I GATE - 1999 I u!

'M

It==:- CHEMICAL ENGINEERING

:.=::=====:=:J
SECTION A 3, 1,25
b I3
(75 Maltul)
c. 1,35
ONE MARKS QUESTIONS (1 - 35) d. I .2
For each of the followmg questions ( I IO 35 ), four Puru A in gQS phase e~uers a reactor 5(\%

om
altemati"es - A. B, C and 0 arll pro1'ided. of Lhts A is conened to B Uuougl1 the
U1dicate the correct answer by writing A, B. C or tll{lction A~ 3 B. Mole- fracnon of A .iu
0. ns npproprinte, !\Dinst the corresponding the e.XLt streaQl iS
question number in the bloc~ 1n the ~tSIH:r book.
1/2
(1,
I Marks : I ' 35 = 35)
b 1/3

.c
C, 1/4
The system of equations.
d. 1/5
2x + 4) e iO

ce
7 Which uf the folloWJII!l is true for Vtrinl
Sx + 10y = 25 equation of sUIto
n. bas no w1ique solullQn a. Vinal cocff:ictems are wnversal
b. has only one solution ra COilS UlnLS
c. has only two solution:; b Virial coel'ficient B represents thr~e
d. has mtuute solultons bod)' onteroctions
.2 , Four .fnir coins are tossed simulUlilcously c. V.r"11 coemcrents are funchons ol'
The probabi li\)' ~lal nt least one head turns tempernturc only
m
up is d For some gases, Vi rial equations and
1L 1/ )6 ideal gas ~quations are the s;une
b, ISf[(i 15. A g:rs mrxture of three componenLS t~
xa

c. 7/fl brought in c.ontact \\~lh n dispcrston of an

organic phase in water. The degrees of
d. 1/R freedom or the system are
a. -1
.e

3. b. 3
' 5
a. ll d, (i
w

b A pr.pe or I D 4 m is bifurcated mto Lwo

pipes of LD. 2 m each. If the merage
c. 2
w

velocity of warer nowwg through !he .main

d. 3 prpe IS 5 m/s. the average 1 elooi Ly through
T he hannonrcseries L-;;I
~ the birurcared prpes 1s
w

rl JJ a 20 ruts
n. com'erges for p > 1 b. IiJ m/s
b. Jiv,;rges for p > I c, 5 ../2 m/s
c comerges for r < l d 5 mls
d. di verg~s for p < I Ill, In centnfugal pumps. cantallon occurs
5 1\ solution of spec.fic gmvlly J.U consrS1s 1vben pressure of the impeller eye or vane
of 35% A by 11e1ght and the ceruaioing B becomes
1 !he speci [tc gmvtt) of A is U7, !he ,~ Jess thnn nrmospheric pressure
specific gr:wtly ofB i> b. more tban liqurd \'apour pressure
 c. le~$ Otan IJquld vppour pre<sun: a. is oflow Yolntility
d. ono111 thlln ~tmospberle prcssuru b. fotm~ A low-bonln.g uzco1rope
Lt. Fut IMlinnr l1o" thrOugh pocked bed. c, forms hiAhboilioj!. l!Ztolrope
the prcssul'C dr9p 1$ proport.iona\ to (V, j, d. ~~ nnl 11<:1' tbc t'Ciativt l'lllatility ur
the superficini Ii~uid ~do~it.V :md Dv is thc- the original component!.
J>Ilrl ielc diameter)
18. The r~vcry of ponicillln from tb e
a.. V, /l)p' acidified fennent1>1ion broth is done hy
b, v/ D1,l 11; distil Iali on
C. \ , ' I'_.,I,J b. <:Vopomlion

om
d. \1 0 vD.' c. absorption
12. Por n tu<bin...agit.1t d and ))all:led t.1nk:. d. liquid ex~e~on
o perating at low Reynolds number (b~sed
19. Pe:nclratioll tln:ury sla""' Utal the maS-~
on m1pcll.:r dinm<rter). llw powe1 number tronsfer ~'tlofficienl is equal lo (where D, is
(Np) vori~ will1l'<R,. ~s diffu.,ivity and t is time)

.c
:~ ~'~t \'l NJU (D,I)' ~
IJ. N, a ,fN._: b. (DJt{~

ce
c N,- ><:ostanl .:. (-ID,I(nt)) U2
1
d. N0 11IINo. d. (4D.,Ill "

13. Gibbs pluts rule finds oppli"ation whon 20. A n alka1inesolullon is used reduce tlt~:~
lo
heottrnsfer occurs by ra concentntion of cnrbon dioxide in o
3, oondnction
slrcaru !rom I 0 In 0. H o by obsorption
wilh irTeversible chemical renclion. The
b~ convec_tion ovem ll number of lmru;J'e.- units based on
C. J'>ldi3tiOli g.. phase is
m
d. c:andt:usntion . 9,2 1
14. As the dill'wenc:.: between Ute wall b. 4.605
tcmporoturc ond the bu"' tempcrnllll\l c. I()()
xa

locre.1~es. tha- boiling he.lt lrJmfi!r

d. 0.00 1
CA>eJiicicnl
2 1. (n.,rnll ordl!l' of reaction for which nle
a. continues IQ increnst:" conslanl ha~ units of(mol L) ~.\'% ~ec' 1 is
b. conli ouef\ to decrease
.e

. - 3'2
c g<JCS throush ll minimum
b. 112
cl s~ thw ug h maximum
c. 312
15. tn pipe llow. bc.1t ~~ itonsf=od lrom hut
w

\1 all In the liquid by

d. 512
u~ condoctinn only
22 Forlhet'eactionA 1D _,.2B 1C.
ll, I"A ~ lb
w

b. forecd ~110\'C~:tion unly

e. .foJ'ced ~.:oovcctiou nud condut:t.iou b. rA = -1'fl
rl. fret: lind CmeeJ cOnyj:ctino "' r, ~ 2 l'fl
r,
w

16. tlcot IIant ler uccun; by nawrnl corwcetion d. = l'fl 2

becnuse chanJ!,C In U.'tl\l'trnmre Couse 'I he .:xi1 uge dislribuli<m cun'e l;(fl) fvr :m
djfferCJ1ces in id~ul C'S'fR Willi I!Jt UVcr:tge residence

n, vis~ns ity lime'<. is g.lvcn by

b. density a. e"1'
ll. lltcmJill i!l>ndud i1i1y b. ( I t )e ~
c._ l_t:;~
d. heat ""pacily
l7 So lvent used in o.xttoulive distillati.oro d. 1- ( Ut)ol/<

An endothermi~ second-order rea..:tion l>
l!lllrled out ln n adi:tbatic plug flo\\
rcttetor. The rule nl'btalgcnerallon i~
~. maximum althc inlet oflhc rca~lcor
b, ma.~imum at thce;(fl oflhe reactot
" mxximum at the ~enter or 1herea~tor
IL c<Jnst3nl throughout the r~clor
2 5. rbe LapL!co lran.Com> of ~p(al), where n
~ 0. is ilc:fin~:d rm ly Cor th.: !,place
3 u{~
30. HMtcUoy C is d .good m:rtwl ot'
construction In cllamica l process industry
sin.:e it is.
a. high ly eorto~ionfCliislont ll'lld is
r<:-'ltlily tabticaled
b. relative!~ inc.xpcnive alllitl"!!h it con
l>t>fallcicotcd witl1 """c di.Jljc.ulty
c. corrosioorcsisl3nl lo rnosl nlkalis,
pnrticu!ttrly because of it~ ru CClnlent

parnmolcr. S > ct. since
a. the function is e.wont:ni.Jnl 3].
b !he L~ploca-transform Integral af
~nt) llliS finjte vnJu.,: only for s ~ a
.:. ll1e Ln1lla~e-transf01m Integral of
om
d. ligltt ond rei.,l'i ollaek by ucills
[n a l1ca1 O.'lc)langcr, lloating hcd Is
)lrovided to
a. l1>Cililate clcMing o.f Ute cxchngcr
b. increase Ute heat b'l>nst'e1- atCJ!

.c
""p(nt) hru! initial values onl) fou a .:. rdiew llr""'"' o:4U>Cd by lhQ'fllal
d. lh.: fimllllon exp(ll is pidl.le-wl~e cxpan~lun
continuous only- for s a d. .inuronsc U1u Jog moon lom>pCTllture

ce
26. A system "ilh a doubt.. pole ot lit'> origin gradient
is anstablo since the conusponding tcnn iu 32, Suc.nlS-C is a disaccharide consi~ting or
the lime domain a. glucose md _glucose
n. ls a const-ant ra b. glucose nnd fru<:lose
b.. grows- e~-,>onenti:aUy with time. c. gluoose and ~obdo.e
c. grows linonrly wiU1 time d. fructose nnd gruactose
tl. aooay lin.:nrly will\ tlmd 33. The organiil add monomer In :Nylon G6 tS
m
27. A ~inusoidal variation in d1.: inlnJt P""irrg 11. $ebootc ac1d
through linear firsl-order system b. terephtll"lllc ~cid
a. b<lCOrnC.S moro Cllscillolor:y (frequcnc) C. dipic 3CIIi
xa

incrooses)
d. bL'IlZnic acid
b. become.< less oscillatory (i'n:qu~ncr
decrea~es)
34. Which one of the lbllowing is noL lil!dy IIJ
be li con.<tituenl.ufvegetoble Oll!?
" gaL< nmplificd (magnitude mcreases)
.e

:a. citric acid

d. gi>l oUcnuatcd (magnitude decreases )
b. o!ejc dd
28. A typical example of physical system
t:. $I CUrie m:id
wrtll itnderdamped cllarncterislics is
w

:t. IJ-tube m..1nometer d. glycerol

h, <prin&loaded dil!plmlgp> vlve 35. n,e gtt5 "hielt t\lntrihuk-s the ma).imtJm
'" tlte healing value or natural ga;, i
w

.:. CSTR wiU1 .Gil!t-ord.:.1' "'ant ion

11- lhc:nnqc.ouple lttpt iruntol!'Scd in
. co
liq ui<l-filled U!ermowell l1. CO:
u,
w

29. ln tt manufacturing lndu~uy, bt'I:Jlkel'i!!11 ~.

pOint occur. when d. (.'HI

;t. Lhe total annual r~tc of prod11ctiOt1
equals llle ssigned ' alue
ll. Ihe tom I nnu~l product co&1 equt~lsth~
i<lbl ann\w I ,.].~
c.. the annual profit oquals the c~ected
value
d. Ihe llllnlllll $al~ cqUHlllhc ti:..ad C<lLs
ie,',l ,\f '.l:1 111 ~ $[1:: If{ t!II
Fat each of the lo llowin.!l qm:stions (36 to 52),
four ~llc'tttotiv"" - A. B. C 31ld D aro pmvitkd.
Indic.Jlto the corTCc( answer by writing A. R C or
(). os appropriate. against the coiTilSpondinJI
question num!}t:r In tho answer book. For
 J ura
questiont 53 to 55 two itclll!i are indicoled in the
lcl\-1\and column lind oil; items in !he righHmnd
column. Each item in the icll-htmcl c41umn It
closely ossoeiatod \Vith one of the items in the
b. ( rW ' --( {!1"
righr-hnnd I.'Ohnnn. F'or ench. <tue<~Lion, write the
nppmpriBte mnlch in t)le cQoTe.s-p<mding i)(IX in the
t,P t.., ili ...

C~ t. =( :~'.
11n.1wcrboo.k
!Marks: 2 20 = 401 c.

r:: t ,.l~~ ~...

36. A box C4lnLiins S bnll. 2 of whrch an:
defective. The pmbnbillry that none oflhe
boUs drown aJ'e doooCiive when lwo ore
drBwn nt random without rq>lat.:c:ment is
" 15f2S
om
d.
.jf. Velocity ofn ~ moll p:lrtlclc Qfdiornch.1' Dp
at " 1li~tJmc~ r lrum lhe rotation I axis of"
cyclone rotntlng nl n l\!luL1r Apeed co i<
civeu b)' (tJte 0 tl1er S~>JI bois are OS peo

.c
b. 9116
stand:trd nol~t.ion)
1:. 7116
d. lJS a, (D,p,-p)lllr
I~

ce
37. f'hc tirn~ic:nl 01" S),l + yz-l at lhg point (- I'
t.l, t) is
b ( l)'cP,- p)filr'
n. 3i- Jj+3k 18 Jl
ll. 3i-3j+6k
" P.- p)nhJ.
c. 4o-:i- 3k
d 4i- ;\j+6k
ra rD~
18 ,,
S<l1urnted ~olutign ol' benz""e in wnler is ln
d. [ D'~ f/,- Jl l~h
:"8.
m
equtltboium "ltlr A mixuore <>I' alr and
I~ fL
""JIOUI'll Of benzene and Woter ul tOCliO
tcmllCtllture bOd Jl<Cs~=- Mole frntlion of -12. \Vater is Oowing :ll l m/~ tJtrougll a pip~
ben1..ene tn liquid is 'Xn nnd the vp11ur
xa

(cJf 10 em J.D.) "itl\ o right angle bend.

pre:<sures ol' hen.letH' and water at thc:.c The l'o l'l!c in Newton~ e:<ertoo C'1l the ~Cild
.:onclitions oro p,8 41\d 1>.w r~pCL1ivc:~l' by the watcr i~
Ute part~! pressor" of b<;nzone in a1r-
vopour mL'(tU['C is
. 10../2#
.e

;t, Pn b. S1r 2
b. sup. 9 c. s..fir.
>l, (p- - Pv"') 11]1 d. 511 ..fi
w

d. l!<np..,.. .IS, Rllte of heallrnrtsf<l Uttuugh a Jlipe w~ll is

~9. For lht r<Ntniibl~ rt::~cti<ln A [] 28. iflht given by
w

t:<~Uilibnum C4ln.,~1nt K is 0.05 moUnt, liJrk[T, - / 0 )

In(~ )
~Utdin,g frmn initially "2 moles of A and
zero mnles of B. how mnny moleo will nt: q
w

fmmed t "''uilihrium7
.1 (1,25~ f'Qr cylindim< tJf very thin wall. q C:tll be
h. (J 338 approximnll!d by
c. O.IS2 " " llrkJJ ~ 1~) 2]
<L 0.637 u. , )
In ~
-10. Mnxwtlrs oolatiu11 cur...,.puudiug tu the ~
td<mtity.dU - TtlS I '\'dP > ~f!Jdnt ill-
2nr,k(T 1;.)
b. 'J - _,._,.__,...,'"-
(r,, - r )
 sura
2nf<(T - T0 ) b. 0,6
IJ -
>).
(r.,-r, ) e. o.s
d, 0,2
L 2irk (T To) -18. For the liquid pbll!IU tt:roo(tfd~ irrev~siblt
'1 -Jr,+r,)/2]
l'll>cllon A > B, tho. corove,..ioo of A in
44. For a coumer-cm-r.:nt ltJ:OL cKalt:tngcr wiU1 C'STR i~ lilund 111 be 11.3 Ill " "I'"""
T'to= 80 C. T, = 60 C, T~ =50 C, and T 1, 1eiO<;ity of 0.1 min 1 Whnt will be the
= )0 r. and Inc tempermure ditlero1ee convcrston (or f'FR with space velocity
betweeu Ule IWO >lt'tmms being u.e S3111C ot0.2 mrn- 1 1 j\sume llint tb<l alllhe other

om
e\'01')'1\'b~rc long z, the direction of flo" opcpting condJtion are the s:nne tor
cof the hC)t lluid, the temperature prolile CSTR and PFR.
~1\ould satisl) ;1. 0. 15
J'T " I'l b. u.:;
II. l
<I: c. (),(j

.c
J'i d. 0.9
b. - ,=II -19. Consider the oU1 O)rdcr io'C\'Ct'Sible liquid
(/z_
phose: rcction A- B. Which one uf the

ce
c.
'''<1:"r 0 f<JIIIJWing. pl<m mvolving hnlf-lif~ nf the
t>:aetiun (tn.l oud the initi~l J'dlclanl
d. i/T - () conecntrt i~n (C.~o) givCII strisht Llno
<I: ra plot
-IS, \Vall of' a oubical oven an: ul' UJicknesa L C,..,. v.-.. lt;:t
and tbuv '~ tUJ~de of moteriol of tbeowol
couducti,.iLy,. k. The lcmpcwature _i:nside the
- lu C11o
~.
e, CAn"' In t 1r.t
v~ It ~

oven os I 0() C and the inside heal l:rof\Sfer

c.,., vs. In
m
d. In t 112
'
C.Qt:j]j etent '
Hi T:'ill _If u1e
1 ' W3 I"u lt:m{'trnl.ure 50. At a gt''"" va lue or E/R (J'lltio ..,r octivat.ion
enc'f8Y nod go:~ constant). Ute t11t.io llr the
un the owt~ide is= held At 1S C. what ;.,. the
xa

rote oonstrutts M 500 K ond 400 K is 2 if

inside wuU l<!mp<:rature iu degn:Cl, C'l Arrhenill$ Ia\\ m used. WhAt 1-tll 1> this
n. 355 mtitl il' trnn5itlllnsiatc Ulouo-y i~ Ulled with
b. 43.7S 1111~ snme VAlue of EIR!l

c. 8l.25 a Lli
.e

d. 48.2S b. 2
46. lf the $pecitic heal$ of :1 gas and o vpour \:, 2.24
nre 0.2 ~.likJ! K nd I.S kJ kg K d. u
w

re-spectively, 1111d the ltutnirul\' is 0.01. the S I. A C<mtrol Y~tem hlL\ Ihe followins
lmrniil heal. in k.l/1..1! K is lransler runcltun,
w

l l , 0.31 a. I
b. 0.1Ci7 b. liS
1!.0.017 c. 7/R
w

tL 0.215 d. l
tbe Vapour pressw-es of l>enzene und Which of tl1e ~y!<tcm l~>V1J18 tlJe followinll
wlucnu aJ'<> 3 and .\1~ alluu;phcre; lTan5fer filnctlons i~ .!<it3ble'l
rc:sp<...:tively. A liquid Iced of tlA mules of
bc'117.eni: ;md t),6 molll'l nf toluen~ ;, 1
a.
vaiJ')rit.ed. ."-~sumin~ tht tile pl'(>dlli!ts ~r" 72
in olquilibtium, the vfipout tlh~!e mole I
lhlction of bcn7.<.>ne ;, b. 1
s - 2.; + 3
"' o.~
 6 ufR
SECTION.
flwe Merb a-t.._ (II A 71
cxp(- 20.r) A.uJ\\'et tlfJ) JV~.t~Jt qot'bl.'ltle
d.
'.,- 2, - 1 (1\latl.,s: .5 1.5 - 751
53 Euch item gJven in the lefl-hlllld rolumn Is I
closely ajsi>Cifilt:li \ 1ith a specific ~(i. l::vnluate J( 4K' -t .1').1.> hy ltupezoldl
chnrnct<~i,tic listotl in the riJ~hlhund
~lumn. t.latch <!.'lch of'lhe item~ 11~Lh the
'
t'Ulc, Usc ~ J!tap ize of 0.2. Ohlll iJ1 lite
UIJrfC$ponding charJtlcri~t lc. error b{>nnds for this solution. ('ampule the

om
ahsohth>error of the nnmeric.1l solution hy
(\\'rile hoth aJts\\c:rs in 13nx Nn. .53)
evolualing the integral analyll.u>ll) .
A. 'l'rlnl>'J)IIrl:ni<ln htl!
tA
I;! Control vnlve S7. Solve tb; - 6XJ=-6x by the following
J. lnc1'ease in gam mar_gin metb<xls:
2, Phose l.ag i< proportional to fiujUC!lCY

.c
a. vnrintjon of L>i'lrnmeten
3, H)l"'rbofic b. ~eparntion of'\13riah les
~. Unslllblc rospon>c 58.

ce
5. luOJ\!35~ in pbaso murgin a, AI what. poinls are Ihe CaucltyRciman
G. Pba~e angl~ i~ - 90 eq\lations satislied ror lhe fnuellon,
S4. Each of Ute methods given in the left-band F(z) xj -t i x."y 1 Whetc> i f.(z)
column i! closely Jink"d to one> of thd ra analytic?
items listed tn tltc right-hand column b. Compute lbc distinct cube rool5 nf
Match e.1ch method witl1 the (H).
corresponding item. 59. II is proposed to produce occt.llch::hydo by
l Write both answe~ ul Ho~ No. 541 o;odation of ethanol m gas ph:tSe
m
A, Discounted cah !low C,fl, OH (g) ' 112 O:(g) - > ClhGIO (g)
B. D~llning balance H:zO (g)
'The ratiO of atr to elbnool in d1e fl-esh tbed
xa

I. Depred ation
2. Jluyout poriod (before it i.s mt,ed with r.:cycle stn:m) i>
10 to !. The c~>nver:siou Qf ~th~nol oo
3. l'rolit.1bitity ann lysis
single pa!s through the rc.ctor is 25'1., l11c
-t Solvlli!~ \loluc unrcactcd ethanol is completel) separated
.e

.5. Annuilv fi'om the TCI\Ciion products and rooycled.

(i. WClr-king CJ~rll.al \Vital i U1e talitl of rccy,lc stream Ill the
55. l'vlntch each rol)mer mentioned in the left- fresh 1<.-ed ~tremu? \Vhnt i the
w

hand ~11urn11 wi01 Ute corrc:spouding camposititm of the QU[Iel >1re:tm. lh>m th<:-
cbc"llllenl nature listt d ln the ri!fll~hruul n:ctor in mass fr.tctinn nnd n111fc l'rncti&?n'l
column. 60. ("nCO., , lurry has In be dried. l11c drier i~
w

(Write both Answ~ in Box Ko. jS) dcigoed l<1 l'llJilQVe 100 k& mot>litre fl<r
hour, r\ir I 20 C ~tnd 40o refalivc:
A. Pcrs,>c:>< humidity. enters the dncr and leaves nt 65
w

B. Rnyon c nnd 65o rolative humidity. Whal ts Ihe

I. Pol )'AO~chartde weight rin kg) of bon.c-dty nir rcquU'ed per
L Pllyamtdc hour? Th<> ntrurnophcric pras.utt i 103
kP:a. If the} humtdity <tfthe ntr entering the
:;. P<llyllt.'fylatc
drier c.nn bt: V:lried, whal i" t.bt: minimum
.t. Pol)ester amount of llry ir r<:quired2 The -oM;t..ln~
5. Polyether for Antoine e<Juotion for vqpour pressure.
6. Pol)'lllefin of wnter Iii mni Hg may be taken ns A =
IVOii. B - 3816.#. ~nu <: ~ -46. 1J.

61 For Ute binary ~ystem methanol (I ) and
J)cu:tcnc (2). the fC<!OlllffiOOdcJ VaiUilS ol
the Wil90n pu.mwelers ul 68 C ur" A1: =
0. L7.5 1 rmd A~t - 0.3456. The vupour
press"'" of pur" spedos ut68 Cure Pt.. -
68.75 kl'a und P:i"' ~ 11.5.89 kPil ShQ\1
~tal tho given s:y~1c tn cHill lorm ,UJ
ll't<!otrupe a1 68 C. A~um" thuJ Ute VIIJli>Ur
ll.::ltavcs liko au itle:Jl!!,U.S..
62. FI0\1 I'Ule or II'Ul~r llowin!l tlut>ll~h a f'lJl"
is being UIC'.JSUI\:d by usina an uriticu
ruerr tL~ slm u in the Gollowllig figur
a. What ts l.bc d~recdon ol' lluw rn tho ra
pi l"''t
b. Dcm e an expression tbr vcloolh'
thruugh tho critic<:, l:l.--t~nninctlte n..;v
rnt.o ll'r ou urdice cncl'ticicnt nJ' 0.8.
m
()J Don\'..: nn cxprossmn to obtam the ._.lfiU
required IO op1pl) the \'O!!Scl con taining
1\'atcr as sb"'ll In thG fol l~"iug Jigure.
xa
'J'hc cmss S<>clionol urea of tho opening at
tho hu11ouo nf Ute tullk i ~ u. As!nuuo that I lot
< II
T
.e
H in wnt~r is '2,574 -< I0 atm m3 mnl,
w
1 68.
w
6<1 ui JQfviscostrv 100 cT' IS to be pumped ns
w
shmvn in the Jollo\vtng figure. n te P'Jl"
u:<cd cl'ery whcr., ol" 7 em J.D. If tho
ofGci~IIC)' uf IIJe fttiiJIJl is 80 ''%, lind the
CJtcrsy n:qUtred for pumping. lite oil ni 20
uo1'hr. o~nsity t>l1he oil Is 800 kgnn3
"I til ~
T
om
65. Obuun expn:ssiuus [or Sb>udystat~
toUlJ>Crulure prolilo nut! beat tmusfcr mte
for u hollow spbencul contnhter. n,_,
iwt~t
SU$[Oce (nt r = r,} is maintained ut T ~ T,.
and the outer Sllrlllce (at r - r,,) is
muiutained ut T - '1'~.
.c
(,(, , 150 kg of wolcr is lo be heated in n slcom
J3CI.et~d v-ossel (r('lm 2.5 C IC> 80 C. St.:auo
ts ooutlcJU;ing ut 110 C. and the heal
ce
transfer urea ts 0.15 nl! 'l'lo~ h"11l trnusfer
coetlicio>nls lbr c~udeusatiou {f steam and
.
heating of wmer bv - couvecuon
,
Wim C sud 500 W!nt C r~spectwelv
arc I00(1
Writ~ appropn:nc uusteadv balun<:<:
C<JUilttuns 11nd liud the tlme ~>:qwred for
ile:JUD& th~ W~tdf AssWUd tllol. tll< Sfi"O[UO
hem Of Water iu tho ~mjl<:ttiiUII: rannc of
io11or~st is4:18 ~ 10; Hg C. -
67 Slnpping of 1lll10li>Lii~ is curriod oul at a
prussu~'<> o( 1.1 alms. One ml of water
enl<l.:S U1e system aud the ratio of Ute molar
ilow r~ uf nir -and tlllrt OJ' tho II OtU ~~ 4.
The mlet air and Ute inlet wnt~r ho1e 0. l
and ! .(1 mnlo porcu,Jt of uruo11nuu
N~P"ctiv~l) , Th.o Mu'l'hl'te vapour pluta
elliciency for nmmonia remtwnl ~ 50" b
at!d the HcntiS 1011 con.llimt fur mtlm(nnu
dctemtine tltc exi t wut>t CQm[lO$i lion nnd
the exit n~r composition.
D~tcrmlnatilln of c flicicnc, is omucnl in
plolo column design. llta -gns nod liqlllcl
rntcs arc 0 I and 11.25 kmol!s rllsp::~tively.
The tntcrtiwinl nnw for miL trons.tcr is 35
Dl-'nr' ltlluJ
on Ihe pl utc. Tuc
t.. restdoncc
'
tnl1u of both the liquid and gas in the fmth
1.onc is 3scoonds, The liquid phose and gn.
f'h:JS(l mas~ transfer ~utlici~nts are I <
10- 2 ml~ und 2 ' -l (r' m!~ ""~P"clively.
Culculuw
u, Uquid phMe llUnsf~r unitS
b. ]tiS phuse lnUlsf.n unit>

c. ~tripping fo~tor. l! "o:n lhtthe ~lope of
the "'JUilibrlum ~urvc '' S
d . owrull tnmfer uniiS
e Mlll'JlhNC point etlieu~nc)
69 T\\IJ purollcl liratordcr reactions A B
and .\ (" orc tkmg pJ.,~c In liiJUid phae
m a '' tll-m L'ed bat.:h re1ctor \Jlcr 60
mm uf opcr:IIK>n. RO o of 1\ h rca.:tcd
O\\ bile 2 1nolcs of 8 pu n1olo of C "
d<tc:ctcd 1n the =~tor C:okuhltc the rote
.:on.toots k, ond k, f"" the '" 0 reoctillnJ
,illume dtt no B lllld C "ere intldll)
pn:scntutth~ I'I:.>Ctot .
70. Au isothermal plug Oo\\ ....,ctor io
dcsignod to sh-.:: ~0 . com=ion of.\ for
a sccond-onlcr hq111d phoc rcocllon A
B. Pure A at .:onccntration I l;mol;m1 is
ted to th reactor ot o Oow rotc of S m1 hr
fhc rotc conJilont for the rcoctoon ~~
poctliod opct:~uns tcmpCI'llturc os 0.3
m1 ~mol h \\1ten the reactor " !1Cil,.11)
operotcd b~~.>ed on th-" dotugn. it wu~ found
o 1\ollm~ed reactOr while U1~ remaining
ra
tbot 30 " of ll1~ utitiot re.1ct"r 11\:h.-ed
l!ehavcd as a plug llow rea~tllr C'alculatc
the cumt.'1'Kivu ()bCflint.:d in ~u~.:H a rc;,~I.OI .
m
71 F11r an c;wthunlllc rca<:hon A U, !>0
lonol of U ooo to be: ptoduccd wh~~
o~hlcving 90 " conwrion or 1\ rn ~~~
xa
IS<Jihermnl bnl..:h rca..:tllr operated AI 300 1\
'l'he rc;o~ttun h li1 l!c ~tuned "ith pure A at
tbc cllncc:utralll/!1 ol' J() i.IUOJ/ml
Ddcnninc tho \'Oiumc nf the reodnr,
dur:llion of tho: bat~h upcrounn ond the:
.e
totol lldl rerno1cd during lite ~othemt~l
opcrotion. ll1c heal of the I'Cllotion at SOO
K Ill - 40 ~J mol of A r~ctcd Follull inl!
w
additional infonnohon L< 0\'aobble to
d~tt:I'Diint the: onlcr and rlc conlit4nl of
the n:c:tion Laboro\(>0 <!.~p<:!inn:nlJ
w
""nduclcd t Stl() 1- with I. kmol m1 UliUal
COncct~ll':ltion of pure A \hO\\ .:d lhot lO"o
wd\ co11.1o i. oblllu1~d in 20 milL "hllc
w
500o corwmiun " ot-U.incd in~ mon llu:
I'C.1CIIOII " '"-'p<:<:ICd IO l!c C:llht:t lir<l 01'
Sec<JOO 1)1\ICI
72 A pmponionol .:onuollcr " us.:d fo. the
couttOI of f111Hmlcr i\'11'"" If the
dynllllucs of >II tltc nu..:r' un1t. in tho
~Ill ~
control loop are nesligibl~ ond dteir
st~dy-<1.\tct BaiM are all equal I(! tmit~.
!!hOI that
a. the rc>~ponsc of the c(>ntntllcJ pn..:c"
i f>stcr Un that uf Uoe tmconholled
pmteS3, ond
b. the n1T1ct, both JC,r cbugcti on the ct
pninr ond in rhe ltl><i l'>riahle,
dc:erea~ as tile P"l"ilmet.:r uf the
om
~011tnll.lcr is incrca.cd..
7J.. 1\ s'-"'nd-<ll'dcr p~ "1th the ll':ln<fcr
1\mction
KG
T ~ ,)'-2s - 3
.c
Is eootroll.:d "lth a pmpcmonolullegnl
contrnUor. if ill the other lags in th~
control loop :ttc ncgli!l'blo nd Urcir
ste;,dy-nate gin are II equl to unil) ,
ce
find the rciJtiou bet\Veetl tliC pam meta'S of
tltc conlroUcr. that bould be sJfi..fied for
the control sys1om to b bblc.
7~. A new cquiJllDcnl mdc of uutcriol A
co<ts, pot in<t llation. k. 3 lokhs o.nd ls
expc.::ted to have a scup volue of lll"o of
Ulis cost at Ute ~nd of a U!cful life of I 0
yeot~. Simibr oquiprncnt made of maluriol
H crn~ts Rs. 1.5 lkh<. but i likely to hn\'1!
no Nl!mp value, A5~ume !lUll both lypCll uf
Ute equipment coulU b<' replaced nt a CONL
thol is 20 "' more thon the original v luo.
On the basi of equal capitollzod C<Jb thr
bollt typCJ of the equipment. cstimnt.: whot
!llwuld. be the u.eful life for equipment
modo of motc:riol B. The compan) hn tu
p~) n onnuol int.:n::<l on the in\C'I!menl at
rule of 15 ,.,
75. the thcmll:lll n:.ctitm
Write nlcnll
(stoi~hiomctrkJly l>olooccd) ror \be
manufacture of each of the fotlo<~ tn8
chetnic31s
'm}iacetalc from ethylene
b llTC3 from ammoni:t
.:. <fl "'"c Jiom tth~ I ~ene
d. caustk soda from brine
c. tripk ~uper phtlSpbatc from r'""'(lllate
rod..