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Chapter 4 Amount
Concentration
Density
Stoichiometry
Calculations in Analytical Chemistry
SI UNITS You must learn the units, the prefixes and unit conversions
In science generally use SI units are used but in Analytical using conversion factors!
Chemistry, due to the very wide range of quantities (from
very small to very large) we sue derived SI orr sometimes
non SI units.
n=
Example
How many grams of C is present in a 72.8 g sample of
Iron(III) carbonate.
.
Equilibrium Molarity is the molar concentration of a particular
cX =
species in a solution. This can either be calculated if the
relevant equilibrium constants are known or measured
experimentally.
Example
Calculate the molar concentration of ethanol in an aqueous Example
solution that contains 5.80g ethanol in 2.50 L solution Calculate the analytical and equilibrium molar concentrations
of the solute species in an aqueous solution that contains 285
mg of trichloroacetic acid in 10.0 mL(the acid is 73% ionized
in water).
Other concentration units Other concentration units
Try and avoid the use of these units. Only w/w is temperature
independent
p-functions
Frequently in chemistry the p-function or p-value is used to
express the concentration of certain species. This is the
negative logarithm (to the base 10) of the molar concentration
of that species. Thus for species X:
pX=-log10[X]
APPROXIMATION Example
For dilute aqueous solutions whose densities are approximately Calculate the molar concentration of Ag+ in a solution that has
1.00 g/mL. a pAg+ of 6.372.
1ppm= 1.00 mg/L
1ppb= 1.00 g/L
DENSITY AND SPECIFIC GRAVITY OF SOLUTIONS
Example
1. A 25.00-g sample of an orange compound contains 6.64 g 2. Establish stoichiometric factors between the reactant and
of potassium, 8.84 g of chromium, and 9.52 g of oxygen. product species
Find the empirical formula.
2. From the elemental analysis of 5.00-g acetic acid, we get 3. Use these factors to calculate unknown quantities from
7.33 g CO2 and 3.00 g H2O. The compound is known to known quantities.
contain C, H and O only. Find the empirical formula.
3. Analysis by a mass spectrometer gives the molar mass of
acetic acid as 60 g/mol. Determine its molecular formula.
Example