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Content
Introduction
Nanotechnology
History
Tools and techniques
Lithography
Approaches in Nanotechnology
Top-down/Bottom-up Approach
Nanomaterials
Types of Nan0-materials
Conclusions
References
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INTRODUCTION
Nano
The word nano is derived from greek word nanos
which means extremely small or dwarf.
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Manufactured products are made from atoms.
The properties of those products depend on
how those atoms are arranged.
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History (Contd.)
In 2000s, saw the beginnings of the commercial
applications of nanotechnology although these were
limited to bulk application of nanomaterials.
Silver nano-platform for using silver nanoparticle as an
anti bacterial agent, nanoparticle based transparent
sunscreens and carbon nanotubes for stain resistant
textiles were developed.
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Characterization Techniques
There are several characterization techniques used:
Scanning Electron Microscope (SEM)
Atomic force microscope (AFM)
Scanning tunneling microscope (STM)
Transmission Electron Microscope (TEM)
X-Ray Diffractometer (XRD)
Differential Scanning Calorimeter (DSC)
Thermo Gravimetric Analysis (TGA)
Thermo Mechanical Analysis (TMA)
Fourier Transform Infra Red Spectrometer (FTIR)
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Lithography
Lithography in MEMS context is typically the transform of
a pattern into a photosensitive material by selective
exposure to a radiation source such as light.
Nano technology
Approaches
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Top down method
Bulk material
Nanoparticle
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Nano manufacturing Top-down
approaches
Lithography optical, ultraviolet, electron beam, SPM
based.
Nano machining
Fragmentation - mechanical milling, spark erosion
etc.
Sintering of nano-precursors
Thermal treatment of metals, ceramics, composites
Fluidics
Nano scale robotics
Bio-evolutionary approaches
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Bottom-up approach
Self assembly from
Atom/Molecules
v
v
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Nano-manufacturing typical
Bottom up process
Controlled Nucleation and growth- aerosol, colloidal
dispersion, deposition on surface.
Self assembling- natural process in living system and
biomimetics, chemistry/chemical manufacturing.
Templating-Al and CNT, by substrate and local reactors.
Engineered molecules and molecular assemblies designed
molecules as devices or for self assembling.
Biomethods- selectivity, self assembling, synthetic biology.
Bottom up modular nano systems.
Controlled replicating nanostructures.
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Applications of Nanotechnology
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Nanotechnology in Fabrics
The properties of familiar materials are being changed by
manufacturers who are adding nano-sized components to
conventional materials to improve performance.
For example some clothing manufacturers are making
water and stain repellent clothing using nano sized
whiskers in the fabric that cause water to bead up on the
surface.
In manufacturing bullet proof jackets.
Making spill and dirt resistant antimicrobial, antibacterial
fabrics.
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Nanotechnology in Mobile
Morph, a nanotechnology concept device developed by
Nokia Research Center (NRC) and the University of
Cambridge (UK).
The morph will be super hydrophobic, making it extremely
dirt repellent.
It will be able to charge itself from available sources using
photovoltaic nanowire grass covering its surface.
Nano skill electronics also allow stretching. Nokia envisage
that a nano scale mesh of fibers will allow our mobile
devices to be bent, stretched and folded into any number
of conceivable shapes.
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Nanotechnology in Electronics
Electrodes made from nanowires enable flat panel
displays to be flexible as well as thinner than
current flat panel displays.
Nanolithography is used for fabrication of chips.
The transistors are made of nanowires that are
assembled on glass or thin film of flexible plastic.
E-paper displays on sunglasses and map on car
windshields.
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Nanotechnology in Computers
The silicon transistors in your computer may be
replaced by transistors based on carbon
nanotubes.
Nanorods is upcoming technology in the displays
techniques due to less consumption of electricity
and less heat emission.
Size of microprocessors are reduced to grater
extent.
Hewett packard is developing a memory devices
that uses nanowires coated with titanium dioxide.
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Nanotechnology in Computers
Magnetic nanowires made of an alloy of iron and
nickel are being used to create dense devices.
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Other uses
Cutting tools made of nanocrystalline materials such as
tungsten carbide, tantalum carbide and titanium carbide,
are more wear and erosion-resistant and last longer than
their conventional counterparts.
Silver nanocrystals have been embedded in bandages to kill
bacteria and prevent infection.
Nanoparticulate based synthetic bone formed by
manipulating calcium and phosphate at the molecular
level.
Aerogels, the lightest known solid due to good insulating
properties is used in space suits and are proposed to use in
space craft.
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Nano-materials
Nanomaterials : Having at least one dimensions
less than 100 nm.
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Nanostructured Materials
Generally, the nanostructured materials can be
categorized as materials whose inner critical structural
features are in the range of nanometers.
This can include the size of pore for porous materials,
the size of unit cell for those with crystal - like
symmetry, and the size of repeating unit (or
component) for hybrid or composite materials.
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Applications of nano materials
To improve mechanical properties.
treatment etc.
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Nanoparticles
It refers to materials whose all three dimensions are in
the range of the nanometer scale.
All particles, regardless of shape, can be referred to as
nanoparticles as long as all three of their dimensions
are in the range of the nanometer scale.
This can include small dust particles, aerosols,
colloidal objects, quantum dots, small metal and
semiconductor particles, and so on.
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Nano-Particles (Contd.)
Sunscreens are utilizing nanoparticles that are extremely
effective at absorbing light, especially in the ultra-violet
(UV) range. Due to the particle size, they spread more
easily, cover better, and cost effective. They are transparent,
unlike traditional screens, which are white.
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Carbon nano tube
Carbon nanotubes are allotropes of carbon with a
cylindrical nanostructure.
They have length to diameter ratio up to 1.32 x 108: 1.
Nanotubes are members of the fullerene structural
family. Their name is derived from long, hollow
structure with the wall formed by one atom thick
sheets of carbon, called graphene.
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Properties of CNT
Highest strength to weight ratio, helps in creating light
weight spacecraft.
Electrical resistance changes significantly when other
molecules attach themselves to the carbon atoms,
helps in developing sensors that can detect chemical
vapors.
Easily penetrate membrane such as cell walls, helps in
cancer treatment.
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CNT applications
Easton bell sports, using CNT in making bicycle
component.
Zyvex technologies, using CNT for manufacturing of
light weight boats.
Replacing transistors from the silicon chips as they are
small and emits less heat.
In electric cables and wires
In solar cells
In fabrics
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Nanorods (quantum dots)
Nanorods are one morphology of nanoscale objects
having dimensions from 1 to 100 nm.
They can be synthesized from metals or
semiconducting materials.
A combination of ligands acts as shape control agents
and bond to different facets of the nanorod with
different strength. This allow a different faces of
nanorod to grow at different rates, producing an
elongated objects.
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Uses of nanorods
In display technologies because, the reflectivity of the
rods can be changed by changing their orientation
with an applied electric fields.
In cancer therapeutics.
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Nanocrystals
Nanocrystals absorb then re-emit the light in a different color
- the size of the nanocrystal determines the color as shown in
Figure.
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Applications of dendrimers
Dendrimers can act as nanoscale carrier molecules and
as such could be used in drug delivery.
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Nano Composite Materials
Phase-1 (Matrix) Phase -2
(Reinforcement)
Nano
Composites
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Metal matrix Nano composites
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Polymer matrix Nano composites
Polymer matrix
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Nanocomposites
Pacific Northwest National Laboratory have developed
a coating process to make sponge-like silica latch onto
toxic metals in water i.e. SAMMS nanocomposite (Self-
Assembled Monolayers on Mesoporous Supports).
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CONCLUSIONS
Nanotechnology is a vastly growing area and has high
potential for research and development work.