Determination of Magnetic moments CHEM2031

Fill in the experimental data, then insert formulae into the blank columns to calculate the number of
Student names SID unpaired electrons for each sample. Assign the d electron configuration, geometry and spin-state for
Steven Chan z5021457 each sample
Put your names and
Kam Wan z5062098
SID here

Temperature (K) 298

In this column, In this column, assign
assign the actual the d electron
number of unpaired configuration of the In this column, assign the
electrons in each metal ion in each geometry and spin state of
Enter your raw data into the cells below Add formula to these cells to calculate the number of unpaired electrons. complex complex each complex
Correctd. Mol'r Expt Mag Calc. #
length Mass Molar Mass Diamagnet. Corr. Diamagnet. Corr. Mass Suscept. Mol'r Suscept. (m), Suscept. ('mcorr),x10- Moment Spin magnetic unpaired Actual # unpaired
Compound Ro (empty tube) R (sample) (sample/cm) (sample/g) g/mol x10-6 cgs/mol units x10-6 cgs/mol ('g), cm3g-1 cm3mol-1 6
cgs/mol (expt,- B) moment (s) electons electrons d electron config Geometry and spin state
Ni(acac)2(H2O)2 -30 320 2.4 0.092 292.9 -148.0 0.0 9.17E-06 2.69E-03 2.8E-03 2.60 2.6 1.8 2 8 high + octahedral
Ni(dmgH)2 -30 -40 1.8 0.057 288.9 -107.0 0.0 -3.16E-07 -9.12E-05 1.6E-05 0.19 0.2 -0.6 0 8 high + spuare planar
Fe(acac)3 -30 1120 2 0.064 353.2 -175.0 0.0 3.58E-05 1.27E-02 1.3E-02 5.53 5.5 4.7 5 5 high + octahedral
Cu(en)2(NO3)2 -30 140 1.9 0.099 307.8 -141.0 0.0 3.26E-06 1.00E-03 1.1E-03 1.65 1.7 0.9 1 9 low + octahedral
K3[Fe(CN)6] 0 430 3 0.254 329.2 -127.0 0.0 5.08E-06 1.67E-03 1.8E-03 2.07 2.1 1.3 1 5 low + octahedral
[Fe(bpy)3(PF6)2 -30 -40 1.8 0.069 814.3 -456.2 0.0 -2.61E-07 -2.12E-04 2.4E-04 0.76 0.8 0.0 0 6 low + octahedral
[Co(en)3]Cl3.3H2O 399.6 -265.0 0.0 0.0 0.0 -0.8 0 6 high + octahedral
K3[CoF6] 290.2 -115.0 0.0 5.2 5.2 4.4 4 6 high + octahedral
K2[Ni(CN)4] 241.0 -90.0 0.0 0.0 0.0 -0.8 0 8 low + square plaanr
K3[Fe(ox)3] 437.2 -124.0 0.0 5.9 5.9 5.1 5 5 high + octahedral

Data to be replaced with student data

Cells where formulas must be entered
Samples where data is given, not measured in this expt.
Supplied data and formulas
Cells where answers must be entered