a) (ii) ii) (iv) (vy) Trick 6 Tech: fi Physical Appearanede: Actinoids are silvery white metals. They get tarnished when exposed to the attack of alkalies. Colour of the actinoid ions: In general, are coloured: The appearace of colour Depends upon the number of 5f- electrons Melting and Boiling Points: They have high melting and boiling points. They do} not follow regular gradation of melting or boiling point with increase in atomic number. Magnetic Properties: The actinoid clements are paramagnetic duc to the presence of unpaired electrons. However the magnetic properties of actinoids are more complex than those of lanthanoids. Actinoid Contraction: The size of atoms or M** ions decrease regularly along the actinoids series. The steady decrease in ionic radii with increase in atomic number is referred to as actnoid contraction. © — Mixed oxides of lan thanoids are used as catalysts in petroleum cracking, © — Many lanthanoid oxides are used as phosphors in colour TV tubes. © Plutonium is used as fuel for atomic reactors as well as in atomic bombs. Some Important Points Compounds of Mn © —MnO,-black solid amphoteric in nature. MnO, »Mn,0, —*»Mn30, Mno, —*#2:_, KMnO,4(Pink) K,Mno, —4#8%_, KMnO, er O}/h,0 KMnO, —*-+K,MnO,+MnO, +O, ‘roen KMnO, +H,S0, —>K,SO, +MnSO, +H,0+[0] Basie Pa K,MnO, —>—KMn0, —" 5 Mr Neti 87ene Trick & Tech: Compounds of © K,Cr,0, (Orange) 1. Itis prepared by double decomposition of Na,Cr,0, Na,Cr,0, +2KCl —> NaCl+K,Cr,0, 2, Itis triclinic, crystal not hycroscopic. 3. Itis easily recrystalize and on heating it gives. K,Cr,07 "> K,CrO, + Cr,0, +0, Yalow Green 4. KCr,07 +H,0, "4 Cr0, +H,0 si x] ON. of Cr = +6 No. Butterfly Structure K,Cr,0; +KOH—> K,Cro, "8% k,Cr,0, Base Yellow Grange H>7 P CrO;7 Cr,.07> = pli< By Base (9) By acid (5) ‘Tetrahedral structure 6Cr—OOnetype — gys 2. Cr—O Other type ° K,Cr,0; —S-» K,Cr0,+ Cr,03+0,8 range | 81!K Yelow ” gteen Compounds of Ag 1. AgNO, (Lunar caustic) Ag +HNO, —> AgNO, +NH,NO, +H,0 very 88Trick 6 Tech: 2. AggS Silver glance. 3. AgNOs absorbs NH, to given a complex © With KCN. KCN + AgNO, —>AgCN —S% 5 K[Ag (CN),] AgNO. ae HIO, +Agl+HNO, these) aot . Ea PAGIO3 + Agl+ HNO, Amm. AgNOy is known as Tollen’s Reagent NaCl AgCl (White) [Nebr Appr (Yetlow) [Nal__,, Ag (Dark Yellow) NaS AgyS (Black) AgNOy———} _, ag, cro, (Red) NasPOe ‘AgsPO, (Yellow) NwSO1__, ag,S0, (White) | Nax80s__, agysy0, Nes, NaglAg(S;03)o] NaCNS AgCNS (White) © Ag,S,0; — Ag,0+Ag,S Black Color © — Nas[Ag(S;O;)p ] used as fixer in photograpy }® Compound of Zn on heating become yellow and on cooling become white. ZnSO,, 7H,0- White vitrole Compounds of Cu CuFeS, (Copper Pyrctise) CuSO,.5H,0 - Blue vitrol Cu,S (Copper Glance) Cu,O- Red CuCO5.Cu(OH), (Malachite - Green) Cu,Cl, (Cupprous Chloride - Red) 89ene Trick & Tech: © CuCl, Cu+HCl+ [0] —> CuCl, —°>Cu,Cl, CuCl —“ uy = we (dry) u (NHg)9Cl CuCNHy © CuS0,.5H,0 (Blue Vitrole) Cu0+H,S0, —> CuSO, CuSO, +5H,0 —+ CuSO,5H,O Back cobuies Dak ue © — CuoyBlack): Exposer CuS04.3H20 YS, Cuso4Hy0 CuS04.5H20 CuO + S02 + 0p

Ky[Fe(CN),] © Important : 42. EKER +2 + CuSO, Ca (CN)7—?-> Cuy(CN)y + CN S cyanogen Cu(OH), Kg[Cu(CN)4] | ps0, + Nti,o1 [Cu(NH3)4]SO4 90 aTrick 6 Tech: © Here KCN as complexing and reducer. Compounds of Fe FeO, Magnetite (Richest ore of iron) Fe,0, Haematite (Most stable oxide (Red brown) Fe,03.3H,0 Limonite (Yellow brown) CuFeS, Chalco pyrites / copper pyritese © Fe, 04.2, 0 - Rust Fe, Oy FeSO, —*-» Fe,0, +0, +80, NaFeO) FeSO, +H, Fes —S_, Feso,+NO,+H,0 Hat cane Chemical Properties: FeSO,.7H,0 2-5 FeSO, +7H,0 FeSO, +H,O ———+ Fe(OH), +H,SO, aide Hydrolysis is according to that, which is weak, means => Fe(OH), = Cationic hydrolysis a1ene Trick & Tech: +2 K4l Fe(CN)g. FeSO; PONS, FeSO4.NO (Brown Ring) AuCly KMn04 + HyS Feg (SO4)3 + KySO4 + MnSO4q + Hy0 Au + Fe (SO4)3 + FeCls FeSo, 8% 5 Hg,Cl, + Fe,(SO,); + FeCl, FeSO4.7H,0 It is use in making blueblack ink. (NH4)2S0, . FeSQ,.6H,0 (Mohar salt) H, SO,.N ))s NO] SO, are brown ring. FeCl, (Yellow): Fe+Cl, —> FeCl, Fe(OH), +HC1 —> FeCl, x > 750°C FegClg—=> FeClz ———> FeCl + Cly Ne a Ze Becomes dimer S\N ZN cl cl Cl FeCl, is good oxidiser. 92Trick 6 Tech: Chemical Properti I NHOH Reig LSS, FeCl + SnCly 802 +10 Fe(OH); + NHyCl_ #28 arr Red. Brown 203 FeCly + § + HCl, HySO4 + FeCl, + HCL KL KCNS Ip + FeCly + KCI FeCly Fe(CNS)3 Blood Red KCN €H3coo- +3 Kg [Fe(CN)g] _ Fe(CH3COO) Blood Red Compounds of Hg Hg,Cly (White) = Calomal HgCl, +SnCly —> Hg,Cl, +SnCl, {Ha Hg,Cl, Properties: “1 Hapcl, > Hg + Sac 37 | sets ig (0,) +HigCl, +H,0+NO HgCl, (Corrosive sublimate) — very poisonous HgSO, +NaCl—>HgCl, & 3ene Trick & Tech: NH3_Figcy |_Hes Hs [4] J 28s gs SEL Hg (aa) Newent iydrogen Ug (NHg)9|Cly |S HgyCly “2, Hg White Gray HgCl, + NsQH—> Hg(OH)) + NaCl + H,0 Hg0 HgCly + KI —> Hgly (Red) KI KyHgly (Nesler's Reagent) For More detail Can See ‘Inorganic in My Pocket’ & ‘Inorganic nee Youg{UD) Type & www.