Part-I Annual Examination 2008" ‘CHEMISTRY Time:allowed:3 Hours Max: Marks: 75 Note: Attempt any Five Questions. | Q.1(a) Explain the following. 06 {.Zera as a significant. 2, Exponential Notation 3. Limiting Reactant. | ' (b)Acetic acid contains C,H and O. 8.48 grams of sample on complete combustion gave 12.42 grams CO2 and 5.08 grams water (H,0). The molecular mass of acetic acid is 60. Find out the E.F and M.F of acetic acid. 2 | Q.2(a)Derive General Gas Equation, | (b)A given mass of a gas occupies 90 dm? at arc and 940 torrpressure. Calculate the volume atS.T.P, (c) Why a liquid boils at different temperatures a sea level, and TMountain level? ‘Q.3(a) How did Bahr's atomic model explains hydrogen spectrum? (b) Differentiate between: | 1, Continous and line spectrum. : 2. Sigma and Pi-bond. Q.4(a) Derive an expression for the calculation, of radiusiof an orbit with the help. ‘of Bohr's feo (b) Write short note on “Bond Energy” (c)Explain the shapes of HO and NHs on! Eleetron repulsion and hybrid model. Q.5(a) State and explain Hess's law. i (b)Calculate Heat of formation of Berizene:- 6C + 3Hp —3Ce He AHF =. i. C+O0;—> CO, AHS- 384 K ii, Hp + 4.02 —5 HO RH S- 286 kj ill, Co Het 7.5 O2—& GCOZ+ 3H2O AH = - 3267 kj z Q.6(a) Define chemical bond, Explain by giving examples of it's different types? (b} Write down molecular orbital diagram of the Eee i CHa i.C2 Ha ii,Ce He Q.7(a) Describe the industrial applications of Le Chatelier’s principle. (b) What do youmean, by common Ion effect?. Q.8(a) What ig meant of Solubility product? Give it's uses. (b) Givé'main points of theory of Ionization? Q.9{a)Explain Hydration and Hydrolysis? (b) Calculate the ox: iv. Me'He © i MOg 3 v. Naz MeOs viMer O4 y i Q.10 Write down the short notes on any Three of the following. 15 i, Activation Energy ii. Neutralization fii. Oxidation and reduction reaction y. Hund’s rule.