CHEM 154 PROBLEM SET 2: Due February 16, 2017 Tuesday

A complete solution is required. Use only bond paper. Include the original questions.
Provide the derivation, graphs, linear equation and coefficient of determination.

1. The following data for an aqueous solution of a protein with cp=2.0 kg m-3 were obtained at 20
C with laser light at =532 nm.

/ 15.0 45.0 70.0 85.0 90.0

R/m3 23.8 22.9 21.6 20.7 20.4

In a separate experiment, it was determined that K=2.40 x 10 -2 mol m5kg-2. From this information,
calculate the radius of gyration and the molar mass of the protein. Assume that B is negligible
small and that the protein is small enough that eqn 19.9 holds.

2.

3.

4.