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Nama : ...................................................... Tingkatan: ....................

CHEMISTRY
Kertas 2
SEKOLAH MENENGAH KEBANGSAAN
Oct 2016
ST. FRANCIS
2 jam
JALAN PARAMESWARA
75000 MELAKA

PEPERIKSAAN AKHIR TAHUN

CHEMISTRY

Paper 2

Two hours and thirty minutes

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. This question paper consists of three sections, Section SECTION QUESTIONS MARKS
A, Section B and Section C

3. You are advised to spend 90 minutes to answer 1 9

questions in Section A, 30 minutes for Section B and 30
minutes for Section C 2 9
3. Choose only ONE question from Section B and ONE 3 10
question from Section C A
4 10
5 11
6 11
7 20
B
8 20
9 20
C
10 20
TOTAL 100

Kertas soalan ini mengandungi 14 halaman bercetak

Section A
Answer all questions in this section
 [60 marks]

1. Table 1 shows the incomplete information about three atoms X, Y and Z.

Atom Proton number Number of neutron Number of electron
X 8 6
Y 6 6
Z 17 17
Table 1.
(a) Complete Table 1 using the following information :-
i. The total number of proton and neutron for atom Z is 35
ii. Atom X and Y are isotopes of an element
(2 marks)
(b) State the name of the subatomic particles that are found in the nucleus of an atom.
........................................................................................................................................................
(1 mark)
(c) (i) What is term given to the sum of proton and neutron in an atom?
.................................................................................................................................................
(1 mark)
(ii) Write the symbol for atom Z using the standard representation,
.................................................................................................................................................
(1 mark)
(iii) Draw the atomic structure of atom Z.

(2 marks)
(iv) Write the electron arrangement of atom Y
................................................................................................................................................
(1 mark)
(v) What is the valence electron of atom X?
.................................................................................................................................................
(1 mark)
2. Diagram 2shows an experiment carried out by a student to prepare lead (II) chloride. Sodium
chloride solution is placed in a beaker and lead (II) nitrate solution is added into the beaker. Lead (II)
chloride is formed with solution of sodium nitrate

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 50 cm3 1.0 moldm-3sodium chloride solution.
50 cm3 1.0 moldm-3 laruitan natrium klorida

Diagram 2

(a) (i) Write a chemical equation for the reaction between sodium chloride and lead (II) nitrate.

..
(2 marks)
(ii) Describe the chemical equation in terms of qualitative and quantitative aspect.

Quantitative : .
Qualitative :
(2 marks)
(b) State the solubility of lead (II) chloride formed from the reaction in Diagram 2.

(1 mark)
(c) State one physical property of lead (II) chloride formed.

(1 mark)
(d) Calculate the mass of salt formed in (c). [Relative atomic mass: Pb=207, Cl=35.5, K=39, N=14,
O=16]

(3 marks)
3. Diagram 3 shows the positions of 6 elements represented by the letters A, B, C, D, E, F in the
Periodic Table of Elements.

3
Using these letters, answer the following questions

(a) State the element which exist as diatomic molecule under room condition

.
(1 mark)
(b) State one special characteristics of element F

.
(1 mark)
(c) (i) Arrange atoms A, B, C, D, E and F in decreasing order of atomic size.

(1 mark)
(ii) Explain your answer in (c)(i)

(3 marks)

(d) (i) When A is put in a basin of water, hydrogen gas is released and hydroxide of A is
produced. The chemical equation for the reaction is as follows

2A + 2H2O 2AOH + H2

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 If 4.6 g of A is used, calculate the volume of hydrogen gas released at room
condition.
[RAM of A=23, molar volume of 1 mol of gas at room condition is 24 dm3]

(3 marks)

(ii) What changes can be observed when blue litmus paper is added to the basin
containing product of the reaction in (d)(i)?

(1 mark)

4. Table 4 shows the electron arrangement of six elements T, U, V, W, X and Y.

Elements Proton Number Electron arrangement

T 6 2.4
U 17 2.8.7
V 11 2.8.1
W 12 2.8.2
X 2.8.8
Y 19
Table 4

(a) Based on Table 4, answer the following questions

(i) What is the proton number of element X?

(1 mark)
(ii) What is the electron arrangement for ion Y?

....................
(1 mark)
(b) Element T reacts with element U to form a compound.

(i) Give the molecular formula of compound formed

................

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 (1 mark)
(ii) State the type of bonding in the compound formed in (b)(i)

(1 mark)
(iii) Give two physical properties of the compound formed

(2 marks)
(iv) Draw the electron arrangement of the compound formed in (b)(i)

(2 marks)

(c) Element W reacts with element U to form a compound. Write the chemical formula of the
compound formed by U and W.

................
(1 mark)
(d) State an element from Table 4 that can form a cation.

(1 mark)

5. Diagram 5 shows the set-up of apparatus of electrolysis of 0.001 moldm -3 sodium chloride solution
using carbon electrodes P and Q.

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 Diagram 5
(a) Write the formula of all the ions present in copper (II) chloride solution.
..................
(1 mark)
(b) (i) State the observation obtained at carbon electrode P

(1 mark)
(ii) Write the half-equation for the reaction that takes place at electrode P

(1 mark)
(c) State the name of the gas released at electrode Q and describe a test to identify the gas.

..
..
..
..
(3 marks)
(d) After 30 minutes, state the change in colour of copper (II) chloride solution. Explain your answer

..
..
..
(2 marks)
(e) If the experiment is repeated using 2.0 moldm -3 of copper (II) chloride solution, different product is
formed at anode. Explain the difference.

..
..
..
(3 marks)

6. Diagram 6.1 shows the apparatus set-up of three set of experiments to study between concentration
of acid and its pH value.

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 Hydrochloric Hydrochloric Ethanoic acid
acid acid 0.01 moldm-3
0.01 moldm-3 0.001 moldm-3

Diagram 6.1
a) i) State the definition of acid
................
(1 mark)
ii) State the pH value of hydrochloric acid in Set II

(1 mark)
iii) Explain your answer in (a) (ii)


(2 marks)
iv) Explain why the pH value of ethanoic acid in Set III is higher compared to pH value
of hydrochloric acid in Set I.

(3 marks)
b) Diagram 6.2 shows the apparatus set-up for the neutralization reaction between nitric acid and
potassium hydroxide solution to prepare salt X.

8
 Diagram 6.2
i) State the colour change of the solution in the conical flask at the end-point.

(1 mark)
ii) Calculate the concentration of potassium hydroxide used.

(3 mark)

Section B
Answer only ONE question from this section
[20 marks]
7. Diagram 7.1 shows the apparatus set-up for the electrolysis of copper (II) sulphate solution using
copper electrode P and copper electrode Q. After 60 minutes, changes were observed at both
electrodes.

9
 Electrode P
Elektrod P

Diagram 7.1
(a) Based on Diagram 7.1, state the factor that determined the product formed at electrode Q and
electrode P.
(2 marks)

(b) Explain the reaction at electrode P and Q. Your explanation should include the following:
All ions present
Ions attracted to each electrode
Name of the product formed at electrode Q. Explain why the products are formed.
State the ion that is selectively discharge at cathode and explain why this occurred.
Half equations for the reaction at each electrode.
(10 marks)

(c) If both of the electrodes are replaced with carbon electrode:

(i) State the observation at anode. Give one reason why the observation was seen.
(2 marks)

(ii) Write the half-equation for the reaction at anode

(2 marks)

(d) Diagram 7.2 shows a chemical cell.

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 Diagram 7.2

(i) State the negative terminal of the chemical cell and explain your answer.
(2 marks)

(ii) Suggest one suitable substance that can be used as solution X and state its function
(2 marks)

8. Diagram 8 shows the formula of four types of gases released during an eruption of a volcano.

N2 CO2 H 2S H2O
Diagram 8
(a) Calculate the molar mass of each of the gas shown in Diagram 8
(4 marks)

(b) Show that 0.9 g of water vapour contains the same number of molecules as in 2.2 g of carbon
dioxide.
(4 marks)

(c) A sample contains 0.1 mol of carbon dioxide gas at room temperature. Calculate its:
(i) Volume under room condition
(ii) Mass
(iii) Number of molecules
(iv)Number of atoms
[Relative atomic mass: H=1, C=12, O=16, molar volume of 1 mol of gas under room conditions
is 24 dm3, Avogadros Constant = 6.02 X 1023]
(5 marks)

(d) Referring to the information given:

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 At a very high temperature, hydrogen sulphide gas released from the
eruption of the volcano will react with oxygen in the air to produce sulphur
dioxide and water vapour.

(i) Write the chemical equation to represent the reaction

(ii) Calculate the maximum mass of sulphur dioxide produced if 952 g of hydrogen
sulphide is released from the volcanic eruption
(7 marks)

Section C
Answer only ONE question from the following
[20 marks]

9. Diagram 9 shows the information of acids HX and H2X

Acid HX is a monoprotic acid while H2X is a diprotic acid

Both acid HX and H2X are strong acids

Diagram 9

(a) Based on the information in Diagram 9,

(i) Suggest a suitable example of the diprotic and monoprotic acids.
(ii) Based on your answer in (a)(i) explain what is meant by monoprotic acid and
diprotic acid
(4 marks)
(b) Table 9shows the pH value of sodium hydroxide solution and ammonia solution of the same
concentration.

Table 9
Explain why sodium hydroxide solution and ammonia solution of the same concentration have
different pH value.
(6 marks)

(c) A student wanted to prepare 250 cm3 of 1.0 moldm-3 potassium hydroxide from the potassium
hydroxide pellets found in the lab for his experiment.
12
 (i) Describe an experiment that can be carried out in the laboratory to help him prepare the
solution. Include in your answer any calculations of mass needed for the preparation.

(ii) He also discovered that he needed 250 cm 3 of 0.2 moldm-3 of potassium hydroxide
solution for a further reaction. Describe another experiment that can be carried out in
the lab for him to prepare 250 cm3 of 0.2 moldm-3 from the solution that he prepared in
(c)(i).
(10 marks)

10. Diagram 10.1shows a reaction where lead (II) nitrate is poured into a beaker containing solution
of X carbonate.

Lead (II)
nitrate
0.1 moldm-3

X carbonate
solution
0.1 moldm-3

Diagram 10.1

(a) Based on Diagram 10,

(i) Suggest an identity for the solution of X carbonate.
(ii) Write down the chemical equation involved for the reaction in Diagram 10.1 and the ionic
equation involved.
(4 marks)

(b) Diagram 10.2 shows two different type of salt found in a school laboratory.
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 Potassium Silver nitrate
nitrate 0.1 moldm-3
0.1 moldm-3

Salt I Salt II

Diagram 10.2

(i) Describe the difference in method of preparation of the two salts shown in Diagram 10.2.
State the reactants needed to prepare salt I
(4 marks)

(ii) Describe an experiment that can be carried out in the laboratory to prepare salt II in
Diagram 10.2. in your description, please include any chemical equation involved in the
reaction.
(12 marks)

END OF QUESTION PAPER

Prepared by, Checked by, Seen by,

..
(En. Amin Kamarun Zaman) (Pn Nurul Ain Ashikin Halin) (Pn. Noraini Bt. Ismail)
Chemistry Teacher Head of Chemistry Panel Head of Science &
Mathematics
Department

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