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Components involve:
4 Inlet 30 4.5
Inlet FBR
Stream 2
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 0 0 0
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 7894.647 0
Oxygen 0 8459.949 0
Nitrogen 5.69093505 8206.952 46705.2308
5868052.75
TOTAL
Table: Heat of FBR input
Inlet FBR
Stream 3b
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0 0 0
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 11837.823
Carbondioxide 1.97 6009.047 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 11837.823
Table: Heat of FBR input
Inlet FBR
Stream 1
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 490.207 38682.234
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 38682.234
Table: Heat of FBR input
Inlet FBR
Stream 5
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 62884.548 4962219.68
1-Butene 26.99 54976.598 1483818.38
2-Butene 57.84 54709.397 3164391.52
1,3-Butadiene 5.79 50283.658 291142.38
Water 197.48 15107.457 2983420.61
Carbondioxide 3.64 18599.423 67701.9
Hydrogen 712.16 12328.319 8779735.66
Oxygen 0 0 0
Nitrogen 205.03 12849.743 2634582.81
TOTAL 24367012.9
Table: Heat of FBR output
Heat Formation (Endothermic reaction)
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 78.91 -1.26E+005 -9926088.9
1-Butene 26.99 -5.40E+002 -14574.6
2-Butene 57.84 -5.40E+002 -31233.6
1,3-Butadiene 5.79 1.09E+005 632499.6
Water 197.48 -2.42E+004 -4779016
Carbondioxide 3.64 -3.94E+005 -1432372.8
Hydrogen 712.16 0 0
Oxygen 0 0 0
Nitrogen 205.03 0 0
TOTAL -15550786
Table: Heat formation of process
2.3.3 Mass Balance in Fixed Bed Reactor (2nd reactor) - Oxo-D reaction
R-102
STREAM DESCRIPTION TEMPERATURE(0C) PRESSURE(atm)
6 Inlet 34 1.0
Inlet FBR
Stream 5
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 78.91 62884.548 4962219.68
1-Butene 26.99 54976.598 1483818.38
2-Butene 57.84 54709.397 3164391.52
1,3-Butadiene 5.79 50283.658 291142.38
Water 197.48 15107.457 2983420.61
Carbondioxide 3.64 18599.423 67701.9
Hydrogen 712.16 12328.319 8779735.66
Oxygen 0 0 0
Nitrogen 205.03 12849.743 2634582.81
TOTAL 24367012.9
Table: Inlet Stream of FBR (2nd reactor)
Inlet FBR
Stream 6
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0 0 0
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 281.83 270.038 76104.81
Nitrogen 492.93 262.032 129163.434
TOTAL 205268.244
Table: Inlet Stream of FBR (2nd reactor)
Inlet FBR
Stream 7
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 62884.548 4962219.68
1-Butene 0 0 0
2-Butene 37.2 54709.397 2035189.57
1,3-Butadiene 52.86 50283.658 2657994.16
Water 362.2 15107.457 5471920.93
Carbondioxide 13.41 18599.423 249418.262
Hydrogen 860.85 12328.319 10612833.4
Oxygen 608.78 13249.802 8066214.46
Nitrogen 197.12 12849.743 2532941.34
TOTAL 36588731.8
Table: Outlet Stream of FBR (2nd reactor)
Heat Formation
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 78.91 -1.26E+005 -9926088.9
1-Butene 0 -5.40E+002 0
2-Butene 37.2 -5.40E+002 -20088
1,3-Butadiene 52.86 1.09E+005 5774426.4
Water 362.2 -2.42E+004 -8765240
Carbondioxide 13.41 -3.94E+005 -5276955.7
Hydrogen 860.85 0 0
Oxygen 608.78 0 0
Nitrogen 197.12 0 0
TOTAL -18213946
Table: Heat of Formation for the process
2.3.5 Mass Balance in Heat Exchanger
E-101
8 Outlet 40 1.0
9a Outlet 40 0.095
Stream 7
E-101 Stream 7a
Function
To remove the water, maintain the temperature and recycle the
water into condenser
Condition
Phase : Liquid Phase
Operating Temperature : 160oc
Operating Pressure : 1 atm
Inlet FBR
Stream 7
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 62884.548 4962219.68
1-Butene 0 0 0
2-Butene 37.2 54709.397 2035189.57
1,3-Butadiene 52.86 50283.658 2657994.16
Water 362.2 15107.457 5471920.93
Carbondioxide 13.41 18599.423 249418.262
Hydrogen 860.85 12328.319 10612833.4
Oxygen 608.78 13249.802 8066214.46
Nitrogen 197.12 12849.743 2532941.34
TOTAL 36588731.8
Table: Energy balance at inlet stream for Heat
Exchanger
Inlet FBR
Stream 7a
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 101.16 21056.087 2130033.76
1-Butene 0 0 0
2-Butene 47.69 18566.496 885436.194
1,3-Butadiene 67.77 16781.533 1137284.49
Water 464.37 6009.047 2790421.16
Carbondioxide 17.19 7258.533 124774.182
Hydrogen 3513.27 4988.39 17525560.9
Oxygen 69.53 5334.38 370899.441
Nitrogen 891.37 5175.577 4613354.07
TOTAL 29577764.2
Table: Energy balance at Outlet stream for Heat
Exchanger
Inlet FBR
Stream 9a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 1491.535 150824.019
1-Butene 0 0 0
2-Butene 37.27 1340.899 49975.306
1,3-Butadiene 67.82 1220.147 82750.37
Water 23.79 1125.511 26775.907
Carbondioxide 16.91 598.945 10128.16
Hydrogen 1107.25 0 0
Oxygen 780.43 450.326 351447.92
Nitrogen 252.61 436.974 110384.002
TOTAL 782285.684
Table: Energy Balance at Outlet stream for Heat
Exchanger
Outlet
Heat Vapourization
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 22.305 2255.482
1-Butene 0 21.916 0
2-Butene 37.27 21.916 816.809
1,3-Butadiene 67.82 0 0
Water 23.79 40.706 968.396
Carbondioxide 16.91 15.326 259.163
Hydrogen 1107.25 0.964 1067.389
Oxygen 780.43 6.82 5322.533
Nitrogen 252.61 5.577 1408.806
TOTAL 12098.578
Table: Heat Vaporization at Heat Exchanger
8 Outlet 30 1.0
9 Outlet 40 1.0
Stream 8
E-102
Stream 7a Stream 9
Function
To recycle back the water to cover another process
Condition.
Phase : Liquid Phase
Operating Temperature : 100 oc
Operating Pressure : 1 atm
S7a S8 S9
1-Butene 0 0 0
NMP 0 0 0
Inlet FBR
Stream 8
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0.01 7540 75.4
1-Butene 0 0
2-Butene 10.39 874.972 9090.959
1,3-Butadiene 0.03 7020 210.6
Water 440.46 11913.966 5247625.46
Carbondioxide 0.21 5720 1201.2
Hydrogen 0.42 260 109.2
Oxygen 0.03 4160 124.8
Nitrogen 0.03 3640 109.2
TOTAL 5258546.82
Table: Inlet Stream of Condenser
Inlet FBR
Stream 9
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 10086.2 1019916.54
1-Butene 0 0
2-Butene 37.27 9738.4 362950.168
1,3-Butadiene 67.82 9390.6 636870.492
Water 23.79 3130.2 74467.458
Carbondioxide 16.91 7651.6 129388.556
Hydrogen 1107.25 347.8 385101.55
Oxygen 780.43 5564.8 4342936.86
Nitrogen 252.61 4869.2 1230008.61
TOTAL 8181640.24
Table: Outlet Stream Condenser (air
cooled)
9a Inlet 40 0.95
Inlet FBR
Stream 9
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 101.12 1491.535 150824.019
1-Butene 0 0
2-Butene 37.27 1340.899 49975.306
1,3-Butadiene 67.82 1220.147 82750.37
Water 23.79 1125.511 26775.907
Carbondioxide 16.91 598.945 10128.16
Hydrogen 1107.25 422.643 467971.462
Oxygen 780.43 450.326 351447.92
Nitrogen 252.61 436.974 110384.002
TOTAL 1250257.15
Table: Energy Balance at Compressor
Inlet FBR
Stream 9a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 2122.514 214628.616
1-Butene 0 0
2-Butene 37.27 7189.784 267963.25
1,3-Butadiene 67.82 6609.026 448224.143
Water 23.79 2543.847 60518.12
Carbondioxide 16.91 3038.834 51386.683
Hydrogen 1107.25 2122.514 2350153.63
Oxygen 780.43 2264.693 1767434.36
Nitrogen 252.61 2197.475 555104.16
TOTAL 5715412.96
Table: Energy Balance at Compressor
Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Stream 10
Stream 9 Stream 11
T-101
Function
To remove the water and inert gas .
S9 S10 S11
1-Butene 0 0 0
NMP 0 0 0
Inlet FBR
Stream 9
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 101.12 2122.514 214628.616
1-Butene 0 0
2-Butene 37.27 7189.784 267963.25
1,3-Butadiene 67.82 6609.026 448224.143
Water 23.79 2543.847 60518.12
Carbondioxide 16.91 3038.834 51386.683
Hydrogen 1107.25 2122.514 2350153.63
Oxygen 780.43 2264.693 1767434.36
Nitrogen 252.61 2197.475 555104.16
TOTAL 5715412.96
Table: Energy balance for Input Absorption Tower
Inlet FBR
Stream 10
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0.361 1491.535 538.444
1-Butene 0 0
2-Butene 0.498 1340.899 667.768
1,3-Butadiene 0.258 1220.147 314.798
Water 5.627 1125.511 6333.25
Carbondioxide 11.914 598.945 7135.831
Hydrogen 3511.148 422.643 1483962.12
Oxygen 69.365 450.326 31236.863
Nitrogen 891.102 436.974 389388.405
TOTAL 1919577.48
Table: Energy Balance for Output Absorption
Tower
Inlet FBR
Stream 11
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 100.766 1491.535 150296.016
1-Butene 0 0
2-Butene 36.803 1340.899 49349.106
1,3-Butadiene 67.545 1220.147 82414.829
Water 18.258 1125.511 20549.58
Carbondioxide 4.937 598.945 2956.991
Hydrogen 0 422.643 0
Oxygen 0.341 450.326 153.561
Nitrogen 0.217 436.974 94.823
TOTAL 305814.906
Table: Energy Balance for Output Absorption
Tower
Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 100.766 22.305 2247.586
1-Butene 0 21.916 0
2-Butene 36.803 21.916 806.575
1,3-Butadiene 67.545 0 0
Water 18.258 40.706 743.21
Carbondioxide 4.937 15.326 75.664
Hydrogen 0 0.964 0
Oxygen 0.341 6.82 2.326
Nitrogen 0.217 5.577 1.21
TOTAL 3876.571
Table: Heat Vaporization at Absorption Tower
Function
To remove water, maintain the temperature and recycle the water
into waste boiler
Condition
Phase : Liquid Phase
Operating Temperature : 30 oc
Operating Pressure : 5 atm
1-Butene 0 0 0
Hydrogen 0 0 0
NMP 0 0 0
Inlet FBR
Stream 12
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 92.084 4659.945 429106.375
1-Butene 0 0 0
2-Butene 36.478 4169.698 152102.244
1,3-Butadiene 0.293 0 0
Water 16.723 1521.028 25436.151
Carbondioxide 4.504 1810.12 8152.78
Hydrogen 0 0 0
Oxygen 0.322 1354.907 436.28
Nitrogen 0.17 1314.716 223.502
TOTAL 615457.332
Table: Energy Balance for Output Extractive
Distillation Column
Inlet FBR
Stream 13
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0.724 209.3 151.533
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 77.038 7251.714 558657.543
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 558809.076
Table: Energy Balance for Output Extractive
Distillation Column
Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 92.084 22.305 2053.934
1-Butene 0 21.916 0
2-Butene 36.478 21.916 799.452
1,3-Butadiene 0.293 0 0
Water 16.723 40.706 680.726
Carbondioxide 4.504 15.326 69.028
Hydrogen 0 0.964 0
Oxygen 0.322 6.82 2.196
Nitrogen 0.17 5.577 0.948
TOTAL 3606.284
Table: Heat Vaporization at Extractive Distillation
Column
COMPONENT Mass flow rate (kg/hr)
1-Butene 0 41.0178316 0
1,3-Butadiene 0 0 0
Carbondioxide 2.47479729 0 0
Hydrogen 0 0.08700459 0
Nitrogen 0.05800306 0 0
NMP 0 0 13.3210655
Total 96.6814362 93.4912678 0
Inlet FBR
Stream 12
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 114.802 4659.945 534971.006
1-Butene 0 0 0
2-Butene 41.96 4169.698 174960.528
1,3-Butadiene 0 0 0
Water 20.873 1521.028 31748.417
Carbondioxide 5.623 1810.12 10178.305
Hydrogen 0 0 0
Oxygen 0.393 1354.907 532.478
Nitrogen 0.207 1314.716 272.146
TOTAL 752662.88
Table: Energy balance for Input Solvent Recovery
Column
Inlet FBR
Stream 12a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 84.446 53583.913 4524947.12
1-Butene 73.098 46892.33 3427735.54
2-Butene 5.376 46698.873 251053.141
1,3-Butadiene 0 0 0
Water 1.395 13233.507 18460.742
Carbondioxide 7.271 16244.64 118114.777
Hydrogen 4.316 0 0
Oxygen 0.121 11639.901 1408.428
Nitrogen 0 11289.699 0
TOTAL 8341719.74
Table: Energy Balance for Output Solvent
Recovery Column
Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 84.446 22.305 1883.568
1-Butene 73.098 21.916 1602.016
2-Butene 5.376 21.916 117.82
1,3-Butadiene 0 0 0
Water 1.395 40.706 56.785
Carbondioxide 7.271 15.326 111.435
Hydrogen 4.316 0.964 4.161
Oxygen 0.121 6.82 0.825
Nitrogen 0 5.577 0
TOTAL 3776.61
Table: Heat Vaporization at Solvent Recovery
Column
Mass flow rate (kg/hr)
COMPONENT
S12 S12a
1-Butene 0 41.0178316
1,3-Butadiene 0 0
Carbondioxide 2.47479729 0
Hydrogen 0 0.08700459
Nitrogen 0.05800306 0
NMP 0 0
Total 96.6814362 93.4912678
Table: Inlet and Outlet streams
Inlet FBR
Stream 12
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 114.802 4659.945 534971.006
1-Butene 0 0 0
2-Butene 41.96 4169.698 174960.528
1,3-Butadiene 0 0 0
Water 20.873 1521.028 31748.417
Carbondioxide 5.623 1810.12 10178.305
Hydrogen 0 0 0
Oxygen 0.393 1354.907 532.478
Nitrogen 0.207 1314.716 0
TOTAL 752390.734
Table: Energy balance for Input Isomerization Stage
in FBR
Inlet FBR
Stream 12a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 84.446 53583.913 4524947.12
1-Butene 73.098 46892.33 3427735.54
2-Butene 5.376 46698.873 251053.141
1,3-Butadiene 0 0 0
Water 1.395 13233.507 18460.742
Carbondioxide 7.271 16244.64 118114.777
Hydrogen 4.316 0 0
Oxygen 0.121 11639.901 1408.428
Nitrogen 0 11289.699 0
TOTAL 8341719.74
Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 114.802 22.305 2560.659
1-Butene 0 21.916 0
2-Butene 41.96 21.916 919.595
1,3-Butadiene 0 0 0
Water 20.873 40.706 849.656
Carbondioxide 5.623 15.326 86.178
Hydrogen 0 0.964 0
Oxygen 0.393 6.82 2.68
Nitrogen 0.207 5.577 1.154
TOTAL 4419.922
Table: Heat Vaporization at Isomerization Stage in
FBR
Inlet FBR
Stream 14
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 79.073 490.207 38762.138
1-Butene 0 0 0
2-Butene 5.507 441.451 2431.071
1,3-Butadiene 0 0 0
Water 1.395 168.254 234.714
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 41427.923
Table: Energy Balance for Output Distillation
Column
Inlet FBR
Stream 15
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 4.639 887.404 4116.667
1-Butene 73.498 780.367 57355.414
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 7.57 358.833 2716.366
Hydrogen 0 0 0
Oxygen 0.281 270.038 75.881
Nitrogen 0.118 262.032 30.92
TOTAL 64295.248
Table: Energy Balance for Output Distillation
Column
Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 79.073 22.305 1763.723
1-Butene 0 21.916 0
2-Butene 5.507 21.916 120.691
1,3-Butadiene 0 0 0
Water 1.395 40.706 56.785
Carbondioxide 0 15.326 0
Hydrogen 0 0.964 0
Oxygen 0 6.82 0
Nitrogen 0 5.577 0
TOTAL 1941.199
Table: Heat Vaporization at Distillation Column