CHEM 1214 Practice Test 2B Chapter 14 and Chapter 15

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Practice Test 2B

Chapter 14 and Chapter 15 (Sections 1 6)

1. Which of the following is a strong acid in water?

A.

D. 2. HF

H2CO3 B.

E. HI

HClO2 C. H3PO4 B The net ionic equation for the neutralization of

citric acid by a base is

H3C6H5O6(aq) + 3OH(aq) 3H2O(l) + C6H5O63(aq)

Therefore

A.

C.

E:

3. citric acid is a strong acid.

citric acid is the spectator ion.

none of these is true. D. B.

the base is a strong base.

NH3 could have been the base used. B H2S(aq) + H2O H3O+(aq) +
HS(aq)

HS(aq) + H2O H3O+(aq) + S2(aq)

In the above reversible reactions, which are the Bronsted acids?

A.

C.

E. ANSWER:

4. H2S, H2O, HS

HS, H2O, S2

H2O, H3O+, HS B.

D. H3O+, H2O, S2

H2S, H3O+, HS D Consider the reactions represented by the following

net ionic equations:

1. Mg(s) + 2H3O+(aq) Mg2+(aq) + H2(g) + 2H2O(l)

2. CO32(aq) + H3O+(aq) HCO3(aq) + H2O(l)

3. H3O+(aq) + OH(aq) 2H2O(l)

Which of the reactions are characterized as acid-base?

A.

D. ANSWER: 3 only
2 and 3

D B.

E. 1 and 2

1, 2, and 3 C. 1 and 3 5. All of the following salts can be obtained from a

strong acid and a strong base except

A.

D. ANSWER:

6. ANSWER: ANSWER: Ba(NO3)2 C. H2PO4 D H3O+

H3PO4 B.

E. HPO42

PO43 C strong, stronger, stronger

weak, stronger, stronger

strong, weaker, stronger B.

D. weak, weaker, weaker

strong, weaker, weaker C Which of the following statements is true in a

reaction system at equilibrium?

A.

B.

C.

D.
E. The number of collisions per unit time between reactants is equal to
the number of collisions

per unit between products.

Reactants are reacting to form products at the same rate as products are
reacting to

form reactants.

The product of the concentrations of the reactants is equal to the product

of the

concentrations of the products.

All concentrations of reactants and products are the same.

No products are being formed, and no reactants are being formed.

Answer B

9. C. H3PO4 is a __________ acid, H3PO4 is a __________ acid than

H2PO4, and H2PO4

is a __________ acid than HPO42.

A.

C.

E. 8. E. B.

LiI

KClO4 What is the conjugate acid of HPO42?

A.

D. 7. CsCl
NaF The equilibrium constant, Kc , for the reaction

H2(g) + I2(g) 2HI(g)

is 55 at 425 C. The value for the equilibrium constant will be changed if

A.

B.

C.

D.

E. Answer D concentrations are given in atmospheres instead of mol/L.

a catalyst is added to the reaction system.

the size of a reaction vessel is doubled.

the temperature is changed to 400 C.

additional HI is added to the reaction system. 10. The equilibrium

expression for Kc for the system

CO2(g) + CaO(s) CaCO3(s)

is A.

D. Answer

11. D. 1

[CO 2 ] C. [CaCO 3 ]

[CO 2 ] [CO2] [CO2][CaO] D

In which of the following does the reaction go farthest to completion

(most products
formed)?

A.

D. Answer

12. B. [CaCO 3 ]

[CO 2 ][CaO] K = 105

K = 100 B. K = 105

E.

K=1 c. K = 1000 A

Carbon disulfide and chlorine react according to the following equation:

CS2(g) + 3Cl2(g) S2Cl2(g) + CCl4(g) When 1.00 mol of CS2 and 3.00
mol of Cl2 are placed in a 2.00-L container and allowed to come to

equilibrium, the mixture is found to contain 0.250 mol of CCl 4. What is

the amount of Cl 2 at

equilibrium?

A.

D.

Answer

13. 2.25 mol

0.25 mol B.

E. 2.75 mol

0.50 mol C. 0.75 mol A

A mixture of NO and O2 at a fixed temperature reacts according to the
equation

NO(g) + O2(g) NO2(g)

When equilibrium is established, which of the following ratios is

constant, regardless of the initial

concentrations of NO and O2?

A. [NO 2 ]

[NO][O 2 ] B. [O 2 ][NO]

[NO 2 ] C. [O 2 ][NO]2

[NO 2 ]2 D. [NO 2 ]

[NO][1/2 O 2 ] E. [NO 2 ]

1/2 [NO][ O 2 ] Answer

14.

Which expression correctly describes the equilibrium constant for the

following reaction?

4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g)

A. Kc = C. 15. D. [H 2 O]6 [NO]4

[NH 3 ] 4 [O 2 ]5 [NH 3 ] 4 [O 2 ]5

[H 2 O]6 [NO]4 If K = 0.145 for: A2 + 2B 2AB, then for: AB B + A2,

K would equal A. 0.145.

D. 2.63. B. -0.145.
E. 6.90. C. 0.381. D

For which of the following equilibria would Kc = Kp?

A.

C.

E. CaCO3(s) CaO(s) + CO2(g)

B.

2NO2(g) N2O4(g)

D.

O3(g) + NO(g) NO2(g) + O2(g) Answer E

17. 6[H 2 O] 4[NO]

4[NH 3 ] 5[O 2 ] D Answer

16. B. [H 2 O][NO]

[NH 3 ][O 2 ] E. Answer 4[NH 3 ] 5[O 2 ]

6[H 2 O] 4[NO] For the reaction system:

2HI(g) H2(g) + I2(g) 2H2(g) + O2(g) 2H2O(g)

2NO(g) + O2(g) 2NO2(g) Kc = 0.020 at 720 K. If the initial

concentrations of HI, H2, and I2 are all 1.50 x 103 M at 720 K,

which one of the following statements is correct ?

A.

B The system is at equilibrium.

The concentrations of HI and I will increase as the system is
approaching

equilibrium.

C.

The concentrations of H and HI will decrease as the system is

approaching

equilibrium.

D.

The concentration HI will increase as the system is approaching

equilibrium.

E.

The concentrations of H and I will increase as the system is approaching

equilibrium.

Answer

18.

A 1.00-mol sample of HI is placed in a 1-L vessel at 460oC, and the

reaction system is allowed to

come to equilibrium. The HI partially decomposes, forming 0.11 mol H2

and 0.11 mol I2. What is the

equilibrium constant for the reaction

H2(g) + I2(g) 2HI(g)

at 460oC?

A.

D.

Answer

19. 0.020

50 B.

E. 7.1

65 C. 8.1 D

A mixture of nitrogen and hydrogen was allowed to come to equilibrium

at a given temperature.

3H2 + N2 2NH3

An analysis of the mixture at equilibrium contained 2.0 mol N2, 3.0 mol
H2, and

1.5 mol NH3 . How many moles of H2 were present at the beginning of
the reaction?

A.

D. Answer

20. B.

E. 4.0

6.0 C. 4.5 D

Consider the equilibrium:

N2(g) + 3H (g) 2NH3(g)

at a certain temperature. An equilibrium mixture in a 4.00-L vessel

contains

1.60 mol NH3, 0.800 mol N2, and 1.20 mol H2. What is the value of
Kc?

A.

D. Answewr

21. 3.0

5.3 9.00

17.1 E. B.

7.41 29.6 B The equilibrium constant for the reaction

H2(g) + I2(g) 2HI(g) C. 3.37 is 62.5 at 800 K. What is the equilibrium

concentration of I2 if [HI] = 0.20 M and

[H2] = 0.10 M at equilibrium?

A.

D. 3.2 x 102 M

0.10 M B.

E. 8.0 x 104 M

6.4 x 103 M C. 0.20 M Answer E 22. Exactly 1.0 mol N2O4 is placed
in an empty 1.0-L container and is allowed to reach equilibrium

described by the equation

N2O4(g) 2NO2(g)
If at equilibrium the N2O4 is 20% dissociated, what is the value of the
equilibrium constant for the

reaction under these conditions?

A.

D. Answer

23. 0.05

20 B.

E. 0.2

400 C. 0.5 B

At a given temperature, 0.300 mol NO, 0.200 mol Cl2, and 0.500 mol
ClNO were placed in a 25.0-L

container. The following equilibrium is established:

2ClNO(g) 2NO(g) + Cl2(g)

At equilibrium, 0.600 mol ClNO are present. How many moles of Cl2
are present at equilibrium?

A.

D. Answer

24. 0.050

0.200 B.

E. 0.100

0.250 C. 0.150 C
At a given temperature, an equilibrium mixture of the reaction

2NO(g) + O2(g) 2NO2(g)

contains 0.090 mol NO, 0.120 mol O2, and 0.060 mol NO2 in a 3.00-L
container. The value of Kc

is

A.

D. 3.7.

11. Answer D

25. Consider the reaction B.

E. 6.1.

17. C. 9.3. S2Cl2(l) + CCl4(l) CS2(g) + 3Cl2(g) Ho = 84.3 kJ If the

above reactants and products are contained in a closed vessel and the
reaction system is at

equilibrium, the number of moles of CS2 can be increased by

A.

B.

C.

D.

E. adding some S2Cl2 to the system.

removing some CCl4 from the system.

decreasing the size of the reaction vessel.

increasing the temperature of the reaction system.

adding some Cl to the system. Answer

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