1,5310 1,5267 1,5225 1,5140 1,5058 1,4977 1,4815 1,4660
64 1,5600 1,5510 1,5465 1,5421 1,5378 1,5335 1,5250 1,5167 1,5086 1,4923 1,4766
65 1,5714 1,5623 1,5578 1,5533 1,5490 1,5446 1,5361 1,5277 1,5195 1,5031 1,4873
66 1,5828 1,5736 1,5691 1,5646 1,5602 1,5558 1,5472 1,5388 1,5305 1,5140 1,4981
67 1,5943 1,5850 1,5805 1,5760 1,5715 1,5671 1,5584 1,5499 1,5416 1,5249 1,5089
68 1,6059 1,5965 1,5920 1,5874 1,5829 1,5785 1,5697 1,5611 1,5528 1,5359 1,5198
69 1,6176 1,6081 1,6035 1,5989 1,5944 1,5899 1,5811 1,5724 1,5640 1,5470 1,5307
70 1,6293 1,6198 1,6151 1,6105 1,6059 1,6014 1,5925 1,5838 1,5753 1,5582 1,5417
71 1,6411 1,6315 1,6268 1,6221 1,6175 1,6130 1,6040 1,5952 1,5867 1,5694 1,5527
72 1,6529 1,6433 1,6385 1,6338 1,6293 1,6246 1,6155 1,6067 1,5981 1,5806 1,5637
73 1,6648 1,6551 1,6503 1,6456 1,6409 1,6363 1,6271 1,6182 1,6095 1,5919 1,5747
74 1,6768 1,6670 1,6622 1,6574 1,6526 1,6480 1,6387 1,6297 1,6209 1,6031 1,5857
75 1,6888 1,6789 1,6740 1,6692 1,6644 1,6597 1,6503 1,6412 1,6322 1,6142 1,5966
76 1,7008 1,6908 1,6858 1,6810 1,6761 1,6713 1,6619 1,6526 1,6435 1,6552 1,6074
77 1,7128 1,7026 1,6976 1,6927 1,6878 1,6829 1,6734 1,6640 1,6547 1,6361 1,6181
78 1,7247 1,7144 1,7093 1,7043 1,6994 1,6944 1,6847 1,6751 1,6657 1,6469 1,6286
79 1,7365 1,7261 1,7209 1,7158 1,7108 1,7058 1,6959 1,6862 1,6766 1,6575 1,6390
42 . 1. -


X ,- %
0 10 15 20 25 30 40 50 60 80 100

80 1,7482 1,7376 1,7323 1,7272 1,7221 1,7172 1,7069 1,6971 1,6873 1,6680 1,6493
81 1,7597 1,7489 1,7435 1,7383 1,7331 1,7279 1,7177 1,7077 1,6978 1,6782 1,6594
82 1,7709 1,7599 1,7544 1,7491 1,7437 1,7385 1,7281 1,7180 1,7080 1,6882 1,6692
83 1,7815 1,7704 1,7649 1,7594 1,7540 1,7487 1,7382 1,7279 1,7179 1,6979 1,6787
84 1,7916 1,7804 1,7748 1,7693 1,7639 1,7585 1,7479 1,7375 1,7274 1,7072 1,6878

85 1,8009 1,7897 1,7841 1,7786 1,7732 1,7678 1,7571 1,7466 1,7364 1,7161 1,6966
86 1;8095 1,7983 1,7927 1,7872 1,7818 1,7763 1,7657 1,7552 1,7449 1,7245 1,7050
87 1,8173 1,8061 1,8006 1,7951 1,7897 1,7842 1,7736 1;7632 1,7529 1,7324 1,7129
88 1,8243 1,8132 1,8077 1,8022 1,7968 1,7914 1,7809 1,7705 1,7602 1,7397 1,7202
89 1,8306 1,8195 1,8141 1,8087 1,8033 1,7979 1,7874 1,7770 1,7669 1,7464 1,7269

90 1,8361 1,8252 1,8198 1,8144 1,8091 1,8038 1,7933 1,7829 1,7729 1,7525 1,7331
91 1,8410 1,8302 1,8248 1,8195 1,8142 1,8090 1,7986 1,7883 1,7783 1,7581 1,7388
92 1,8453 1,8346 1,8293 1,8240 1,8188 1,8136 1,8033 1,7932 1,7832 1,7633 1,7439
93 1,8490 1,8384 1,8331 1,8279 1,8227 1,8176 1,8074 1,7974 1,7876 1,7681 1,7485
94 1,8520 1,8415 1,8363 1,8312 1,8260 1,8210 1,8109 1,8011 1,7914

95 1,8544 1,8439 1,8388 1,8337 1,8286 1,8236 1,8137 1,8040 1,7944


96 1,8560 1,8457 1,8406 1,8355 1,8305 1,8255 1,8157 1,8060 1,7965
97 1,8569 1,8466 1,8414 1,8364 1,8314 1,8264 1,8166 1,8071 1,7977
98 1,8567 1,8463 1,8411 1,8361 1,8310 1,8261 1,8163 1,8068 1,7976
99 1,8551 1,8445 1,8393 1,8342 1,8292 1,8242 1,8145 1,8050 1,7958
100 1,8517 1,8409 1,8357 1,8305 1,8255 1,8205 1,8107 1,8013 1,7922

1-60
1-61

( ) HClO4

.5 ,9 6 .1 3 ,0 0 .1 8 ,0 0 5 .25 .5 0 15
, % 4 , % 4 4 , % 4 4 dA Xt % d4 dT dT

0,005 1,000 0140 0,05 0,999 810 0,999 028 1 1,0050 1,0020 0,9933 26 1,1738 1,1697 1,1490
0,01 1,000 0576 0,1 1,000 185 0,999 400 1,0070 0,9986 28 1,1900 1,1851 1,1645
2 1,0109
0,02 1,000 1434 0,2 1,000 912 1,000 119
0,03 1,000 2276 0,3 1,001 623 1,000 820 4 1,0228 1,0169 0,9906 30 1,2067 1,2013 1,1800
0,04 1,000 3104 0,4 1,002 326 1,001 512 1,0270 1,0205 32 1,2239 1,2183 1,1960
6 1,0348
0,05 1,000 3920 0,5 1,003 023 1,002 197
0,06 1,000 4726 0,6 1,003 716 1,002 877 8 1,0471 1,0372 1,0320, 34 1,2418 1,2359 1,2130
0,07 1,000 5523 0,8 % 1,005 090 1,004 227 1,0475 1,0440 36 1,2603 1,2542 1,2310
10 1,0597
0,08 1,000 6313 1,0 1,006 452 1,005 570
0,09 1,000 7098 1,007 807 1,006 909 12 1,0726 1,0560 38 1,2794 1,2732 1,2490
U
0,10 1,000 7880 1,4 1,009 159 1,008 247 14 1,0680 40 1,2991 1,2927 1,2680
.
0,15 1,001 1732 1,6 1,010 510 1,009 583
0,20 1,001 5514 1,8 1,011 860 1,010 918 16 1,0995 1,0810 45 1,3521 1,3450 1,3180
0,25 1,001 9254 2,0 1,013 209 1,012 252 18 1,1135 1,0940 50 1,4103 1,4018 1,3730
. . .
0,30 1,002 2961 2,2 1,014 557 1,013 586
1,002 6639 2,4 1,015 904 1,014 919 20 1,1279 1,1070 55 1,4733 1,4636 1,4320
0,35

0,40 1,003 0292 22 1,1428 1,1205 60 1,5389 1,5298 1,4950


0,45 1,003 3923
1,003 7534 24 1,1581 1,1345 65 1,6059 1,5986 1,5620
0,50
70 1,6736 1,6680 1,6290
I
43

1-62 1-67
MgSO4 Na3AsO4

Ii * 17 W17
Xt % I7 AT* % dA Xt % dA
X, %
0 20 30 40 50 60 80
1 1 ,0 0 9 7 4 1,0431 10 1 ,1 1 3 0
2 1 ,0 2 0 7 II 8 1 ,0 8 9 2 II 12 1 ,1 3 7 3
2 1 ,0210 1 ,0 1 8 6 1 ,0 1 5 8 1 ,0 1 2 3 1,0081 1 ,0 0 3 2 0 ,9 9 1 6
4 1,0423 1 ,0 3 9 2 1 ,0 3 6 2 1 ,0 3 2 6 1 ,0 2 8 3 1 ,0 2 3 4 1 ,0 1 1 8 1 68
8 1,0858 1 ,0 8 1 6 1 ,0 7 8 2 1 ,0 7 4 3 1 ,0 7 0 0 1 ,0 6 5 0 1 ,0 5 3 4
12 1,1309 1 ,1 2 5 6 1 ,1 2 2 0 1 ,1 1 7 9 1 ,1 1 3 5 1 ,1 0 8 3 1 ,0 9 6 8 CH3COONa
16 1,1777 1 ,1 7 1 7 1 ,1 6 7 9 1 ,1 6 3 7 1 ,1 5 9 2
20 1,2264 1 ,2 1 9 8 1 ,2 1 5 9 1 ,2 1 1 7 1 ,2 0 7 2 W23
, % d 20 Xt % , % d f
26 1,3032 1,2961 1 ,2 9 2 2 1 ,2 8 7 9 1 ,2 8 3 6 4 4

1-63 1 1 ,0 0 3 3 8 1 ,0 3 9 2 20 1 ,1021
MgCI2 2 1 ,0 0 8 4 12 1 ,0 5 9 8 26 1,1351
4 1 ,0 1 8 6 18 1 ,0 8 0 7 28 1 ,1 4 6 2
d*
1-69
, %
0 20 40 60 80 IOO0 C Na2Cr2O7

2
4
1 ,0168
1 ,0 3 3 8
1 ,0 1 4 6
1 ,0311
1 ,0 0 8 4
1 ,0 2 4 8
0 ,9 9 9 5
1 ,0 1 5 9
0 ,9 8 8 3
1 ,0 0 5 0
0 ,9 7 5 3
0 ,9 9 2 3
X, % I X, % dA , % A 5 Xt %
W15
dA

8 1 ,0 6 8 3 1 ,0 6 4 6 1 ,0 5 8 0 1 ,0 4 9 3 1 ,0 3 8 8 1 ,0 2 6 9
12 1 ,1 0 3 5 1 ,0 9 8 9 1,0 9 2 1 1 ,0 8 3 6 1 ,0 7 3 5 1 ,0 6 2 2 1 1 ,0 0 6 12 1 ,0 8 4 28 1,1 9 3 40 1 ,2 7 9
16 1 ,1 3 9 5 1 ,1 3 4 2 1 ,1 2 7 2 1 ,1 1 8 8 1 ,1 0 9 2 1 ,0 9 8 4 2 1 ,013 16 1 ,112 30 1,2 0 7 45 1 ,3 1 2
20 1 ,1 7 6 4 1 ,1 7 0 6 1 ,1 6 3 5 1 ,1 5 5 2 1 ,1 4 6 0 1 ,1 3 5 9 4 1 ,027 20 1 ,1 4 0 35 1,2 4 4 50 1 ,3 4 2
25 1 ,2 2 4 6 1 ,2 1 8 4 1,2111 1,2 0 3 1 1 ,1 9 4 2 1 ,1 8 4 7 8 1,0 5 6 I 24 1 ,1 6 6
30 ; 1,2754 1 ,2 6 8 8 1 ,2 6 1 4 1 ,2 5 3 5 1,2451 1 ,2 3 6 0
1-70
1-64
NaBr
(II) Cu(NO3) 2
17 W17 ^ 7
X1 % X, % , % dA
, % df Xt % Xt % W20
, % W23 dA dA
4 4 dA

1 1 ,0 0 6 0 8 1,0631 20 1 ,1 7 4 5
1 1,007 4 1,0 3 2 12 1,1 0 7 20 1 ,1 8 9 1 ,0 1 3 9 10 1 ,0 8 0 3 30 1 ,28
2
2 1,015 8 1 ,0 6 9 16 1 ,1 4 7 25 1 ,2 4 8 40 1 ,4 1 3 8
4 1 ,0 2 9 8 12 1,0981

1-65 1-71
(II) CuSO4
NaOH
d * d* {
4 t
, % Xt %
, %
O0 C 20 jI 40 O0 C I 20 I 40 O0 C 15 20 40 60 80 C IOO0 C

1 1,0104 1 ,0 0 8 6 1 ,0 0 2 4 12 1 ,1 3 7 9 1 ,1 3 0 8 1 ,1 2 2 2
1 1 ,0 1 2 4 1 ,0 1 0 6 5 1 ,0 0 9 5 1 ,0 0 3 3 0 ,9 9 4 1 0 ,9 8 2 4 0 ,9 6 9 3
4 1 ,0429 1,0401 1 ,0 3 3 2 16 . 1 ,1 8 0
2 1 ,0 2 4 4 1 ,0 2 1 9 8 1 ,0 2 0 7 1 ,0 1 3 9 1 ,0 0 4 5 0 ,9 9 2 9 0 ,9 7 9 7
8 1,0887 1 ,0 8 4 1 ,0 7 6 4 j 18 . . . 1 ,2 0 6
' 4 1 ,0 4 8 2 1,04441 1 ,0 4 2 8 1 ,0 3 5 2 1 ,0 2 5 4 1 ,0 1 3 9 1 ,0 0 0 9
8 1 ,0 9 4 3 1 ,0 8 8 8 7 1 ,0 8 6 9 1 ,0 7 8 0 1 ,0 6 7 6 1 ,0 5 6 0 1 ,0 4 3 2
1-66
12 1 ,1 3 9 9 1 ,1 3 3 2 7 1 ,1 3 0 9 1 ,1 2 1 0 1,1101 1 ,0 9 8 3 1 ,0 8 5 5
(I) Cu2Cl2 1 ,1 4 0 8 1 ,1 2 7 7
16 1 ,1 8 4 9 1 ,1 7 7 6 1 1,1751 1 ,1 6 4 5 1 ,1531
20 1 ,2 2 9 6 1 ,2 2 1 8 3 1,2191 1 ,2 0 7 9 1 ,1 9 6 0 1 ,1 8 3 3 1 ,1 7 0 0
dj d* 24 1,2741 1 ,2 6 5 8 2 1 ,2 6 2 9 1 ,2 5 1 2 1 ,2 3 8 8 1 ,2 2 5 9 1 ,2 1 2 4
, % X, % 28 1 ,3 1 8 5 1 .3 0 9 4 1 ,3 0 6 4 1 ,2 9 4 2 1 ,2 8 1 4 1 ,2 6 8 2 1 ,2 5 4 6
32 1 ,3 6 1 4 1 ,3 5 2 0 1 ,3 4 9 0 1 ,3 3 6 2 1 ,3 3 3 2 1 ,3 0 9 7 1 ,2 9 6 0
O0 C 20 40 O0 C 20 40
36 1 ,4 0 3 0 1 ,3 9 3 3 1 ,3 9 0 0 1 ,3 7 6 8 1 ,3 6 3 4 1 ,3 4 9 8 1 ,3 3 6 0
40 1 ,4 4 3 5 1 ,4 3 3 4 1 ,4 3 0 0 1 ,4 1 6 4 1 ,4 0 2 7 1 ,3 8 8 9 1 ,3 7 5 0
1 1,0095 1 ,0 0 7 2 1 ,0 0 2 12 1 ,1 2 0 8 1 ,1 1 6 5 1 ,1 0 7 44 1 ,4 8 2 5 1 ,4 7 2 0 1 ,4 6 8 5 1 ,4 5 4 5 1 ,4 4 0 5 1 ,4 2 6 6 1 ,4 1 2 7
4 1,0387 1 ,0 3 6 1 ,0 3 0 5 16 1 ,1 6 5 3 1 ,1 5 9 5 1,151 48 1 ,5 2 1 0 1 ,5 1 0 2 1 ,5 0 6 5 1 ,4 9 2 2 1,4781 1,4641 1 ,4 5 0 3
8 1,0788 1 ,0 7 5 4 1 ,0 6 8 2 20 1,2121 1 ,2 0 5 2 1 ,1 9 5 3 50 1 ,5 4 0 0 1 ,5 2 9 0 1 ,5 2 5 3 1 ,5 1 0 9 1,4 9 6 7 1,4 8 2 7 1 ,4 6 9 0
44 . /. -

1-72 1-73
Na2CO3 NaNO3

< d 4
X
X, %
% 0 20 I 40 I 60 80 I 100
O0 C 10 20 30 40 60 80 IOO0 C
\ 1,0071 1.0049 0,9986 0,9894 0,9779 0,9644
2 1,0144 1.0117 1,0050 0,9956 0,5840 0,9704
0,9683 4 . 1,0290 1,0254 1,0180 1,0082- 0,9964 0,9826
I 1,0109 1,0103 1,0086 1,0058 1,0022 0,9929 0,9814 -8 1,0587 1,0532 . 1,0447 1,0340 1,0218 1,0078
2 1,0219 1,0210 1,0190 1,0159 1,0122 1,0027 0,9910 0,9785 12 1,0891 1,0819 1,0724 1,0609 1,0481 1,0340
16 1,1203 1,1118 1,1013 1,0892 - 1,0757 1,0614
4 1,0439 1,0423 1,0398 1,0363 1,0323 1,0223 1,0105 0,9980 20 1,1526 1,1429 1,1314 1,1187 1,1048 1,0901
1,0380 24 1,1860 1,1752 1,1629 1,1496 1,1351 1,1200
8 1,0878 1,0850 1,0816 1,0775 1,0732 1,0625 1,0503 28 1,2204 1,2085 1,1955 1,1816 1,1667 1,1513
12 1,1319 1,1284 1,1244 1,1200 1,1150 1,1039 1,0914 1,0787 30 1,2380 1,2256 1,2122 1,1980 1,1830 1,1674
35 1,2834 1,2701 1,2560 1,2413 1,2258 1,2100
14 1,1543 1,1506 1,1463 1,1417 1,1365 1,1251 1,1125 1,0996 40 1,3316 1,3175 1,3027 1,2875 1,2715 1,2555
45 1,3683 1,3528 1,3371 1,3206 1,3344
16 1,1636
18 1,1859 -74
20 1,2086 NaNO2
24 1,2552
', % , % , % 16 X, % W 15
28 1,3031 4 d A

30 . . . 1,3274
1
2
1,0058
1,0125
4
8
1,0260
1,0532 I
12
16
1,0816
I 1,1103 j
20 1,1398

1-75

d

i% 2% 4% 8% 10% !4 % 20 % 24% 30% 30 % 40 % 45% 50%

N a20 / 3 ,9 S i 0 2 1,006 1.014 1.030 1,063 1,080' 1,116 1,172 1,211 1,275
N a 20 /3 ,3 6 S i0 2 1,006 1.014 1.030 1,065 1,083 1,120 1,179 1,222 1,290 1,365
N a2O /2,40S iO 2 1,007 1,016 1,034 1,071 1,090 1,130
N a 20 /2 ,4 4 S i0 2 1,309 1,387 1,445
N a 2O /2,06S iO 2 1.007 1,016 1.035 1,073 1,093 1,134 1,200 1,247 1,321 1,397 1,450 1,520 1,594
N a 20 / l , 6 9 S i 0 2 1.007 1,017 1.036 1,077 1,098 1,141 1,210 1,259 1,337 1,424

I 76 1-78
Na2SO4
.Na2SO3
d1*
19
X, % X, % X, % dA , %
O0 20 30 40 60 80 IOO0 C

1 1,0078 8 1,0751 1,1549


1 1.094 1,0073 1,0046 1,0010 0,9919 0,9808 0,9671 16

I
2 1,0007 0,9892 0,9758 2 1,0172 12 1,1146 1,1755
1,0189 1,0164 1,0135 1,0098 18
4 1,0381 1,0348. 1,0315 1,0276 1,0184 1,0068 0,9934 4 1,0363
8 1,0773 1,0724 1,0682 1,0639 1,0544 1,0426 1,0292
12 1,1174 1,1109 1,1062 1,1015 1,0915 1,0795 1,0661
16 1,1585 1,1506 1,1456 1,1406 1,1299 1,1176 1,1042
20 1,2008 1,1915 1,1865 1,1813 1,1696 1,1569
1-79
24 1,2443 1,2326 I 1,2292 1,2234
Na2S2O3
1-77

Na2S .20 j2 0 .2 0
, % 4 X, % 4 , % , % 4

W18 18 18
X, % dA X, % 4 , % 4
1 1,0065 12 1,1003 28 1,2532 35 1,3273
2 1,0148 20 1,1740 30 1,2739 40 1,3827
1 1,0098 8 1,0907 16 1,1885
2 1,0211 12 1,1388 18 1,2140 4 1,0315 24 1,2128
4 1,0440
45

1-80 1-85
Ni(NO3)2
Na2S2O3 520
.20 .20 .20
, % X, % d A , % d A
W19 .19 4
X, % d 419 , % d A X f % < 9 X, % 4

1 1,0035 8 1,0688 20 1,191


1 1,0052 8 1,0423 20 1,1087 30 1,1676 2 1,0150 12 1,0070 30 1,311
2 1,0105 12 1,0639 24 1,1322 40 1,2297 4 1,0325 I 16 1,1480 35 1,377
4 1,0211 16 1,0863 28 1,1558 50 1,2954
I-81

1-81 NiSO4
HCOONa
^*8
t
X / '^ 8 , % 4 , % '
,25 w25
X, % d 425 X, % X, % d4 x, % d 42b

1 1,0091 8 1,0852 16 1,1825


2 1,0198 12 1,1325 18 1,2090
I 1,003 8 1,048 20 1,127 30 1,199 4 1,0415
2 1,009 12 1,074 24 1,155 35 1,236
4 1 ,0 2 2 16 1 ,1 0 0 28 1,184 40 1,274 1-87
NiCl2
1-82
NaClO3 , % X, % % 13 , % 13
d A 4* , d A dA

.18 18 I
X t % d A , % j1 >
d A Xt % , % d A
1 1,0082 4 1,0375 12 1,1217 20 1,2163
2 1,0179 8 1,0785 16 1,1674 30 1,353
1 1,0053 10 1,0681 20 1,1449 28 1,2128
2 1,0121 12 1,0827 22 1,1614 30 1,2307 1-88
4 1,0258 14 1,0977 24 1,1782 32 1,2491 (II) SnCI2
6 1,0397 16 1,1131 26 1,1954 34 1,2680
8 1,0538 18 1,1288
, % 15
V Xt %
^8 % W15 , %
dA dA d A
ll 4
1-83
NaCI 1 1,0068 16 1,1353 30 1,2837 50 1,5729
f-
2 1,0146 20 1,1743 35 1,3461 55 1,6656
d\ ; 4 1,0306 24 1,2159 40 1,4145 60 1,7695
X, % 8 1,0638 28 1,2603 45 1,4897 65 1,8865
O0 C IO0 C 25 40 60 80 100 12 1,09861
1-89
I 1,00747 1,00707 1,00409 0,99908 0,9900 0,9785 0,9651 (IV) SnCl4
2 1,01509 1,01442 1 ,0 1 1 1 2 1,00593 0,9967 0,9852 0,9719
4 1,03038 1,02920 1,02530 1,01977 1,0103 0,9988 0,9855
15 % .15
8 1,06121 1,05907 1,05412 1,04798 1,0381 1,0261 1,0134 X, % dA X, % dA Xt % * X, d A
12 1,09244 1,08946 1,08365 1,07699 1,0667 1,0549 1,0420
16 1,12419 1,12056 1,11401 1,10688 1,0962 1,0842 1,0713
20 1,15663 1,15254 1,14533 1,13774 1,1268 1,1146 1,1017 1 1,007 16 1,135 35 1,337 55 1,644
24 1,18999 1,18557 1,17776 1,16971 1,1584 1,1463 1,1331 2 1,015 20 1,173 40 1,403 60 1,742
26 1,20709 1,20254 1,19443 1,18614 1,1747 1,1626 1,1492 4 1,031 24 1 ,212 45 1,475 65 1,851
8 1,064 28 1,255 50 1,555 70 1,971
12 1,099 30 1,278
1-84 I 90
Na2CrO4 CrO3

X, % W18 Yy / I , % d ]8
.13 18
X /Q , % d A X, % X. %
A5 Xf % d A

1 1,0074 8 1,0718 20 1,1942 1 1,005 10 1,076 26 1 ,2 2 0 50 1,505


2 1,0164 12 1 ,1 1 1 0 24 1,2383 2 1,014 16 1,127 30 1,260 60 1,663
4 1,0344 I 16 1,1518 26 1,2611 6 1,045 20 1,163 I 40 1,371
46 . L -

1-91 . 1-93
(IIl) CrCl3 Zn(NO3) 2

d*s 18 W18
Xt %
4
X. % dI8 Xt % , % dI8
X, %

2 1,0154 10 1,0859 18 1,1652 35 1,3678

4 1,0322 12 1,1048 20 1,1865 40 1,4378
6 1,0496 14 1,1244 25 1,2427 45 1,5134
I 1,0076 1,0071 1,0075 8 1,0675 I 16 1,1445 30 1,30291 50 1,5944
2 1,0166 1,0157 1,0165
4 1,0349 1,0332 1,0347 1-94
8 1,0724 1,0691 1,0722
12 1,1114 1,1065 1,1111
ZnSO4
14 1,1316
Xt % dJ0 J Xt % ' d 20
uA Xt % d 20
Xt %
20
4

1-92 2 1,019 6 1,0620 10 1,1071 14 1,1553


ZnBr2 4 1,0403 I 8 1,0842 12 1,13081 16 1,1806

d* 1-95

X, % ZnCl2
O0 C 20 40 60 80 100

Xt %
2 1,0188 1,0167 1,0102 1,0008 0,9890 0,9751 O0 C 20 40 60 80 100
4 1,0381 1,0354 1,0285 1,0187 1,0065 0,9921
8 1,0777 1,0738 1,0660 1,0554 1,0422 1,0270
12 1,1186 1,1135 1,1046 1,0932 1,0789 1,0629 2 1,0192 1,0167 1,0099 1,0003 0,9882 0,9739
4 1,0384 1,0350 1,0274 1,0172 1,0044 0,9894
16 1,1609 1,1544 1,1445 1,1320 1,1169 1,1000 8 1,0769 1 0715 1,0624 1,0508 1.0369 1,0211
20 1,2043 1,1965 1,1855 1,1720 1,1560 1,1382 12 1,1159 1,1085 1 0980 1,0853 1,0704 1,0541
30 1,3288 1,3170 1,3030 1,2868 1,2688 1,2489 16 1,1558 1,1468 1,1350 1,1212 1,1055 1,0888
1,477 20 1,1970 1,1866 1-1736 1,1590 1,1428 1,1253
40 1,462 1,445 1,427 1,406 1,385 30 1,3062 1,2928 1,2778 1,2614 1,2438 1,2252
50 1,661 1,643 1,623 1,602 1,579 1,555 40 1,4329 1,4173 1,4003 1,3824 1,3637 1,3441
60 1,891 1,869 1,845 1,822 1,797 1,771 50 1,5660 1,5681 1,5495 1,5300 1,5097 1,4892
60 1,749
65 2,026 2,002 1,976 1,951 1,924 1,898 70 . . 1,962


:
; ^ t ( 4 ).

1-96
22

^4 d 4
, % X, %
15 15,5 20 25 30 15 15,5 20 25 30

100 1,26415 1,26381 1,26108 1,15802 1,25495 90 1,23810 1,23775 1,23510 1,23200 1,22890
99 1,26160 1,26125 1,25850 1,25545 1,25235 89 1,23545 1,23510 1,23245 1,22935 1,22625
98 1,25900 1,25865 1,25590 1,25290 1,24975 88 1,23280 1,23245 1,22975 1*22665 1,22360
97 1,25645 1,25610 1,25335 1,25030 1,24710 87 1,23015 1,22980 1,22710 1,22400 1,22095
96 1,25385 1,25350 1,25080 1,24770 1,24450 86 1,22750 1,22710 1,22445 1,22135 1,21830
95 1,25130 1,25095 1,24825 1,24515 1,24190 85 1,22485 1,22445 1,22180 1,21870 1,21565
94 1,24865 1,24830 1,24560 1,24250 1,23930 84 1,22220 1,22180 1,21915 1,21605 1,21300
93 1,24600 1,24565 1,24300 1,23985 1,23670 83 1,21955 1,21915 1,21650 1,21340 1,21035
92 1,24340 1,24305 1,24035 1,23725 1,23410 82 1,21690 1,21650 1,21380 1,21075 1,20770
91 1,24075 1,24040 1,23770 1,23460 1,23150 81 1,21425 1,21385 1.21115 1,20810 1,20505
47

d* ctA
X, % X, %
15 15,5 20 25 30 15 15,5 20 25 30

80 1,21160 1,21120 1,20850 1,20545 1,20240 40 1,10145 1,10130 1,09930 1,09475 1,09475
79 1,20885 1,20845 1,20575 1,20275 1,19970 39 1,09875 1,09860 1,09665 1,09445 1,09215
78 1,20610 1,20570 1,20305 1,20005 1,19705 38 1,09605 1,09590 1,09400 1,09180 1,08955
77 1,20335 1,20300 1,20030 1,19735 1,19435 37 1,09340 1,09320 1,09135 1,08915 1,08690
76 1,20060 1,20025 1,19760 1,19465 1,19170 36 1,09070 1,09050 1,08865 1,08655 1,08430
75 1,19785 1,19750 1,19485 1,19195 1,18900 35 1,08800 1,08780 1,08600 1,08390 1,08165
74 1,19510 1,19480 1,19215 1,18925 1,18635 34 1,08530 1,08515 1,08335 1,08125 1,07905
73 1,19235 1,19205 1,18940 1,18650 1,18365 33 1,08265 1,08245 1,08070 1,07860 1,07645
72 1,18965 1,18930 1,18670 1,18380 1,18100 32 1,07995 1,07975 1,07800 1,07600 1,07380
71 1,18690 1,18655 1,18395 1,18110 1,17830 31 1,07725 1,07705 1,07535 1,07335 0,07120
70 1,18415 1,18385 1,18125 1,17840 1,17565 30 1,07455 1,07435 1,07270 1,07070 1,06855
69 1,18135 1,18105 1,17850 1,17565 1,17290 29 1,07195 1,07175 1,07010 1,06815 1,06605
68 1,17860 1,17830 1,17575 1,17295 1,17020 28 1,06935 1,06915 1,06755 1,06560 1,06355
67 1,17585 1,17830 1,17575 1,17295 1,17020 27 1,06670 1,06655 1,06495 1,06305 1,06105
66 1,17305 1,17275 1,17025 1,16745 1,16470 26 1,06410 1,06390 1,06240 1,06055 1,05855
65 1,17030 1,17000 1,16750 1,16475 1,16195 25 1,06150 1,06130 1,05980 1,05800 1,05605
64 1,16755 1,16725 1,16475 1,16200 1,15925 24 1,05885 1,05870 1,05720 1,05545 1,05360
63 1,16480 1,16445 1,16205 1,15925 1,15650 23 1,05625 1,05350 1,05205 1,05035 1,04850
62 1,16200 1,16170 1,15930 1,15655 1,15375 22 1,05365 1,05350 1,05205 1,05035 1,04850
61 1,15925 1,15895 1,15655 1,15380 1,15100 21 1,05100 1,05090 1,04950 1,04780 1,04600
60 1,15650 1,15615 1,15380 1,15105 1,14830 20 1,04840 1,04825 1,04690 1,04525 1,04350
59 1,15370 1,15340 1,15105 1,14835 1,14555 19 1,04590 1,04575 1,04440 1,04280 1,04105
58 1,15095 1,15065 1,14830 1,14560 1,14285 18 1,04335 1,04325 1,04395 1,04035 1,03960
57 1,14815 1,14785 1,14555 1,14285 1,14010 17 1,04085 1,04075 1,03945 1,03790 1,03615
56 1,14535 1,14510 1,14280 1,14015 1,13740 16 1,03835 1,03825 1,03695 1,03545 1,03370
55 1,14260 1,14230 1,14005 1,13740 1,13470 15 1,03580 1,03570 1,03450 1,03300 1,03130
54 1,13980 1,13955 1,13730 1,13465 1,13195 14 1,03330 1,03320 1,03200 1,03055 1,02885
53 1,13705 1,13680 1,13455 1,13195 1,12925 13 1,03080 1,03070 1,02955 1,02805 1,02395
52 1,13425 1,13400 1,13180 1,12920 1,12650 12 1,02830 1,02820 1,02705 1,02560 1,02395
51 1,13150 1,13125 1,12905 1,12650 1,12380 11 1,02575 1,02565 1,02455 1,02315 1,02150
50 1,12870 1,12845 1,12630 1,12375 1,12110 10 1,02325 1,02315 1,02210 1,02070 1,01905
49 1,12600 1,12575 1,12360 1,12110 1,11845 9 1,02085 1,02075 1,01970 1,01835 1,01670
48 1,12325 1,12305 1,12090 1,11840 1,11580 8 1,01840 1,01835 1,01730 1,01600 1,01440
47 1,12055 1,12030 1,11820 1,11575 1,11320 7 1,01600 1,01590 1,01495' 1,01360 1,01295
46 1,11780 1,11760 1,11550 1,11310 1,11055 6 1,01360 1,01350 1,01255 1,01125 1,00970
45 1,11510 1,11490 1,11280 1,11040 1,10795 5 1,01120 1,01110 1,01015 1,00890 1,00735
44 1,11235 1,11215 1,11010 1,10775 1,10530 4 1,00875 1,00870 1,00780 1,00655 1,00505
43 1,10960 1,10945 1,10740 1,10510 1,10265 3 1,00635 1,00630 1,00540 1,00415 1,00270
42 1,10690 1,10670 1,10470 1,10240 1,10005 2 1,00395 1,00385 1,00300 1,00180 1,00035
41 1,10415 1,10400 1,10200 1,09975 1,09740 1 1,00155 1,00145 1,00060 0,99945 0,99800
0 0,99913 0,99905 0,99823 0,99708 0,99568

I-Q7
HCOOH

d A d*
X, % X, %
O0 C 15 20 30 0 15 20 30

0 0,9999 0,9991 0,9982 0,9957 10 1,0295 1,0256 1,0246 1,0197


1 1,0028 1,0019 1,0019 0,9980 11 1,0324 1,0281 1,0271 1,0221
2 1,0059 1,0045 1,0044 1,0004 12 1,0351 1,0306 1,0296 1,0244
3 1,0090 1,0072 1,0070 1,0028 13 1,0379 1,0330 1,0321 1,0267
4 1,0120 1,0100 1.0093 1,0053 14 1,0407 1,0355 1,0345 1,0290
5 1,0150 1,0124 1,0115 1,0075 15 1,0435 1,0380 1,0370 1,0313
6 1,0179 1,0151 1,0141 1,0101 16 1,0463 1,0405 1,0393 1,0336
7 1,0207 1,0171 1,0170' 1,0125 17 1,0491 1,0430 1,0417 1,0358
8 1,0237 1,0204 1,0196 1,0149 18 1,0518 1,0455 1,0441 1 0381
9 1,0266 1,0230 1,0221 1.0173 19 1,0545 1,0480 1,0464 1,0404
48 . I. -

d 4 d 4
, %
O0 C IS0 C 20 30 O0 C 15 20 30

20 1 0571 1,0505 1,0488 1,0427 60 1,1597 1,1458 1,1424 1,1317


21 1,0598 1,0532 1,0512 1,0451 61 1,1621 1,1481 1,1448 1,1338
22 1,0625 1,0556 1,0537 1,0473 62 1,1645 1,1504 1,1473 1,1360
23 1,0652 1,0580 1,0561 1,0496 63 1,1669 1,1526 1,1493 1,1382
24 1,0679 1,0604 1,0585 1,0518 64 1,1694 1,1549 1,1517 1,1403
25 1,0706 1,0627 1,0609 1,0540 65 1,1718 1,1572 1,1543 1,1425
26 1,0733 1,0652 1,0663 1,0564 66 1,1742 1,1595 1,1565 1,1446
27 1,0760 1,0678 1,0656 1,0587 67 1,1766 1,1618 1,1584 1,1467
28 1,0787 1,0702 1,0681 1,0609 68 1,1790 1,1640 1,1604 1,1489
29 1,0813 1,0726 1,0705 1,0632 69 1,1813 1,1663 1,1628 1,1510
30 1,0839 1,0750 1,0729 1,0654 70 1,1835 1,1685 1,1655 1,1531
31 1,0866 1,0774 1,0753 1,0676 71 1,1858 1,1707 1,1677 1,1552
32 1,0891 1,0798 1,0777 1,0699 72 1,1882 1,1729 1,1702 1,1573
33 1,0916 1,0821 1,0800 1,0721 73 1,1906 1,1751 1,1728 1,1595
34 1,0941 1,0844 1,0823 1,0743 74 1,1929 1,1773 1,1752 1,1615
35 1,0966 1,0867 1,0847 1,0766 75 1,1953 1,1794 1,1769 1,1636
36 1,0993 1,0892 1,0871 1,0788 76 1,1976 1,1816 1,1785 1,1656
37 1,1018 1,0916 1,0895 1,0810 77 1,1999 1,1837 1,1801 1,1676
38 1,1043 1,0940 1,0919 1,0832 78 1,2021 1,1859 1,1818 1,1697
39 1,1069 1,0964 1,0940 1,0854 79 1,2043 1,1881 1,1837 1,1717
40 1,1095 1,0988 1,0963 1,0876 80 1,2065 1,1902 1,1806 1,1737
41 1,1122 1,1012 1,0990 1,0898 81 1,2088 1,1924 1,1876 1,1758
42 1,1148 1,1036 1,1015 1,0920 82 1,2110 1,1944 1,1896 1,1778
43 1,1174 1,1060 1,1038 1,0943 83 1,2132 1,1965 1,1914 1,1798
44 1,1199 1,1084 1,1062 1,0965 84 1,2154 1,1985 1,1929 1,1817
45 1,1224 1,1109 1,1085 1,0987 85 1,2176 1,2005 1,1953 1,1837
46 1,1249 1,1133 1,1108 1,1009 86 1,2196 1,2025 1,1976 1,1856
47 1,1274 1,1156 1.1130 1,1031 87 1,2217 1,2045 1,1994 1,1875
48 1,1299 1,1179 1,1157 1,1053 1,2237 1,2064 1,2012 1,1894
49 1,1324 1,1202 1,1185 1,1076 1,2258 1,2084 1,2028 1,1910
50 1,1349 1,1225 1,1207 1,1098 90 1,2278 1,2102 1,2044 1,1927 .
51 1,137* 1,1248 1,1223 1,1120 91 1,2297 1,2121 1,2059 1,1945
52 1,1399 1,1271 1,1244 1,1142 92 1,2316 1,2139 1,2078 1,1961
53 1,1424 1,1294 1,1269 1,1164 93 1,2335 1,2157 1,2099 1,1978
54 1,1448 1,1318 1,1295 1,1186 94 1,2354 1,2174 1,2117 1.1994
55 1,1472 1,1341 1,1320 1,1208 1,2372 1,2191 1,2140 1,2008
56 1,1497 1,1365 1,1342 1,1230 96 1,2390 1,2208 1,2158 1,2022
57 1,1523 1,1388 1,1361 1,1253 97 1,2408 1,2224 1,2170 1,2036
58 1,1548 1,1411 1,1381 1,1274 1,2425 1,2240 1,2183 1.1994
59 1,1573 1,1434 1,1401 1,1295 1,2441 1,2257 1,2202 1,2061
100 1,2456 1,2273 1,2212 1,2073

-98
CH3COOH

d 4 d 4
X, % , %
O2 C IO0 C 15 20 25 30 40 O0 C IO0 C 15 20 25 30 40

0 0,9999 0,9997 0,9991 0,9982 0,9971 0,9957 0,9922 15 1,0262 1,0232 1,0213 1,0195 1,072 1,0151 1,0099
1 1,0016 1,0013 1,0006 0,9996 0,9987 0,9971 0,9934 16 1,0278 1,0247 1,0227 1,0209 1,0185 1,0163 1,0110
2 1,0033 1,0029 1,0021 1,0012 1,0000 1,9964 0,9946 17 1,0295 1,0262 1,0241 1,0223 1,0198 1,0175 1,0121
3 1,0051 1,0044 1,0036 1,0025 1,0013 1,9997 0,9958 18 1,0311 1,0276 1,0255 1,0236 1,0210 1,0187 1,0132
4 1,0070 1,0060 1,0051 1,0040 1,0027 1,0011 0,9970 19 1,0327 1,0291 1,0269 1,0250 1,0223 1,0198 1,0142
5 1,0088 1,0076 1,0066 1,0055 1,0041 1,0024 0,9982 20 1,0343 1,0305 1,0283 1,0263 1,0235 1,0210 1,0153
6 1,0106 1,0092 1,0081 1,0069 1,0055 1,0037 0,9994 21 1,0358 1,0319 1,0297 1,0276 1,0248 1,0222 1,0164
7 1,0124 1,0108 1,0096 1,0083 1,0068 1,0050 1,0006 22 1,0374 1,0333 1,0310 1,0288 1,0260 1,0233 1,0174
8 1,0142 1,0124 1,0111 1,0097 1,0081 1,0063 1,0018 23 1,0389 1,0347 1,0323 1,0301 1,0272 1,0244 1,0185
9 1,0159 1,0140 1,0126 1,0111 1,0094 1,0076 1,0030 24 1,0404 1,0361 1,0336 1,0313 1,0283 1,0256 1,0195
10 1,0177 1,0156 1,0141 1,0125 1,0107 1,0089 1,0042 25 1,0419 1,0375 1,0349 1,0326 1,0295 1,0267 1,0205
1,0194 i;0171 1,0155 1,0139 1,0120 1,0102 1,0054 2 1,0434 1,0388 1,0362 1,0338 1,0307 1,0278 1,0215
12 1,0211 1,0187 1,0170 1,0154 1,0133 1,0115 1,0065 27 1,0449 1,0401 1,0374 1,0349 1,0318 1,0289 1,0225
13 1,0228 1,0202 1,0184 1,0168 1,0146 1,0127 1,0077 28 1,0463 1,0414 1,0386 1,0361 1,0329 1,0299 1,0234
14 1,0245 1,0217 1,0199 1,0182 1,0159 1,039 1,0088 29 1,0477 1,0427 1,0399 1,0372 1,0340 1,0310 1,0244

49

d* tt 4 i\
, % , %
0 10 15 20 25 30 40 0 IO0 C J5 20 25 30 40J

30 1,0491 1 ,0 4 4 0 1,0 4 1 1 1 ,0 3 8 4 1 ,0 3 5 0 1 ,0 3 2 0 1 ,0 2 5 3 65 1 ,0 8 4 4 1 ,0 7 5 7 1,0711 1 ,0 6 6 6 1,0621 1 ,0 5 7 5 1 ,0 4 8 0


31 1 ,0 5 0 5 1 ,0 4 5 3 1 ,0 4 2 3 1 ,0 3 9 5 1,0 3 6 1 1 ,0 3 3 0 1 ,0 2 6 2 66 1 ,0 8 5 0 1 ,0 7 6 2 1 ,0 7 1 6 1,0671 1 ,0 6 2 4 1 ,0 5 7 8 1 ,0 4 8 3
32 1 ,0 5 1 9 1 ,0 4 6 5 1 ,0 4 3 5 1 ,0 4 0 6 1 ,0 3 7 2 1 ,0 3 4 1 1 ,0 2 7 2 67 1 ,0 8 5 6 1 ,0 7 6 7 1 ,0 7 2 0 1 ,0 6 7 5 1 ,0 6 2 8 1 ,0 5 8 2 1 ,0 4 8 6
33 1,0 5 3 2 1 ,0 4 7 7 1 ,0 4 4 6 1 ,0 4 1 7 1 ,0 3 8 2 1 ,0 3 5 1 1,0271 68 1 ,0 8 6 0 1,0771 1 ,0 7 2 5 1 ,0 6 7 8 1,0631 1 ,0 5 8 5 1 ,0 4 8 9
34 1 ,0 5 4 5 1 ,0 4 8 9 1 ,0 4 5 8 1 ,0 4 2 8 1 ,0 3 9 2 1 ,0 3 6 1 1 ,0 2 8 9 69 1 ,0 8 6 5 1 ,0 7 7 5 1 ,0 7 2 9 1 ,0 6 8 2 1 ,0 6 3 4 1 ,0 5 8 8 1,0491

35 1,0 5 5 8 1,0501 1 ,0 4 6 9 1 ,0 4 3 8 1 ,0 4 0 2 1,0 3 7 1 1 ,0 2 0 8 70 1 ,0 8 6 9 1 ,0 7 7 9 1 ,0 7 3 2 1 ,0 6 8 5 1 ,0 6 3 7 1 ,0 5 9 0 1 ,0 4 9 3


36 1,0571 1 ,0 5 1 3 1 ,0 4 8 0 1 ,0 4 4 9 1 ,0 4 1 2 1 ,0 3 8 0 1 ,0 3 0 6 71 1 ,0 8 7 4 1 ,0 7 8 3 1 ,0 7 3 6 1 ,0 6 8 7 1 ,0 6 4 0 1 ,0 5 9 2 1 ,0 4 9 5
37 1 ,0 5 8 4 1 ,0 5 2 4 1,0 4 9 1 1 ,0 4 5 9 1 ,0 4 2 2 1 ,0 3 9 0 1 ,0 3 1 4 72 1 ,0 8 7 7 1 ,0 7 8 6 1 ,0 7 3 8 1 ,0 6 9 0 1,0 6 4 2 1 ,0 5 9 4 1 ,0 4 9 6
38 1,0 5 9 6 1 ,0 5 3 5 1 ,0501 1 ,0 4 6 9 1 ,0 4 3 2 1 ,0 3 9 9 1 ,0 3 2 2 73 1,0881 1,0 7 8 9 1,0741 1 ,0 6 9 3 1 ,0 6 4 4 1 ,0 5 9 5 1 ,0 4 9 7
39 1 ,0 6 0 8 1 ,0 5 4 6 1 ,0 5 1 2 1 ,0 4 7 9 1,0 4 4 1 1 ,0 4 0 8 1 ,0 3 3 0 74 1,0 8 8 4 1 ,0 7 9 2 1 ,0 7 4 3 1 ,0 6 9 4 1 ,0 6 4 5 1 ,0 5 9 6 1 ,0 4 9 8
40 1,0621 1 ,0 5 5 7 1 ,0 5 2 2 1 ,0 4 8 8 1 ,0 4 5 0 1 ,0 4 1 6 1 ,0 3 3 8 75 1 ,0 8 8 7 1 ,0 7 9 4 1 ,0 7 4 5 1 ,0 6 9 6 1 ,0 6 4 7 1 ,0 5 9 7 1 ,0 4 9 9
41 1 ,0 6 3 3 1 ,0 5 6 8 1 ,0 5 3 2 1 ,0 4 9 6 1 ,0 4 6 0 1 ,0 4 2 5 1 ,0 3 4 6 76 1 ,0 8 8 9 1 ,0 7 9 6 1 ,0 7 4 6 1 ,0 6 9 8 1 ,0 6 4 8 1 ,0 5 9 8 1 ,0 4 9 9
42 1,0 6 4 4 1 ,0 5 7 8 1 ,0 5 4 2 1 ,0 5 0 7 1 ,0 4 6 9 1 ,0 4 3 3 1 ,0 3 5 3 77 1,0891 1 ,0 7 9 7 1 ,0 7 4 7 1 ,0 6 9 9 1 ,0 6 4 8 1 ,0 5 9 8 1 ,0 4 9 9
43 1 ,0 6 5 6 1 ,0 5 8 8 1,0551 1 ,0 5 1 6 1 ,0 4 7 7 1,0441 1,0361 78 1 ,0 8 9 3 1 ,0 7 9 8 1 ,0 7 4 7 1 ,0 7 0 0 1 ,0 6 4 8 1 ,0 5 9 8 1 ,0 4 9 8
44 1,0 6 6 7 1 ,0 5 9 8 1 ,0561 1 ,0 5 2 5 1 ,0 4 8 6 1 ,0 4 4 9 1 ,0 3 6 8 79 1 ,0 8 9 4 1 ,0 7 9 8 1 ,0 7 4 7 . 1 ,0 7 0 0 1 ,0 6 4 8 1 ,0 5 9 7 1 ,0 4 9 7
45 1,0 6 7 9 1 ,0 6 0 8 1 ,0 5 7 0 1 ,0 5 3 4 1 ,0 4 9 5 1 ,0 4 5 6 1 ,0 3 7 5 80 1 ,0 8 9 5 1 ,0 7 9 8 1 ,0 7 4 7 1 ,0 7 0 0 1 ,0 6 4 7 1 ,0 5 9 6 1 ,0 4 9 5
46 1 ,0689 1 ,0 6 1 8 1 ,0 5 7 9 1 ,0 5 4 2 1 ,0 5 0 3 1 ,0 4 6 4 1 ,0 3 8 2 81 1 ,0 8 9 5 1 ,0 7 9 7 1 ,0 7 4 5 1,0 6 9 9 1 ,0 6 4 6 1 ,0 5 9 4 1 ,0 4 9 3
47 1,0 6 9 9 1 ,0 6 2 7 1 ,0 5 8 8 1,0551 1,0511 1 ,0471 1 ,0 3 8 9 82 1 ,0 8 9 5 1,0 7 9 6 1 ,0 7 4 3 1,0 6 9 8 1 ,0 6 4 4 1 ,0 5 9 2 1 ,0 4 9 0
48 1 ,0709 1 ,0 6 3 6 1 ,0 5 9 7 1 ,0 5 5 9 1 ,0 5 1 8 1 ,0 4 7 9 1 ,0 3 9 5 83 1 ,0 8 9 5 1 ,0 7 9 5 1,0741 1,0 6 9 6 1 ,0 6 4 2 1 ,0 5 8 9 1 ,0 4 8 7
49 1 ,0 7 2 0 1 ,0 6 4 5 1 ,0 6 0 5 1 ,0 5 6 7 1 ,0 5 2 6 1 ,0 4 8 6 1 ,0 4 0 2 84 1 ,0 8 9 3 1 ,0 7 9 3 1 ,0 7 3 8 1 ,0 6 9 3 1 ,0 6 3 8 1 ,0 5 8 5 1 ,0 4 8 3
50 1 ,0 7 2 9 1 ,0 6 5 4 1 ,0 6 1 3 1 ,0 5 7 5 1 ,0 5 3 4 1 ,0 4 9 2 1 ,0 4 0 8 85 1,0891 1 ,0 7 9 0 1 ,0 7 3 5 1 ,0 6 8 9 1 ,0 6 3 5 1,0 5 8 2 1 ,0 4 7 9
51 1 ,0 7 3 8 1 ,0 6 6 3 1 ,0 6 2 2 1 ,0 5 8 2 1 ,0 5 4 2 1 ,0 4 9 9 1 ,0 4 1 4 86 1 ,0 8 8 7 1 ,0 7 8 7 1,0731 1 ,0 6 8 5 1 ,0 6 3 0 1 ,0 5 7 6 1 ,0 4 7 3
52 1,0748 1,0671 1 ,0 6 2 9 1 ,0 5 9 0 1 ,0 5 4 9 1 ,0 5 0 6 1,0421 87 1 ,0 8 8 3 1 ,0 7 8 3 1 ,0 7 2 6 1 ,0 6 8 0 1 ,0 6 2 6 1,0571 1 ,0 4 6 7
53 1 ,0 7 5 7 1 ,0 6 7 9 1 ,0 6 3 7 1 ,0 5 9 7 1 ,0 5 5 5 1 ,0 5 1 2 1 ,0 4 2 7 88 1 ,0 8 7 7 1 ,0 7 7 8 1,0721 1 ,0 6 7 5 1 ,0 6 2 0 1 ,0 5 6 4 1 ,0 4 6 0
54 1 ,0 7 6 5 1 ,0 6 8 7 1 ,0 6 4 4 1 ,0 6 0 4 1 ,0 5 6 2 1 ,0 5 1 8 1 ,0 4 3 2 89 1 ,0 8 7 2 1 ,0 7 7 3 1 ,0 7 1 5 1 ,0 6 6 8 1 ,0 6 1 3 1 ,0 5 5 7 1 ,0 4 5 3
55 1 ,0774 1 ,0 6 9 4 1 ,0651 1,0611 1 ,0 5 6 8 1 ,0 5 2 5 1 ,0 4 3 8 90 1 ,0 8 6 5 1 ,0 7 6 6 1 ,0 7 0 8 1,0661 1 ,0 6 0 5 1 ,0 5 4 9 1 ,0 4 4 5
56 1 ,0 7 8 2 1,0701 1 ,0 6 5 8 1 ,0 6 1 8 1 ,0 5 7 4 1,0531 1 ,0 4 4 3 91 1 ,0 8 5 7 1,0 7 5 8 1 ,0 7 0 0 1 ,0 6 5 2 1 ,0 5 9 7 1,0541 1 ,0 4 3 6
57 1,0 7 9 0 1 ,0 7 0 8 1 ,0 6 6 5 1 ,0 6 2 4 1 ,0 5 8 0 1 ,0 5 3 6 1 ,0 4 4 8 92 1,0 8 4 8 1 ,0 7 4 9 1 ,0 6 9 0 1 ,0 6 4 3 1 ,0 5 8 7 1 ,0 5 3 0 1 ,0 4 2 6
58 1,0798 1 ,0 7 1 5 1 ,0 6 7 2 1,0631 1 ,0 5 8 6 1 ,0 5 4 2 1 ,0 4 5 3 93 1 ,0 8 3 8 1 ,0 7 3 9 1 ,0 6 8 0 1 ,0 6 3 2 1 ,0 5 7 7 1 ,0 5 1 8 1 ,0 4 1 4
59 1,0805 1 ,0 7 2 2 1 ,0 6 7 8 1 ,0 6 3 7 1 ,0 5 9 2 1 ,0 5 4 7 1 ,0 4 5 8 94 1 ,0 8 2 6 1 ,0 7 2 7 1 ,0 6 6 7 1 ,0 6 1 9 1 ,0 5 6 4 1 ,0 5 0 6 1 ,0401
60 1 ,0813 1 ,0 7 2 8 1 ,0 6 8 4 1 ,0 6 4 2 1 ,0 5 9 7 1 ,0 5 5 2 1 ,0 4 6 2 95 1 ,0 8 1 3 1 ,0 7 1 4 1 ,0 6 5 2 1 ,0 6 0 5 1,0551 1,0491 1 ,0 3 8 6
61 1 ,0820 1 ,0 7 3 4 1 ,0 6 9 0 1 ,0 6 4 8 1 ,0 6 0 2 1 ,0 5 5 7 1 ,0 4 6 6 96 1 ,0 7 9 8 . 1 ,0 6 3 2 1 ,0 5 8 8 1 ,0 5 3 5 1 ,0 4 7 3 1 ,0 3 6 8
62 1,0826 1 ,0 7 4 0 1 ,0 6 9 6 1 ,0 6 5 3 1 ,0 6 0 7 1 ,0 5 6 2 1 ,0 4 7 0 97 1 ,0 7 8 0 1,0611 1 ,0 5 7 0 1 ,0 5 1 6 1 ,0 4 5 4 1 ,0 3 4 8
63 1,0833 1 ,0 7 4 6 1 ,0701 1 ,0 6 5 8 1 ,0 6 1 2 1 ,0 5 6 6 1 ,0 4 7 3 98 1 ,0 7 5 9 1 ,0 5 9 0 1 ,0 5 4 9 1 ,0 4 9 5 1,0431 1 ,0 3 2 5
64 1,0838 1 ,0 7 5 2 1 ,0 7 0 6 1 ,0 6 6 2 1 ,0 6 1 6 1,0571 1 ,0 4 7 7 99 1 ,0 7 3 0 1 ,0 5 6 7 1 ,0 5 2 4 1 ,0 4 6 8 1 ,0 4 0 7 1 ,0 2 9 9
100 1 ,0 6 9 7 . . . 1 ,0 5 4 5 1 ,0 4 9 8 1 ,0 4 4 0 1 ,0 3 8 0 1,0 2 7 1

HOOCCOOH
V /0
X. d 4] 7*5 X, % V 1 d j 75 X, % ^ 1 7 ,5
4 X, %
.1 7 ,5
dA , %
.1 7 ,5
dA

I I 1,0 0 3 5 I 2 I 1 ,0 0 7 0 I 4 | 1 ,0 1 4 0 | 8 1 ,0 2 8 0 10 1 ,0 3 5 0 I 12 I 1 ,0 4 2 0

MOO
37
d j d4
V, % X, %
0 15 1 15 1 20 30 0 15 1 15 1 20 C 30

0 0 ,9 9 9 9 0 ,9 9 9 1 0 ,9 9 9 1 3 0 ,9 9 8 2 0 ,9 9 5 7 5 0 ,9 9 1 6 0 ,9 9 0 6 0 ,9 9 0 4 0 ,9 8 9 3 0 ,9 8 7 1
1 0 ,9 9 8 0 0 ,9 9 7 3 0 ,9 9 7 2 0 ,9 9 6 2 0 ,9 9 3 9 6 0 ,9 9 0 2 0 ,9 8 9 2 0 ,9 8 9 0 0 ,9 8 5 5 0 ,9 8 5 5
2 0 ,9 9 6 2 0 ,9 9 5 6 0 ,9 9 5 4 0 ,9 9 4 4 0 ,9 9 2 1 7 0 ,9 8 9 0 0 ,9 8 7 8 0 ,9 8 7 5 0 ,9 8 3 9 0 ,9 8 3 9
3 0 ,9 9 4 6 0 ,9 9 3 8 0 ,9 9 3 6 0 ,9 9 2 6 .0 ,9 9 0 4 8 0 ,9 8 7 8 0 ,9 8 6 4 0 ,9 8 6 2 0 ,9 8 2 4 0 ,9 8 2 4
4 0 ,9 9 3 0 0 ,9 9 2 2 0 ,9 9 2 0 0 ,9 9 0 9 0 ,9 8 8 7 9 0 ,9 8 6 6 0 ,9 8 5 1 0 ,9 8 4 9 0 ,9 8 0 9 0 ,9 8 0 9

* d ]5 .
50 . I. -

d*4 d4
X, % X, %
0 15 1 15 1 20 30 0 15 1 15 1 20 30

10 0,9856 0,9838 0,98362 0,9820 0,9794 55 0,9109 0,8988 0,8946 0,8871


0,9846 0,9826 0,9824 0,9808 0,9778 56 0,9086 03964 03921 0,8847
12 0,9838 0,9813 0,9812 0,9797 0,9764 57 0,9063 03940 0,8896 0,8823
13 0,9829 0,9802 0,9800 0,9876 0,9750 58 0,9040 0,8917 0,8874 0,8800
14 0,9821 0,9790 0,9788 0,9776 0,9735 59 0,9017 0,8893 0,8850 0,8777

15 0,9814 0,9779 0,9777 0,9765 0,9720 60 0,8994 0,88690 03825 0,8752


16 0,9806 0,9768 0,9765 0,9754 0,9705 61 0,9870 . 0,8845 0,8800 0,8728
17 0,9799 0,9756 0,9753 0,9743 0,9690 62 0,8947 0,8829 0,8821 0,8776 0,8106
18 0,9792 0,9745 0,9741 0,9731 0,9675 63 0,8947 0,8805 0,8798 0,8751 0,8680
19 0,9784 0,9730 0,9728 0,9717 0,9658 64 0,8901 03781 0,8775 0,8727 0,8656

20 0,9777 0,9719 0,97158 0,9703 0,9642 65 0,8878 0,8757 0,8752 0,8702 0,8631
21 0,9768 0,9704 0,9703 0,9688 0,9624 66 0,8854 0,8733 0,8728 0,8679 0,8607
22 0,9759 0,9690 0,9689 0,9669 0,9606 67 0,8831 0,8710 0,8705 0,8656 0,8583
23 0,9749 0,9675 0,9674 0,9651 0,9587 68 0,8807 0,8686 0,8682 0,8632 0,8559
24 0,9739 0,9660 0,9659 0,9634 0,9569 69 0,8784 0,8662 0,8658 0,8609 0,8535

25 0,9727 0,9643 0,9642 0,9615 0,9649 70 0,8761 0,8639 0,86346 0,8584 03511
26 0,9714 0,9626 0,9624 0,9597 0,9529 71 0,8738 0,8615 0,8611 0,8560 0,8487
27 0,9699 0,9608 0,9605 0,9577 0,9509 72 0,8714 0,8592 . 0,8588 0,8537 0,8464
28 0,9684 0,9590 0,9586 0,9558 0,9488 73 0,8691 0,8568 03564 0,8513 0,8440
29 0,9669 0,9570 0,9568 0,9540 0,9467 74 0,8668 0,8545 0,8541 0,8489 0,8416

30 0,9652 0,9551 0,95493 0,9520 0,9446 75 0,8644 0,8521 0,8517 0,8464 0,8392
31 0,9634 . 0,9530 0,9500 0,9426 76 0,8621 03497 0,8493 0,8439 0,8368
32 0,9615 ... 0,9510 0,9481 0,9405 77 0,8598 0,8474 0,8470 0,8415 0,8344
33 0,9596 ... 0,9489 0,9460 0,9383 78 0,8575 03450 0,8446 0,8391 0,8321
34 0,9577 0,9468 0,9440 0,9361 79 0,8551 03426 0,8422 03366 0,8297

35 0,9557 0,9446 0,9419 0,9338 80 0,8528 0,8403 0,83979 0,8342 0,8273


36 0,9536 ... 0,9424 0,9399 0,9315 81 0,8503 0,8379 0,8374 0,8317 0,8248
37 0,9514 ... 0,9401 0,9377 0,9292 82 0,8479 0,8355 0,8350 0,8292 0,8224
38 0,9493 0,9379 0,9355 0,9269 83 0,8456 0,8331 0,8326 0,8268 0,8200
39 0,9472 . . . 0,9356 0,9333 0,9246 84 0,8432 0,8307 0,8302 03243 0,8175

40 0,9450 0,93333 0,9310 0,92 85 0,8408 0,8282 0,8278 0,8219 0,8151


41 0,9428 . . 0,9311 0,9287 0,9201 86 0,8384 0,8259 0,8254 0,8194 0,8127
42 0,9406 . . 0,9288 0,9264 0,9177 87 0,8360 0,8234 0,8229 0,8169 03101
43 0,9384 . 0,9266 0,9239 0,9154 88 0,8336 0,8209 0,8205 0,8145 0,8078
44 0,9361 . . . 0,9243 0,9215 0,9130 89 0,8311 0,8184 0,8180 0,8120 0,8053

45 0,9338 0,9220 0,9191 0,9106 90 0,8287 0,8161 031553 0,8096 0,8029


46 0,9315 . 0,9197 0,9191 0,9106 91 0,8262 0,8136 0,8130 0,8072 0,8004
47 0,9292 0,9174 0,9141 0,9059 92 0,8237 0,8110 0,8104 0,8047 0,7979
48 0,9270 0,9150 0,9117 0,9036 93 0,8212 0,8085 0,8079 0,8023 0,7954
49 0,9247 0,9127 0,9093 0,9013 94 0,8186 f 0,8060 0,8052 0,7998 0,7929

50 0,9224 0,91043 0,9069 0,8990 95 0,8160 0,8034 0,8026 0,7973 0,7904


51 0,9201 0,9081 0,9044 0,8966 96 0,8133 0,8008 0,7999 0,7949 0,7878
52 0,9178 0,9058 0,9020 0,8943 97 0,8106 0,7981 0,7972 0,7925 0,7852
53 0,9155 0,9035 0,8996 0,8919 98 0,8078 0,7954 0,7945 0,7901 0,7826
54 0,9132 0,9011 0,8971 0,8895 99 0,8048 0,7926 0,7918 0,7877 0,7799
100 0,8016 0,7896 0,78913 0,7854 0,7770

1 d |5 Ho .
51

MOl
CH3OH

d* d 4
X, % , %
0C IO0C 15 20 10 Io0C 20

0 0,9999 0,9997 0,99913 0,9982 50 0,9287 0,9221 0,91852 0,9156


I 0,9981 0,9980 0,99727 0,9965 51 0,9269 0,9202 0,91653 0,9135
2 0,9963 0,9962 0,99543 0,9948 52 0,9250 0,9182 0,91451 0,9114
3 0,9946 0,9945 0,99370 0,9931 53 0,9230 0,9162 0,91248 0,9094
4 0,9930 0,9929 0,99198 0,9914 54 0,9211 0,9142 0,91044 0,9073
5 0,9914 0,9912 0,99029 0,9896 55 0,9191 0,9122 0,90839 0,9052
6 0,9899 0,9896 0,98864 0,9880 56 0,9172 0,9101 0,90631 0,9032
7 0,9884 0,9881 0,98701 0,9863 57 0,9151 0,9080 0,90421 0,9010
8 0,9870 0,9865 0,98547 0,9847 58 0,9131 0,9060 0,90210 0,8988
9 0,9856 0,9849 0,98394 0,9831 59 0,9111 0,9039 0,89996 0,8968
10 0,9842 0,9834 0,98241 0,9815 60 0,9090 0,9018 0,89781 0,8946
11 0,9829 0,9820 0,98093 0,9799 61 0,9068 0,8998 0,89563 0,8924
12 0,9816 0,9805 0,97945 0,9784 62 0,9046 0,8977 0,89341 0,8902
13 0,9804 0,9791 0,97802 0,9768 63 0,9024 0,8955 0,89117 0,8879
14 0,9792 0,9778 0,97660 0,9754 64 0,9002 0,8933 0,88890 0,8856
15 0,9780 0,9764 0,97518 0,9740 65 0,8980 0,8911 0,88662 0,8834
16 0,9769 0,9751 0,97377 0,9725 66 0,8958 0,8888 0,88433 0,8811
17 0,9758 0,9739 0,97237 0,9710 67 0,8935 0,8865 0,88203 0,8787
18 0,9747 0,9726 0,97096 0,9696 68 0,8913 0,8842 0,87971 0,8763
19 0,9736 0,9713 0,96955 0,9681 69 0,8891 0,8818 0,87739 0,8738
20 0,9725 0,9700 0,96814 0,9666 70 0,8869 0,8794 0,87507 0,8715
21 0,9714 0,9687 0,96673 0,9651 71 0,8847 0,8770 0,87271 0,8690
22 0,9702 0,9673 0,96533 0,9636 72 0,8824 0,8747 0,87033 0,8665
23 0,9690 0,9660 0,96392 0,9622 73 0,8801 0,8724 0,86792 0,8641
24 0,9678 0,9646 0,96251 0,9607 74 0,8778 0,8699 0,86546 0,8616
25 0,9666 0,9632 0,96108 0,9592 75 0,8754 0,8676 0,86300 0,8592
26 0,9654 0,9618 0,95963 0,9576 76 0,8729 0,8651 0,86051 0,8567
27 0,9642 0,9604 0,95817 0,9562 77 0,8705 0,8626 0,85801 0,8542
28 0,9629 0,9590 0,95668 0,9546 78 0,8680 0,8602 0,85551 0,8518
29 0,9616 0,9575 0,95518 0,9531 79 0,8657 0,8577 0,85300 0,8494
30 0,9604 0,9560 0,95366 0,9515 80 0,8634 0,8551 0,85048 0,8469
31 0,9590 0,9546 0,95213 0,9599 81 0,8610 0,8527 0,84794 0,8446
32 0,9576 0,9531 0,95056 0,9483 82 0,8585 0,8501 0,84536 0,8420
33 0,9563 0,9516 0,94896 0,9466 83 0,8560 0,8475 0,84274 0,8394
34 0,9549 0,9500 0,94734 0,9450 84 0,8535 0,8449 0,84009 0,8366
35 0,9534 0,9484 0,94570 0,9433 85 0,8510 0,8422 0,83742 0,8340
36 0,9520 0,9469 0,94404 0,9416 86 0,8483 0,8394 0,83475 0,8314
37 0,9505 0,9453 0,94237 0,9398 87 0,8456 0,8367 0,83207 0,8286
38 0,9490 0,9437 0,94067 0,9381 88 0,8428 0,8340 0,82937 0,8258
39 0,9475 0,9420 0,93894 0,9363 89 0,8400 0,8314 0,82667 0,8230
40 0,9459 0,9403 0,93720 0,9345 90 0,8374 0,8287 0,82396 0,8202
41 0,9443 0,9387 0,93543 0,9327 91 0,8347 0,8261 0,82124 0,8174
42 0,9427 0,9370 0,93365 0,9309 92 0,8320 0,8234 0,81849 0,8146
43 0,9411 0,9352 0,93185 0,9290 93 0,8293 0,8208 0,81568 0,8118
44 0,9395 0,9334 0,93001 0,9272 94 0,8266 0,8180 0,81285 0,8090
45 0,9377 0,9316 0,92815 0,9252 95 0,8240 0,8152 0,80999 0,8062
46 0,9360 0,9298 0,92627 0,9234 96 0,8212 0,8124 0,80713 0,8034
47 0,9342 0,9279 0,92436 0,9214 97 0,8186 0,8096 0,80428 0,8005
.48 0,9324 0,9260 0,92242 0,9196 98 0,8158 0,8068 0,80143 0,7976
49 0,9306 0,9240 0,92048 0,9176 99 0,8130 0,8040 0,79859 0,7948
IOO1 0,8102 0,8009 0,79577 0,7917

1 100% . , A m erican In stitu te of P h y sic s H and


book, New York, 1957. - H andbook o f C hem ical D ata, N ew York, 1957.
52 . I. -

1-102

C3H7OH

d \4 d4 d?4 d 4/
X. % X, % X, % X, %
O0 15 30 0 15 30 0 15 I 30 O0 j 15 30

0 0,9999 0,9991 0,9957 25 0,9717 0,9633 0,9543 50 0,9232 0,9124 0,9015 75 0,8736 0,8618 0,8497
1 0,9982 0,9974 0,9940 26 0,9700 0,9614 0,9522 51 0,9213 0,9104 0,8994 76 0,8716 0,8598 0,8477
2 0,9967 0,9960 0,9924 27 0,9682 0,9594 0,9501 52 0,9192 0,9084 0,8973 77 0,8695 0,8577 0,8456
3 0,9952 0,9944 0,9908 28 0,9664 0,9576 0,9481 53 0,9173 0,9064 0,8952 78 0,8675 0,8556 0,8435
4 0,9939 0,9929 0,9893 29 0,9646 0,9556 0,9460 54 0,9153 0,9044 0,8931 79 0,8655 0,8536 0,8414
5 0,9926 0,9915 0,9877 30 0,9627 0,9535 0,9439 55 0,9 32 0,9023 0,8911 80 0,8634 0,8516 0,8394
6 0,9914 0,9902 0,9862 31 0,9608 0,9516 0,9418 56 0,9112 0,9003 0,8890 81 0,8614 0,8496 0,8373
7 0,9904 0,9890 0,9848 32 0,9589 0,9495 0,9396 57 0,9093 0,8983 0,8869 82 0,8594 0,8475 0,8352
8 0,9894 0,9877 0,9834 33 0,9570 0,9474 0,9375 58 0,9073 0,8963 0,8849 83 0,8574 0,8454 0,8332
9 0,9883 0,9864 0,9819 34 0,9550 0,9454 0,9354 59 0,9053 0,8942 0,8828 84 0,8554 0,8434 0,8311
10 0,9874 0,9852 0,9804 35 0,9530 0,9434 0,9333 60 0,9033 0,8992 0,8807 85 0,8534 0,8413 0,8290
11 0,9865 0,9840 0,9790 36 0,9511 0,9413 0,9312 61 0,9013 0,8902 0,8786 86 0,8513 0,8393 0,8269
12 0,9857 0,9828 0,9775 37 0,9491 0,9372 0,9289 62 0,8994 0,8882 0,8766 87 0,8492 0,8372 0,8248
13 0,9849 0,9817 0,9760 38 0,9471 0,9372 0,9269 63 0,8974 0,8861 0,8745 88 0,8471 0,8351 0,8227
14 0,9841 0,9806 0,9746 39 0,9450 0,9351 0,9247 64 0,8954 0,8841 0,8724 89 0,8450 0,8330 0,8206
15 0,9833 0,9793 0,9730 40 0,9430 0,9331 0,9226 65 0,8934 0,8820 0,8703 90 0,8429 0,8308 0,8185
16 0,9825 0,9780 0,9714 41 0,9411 0,9310 0,9205 66 0,8913 0,8800 0,8682 91 0,8408 0,8227 0,8164
17 0,9817 0,9768 0,9698 42 0,9391 0,9290 0,9184 67 0,8894 0,8779 0,8662 92 0,8387 0,8266 0,8142
18 0,9808 0,9752 0,9680 43 0,9371 0,9269 0,9164 68 0,8874 0,8759 0,8641 93 0,8364 0,8244 0,8140
19 0,9800 0,9739 0,9661 44 0,9352 0,9248 0,9143 69 0,8854 0,8739 0,8620 94 0,8342 0,8221 0,8098
20 0,9789 0,9723 0,9643 45 0,9332 0,9228 0,9122 70 0,8835 0,8719 0,8600 95 0,8320 0,8199 0,8077
21 0,9776 0,9705 0,9622 46 0,9311 0,9207 0,9100 71 0,8815 0,8700 0,8580 96 0,8296 0,8176 0,8054
22 0,9763 0,9688 0,9602 47 0,9291 0,9186 0,9079 72 0,8795 0,8680 0,8559 97 0,8272 0,8153 0,8031
23 0,9748 0,9670 0,9583 48 0,9271 0,9165 0,9057 73 0,8776 0,8659 0,8539 98 0,8248 0,8128 0,8008
24 0,9733 0,9651 0,9563 49 0,9252 0,9145 0,9036 74 0,8756 0,8639 0,8518 99 0,8222 0,8104 0,7984
100 0,8194 0,8077 0,7958

1-103

C2H5OH

d*
, %
IO0 C 15 20 25 30 35 40

0 0,99973 0,99913 0,99823 0,99708 0,99568 0,99406 0,99225


1 785 725 636 520 379 217 034
2 602 542 453 336 194 031 0,98846
3 426 365 275 157 014 0,98849 663
4 258 195 103 0,98984 0,98839 672 485

5 098 032 0,98938 817 670 501 311


6 0,98946 0,98877 780 656 507 335 142
7 801 729 627 500 347 172 0,97975
8 600 584 478 346 189 009 808
9 524 442 331 193 031 0,97846 641

10 393 304 187 043 0,97875 685 475


11 267 171 047 0,97897 723 527 312
12 145 041 0,97910 753 573 371 150
13 026 0,97914 775 611 424 216 0,96989
14 0,97911 790 643 472 278 063 828
53


X, %
10 1 : 20 25 30 35 40

15 0,97800 0,97669 0,97514 0,97334 0,97133 0,96911 0,96670


16 692 552 387 399 0,96990 760 512
17 583 433 259 062 844 607 352
18 473 313 129 0,96923 697 452 189
19 363 191 0,96997 782 547 294 023
20 252 068 864 639 395 134 0,95856
21 139 0,96944 729 495 242 0,95973 687
22 024 818 592 348 087 809 516
23 0,96907 689 453 199 0,95929 643 343
24 787 558 312 048 769 476 168
25 665 424 168 0,95895 607 306 0,94991
26 539 287 020 738 442 133 810
27 406 144 0,95867 576 272 0,94955 625
28 268 0,95996 710 410 098 774 438
29 125 844 548 241 0,94922 590 248
30 0,95977 686 382 067 741 403 055
31 823 524 212 0,94890 557 214 0,93860
32 665 357 038 709 370 021 662
33 502 186 0,94860 525 180 0,93825 461
34 334 011 679 337 0,93986 626 257
35 162 0,94832 494 146 790 425 051
36 0,94986 650 306 0,93952 591 221 0,92843
37 805 464 114 756 390 016 634
38 620 273 0,93919 556 186 0,92808 422
39 431 079 720 353 0,92979 597 208
40 238 0,93882 518 148 770 385 0,91992
41 042 682 314 0,92940 558 170 774
42 0,93842 478 107 729 344 0,91952 554
43 639 271 0,92897 516 128 733 332
44 433 062 685 301 0,91910 513 108
45 226 0,92852 472 085 692 291 0,90884
46 017 640 257 0,91868 472 069 660
47 0,92806 426 041 649 250 0,90845 434
48 593 211 0,91823 429 028 621 207
49 379 0,91995 604 208 0,90805 396 0,89979
50 126 776 384 0,90985 580 168 750
51 0,91943 555 160 760 353 0,89940 519
52 723 333 0,90936 534 125 710 288
53 502 HO 711 307 0,89896 479 056
54 279 0,90885 485 097 667 248 0,88823
55 055 659 258 0,89850 437 016 589
56 0,90831 433 031 621 206 0,88784 356
57 607 207 0,89803 392 0,88975 552 122
58 381 0,89980 574 162 744 319 0,87888
59 154 752 344 0,88931 512 085 653
60 0,89927 523 113 699 278 0,87851 417
61 698 293 0,88882 446 044 615 180
62 468 062 650 233 0,87809 379 0,86943
63 237 0,88830 417 0,87998 574 142 705
64 006 597 183 763 337 0,86905 466
65 0,88774 364 0,87948 527 100 667 227
66 541 130 713 291 0,86863 429 0,85987
67 308 0,87895 477 054 625 190 747
68 074 660 241 0,86817 387 0,85980 407
69 0,87839 424 004 579 148 710 266
54 . /. -

d*
X, %
10 15 20 25 30 35 40

70 0,87602 0,87187 0,86766 0,86340 0,85908 0,85470 0,85025


71 365 0,86949 527 100 667 228 0,84783
72 127 710 287 0,85859 426 0,84986 540
73 0,86888 470 047 618 184 743 297
74 648 229 0,85806 376 0,84941 500 053
75 408 0,85988 564 134 698 257 0,83809
76 168 747 322 0,84891 455 013 564
77 0,85927 505 079 647 211 0,83768 319
78 6 85 262 0,84835 403 0,83966 523 074
79 442 018 590 158 720 277 0,82827
80 197 0,84772 344 0,83911 473 029 578
81 0,84950 525 096 664 224 0,82780 329
82 702 277 0,83848 415 0,82974 530 079
83 453 028 599 164 724 279 0,81828
84 203 ' 0,83777 348 0,82913 473 027 576
85 0,83951 525 095 660 220 0,81774 322
86 697 271 0,82840 405 0,81965 519 067
87 441 014 583 148 708 262 0,80811
88 181 0,82754 323 0,81888 448 003 552
89 0,82919 492 062 626 186 0,80742 291
90 654 227 0,81797 362 0,80922 478 028
91 386 0,81959 529 094 655 211 0,79761
92 114 688 257 0,80823 384 0,79941 491
93 0,81839 413 0,80983 549 111 669 220
94 561 134 705 272 0,79835 393 0,78947
95 278 0,80852 424 0,79991 555 114 670
96 0,80991 566 138 706 271 0,78831 388
97 698 274 0,79846 415 0,78981 542 100
98 399 0,79975 547 117 684 247 0,77806
99 094 670 243 0,78814 382 0,77946 507
100 0,79784 360 0,78934 506 075 641 203

1*104
C2H5OH
( {) 20 .


Xt % , %
2 5 7 8 9 0 1 2 I 4 6 7 8 9
0 I I 3 I 4 I 6 I 3 I 5

0 0,99823 804 785 766 748 729 710 692 673 655 15 0,97514 501 488 475 462 450 438 425 412 400
1 636 618 595 581 562 544 525 507 489 471 16 387 374 361 349 336 323 310 297 284 272
2 453 435 417 399 381 363 345 327 310 292 17 259 246 233 220 '207 194 181 168 155 142
3 275 257 240 222 205 188 171 154 137 120 18 129 116 103 089 076 063 050 037 024 010
4 103 087 070 050 037 020 003 987 971 954 19 0,96997 984 971 957 944 931 917 904 891 877
5 0,98938 922 906 890 874 859 843 827 811 796 20 864 850 837 823 810 796 783 769 756 742
6 780 765 749 734 718 703 688 673 658 642 21 729 716 702 688 675 661 647 634 620 606
7 627 612 597 582 567 553 538 523 508 493 22 592 578 564 551 537 523 509 495 481 467
8 478 463 449 434 419 404 389 374 360 345 23 453 439 425 411 396 382 368 354 340 326
9 331 316 301 287 273 258 244 229 215 201 24 312 297 283 269 254 240 225 211 196 182
10 187 172 158 144 130 117 103 089 075 061 25 168 153 139 124 109 094 080 065 050 035
11 047 033 019 006 992 978 964 951 937 923 26 020 005 990 975 959 944 929 914 898 883
12 0,97910 896 883 869 855 842 828 815 801 788 27 0,95867 851 836 820 805 789 773 757 742 726
13 775 761 748 735 722 79 696 683 670 657 28 710 694 678 662 646 630 613 597 581 565
14 643 630 617 604 591 578 565 552 539 526 29 548 532 516 499 483 466 450 433 416 400
- 55



X, %
4 j 5 j 6 j 7 I 8 j 9 1 2 3 4 6 7 8 9
I 2 5 I
30 0,95382 365 349 332 315 298 281 264 247 230 65 0,87948 925 901 878 854 831 807 784 760 737
31 212 195 178 161 143 126 108 091 074 056 66 713 689 666 642 619 595 572 548 524 501
32 038 020 003 985 967 950 932 914 896 878 67 477 454 430 406 383 359 336 312 288 265
33 0,94860 842 824 806 788 770 752 734 715 697 68 241 218 194 170 147 123 099 075 052 028
34 679 660 642 624 605 587 568 550 531 512 69 004 981 957 933 909 885 862 838 814 790
35 494 475 456 438 419 400 382 363 344 325 70 0,86766 742 718 694 671 647 623 599 575 551
36 306 287 268 249 230 211 192 172 153 134 71 527 503 479 455 431 407 383 339 335 311
37 114 095 075 056 036 017 997 978 958 939 72 287 263 239 215 191 167 143 119 095 071
38 0,93919 899 879 859 840 820 800 780 760 740 73 047 022 998 974 950 926 902 878 854 530
39 720 700 680 660 640 620 599 579 559 539 74 0,85806 781 757 733 709 685 661 636 612 588
40 518 498 478 458 437 417 396 376 356 335 75 564 540575 491
443 467 419 394 370 346
41 314 294 273 253 232 212 191 170 149 129 76 322 297273 200
249 225 176 152 128 103
42 107 086 065 044 023 002 981 960 939 918 77 079 055031 958
006 982 933 909 884 860
43 0,92897 876 855 834 812 791 770 749 728 707 78 0,84835 811787 713
762 738 689 664 640 615
44 685 664 642 621 600 579 557 536 515 493 79 590 566541 467
517 492 443 418 393 369
45 472 450 429 408 386 365 343 322 300 279 80 344 319294 270 245 220 196 171 146 121
46 257 236 214 193 171 150 128 106 085 063 81 096 072047 022 997 972 947 923 898 873
47 041 019 997 976 954 932 910 889 867 845 82 0,83848 823798 773 748 723 698 674 649 624
48 0,91823 801 780 758 736 714 692 670 648 626 83 599 574549 523 498 473 448 423 398 373
49 604 582 560 538 516 494 472 450 428 406 84 348 323297 272 247 222 196 171 146 120
50 384 361 339 317 295 272 250 228 206 183 85 095 070 044 019 994 968 943 917 892 866
51 160 138 116 093 071 049 026 004 981 959 86 0,82840 815 789 763 738 712 686 660 635 609
52 0,90936 914 891 869 846 824 801 779 756 734 87 583 557 531 505 479 453 427 401 375 349
53 711 689 666 644 621 598 576 553 531 508 88 323 297 271 245 219 193 167 140 114 088
54 485 463 440 417 395 372 349 327 304 281 89 062 035 009 983 956 930 903 877 850 824
55 258 236 213 190 167 145 122 099 076 054 90 0,81797 770 744 717 690 664 637 610 583 556
56 031 008 985 962 939 917 894 871 848 823 91 529 502 475 448 421 394 366 339 312 285
57 0,89803 780 757 734 711 688 665 643 620 597 92 9<7 230 203 175 148 120 093 066 038 010
58 574 551 528 505 482 459 436 413 390 367 93 0,80983 955 928 900 872 844 817 789 761 733
59 344 321 298 275 252 229 206 183 160 137 94 705 677 649 621 593 565 537 509 480 452
60 113 090 067 044 021 998 975 951 928 905 95 424 395 367 338 310 281 253 224 195 166
61 0,88882 859 836 812 789 766 743 720 696 673 96 138 109 080 051 022 993 963 934 905 875
62 650 626 603 580 557 533 510 487 463 440 97 0,79846 816 787 757 727 698 668 638 608 578
63 417 393 370 347 323 300 277 253 230 206 98 547 517 487 456 426 396 365 335 305 274
64 183 160 136 113 089 066 042 019 995 972 99 243 213 182 151 120 089 059 028 997 966
100 0,78934
I 105
C2H5OH
15,56


, ,
.
0 1 2 3 4 5 6 7 8 9 % 0 1 2 3 4 5 6 7 8

0 1,00000 985 970 955 940 925 910 895 880 865 15 0,98104 093 083 072 062 051 040 030 019 009
1 0,99850 835 820 806 791 776 761 747 732 717 16 0,97998 988 977 967 956 946 936 925 915 905
2 703 688 674 659 645 630 616 602 587 573 17 895 885 875 864 854 844 834 824 814 804
3 559 454 531 516 502 488 474 460 446 432 18 794 784 774 764 754 744 734 724 714 704
4 419 405 391 378 364 350 336 323 309 296 19 694 684 674 664 654 645 635 625 615 605
5 282 269 255 242 228 215 202 189 176 163 20 596 586 576 566 556 546 536 526 516 506
6 150 137 124 111 098 085 073 060 047 035 21 496 486 476 466 456 446 436 425 415 405
7 022 009 997 984 972 960 947 935 923 911 22 395 385 375 365 354 344 384 324 313 303
8 0,98899 887 875 863 851 838 826 814 803 791 23 293 283 272 262 252 241 231 221 210 200
9 779 767 755 743 731 720 708 696 684 672 24 189 179 168 158 147 137 126 116 105 095
10 661 649 637 625 614 602 590 579 567 556 25 084 073 063 052 042 031 020 010 999 988
11 544 532 521 509 498 487 475 464 452 441 26 0,96978 967 957 946 935 24 914 903 892 881
12 430 419 408 396 385 374 363 352 341 330 27 870 859 848 837 826 815 804 793 782 771
13 319 308 297 286 275 264 254 243 232 221 28 760 749 738 727 715 704 693 682 671 659
14 210 200 190 179 ,168 157 157 136 125 115 29 648 637 625 614 603 591 580 568 557 546
56 . I. -


, ,
. .
% 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 7 H 9

30 0,96534 522 511 499 488 476 464 453 441 429 65 0,90202 179 155 132 108 085 061 038 014 991
31 418 406 394 382 370 358 346 334 321 309 66 0,89967 943 920 896 872 848 825 801 777 753
32 296 284 271 259 246 234 221 209 196 183 67 729 705 681 657 633 609 585 561 537 513
33 170 157 144 132 119 106 093 080 067 054 68 489 465 441 416 392 368 343 319 295 270
34 041 028 015 002 988 975 962 948 935 921 69 245 220 196 171 147 122 098 073 048 024
35 0,95908 894 881 867 854 840 826 812 798 784 70 0,88999 974 950 925 900 875 850 825 801 776
36 770 756 742 728 714 700 685 671 757 643 71 751 725 700 675 650 625 600 574 549 524
37 628 614 599 585 570 556 541 526 512 497 72 499 474 448 423 397 372 346 321 296 270
38 482 467 452 437 423 408 393 378 362 347 73 244 218 193 167 141 116 090 064 039 013
39 332 317 302 286 271 256 240 225 209 194 74 0,87987 961 935 910 884 858 832 806 780 754
40 178 162 147 131 115 100 084 068 052 036 75 728 702 676 650 623 597 571 545 518 492
41 020 004 938 972 956 940 923 907 891 875 76 465 439 412 386 359 332 306 279 252 226
42 0,94858 842 825 809 792 776 759 743 726 710 77 199 172 145 118 092 065 038 011 984 957
43 693 676 660 643 626 609 592 575 558 541 78 0,86929 902 875 847 820 793 766 738 711 684
44 524 507 490 473 425 438 421 403 386 369 79 656 629 601 574 546 518 491 463 435 408
45 351 334 316 298 281 263 245 228 210 192 80 380 352 324 296 269 241 213 185 157 129
46 174 156 138 120 102 084 066 048 030 011 81 100 072 044 015 987 959 213 902 874 846
47 0,93993 975 956 938 920 901 883 864 845 827 82 0,85817 789 760 732 703 674 646 617 588 560
48 808 789 771 752 733 714 695 676 657 638 83 531 502 473 444 415 386 357 628 299 270
49 619 600 581 582 543 523 504 485 465 446 84 240 211 181 152 122 093 063 033 004 974
50 426 407 387 368 348 328 309 289 270 250 85 0,84944 914 884 854 824 794 764 734 703 673
51 230 210 190 171 151 131 111 091 071 051 86 642 612 581 551 520 490 459 428 398 367
52 031 011 991 971 951 931 911 890 870 850 87 336 305 274 243 212 181 150 119 088 056
53 0,92830 810 789 769 749 728 708 688 667 647 88 025 994 962 930 899 867 835 803 771 739
54 626 605 585 564 544 523 502 482 461 440 89 0,83707 675 643 610 578 545 513 480 447 415
55 419 398 377 357 336 315 294 273 252 231 90 382 349 315 282 249 216 183 150 116 083
56 210 189 168 147 126 105 084 062 041 029 91 049 015 981 947 913 879 845 810 776 741
57 0,91999 978 956 935 914 892 871 849 827 806 92 0,82705 670 635 600 565 529 494 458 423 387
58 784 762 741 719 697 675 653 631 610 588 93 351 315 279 243 206 170 133 096 059 022
59 565 543 521 499 477 455 433 410 388 366 94 0,81984 947 909 871 834 796 757 719 681 642
60 344 322 299 277 255 232 210 188 165 143 95 603 564 525 486 446 407 367 327 287 247
61 120 097 075 052 030 007 984 962 939 936 96 206 165 125 084 042 001 960 918 876 834
62 0,90893 870 847 825 802 779 756 733 710 687 97 0,80792 750 707 664 620 577 533 489 445 401
63 664 641 618 595 572 549 526 503 480 457 98 356 311 265 219 173 127 080 033 955 937
64 434 411 388 365 341 318 295 272 249 225 99 0,79889 841 792 743 693 643 593 543 492 441
100 389
1] 1-106

, , :
+ A x + B x i + C xi
, !\ , , .
.



, ,
cC %
I

C3H6O 0 0 -8 9 0,033729 0 , 041232 0 2984


C2H 4O 18 0 -3 0 0,03255 0,0516
C2H5NO 15 0 -6 0,03639 0,04171
C3H6O 0 0 -1 0 0 0,03856 0,05449 0,07588
4 0 -1 0 0 0,037648 - 0 , 041193 0,08272
15 0 -1 0 0 0,021009 0,059682 -0 6 2 4
20 0 -1 0 0 - 0 , 021233 0,053529 -0 5 3 2 7
25 0 -1 0 0 - 0 , 021171 -0 9 0 4 0,0356
C2H3N 15 0 -1 6 - 0 , 021175 02024
-. 6 10 25 0 -0 ,6 0,025615 0 O2117
C4H 10O 20 0 - 7 ,9 0,021651 0285
57




, ,
% I I
C5H 10O2 25 0 -3 0 ,0 334 0 ,0 42 7
C4H6O6 15 0 -1 5 0,024482 0 ,0 4185
C2H2Cl2O2 20 0 -3 0 0,0 24227 0 537 0 7534
25 0 -9 7 0,0 24427 0 537 0 7534
C4H 12ClN 21 0 -3 6 0,0334 0 ,0 76
CeH14O6 15 0 -9 5 0 2367 0 ,0 5358 -0 6 0 0 5
O5H 12O 20 0 - 2 ,5 0 ,0 2155 0 ,0 43
C4H 10O 15 0 -8 0,0 2146 0 ,0 56
20 0 -8 0 ,0 2169 0 ,0 438
C5H 10O2 25 0 -5 0 ,0 3253 0 ,0 4282
C 4H g O 2 15 0 -9 0 ,0 352
18 0 -9 0,0 345
25 0 -1 2 0 ,0 33 7
C 5H gO 7 18 0 -5 0 03824 OjO4I 141 17
C 4H 4O 4 25 0 -4 0 0 ,0 234 0 75
C 3H 4O 4 20 0 -4 0 0 ,0 2389 1066
C 4H 8O 2 18 0 -1 0 0 ,0 3414 0 ,0 4131
25 0 -6 2 0 ,0 35135 - 0 , 0 4166
C 3H 6O 2 20 0 -2 0 0 ,0 340 -0 7 4
C 3H 8O 3 25 0 -1 1 0 ,0 2207 0 ,0 423
C 3H 6O 3 25 0 -9 0 ,02231 OjO5 186
C H 4N 2O 14,8 0 -1 2 0 ,023 2 13 0 ,0 44802 1216
18 0 -5 1 0 ,0 22718 0 ,0 51552 0 2573
20 0 -3 5 0 ,0 22702 0 3712 - 0 , 0 72285
25 0 -1 0 0 2728 0 ,0 41817 1379
C 10H 14N2 20 0 -6 0 0,03642 0 ,05454 0 ,0 7687
/- C6H5NO3 15 0 - 1 ,5 0 ,0 23216 0 ,0 455
- C6H7N 25 0 -7 0 0 ,0 4386 0 ,0 51405
- C6H7N 25 0 -6 0 0 ,0 4683 - 13
C5H5N 25 0 -6 0 0 ,0 3229 -0 2 0 4 - 28
C3H6O2 18 0 -1 0 0 ,0 395 - 0 , 0 4172
25 0 -4 0 0 ,039245 -0 9 9 0 361
C6H6O2 18 0 -5 2 0 ,0 2201 0 519 - 19
C8H20ClN 21 0 -6 3 0 ,0 31884 0 ,0 56 122
CH4N2S 15 0 -7 0 ,022995 0 374
C2HClO2 12,5 0 -6 1 0 ,0 2499 153
20 1 0 -3 0 0 5033 1387
25 0 -9 4 0 ,025051 0 6119 1038
C6H 16CIN 21 0 -5 4 0 ,0 46 0 558 -0 6 9
C3H7NO2 20 0 -5 6 0 ,0 21278 -0 2 4 5 -0 3 4 3 7
C6H6O 15 0 -5 0,0 21 11 0 ,0 4283
80 0 -6 5 0 ,0 3462 -0 8 6
CH2O 15 0 -4 0 0 2518 0 ,0 5658 0 ,0 6542
CH3NO 25 2 2 -9 6 0 ,02 1217 0 3199 -0 2 5 2 9
C5H 4O2 20 0 -8 0 ,02 1827 0 ,0 5366
25 0 -8 0,0 2 1664 0 21
C2H3CI3O2 0 -7 0 0,024489 0 ,0 ^ 8 0 2 1291
15 0 -7 8 0 ,0 24455 0 2198 0 ,0 74366
30 0 -9 0 0 ,0 24401 OjO41887 0 6549
C2H3ClO2 20 0 -3 2 0 ,0 23648 0 302
25 0 -8 6 0 ,0 23602 0,05552 0 ,0 722
C2H2O4 0 -4 0 ,0 25898 -0 3 1 8 5 0 41
15 0 -4 0,0 2494 -0 8
17,5 0 -9 0,0 2494 0 8
20 0 -4 0 ,0 25264 1996 0 ,0 425 4
25 0 -4 0 ,0 25 108 - 1607 0 ,0 4208
C2H8ClN 21 0 -6 5 0 ,0 21193 -0 3 0 7 -0 4 7
C2H6O2 0 -1 0 0 O5O2 1483 0 2992 -0 5 2 4 8
15 0 -6 0 ,0 2133 108
() C4H 10O 20 0 -5 0 ,0 2221 0 48
25 0 -4 5 0 ,0 2221 0 ,0 435
C4H6O5 20 0 -4 0 0 ,0 23933 0 957
25 0 -4 0 0 ,0 23736 4 175 J
C4H6O 4 25 0 - 5 ,5 0 ,0 2304
58 . I. -


I 107
( pm . cm.)
15 0

0 I 2 3 4 5 6 7 8 9

-1 4 1,361 1,348 1,336 1,324 1,312 1,300 1,288 1,276 1,264 1,253
-1 3 1,490 1,477 1,464 1,450 1,437 1,424 1,411 1,399 1,386 1,373
-1 2 1,632 1,617 1,602 1,588 1,574 1,559 1,546 1,532 1,518 1,504
-1 1 1,785 1,769 1,753 1,737 1,722 1,707 1,691 1,676 1,661 1.646
- 10 1,950 1,934 1,916 1,899 1,883 1,866 1,849 1,833 1,817 1.800
-9 2,13! 2,112 2,093 2,075 2,057 2,039 2,021 2,003 1,985 1,968
-8 2,326 2,306 2,285 2,266 2,246 2,226 2,207 2,187 2,168 2,149
-7 2,537 2,515 2,493 2,472 2,450 2,429 2,408 2,387 2,367 2,346
-6 2,765 2,742 2,718 2,695 2,672 2,649 2,626 2,603 2,581 2,559
3,013 2,987 2,962 2,937 2,912 .2,887 2,862 2,838 2,813 2,790
-4 3,280 3,252 3,225 3,198 3,171 3,144 3,117 3,091 3,065 3,039
-3 3,568 3,539 3,509 3,480 3,451 3,422 3,393 3,364 3,336 3,308
2 3,880 3,848 3,816 3,785 3,753 3,722 3,691 3.660 3,630 3,599
- 4,217 4,182 4,147 4,113 4,079 4.045 4,012 3,979 3,946 3,913
0 4,579 4,542 4,504 4,467 4,431 4,395 4,359 4,323 4,287 4,252

MOO
( pm. cm.)
16 0

0 1 2 3 4 5 6 7 8 9

-1 5 1,436 1,425 1,414 1,402 1,390 1,379 1,368 1.356 1,345 1,334
-1 4 1,560 1,547 1,534 1.522 1,511 1,497 1,485 1,472 1,460 1,449
-1 3 1,691 1,678 1,665 1,651 1,637 1,624 1,611 1,599 1,585 I *572
-1 2 1,834 1,819 1,804 1,790 1,776 1,761 1,748 1,734 1,720 1,705
-1 1 1,987 1,971 1,955 1,939 1,924 1,909 1,893 1,878 1,863 1,848
-1 0 2,149 2,134 2,116 2,099 2,084 2,067 2,050 2,034 2,018 2.001
-9 2,326 2,307 2,289 2,271 2,254 2,236 2,219 2,201 2,184 2,167
-8 2,514 2,495 2,475 2,456 2,437 2,418 2,399 2,380 2,362 2,343
-7 2,715 2,695 2,674 2,654 2,633 2,613 2,593 2,572 2,553 2,533
-6 2,931 2,909 2,887 2,866 2,843 2,822 2,800 2,778 2,757 2,736
. 5 . . 3.163 3,139 3,115 3,092 3,069 3,046 3,022 3.000 2,976 2,955
-4 3.410 3,384 3,359 3,334 3,309 3,284 3,259 3,235 3,211 3,187
-3 3.673 3,647 3,620 3,593 3,567 3,540 3,514 3,487 3,461 3,436
-2 3,956 3,927 3,898 3,871 3,841 3,813 3,785 3,757 3,730 3,702
-1 4,258 4,227 4,196 4,165 4,135 4,105 4,075 4,045 4,016 3.986
0 4,579 4,546 4,513 4,480 4,448 4,416 4,385 4,353 4,320 4,289

09
( pm. cm.)
100 1




0 1 2 3 4 5 6 7 8 9

0 4,579 4,613 4,647 4,681 4,715 4,750 4,785 4,820 4,855 4,890
1 4,926 4,962 4,998 5,034 5,070 5,107 5,144 5,181 5,219 5,256
2 5,294 5,332 5,370 5,408 5,447 5,486 5,525 5,565 5,605 5,645
3 5,685 5,725 5,766 5,807 5,848 5,889 5,931 5,973 6,015 6,058
4 6,101 6,144 6,187 6,230 6,274 6,318 6,363 6,408 6,453 6.498
5 6,543 6,589 6,635 6,681 6,728 6,775 6,822 6,869 6,917 6,965
6 7,013 7,062 7,111 7,160 7,209 7,259 7,309 7,360 7,411 7,462
7 7,513 7,566 7,617 7,669 7.722 7,775 7,828 7,882 7,936 7,990
8 8,045 8,100 8,155 8,211 8,267 8,323 8,380 8.437 8,494 8,551
.9 8,609 8,668 8,727 8,786 8,845 8,905 8,965 9,025 9,086 9,147

1Holborn, Scheel, Henning, W rm etabellen, B runsw ick, 1909.


59

0 1 2 3 4 5 6 7 8 9

10 9,209 9,21 9,333 9,395 9,458 9,521 9,585 9,649 9,714 9.779
11 9,844 9,910 9,976 10,042 10,109 10,176 10,244 10,312 10,380 10,449
12 10,518 10,588 10,658 10,728 10,799 10,870 10,941 11,013 11,085 11,158
13 11,231 11,305 11,379 11,453 11,528 11,604 11,680 11,756 11,833 11,910
14 11,987 12,065 12,144 12,223 12,302 12,382 12,462 12,543 12,624 12,706
15 12,788 12,870 12,953 13,037 13,121 13,205 13,290 13,375, 13.461 13,547
16 13,634 13,721 13,809 13,898 13,987 14,076 14,166 14,256 14,347 14,438
17 14,530 14,622 14,715 14,809 14,903 14,997 15,092 15,188 15,284 15,380
18 15,477 15,575 15,673 15,772 15,871 15,971 16,071 16,171 16,272 16,374
19 16,477 16,581 16,685 16,789 16,894 16,999 17,105 17,212 17,319 17,427
20 17,535 17,644 17,753 17,863 17,974 18,085 18,197 18,309 18,422 18,536
21 18,650 18,765 18,880 18,996 19,113 19,231 19,349 19,468 19,587 19,707
22 19,827 19,948 20,070 20,193 20,316 20,440 20,565 20,690 20,815 20,941
23 21,068 21,196 21,324 21,453 21,583 21,714 21,845 21,977 22,110 22,243
24 22,377 22,512 22,648 22,785 22,922 23,060 23,198 23,337 23,476 23,616
25 23,756 23,897 24,039 24,182 24,326 24,471 24,617 24,764 24,912 25,060
26 25,209 25,359 25,509 25,660 25,812 25,964 26,117 26,271 26,426 26,582
27 26,739 26,897 27,055 27,214, 27,374 27,535 27,697 27,858 28,021 28,185
28 28,349 28,514 28,680 28,847 29,015 29,184 29,354 29,525 29,697 29,870
29 30,043 30,217 30.392 30,568 30,745 30,923 31,102 31,281 31,461 31,642
30 31,824 32.007 32,191 32,376 32,561 32,747 32,934 33,112 33,322 33,503
31 33,695 33,888 34,082 34,276 34,471 34,667 34,864 35,062 35,261 35,462
32 35,663 35,865 36,068 36,272 36,477 36,683 36,891 37,099 37,308 37,518
33 37,729 37,942 38,155 38,369 38.584 38,801 39,018 39,237 39,457 39,677
34 39,898 40.121 40,344 40,569 40,796 41,023 41,251 41,480 41,710 41,942

35 42,175 42,409 42,644 42,880 43,117 43,355 43,595 43,836 44,078 44,320
36 44,563 44,808 45,054 45,301 45,549 45,799 46,050 46,302 46,556 46,811
37 47.067 47,324 47,582 47,841 48,102 48,364 48,627 48,891 49,157 49,424
38 49,692 49,961 50.231 50,502 50,774 51,048 51,323 51,600 51,879 62,160
39 52,442 52,725 53,009 53,294 53,580 53,867 54,156 54,446 54,737 55,030
40 55,324 55,61 55,91 56,21 56,51 56,81 57,11 57,41 57,72 58,03
41 58,34 58,65 58,96 59,27 59,58 59,90 60,22 60,54 60,86 61,18
42 61,50 61,82 62,14 62,47 62,80 63,13 63,46 63,79 64,12 64,46
43 64,80 65,14 65,48 65,82 66,16 66,51 66,86 67,21 67,56 67,91
44 68,26 68,61 68,97 69,33 69,69 70,05 70,41 70,77 71,14 71,51
45 71,88 72,25 72,62 72,99 73,36 73,74 74,12 74,50 74,88 75.26
46 75,65 76,04 76,43 76,82 77,21 77,60 78,00 78,40 78,80 79,20
47 79.60 80,00 80,41 80,82 81,23 81,64 82,05 82,46 82,87 83,29
48 83,71 84,13 84,56 84,99 85.42 85,85 86,28 86,71 87,14 87,58
49 88,02 88,46 88,90 89,34 89,79 90,24 90,69 91,14 91,59 92,05

, 0C (

0 I j 2 4 6
3 I 5 I 7 I 8 I 9

50 92,51 97,20 102,09 107,20 112,51 118,04 123,80 129,82 136,08 142,60
60 149,38 156,43 163,77 171,38 179,31 187,54 196,09 204,96 214,17 223,73
70 233,7 243,9 254,6 265,7 277,2 289,1 301,4 314,1 327,3 341,0
80 355,1 369,7 384,9 400,6 416,8 433,6 450,9 468,7 487,1 506,1

0 1 2 3 4 5 6 7 8 9

90 525,76 527,76 529,77 531,78 533,80 535,82 537,86 539,90 541,95 544,00
91 546,05 548,11 550,18 552,26 554,35 556,44 558,53 560,64 562,75 564,87
92 566,99 569,12 571,26 573,40 575,55 577,71 579,87 582,04 584,22 586,41
93 588,60 590,80 593,00 595,21 597.43 599,66 601,89 604,13 606,38 608,64
94 610,90 613.17 615,44 617,72 620,01 622,31 624,61 626,92 629,24 631,57
95 633,90 636,24 638,59 640,94 643,30 645,67 648,05 650,43 652,82 655,22
96 657,62 660,03 662,45 644,88 667,31 669,75 672,20 674,66 677,12 679,69
97 682,07 684,55 687,04 689,54 692,05 694,57 697,10 699,63 702,17 704,71
98 707,27 709,83 712,40 714,98 717,56 720,15 722,75 725,36 727,98 730,61
99 733,24 735,88 738,53 741,18 743,85 746,52 749,20 751,89 754,58 757,29
100 760,00 762,72 765,45 768,19 770,93 773,68 776,44 779,22 782,00 784,78
101 787,57 790,37 793,18 796,00 789,82 801,66 804,50 807,35 810,21 813,08

-

L a n g e (H andbook of H and book of C hem ical D ata, N ew York, 1957.
C hem istry, 10 ed., N ew York, 1961). . J. Chem. E ng. D ata, 4, 212 (1959).
. A t ,

MlO

, . ,
( ) 100 , .

, 0C


20 30 40 50 60 70 90 100

. . . NO2 0,1705 0 ,1 2 1 1
..................... NO 0,00984 0,00757 0,00618 0,0517 0,00440 0,00376 0,00324 0,00267 0,00199 0,00114

. I. -
-
. . (N H 4)2Al2(S O 4)4 ' 24 H 2O 2,1 4,99 7.74 10,94 14,88 20,10 26,70 109,795
. A l2(S O 4) 3 1820 31,2 33,5 36,4 40,4 46,1 52,2 59,2 66,1 73,0 80,8 89,0
................ A lC l3 620 69,8615
-
. . . . (N H 4) 2Cr2(S O 4) 4 2420 10,7825
N H 4HCO3 11,9 15,8 21 27
. . . . (N H 4)2Cr2O 7 47,17
................ N H 4Br 60,6 63 75,5 83,2 91,1 99.2 107.8 116,8 126 135,6 145,6
. . . . N H 4V O3 0,48 0,84 1,32 1,78 3,05
.................... N H 4I 154.2 * 163,2* 172,3 181,4 190,5 199,6 209.9 218,7 228,8 250,3
. . . . . N H 4NO3 118.3 192 241,8 297,0 344,0 421,0 499,0 580,0 *740,0 ' 8710
................ (N H 4) 2C2O 4 H 2O 2,2 3.1 4.4 5,9 8,0 10.3
. . . (N H 4)2S 2O3 58,2
I . . . N H 4ClO4 11,56 20,85 30,58 39,05 48,19 57,01
. . . . NH 4SCN 119,8 144 170 207,7
. . . . (N H 4) 2SO 4 70,6 7 3 ,0 75,4 78,0 81,0 88,0 103,3

. . . . . . (N H 4)2H PO 4 13115

.................... N H 4H 2PO 3 171 19014*5 26031
................ N H 4Cl 29,4 33,3 37,2 41,4 45,8 50,4 60,2 65,6 77,3
,/ 71,3
. . (N H 4)2[P tC l6] 1,25
................ (N H 4) 2CrO4 40,4
-
............................ N H 4M gPO 4 620 0,023 0,052 0,036 0,030 0,040 0,016 0,019
-
.................... N H 4M nPO4 720 0.005 0,007
. . . . B a(C 2H 3O2)2 2 59 63 71
................ B a(C 2H 3O2)2 IH2O 75 79 77 74 74
. . . B a (O H )2 820 1,67* 2,48 * 3,89 * 5,59 8,22 13,12 20,94 101,4
.................... B a I2 620 170,2 185,7 203.1 219,6
..................... B a I2 220 231,9 247,3 261,0 271,7
. . . . BaCO3 0,00168 0,002218 0,002424
. . . . . B a(N O 3)2 5.0 7,0 9,2 11,6 14,2 17,1 20,3 27,0 34,2
................ B a(N O 2)2 IH2O 67,5 205,8 300
................ BaC2O4 0,00168 0,002218 0,002424
. . . B a(C lO 4) 2 3H2 205,8 289.1 358,7 426,3 495,2 562,3
. . . . B aSO 4 1,15-10" 2 ,0 -IO"4 2 ,4 -IO"4 2,85-10"4
................ B a (C lO 3)2 IH2O* 20,34 26,95 33,80 41,70 49,61 66,81 84,84 104,9
................ B aC l2 220 31,6 45 7 38,2 40,7 43,6 46,4 49,4 52,4 58,8
................. BaCrO4 0,0002 ,00028 0^00037 0,00046
. . B eSO 4 6 2 ' 52 60,67
. . . . B eSO 4 420 43,78 46,74 62 83 100
. . . . B eSO 4 220 84,76 HO
. . . . . B2O 3 1.1 1,5 2.2 4,0 6,2 9,5 15,7
. . . H 3BO3 2,66 3,57 5,01 6,60 8,72 11,54 14,81 16,73 23,75 30,38 40,25
. ........................ Br2 4,22 3.4 3,20 3,13

..................... HBr 221,2 2 1 0 ,3 1 7 1,5 130


F c ( N O 3) 2 02 7 1 ,0 2
F eS O 4 7 20 15,65
F eS O 4 3 2 .9
IH 2O
F e C l3 4 3 ,6
81,9 315,1
F e C l2 4 2 * 5 2 5 ,8 5 3 5 .7
6 4 ,5
F e C l2
73,0* 7 7 ,3 8 2 ,5 100
. . . . 12 0,04 0,056 0,078
105,3 105.8
Cd(OH)2
2,6* 10~4
. CdSO4 25
76,48 76,00 76,60 78,54
. CdCl2 H 2O 97,59 83,68 63,13 60,77
. 125,1
CdCl2 !,520 90,01
. CdCl2 132,1
H 2O 135*1* 134.5
. 135,3 . . . 136,5 140,4 147,0
Cd(CN)2
- 1,715
. KoAl2(SO4)4 2420
. KC2H 3O2 3,0 4,0 5,9 8,39 11,70 17,00 24,75
,SH2O 216.7 233,9 255.6 283,8 40,0 71,0 109,0
. . KC2H 3O2 |,520 323,3
KHCO3 . . . 337,3 350 364,8 380,1 396,3
*22,4 27,7* *33,2* *39, 45,4 60,0
KHSO4 36.3 51,4
*
KHC4H 4O6 67,3' 121,6
. 0,32 0,40 0.53 0,90 1,32 1,83 2,46
K2Cr2O7 7 12 4,6 6,95
1 220
5 20 26 34 43 52 61 70 80
97 103 112 126
H 2O
. K2CO3 220 140 178
. . 105,5 * 108 110,5* 1*13,7* 1*16,9* 121,2 126,8
KNO3 13.3 20,9 31,6 133,1 139,8 147,5 155.7
. . KNO2 45,8 63,9 85,5 110,0 138 169 202 246
278.8 238.4 334,9
KMnO4 2,83 *4,4* 6.4 412.8
K2S 2O8 1,62 2,60 4,43
9,0 12,56 16,89 22,2
K C io 4 7,19 9,89
. KSCN
0,75 1,05 1,80 2,6 4,4 6,5 9 11,8 14,8 18 21,8
177.0 217.5
. K2SO 4 * 9,22 11,11
7,35 12,97 14,76 16,50 18,17 19,75 21,4 22,8 24,1
K3IFe(CN)6] 36 43
. , KClO3
31
5
50 60 66 82,6
3,3 7.4 10,5 14 * 19,3 * 24.5 38.5
. . KCl 57


27,6 31.0 34,0 37,0 40.0 42,6 45.5 48.3
. . K2CrO4 51.1 54.0 56,7
Ca(C2H 3O2)2
58,2 60.0 61.7 63,4 65,2 66,8 68.6 70.4 72.1 73,9 75.6
220 37.4 36,0 34.7 33,8 ,2 32,7
. . Ca(C2H 3O2)2 H 2O 33.5
()2 . . . . 31.1 29.7
16,15* *16,6*0 * *17,05 * 1*7,50* *17,95 * 18,40
Ca(O H )2 0,185 0,176 0,165
. . 0.153 0,141 0,123 0,116 0,106 0,094 *0,085 0,077
Ca(NO3)2 420 102.0 115,3 121,3 152,6 195,9
. . Ca(NO3)2 2 237,5 281,5
. . Ca(NO3)2
. . Ca(NO2)2 420 363,6
62,07 76,68
. . Ca(NO2)2 220 132,6 151,9 244,8
. CaC2O4 6,7*10 * 6,8*10 *
13 25 14*10
, CaSO 4 220 0,1928 95
0,1759 0,2090 0,2097 0,2047 0,1966 0,1619
. . C aF2 0,001618 0,001726
. , CaCl3 620 * 59,5 65,0 74,5 102
. . CaCl2 220
136,8 141,7 147,0 152,7 159
M gBr2 620 *91,0 94,5* 96,5 99,2 101,6 104,1 113,7

107,5 120,2
M g(OH)2 0,000918
. . M g(N O 3)2 620 * 66,55 84,74
M gSO 4 137.0
720 30,9 35.5 40,8 45,6
. M gSO 4 620 40,8 * 42,2 44.5 45.3 50,4 53,5 59,5 64,2
. M gSO 4 69.0 74.0
IH2O 62,9
. . M gC l2 620 68,3

52,8 53.5 54.5 57,5 61,0 ' 66,0 73.0
M nSO 4 720 53,23 60,01
M nSO 4 520 59.5 62,9 67,76
M nSO 4 420 64.5 6,44 68,8 72,6
M nSO 4 IH2O 58,17 55,0 52,0 48,0
. 42,5 34,0
C u(N O 3)2 620 81,8 95,28 125,1
. Cu(NO3)2 20 159,8 178,8 207,8
C uSO 4 520 *17,4* *20,7* 25 28,5 33,3 40 55
1*4,3 75.4
CuS 3,3*10 5
18

1 ua 100 3

, 0C


10 20 30 40 50 60 70 80 90 100

. . . CuCl 1,5225
. . . . . CuCl2 220 70,7 73,76 77,0 80,34 83,8 87,44 91,2 99,2 107,9
M oO 3 220 0,138 0,264 0,476 0,687 1,206 2,055 2.106
. . A s2O5 59,5 62,1 65,8 69,5 71,2 73,0 75,1 76,7
* . . A s2S 3 5,17-10"6
18

. . . . . . . N a2H A sO 4 1220 7,3 15,5 26,5 37 47 65 85
................. N a2C2H 3O2 2 36,3 40,8 46,5 54,5 65,5 83 139
. . . N a2C2H 3O2 119 121 123,5 126 129,5 134 139,5 146 153 161 170
. . NaH C O 3 6,9 8,15 9.6 11,1 12,7 14,45 IM
. . , N a2Cr2O7 220 163,0 177,8 244,8 316,7 376,2
. . N a2Cr2O? 426,3
. . . . . N aV O 3 220 15,325 30,2 68,4
................. N aV O 3 21,1026 26,23 32,97 36,9 38,875
. . . NaOH 4 20 42
. . . NaOH 3,520 51,5
. . NaOH IH2O 103 119 129 145 174
. . . NaOH 313 342
.. . N a2CO3 IOH2O 7 12,5 21,5 38,8
.. . . N a2CO3 IH2O 50,5 48,5 46,4 45,8 43,5
. . , . N aN O 3 73 80 88 96 104 114 124 148 180
. . NaN O 2 72,1 78,0 84,5 91,6 98.4 104,1 132,6 163,2
. . . . . N a2C2O4 6,33
. N a4P 2O 7 IOH2O Ie 3,95 6,23 9,95 13,50 17,45 21,83 30.04 40,26
, IO
. . . N a2SO 4 IOH2O 5,0 9,0 19^4 40,8
. . . . N a2S O 4 720 19,5 30 44
. . . . N a 2SO 4 48,8 46,7 45,3 43,7 42,3
. . . . N a2S 9 20 15,42 18,8 22,5 28,5
.. N a2S 5,520 39,82 42,69 45,73 51.40 59,23
, . . . N a2S 6 20 36,4 39,1 43,31 49,14 57,28
.. . . N a2SO 3 720 13,9 20 26,9 36
. . . , N a2SO 3 28 28,2 28,8 28,3
. . , N a2B 4O7 IOH2O 1,3 Ifi 2,7 3,9 10,5 29,3
, , , N a2B4O7 520 24,4 31,5 41 52,5
................ N a3PO 4 1220 1.5 4,1 U 20 31 43 55 81 108

.................... N aH 2PO 4 220 57,9 69,9 85,2 106,5 138,2

N aH 2PO 4 IH2O 158,6

.................... N aH 2P O 4 179,3 190,3 207,3 223.3 246,6

. . . . . . N a2H PO 4 1220 1,67 3.6 7,7 29,8

...................., N a2H PO 4 7 20 51,8

. . . . . N a2H PO 4 2 80,2 82,9 88.1 92,4 102,9

................. Na2H PO 4 102,2
XJlOfCT . . . . , NaCUOa 79 8 !At, 126 140 155 172 189 .230
................. NaCl 35,7 35,8 36.0 36.3 36,6 37.0 37.3 37,8 3 8 .4 9 9 .0 39.8
.. .. . . N a2CrO4 IOH2O 31.70 50,17 88,7
. . . . . N a2CrO4 420 88.7 95,96 104 114,6
............... N a2CrO4 123,0 124.8 125,9
. N i(N O 3)2 620 79,58 96,31 122,2
. . . . . N i(N O 3)2 2 163,1 169,1 235,1
. . N iSO 4 720 27,22 32 42,46
. N iSO 4^ 620 50,15 54,80 59,44 63,17 76,7
. . . . . N iC l2 620 53,9 59,5 64,2 68,9 73,3 78,3 82,2 85,2 87,6
. . Sn SO 4 19 18
................. Sn C l2 . . . . 83,9 269,815
. . . . H gC l * 0,00014 0,0002 0,0007
. . . (2 30 2)2 2 55,0425
. . PbBr2 . . . . 0,4554 0,85 1,15 1,53 1,94 2,36 3,34 4,75
. . PbCO3 0,00011
. . . . . P b(N O 3)2 . . . . 38,8 48,3 56,5 66 75 85 95 115 38,8
. . . . P bSO 4 . . . . 0,0028 0,0035 0,0041 0,0049 0,0056
, . . . . . P b F 2 . . . .......................... 0,060 0,064 0,068
. . . . . PbC l2 . . . . 0,6728 .................... 0,99 1,20 1,45 1,70 1,98 2,62 3,34
. . . . . PbCrO4 7 - IO"6
. . . SO 2 . . . . 22,83 16,21 11,29 7,81 5,41 4.5
, . . A gN O 3 . . . . 122 170 222 300 376 455 525 669 952
. . . . . A g 2SO 4 . . . . 0,573 0,695 0,796 0,888 0,979 1,08 1,15 1,22 1,30 1,36 1,41
. . . . . AgCN . . . . . . . . . . .................... 2,2- IO"5
, . Sr(C2H 3O2)2 420 36,9 43,61
................ Sr(C2H 3O2)2 0,52 . . . . . . 42,95 41,6 39,5 37,35 36,24 36,10 36,4
, . . , . Sr(N O3)2 IH2O 52,7 64,0 83,8 97,2 130,4 139
................. Sr(N O 3)2 4 20 40,1 70.5
. . . . . Sr(N O 3)2 88,6 90,1 93,8 96 98 100
. . . . SrSO 4 . . . . 0,0113 0,0114 0,0114
................ SrCI2 620 43,5 47,7 52,9 58,7 65,3 72,4 81,8
. . . . . SrC l2 220 85,9 90,5 100,8
. . Sb2S 3 0,00017518
................ Sb F 3 . . . . 384,7 444,7 563,6
. , . Tl2SO 4 2,70 3,70 6,16 9,21 10,92 12,74 14.61 16,53 18,45
. . . . 4,87
. . . Th(SO4)2 9 20 0,74 0,98 1,38 1,995 2,998 5,22
. . Th(SO4)2 820 1.0 1,25 1,62
. . . . 620 1,50 2,45 6,64
Th(SO4)2 1,90
. . . . 4,04 2,54 1,63 1,09
Th(SO4)2 420
. CO2 0,0973 0,0761 0,0576 0
0,3346 0,2318 0,1688 0,1257
.................... CO 0,002! 0,0018 0,0015 0.0013 0,0010 0,0006 0
0,0044 0,0035 0,0028 0,0024
................ .... 0,451 0,386 0,324 0,274 0,219 0,125 0
C l2 1,46 0,980 0,716 0,562

.................... HCl 82,3 67,3 63,3 59,6 56,1
174,0 182,1 ..................... . . . . . . 275,5 206,8
CrO3 164,9
. . . . 9,33 14,9 23,0 33,9 47,2 64,4 83,8 107,0 134.0 163,0 197,0
C sN O 3
. . . . C s2SO 4 167,1 173,1 178,7 184,1 189,9 194,9 199,9 205,0 210,3 214,9 220,3
................ CsCl 161,4 174,7 186,5 197,3 203,0 18,5 229,7 239,5 250.0 260,1 270,5
. . . . Zn(NO3)2 6 20 94,78 ..................... 118,3
. . . . . Zn(NO3)2 2 206,9
. . * , ZnSO 4 720 41,9 47 54,4
. , , , ZnSO 4 620 70,1 76,8
. . . . ZnSO 4 IH 2O 86,6 83,7 80,8
. . . . . Zn(ClO3)2 6 20 145,0 152,5
, , . , . Zn(ClO3)2 420 200,3 209,2 223.2 273,1
64 . I. -

,
.
International Critical Tables *.
M il

( ) ( )
O-IOO0 C. - --

\ ( dp \
P0 \ d t J v*
C o p p o k, Phil. M ag. (7), 19, 446 (1935).
. J o h n s o n (ed.), WADD-TR-60-56, 1960.



, <106, , V 106. , V 106, , V 106,
. . 1 MM PT. . JKJK . . " 1 MM PT. . 1

760 3671 760 3672 760 3732 760 3719


994 3673,4 994 3674 760 3674 760 3673,5
760 3790 760 3767,8 1000 3673,3 1000 3675,7
760 3672,4 517 3668 862 3691,6 1000 3689,9
1000 3676 760 3672 1000 3696,7
* 1000 3675 1000 3739,5 1000 3720
760 3660,3 760 3662,7 760 3682 760 3679
1096 3659,0 1000 3662,6 760 3660,6 760 3662,8
760 3671,1 760 3671,6 1007 3660,2 1362,8 3662,3
1000 3674 1000 3675 760 3672 760 3673
760 3659,1 760 3661,3 760 3830 760 3673
994 3657,9 1000 3660,7 760 3734 760 3721
760 3880 760 3840
760 3725 760 3711 () 760 3870 760 3830
1000 3726 760 3735 760 3722

1-112
1
( ), M (
[ It => I0 (I -F at + /2), It -
t\ I q O0 C].

C-IO4, M-IO4, a - IO4, - 6,


, , ,
0C 1 0C "1 0C "1 "2

20 0,224 0 -5 0 0 0,22 0,009


100 0,235
300 0,284
500 0,311
20 0,014
20 0,1031
2 27 0,0444 0 -1 0 0 0,045 105-4- -502 0,0428 0,00058

* C m . Sm ithsonian P h ysical T ables, 9 ed., W ashington,, 1954, Table 142, G o l d s m i t h , Waterman, WADC-TR -58-476,
1959. - J h n s n (ed.), WADD-TR-60-56, 1960.
(300-2700 ):

l t Z308 [! +4,4* KP (t 300) + 4,5-10"10 (/-3 0 0 )2 ]

* International Critical T ables, N ew York, vol I, 1926; vol II, 1927. C m , ,


, . V, 1930.
65

C-IO4, M-IO4, -4, -10


, , ,
0C " 1 " 1 " 1 "

40 0,1210 0 -1 0 0 0,11
20 0,119 ........................ . . . . 0 -7 5 0 0,1170 0,0053
20 0,140 1 7-100 0,143 0 -5 2 0 0,142 0,0022
. . . . . . . . . 191 + 4-17 0,132
40 0,417
. . . . .................... - 1 9 0 - + 17 0,837
20 0,065 0 -8 0 0,0636 0,0032
1070-1720 0,0679 0,0011
0 0,54|| -1 8 0 -+ -1 4 0 0,59|| 2 0 -1 0 0 0,526||
0 0,201 -1 8 0 - - 140 0,1171 2 0 -1 0 0 0,2141
. . . . .................... 0 -5 0 0,83
20 0,123 * . . . 6 -1 2 1 0,121 0,064
40 0,0763 - 3 + + 18 0,0249 -7 5 + -6 7 0,0182
20 0,254 -1 0 0 -+ + 20 0,240 2 0 -5 0 0 0,2480 0,0096
.................... 2 0 -1 0 0 0,260
20 0,233 0 -1 0 0 0,228
-1 9 0 + 0 0,159 2 0 -3 0 0 0,216 0,0121
20 0,162 0 -6 2 5 0,161 0,0040
100 0,166
200 0,170
300 0,175
1 20 0,053 0 -1 0 0 0,052 - 1 4 2 + + 19 0,0515 0,0057
2 5 -1 0 0 0,049 19-305 0,0501 0,0014
2 5 -5 0 0 0,055
20 0,05
- 1 9 0 - + - 17 0,622 0 -5 0 0,72
20 0,126 0 -1 0 0 0,130 - 1 9 0 -+ + 2 0 0,1308 0,0166
2 0 -3 0 0 0,1236 0,0066
500-1000 0,1346 0,0033
20 0,214 8 -9 5 0,2033 0,0263
40 0,066
20 0,1173 -190+- + 100 0,1152 0,00517
0 -1 0 0 0 0,1167 0,0022
20 0,0887 -1 9 0 -+ -1 0 0 0,0875 0,00314
20 0,0893 0 -8 0 0,0890 0,00121
0 -1 0 0 0 0,0887 0,00132
40 0,0850 6 -2 1 0,0876 -1 1 2 + -7 5 0,0746
40 0,0963
(99,9%) 2 0 -1 0 0 0,291 100-240 0,269 0,011
100 0,291 2 0 -2 0 0 0,300
280 0,343
0 0,439 0 -1 0 0 0,660
20 0,1846 0 -1 0 0 0,197 0 -8 7 5 0,1827 0,00479
20 0,195 2 0 -5 0 0 0,1939 0,00295
20 0,114 0 -7 5 0 0,1118 0,0053
20 0,136||
20 0,0801
40 0,302
2 20 0,065 -7 8 + 0 0,099 2 0 -4 0 0 0,0646 0,0009
0 -1 0 0 0,0655

1 (300-2500 )
h ^ F + 5-"6 ( / - 300)+10,5-10"1 ( t - 300)2]
! (3002800 ):
It Z300H + 6,6-JO- 6 - 300) + 5,2- 10- i o (Z - 300)2]
66 . I. -

C-IO4, M -IO4, -4, -IO6,


, , ,
cC " 1 " 1 0C " 1 " 2

20 0,016||
20 0,2721

50 0,012
50 0,06
. . . . ................................... 2 0 -1 0 0 0,068 2 0 -5 0 0 0,086
1 20 0,643|| - 1 4 0 + - 100 0,656 0 -4 0 0 0,354 0,010
20 0,1251 2 0 -1 0 0 0,639||
20 0,358 2 0 -1 0 0 0,1411

1 ( ) G r n e i s e n , G o e n s , Z. P h ys., 29, 141 (1924

1-113
1
, . Vt ==V0 (I + / + / 2 + Y/3), V0
6 ; V t - /; / , . ,
, / = 20 .

a - IO3, -106. Y-IO8, -3.


/. cC
" 1 " 2 " 3 " 1 ( 20

..................................................... 0 -5 4 1,3240 3,8090 -0,87983 1,487


..................................................... 11-81 1,17626 1,27776 0,80648 1,237
......................................................... 0 -5 9 1,06218 1,87714 -0,30854 1,132
......................................................... 0 -3 3 -0,06427 8,5053 -6,7900 0,207
................................................. 0,4853 0,4895 0,505
( 0 ,8 4 6 7 ) ................ 2 4 -1 2 0 0,8994 1,396 0,955
................................. 0,6821 1,1405 -0,539 0,721
..................................................... 0 -3 3 1,4646 3,09319 1,6084 1,608
......................................................... 0 -1 0 0 0,18182 0,0078 0,18180
(10,9% ) . . 0 -3 0 0,2835 2,580 0,387
( 1 0 0 % ) .................... 0 -3 0 0,5758 -0,432 0,558

= 1 ...................................... -3 4 + +60 1,13980 1,37065 1,91225 1,218


P q 6 c = 500 ................................ 0 -5 0 0,940
P a 6 c = 3000 ................................ 0 -5 0 0,581
................................................ - 9 + + 106 0,9003 1,9595 -0,44998 0,973
(33,2% ) . 0 -3 3 0,4460 0,215 ........................ 0,455

......................................... -1 5 + +80 0,9001 0,6573 1,18458 0,902


.................................... 0 -6 1 1,1342 1,3635 0,8741 1,199
(30 . %) . . . 1 8 -3 9 0,2928 10,790 -11,87
(50 . %) . . . 0 -3 9 0,7450 1,85 0,730
(99 . %) . . . 2 4 -4 6 1,012 2,20 1,12
(24% ) . . 1 1 -4 0 0,3599 1,258 ........................ 0,410
................................ 16-107 1,0630 0,12636 1,0876 1,071

I Sm ithsonian P h y sica l T ables, 9 ed., W ashington, 1954, Table 269.


C m. C o o k , Brit. J. Appl Phys , 7, 285 (1956) H a r l o w , Phil. M ag , 7. 674 929) ( ). J o h n s o n <ea )
WADD-TR-60-56. I960 ( ). - S h e r m a n , S h e r m a n , J. Am. Chem. Soc., 50, 1119 (1928) [ ).
S a m s e n, Ann. P h y s., 9, 91 (1928) ( ).
67

a-IO3, -6, Y-IO8, C-IO3,


/,
" 1 " 2 " 3 " 1 ( 20 )

........................................................ 3 6 -1 5 7 0,8340 0,10732 0,4446 1,090


(24,396 ) . . . 1 6 -2 5 0,2695 2,080 0,353
(5,896 ) . . 18 -2 5 0,07876 4,2742 0,290
(40,996 ) . . 1 7 -2 4 0,42383 0,8571 0,458
(20,696 ) . . 0 -2 9 0,3640 1,237 0,414
............................................ 0 -6 3 1,10715 4,66473 -1,74328 1,273
. . . . 0 -7 6 1,18384 0,89881 1,35135 1,236
() . . . 15-4- + 38 1,51324 2,35918 4,00512 1,656

M 14
1
,
F2 = VrI(I-FCAZ), V2 V \ t 2 11; AZ = Z2 Zi .
( ),
.

/, 0C C-IO4, " 1 /, C-IO4, z p d '

............................................. 40 0,0354 ..................................... 20 5,88


........................................ 0 -1 0 0 0,0105 ..................................... 0 -1 0 0 0,265
........................................ 0 -1 0 0 0,3948 ......................................... 0 -1 0 0 0,8399
......................................... 0 -1 0 0 0,3550 ............................................. 13,2-50,3 2,23
........................................ 0 -1 0 0 0,4411 ..................................... 0 -1 0 0 0,5831
.................................... 40 0,168 . . . . 33,8-45,4 8,1
........................ 5 0 -6 0 1,2120
........................................ 20 4,87 (59 III) 2 0 -1 0 0 0,156
............................................ 0 -1 0 0 0,3840 ................ 0 -1 0 0 0,276
................................................ 20 1 1,1250 ................................. 0 -1 0 0 0,214
............................................ 0 -1 0 0 0,4998 ................ 0 -8 0 0,0129
........................................ 20 2,13 ..................................... 0 -1 0 9 0,3167
............................................ 0 -1 0 0 0,6889 ............................................. 0 -1 0 0 0,8928
. 1-114
2 (100530 ):
V = Vr0O -F 2,16-IO"5/ + 0,95-IO"8 Z2)
2 (130-270 ):
= V0 (1 + 8,04* IO"5/ + 5,9- IO"8 Z2)
,2 (110300 ):
V = V0 ( I -F 1,62 IO"5/ -F 0,2- IO"8/ 2)
(0 34 ):
F = F0( I -F 2,21 - IO"4/ + 0,31 IO"6/ 2)
(34150 ):
F = F 3J l + 7,40* 10"4( / 34) + 5,91 IO"6 (Z- 34)2]
2 (100-280 ):
F = F0O -F 1,60- ~5/ -F 3,2- IO"8/ 2)
3 (046 ):
F = F o( I -F 2,73- "4/ -F 0,39-10 6/ 2)
(46100 ):
F - F 46I I -F 13,10- "4(/ - 46) -F 0,62-10~6</ - 46)2]
4 (0300 ):
V = V0 [ I -F 10~8(93,6/ -F 0,7776t2- 0,003315/3 -F 0,000005244/4)]
3 (067 ):
V = Vr0O -F 2,34-10"4/ -F 0,14- IO"6/ 2)
(67160 ):
F = V67U + 5,02-10"4(/ 67) + 0,43-10 6(/ 67)2]
2 (120360 ):
F = F0( l -F 8,50- 5/ -F 3,9* IO"8/ 2)

I Sm ithsonian P h y sica l T ab les, 9 ed , W a sh in g to n , 1954, Table 268.


2 U f f e l m a n n , Phil. M ag , 10, 633 (1930).
3 S a m s o e n , Ann ph ys., 9, 83 (1928).
4 H a r l o w , Phil. M ag., 7, 674 (1929).
1 Cb
OO
).
, . . , .
, (,
M 15
,

- . , /' '. P. . 1

N2 -147,1 33,5 311 .................... CH4O 240 78,7 272


. N2O 36,5 71,7 450 ()
.................... NO -9 4 65 520 ......................................... C2H6O 126,9 52 271
. . N2O4 158 100 1785 ........................ C4H8O2 257.4 39.3 312
() . . C3H 4 128 ........................ C2H 4O2 214 59,15 349
. . C3H6O 272 . . . . C3H 4O 164.7 43.4 270
. . . C5H 12O 272 ................ C3H sS 260 42
........................ NH3 132.4 111,5 235 ........................................ Na 2543 343
........................ C7HsO 369 41.3 ............................................ Ne -228,7 25,9 484

. I. -
........................ C6H7N 426 52.4 ............................................. C3H i8 296 24,6 234
............................ Ar -1 2 2 48 531 .................... C3H 13O 385
. . . . C2H 4O 188 - . . . . C3H 18O 364
.................... C2H2 36 62 231 . . SnCl4 318.7 37 742
........................ C3H6O 235 47 268 ............................ C6H 12O3 290
. . . . C2H3N 274.7 47.7 240 ............................ C5H 12 197.2 33,0 232
........................ C6H6 288.5 47.7 304 .................................... C5H5N 344
. . . . C7H5N 426,0 41,6 ........................................ C3H8 96,8 42 4540
. BBr3 300 900 ................ C3H7Cl 230 45,2
............................ Br2 311 102 848 ................................ C3H9N 223.8 46.9
................ C6H5Br 397 44.6 486 ............................ C5H 10O2 276.2 32.9 296
-1,3 . . . . C4H6 152 42.7 245 ........................ C7H 14O2 327
............................ C4H 10 153 36,0 . V ............................ C3H6 92,3 45 4290
................ C6H 12O2 306 .................... C7H 14O2 316
. . C4H 10O 287 48,4 ................ C3H 16O2 336
- C4H 10O 265 ................ C3H8O 263,7 49,95 273
- C4H 10O 235 .................... C6H J2O2 305
. . . . C4H7N 309 37,4 ........................ C4H3O 2 264,85 40.1 309
............................ H 2O 374 218 323 . . . . C5H 12O 227.4 32.1 258
.................... H2 -239,9 12,8 31 ............................. C3H5N 291.2 41,3 241
. . . HBr 90 84 . . . . C3H6O2 339.5 53 315
. . . . HI 151 82 ............................................ Rn 104 62
. . . H2Se 138 ............................................. >1550 > 200 4 -5
............................ H2S 100.4 88,9 2860 ............................................ Sf 1040
........................ HF 230,2 ................................ CS2 273 76 441
............................ HCl - 51,4 81,6 420 ........................ 502 157.2 77,7 520
............................ HCN 183.5 53.2 200 ........................ 503 218.3 83,6 630
........................................ -140,7 37.2 350 (310) ............................................. C 10H 14O 425
........................................ C6H 14 234.8 29,5 234 ........................................ C4H4S 317 48
............................................ He -267,9 2,26 69,3 .................................... C7H9N 429 51,3
........................................ C7H 16 266.8 26,8 234 ................................ C8H7N 450
.................................... C7H 16O 365 ......................................... C7H8 320.6 41,6 292
GeCl4 277 38 ............................. C3H9N 161 41
.................................... N2H4 380 145 ......................................... T -2 2 9 ,5 20,8
.................................... D2 -234,4 17,4 ............................. C6H 15N 262 30 251
................ C 1OH22S 391 . . CCl4 283,1 45 558
........................ C8H 11N 415 35,8 ................ CO2 31,1 730 460
........................ C4H6O4 260 9,48 ........................ CO -1 3 9 35 311
............................ C 6H 15N 277 31 ................... COS 105 61
. . . C F 2C I2 1 1 1 ,5 3 9 ,5 6 555 ........................... H 4 2 3 2 1 ,6 5 7 ,2 351
. . __ . . . C 4H 11N 223,5 3 6 ,2 240 ................... C 4 H 6O 3 296 10
................ C7H 14O2 326 ...................................... C 3 H 10O 374 33,8
................ C9H JeO2 346 ......................................... C6H6O 419 60,5
. . . C5H 12S 321 ........................ * . . . COCl2 182 56 520
. . . C5H 12O 307 ........................................ PH 3 51 64 320
. . . C3H 16O2 338 . . . . P H 4Cl 49 73 226
. . . . C 6H 12O 2 303 34 282 ............................................ F2 -1 5 5 25
............................ C 4H 10 134 37 ................................ C6H5F 286 44,6 354
................ C 6H 12O 2 288 31 281 ......................................... C9H7N 520
. . . . C3H 160 2 338 ............................................. Cl2 144 76,1 573
. . . C 8H 16O 2 329 ................................ C6H5Cl 359 44,6 365
. . . C gH 18O 2 348 ................................ CHCl3 263 . . 0,51
. . C 4H 10O 265 48 () ........................ C2N2 128 59
. . . C 7H i 4O 2 319 ................................ C6H 12 281 40,4 270
. . . . C 5H 10O 2 278 38 288 ............................................ C2H6 32,1 48,8 210
C 5H 10O 2 361 ........................ C2H5Br 231 . . . 513
. . C 4H 8O 2 336 . . . 304 ................ C4H 10S2 369
C 5H 12 187,8 32,8 234 ........................ C4H 10S 283,8 39,1 279
C 3H 8O 235 53 ........................ C2H5CI 187,2 52,0 330
. . . . I2 553 .................................... C2H7N 183,2 55,5
C6H5I 448 44,6 581 ................................ C4H8O2 250,1 37,8 308
C7H 11N 340 32,2 ................................ C6H 12O2 293 30 276
. O2 -1 1 8 49,7 430 ................................ C7H 14O2 297


- . C 7H 8O 422 49,4 ........................................ C2H4 9,7 50,5 220
- . C 7H 8O 432 45 .................... C2H 4CI2 290 . . 450
n - . C 7H 8O 426 50,8 ............................ C2H 4O 192
SiF4 1,5 50 ........................ C6H 12O2 280 30 276
() S iH 4 - 3 ,5 48 ........................ C7H 140 2 315
Kr - 6 3 ,8 54.3 1100 ............................ C10H20O2 386
. . Xe 16,6 58,2 1155 ........................ C2H6S 225,5 54,2 301
C 4H 8O 2 355 302 . . . . CaH8O 164,7 43,2 270
................ CH4 - 8 2 ,5 *45,8 162 .................... C3H8S 260 42
C2H6S 229,9 54,6 305 ........................ C2H6O 243,1 61,1 275,5
CH3F 44,9 62 () C4H 10O 194,6 35,5 262,5
CH3Cl 143,1 65,8 370
. . C 3H 8O 2 224 .................................... C11H22O2 400
. CH5N 156,9 73,6
C3H6O2 233,7 46,3 325 .................................... C3H5O2Cl < 2 3 5
C5H 10O 2 281,3 34,2 300 . . . . C5H 12O 227,4 32,1 258
C6H 12O2 294 32 279 ........................ C5H 10O2 272,9 33 296,5
C5H 10O2 267,55 33,7 301 ............................ C3H6O2 235,3 46,8 323
CH4S 196,8 71,4 323
1 C m. A irerican In stitu te of P h y sics H andbook, N ew York, 1957. I n a t o m i p P a r r i s h , AEC Rept NAA-SR-62, 1950. D a u n t , H andbuch dr P hysik, Bd. 14,
B erlin , 1956. K o b e , L y n n , Chem. Rev., 52, 117 (1953). R i e d e I, Z. E lektrochem . 33, 202 (1949). Chem. Ing. T echn., 24, 353 (1952). R o w l i n s o n, J. Chem.
P h ys , 19, 831 (1951).
1-116
1

Pk. , 3!
V * 0*3/| V ,

- 1 2 .................................... CCl2F2 112 39,6 218 -2 3 ..................................... CHF3 33 47 136


- 1 3 ................................ ... CClF3 29 39 180 -12--1........................ CBrClF2 154 41,2 232
- 1 4 .................................... CF4 -4 5 36,8 139 -115.................................... CF3CClF2 60 30,8 260
- 2 2 .................................... CHClF2 97 48,5 165 - 318................................ C4F8 117 331
1 C h a p m a n, NACA Rept 1259, 1959,
70 . I. -


International Critical Tables *.
. . 1-19.
1-117
pv pv 0 760 . . 1

, 0C
,

-1 4 6 ,3 -1 3 0 -1 0 0 -7 0 -5 0 -2 5 0 20

1 0,5209 0,6319 0,7426 0,8162 0,9077 1,0000 1,0730


10 0,4873 0,6109 0,7292 0,8060 0,9010 0,9962 1,0705
20 0,3539 0,4465 0,5874 0,7130 0,7951 0,8940 0,9925 1,0690
30 0,2670 0,4005 0,5637 0,7010 0,7851 0,8886 0,9894 1,0677
40 0,3487 0,5404 0,6850 0,7757 0.8830 0,9870 1,0668
50 0,2943 0,5180 0,6716 0,7672 0,8790 0,9848 1,0669
60 0,2483 0,4970 0,6620 0,7596 0,8764 0,9840 1,0670
80 0,2986 0,4632 0,6432 0,7476 0,8700 0,9835 1,0687
100 0,4471 0,6362 0,7424 0,8676 0,9848 1,0749
200 0,6823 0,7854 0,9151 1,0355 1,1309
300 0,8053 0,8986 1,0179 1,1335 1,2293
400 0,9477 1,0334 1,1445 1,2557 1,3467
500 1,0914 1,1748 1,2798 1,3885 1,4782
600 1,2331 1,3159 1,4186 1,5214 1,6098
800 1,5111 1,5928 1,6958 1,7959 1,8817
1000 1,7783 1,8573 1,9600 2,0641 2,1481

, 0C , eC

, ,
50 100 200 300 400 50 100 200 300 400

1 1,1835 1,3669 1,7335 2,1000 2,4663 100 1,2046 1,4121 1,8111 2,1973 2,5751
10 1,1836 1,3695 1,7398 2,1083 2,4758 200 1,2742 1,4965 1,9119 2,3127 2,6971
20 1,1842 1,3728 1,7469 2,1175 2,4864 300 1,3711 1,5978 2,0216 2,4287 2,8193
30 1,1851 1,3765 1,7542 2,1271 2,4971 400 1,4870 1,7119 2,1455 2,5506 2,9450
40 1,1866 1,3805 1,7617 2,1366 2,5079 500 1,6171 1,8388 2,2708 2,6774 3,0714
50 1,1884 1,3849 1,7694 2,1462 2,5189 600 1,7473 1,9657 2,3961 2,8042 3,1977
60 1,1907 1,3896 1,7772 2,1559 2,5299 800 2,0155 2,2279 2,6557 3,0623 3,4587
80 1,1906 1,4002 1,7935 2,1755 2,5522 1000 2,2825 2,4948 2,9212 3,3203 3,7224
1 H o l b o r n , O t t o , Z. P h ys., 23, 77 (1924); 33, I (1925). V s h I , Proc. Roy. Soc., 1, 552 (1926). H 1 ,
O t t o , Z. P h y s., 38, 359 (1926). B a r t l e t t , H e t h e r i n g t o n, K v a l n e s, T r e m e a r n , J. Am. Chem. S oc., 52, 1363 (1930).

1-118
pv pv O0 760 . . 1
,
,
150 300
0 25 50 100 132,9 200 250

1 1,000 1,095 1,191 1,379 1,503 1,567 1,754 1,940 2,126


2 0,986 1,085 1,182 1,373 1,498 1,563 1,750 1,937 2,124
5 1,049 1,153 1,354 1,483 1,549 1,740 1,930 2,119
10 1,103 1,321 1,457 1,526 1,724 1,917 2,109
20 0,988 1,252 1,404 1,479 1,690 1,892 2,089
30 1,176 1,349 1,430 1,656 1,867 2,071
40 1,090 1,290 1,378 1,621 1,840 2,051
50 0,995 1,227 1,326 1,586 1,816 2,032
60 . . . 1,160 1,272 1,551 1,791 2,013
80 * . . . 1,157 1,479 1,740 1,976
100 . . . . . . ... 1,408 1,690 1,938
120 . . . . . . . . . 1,903
1 B e a t t i e , L a w r e n c e , J. Am. Chem. S oc., 52, 6 (1930)
K e y e s , J. Am. Chem. S o c., 53, 965 (1931).

* Internation al C ritical T ables, N ew York, vol. II, 1927, vol. I l l , 1928; vol. V, 192. C m. , ,
, . V , 1930.
71

, <
,

O1 10 20 30 40 50 60 70 80 90 100
__ \.

100 0,1196 0,1223 0,1250 0,1279 0,1305 0,1334 0,1373 0,1417 0,1465 0,1535 0,1606
200 0,2437 0,2457 0,2484 0,2526 0,2570 0,2628 0,2693 0,2769 0,2859 0,2963 0,3081
300 0,3533 0,3594 0,3657 0,3722 0,3796 0,3886 0,3980 0,4082 0,4190 0,4309 0,4441
400 0,4720 0,4777 0,4843 0,4913 0,4998 0,5094 0,5206 0,5322 0,5449 0,5593 0,5705
500 0,5839 0,5914 0,5995 0,6084 0,6186 0,6300 0,6419 0,6552 0 ,6 6 9 6 0,6853 0,7019
600 0,6942 0,7027 0,7113 0,7213 0,7321 0,7443 0,7576 0,7728 0,7898 0,8076 0,8261
700 0,8060 0,8137 0,8222 0,8330 0,8453 0,8608 0,8754 0,8916 0,9094 0,9279 0,9472
800 0,9171 0,9256 0,9340 0,9441 0,9564 0,9711 0,9873 1,0050 1,0243 1,0443 1,0659
900 1,0281 1,0351 1,0436 1,0544 1,0659 1,0814 1,0976 1,1168 1,1361 1,1577 1,1801
1000 1,1431 1,1489 1,1562 1,1654 1,1770 1,1917 1,2086 1,2279 1,2495 1,2719 1,2942 ,
1100 1,2557 1,2603 1,2672 1,2757 1,2873 1,3012 1,3182 1,3382 1,3606 1,3829 1,4069

. <S
,

HO 120 130 140 150 160 170 180 190 200 210

100 0,1724
200 0,3209 0,3363 0,3563 0,3845 0,4273 0,4921 . 0,5769 0,6841 0,8137 0,9680
300 0,4588 0,4760 0,4963 0,5199 0,5479 0,5798 0,6209 0,6703 0,7327 0,8114
400 0,5917 0,6097 0,6308 0,6541 0,6801 0,7090 0,7421 0,7790 0,8237 0,8700
500 0,7204 0,7404 0,7622 0,7852 0,8099 0,8369 0,8669 0,8797 0,9387 0,9788
600 0,8469 0,8677 0,8901 0,9132 0,9379 0,9634 0,9927 1,0243 1,0567 1,0922
700 0,9680 0,9896 1,0127 1,0366 1,0613 1,0875 1,1153 1,1423 1,1708 1,2001
800 1,0875 1,1107 1,1346 1,1585 1,1839 1,2102 1,2372 1,2665 1,2958 1,3266
900 1,2032 1,2271 1,2518 1,2773 1,3035 1,3297 1,3583 1,3868 1,4161 1,4477 1,4817
1000 1,3189 1,3436 1,3698 1,3961 1,4223 1,4493 1,4778 1,5056 1,5364 1,5673 1,5989
1100 1,4323 1,4585 1,4855 1,5118 1,5395 1,5673 1,5958 1,6259 1,6560 1,6861 1,7161

1 O0 C .

1-119

Z 1

, ,

, ,
0K 1 4 7 10 40 70 100 1 4 7 10 40 70 100

100 0,9782 0,9079 450 1,0001 1,0004 1,0007 1,0011 1,0050 1,0101 1,0162
150 0,9930 0,9716 0,950 0,927 500 1,0002 1,0007 1,0013 1,0018 1,0079 1,0147 1,0224
200 0,9971 0,9882 0,9792 0,9702 0,8978 0,7838 0,6917 550 1,0002 1,0009 1,0016 1,0023 1,0095 1,0174 1,0259
250 0,9986 0,9945 0,9905 0,9864 0,9476 0,9141 0,8878 600 1,0003 1,0010 1,0018 1,0026 1,0105 1,0190 1,0279
270 0,9990 0,9960 0,9930 0,9900 0,9622 0,9388 0,9208 650 1,0003 1,0011 1,0019 1,0027 1,0111 1,0198 1,0289
280 0,9991 0,9966 0,9940 0,9915 0,9679 0,9486 0,9340 700 1,0003 1,0011 1,0019 1,0028 1,0113 1,0201 1,0292
290 0,9993 0,9971 0,9949 0,9927 0,9729 0,9570 0,9454 750 1,0003 1,0011 1,0020 1,0028 1,0114 1,0202 1,0292
300 0,9994 0,9975 0,9957 0,9938 0,9773 0,9643 0,9553 800 1,0003 1,0011 1,0020 1,0028 1,0113 1,0199 1,0288
310 0,9995 0,9979 0,9963 0,9948 0,9810 0,9706 0,9637 900 1,0003 1,0011 1,0019 1,0027 1,0110 1,0194 1,0279
320 0,9996 0,9982 0,9969 0,9956 0,9843 0,9761 0,9710 1000 1,0003 1,0010 1,0018 1,0026 1,0105 1,0185 1,0265
350 0,9998 0,9990 0,9983 0,9977 0,9921 0,9888 0,9879 1100 1,0003 1,0010 1,0017 1,0025 1,0100 1,0176 1,0252
400 1,0000 0,9999 0,9999 0,9989 1,0002 1,0022 1,0057 1200 1,0002 1,0010 1,0017 1,0024 1,0095 1,0167 1,0239

1H i l s e n r a t h et al., NBS Circ. 564, 1955.


72 . I. -

1-120 1-122
pv pv 0 pv ( 3 : 1 )
760 . .1 pv O0C 760 . . 1
, , eC
, , eC
,
0 25 0 25 ,
-7 0 50 -2 5 0 25 50 100 200 300

0,5 1,0057 1,0989 6,0 0,9530 1,0531 25 0,7506 0,8251 0,9187


1,0 1,0000 1,0937 8,0 0,9360 1,0385 50 0,7593 0,8364 0,9320 1,0263 1 1291 1,2133 1,4009 1,7704 2,1323
2 ,0 0,9891 1,0841 10,0 0,9194 1,0255 75 0,7700 0,8481 0,9449
100 0,7816 0,8615 0,9601 1,0569 1,1527 1,2466 1,4377 1,8098 '2,1759
4,0 0,9708 1,0684 12,0 0,9026 1,0139 125 0,7947 0,8750 0,9760
150 0,8092 0,8901 0,9909
l S a m e s h i m a , B ull. Chem. Soc. Japan , 1,41 (1926) 200 0,8430 0,9256 1,0264 1,1273 1,2247 1,3207 1,5149 1,8912 2,2600
300 0,9180 1,0003 1,1024
400 1,0019 1,0833 1,1833 1,2864 1,3850 1,4825 1,6781 2,0601 2,4303
500 1,0897 1,1693 1,2679
600 1,1771 1,2568 1,3561 1,4564 1,5549 1,6513 1,8472 2,2278 2,5993
1-121 800 1,3531 1,4306 1,5280 1,6295 1,7259 1,8217 2,0176 2,3962 2,7684
1000 1,5264 1,6024 1,6987 1,8009 1,8966 1,9916 2,1867 2,5654 2.9352
pv pv 0C
760 . .1
1 W i e b ,


60, 2300 (1938).


G I d d , J. Am , Chem


, 0C
,

-2 3 9 ,9 207,9 183 150 100 70 50

1 0.2380 0,3297 0,4508 0,6340 0.7438 0,8170 1-123


10 . ! . . 0,2308 0,3279 0,4520 0,6377 0,7482 0,8219
20 0,0286 0,2239 0,3265 0,4541 0,6421 0,7535 0,8275 pv
30 0,0389 0,2183 0,3260 0,4564 0,6466 0,7583 0,8331 pv O0C 760 . . 1
40 0,0595 0,2144 0,3262 0,4591 0,6513 0,7642 0,8389
50 0,0717 0,2126 0,3271 0,4623 0,6562 0,7695 0,8447
60 0,2127 0,3289 0,4658 0,6613 0,7752 0.8506 . 0C
80 0,2187 0,3346 0,4740 0,6720 0,7870 0,8628
100 0,2301 0,3434 0,4839 . 0,6834 0,8003 0,8754
200 0,8640 0,9411 P - 5, 700 800 900 1000
12 200 300 400 500 600
300 0,9340 1,0112
400 1,0075 1,0832
500 1,0804 1,1568
600 1,1555 1,2301 100 1,6181 2,0829 2,5088 2,9154 3,3134 3,7078 4,0950 4,4803 4,8638
800 1,3018 1,3755 200 1,5256 2,0578 2,5252 2,9529 3,3670 3,7736 4,1719 4,5652 4,9554
1000 1,4443 1,5185 300 1,5174 2,0843 2,5685 3,0211 3,4479 3,8600 4,2614 4,6656 5,0573
400 1,5816 2,1438 2,6499 3,1177 3,5492 3,9643 4,3711 4,7750 5,1680
500 1,6943 2,2284 2,7436 3,2216 3,6630 4,0816 4,4924 4,8948 5,2843
600 1,8287 2,3343 2,8429 3,3280 3,7760 4,2032 4,6154 5,0184 5,4054
700 1,9774 2,4596 2,9536 3,4415 3,8965 4,3269 4,7425 5,1470 5,5292
, 800 2,1305 2,6025 3,0828 3,5627 4,0221 4,4519 4,8674 5,2701 5,6577
, 900 2,2843 2,7548 3,2258 3,6914 4,1475 4,5825 5,0011 5,3989 5,7803
1000 2.4372 2,9044 3,3738 3,8270 4,2790 4,7148 5,1282 5,5279 5,9067
25 0 20 50 100 200 300

1 0,9085 1,0000 1,0732 1,1830 1,3660 1,7317 2,0974 1 P r i c e , Ind. Eng. Chem ., 47, 1650 (1955).
10 0,9138 1,0057 1,0791 1.1891 1,3723 1,7380 2,1037
20 0,9187 1,0120 1,0855 1,1959 1,3792 1,7450 2,1108
30 0,9257 1,0183 1,0920 1,2027 1,3862 1,7520 2,1178
40 0,9318 1,0247 1,0985 1,2094 1,3931 1,7590 2,1249
50 0,9378 1,0309 1,1051 1,2162 1,4001 1,7660 2,1319
60 0,9441 1,0376 1,1116 1,2230 1,4070. 1,7731 2,1392
80 0,9567 1,0507 1,1249 1,2365 1,4209 1,7871 2,1530
100 0,9700 1,0639 1,1388 1,2510 1,4356 1,8042 2,1733 1*124
200 1,0383 1,1336 1,2066 1,3203 1,5071 1,8756 2,2393
300 1,1093 1,2045 1,2799 1,3915 1,5790 pv pv
400 1,1803 1,2775 1,3511 1,4635 1,6513 2,0206 2 3826 O0C 760 . . 1
500 1,2542 1,3500 1,4240 1,5357 1,7235
600 1,3272 1,4226 1,4958 1,6081 1,7955 2,1628 2,2546
800 1,4717 1,5665 1,6391 1,7512 1,9380 2,3043 2,6653 , 0C , eC
1000 1,6139 1,7101 1,7795 1,8917 2,0784 2,4568 2,8026
, ,
0 50 100 0 50 100
G r o m m e l i n , S w a l l o w , Proe. 4 Intern. C ongr. R efrig.,
I, 53 (1924). - H o l b o r n , O t t o , Z. Phys , 23, 77 (1924), 33, I
(1925).- V e s h I e, Proc. Roy. S oc., lH A , 552 (1926). - H 1-
b n, O t t o , Z. P h y s., 38, 359 (1926). - B a r t l e t t , C u p p - 1 1,0000 1,1838 1,3674 50 0,9569 1,1642 1,3630
I e s, T r e m e a r n e, J. Am. Chem. Soc., 50, 1275 (1928). B a r t 10 0,9913 1,1796 1,3661 75 0,9388 1,1571 1,3632
l e t t , H e t h e r i n g t o n, K v a l n e s, T r e m e a r n e, J. Am. 25 0,9776 1,1732 1,3644 100 0,9234 1,1520 1,3651
Chem. Soc., 52, 1363 (1930). M i c h e l s , N i j h o f f G e r v e r,
Ann. P h ys., 12, 562 (1932). W i e b e , G a d d y, J. Am. Chem. Soc., I
60, 2300 (1938).
C m. D e m i n g, S h u p e, P h vs Rev , 40, 848 (1932).
D e m i n g, D e m i n g, P h y s. R ev., 45, 109 (1934). ^ 1 H I n, 11 , Z. P h ys., 33, 1 (1925).
73

1-125 1-127

p v p v p v

0 760 pm . c m .1

,

, 16 84,95?
-7 0 50 25 25 50 100 150 200 1,033 1,0000 16,19 1,0909
1,63 0,9796 16,59 1,0834
2,25 0,9648 17,09 1,0734
1 0,7410 0,8150 0,9075 1,0000 1,0922 1.1845 1,3686 1,5525 1,7363 2,85 0,9533 17,61 1.0665
10 0,6985 0,7795 0,8803 0,9785 1,0733 1,1780 1,3595 1,5470 1,7348 3,80 0,9335 18,13 1,0561
20 0,6473 0,7402 0,8493 0,9543 1,0549 1,1590 1,3500 1,5422 1,7330 18,74 1,0477
69,9 19,36 1,0368
30 0,5910 0,6991 0,8183 0,9297 1,0373 1,1412 1,3411 1,5370 1,7311
40 0,5244 0,6547 0,7873 0,9061 1,0198 1,1275 1,3335 1,5345 1,7309 15,065 1,0251 19,40 1,0367
50 0,4425 0,6069 0,7558 0,8830 1,0034 1,1152 1,3268 1,5319 1.7307 15,425 1,0190 20,00 1,0239
60 0,3366 0,5551 0,7243 0,8607 0,9871 0,1017 1,3200 1,5292 1.7308 15,76 1,0115 20,68 1,0106
80 0,2556 0,4604 0,6651 0,8192 0,9569 1,0799 1,3098 1,5248 1,7322 16,10 1,0062 21,49 0,9969
0 0,2808 0,4088 0,6167 0,7845 0,9319 1,0624 1,3018 1,5337 1,7357 16,44 0,9966 22,24 0,9813
120 0,3175 0,4095 0,5877 0,7604 0,9126 1,0487 1,2965 1,5241 1,7414
140 0,3543 0,4304 0,5801 0,7457 0,9003 1,0399 1,2939 1,5272 1,7485
160 0,3915 0,4601 0,5891 0,7425 0,8949 1,0367 1,2952 1,7570 1-128
1,5325
180 0,4288 0,4924 0,6079 0,7482 0,8970 1,0373 1,2997 1,5398 1,7668 V %
200 0,4656 0,5269 0,6319 0,7631 0,9048 1,0437 1,3076 1,5500 1,7774 ( ) 1
250 0,5567 0,6142 0,7066 0,8184 0,9469 1,0776 1,3364 1,5867 1,8126
300 0,6458 0,7025 0,7879 0,8886 1,0062 1,1286 1,3785 1,6234 1,8534
400 0,8185 0,8750 0,9561 1,0468 1,1499 1,2608 1,4929 1,7268 1,9586 , !
500 0,9867 1,0433 1,1221 1,2086 1,3064 1,4106 1,6277 1,8542 2,0903
600 1,1487 1,2071 1,2862 1,3709 1,4659 1,5653 1,7729 1,9935 2,2131 .
800 1,4631 1,5246 1,6046 1,6894 1,7801 1,8781 2,0744 2,2828 2,4949 0.5 1,0 1,5 2,0 2,5 . 3,5 4.0 4.5 5,0
1000 1,7656 1,8287 1,9110 2,0000 2,0892 2.1845 2,3757 2,5797 2,7861

a I ,
1 K e y e s , S m i t h , J o u b e r t, J. M ath. P h y s., 1, 19 T 50 12,24 22,58 31,24 38,41 44,27 49,02 52,87 55,97 58,49 60,56
(1922). - K v a l n e s l G a d d y , J. Am. Chem. S oc., 53, 394 (1931). 75 13,34 24,95 35,08 43,80 51,37 57,98 63,78 68,89 73,52 77,79
100 14,43 27,28 38,79 49,03 58,29 66,68 74,36 81,50 88,25 94,73
( 1675 300) 125 15,52 29,64 42,49 54,25 65,13 75,26 84,81 93,91 102,73 111,46
. . . , . . , , 150 16,60 31.89 46,08 59,31 71,78 83,61 94,99 106,06 117,00 127,98
18, 380 (1944). - < 60 . 175 17,67 34,17 49,66 64,36 78,40 91,93 105,13 118,16 131,20 144,41
M i c h e l s , N e d e r b r a g t , P h ysica, 6, 656 (1939). 200 18,71 36,44 53,25 69,38 84,97 100,19 115,20 130,18 145,30 160,77
225 19,80 38,64 56,73 74,27 91,38 108,24 125,02 141,90 159,08 176,73
250 20,89 40,87 60,23 79,16 97,81 116,30 134,84 153,59 172,87 192,77

- , /

1-126 ,
5,5 6,0 6,5 7,0 7,5 8.0 9,0 10,0
p v p v
O0C 760 p m . cm . ,
50 62,40 63,99 65,52 67,08 68,82 70,88 76,90 87,76
75 81,97 85,95 90,00 94,29 99,01 104.38 118,32 139,23
, 100 101,36 107;86 114,60 121,83 129,74 138,64 160,77 191,98
125 120,56 129,64 139,19 149,41 160,60 173,10 203,63 144,97
, 150 139,68 151,38 163,70 176,99 191,52 207.66 146.57 298,02
70 50 25 0 25 50 109 150 200 175 158,68 172,98 188,20 204,54 222,44 242,24 289,49 350,95
200 177,62 194,53 212,59 232,03 253,29 276,76 332,56
225 196,44 215,98 236,88 259,42 284,02 311,09
1 0,7427 0,8162 0,9082 1,0000 1,0918 1,1836 1,3671 1,5504 1,7336 250 215,21 237,38 261,13 286,74 314,67 345.38
10 0,7275 0,8061 0,9025 0,9960 1,0885 1,1830 1,3700 1,5565 1,7423
25 0,7115 0,7947 0,8960 0,9912 1,0858 1,1827 1,3735 1,5630 1,7510 1 B e a t t i e , H a n d l o c k , P o f f e n b e r g e , J. Chem
30 0,6950 0,7840 0,8895 0,9868 1,0836 1,1820 1,3769 1,5695 1,7595 P h ys 3, 93 (1935) a t 1 1 , S u, S i in d, J. Am. C hem .
40 0,6792 0,7730 0,8833 0,9825 1,0820 1,1821 1,3800 1,5755 1,7683 S o c 1 61. 926 (1939).
50 0,6636 0,7622 '0,8768 0,9780 1,0814 1,1826 1,3837 1,5823 1,7758
60 0,6495 0,7550 0,8712 0,9755 1,0810 1,1842 1,3878 1,5880 1,7833
80 0,6274 0,7355 0,8620 0,9718 1,0820 1,1893 1,3967 1,6008 1,7935 1-129
100 0,6147 0,7264 0,8592 0,9725 1,0851 1,1955 1,4062 1,6151 1,8146 p v p v
120 0,6110 0,7240 0,8590 0,9763 1,0917 1,2042 1,4176 1,6288 1,8310
140 0,6142 0,7270 0,8627 0,9832 1,1009 1,2139 1,4312 1,6450 1,8492 0 760 pm . c m . 1
160 0,6255 0,7355 0,8715 0,9935 1,1125 1,2255 1,4456 1,6620 1,8683
180 0,6431 0,7485 0,8856 1,0125 1,1255 1,2400 1,4615 1,6792 1,8883 ,
20 J 0,6631 0,7656 0,9022 1,0200 1,1415 1,2561 1,4794 1,6987 1,9090
250 0,7247 0,8205 0,9520 1,0665 1,1885 1,3022 1,5280 1,7500 1,9632 ,
0,7955 0,8872 1,0087 1,1211 1,2408 1,3521 1,5798 1,8054 2,0183
400 0 20 40 60 80 100
0,9434 1,0285 1,1403 1,2487 1,3625 1,4716 1,6963 1,9178 2,1380
500 1,0920 1,1755 1,2831 1,3843 1,4940 1,6023 1,8235 2,0450 2,2627
1,2386 1,3225 1,4282 1,5256 1,6317 1,7378 1,9557 2,1757 2,3923 50 0,1755 0,6290 0,8140 0,9535 1,0770 1,1920
800 1,5236 1,6100 1,7153 1,8064 1,9115 2,0144 2,2214 2,4442 2,6602 0,3600 0,4705 0,6680 0,8465
100 0,3100 1,0050
1000 1,7992 1,8871 1,9935 2,0827 2,1857 2,2879 2,4935 2,7142 2,9264 150 0,4850 0,5505 0,6490 0,7760 0,9240
0,4405
200 0,5650 0,6095 0,6690 0,7440 0,8380 0,946 J
300 0,8055 0,8520 0,9075 0,9720 1,0475 1,1380
1 B a r t l e t t , H e t h e r i n g t o n, K v a l n e s, T r e m e - 500 1,2555 1,3075 1,3670 1,4310 1,5000 1,5775
n , J. Am. Chem. S o c., 52, 1374 (1930). G o i g , Compt. rend., 1000 2,2890 2,3535 2,4215 2,4925 2,5660 2,6425
189, 246 (1929).- S t t, Proc Roy Soc., 122, 283 (1929).
. P h y s. Re v ., 38, 2245 1 C m Michels, DeGruyter, Ni l s e n , Phy-
(1931); 45, 109 (1934). s i c a , 3 , 3 4 6 (1 9 3 ).
. I. -

I dy
3 -----^
Vo
, . i
( > 1000 ).

, HlM2 -1011, (12 t, P-IO"5, !2

17 32
20 500
23 111 20
500 61 1000
20 12 000 8
1000 52 15
12 000 9 23 103
20 200 95
5 89 20 400 80
200 77 20 500 65
400 67 20 1000 54
20 12 000 8
13 49 20
49 200 77
200 20
41 400 67
400 20 500
500 39 65
38 20 1 000 47
500 20 12 000
1000 33 7
9 14 23 100
12 000 20 500 63
300 3,97 20 1000 54
20 12 000 8
1000 34
2 000 24 20 200 74
500 20 400 64
55
1 000 45 10 250 71
12 000 8 20 500 63
20 1000 47
200 69 20 8
400 12 000
60
20 200 83
20 400 70
5 46
5 51 13 23 [03
5 53 20 200 90
5 55

59 20 200 100
300 3,95 20 400 82
500 3,97 20 500 70
1 000 3,91 20 1000 54
12 000 2,37 20 12 000 8
20 200 81
21 86 20 400 69
500 57 20 64
1 000 500
48 20 1000 50
12 000 6 20 12 000 8
15 23 151
20 500 102
23 88
500 61 20 1000 66
1 000 46 20 12 000 8
12 000 8 25 23 [88
12 000 8 (- 20 500 84
200 84 ) 20 1000 61
400 70 20 12 000 10
8 97
200 81
400 64
75


1-131

L njl L ncn
( ). , .
.
U. S. Bur. M ines B ull., 383 (1935); 393 (1936).
Cm. S c o t t , C ryogenic E n g in eerin g , P rin ceton , New York, 1959 ( T 1,5 - 4,2 ,
7 = 6 0+ 126 , = 67 + 155 ) . J o h n s o n (ed.), WADD-TR-60-56, 1960 ( , ,
, , , , ). Am erican Institute of P h ysics Handbook, N ew York, 1957.

W ^ * ^ W ^ * ^*
/ / / !


1 336 (.)
N2 .................... -210,0 172 -195,8
NF3 ................ -129,0 3 000 BiCl3 ................ 224 2 600 441 17 350
NH31 . . . . -7 7 ,7 1 352 -3 3 ,4 5 581 Bi2O3 . . . . 817 6 800
NH4SCN . . . 146 (4 700) Bi2S5 ................ 747 8 900
NH4NO3 . . . -169,6 1 460
N2O ................ -9 0 ,8 1 563 -8 8 ,5 3 950
N O ................ -163,6 550 -151,7 3 307 H2 .................... -259,2 28 -2 5 2 ,7
N2O4 ................ -1 3 5 540 30 7 040 216
H B r ................ -8 6 ,9 575 -6 6 ,7 4210
NjO5 ................ 32,4* 13 800* H C l ................ -114,2 476 -8 5 ,0
NOCl . . . . 6,4 6 140 3 860
HCN4 . . . . -1 3 ,2 2 009 25,7 6 027
H F .................... -8 3 ,0 1094 33,3 7 460
(HF)6 . . . . 51,2 5 020
A l .................... 660 2 550 2 057 61 020 H I .................... -5 0 ,8 * 686
Al2Br6 . . . . 97,5 5 420 256,4 10 920 H2O ................ 0,0 1 436 100,0 9 729 6
Al2Cl6 . . . . 192,5 16 960 180*2* 26 750* H 2O(D2O) . . 3,8 1 501 5 101,4
AlF3 3NaF . . 1000 16 380 9 9457
191 7 960 385,5 H2O2 ................ -2 2 520 158 10 270
Al2I6 ................ 15 360
Al2O3 . . . . 2045 (26 ) 3 000 HNO3 . . . . -4 7 600
H3PO2 . . . . 17,4 2 310
Ar -189,3 290 -185,8 1 590 H3PO3 . . . . 74 3 070
H3PO4 . . . . 42,7 2 520
H4P2O6 . . . . 55 8 300
Ba 2 ................ 704 (1 400) 1638 35 670 H2S 6 ................ -8 5 ,5 568 -6 0 ,3 4 463
BaBr2 . . . . 847 6 000 H 2S2 ................ -8 7 ,6 1805
BaCl2 . . . . 960 5 370 H2SO4 . . . . 10,5 2 360
BaF2 ................ 1287 3 000 H2S e ................ . . . . ................ -4 1 ,3 4 880
Ba(NO3)2 . . . 595 (5 900) H2SeO4 . . . . 58 3 450
Ba3(PO4)2 . . 1730 18 600 H2T e ................ -4 8 ,9 1670 - 2 ,2 5 650
BaSO4 . . . . 1350 9 700

W .................... 3 390 (8 400) (5 900) (176 000)
BBr3 ................ 91,3 7 300 WF6 ................ -0 ,4 1 800 17,3 6 350
BCl3 ................ 12,5 5 680
BF3 ................ -1 2 8 480 -100,9 4 620 Ga 29,8 1336 2 071
B2H6 ................ -165,5 -9 2 ,4 3 685 He -271,4
B3H10 . . . . 16 -268,4 22
-119,8 6 470
B5H9 ................ -4 6 ,9 58 7 700
B5H11 . . . . 67 8 500
B10H14 . . . . 99,7 7 800 C m. 3 11 600 G e .................... 959 (8 300)
B2H5B r. . . . -1 0 4 16 6 230 GeBr4 . . . . 26,1 189 8 560
B3N3H6 . . . . -5 8 50,4 7670 GeCI4 . . . . -4 9 ,5 84 7 030
Ge(CH3)4 . . . -8 8 44 6 460
Ge H4 . . . . . -1 6 5 -8 9 ,1 3 580
B i .................... 271,3 2 505 1 420 Ge2H6 . . . . -1 0 9 31,4 5 900
BiBr3 . . . . 461 18 020 I Ge3H8 . . . . 105,6 110,6 7 550
I GeHCI3 . . . -7 1 75 9 8 000
' O v e r s t r e e t , G i a u q u e, J. Am. Chem. Soc., 59, 254 (1937).
2 B i c h o w s k y , R o s s i n i , T erm ochem istry of the Chem ical S u b sta n ces, New York, 1936.
3 .
4 G i a u q u e , R u e h r w e i n , J. Am. Chem. Soc., 61, 6226 (1939).
5 L o n g , K e m p , J. Am. Chem. S oc., 58, 1829 (1936).
6 O s b o r n e , S t i m s o n, G i n n i n g s, J. Res. Nat. Eur. Stand., 23, 197, 261 (1939).
7 M i l e s , M e n z i e s, J. Am. Chem. Soc., 58, 1067 (1936).
8 G i a u q u e , B l u e , J. Am. Chem. S oc., 58, 831 (1936).
1 / = 4O0 C; .
76 . 1. -

W ^ * ^HCIT W ^ *1
1 / KKaAfKMOAb KKaAlKMOAb


F e .................... 1530 3 560 2 735 84 600 O2 .................... -2 1 8 ,9 106 -1 8 3 ,0 1 629
FeCl2 . . . . 677 7 800 1 026 30210 O3 . . . . . . -1 1 1 2 880
Fe2Cl6 . . . . 304 20 590 319 12 040
Fe(CO)5 . . . -2 1 3 250 105 9 000
F e O ................ 1380 (7 700) 1490
C o .................... 3 660
F e S ................ I 195 5 000 727 7 390 27 170
CoCl2 . . . . 1050
Au 1063,0 3 030 2 966 81 800
In 781
156,4
S i .................... 1427 9 470 2290
SiCl4 . . . . . -6 7 ,6 1845 56,8 6 860
I2 .................... 113,0 3 650 183 10 390 Si2Cl6 . . . . -1 ................ 139
G -IC l................ 17,2 2 660 Si3Cl8 . . . . . . . . ................ 211,i 12 340
- I C l................ 13,9 2 270 (SiCl3)2O . . . -3 3 ................ 135,6 8 220
IF7 .................... 4* 7 460* SiF4 ................ . . . . -94,8* 6 130*
11 ....................... -1 8 ,5 3 900 -18,9* 10 400*
Si2F6 . . . . .
SiF3Cl . . . . -1 3 8 ................ -7 0 ,1 4 460
SiF2Cl2 . . . . -1 4 4 -3 1 ,5 5 080
Cd . . . . . . 320,9 1 460 765 23 870 SiH 4 ................ -185 2 960
-1 11,6
CdBr2 . . . . 568 (5 ) Si2H6 . . . . -1 3 2 ,5 . . .. . -1 4 ,3 5110
CdCl2 . . . . 568 5 300 967 29 860 Si3H8 . . . . -1 1 7 6 780
53,1
CdF2 ................ I 100 (5 400) -9 3 ,5 100 8 890
CdI2 ................ 387 3 660 796 25 400 Si4H j0 *
SiH3Br . . . . -9 3 ,8 ................ 2,4 5 650
C d O ................ 1 559* 53 820* -7 0 ,0 70,5 6 840
4 790 SiH2Br2 . . .
CdSO4 . . . . 1 SiHCl3 . . . . - 126,5 . . . 31,8 6 360
(SiH3)3N . . . -105,6 ................ 48,7 6 850
(SiH 3)2O . . . -1 4 4 . . . . . -1 5 ,4 5 350
.................... 63,5 574 776 18 920 SiO2 () . 1470 3 400 2 230
KBO2 . . . . 947 (5 700) SiO2 (-
K B r ................ 742 5 000 1 383 37060 ) . . . 1 700 2 100
K C l ................ 770 6410 1 407 38 840
KCN . . . . . 623 (3 500) Kr -1 5 7 360 152,9 2310
K2CO3 . . . . 897 7 800
K2CrO4 . . . . 984 6 920 Xe -111,5 740 -108,0 3 110
K2Cr2O7 . . . 398 8 770
K F .................... 857 6 500
K I .................... 682 4 100 1324 34 690
K2MoO4 . . . 922 (4000) L i .................... 179 1 100 1372 32 250
KNO3 . . . . 338 2 840 LiBO2 . . . . -845 (5 570)
K O H ................ 360 (2 ) 1 327 30 850 L i B r ................ 552 2 900 1310 35 420
KPO3 . . . . 817 2 110 L i C l ................ 614 3 200 1382 35 960
K3PO4 . . . . 1340 8 900 L i F ................ 847 (2 360) 1681 50 970
K4P2O7 . . . . 1092 14 000 L i I .................... 440 (1 420) 1 171 40 770
KSCN . . . . 179 2 250 LiOH . . . . 462 2 480
K2SO4 . . . . 1 074 8 100 Li2MoO4 . . . 705 4 200
K2TiO3 . . . . 810 (10 600) Li2SiO3 . . . . 1 177 7210
K2WO4 . . . . 927 (4 400) Li4SiO4 . . . . 1249 7 430
Li2SO4 . . . . 857 3 040
Li2WO4 . . . 742 (6 700)
C a ..................... 851 2 230 1487 36 580
CaBr2 . . . . 730 4 180
CaCO3 . . . . 1282 (12 700)
CaCi2 . . . . 782 6 100 Mg 650 2 160 1 107 32 520
CaF2 ................ 1392 4 100 MgBr2 . . . . 711 8 300
Ca(NO3)2 . . . 561 5120 MgCl2 . . . . 712 8 100 1 418 32 690
C a O ................ 2 707 (12 240) MgF2 ................ 1221 5 900
CaO A l2O3 -2 S i0 2 1 550 29 400 M g O ................ 2 642 18 500
CaO -M gO 2 S i0 2 1 392 (18 200) Mg3(PO 4)2 . . 1 184 (11 300)
CaO SiO2 . . 1 512 13 400 MgSO3 . . . . 1 524 - - 14 700
CaSO 4 . . . . 1 297 6 700 MgSO4 . . . . 1 127 3 500
MgZn2 . . . . 589 (8 270)
I
77

A .T
* - /
* A crr
!
.W ^m r
!
* *
/

Mn .................... 1220 3 450 2 152 55 150 Sn4 ................ 2 3 1 ,8 1 720 2 270 68 000
MnCl2 . . . . 650 7 340 1 190 29 630 SnBr2 . . . . 232 (1 7 0 0 )
MnSiO3 . . . 1274 (8 2 0 0 ) SnBr4 . . . . 30 3 000
MnTiO3 . . . 1 404 (7 960) SnCl2 . . . . 247 3 050 623 20 740
SnCl4 . . . . -3 3 ,2 2 190 113 8 330
Sn(CH3)4 . . . 78,3 7 320
C u .................... 1083,0 3 HO 2 595 72 810 SnH 4 ................ -149,8 52,3 4 420
1 355 16310 S nI4 ................ 143,5 * (4 300)*
Cu2Cl2 . . . . 430 4 890 1 490 11 920
Cu2(CN)2 473 (5 400)
1336 OsF8 ................ 47,4 6 840
C u l ................ 15910 56 4 060 9 450
Cu2O ................ *1 *230 * *(1*3 400)* OsO4 () 130
1 447 O sO 4 () . 42 2 340
C u O ................ 2 820
Cu2S ................ 1 127 5 500 1 554 4 120
Pd

Pt 1773,5 4 700 (4 400) (107 )
M o .................... 2 622 (6 660) (4 800) (128 )
MoF6 ................ 17 2 500 36 6 000 -
MoO3 . . . . 745 (2 500) 1 151 M Pr 932 2 700
Rn -71 -6 1 ,8 4010

A s .................... 814 (6 620) 610* 31 000* P
AsBr3 . . . . 31 2810 R e .................... (3 )
AsCl3 . . . . - 16 2 420 122 7 570 Re2O7 . . . . 296 15 340 362,4 18 060
AsF5 ................ -8 0 ,7 2 800 -5 2 ,8 4 980 Re2O8 . . . . 147 3 800
As4O6 . . . . 313 8 000 457,2 14 300 P
R b .................... 39,1 525 679 18110
N a .................... 914 R b B r ................ 677 3 700 1 352 37120
97,7 630 23 120 36 920
NaBO2 . . . . 966 8 660 R b C l................ 717 4 400 1 381
N aB r................ 747 6 140 1 392 R b F ................ 833 4 130 1 408 39 510
37 950 R b I ................ 35 960
N aC l................ 800 7 220 1 465 40 810 638 2 990 1304
NaClO3 . . . 255 5 290 RbNO3 . . . . 305 1 340
NaCN . . . . 562 (4 400) 1 500 37280
Na2CO3 . . . 854 7 000 P b .................... 327,4 1 224 1 744 42 060
N a F ................ 992 7 000 1 704 ' 53 260 PbBr2 . . . . 488 4 290 914 27 700
NaI . . . . . 662 5 240 PbCl2 . . . . 498 5 650 954 29 600
Na2MoO4 . . . 687 3 600 PbF2 ................ 824 1 860 1 293 38 300
NaNO3 . . . . 310 3 760 PbI2 ................ 412 5 970 872 24 850
NaOH . . . . 322 2 000 1378 PbMoO4 . . . 1 065 (25 800)
V2Na2O-1AAl2O 3-SSiO2 I IU / 13 150 P b O ................ 890 2 820 1 472 51310
JNaFO3 . . . . 988 (5 000) P b S ................ (50 000)
1 114 4 150 1281
Na4P2O7 . . . 970 (13 700) PbSO 4 . . . . 1 087 9 600
Na2S ................ 920 (1 200) PbWO4 . . . . 1 123 (15 200)
NaSCN. . . . 323 4 450
Na2SO4 . . . . 884 5 830
Na2SiO3 . . 1087 10 300 S (
Na2Si2O5 . . . 884 8 460 ) . . . . 112,8 2 200
Na2WO4 . . . ................ 444,6
702 5 800 S (
Ne -248,5 77 -246,0 440 ) . . . . 119,2
S2Cl2 ................ 138 8 720
SF6 ................ -63,5* 5 600*
N i .................... 1 455 4 200 2 730 87300 SO2 1 ................ -7 5 ,5 1769 -5 ,0 5 960
NiCl2 . . . . 987* 48 360* Ct-SO3 . . . . 17 2 060 44,8 10 190
Ni(CO)4 . . , 42,5 7 000 -so3 . . . . 32,4 2 890
Ni2S ................ 645 (2 980) Y-SO3 . . . . 62,2 6310
Ni3S2 ................ 790 5 800 SOBr2 . . . . 139,5 9 920
SOCl2 . . . . 75,4 7 600
SO2Cl2 . . . . 69,2 7 760

1Glauque, Stephenson, J. Am. Chem. Soc., 60, 1389 (1938).


78 . I. -

^ ^
! ! ! /


960,5 2 700 2212 60 720 (.)
Ag . .
AgBr . 430 2 180 CNI . . . . 141* 13 980*
AgCl . 455 3155 1564 42 520 CO. . . . . -205,0 200 -191,5 1 444
AgCN 350 2 750 CO2 ................ -5 6 ,5 : 900 -78,4* 6 030*
AgI . 557 2 250 1 506 34 450 COCl2 . . . 8,0 5 990
AgNO3 209 2 755 COS3 . . . -138,8 1 129 -5 0 ,2 4 423
Ag2S . 842 3 360 112,0 1 049
Ag2SO4 657 (4 300)

UF6 ................ 55, V 9 990*
Sr . . . 757 2 190 1384 33 610
SrB r2 643 4 780 P () . . 44,2 615 280 12 520
SrCl2 . . 872 4 00 P () 417* 25 600*
S rF 2 . . 1 400 4 260 P () . . 453* 33 IOOil
Sr3(PO 4)2 1770 18 500 PC l3 ................ 74,2 7 280
PH 35 ................ -133,8 270 -8 7 ,7 3 489
P 4O5 ................ 23,8 3 360 174 10 380
O-P4O 10. . . . 569 17 080 591 20 670
Sb . . 630,5 4 770 1 440 46 670
97 P-P4O 10. . . . 358*
SbBr3 3510 POCl3 . . . . 3 HO 105,1 8 380
SbCl3 73,4 3 030 219 10 360
11570 P2S3 ................ 508
SbCl5 4 2 400 ^ 172 1
Sb4O5 655 (27 000) 1 425 17 820
Sb4S5 546 11200
F2 . -2 2 3 -188,2 1640
F2O -144,8 2 650
Tl . . 302,5 1 030 1 457 38 810
TlBr . 460 5 990 819 23 800 1 531 4 878
807 Cl2 6 . -101,0 -34,1
TlCl . 427 4 260 24 420
ClF . -1 0 1
Tl2CO3 273 4 400 11,3 5 890
440 3125 823 25 030 ClF3 .
TH . . Cl2O . 2,0 6 280
TlNO3 207 2 290 7100
ClO2 . 10,9
Tl2S . 449 3 000 Cl2O7 79 8 480
Tl2SO4 632 5 500

T
C s .................... 28,4 500 690 16 320
T e ................ 453 3 230 1 090 C s B r ................ I 300 35 990
TeCl4 . . . 392 16 830 C s C l ................ 642 3 600 1300 35 690
TeF6 . . . . -38,6* 6 700* C s F ................ 715 (2 450) I 251 34 330
CsI ................ I 280 35 930
CsNO3 . . . . 407 3 250
TiBr4 . . . . 38,2 (2 060) Ce 775 2 120
TiCl4 . . . . -2 3 2 240 136 8 350
TiO2 . . . . 1 825 (11 400)
Z n .................... 419,5 1 595 907 27 430
ZnCl2 . . . . 283 (5 500) 732 28 710
() 3 600 11000 Zn(C2H5)2 . . 118 8 960
CBr4 90 1 050 Z n O ................ 1 975 4 470
CCl4 -2 4 ,0 644 77 7 280 Z n S ................ 1 645 (9 000)
CF4 -127,9 3 HO
CH4 -182,5 224 -161,4 2 040
C2N2 2 -2 7 ,8 1938 -21,1 5 576 ZrB r4 . . . . 357* 25 800*
CNBr 52 11 010 ZrCl4 . . . . 311* 25 290*
CNCl -5 2 240 *13 * 6 300 Z rI4 ................ 431* 29 030*
CNF -72,8* 5 780* ZrO2 ................ 2 715 20 800

1 / = 75 ; .
2 R u e h r w e i n , G i a u q u e , J. Am. Chem. S o c ., 61, 2940 (1939).
8 K e m p , G i a u g u e , J. Am. Chem. Soc., 59, 79 (1937).
4 B r o w n , M a n o v , J. Am, Chem. S o c., 59, 500 (1937).
6 S t e p h e n s o n , G i a u q u e , J. Chem. P h y s., 5, 149 (1937).
6 G i a u q u e , P o w e l l , J. Am. Chem, S o c,, 61, 1970 (1939).
79

1-132
//
, .
.

*. W **
/ /

................ C8H i0 94,950 20,629


- ........................ C8H 10 25,187 30,614
182,48 14,03 +........................ C8H 10 47,872 26,045
................................ CH4
183,23 22,712 /- ........................ C8H 10 13,263 38,526
................................ C2H6
187,65 19,100 . . . . C9H 12 99,500 16,97
............................ C3H8
138,33 19,167 . . . C9H 12 96,028 19,22
................................ C4H 10
159,60 18,668 1--2- C9H 12 80,833 21.13
2- . . . . C4H 10
129,723 27,874 1--- C9H 12 95,55 15.14
............................ C5H 12
159,890 17,076 1--4- C9H 12 62,350 25,29
2- ................ C5H 12
C5H 12 16,6 10,786 1.2.3- CgH12 25,375 16,64
2,2- . .
95,320 36,138 1.2.4- CgH12 43,80 24,54
............................ C6H u
153,680 17,407 1,3,5- CgH12 -4 4 ,7 2 18,97
2- . . . . C6H i4
99,73 1,607 .................... C 10H8 80,0 36,0
2,2- . . . C6H j4
128,41 2,251 ............................ C 10H 14 79,3 37,0
2,3- . . . C6H u
90,595 33,513 .................... C10H i4 24,0 23,0
............................ C7H 16
118,270 21,158 .................... C10H 14 - 7 ,7 20,0
2-................ C7H 16
- ................ C7H 16 118,593 22,555 /- ......................... C10H 14 68,9
123,790 13,982 ................ C 10H 14 88,5 19,5
2,2- . . . C7H 16
119,230 15,968 - . . . C 10H 14 58,1 14,9
2,4- . . . C7H 16
134,46 16,856 ........................ C 10H 16 51 57,0
3,3- . . . C7H 16
2,2,3- . . 24,96 5,250 - . . Cn H 10 34,1 20,1
C7H 16
56,798 43,169 ......................... C 12H 10 68,1 28,8
............................ C8H 14
109,04 21,458 . . C12H 18 165,5 30,4
2- . . . . C8H 18
120,50 23,795 . . . . C13H 12 25,2 26,4
- . . . . C8H 18
120,955 22,692 .................... C 14H 10 216,5 38,7
4- . . . . C8H 18
121,18 24,226 ..................... C14H 10 96,3 25,0
2,2- . . . C8H 18
91,200 26,903 ............................. C14H 10 60 28,7
2,5- . . . C8H 18
126,10 14,9 ......................... C 14H 12 124 40,0
3,3- . . . C8H 18
2--- 114,960 23,690 ................ C i4H 14 51,4 30,7
C8H 18
--- 90,870 22,657 . . C19H 16 92,1 21
C8H 18
2,2,3- C8H 18 112,27 18,061 -
2,2,4- C8H 18 107,365 19,278
2,3,3- C8H 18 100,70 3,204 ................ C6H 12 6,67 7,569
2,3,4- C8H 18 109,21 19,392 . . C7H 14 126,58 16,429
2,2,3,3- C8H 18 100,69 14,900
53,9 41,2 -
............................ CgH2O
................................ C 10H22 30,0 48,2
................. C6H 10 93,80 2,068
............................. C 11H24 25,9 34,1
. . C6H 12 142,445 19,68
........................ C12H26 9,6 51,3
. . . C7H 14 138,435 11,10
............................ C20H42 36,4 52
1,1- -
.................... C25H52 53,3 53,6 . . . C7H 14 69,73 3,36
. . . . C33H68 71 54 -1,2--
........................ C7H 14 53,85 3,87

-1,2- -
.................... C7H 14 117,57 15,68
............................ C6H6 5,533 30,1 -1,3--
............................ C7H8 94,991 17,171 ..................... C7H 14 133,680 17,93
80 . I. -


AH
AH
n Zint
* / ' !

- . . . C6H4BrCl 21,2 15,29


() ................ C2H 4 169,15 28,547 /- . . . C6H4BrCl 64,6 23,41
() . . C3H6 185,25 17,054 . . . C4H 10O 89,2 29,93
-1 ............................. C4H8 185,35 16,393 - C4H 10O 25,4 21,88
- - 2 .................... C4H8 138,91 31,135 ........................ C8H 10O2 *22,5 27,45
- - 2 ................ C4H8 105,55 41,564 . . . . Ci2H j2N2 134 22,89
2- ( CgH J0O2 48 28,14
) ........................ C4H8 140,35 25,265
() C2H6O2 11,5 43,26.
- 1 ........................ C5H 10 165,27 16,82 18,07
........................ C3H8O3 47,39
^ :- -2 ................ C5H 10 151,363 24,239
. . C5H8O4 97,5 37,39
--2 . . . . C5H 10 140,235 26,536
- . . . . C6H4Br2 1,8 12,78
2- -1 . . . . C5H 10 137,560 26,879
<- . . . . C6H4Br2 6,9 13,38
--1 . . . . C5H 10 168,500 18,009 86
- . . . . C6H4Br2 20,55
2--2 . . . . C5H 10 133,720 25,738
- . . . . C8H8Br2 95 24,25
*- . . . . C8H8Br2 77 21,45
81,5 2,4- . . . C6I I4Br2O 12 13,97
........................ C2H2 23,04
................ C2H2Br2 10,012 13,52
-2 (-
) ............................ C4H6 -132,23 40,808 - . . . . C6H4I2 23,4 10,15
<- . . . . C6H 4I2 34,2 11,54
- . . . . C6H4I2 129 16,20
.................... C 12H 10N2 67,1 28,91
dZ- . . C6H 106 87 35,12
................ C 12H 10N2O 36 21,62
37,03
. . C3H 4O2 12,3 d - . . C6H 10O6 49 21,5
. . C4H8N2S 77 33,45
-
CgH8O2 68 27,35 . . C6H8O4 102 57,93
. . . . C5H 12O 78,9 26,65
- . . C4H6O4 54,35 42,64
............................. C7H7NO2 145 37,48
*- . . . C6H 10O4 19,5 35,72
............................ C7H7NO2 179,5 38,03 - . . . C6H4N2O4 116,93 32,25
- - . . . C6H 4N2O4 89,7 24,7
............................ C7H7NO2 188,5 36,46 C6H 4N2O4 173,5 39,99
/- . . .
............................. C 10H 12O 22,5 25,80 C6H6N2O4 70,14 26,40
2,4- . . .
............................ C6H7N - 6 ,3 27,09 C4H8O2 11,0 34,85
........................
.................... C 14H8O2 284,8 37,48 - . . . . C6H6O2 104,3 49,40
................................. C 12H 14O4 29,5 25,80 - . . . . C6H6O2 109,65 46,20
............................. C3H6O 95,5 23,42 C6H6O2 172,3 58,77
/- . . . .
............................. C 14H 10O2 95,2 22,15 ................ C 12H 11N 52,98 25,23
N- . . . . C 13H 13N 32,37 21,86 - . . . . C6H4Ci2 16,7 21,02
. . C7H6O2 122,45 33,90 - . . . . C6H4CI2 24,8 20,55
.................... C 13H 10O 47,85 23,53 /- . . . . C6H 4Cl2 53,13 29,67
. . . . C2H3Br3O2 46 16,90 - . . . . C8H8Cl2 55 29,03
- . . . C6H4BrI 21 12,18 - . . . . C8H8Cl2 34 26,04
- . . . C6H4BrI 9,3 10,24 /- . . . . C8H8Cl2 100 32,73
- . . . C6H4BrI 90,1 16,60
. . C 10H 15BrO 78 41,57 ............................ C2H2Cl2O2 4 14,21
- ................ C7H7Br 28 20,86 C3H8O 88,5 21,08
/ - ................ C6H5BrO 63,5 20,50 C6H 14O 86,8 25,79
- . . . C6H4BrCl 12,6 15,41 - . . . . . C7H7I 34 18,75
81

* ^ "-
/ *> /

. . C8H 16O2 16,3 35,40 ............................ C4H 4S -3 9 ,4 14,11


. . C 10H20O2 31,99 38,87 - .................... C7H 9N 43,3 39,90
........................ C 12H9N 243 42,05 -
C8H8O2 103,7 35,40
. . . CgH8O2 133 36,50 - C8H8O2 108,75 27,59
/i- ........................ C7H8O 34,6 26,28 - C8H8O2 179,6 39,90
- C4H6O2 72 25,32 2,4,6- . . C6H3Br3O 93 13,38
- C4H6O2 71,2 34,90 . . . C3H5N3O9 12,9 23,02
. . Cj2H24O2 43,22 43,72 2,4,6- C7H5N3O6 80,83 22,34
C5H8O3 33 18,97 .................... C57H 110O6 70,8 (54,5) 45,63
. . . C4H8O2 - 5 ,7 30,04
C 10H20O 43,5 ............................ C2HCI3O2 57,5 8,60
I- ........................ 18,63
. . . C2H 4O2 16,7 46,68
. . . CH4O -9 7 ,8 23,7
- 2202 28,25 32,20

. . . C10H 10O2 36 26,53 - C 11H22O2 42,91
- ............................ C3H7NO2 43,7 40,85
. . . . C6H8N2 19,6
............................ C10H8O2 18 36,31
22,86
C8H8O2 76,7 25,44
C14H28O2 53,86 47,49
.................... .... . . C6H6O 40,92 29,03
. . CH2O2 8,40 58,89
............................ C6H 4O2 115,7 40,85
* . . . . C 10H9N 50 22,34
C 10H8O . . . C4H7Cl3O2 9 24,03
- ........................ 95,0 38,94
C 10H8O 120,6 . . . . C2H3Cl3O2 47,4 33,18
- ........................ 31,30
- . . . . C6H6N2O2 71,2 - ................ C6H6CIN 71 37,15
27,88
- . . . . C6H6N2O2 114,0 -
40,97 ............................ C7H5C io 2 140,2 39,30
- . . . . C6H6N2O2 147,3 36,46 -
- ............................ C7H5ClO2 154,25 36,41
............................ C7H5NO4 145,8 40,06 -
- ............................ C7H5ClO2 239,7 49,21
............................ C7H5NO4 141,1 27,59 - . . C6H4ClNO2 44,4 29,38
-
239,2 - . . C6H 4ClNO2 83,5 31,51
............................ C7H5NO4 52,80
5,85 - C2H 3ClO2 61,2 31,06
................ C6H5NO2 22,52
. . . . C 10H7NO2 56,7 - C2H3ClO2 56 35,12
25,44
- ................ C6H5NO3 45,13 . . . C 16H34O 40,27 33,80
26,76
. . . . C8H9NO2 91,3 ........................ CH2N2 44 49,81
33,59
61,82 . . . . C6H 12O 25,46 4,19
C 16H32O2 39,18
................ C6H 12O3 10,5
25,02 ................................ CCl4 -2 2 ,8 41,57
* C9H 18O2 12,35 30,63 C 18H34O2 44,4 52,08
- C9H 18O2 39,04 . . . . C2H6O -1 1 4 ,4 25,76
. . . C6H 14O -126,1 20,66
()
C 18H36O2 68,82 47,54 ............................ C4H 10O -116,3 23,54
- . . . C8H6Cl4 86 21,02
- . . . 95 22,10 ................ C4H 8O2 83,8 28,43
C8H6Cl4
................................ C i0H 14O 51,5 27,47 . . C4H 4O3 119 48,74
82 . I. -

/ /

, .
.
C m. . 1-15 1-16.

*- ** * **
0C / 0C !



CH4 -161,6 121,87 2,3- C8H 18 25 81,17
C2H6 -8 8 ,9 116,87 115,60 70,2
C3H8 25 81,76 2,4- C8H 18 25 79,02
-42,1 101,76 109,43 68,5
C4H 10 25 86,63 2,5- C8H 18 25 79,21
-0 ,5 0 92,09 109,10 68,6
2- C4H 10 25 78,63 3,3- C8H 18 25 78,54
-11,72 87,56 111,97 68,5
C5H 12 25 87,54 3,4- C8H 18 25 81,55
36,08 85,38 117,72 70,2
2- C5H 12 25 81,47 2--- C8H 18 25 80,60
27,86 80,97 115,65 69,7
2,2- C5H 12 25 72,15 --- C8H 18 25 79,49
9,45 75,37 118,26 69,3
C6H 14 25 87,50 2,2,3- C8H 18 25 77,24
68,74 80,48 109,84 67,3
2- C6H 14 25 82,83 2,2,4- C8H 18 25 73,50
60,27 76,89 99,24 64,87
- C5H 14 25 83,96 2,3,3- C8H 18 25 77,87
63,28 78,42 114,76 68,1
2,2- C6H 14 25 76,79 2,3,4- C8H 18 25 78,90
49,74 73,75 113,47 68,37
2,3- C6H 14 25 80,77 2,2,3,3- C8H 18 106,30 66,2
57,99 76,53
C7H 16 25 87,18
98,43 76,45
C7H 16 25 83,02 C6H6 25 103,57
2- 80,10 94,14
90,05 73,4
C7H 16 25 83,68 C7H8 25 98,55
- 110,62 86,8
91,95 74 1
C7H 16 25 84,02 C8H 10 25 95,11
- 136,19 81,0
93,47 74,3
C7H 16 25 77,36 - C8H 10 25 97,79
2,2- 144,42 82,9
79,20 69,7
C7H 16 25 81,68 - C8H 10 25 96,03
2,3- 139,10 82,0
89,79 72,9
C7H 16 25 78,44 - C8H 10 25 95,40
2,4- 138,35 81,2
80,51 70,9
C7H 16 25 78,76 C9H 12 25 91,93
3,3- 159,22 76,0
86,06 70,6
C7H 16 25 76,42 C9H 12 25 89,77
2,2,3- 152,40 74,6
80,88 69,3
C8H 18 95 86,80 1--2- C9H 12 25 94,9
165,15 77,3
125,66 73,19
C8H 18 25 83.02 1- -- C9H 12 25 93,3
2- 161,30 76,6
117,64 70.3
C8H 18 25 83,35 1--4- C9H 12 25 92,7
- 162,05
118,92 71,3 76,4
C8H 18 25 83,01 1,2,3- C9H 12 25 97,56
4- 176,15
117,71 70,91 79,6
- C8H 18 25 82,95 1,2,4- C9H 12 25 95,33
118,53 71,7 169,25 78,0
2,2- C8H 18 25 78,02 1,3,5- C9H 12 25 94,40
106,84 67,7 164,70 77,6

^ <
0C ! /

C 7H 14O 82,
C 5H 12O 120,
- C5H 12O 105,
C6H 12 25 93,81 C i0H 22O 69,
80,74 85.6 C 10H 12O 71,
C7H 14 86.07 C 6H 7N 103,
100,94 76.9 C 6H 14O 2 66,
C8H 16 25 86,21 C 2H 4O 136,
131,79 73.7 C2H3ClO 78,
C8H 16 25 80.9 C3H6O 134,
119,50 70.7 131,
C8H 16 25 84,59 128,
129,73 72.9 123,
C8H 16 25 81,70 118,
123,42 71.1 112,
C8Htl6 25 83,49 0
124,45 72.1 C2H3N 173,
C8H 16 25 8 1,42 C8H8O 77,
120,09 70.9 C7H6O 86,
C8H 16 25 83,13 C7H8O 112,
124,32 71.9 C7H5N 87,
C8H 16 95 80,67 C6H5Br 57,
119,35 70,4 C6H 12O 82,
C4H 10O 141,
- C4H 10O 134,
- C4H 10O 130,
C5H 10 25 97.1
C7H 14O2 71,
C5H 10O2 86,
49,26 93.1
C6H 12 25
C5H9N 96,
89,83
71,81 83.2
HCN 210,
C7H 14 C8H 16O 74,
25 88,6 C7H 16O
103,45 78.3
104,
C7H 14 25
C8H 19N 65,
82.5
C8H 11N 80,
87,5 74.6
C7H 14 25
C3H6O3 88,
86.4
99,3
C6H 15N 75,
77,0
C7H 14 25 83,9
C7H 14O 75,
91,9 75.5
CCl2F2 40,
C7H 14 25 8 3 ,G
C2H2Cl2O2 77,
90,8 75,3

C 4H IN 91,
C 5FI 003 73,
C 5H 90,
C2H 4 - 1 0 3 ,7 1 115,39
C 6H 004 67,
C3H6 - 4 7 ,7 0 104,62
C7H 40 2 69,
C4H8 25 86,8 C 9H 80 2 61,
-6 ,2 5 9 3,36
C i0H 202 56,
C4H8 25 94,5
C 9H 8^2 57,
3,72 99,46
C 5H 20 119,
C4H8 25 91,8
C 8H 02 65,
0,88 9 6 ,94
C 6H 2 2 73,
C4H8 25 87,7 C 6H 20 2 73,
- 6 ,9 0 94,22
C 8H 02 64,
C 9H 02 57,
C 8H O2 63,
[ C 9H 02 60,
C 4H 138,
C 3H 6O 96 163,41 C 7H 40 2 65,
C 5H 13N 95 98,67 C 5H 0 2 78,
C 5H 11Br 129 48,26 C 5H 0 2 101,
C 5H 11I 155 47,54
C 5H 10 12,5 75,01 C4H8O2 111,
84 . I. -

* ** ** **
0C / 0C /

C5H 10O 92 89,83 C2HCI3 85,7 57,24


C3H8O 82,3 159,35 C2H4O2 118,3 96,75
C6H 11N 156 88,15 140 94,37
C 10H 14O 237 68,09 220 81,23
- C7H6O 202 100,58 321 0
C10H 16 165 69,52 C4H 6O3 137. 92,2
C4H 8O2 163,5 113,96 C7H8O 153 81,46
C4H7N 117,4 114,91 C4H4O 31 95,32
C5H 4O2 160,5 107,51
C6H 10O 128 85,77 C2HCl3O . 53,99
CH3I 42 45,87 C2H3CI3O* 96 131,87
CH3Cl 23,8 102,25 C6H5Cl 130,6 77,59
15,0 96,04 CHCl3 0 64,74
20,0 95,32 40 60,92
25,0 94,60 61,5 59,01
C3H6O2 42 89,83 100 55,19
C7H 14O 149,2 82,66 260 0
C7H9N 194 95,56 - C7H 7Cl 158,1 72,63
C3H6O2 0,0 113,96 - C7H7Cl 160,4 73,13
56,3 98,09 C6H 11Cl 142,0 74,78
C6H 12O 127 82,42 - C4H7ClO2 141,5 80,75
C5H 10O2 102,6 79,79 2- C2H5ClO 126,5 122,94
C6H 12O2 116,0 70,00 () (CN)2 0 102,97
C8H 16O 173 74,06 CNCl 13 134,98
C5H 10O2 91,1 78,12 C6H 12O 161,1 108,22
C6H 12O2 116 72,39 CCl4 0 52,06
C5H 10O 92 89,83 76,75 46,42
CH 4O 284,29 200 32,73
64,7 262,79 C2H5Br 38,4 59,92
100 241,29 C2H5I 71,2 45,61
160 193,51 C2H5CI 4,7 92,93
200 148,12 15,0 92,45
220 109,89 20,0 92,22
240 0 25,0 91,98
C4H8O2 79,0 87,56 CoH7N 15 145,97
C2H4O2 31,3 112,35 C4H8O2 0,0 102,01
C4H8O 78,2 105,93 C9H 10O2 213 64,50
CH2O2 101 119,93 C6H 12O2 118,9 74,68
C 10H8 218 75,49 C7H 14O2 98 77,16
C6H5NO2 210 79,08 C2H 4Br2 130,8 46,23
CH3NO2 99,9 134,98 C2H 4Cl2 0 85,29
- C6H7N 129 90,78 82.3 77,33
C5H 11N 106 89,35 C2H4O 13 138,56
C5H5N 114,1 107,36 C2H6O2 197 191,12
C5H 10O2 100,4 80,27 C2H 4Cl2 0,0 76,69
C7H 14O2 143,6 68,33 60 67,13
C7H 14O2 134 63,79 C6H 14O 79,0 74,78
C8H 16O2 156 64,50
C3H8O 97,2 164,36 C6H 12O2 109,2 72,05
C6H 12O2 120,6 73,15 C7H 14O2 144 67,85
C4H8O2 80,0 88,13 C10H20O2 207 60,44
C3H5N 97 134,26 C4H9NO 182 115,87
C3H6O2 139,3 98,81 C4H8O 78,2 105,93
C7H6O2 196 74,78 C 11H22O2 227 58,05
CS2 89,35 C2H6O 78,3 204,26
46,25 84,09 () C4H 10O 34,6 83,85
100 75,49
140 67,37 C5H 12O 60 82,66
1,1,2,2- C2H 2Cl4 145 55,07 C5H 10O2 97,6 80,08
T C2Cl4 120,7 50,05 C3H6O2 53,3 97,18
- C7H9N 198 95,08

t w - t , /, /
1000 10
900
800
700
600-
500 20

400
30
300
1
40

50
200
4 O lO

00
OJO
* 70
14
80
vag 90
2f > 20
100 - 22 23 100
90 - 025
80
70 26
27
60

50 200

40
30

300
30

20- 500

600
700
800
900
10 - J E - 1000
. 1-15.

*> *> f Kp*
/ - / .
0C f Kp - L 0C * - * . 0C

29 50200 133 27 40-250 240 -113 1 9 0 -250 214


22 120210 235 20 70 -2 5 0 143
13 10400 289 9 3 0 -300 296
16 90200 153 12 2 0 - 200 197 17 100-250 187
30 100500 374 23 4 0 -2 0 0 96
11 50225 235 24 20-200 264 7 140-275 263
10 20300 267 2 3 0 -250 283
14 9 0 -1 6 0 157 4 140-275 273
21 10-100 31 18 100-225 321 25 25-150 32
26 2 0-140 243
3 175-400 527 11 2 70-250 198
8 150-250 216 12 2 4 0 -200 Ul 28 140-300 243
19 25-1 5 0 36 21 5 70 - 250 178
15 8 0 -2 0 0 134 -22 6 50-170 96 ( 13 10-400 194
)
86 . I. -

-40 40 80 120 160 POO 240 280 300 360 400


,

. 1-16. - .

1-134

* * *n.r "
0C / 0C /

() .................... 61,8 42,3 .................................... 43,3 37,0

CaAl2Si2O8 .................... . 100 30,5Pb + 6 9 ,5 S n ........................ 183 17

KAlSi2O8 ................................ 100 36,9 -F 63,1 S n ........................ 179 15,5

KAlSi3O8 ................................ 83 63,7Pb -F 36,3Sn / .................... 177,5 11,6

CaSiO3 .................................... 100 77,8Pb + 2 2 ,2 S n ........................ 176,5 9,54

Ca3M gSi4Oi2 ............................ 94 24Pb + 27,3Sn + 48,7Bi . . . 98,8 6,85

CaMgSi2O6 . ........................ 100 25,8Pb + 14,7Sn + 52,4Bi + 7Cd 75,5 8,4

Mg2SiO4 ..................................... 130

Fe2SiO4 ..................................... 85

1-135
Cp
: . , . , 40, 2152 (1948) (
, . . 00). . . , . ., 25, 2 ,
U. S. Bur. M ines B u ll., 371 (1934); 477 (1948). 47 (1947) ( ).
. J o h n s o n (ed.), WADD-TR-60-56, 1960, ( . . 1-17 1-18.
). S , Ind. E ng. Chem.,


, 0K , 0K
^Py - P' -

3 T 1 3 Ar 4,97
N2 . 300-3000 6,50 + 0,001007
N II3 . 300-800 6,70 + 0,006307
N H 4Br . 274-328 22,8
N H 4Cl () . 9,80 + 0,03687 BaCl2 . 273- -1198 17.0 + 0,003347
273-457 BaCl2 H2O . 273- -308 28,2
N H 4Cl () . 457-523 5,0 + 0,03407
. BaCl2 220 . 273- -307 37,3
N H 4I 273328 17.8 Ba(ClO3)2 H2O . 51
N H 4NO3 . 273-293 31.8 289- -320
(N H 4)2SO4 . BaCO3 () . 273- -1083 17,26 + 0,0131
275-328 51,6


. 300-5000 8,05 + 0,000233 7- 156 300/T 2 BaCO3 () . 1083 -1255 30.0
NO BaMoO4 . 273- -297 34
2 Ba(NO3)2 . 285- -371 39,8
BaSO4 . 273- -1323 21,35 + 0,0141 T
Al . 273- 931 4,80 + 0,00322 7
. 931 - 1273 7,00 4
AlBr3 . 273- -370 18,74 + 0,018667
. 370- -407 29 5 Be . 273-1173 4,698 + 0,0015557 121 000/2
AlCl3 . 273- 465 13*25 + 0,028007 BeO . 273-1175 8,69 + 0,00365 - 313 /T2
. 465- 504 31.2 BeO Al2O3 . 2 7 3 -3 7 3 25,4
AlCl3 -6 20 . 288- 327 76 BeSO4 . 2 73-373 20,8
A lF3 . 288- 326 19.3
A lF3 220 . 288- -326 50.5
AlF3 3NaF . 273- 1273 38,63 + 0,047607 - 449 200/72 273-1174 1,54 + 0,00440
. .
1273- 1373 142 . 27 3 -5 1 3 5,14 + 0,03207
. 273- 464 16,88 + 0,022667 B2O3
A lI3 . 5 13-623 30,4
. 464- 480 28,8 . 273-1173 1,61 +0,004007
Al2O3 . 22,08 + 0,0089717 - 522 500/72 BN
273- 1973
A l2O3 SiO2 ( . 273- 1573 40,79 + 0,0047637 - 992 800/72 300-2000 9,00
) Br2
Al2O3 SiO2 ( 273-1673 41,81 + 0,0052837- 1 211 000/72 273-1993 5,57 + 0,000977
) V
Al2O3 -SiO 2 ( . 273-1573 43,93 + 0,0019237- I 086000/72
) 5
12 2 S i0 2 . 273-576 59,65 + 0,05707 Bi . 2 7 3 -544 5,38 + 0,002607
() . 544-1273 7,60
4120 3 *3Si02 . 273-575 113,2 + 0,06527 Bi2O3 . 2 7 3 -7 7 7 23,27 + 0,011057
Al2(SO4)3 . 273-373 63.5 Bi2S3 . 2 8 4 -3 7 2 30,4
Al2(SO4)3 . 1820 . 2 88-325 235

1 , CM J o h n s o n (e d .), WADD-TR-60-56, 1960.


* Cm. . 1-136. T < 298 . S c o t t , C ryogenic E nqineering, P rinceton, N ew York, 1959.
3 . J o h n s o n (e d .), WADD-TR-60-56, 1960.
4 - 2 2 0 + 1440 . S t a l d e z , NACA Tech. N ote, 4141, 1957 (* 1-5),
8 C m. , 1-136,
88
. I. -

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X X
X X X X X X X C O ,^0{1,^11, ttf UhU4 <:
2 In . S i O 2 ( , ) 27 3 848 1 0 ,8 7 + - 0 , 0 0 8 7 12 2 4 1 2 0 0 / T 2
I2 . 3 0 0 -2 0 0 0 9 ,0 0 S i O 2 ( , ) . 8 4 8 -1 8 7 3 1 0 ,9 5 + 0 ,0 0 5 5 0 /
S iO 2 ( - . 2 7 3 -5 2 3 3 ,6 5 + 0 ,0 2 4 0 7
Ir . 2 7 3 -1 8 7 3 5,50 + 0,001437 , )
SiO2 (- 523-1973 17,09 + 0,0004547 - 897 200/72
, )
Cd . 2 73-594 5,46 + 0,0024667 SiO2 . 273-1973 12,80 + 0,004477 - 302 000/72
. 594-973 7 13 Kr . 4.97
CdO . 273-2086 9,65 + 0,002087
CdS . 2 7 3 - 1,273 12,9 + 0,000907 K c e Xe . 4.97
CdSO4 -V 3 H2O . 293 51,3
2
La . 273-1009 5,91 +0,001007
. 273-336 5,24 + 0,005557 La2O3 . 273-2273 22,6 + 0,005447
. 336-373 7.7 La2(MoO4)3 . 27 3 -307 86
. 4,97 La2(SO4)3 . 2 7 3 -3 7 3 66,9
K2 . 300-2000 9,00 La2(SO 4)3 *920 . 27 3 -319 152
KAsO3 . 290-372 25 3
KBO2 . 273-1220 12^6 + 0,01267
K2B4O7 . 2 90-372 51.3 Li k. 273-45 0,68 + 0,01807
KBr . 273-543 11 49 + 0,003607 . 4,97
KCl . 273-1043 10,93 + 0,003767 LiBr . 273-825 11.5 + 0,003027


KClO3 . 289-371 25.7 Li Br - H2O . 278-318 22.6
KClO4 . 287-318 26.3 LiCI . 27 3 -8 8 7 11,0 + 0,003397
21- CuCl2 -220 . 2 92-323 63 LiCl - H2O . 2 7 9 -360 23,6
21 P tC l4 . 2 86-319 55 LiF . 273-1117 8,20 + 0,005207
21-S n C l4 . 292-323 54.5 LiI . 273 - 723 12.5 + 0,002087
2 1-ZnCl2 . 279-319 43.4 LiI H2O . 2 7 7-359 23.6
2KCN Zn(CN)2 . 277-319 57.4 LiI -2 20 . 277-345 32,9
K2CO3 . 296-372 29.9 LiI 20 . 2 7 7-347 43 2
K2CrO4 . 289-371 35 9 LiNO3 . 273-523 9,1*7 + 0,03607
K2Cr 20 7 . 273-671 42*80 + 0,04107 . 523-575 26,8
. 671-757 96.9
KF . 273-1129 10.8 + 0,002847 2
K4Fe(CN)6 . 2 73-319 80,1 Mg . 273-923 6,20 + 0,001337 - 67 800/72
K4Fe(CN)6 - 20 . 273-310 114.5 . 923-1048 7.4
KH2AsO4 . 289-319 32 MgAg . 2 7 3 -905 10,58 + 0,004127
KH2PO4 . 290-320 28,3 M g4Al3 . 273-736 34.4 + 0,01987
KHSO4 . 292-324 30 MgAu . 273- 1433 11,3 + 0,001897
KMnO4 . 287-318 28 Mg2Au . 273-1073 16.2 + 0,004517
KNO3 . 273-401 6,42 + 0,05307 Mg3Au . 273-1103 21.2 + 0,006147
. 401-611 28.8 MgCl2 . 273-991 17.3 + 0,003777
. 611-683 29 5 M g C L -620 . 2 9 2-342 77,1
K2O- Al2O3 -3 S i0 2 . 273-1373 6 9 ,2 6 + 0 ,0 0 8 2 1 7 - 2 3 3 1 0 0 0 /7 2 MgCO3 . 290 16,9
() . 273-1373 69,81 + 0,010537 - 2 403''000/72 MgCu2 . 2 7 3 -9 0 3 14,96 + 0,007767
K2O -A l2O3 -3 S i0 2 . 273-1373 65,65 + 0,011027 - 1 748 //2 Mg2Cu . 2 7 3 -843 15.5 + 0,006527
() . 273-1373 64,83 + 0,014387 - 1 641 0 0 0 / 2 MgNi2 . 2 7 3 -903 15,87 + 0,006927
K4P2O7 . 290-371 63.1 MgO . 273-2073 10,86 + 0,0011977 - 208 700/72
K2SO4 . 287-371 33.1 MgO - AI2O3 . 2 8 8 -3 1 9 28
K2SO4 Al2(SO4)3 . 292-322 352 MgO SiO2 ( - . 273-1373 25,60 + 0,0043807 - 674 200/72
LMH2O )

, . J o h n s o n (ed ). WADD-TR-60-56, 1960.


C m . . I 136.
* . B r a b e t s , W a t e r m a n . J . Chem. P h y s , 28, 1212 (1958),



. 0K , 0K
P' - " P' -

( .) ( .)
MgO SiO2 ( . 273-773 23,35 + 0,0080627 - 558 800/2 Ni . 1725-1903 8,55
) NiO . 273-1273 11.3 + 0,002157
MgO SiO2 . 273-973 23,30 + 0,0077347 - 542 000/72 NiS . 2 7 3 -5 9 7 9,25 + 0,006407
6MgO MgCi2 . 273-538 58,7 + 0,4087 NiSO4 . 29 3 -3 7 3 33.4
SB2O3 () NiSO4 620 . 29 1 -3 2 5 82
6MgO - MgCI 2- . 538-623 107,2 + 0,28767 Ni2Si . 273-1582 15,8 + 0.003297
-SB2O3 (P) NiSi . 273-1273 10.0 + 0,003127
Mg(OH)2 . 292-323 18,2 Ni3Sn . 27 3 -9 0 4 20,78 + 0,01027
M gSO4 . 296-372 26,7 NiTe . 27 3 -7 0 0 11.00 + 0,004337
M gSO4 H2O . 287 33
M gSO4 '620 .. 282 80 4

. I. -
M gSO4 720 . 291-319 89
M g3Sb2 . 273-1234 28,2 + 0,005607 Sn . 2 7 3 -5 0 4 5.05 + 0,004807
Mg2Si . 273-1343 15,4 + 0,004157 . 504-1273 6.6
SnAu . 273-581 11,79 + 0,002337
SnCl2 . 2 7 3 -5 2 0 16,2 + 0,009267
SnCl4 . 286-371 38.4
Mn () . 273-1108 3,76 + 0,007477 SnO . 273-1273 9.40 + 0,003627
Mn ( ) . 1108-1317 5,06 + 0,003957 SnO2 . 273-1373 13,94 + 0,005657- 252 /
Mn ( ) . 1317-1493 4,80 + 0,004227 SnPt . 273-1318
Mn 11,49 + 0,001907
. 1493-1673 11,0 SnS . 273-1153 12,1 + 0,001657
MnCI2 . 273-923 16,2 + 0,005207 SnS2 . 27 3 -873
MnCO3 20.5 + 0,004007
. 273-773 7,79 + 0,0421 T + 0,000009072
MnO . 273-1923 7,43 + 0,010387 - 0,0000036272 Os . 273-1877
Mn2O3 5,686 + 0,0008757
. 273-1173 10,33 + 0,05307 - 0,000025772
M n3O4 . 273-1773 19,25 + 0,05387 - 0,000020972 4 Pd . 273-1822
MnO2 5.41 +0,001847
. 273-773 1,92 + 0,04717 - 0,000029772
Mn2O3 - H2O . 291-322 31 4 Pt . 273-1873 5,92 + 0,001167
MnS . 273-1883 10,21 + 0,006567 - 0,000002427
M nSO4 . 293-373 27,5 Pm .
MnSO4 -5 20 . 290-319 78
Rn . 4,97
1
Cii 273-1357 Re . 273-2273 6,30 + 0,000537
. 5,44 + 0,0014627
. 1357-1573 7,50
CuAI . 273-7 3 3 9,88 + 0,005007 Rh . 273-1877 5,40 + 0,002197
CuAI2 . 2 73-773 16,78 + 0,003667
Cu3Al . 273 - 775 5
19,61 + 0,010547
CuI . 273-675 12,1 +0,002867 Hg 2 7 3 -630
CuI2
. . 6,61
. 274-328 20,1 . 4,97
CuO . 273-810 10,87 + 0,0035767 - 150 600/2 H g2 . 300-2000 9.00
CuO SiO2 - H2O . 293-323 29 Hg(CN)2 . 28 5 -3 1 9
CuS 25
. 273-1273 10,6 + 0,002647 HgCi . 27 3 -7 9 8 11,05 + 0,003707
Cu2S () . 2 73-376 9,38 + 0,03127 HgCl2 .
Cu2S (P) 2 7 3 -553 15.3 + 0,01037
. 376-1173 20,9 HgI . 2 7 3 -563 11.4 + 0,004617
CuS FeS . 292-321 24 H gI2 () .
CuSO4 273-403 17.4 + 0,0040017
. 282 24,1 H gI2 (P) . 403-523 20,2
CuSO4 H2O . 282 31,3 HgO . 278-371 11.5
CuSO4 - 2 . 282 49,0 HgS . 27 3 -8 5 3 10,9 + 0,003657
CuSO4 - 520 . 282 6 7 ,2 H g2SO 4 . 2 7 3 -3 0 7 3 1 .0
Cu2Sb 273 573 13 ,7 3 + 0 ,0 1 3 5 0 7
Cu2Se () 2 7 3 -3 8 3 20,85
Cu2Se () 3 83-488 20,35 Rb . 27 3 -3 1 2 3 , 2 7 + 0 ,0 1 3 1
Cu3Si 273-1135 21,3 + 0,005877 . 3 1 2 -3 7 3 7,85
RbBr . 2 73-954 11,6 + 0,002557
Rb2CO3 . 2 9 1 -320 28,4
Mo RbCl . 2 7 3 -987 11,5 + 0,002497
273-1773 5,69 + 0,001887-50 300/72 11,3 + 0,00256
MoO3 273-1068 15,1+0,01217 RbF . 273-1048
MoS2 RbI . 273-913 11,6 + 0,00263
2 73-729 19,7 + 0,003157
4
As . 273-1168 5,17 + 0,002347
AsCl3 . 286-371 Pb . 2 7 3 -600 5,77 + 0,002027
31 9
As2O3 . 273-548 8,37 + 0,04867 . 600-1273 6,8
As2S3 . 293-373 Pb3(AsO4)2 . 2 86-370 65,5
25,8 288-371 26,5
PbB2O4 .
1 PbB4O7 . 289-371 41,4
PbBr2 . 273-761 18,13 + 0,003107*
Na . 273-371 5.01 +0,005367 . 761-860 27,4
. 371-451 7,50 PbCO3 . 286-320 21,1
. 4.97 PbCl2 . 273-771 15,88 + 0,008357*
NaBO2 . 273-1239 10.4 + 0,01997 . 771-851 27,2


N a2B4O7 . 289-371 47.9 212 NH4Cl . 293 53,1
Na2B4O7 IOH2O . 292-323 147 PbCrO4 . 2 92-323 29,1
NaBr . 273-543 11,74 + 0,002337 PbF2 . 273-1091 16,5 + 0,004127*
NaCNO . 273-353 13.1 PbI2 . 2 73-648 18,66 + 0,00293
N a2CO3 . 288-371 28.9 . 6 4 8 -776 32,3
NaCl . 273-1074 10,79 + 0,004207 PbMoO4 . 2 92-322 30,4
. 1073-1205 15.9 Pb(NO3)2 . 2 86-320 36,4
NaClO3 . 273-528 9,48 + 0,04687 PbO . 273-544 10,33 + 0,003187*
. 528-572 318 PbO2 . 273 12,7 + 0,007807*
NaF . 273-1261 10^4 + 0,002897 Pb2P2O7 . 284-371 48,3
N a2H PO 4 720 . 275-307 86,6 PbS . 2 7 3 -873 10,63 + 0,00401
N a2H PO 4- 1220 . 275-307 133.4 PbSO4 . 293-372 26,4
NaI . 273-936 12,5 + 0,001627 PbS2O3 . 293-373 29
NaNO3 . 273-583 4,56 + 0,05807 PbWO4 . 2 73-297 35
. 583-703 37 2
Na2O Al2O3 3SiO; . 273-1373 63J8 + 0,011717 - 1 678 000/72
. '273-1173 61,25 + 0,01768 7 - 1 545 000/72
NaPO3 . 2 90-319 22.1
N a4P2O7 . 290-371 60.7 Se . 273-490 4,53 + 0,005507
Na2SO4 . 289-371 32.8 . 490-570 8,35
Na2S2O3 . 2 73-307 34.9
. 273-307 86,2
Cepa6
3 Ne 4.97 3,63 + 0,006407*
S (.) . ' 2 7 3 -368
' S (.) . 368-392 4,38 + 0,004407*
S2 . 300-2500 8,58 + 0,000307*
Ni () . 273-626 4,26 + 0,005407 S2Cl2 . 273-332 - 27,5
Ni () . 626-1725 6,99 + 0,0009057 SO2 . 300-2500 7,70 + 0,00530 -

1 = 2 2 0 -M 300 . S t a l d e r , NACA Tech. N ote, 4141, 1957,


2 810 . L u b a r s k y , K a u f m a n , NACA Rept, 1270, 1956*
3 , . J o h n s o n (ed.), WADD-TR-6J-56, 1960.
4 C m. . 1-136.
b C m. Douglas, Ball et al., J. Res. Nat Bur. Stand., 46, 334 (1951). B u s e y, G i a q u e, J. Am. Chem. Soc , 75, 806 (1953).
. E v a n s , W a g m a n, J. Res. Nat. Bur. Stand., 49, 141 (1952). G u t h r e e, S c o t t et al., J. Am. Chem. Soc , 76, 1488 (1954).
! CO


, 0K
Pt - Pt '

1 2
Ag . 273- 1234 5.60 + 0,001507 () . 273-1373 2,6732 + 0,0026177 - 116000/2
. 1234- 1573 82 () . 273-1313 2,162 + 0,0030597 - 130 300/72
Ag2Ai . 273- 903 16,85 + 0,004507 CH 4 . 273-1200 5.34 + 0,01157
A g3Al . 273- 902 22,56 + 0,005707 CO3 . 273-2500 6,60 + 0,001207
AgAl12 . 273- 768 58,62 + 0,05757 CO2 . 273-1200 10.34 + 0,002747- 195 500/72
AgBr . 273- 703 8.58 + 0,01417 CS2 . 293 18,4
. 703- 836 14,9
AgCNO . 273- 353 18.7
AgCl . 273- 728 9.60 + 0,009297
. 728- 806 14,05 U . 27 3 -3 7 2 6,64
AgI () . 273- 423 8.58 + 0,01417 U3O8 . 27 6 -3 1 4 59,8

. /. -
AgNO3 () . 273- 433 18,83 + 0,01607
AgNO3 ( ) . 433- 482 25.7
. 482- 541
AgNO3 30.2
Ag3PO4 . 293- 325 37,5 P ()
Ag2S () . 273- 448 18.8 . 273 317 55
P () . 2 73-472 0*21 + 0,01807
Ag2S ( ) . 448- 597 21,8 P
. 273- 694 19,53 + 0,01607 . 3 1 7 -373 6,6
Ag3Sb PCl3 .
Ag2Se () . 273- 406 20.2 284-371 28 7
. 406- 460 20,4 P 4Q 10 . 273 - 631 15*72 + 0,10927
Ag2Se () . 631-1371 73,6
3 F2 . 300-3000 6,50 + 0,001007
Se2O3 273 373 21,1
Sc2(SO4)3 273-373 62,0 Cl2 . 273-2000 8,28 + 0,000567

X 1
Sr Br2 273-923 18.1 + 0,003117
SrB r2 - H2O .277-370 28.9 Cr . 273-1823 4,84 + 0,002957
SrB r2 620 276-327 82.1 . 1823-1923 9,70
SrCO3 281-371 21 8 CrCl3 . 2 8 6 -319 23
S rC l2 273-1143 18*2 + 0,002447 Cr2O3 . 273-2263 26,0 + 0,004007
SrC l2 H2O 2 7 6 - 365 28,7 Cr2(SO 4)3 . 27 3 -373 67,4
SrC l2 . 220 2 77-366 38.3 CrSb . 273-1383 12,3 + 0,001207
S rI2 273-783 18,6 + 0,003047 CrSb2 . 273 - 949 19,2 + 0,001847
S rI2 . H2O 2 76-363 28,5
S rI2 220 275-336 39.1
S rI2 620 275 - 333 84.9
SrMoO4 273-297 37 Cs . 273-301 1.96 + 0,01827
Sr(NO3)2 290-320 38.3 . 302 8,00
SrSO 4 293-369 26.2 . 4.97
CsBr . 273-909 12.6 + 0,002597
CsCl . 273 - 752 11.7 + 0,003097
Sb . 273-903 5,51 +0,001787 CsF . 2 7 3 -2 5 7 11,3 + 0,002857
. 9 0 3 - 1273 7,15 CsI . 2 7 3 -8 9 4 11,6 + 0,002687
SbBr3 . 2 73-370 17.2 + 0,02937
SbCl3 . 273-346 10.3 + 0,05117
Sb2O3 . 273 - 929 10,1 +0,01717
S b 2O 4 . 273-1198 22,6 + 0 ,0 1 6 2 7 Ce 273-908 5,88 + 0 ,0 0 1 2 3 7
S baS3 2 7 3 82 1 2 4 J2 + 0 ,01327* C eO 3 273 373 15,1

Ti () . 273-500 5,32 - 0,003857 Ce2(MoO4)3 . 27 3 -2 9 7 96
TI () . 500-576 8,12 Ce2(SO 4)3 . 27 3 -3 7 3 66,4
Tl . 576-773 7,12 Ce2(SO 4)3 520 . 2 7 3-319 131,6
TlBr . 273-733 12,53-0,001007
. 733-800 16,0
TlCl . 273-700 12,56 + 0,000887 1
. 700-803 14,2
Zn . 27 3 -6 2 9 5,25 + 0,002707
Ta Ii 1 Ta . 273-1173 5,91 + 0,000997 . 692-1122 7,59 + 0,000557
ZnCI2 . 2 7 3 -6 3 8 15,9 + 0,008007
Te . 273-600 5,19 + 0,002507 ZnO . 273-1573 11,40 + 0,001457- 182 400/72
ZnS . 273-1173 12,81 + 0,000957 - 194 600/72
T 1 ZnSO4 . 2 9 3 -373 28
ZnSO4 H2O . 282 34,7
Ti . 273-713 8,91 + 0 ,0 0 1 1 4 7 - ZnSO4 -6 20 . 282 80,8
TiCi4 . 285-372 35,7 ZnSO4 720 . 2 7 3 -3 0 7 100,2
TiO2 . 273-713 11,81 + 0,007547- ZnSb . 2 7 3 -8 1 0 11,5 + 0,003137

1
Th . 273-373 6,40
ThO2 . 273-1273 14,6 + 0,005077 ZrO2 . 273-1673 11,62 + 0,010467 - 177 700/72


Th(SO4)2 . 273-373 41,2 ZrO2 SiO2 . 2 9 7 -372 26,7

1 C m. . 1-136,
2 T=220^-2800 . S t a l d e r , NACA Tech. Note, 4141, 1957 (. 4).
* , . J o h n s o n (ed.), WADD-TR-60-56, I960.

200 400 600 800 1000 1200



. 1-17. . 1-18.
Cp - C v Cp
[ D e m i n g , S h u p e , Phys. Rev., [ D e m i n g , S h u p e , Phys. Rev.,
37, 638 (1931)]. 37, 638 (1931)].
94 . I. -

, - ), 1
, 0K

1,0 1,5 2.0 4.0 10 25 50 100 200
Ag 0,00020 0,00037 0,00063 0,0030 0,048 0,75 2,78 4,82 5.80
Al 0,00036 0,00056 0,00076 0,0018 0,010 0,11 0,91 3,12 5,16
Bi 0,027 0,52 2,43 4,27 5,46 5,98
Co 0,0012 0,0018 0,0024 0,0050 0,017 0,15 0,98 3,25 5,30
Cr 0,00038 0,00058 0,00076 0,0020 0,010 0,06 0,47 2,39 4.81
Fe 0,0012 0,0018 0,0024 0,0051 0,017 0,10 0,72 2,88 5,33
Ge 0,00015 0,018 0,40 1,49 3,34 4,93
Hg 0,20* 1,08 3,16 4,99 5,90 6,57
In 0,0010 0,0020 0,0040 0,025 0,34
In 2 0,00050 0,00017 0,004
La 0,0012 0,0022 0,0037 0,014 0,026 2,20 4.41 5,64
Mg 0,00032 0,00053 0,00074 0,0020 0,01 0,19 1.41 3.77 5,38
Na 0,0055 0,014 0,14 1,45 3,82 8.44 11,09
Nb 0,0022* *0,0039* 0,0066 0,010 0,048
Ni 0,0016 0,0026 0,0036 0,0075 0,025 0,14 0,96 3.26 5,37
Pb 0,00080 0,0029 0,0051 0,037 0,67 3.36 5,11 5,83 6,20
Pb2 0,0016 0,0039 0,0074 0,048
Pd 0,0031 0,0047 0,0066 0,013 0,054 0,41 1,97 4.27 5,79
Pr 0,0034 0,0072 0,014 0,080 0,99 4.36 6,18 6,22
Pt 0,0016 0,0026 0,0035 0,0088 0,052 0,65 2,54 4,70 5,93
Si 0,0004 0,00007 0,00011 0,00054 0,06 0,84 1,74 3,74
Sn 0,00046 0,00085 0,0014 0,0067 *0,22* 1,65 3,68 5,35 6,08
Sn2 0,00018 0,00061 0,0014
Sn3 0,16 1,26 2,67 4,61 5,81
Ta 0,0014 0,0022 0,0031 0,0079 0,05 0,59 2,60 4.78 5,77
T a2 0,00032 0,0011 0,0027 0,016
Ti 0,00079 0,0012 0,0017 0,0046 0,16 1,08 3,37 5,31
Zn 0,00017 0,00028 0,00043 0,0017 0,039 0,77 2,65 4,59 5.72
Zr 0,00073 0,0011 0,0016 0,0043 0,030 0,48 2,21 4.45 5.72
1 S h i f m a n , G eneral E lectric R esearch Laboratory Report, October, 1952.
2 .
a - ( ).
1-137
Cp , ,
Cpf cP > >
t , 0C t, cC t, 0C t, 0C

0 1,00803 25 0,99892 50 0,99919 75 1,00208
1 1,00717 26 0,99885 51 0,99926 76 1,00225
2 1,00636 27 0,99878 52 0,99935 77 1,00241
3 1,00564 28 0,99873 53 0,99943 78 1,00258
4 1,00495 29 0,99869 54 0,99950 79 1,00277
5 1,00433 30 0,99866 55 0,99959 80 1,00294
6 1,00378 31 0,99864 56 0,99969 81 1,00313
7 1,00325 32 0,99861 57 0,99978 82 1,00332
8 1,00277 33 0,99861 58 0,99988 83 1,00351
9 1,00234 34 0,99859 59 0,99998 84 1,00373
10 1,00194 35 0,99859 60 1,00007 85 1,00392
11 1.0058 36 0,99861 61 1,00019 86 1,00414
12 1,00124 37 0,99861 62 1,00029 87 1,00435
13 1,00093 38 0,99864 63 1,00041 88 1,00457
14 1,00067 39 0,99866 64 1,00053 89 1,00480
15 1,00041 40 0,99869 65 1,00065 90 1,00502
16 1,00019 41 0,99871 66 1,00079 91 1,00526
17 0,99998 42 0,99876 67 1,00091 92 1,00550
18 0,99978 43 0,99880 68 1,00105 93 1,00574
19 0,99962 44 0,99883 69 1,00117 94 1,00600
20 0,99947 45 0,99890 70 1,00131 95 1,00626
21 0,99933 46 0,99895 71 1,00146 96 1,00653
22 0,99921 47 0,99900 72 1,00160 97 1,00684
23 0,99912 48 0,99907 73 1,00177 98 1,00705
24 0,99902 49 0,99912 74 1,00191 99 1,00734
100 1,00763

1 O s b o r n e , S t i m s o n , G i n n i n g s , J. Res. Nat Bur. Stand , 23, 197 (1939).


C m. B e n z l e r , A llgem . W arm etech., 5, 222, (1954). . . , . . , , 120, 771
(1958). - G a m b i l l , Chem. E n g., 53, 139 (1959).
95

Cp / I - 138
International Critical T ab les, vol. V, 1929, p. 107.
. H o d g m a n (e d .), H a n d b o o k o f C hem istry and P h ysics, 40 ed. -
, , . U nion Carbide Corp. P u b lication F4763F, 1958.
Cm. . 1-19.

t, 0C
0Py 0P y
C 3H5Cl 0,313 -7 6 ,2 0,443
C5H 8O 2 0,430 -3 3 ,3 0,453
CioHi0O 2 20 0,388 2,3 0,526
C7H i 2O 2 20 0,451 .19,2 0,563
C8H j 4O 2 20 0,288 C7H i 4O 2 20 0,459
C5H 6Cl2O 2 20 0,322 C 5H 10O 2 20 0,459
C 7H i2O 2 20 0,448 C 4H9Cl 20 0,459
- C5H 7ClO 2 20 0,396 C 4H7N 2 1 -1 1 3 0,547
C5H 9N 23 -1 2 1 0,520
C6H i 0O 2 20 0,451 - C7H 14O 1 5 -1 8 0,416
C5H 5Cl3O 2 20 0,228 - C7H 14O 1 5 -1 8 0,420
C3H6O 0 0,386 - C 7H 14O 1 5 -1 8 0,421
5 10 0,282 C 16H 34 0 -5 0 0,496
d- C5H i2O 2 2 -125 0,711 -1,5 C 6H 10 0 0,405
() C 6H 14 0 -5 0 0,527
- C5H 12O 2 0 -9 9 0,753 2 0 -1 0 0 0,600
- C7H 7NO 2 / 0,435 -1 C6H 12 0 -5 0 0,504
C7H 14O 0 0,364
- C7H 7NO2 / 0,435 C7H 16 0 -5 0 0,507
20 0,490
- C 7H 7NO 2 / 0,444 30 0,518
-1 C 7H 14 0 -5 0 0,486
Ci0H i2O 2 2 -3 3 3 0,511 C3H 8O 3 1 5 -5 0 0,576
22,48 0,551 ^-- C 10H 18 1 5 -1 8 0,393
24,59 0,564
25,33 0,612 , / = 159 Ci0H 22 2 1 -1 5 4 0,588
C6H7N 8 -8 2 0,512 / == 162 C 10H 22 0 -5 0 0,493
C6H 14O 2 0,467 / 172 C 10H 22 0 -5 0 0,500
C2H3ClO 0,339 -2 C 10H 20 0 -5 0 0,467
C3H6O 3 -2 2 ,6 0,514 C 8H 10O 4 20 0,424
C2H3N 2 1 -7 6 0,541 C 10H 14O 4 20 0,450
C8H8O 2 0 -1 9 6 0,450 C 10H 20 2 0 -1 3 0 0,543
C7H6O 2 2 -1 7 2 0,428 - C 6H 4Br 2 0 0,179
C7H8O 2 0 -1 0 0 0,511 - C 6H 4Br 2 0 0,175
2 2 -2 0 0 0,540 - C 8H 8Br 2 1 5 -4 0 0,183
C7H7CI 0,323 - C 8H 8Br 2 1 5 -4 0 0,184
CgH 10 0,393 - C 8H 8Br 2 1 5 -4 0 0,180
C6H 6 6 -6 0 0,419 C 10H 18O 4 20 0,439
10 0,340 C 10H 10 1 8 -2 8 0,345
65 0,482 C j 0H 22 21,5-165 0,588
C 7H5N 2 2 -1 8 6 0,441 C 12H 22O 4 20 0,447
- C 13H i0O 3 -4 0 0,382 C 14H 26O 4 0 0,449
0,346 C 8H 19N 2 2 -1 3 0 0,569
C6H5Br 0,215 - C 6H 4I 2 34,2-99,6 0,139
2 0 -1 0 0 0,231 C 8H 11N 0 -2 0 0,416
16,9-65 0,239 0 0,403
- C6H 4BrI 0,153 - C 12H 12 0 0,392
5 -1 0 0 0,160 C7H 8O 2 166 0,547
3,2-64,6 0,157 - C 6H 4N 2O 4 / 0,404
1,8-34 0,157 C 7H 14O 2 0 -1 4 0 0,550
- C6H4BrI 0,152 CgH16O4 20 0,431
5 -1 0 0 0,158 C 8H 14O 4 20 0,431
3,2-64,5 0,156 C 10H 18O 4 20 0,450
1,7-34,1 0,154 C 12H 11N 54 0,437
1,7-36,2 0,149 56 0,441
C6H5BrO 1 8 -7 7 0,316 66 0,480
- C6H 4BrCl 0,215 - C 6H 4CI2 0 0,269
- C 6H4BrCl 0,212 - C 6H 4Cl 2 0 0,269
C 4H i 0 0,549 - C 6H 4Cl2 5 3 -9 9 0,297
CgHi8O2 20 0,459 CCl2F 2 -4 3 0,21
C 4HI0O 21-115 0,687 - C8H 8Cl2 1 5 -4 0 0,283
30 0,582 - C8H 8Cl2 1 5 -4 0 0,295
96 . /. -



t , 0C /, eC
'* P y *(
- C8H8Cl2 1 5 -4 0 0,282 C6H 10O 21-1 2 1 0,521
C2H2Cl2O2 2 1 -1 0 6 0,349 CgH12 0 0,393
2 1 -1 9 6 0,348 C3H8O2 15-41 0,521
C4H 11N 22,5 0,516 C7H9N 12-197 0,512
C5H 10O3 0,245 C3H6O2 15 0,468
2 0 -1 0 0 0,462 C8H8O2 0 0,363
C5H 10O ,2 0 -9 8 ,5 0,555 C6H 12O 2 1 -1 2 7 0,553
C8H 14O5 2 4 -1 8 6 0,473 C5H 10O2 20 0,459
C7H 12O4 20 0,431 C6H 12O2 20 0,459
C6H 10O4 20 0,431 C8HI6O 2 2 -1 6 8 0,552
C8H 14O4 20 0,450 C3H4C l2O2 20 0,311
C4H i0S 0,468 CH2Cl2 1 5 -4 0 0,288
5 -1 0 0,470 C6H 12O 20 0,459
1 0 -1 5 0,473 -- C5H 10O 2 0 -9 1 0,525
2 0 -7 0 0,477 'TOH
C12H 26 0,521 CH4O 5 -1 0 0,590
1 4 -2 0 0,505 C4H8O2 20 0,459
0 -5 0 0,498 C3H3Cl3O2 20 0,267
-1 C 12H24 0 -5 0 0,455 C2H 4O2 1 3 -2 9 0,516
C5H 13N 2 2 -9 1 0,614 C3H5ClO2 20 0,382
C7H 14O2 20 0,459 -- C7H 12O 1 5 -1 8 0,436
CgH18O2 20 0,459 HOH
C 10H20O2 20 0,459 -- C7H 12O 1 5 -1 8 0,441
CgH18O2 20 0,459 HOH
C5H 12O 0,502 -- C7H 12O 1 5 -1 8 0,441
20 0,535 HOH
30 0,570 C4H9NO 21,8-151,5 0,650
47,9 0,662 C4H8O 2 0 -7 8 0,549
10-117 0,693 C 14H28O2 5 6 -1 0 0 0,539
2 1 -1 3 0 0,695
75,5 0,688 CH2O2 0 0,436
C8H 16O2 20 0,459 15,5 0,509
C6H 12O2 1 6 -6 5 0,509 2 0 -1 0 0 0,524
C4H 10 0 0,549 C10H8 87,5 0,402
C6H 12O2 20 0,459 - C 10H9N 53,2 0,475
C8H 16O2 20 0,459 94,2 0,476
C4H 10O 2 1 -1 0 9 0,716 - C7H5NO4 ^ 0,449
C 12H22O4 0 0,442
C5H 10O2 20 0,463 C6H5NO2 10 0,358
2 3 -9 3 0,590 30 0,339
C7H 16 0 -5 0 0,501 50 0,330
C4H8O2 20 0,450 70 0,330
90 0,343
C5H 12 0 0,512 120 0,394
8 0,527 CH3NO2 17 0,412
C6H 11N 18-156 0,541 - C 10H7NO2 58,6 0,365
C6H 12O2 2 9 -1 0 5 0,531 61,4 0,378
C 10H 14O 2 4 -2 3 3 0,575 94,3 0,390
- C7H8O 0 -2 0 0,497 CgH20 0 -5 0 0,503
- ( 780 2 1 -1 9 7 0,551 -1 C9H 18 0 -5 0 0,485
0 -2 0 0,477 C8H 18 0 -5 0 0,505
C4H6O2 71,4 0,500 -1 C8H 16 0 -5 0 0,486
- C8H 10 30 0,411 C16H32O2 6 5 -1 0 4 0,653
39 0,450
- C8H 10 0 0,383 C6H 12O3 0 0,436
9 -4 0 0,400 C 15H32 0 -5 0 0,497
1 6 -3 5 0,387 1-1 C 15H30 0 -5 0 0,471
30 0,401 - C6H7N 2 0 -1 5 2 0,483
- C8H 10 0 0,383 C5H 11N 2 0 -9 8 0,523
30 0,397 C5H5N 20 0,405
40,8 0,428 21 108 0,431
C 12H 24O2 4 0 -1 0 0 0,572 0 -2 0 0395
57 0,515 C3H8 0 0,576
C4H8O2 0 0,444 C5H 10O2 20 0,459
40 0,501 C10H 12O2 20 0398
2 0 -1 0 0 0,515
97



t, 0C t, 0C
P * *

C9H 12 0,400 20 0,308


C7H 14O2 20 0,459 CHCl3 0 0,232
C8H 16O 2 20 0,459 15 0,226
C6H8Cl2O2 20 0,341 / 30 0,2234
C7H 14O2 20 0,459 C7H7Ci 0 0,315
C6H 12O2 20 0,459 C6H5ClO 0 -2 0 0,399
- C5H7Cl3O2 20 0,297 C6H 12O 1 5 -1 8 0,416
C6H 10O 1 5 -1 8 0,431
C9H 12O 0,429 - C10H 14 0 0,398
C7H 14O2 9 0,556
C4H8O2 20 0,450 0 -9 8 0,680
C5H9CiO2 20 0,414 C2H5Br -1 0 0 0,194
C3H5N 0,508 -2 0 0,206
1 9-95 0,538 5 -1 0 0,216
C3H6O2 0,444 1 0 -1 5 0,213
2 0 -1 3 7 0,560 1 5 -2 0 0,214
C3H6O 0,522 C2H5I -3 0 0,156
0 0,161
C9H 12 20 0,414 60 0,171
C7H6O2 18 0,382 C2H5Cl -2 8 -+4 0,426
C 13H 10O3 44,1 0,391 0 0,367
C13H36O2 7 5 -137 0,550 C4H8O2 20 0,457
C 14H3Q 0 -5 0 0,497 2 0 -1 0 0 0,476
- C8H6Cl4 15 -4 0 0,240 C6H 10O3 0 0,428
- C8H6Cl4 15 -4 0 0,242 2 0 -1 0 0 0,476
1,1,2,2- C2H2Cl4 20 0,268 C9H 10O2 20 0,387
C2Cl4 20 0,216 C8H 10 0 0,392
C8H20SiO4 15-98 0,424 30 0,407
jk- C10H 14O 50 0,566 C6H 12O2 20 0,457
- C7H9N 0,454 C7H 14O2 20 0,457
2 2 -195 0,598 C4H6Cl2O2 20 0,328
40,5 0,498 C2H4Br2 8 -9 5 0,182
- C7H9N 43 0,524 13-106 0,175
58 0,634 20 0,173
94 0,533 C2H4Cl2 -3 0 0,278
C7H8 10 0,364 20 0,299
85 0,534 30 0,304
12-99 0,440 50 0,313
C13H28 0 -5 0 0,499 60 0,318
-1 Ci3H26 0 -5 0 0,475 ( C2H6O2 -1 1 ,1 0,535
2,4,6- C7H5N3O6 0,335 ) 0 0,542
C2H3Cl3 20 0,266 2,5 0,550
C2HCl3 20 0,233 5,1 0,554
CCl4 0,198 14,9 0,569
20 0,201 19,9 0,573
30 0,200 C6H 12O2 20 0,457
C2H 4O2 2 6 -9 5 0,522 C2H6O 20 0,505
C8H 10 20 0,446 (- C4H 10O -1 0 0 0,511
C7H8O 0,405 ) -5 0 0,515
2 0 -1 5 2 0,483 -5 0,525
CH3NO 19 0,549 0 0,521
C5H4O2 0,367 30 0,545
2 0 -1 0 0 0,416 80 0,687
C9H7N 0 -2 0 0,352 120 0,800
C2HCl3O 17 -5 3 0,250 140 0,819
C2H3Cl3O2 5 5 -8 8 0,470 180 1,037
- C7H5ClO2 0,390 C5H 10O2 20 0,457
C4H5Cl3O2 10-81 0,294
- C7H5ClO2 0,265 9 -1 3 9 0,305
20 0,284
/- C7H5ClO2 ^ 0,545 C3H6O2 1 4 -4 9 0,508
- 2 0 - + 14 0,454
C6H5Cl 0,273 C4H7ClO2 9 -1 3 8 0,416
10 0,298 20 0,397
OO


l P '


2i



,
S% <

, 0C


2
tJC Q, S .
C o6- H>
200 1CE
2
3
2d 26 0 -1 0 0 0 -1 0 0 8 0 -1 0 0

37 -5 0 + + 2 5 10 -3 0 + + 3 0
4 0 O4A - 0-100
0,3 -* 0-100
52 -7 0 + + 50 49 -4 0 + + 2 0
50
60
30 0 -1 3 0 -- 0-100
150 32 2 0 -5 0
05
7 - 27 -2 0 + + 3 0 -4 0 + + 2 0 .
9 0/0 25%

. /. -
8 0,4 13 - 8 0 + + 20
23 1 0-80 90 - 200
" CfO 3/ 1 5 -2 5
14O ni?1- 0 -1 0 0 51 -4 0 + + 2 0
j*.
100 V e 21
, 44 0 100 -5 0 + + 2 5
" 24
,
25 23 0,5 25%
26 5 0 + + 2 5 13 -3 0 + + 4 0
53 10-200 -5 0 + + 2 5
2O7 Mdg0V 34 35 80-j- +20 - - 2 0 + + 100
28 0 -6 0 4
25 0 3 38 -4 0 + + 2 0
0 -5 0

J0-E 37 39 ,Q 16 0 -2 0 0 10-45 3 10-60
0,6
42 8 11 20+ + 100 ,
CO *4 4<? 98%
43
21 - 8 0 + + 25 100 + + 25
45 q 47
- 24 - 5 0 + + 25
15 80-120 20-100
-O J - 22 30-100 - 25 0 -1 0 0
-E ,
- 16 0 -2 0 0 30% - 39 -4 0 + + 2 0 0
- 3 0 + + 140
-
- 5 -4 0 + + 5 0 42

I
S

050 5/0 0,8 0 -6 0
6 - 3 0 + +60 0 -8 0 ,
100%
-5 0 -= - 41 10-100 46 2 0 -8 0
,
100% .
- 43 0 -1 0 0 -11 -2 0 + + 7 0 95%
0,9 50
2 0 -8 0
-12 40+ +15
47 -2 0 + + 5 0 ,
-21 -2 0 + + 7 0 50%

52
-22 -2 0 + + 6 0
Z - 1,0 31 - 8 0 + + 20 36 -1 0 0 + + 2 5
- - 2 0 + +70
113 (

. 1-19. )

Cp 1 1-139

t, 0C /, 0G P' ^
P -
C i2H i0N2 28 0,330 -1 0 0 0,217
- C7H7NO2 85 - / 0,254 + 0,00136/ 0,330
C5H8O4 20 0,299
- C7H7NO2 120 - / 0,253 + 0,00122/ Z+ ( C6H 12O6 -2 5 0 0,016
) -2 0 0 0,077
- C7H7NO2 128 -s- / 0,287 + 0,00088/ -1 0 0 0,160
0,277
C6H7N 0,741 20 0,300
C h H8O2 0 -2 7 0 0,258 + 0,00069/ (C6H 10O5)* 0 -9 0 0,201 + 0,00096/
C i 4H io 50 0,308 C 14H 14 28 0,363
100 0,350 - C6H 4Br2 -3 6 0,248
150 0,382 - C6H 4Br2 -2 5 0,134
C 12H h O4 10 0 999 - C6H4Br2 50 - +50 0,139 + 0,00038/
C3H6O -2 1 0 - - 8 0 0,540 + 0,0156/ - C6H 4I2 - 5 0 - +15 0,109 + 0,00026/
C7H6O2 20 - / 0,287 + 0,00050/ - C6H 4I2 - 5 2 - - 4 2 0,100 + 0,00026/
C6H6 -2 5 0 0,0399 - C6H 4I2 - 5 0 - +80 0,101 +0,00026/
-2 2 5 0,0908 C4H6O4 1 0 -5 0 0,212 + 0,0044/
-2 0 0 0,124 - C6H4N2O 4 160 ^ 0,252 + 0,00083/


-150 0,170 - C6H4N2O 4 160 * 0,248 + 0,00077/
-1 0 0 0,227 - C6H 4N2O4 119 0,259 + 0,00057/
-5 0 0,229 - C6H6O2 / 163 ^ 0,278 + 0,00098/
0 0,375 - C6H6O2 - 160 - / 0,269 + 0,00118/
C i3H iqO -1 5 0 0,115 - C6H6O2 -2 5 0 0,025
-1 0 0 0,172 -2 0 0 0,081
-5 0 0,220 C 12H 10 40 0,385
0 0,275 C 12H 11N 26 0,337
20 0,303 - C6H 4Cl2 -4 8 ,5 0,185
C 17H i 2O3 -1 5 0 0,129 - C6H4Cl2 -5 2 0,186
-1 0 0 0,167 - C6H 4Cl2 - 5 0 - +53 0,219 + 0,0021/
0 0,248 C2H2Cl2O2 0,406
50 0,308
- C6H4BrI - 5 0 - 0 0,143 + 0,00025/ C2H4N4 0 -2 0 4 0,456
- C6H4BrI - 7 5 - - 1 5 0,143 C6H 14O6 20 0,282
- C6H4BrI - 4 0 - + 50 0,116 + 0,00032/ C3H8O -200 - - 1 6 0 0,051+0,00165/
- C 10H7Br 41 0,260 C6H5I 40 0,191
C6H5BrO 32 0,263 C10H 16 35 0,380
C4H6O6 36 0,287 C8H 16O2 -2 0,628
C 4H6O6 H2O -1 5 0 0,112 C 10H20O2 8 0,695
-1 0 0 0,170 C4H6O2 3 8 -7 0 0,520 + 0,00020/
-5 0 0,231 C 12H22O 11 20 0,287
0 0,308 C12H22O 11 <H 2O 20 0,299
50 0,366 C 12H24O2 30 - + 40 0,430 + 0,000027/
C 16H 34 0,495 C6H 10O5 40 0,607
C2Cl6 * 25* 0,174 C3H4O4 20 0,275
C8H9NO2 41 - / 0,249 + 0,00154* C 12H22O 11 20 0,320
C3H8O3 -2 6 5 0,009 C6H 14O6 0 -1 0 0 0,313 + 0,00025/
-2 6 0 0,022 C3H6N6 40 0,351
-2 5 0 0,047 C 14H458O2 0 -3 5 0,381 + 0,00545/
-2 2 0 0,085 CH 4N2O 20 0,320
-2 0 0 0,115 CH2O2 -2 2 3R7
0 CO
In te r n a tio n a l C ritical T ables, v o l. V, 1929, p. 101. CO


C e /, 0C
P - P t

CioH8 -1 3 0 -^ 0,281 + 0,00111/ C2HCI3O2 0,459


- C 10H9N 0 -5 0 0,270 + 0,0031/
- CioH8O 50 / 0,240 + 0,00147/ C2H4O2 200 -- +45 0,33 + 0,00080/
- CioH8O 61-7- / 0,252 + 0,00128/ C6H6O 1 4 -2 6 0,561
- C6H6N2O2 160 -- / 0,269 + 0,000920/ D- ( C6H 12O6 20 ' 0,275
- C6H6N2O2 160 -- / 0,275 + 0,000946/ )
- C6H6N2O2 160 / 0,276 + 0,001000/ - C8H6O4 20 0,232
- C7H5NO4 163 -- / 0,256 + 0,00085/ C12H 10O4 -2 5 0 0.017
-2 2 5 0,061
- C7H5NO4 66 - / 0,258 + 0,00091/ -2 0 0 0,098
-1 0 0 0,191
- C7H5N-O4 160 -/ 0,247 + 0,00077/ 0 0,256
C6H 4O2 -2 5 0 0,031
C 10H7NO2 0 -5 5 0,236 + 0,00215/ -2 2 5 0,082
0,167

. /. -
Ci6H32O2 -1 8 0 -2 0 0 0,113
-1 4 0 0,208 150 -- / 0,282 + 0,00083/
-100 0,251 C4H 7Ci3O2 78 0,509
-5 0 0,306 C2H3Ci3O2 32 0,213
0,382 - C7H5ClO2 8 0 -T- / 0,228 + 0,00084/
20 0,430
C6H3N3O7 -1 0 0 0,165 - C7H5ClO2 94 -- / 0,232 + 0,00073/
0 0,240
50 0,263 - C7H5ClO2 180 -- / 0,242 + 0,00055/
100 0,297
120 0,332 - C6H 4BrC b 34 0,192
C5H8O4 20 0,301 - C6H 4BrCt -5 2 0,150
C3H8O -2 0 0 0,170 - C6H 4BrCl -4 0 0,150
-1 7 5 0,363 C2H3ClO2 60 0,363
-1 5 0 0,471 C26H52O2 15 0,387
-130 0,497 C3H3N3O3 40 0,263
C3H6O2 -3 3 0,726 CH2N2 20 0,547
C i3H 10O3 32 0,289 C3H3N3O3 40 0,318
C 12H22O j1 20 0,299 CCl4 -2 4 0 0,013
C 18H38O2 15 0,399 -2 0 0 0,081
C2C i4 -4 0 0 0,198 + 0,00018/ -1 6 0 0,131
C7H5N5O8 ^r-IOO 0,182 -1 2 0 0,162
-5 0 0,199 -8 0 0,182
0 0,212 -4 0 0,201
100 0,236 C2H2O4 200 -- +50 0,259 + 0,00076/
C i0H i4O 0 -4 9 0,315 + 0,0031/ C2H2O 4 . 220 -2 0 0 0,117
- C7H9N 0 0,337 -1 0 0 0,239
20 0,387 0 0,338
40 0,440 50 0,385
- C8H8O2 54 -* / 0,277 + 0,00120/ 100 0,416
- C8H8O2 54 -- / 0,239 + 0,00195/ C4H 10O4 60 0,351
- C8H8O2 130 -4-/ ' 0,271 + 0,00106/ (- C2H6O -1 9 0 0,232
T C4H 10O -4 0,559 .) -1 8 0 0,248
C8H7N3O6 185 -- +23 0,241 -1 6 0 0,282
2 0 -5 0 0,423 -1 4 0 0,318
C7H5N3O6 -1 0 0 0,170 -1 3 0 0,376
-5 0 0,253 C2H6O -1 9 0 0,260
0 0,311 (.) -1 8 0 04296
100 0,385 -1 7 5 0,380
Ci9H i6 0 -9 1 0 ,1 8 9 + 0 ,0 0 2 7 / 170 0 ,3 9 9


* *

P- 4,0
2
-3 ,0

- 2,0
t,C
0
100
200
7 - 1,0

300 3 5 -0,9
6 80 0,8
48 0 -
400 11 12 V -0,7
IOQ
500 0,6
15 0 16 -

600 0*7 -0,5


700
7 20 - 0,4
800 - /-\ 19
17
17 D
900 22 23 O 0 ' .
1000
25
H
,30
29

1100
31 - 0,2
32
1200

33 -
1300 - -
34 0 "
1400 I
35
- 0,1
0,09
- 0,08
36
- 0,07
-0,06
1 0,05


,cC , 0C ,0C

26 0-1 4 0 0 24 400-1400 -21 17 0 -1 5 0


12 0 -6 0 0 36 0-1400 -22 17 0 -1 5 0
14 600-1400 ' 23 0-5 0 0 -113 17D 0 -1 5 0
10 0 -2 0 0 29 500-1400 20 0-1400-
15 200 - 400 5 0 -3 0 0 32 0 -2 0 0
16 400-1400 6 300-700 34 200-1400
35 0-1400 7 700-1400 30 0 -1 4 0 0
1 0 -6 0 0 25 0 -7 0 0 3 0 -2 0 0
2 600-1400 28 700-1400 9 200 - 600
17 0 -1400 26 0-1400 8 600-1400
27 0-1400 33 300-1400 4 0 -2 0 0
22 0 -4 0 0 19 0 -7 0 0 11 200-600
31 400-1400 -11 17 0-1 5 0 13 600-1400
18 0 -4 0 0

. 1-20.
102 . I. -

1-140 1-142
Cp 1 CpIcv
1
V
, t\ cplcv
-

N2 15 1,404
209 - 197 0,475
-1 8 1 1,47
-6 0 1,05
NH3 15 1,310
0 1,10 Ar 15 1,668
40 1,16 -1 8 0 1,76 (?)
80 1,29' 0 -1 0 0 1,67
100 1,48 C2H4O 30 1,14
C2H2 15 1,26
HO 1,61
-7 1 1,31
-2 5 8 - -2 5 2 1,75-2,33
C6H6 90 1,10
-2 0 0,313 Br2 2 0 -3 5 0 1,32
0 0,318 HBr 20 1,42
20 0,328 H2 15 1,410
60 0,361 -7 6 1,453
-1 8 1 1,597
100 0,419
. . . . 925 1,36
150 0,846
17 1,403
Jl4
Ul

I-

0,465-0,539

1,408

-7 8
( = 63 ) 1,415
-1 1 8
- 2 1 6 - -2 0 0 0,398 1,08
C6H 14 80
- 1 5 8 -V- - 1 5 6 0,580 He -1 8 0 1,660
-2 0 6 - - 1 9 0 0,0615 SO2 15 1,29
- 1 0 0 - +150 0,235 + 0,00046/ CO2 15 1,304

CCl2F2 25 1,139
N2O 100 1,28
1
15 78 . S 11, C ryogenic 15 1,303
E n gin eerin g, P rin ceton , N ew York, 1959, p. 279.
. J o h n s o n (ed.), W ADD- -3 0 1,31
TR-60-56, 1960. . . , , . II,
, 1960. -7 0 1,34

C4H 10 15 1,11
1-141
185 1,30
, I( ), I2
1,40
J^

HI
850 1,77
,
, 0C O2 15 1,401

1 10 20 40 70 100 -7 6 1,415
-1 8 1 1,45
100 0,237 0,239 0,240 0,245 0,250 0,258 19 1,68
Kr
0 0,238 0,242 0,247 0,251 0,277 0,298 19 1,66
Xe
600 1,113
-5 0 0,238 0,246 0,257 0,279 0,332 0,412 CH4
300 1,16
-1 0 0 0,239 0,259 0,285 0,370 0,846
-1 5 0 0,240 0,311 0,505
* International Critical Tables, vol. V, 1929.
103

43

t, 0C cp / c v

Cp Icv cp j c v

CH4 15 1,31 P t

P f
0
-79,4 O0 - 79,4
-8 0 1,34
-1 1 5 1,41
C3H3O2 13 1,06 25 1,47 1,57 125 1,69 2,40
40 1,09 50 1,53 1,77 150 1,74 2,47
302 15 1,14 75 1,59 2,00 175 1,78 2,41
CH4O 77 1,203 100 1,65 2,20 200 1,83 2,33
( C2H6O 6 -3 0 1,11
)
Na
750-920 1,68
.
Ne 19 1,64 .
NO 15 1,400 I-I44
-4 5 1,39
-8 0 1,38
CO 15 , - ),
1,404

-1 8 0 1,41 Xt . %
C5H 12 86 1,086 2,4 20,6 41 61
Hg 360 1,67
H2S 15 1,32
0 1,01 1,0 0,995 1,0
45 1,30
10,5 0,98 0,995 1,06 1,02
-5 7 1,29
20,9 0,96 0,99 1,03
CS2 100 1,21
31,2 0,956 1,0
C2H4O2 136 1,15
P 41,4 0,985
300 1,17
Cl2 15 1,355
HCl 15 1,41 1-145

100 1,40 ( = 20 )
CHCl3 100 1,15
() (CN)2 15 1,256 Xi . 96 . - 100 95 90,5 82,3 75,2
HCN 65 1,31
0,497 0,52 0,53 0,56 0,581
*
140 1,28
210 1,24
C6H 12 80 1,08 1-146

C2H6 100 1,19


15 1,22 Cp t Cpf
-8 2 1,28 !(-), /( - ),
,
. %
C2H 4 100 1,18 . %

15 1,255 15 326 I 15 32
-9 1 1,35
C2H6O 90 1,13 2,12 0,961 0,960 22,7 0,765 0,758
() C4H 10O 35 1,08 4,66 0,929 0,924 43,9 0,67 0,672

80 1,086 11,5 0,851 0,841 100,0 0,555 0,576
.
104 . I. -

1-147 1-151
(*~ 19 ) (* = 20 ) 1
f

Xt . 96 . . . . 0 0,497 1,64 4,76 9,09 * CX
4C Q
CS <3
Q
*
CS
* * * *
*
d * ?
1,0 0,975 0,93 0,814 0,75
CS * 8
2* 8
CQ *

* S
CX H
CX
<j * ,
j H X

1-148 0,34 0,9968 23,22 0,8205 37,69 0,7023 81,33 0,4481


0,68 0,9937 24,25 0,8127 40,49 0,6770 82,49 0,4467
1.34 0,9877 25,39 0,8041 43,75 0,6476 84,48 0,4408
2,65 0.9762 26,63 0,7945 47,57 0,6153 85,48 0,4346
, /{ - ), 3,50 0,9688 28,00 0,7837 52,13 0,5801 89,36 0,4016
5,16 0,9549 29,52 0,7717 57,65 0,5420 91,81 0,3787
Xy . % 9,82 0,9177 30,34 0,7647 64,47 0,5012 94,82 0,3554
15,36 0,8767 31,20 0,7579 73,13 0,4628 97,44 0,3404
6 20 33 40 21,40 0,8339 33,11 0,7422 77,91 0,4518 100,00 0.3352
22,27 0,8275 35,25 0,7238

0,99 0,945 0,947 0,947 0;947


3,85 0,828 0,831 0,835 0,837 1 V i n a l , G r a i g , J. Res. Nat. Bur. Stand., 24, 475 (1940).

5,66 0,77 0,775 0,778 0,775


1-152
7,41 0,727

, - ),,
1-149
Xy
( = 20 ) . %
0 10 20 40 60

CS <3

.
Xy . %
, . H

CX
\ <\1 CX

<\) ) <\> 0,0 1,00


Xy .

* *
9,09 9,72 0,72 0,74 0,75 0,78
JCx > Il
I_

* ** 16,7 0,61 0,605 0,631 0,645 0,678


20,0 0,58 0,575 0,591 0,615 0,63
0 1,000 30 0,730 60 0,640 80 0,575 25,9 0,55 0,61
10 0,900 40 0,675 70 0,615 90 0,515
20 0,810 50 0,650
1-153

1-150
( 38 )
(tf 21,3 ) 1
Xt . % . . 0 6,98 30,9 54,5 100
< fO <
Q CS

Xy . %

X
[ , . %

Xy . %

CX
<0 CX
* 1,0 0,911 0,73 0,631 0,535
<\1 <\
* * Si
CJ
S
. XCX
.
J H