Aplicações em Fábrica de Cloro.

2008 AppliTek NV/SA,
Safety Workshop: Process Safety Management (PSM)
CDB 2014 AppliTek Nov. 14th 2014 Hilton So Paulo Brazil www.applitek.com
The content of this page/document is entirely a non-binding external opinion. Neither AppliTek NV nor any of its employees can be held liable for damages to people, third parties, goods and assets, that may result from implementing the content
APLICAES EM FABRICAS DE CLORO

O2 em H2-Segurana do Processo
O2 em Cl2-Qualidade do Produto
Analisador a laser
Resposta Rapida- <2 Segundos
Estvel- Calibrao Anual
Resistente- Sem contato com
2900 amostra
In Situ - Sem contato com amostra
Pouca manuteno
H2 em Cl2-Qualidade do Produto
H2 +Cl2 = 2HCl, 2HCl/2 = H2

Estvel- interferenia cruzada =0
Resistente- contato com amostra-
celula de Hastelloy
2500 HCl + Conversor Resposta Rapida-Melhor do que com
TC (termocondutividade)
UV
Soluo
Diagrama de Fluxo da
Amostragem
Ponto de Amostragem
Resposta Rapida-<2 Segundos

Estvel-Calibrao Anual
Resistente- Sem contato com
amostra
Sistema no extrativo-IN SITU
2900
SEM SISTEMA DE AMOSTRAGEM
Baixo limite de deteo-0.03ppm
Soluo
H2O em Cl2-Qualidade do Produto
HCl- Emissoes no Incinerador
Resposta Rapida-<2 Segundos

Estvel-Calibrao Anual
In-Situ-Sem Sistema de Amostragem
Baixa Limite de Deteo-0.05ppm
2900
Relatorio em Base Seca (CONAMA)-
Medio Opcional H2O
Instalao
HCl- Emissoes no Incinerador
Transmissor DN 50 Flanges Receptor
Alinhamento Entrada
Diodo a e Purga de purga Entrada de Detector
Laser
gas de
calibracao
Janela Saida de
gas de calibracao
Gas do
Processo
LINHA APPLITEK- analisadores diversos de gases e liquidos
Analisadores de Oxigenio
Analisadores de diversos gases em Processo e CEMS
Analisadores de umidade (dew point)
Analisadores de Combusto
Detectores fixos e portateis de cloro para proteo da rea

TONI special (Total Ammonia)

Medio on-line de Total Amonia[amonia (NH3)+monocloramina
(NH2Cl) + dicloramina (NHCl2)] em Ultra-Purified brine
Early Warning
Evita formao de nitrogen trichloride (NCl3)
Evita Exploso do nitrogen trichloride (NCl3)
Medio on-line FAST do hidrogenio (H2) em cloro MIDO (Cl2)

using Multi Wavelength InfraRed ( IR ) Technology
Early Warning
Avoid hydrogen (H2) explosion
by: Chris Du Bois
Safety is not Expensive

It is Priceless !
WHY Quality CONTROL

Gas Chromatography
"SAFETY IS NOT EXPENSIVE - IT IS PRICELESS
Safety
on-line Analyzer Workshop:
Systems Process
for Safety and Safety
ControlManagement (PSM)
of Chlorine Production Plants
EZ-Brinesulfate EZ-Brinesulfite www.applitek.com
12 17 18
WHY SAFETY CRITICAL WHY SAFETY CRITICAL SAFETY CRITICALthe content WHY prevent CORROSION
The content of this page/document is entirely a non-binding external opinion. may
range: Neither AppliTek NV nor any of its employees can be held liable for damages to people, third parties, goods and assets, thatWHY result from implementing
range: PROTECT against Explosion PROTECT Plant against hydrogen Explosion
1.000 mg/l range: 10 / 20 / 200 ppm (H2O)
range: 0 1%vol H2 | 0 5%vol 0.5 20 g/kg meta bisulfite oxygen (O2) in range: 10 / 100 / 1,000 / 5,000 < 30 seconds
O2 | 0 2%vol CO2 | 0 2%vol Na2SO4 (Na2S2O5) DRY Chlorine (Cl2) ppm (NCl3) 10 range: 0 5%vol H2 response time
N2 | 90 2%vol Cl2 (by
by Paramagnetic analyzer
calculation sum all components 11
subtracts from 100 for % Cl2). range: 0 5 %vol
10
10 10 12
13 14 13
WHY WHY FAST hydrogen (H2) in DRY chlorine (Cl2) moisture (H2O) in DRY chlorine (Cl2)
PROCESS CONTROL SAFETY by multi wavelength INFRARED by Amperometric (P2O5) cell
chlorine (Cl2) in EZ-NCl3
15 13 DRY Chlorine (Cl2) nitrogen trichloride (NCl3)
16
by multi wavelength UV in DRY chlorine (Cl2)
16 15 WHY SAFETY CRITICAL
PROTECT against hydrogen Explosion
EZ-Bleach range: 0 200 ppm vol (H2)
sodium hypochlorite (NaOCl) 14
sodium carbonate (Na2CO3) 12
sodium hydroxide (NaOH) 11 10 9
sodium chloride (NaCl)
in sodium hypochlorite (NaOCl)
oxygen (O2) in hydrogen (H2)
by Electrochemical cell
WHY brine QUALITY 18
Up-stream Control Brine Purification
LIMIT dosage of 17 9
WHY caustic QUALITY
hydroxides (NaOH) & carbonates (Na2CO3) 2
1 range: 10 100 ppm (Cl-)
1 8
UPA titrimetric 7
2 points acid / base pH titration
range: 1 g/l NaOH | 1.5 g/l Na2CO3 4 5
EZ-Chloride
water
Chlorides (Cl-) in causitc soda (NaOH)
6
3
7
WHY brine QUALITY WHY brine QUALITY WHY brine QUALITY WHY SAFETY CRITICAL WHY SAFETY CRITICAL
Control Brine Filter Cleaning Flush-back Up-stream Control AVOID membrane damage AVOID formation of EARLY WARNING hydrogen detection
nitrogen trichloride (NCl3) PROTECT your Chlorine Plant against hydrogen Explosion
range: 0 50 FTU / NTU range: 20 ppm Ca2+ & Mg2+ range: 0 50 100 ppb
range: 0 10 ppm FAST hydrogen (H2) in WET chlorine (Cl2)
range: 10 ppm Ca2+
Mg2+ by calculation by multi wavelength INFRARED
4
range: 1000 g/l
6 < 30 seconds
2 2 3 5 8 response time
EZ-Brinehigh EZ-Brine TONI special (Total Ammonia)

EZ-Brine Total Ammonia
calcium (Ca2+) calcium (Ca2+) &
calcium (Ca2+) [ ammonia (NH3) +
ULTRASONIC & magnesium (Mg2+) magnesium (Mg2+) FAST oxygen (O2) in WET chlorine (Cl2)
& magnesium (Mg2+) monochloramine (NH2Cl) +
TURBIDITY in Pre-purified Brine in Pre-Purified Brine in HCl (36%) dichloramine (NHCl2)] by Alternating Pressure Paramagnetic analyzer
in Ultra-Purified Brine
2013 AppliTek NV / SA
Leading supplier of on-line brine analyzer systems
Associated Member Technical Correspondent
Works good, Looks Good

Leading supplier of Safety Critical (Life Saving)

on-line hydrogen analyzer systems
Associated Member Technical Correspondent
Works good, Looks Good


on-line Total Ammonia [ ammonia (NH3) + monochloramine (NH2Cl) +
dichloramine (NHCl2)] in Ultra-Purified brine
Early Warning
Prevent formation of nitrogen trichloride (NCl3)
Avoid nitrogen trichloride (NCl3) explosion
WHY SAFETY CRITICAL
AVOID formation of nitrogen trichloride NCl3)
range: 0 10 ppm

Total Ammonia [ ammonia (NH3) +
monochloramine (NH2Cl) +
dichloramine (NHCl2)]

Vacuum
on-line Total Amonia [ amonia (NH3) +
DE- CHLORINATOR
monocloramina (NH2Cl) + dicloramina (NHCl2)] in Ultra-Purified brine
BRINE
caustic soda Further Chlorine
(NaOH) Processing
Return Brine or Depleted Brine DEPLETED HYDROGEN

BRINE PURIFICATIO
TANK N
Water sodium carbonate (Na2CO3) Filtration Aid
hydroxides (NaOH)
WET chlorine hydrogen

Chemicals (Cl2) (H2)
ION EXCHANGER A
ION EXCHANGER B
ION EXCHANGER C
Salt Raw Saturated Brine Pre-Purified Brine FILTRATION
SETTLING
Re-Generation
Re-Generation
Chemicals
Cl2 H2
WHY SAFETY CRITICAL Sludge Solids
Precipitated Depleted
AVOID formation of nitrogen CaCO3 () Brine _
+
trichloride (NCl3) Mg(OH)2 ()
range: 0 10 ppm 33%
MEMBRANE
BRINE NaOH
STORAGE
320 g/l NaCl caustic
Water soda
(NaOH)
cathode
anode
6
hydrogen 30%
Saturate NaOH
chloride ACIDIFICATION Ultra-Purified Brine
d Brine
(HCl)
ELECTROLYZER
Total Ammonia [ ammonia (NH3)
WHERE ?
+ monochloramine (NH2Cl)
+ dichloramine (NHCl2)]
TONI special (Total Ammonia) on-line Total Ammonia [ ammonia (NH3) + monochloramine
(NH2Cl) + dichloramine (NHCl2)] in Ultra-Purified brine
WHY ? EARLY WARNING:

Prevent formation of Nitrogen trichloride (NCl3) | avoid explosion
Most Chlorine (Cl2) is produced by electrolysis of brine generated by dissolving Sodium
Chloride (NaCl) or Potassium Chloride (KCl) in water (H2O). Side reactions with the Nitrogen
impurities in the salt can lead to the formation of Nitrogen trichloride (NCl3) during the
Chlorine process.
Nitrogen compounds present in the BRINE are the main source for the formation of
Nitrogen trichloride (NCl3).
In certain parts of the Chlorine production, the Chlorine is either liquefied or evaporated.
Due to its lower volatility, the NCl3 accumulates in liquid Chlorine.
Traces of Ammonia (NH3) and other Nitrogen compounds in BRINE can produce NCl3 in
Chlorine.
WHY ? EARLY WARNING:

Prevent formation of Nitrogen trichloride (NCl3) | avoid explosion
Prevention of Nitrogen trichloride (NCl3) formation:
Approximately 25% of Nitrogen trichloride (NCl3) formed in cells enters the chlorine process (1)
Ammonia in cell feed brine is the major source (1)
Learning from incidents:

Nitrogen trichlorinde incident @ Orica, Yarraville 30 July 1998 (1)
One of the conclusions after investigation was: Inaccurate method and inadequate frequency of analysis
for ammonia in brine
(1)ManagingRisks Nitrogen Trichloride by Shane Fast - Vice President The Chlorine

Institute @ the WORLD chlorine council meeting.
N-compounds + Cl2 NCl3

HOW ?
Measuring Principle TONI special (Total Ammonia)
by Colorimetric analysis (Adapted Berthelot
method conform ASTM 4500-NH3 F)
To determine the total amount of NH3, NH2Cl and
NHCl2, NH2Cl and NHCl2
they have to be converted to NH3. This is done by
adding thiosulphate.
Reactions:
4 NH2Cl + Na2S2O3 + 5 H2O 2 NaHSO4 + 4 NH3 + 4 HCl
2 NHCl2 + Na2S2O3 + 5 H2O 2 NaHSO4 + 2 NH3 + 4 HCl
HOW ?
Measuring Principle TONI special (Total Ammonia)
injection of BRINE sample in analyzer

addition of buffer Alkaline
Initial absorbance value is measured at () 630 nm (ABS 1)
addition of color solution
Final Absorbance value is measured at () 630 nm (ABS 2)
calculation of result: Lambert Beers Law ABS = . b. C
= molar absorptivity (l . cm-1. mol-1)
b = path length (cm)
C = concentration (mol/liter)
HOW ?
methodology: colorimetric measurement using

adapted Berthelot method
conforms to: ASTM 4500-NH3 F
LED: 630 nm
range: 0 - 2 mg/l NH3
(0 - 10 mg/l NH3 by Sample dilution) ~ 0 50 mg/l N-NH3
higher range by Sample dilution*
detection limit: 100 g/l (for 0-1 mg/l NH3)
precision: < 2% full scale range for standard test solutions
cycle time: 1 cycle/25 minutes
stream selection: 1 stream (up to 3 streams optional)
(NH2Cl) + dichloramine (NHCl2)] in Ultra-Purified brine Field Example
AnaShell protective shelter
Including single stream
TONI Special (Total Ammonia)
in Ultra-purified brine
USA
(NH2Cl) + dichloramine (NHCl2)] in Ultra-Purified brine Field Example
AnaShell protective shelter
Including single stream
TONI Special (Total Ammonia)
in Ultra-purified brine
USA
Early Warning !
Plant SAFETY
Critical Equipment
Eliminating the risk of hydrogen explosions in chlor-alkali plants

on-line FAST determination of hydrogen (H2) in WET chlorine (Cl2) by Multi-Wavelength INFRARED
Vacuum
on-line FAST determination of hydrogen (H2) in WET chlorine (Cl2) by
DE- CHLORINATOR
Multi-Wavelength InfraRed
8
BRINE
caustic soda Further Chlorine
(NaOH) Processing
Return Brine or Depleted Brine DEPLETED HYDROGEN

BRINE PURIFICATION
TANK
Water sodium carbonate (Na2CO3) Filtration Aid
hydroxides (NaOH)
WET chlorine hydrogen

Chemicals (Cl2) (H2)
ION EXCHANGER A
ION EXCHANGER B
ION EXCHANGER C
Salt Raw Saturated Brine Pre-Purified Brine FILTRATION
SETTLING
Re-Generation
8
Re-Generation
Chemicals
Cl2 H2
Sludge Solids
Precipitated Depleted
CaCO3 () Brine + _
Mg(OH)2 ()
33%
MEMBRANE
NaOH
EARLY WARNING hydrogen detection BRINE
PROTECT your Chlorine Plant against hydrogen STORAGE
320 g/l NaCl caustic
8
Explosion Water soda
(NaOH)
cathode
FAST hydrogen (H2) in WET chlorine (Cl2)
anode
by multi wavelength INFRARED hydrogen 30%
Saturated NaOH
< 30 seconds chloride ACIDIFICATION Ultra-Purified Brine
response time Brine
(HCl)
ELECTROLYZER
FAST oxygen (O2) in WET chlorine (Cl2)
WHERE ?
by Alternating Pressure Paramagnetic analyzer
It is Priceless !
High H2 present High Energy present
Defined as: General Purpose Zone (NON explosion Proof)

WHY ?
Low voltage High Current = High Energy
High Electrical Current NO electrical Ex Proof Technology possible
Chlorine Electrolysis Process
FAST on-line analysis of Hydrogen (H2) on-line Hydrogen Analyzer system
in WET Chlorine gas to keep the gas
matrix within the flammability limits.
Field Proven Technology

FAST Response (T90 = 15 seconds)
GOOD results during start-up CELL ROOM
HAZOP approved
It is Priceless !
Misconceptions ! Plant SAFETY

Critical Equipment
Hindenburg disaster
hydrogen is a light gas NO RISK

hydrogen is not an hydrocarbon NO RISK
one of your ONLY protections is to have an
May 6, 1937 Lakehurst, New Jersey
Safety is not Expensive on-line hydrogen (H2) in WET chlorine (Cl2) by Multi-Wavelength InfraRed 8
It is Priceless !
on-line analyzer system for the FAST determination of hydrogen (H2) in WET chlorine (Cl2)
hydrogen is not waiting to ignite until you

are ready with analysis !!!
Every second counts !!!
Response time of < 35 seconds T90
Do not install an analyzer systems that needs minutes to show results
presented by Jean-Pol Debelle (Technical Director Eurochlor)

@ WCC Global Safety Team meeting in Dubai, UAE
October 24th 2013

It is Priceless !
presented by Jean-Pol Debelle (Technical Director Eurochlor)

@ WCC Global Safety Team meeting in Dubai, UAE
October 24th 2013

It is Priceless !
Plant SAFETY
Membrane type Chlorine Production Critical Equipment
on-line H2 in WET Cl2
Cathode
Anode
Safety is not Expensive Courtesy of the Euro Chlor federation, www.eurochlor.org "
It is Priceless !
Protect Your plant against HYDROGEN Explosions
Hydrogen Chlorine mixture can be flammable if Hydrogen > 4% (v/v)

WHY ? temperature: 110C / 230F
Gas Chlorine by volume
initial pressure: 1 bar / 15psi
Cell gas
Chlorine 31%vol
Hydrogen 0.2%vol
Water vapor 68.2%vol
Inerts 0.6%vol
typical gas - matrix @ wet chlorine header electrolysis cells: Hydrogen Chlorine
mixture can be
flammable if
Hydrogen
concentration
> 3 - 4%vol

It is Priceless !

Hydrogen Chlorine mixture can be flammable if Hydrogen > 4% (v/v)
typical chlorine gas travel time = 2,5min.
WHY ? Gas chlorine cell gas outlet compressor 50% liquefaction 90% liquefaction
Chlorine 31%vol 97,5%vol 48.7%vol 9.7%vol
Hydrogen 0.2%vol 0.6%vol 1.2%vol 5%vol
water vapor 68.2%vol - - -
Inerts 0.6%vol 1.9%vol 50.1%vol 85.3%vol
REMARK: Liquefaction is a Dynamic
T90 = 15s
T90 = 15s
T90 = 15s
T90 = 15s
process. Dry Air, Nitrogen or even in
some cases CO2 are injected to keep the DRYER 1st LIQUEFACTION 2nd LIQUEFACTION
mixture H2 Cl2 outside the flammable removal of water vapor Cl2 gas condensed Cl2 gas condensed
limits to Liquid Chlorine to Liquid Chlorine
Double system for Safety Double system for Safety
on-line H2 in WET Cl2 on-line H2 in DRY Cl2 on-line H2 in DRY Cl2

It is Priceless !
on-line analyzer system for the FAST determination of hydrogen (H2) in WET chlorine (Cl2)
by Gas-Chromatograph by by
(GC) 1 Thermal Conductivity (TC) 2 Multi-Wavelength INFRARED (MW-IR) 3
Thermal Conductivity Multi-Wavelength INFRARED

+ +
UV light UV light
H2 + Cl2 2 HCl H2 + Cl2 2 HCl

differential measurement H2 and Cl2 is oxidized by UV to HCl
Delta TC before - and after HCl is measured by MW-IR
Discontinuous measurement oxidation by UV UV reactor % HCl stoechiometrically equal to H2 UV reactor
Long analysis time (several min.!)

Selective measurement for H2
Can only be used for Quality Control Not Selective measurement for H2 Calibration Matrix - independable
Cannot be used for Process Control Calibration Matrix - dependable Fast Response (T90 < 20 seconds)
Cannot be used for SAFETY Does not react first 6 12 min. after Shows Good results @ Plant
Complex Technology Plant Start-up
Start-up
High Maintenance Cannot be used for SAFETY during Best Available Technology
Low Up-time Plant Start-up
Field Proven High Up-time
on-line FAST determination of hydrogen (H2) in DRY chlorine (Cl2) by Multi-Wavelength InfraRed
WHY SAFETY CRITICAL
caustic soda
PROTECT Plant against hydrogen Explosion
(NaOH) 20%
WASTE CHLORINE GAS
< 30 seconds response time

10 range: 0 5%vol H2
SCRUBBER
11
sodium 12
hypochlorite
or
13
bleach
(NaOCl) Tail Gas 13
FAST hydrogen (H2) in DRY chlorine (Cl2)
by multi wavelength InfraRed
LIQUEFIER
CHLORINE
LIQUID CHLORINE CHLORINE Dilution sulfuric acid

STORAGE CONDENSOR Air (H2SO4)
12
CHLORINE DRYER
Cooling High chlorine Low chlorine Chilled
Water CW Pressure Pressure Cooling
Cooling
Water
SECONDARY
Water
COOLER
CW
PRIMARY
COOLER
INTERSTAGE 10 CCW
WET CHLORINE
CHLORINE DRY CHLORINE
COOLER
DEMISTER
11 COMPRESSOR DEMISTER
Cooling
Water CW
WET chlorine
chlorine travel time = 5 to 6 minutes
(Cl2)
hydrogen chlorine mixture can be flammable if Hydrogen > 4% (v/v)
8 on-line analyzer system for the FAST determination of hydrogen (H2) in WET chlorine (Cl2)
by Multi-Wavelength
INFRARED (MW-IR)
3
HOW ?
Best Available Technology
Multi-Wavelength INFRARED measurements eliminates the
influence of the environment and distinguish between H2O
Multi-Wavelength INFRARED
and HCl. This allows measurement of HCl in WET chlorine.
+
UV light
H2 + Cl2 2 HCl
H2 and Cl2 is oxidized by UV to HCl
HCl is measured by MW-IR
% HCl stoechiometrically equal to H2 UV reactor
INFRARED absorption
Selective measurement for H2 IR spectra 100% Hydrogen Chloride
Calibration Matrix - independable
Fast Response (T90 < 20 seconds)
Shows Good results @ Plant
Start-up
Field Proven High Up-time Hydrogen Chloride (HCl) Water (H2O)
single stream on-line FAST determination of hydrogen (H2) in WET chlorine (Cl2) by Multi-Wavelength InfraRed
typical 10 m (32 ft)
Thermostatically controlled electrically traced thick wall PFA insulated sample bundle
Vortex
Cooler Multi-wavelength InfraRed analyzer
Process Valve
Heat Shrink Sample Bundle Entry by Customer DIP-tube
STOP
Main
Chlorine
Salt Washing Header
Water Removal
Salt Filtration
UV reaction (H2 + Cl2 2HCl)
Height = 2 m (6 ft 56)
Pressure Control
double compartment Flow Control
corrosion resistant Sample Aspiration
insulated protected Flame Arrestor Protection
cabinet
IP56 / NEMA 4X
Logic Control
Electrical Compartment 1 Analytical Compartment 2
height = 2 m (6 ft 56) height = 2 m (6 ft 56)
Width = 1 m (3 ft 28) Width = 2 m (6 ft 56)
Depth = 0 m 5 (1 ft 64) Depth = 0 m 5 (1 ft 64)

Shows Good results @ Plant Start-up
Width = 3 m (9 ft 84) Best Available Technology
UV - Reactor
H2 + Cl2 2HCl Water
Lifting / Mounting Condensate Drain Condensation
Support Pump
by Multi-Wavelength
INFRARED (MW-IR)
3
HOW ?
Plant SAFETY
Critical Equipment
by Multi-Wavelength
INFRARED (MW-IR)
3
Pyro Electric Lithium Tantalite
solid-state INFRARED Detector
(FET transistor) with Medium Broadband (Pt)
HOW ?
Sensitivity but High stability. INFRARED source
N2 purged Sapphire N2 purged

NO damage by Cl2 possible Windows NO damage by Cl2 possible
Detector Source
Enclosure Enclosure
Best Available Heated Hastelloy-C Sample Cell Rotating Optical

Technology up to 34 bar (510psi) Filter
Start-up Membrane type Chlorine Plant by Gas-Chromatograph (GC)
0.4% H2 in Cl2
5 min. 30 s 1
by
Multi-Wavelength INFRARED (MW-IR) Air Dilution
3
6 min. Load (kA)
Multi-Wavelength INFRARED (MW-IR)
Start-up Start-up
Hydrogen HydrogenPeak
peak
0 % H2 in Cl2
by Thermal Conductivity (TC)
2
Start-up Membrane type Chlorine Plant by Gas-Chromatograph (GC)
5 min. 30 s 1
0.4% H2 in Cl2
by
Air Dilution
3
5 min.
Hydrogen Start-up Peak
Load (kA)
by Thermal Conductivity (TC)
0% H2 in Cl2
2
Hydrogen (H2) peak during Start-up Membrane type Chlorine Plant

Migration of hydrogen from the cathode compartment to the anode compartment is caused by
small holes in the membrane. This hydrogen flow is mainly depending on the pressure difference
of the two compartments, the pressure in the cathode compartment is higher than in the anode
compartment. This pressure difference is kept constant. Consequently, the flow of hydrogen to the
anode compartment is more or less independent of the cell load.
During start up of the cell, there is hardly any chlorine flow, and consequently, you achieve a
rather high hydrogen concentration. With increasing chlorine production, this hydrogen is diluted,
and the hydrogen concentration decreases.
Hydrogen (H2) peak during Start-up Membrane type Chlorine Plant
Hydrogen in Wet Chlorine

The issue of excessive hydrogen concentrations on the
chlorine side of a membrane cell during start-up has been
raised. The peak concentrations can be dangerously high
depending on the speed at which the facility goes trough the
start up procedure. The Issue team discussed the issue and
agreed that the phenomenon was generally understood by
all producers
Start-up Membrane type Chlorine Plant
20 min.
P H2 / Cl2 (mbar)
2%vol H2 in Cl2
by
3
0,85%vol H2 in Cl2 Load (kA)
2%vol H in Cl
2 2 (MW-IR)
Multi-Wavelength INFRARED
START
Hydrogen Start-up Peak
0%vol H2 in Cl2
on-line hydrogen (H2) in WET chlorine (Cl2) PRECONDITIONING
FIELD proven preconditioning @ Sample Take Off Point (STOP)

Sample Probe with DIP-tube
Sample Cooler / Coalescer
measures the sample after oxidation

(H2 + Cl2 2HCl)
H2 and Cl2 is Oxidized by UV to HCl and is
measured by the INFRARED analyzer
FIELD proven preconditioning

Salt Filtration
Water removal
UV reactor (H2 + Cl2 2HCl)
Flow & Pressure Control

Due to high electrical currents a Chlorine Production Plant is defined
as General Purpose zone Need for Flame Arrestors
Chlorine
resistant Flame
Arrestor
Protection
ANALYZER system CHLORINE Plant
Chlorine
resistant Flame
Arrestor
Your Analyzer system can be a source of explosion for your plant !

FIELD Example
example AnaShell multi-compartment protective cabinet

Plant SAFETY 1 x on-line Analyzer system for Hydrogen in WET Chlorine
Critical Equipment (Multi Wavelength INFRARED)
on-line FAST determination of hydrogen (H2) in WET chlorine (Cl2) by Multi-Wavelength InfraRed
Field Example
Joutseno Finland
1 x on-line Analyzer system for hydrogen in WET chlorine
Plant SAFETY
Critical Equipment
Field Example
Plant SAFETY
Critical Equipment
Joutseno Finland
1 x on-line Analyzer system for Hydrogen in WET Chlorine
Field Example
Plant SAFETY
Critical Equipment
Joutseno Finland
on-line FAST determination of Hydrogen (H2) in WET Chlorine (Cl2) by Multi-Wavelength INFRARED
The bitterness of poor quality remains long after the sweetness of low
price is forgotten, especially for life saving, safety critical equipment
You can only apply Best Available Technology
Safety is not expensive, it is priceless
Plant SAFETY
Critical Equipment
Field Example
Plant SAFETY
Critical Equipment
Yokkaichi,Japan
Field Example Repeat Order
Yokkaichi,Japan
Plant SAFETY example AnaShell multi-compartment protective cabinet
Critical Equipment 1 x on-line Analyzer system for Hydrogen in WET Chlorine
Canada
Plant SAFETY example AnaShell multi-compartment protective cabinet
(Multi Wavelength INFRARED)
Field Example
Banten, Indonesia Plant SAFETY

ASC PHASE V Expansion Project Critical Equipment
AnaShell multi compartment protective cabinet
Field Example
Russian Federation
Plant SAFETY IKRA Project
Plant SAFETY
Critical Equipment
Geismar, LA, USA

Plant SAFETY
Critical Equipment
Geismar, LA, USA

Plant SAFETY
Critical Equipment
Geismar, LA, USA

Manual Stream Selection
Vortex
Cooler
Thermostatically controlled electrically traced thick wall PFA insulated sample bundle
Multi-wavelength InfraRed analyzer
Process Valve
Heat Shrink Sample Bundle Entry by Customer DIP-tube
DIP-tube
DIP-tube
STOP
DIP-tube Main
Chlorine
Salt Washing DIP-tube
Header
Water Removal
Salt Filtration DIP-tube
UV reaction (H2 + Cl2 2HCl) DIP-tube
Pressure Control
double compartment Flow Control DIP-tube
corrosion resistant Sample Aspiration
insulated protected Flame Arrestor Protection
cabinet
IP56 / NEMA 4X
Logic Control

UV - Reactor
H2 + Cl2 2HCl Water
Lifting / Mounting Condensate Drain Condensation
Support Pump
Dual stage
Salt MANUAL
Crystal Flow & Pressure Oxidation
t Cl2 + H2 = 2HCl
Gas Cooler Filter Control
Flame
Arrestor
H2O H2O
Vent
Flame
Arrestor
STOP 1 STOP 2 STOP 3 STOP X Multi-Wavelength

INFRARED ANALYZER
Sample Take Off Probes with dip-tube
OUT
Alarm
4 20mA
% HCl
stoechiometrically
ModuPlex MANUAL Multiple Stream Control

equal to H2
IN
Field Example
Rayong, Thailand
AnaShell multi-compartment protective cabinet
1 x on-line Analyzer system for H2 in WET Chlorine
Plant SAFETY (Multi Wavelength INFRARED)
Critical Equipment
Field Example
Plant SAFETY
Critical Equipment
Rayong, Thailand
ModuPlex Automatic Stream Selection Thermostatically controlled electrically traced thick wall PFA insulated sample bundle
Vortex
Cooler
Multi-wavelength InfraRed analyzer
Process Valve
DIP-tube
Heat Shrink Sample Bundle Entry by Customer
DIP-tube
STOP
DIP-tube Main
Chlorine
DIP-tube
Header
Salt Washing DIP-tube
Water Removal
Salt Filtration DIP-tube
Logic Control double compartment UV reaction (H2 + Cl2 2HCl)

corrosion resistant Pressure Control
insulated protected Flow Control
cabinet Sample Aspiration
IP56 / NEMA 4X Flame Arrestor Protection


Lifting / Mounting
Support ModuPlex
Automatic Stream Selector
UV - Reactor
H2 + Cl2 2HCl Water
Condensate Drain
Pump Condensation
Dual stage
ModuPLEX Salt Crystal Flow & Pressure Oxidation
Stream t Cl2 + H2 = 2HCl
Selection
Gas Cooler Filter Control
Flame
Arrestor
H2O H2O
Coalescer Coolers
Vent
Cooling
Sample take-off PROBEs with DIP-Tubes Flame

Arrestor
STOP 1 STOP 2 STOP 3 STOP 9
Multi-Wavelength
WET Chlorine Headers
INFRARED ANALYZER
OUT
Alarm
ModuPlex AUTOMATIC Multiple Stream Control

4 20mA
% HCl
stoechiometrically
equal to H2
IN
Field Example

4 x on-line Analyzer system for Hydrogen in WET Chlorine Plant SAFETY
(multiple Wavelength INFRARED) Critical Equipment
Including NEW ModuPLEX Multiple Stream Control
Field Example
Plant SAFETY
Critical Equipment
2 pc AnaShell multi-compartment protective cabinets

by multi-Wavelength INFRARED)
1 x on-line Analyzer system for Oxygen in WET Chlorine
(alternating pressure PARAMAGNETIC analyzer)
Field Example
Plant SAFETY
Critical Equipment
Jubail, Saudi Arabia

1 x on-line Analyzer system for H2 in WET Chlorine using NEW ModuPlex stream selector
(multiple (19) streams !)
Field Example
Plant SAFETY
Critical Equipment
Jubail, Saudi Arabia

1 x on-line Analyzer system for H2 in WET Chlorine using NEW ModuPlex stream selector
(multiple (19) streams !)
Field Example
Plant SAFETY
Critical Equipment
Brasil
AppliTek REFERENCES ?

Aplicações em Fábrica de Cloro.

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2008 AppliTek NV/SA,

Safety Workshop: Process Safety Management (PSM)

APLICAES EM FABRICAS DE CLORO

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

H2 +Cl2 = 2HCl, 2HCl/2 = H2

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

H20 em Cl2-Qualidade do Produto

Resposta Rapida-<2 Segundos

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

HCl- Emissoes no Incinerador

Resposta Rapida-<2 Segundos

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

LINHA APPLITEK- analisadores diversos de gases e liquidos

Analisadores de diversos gases em Processo e CEMS

Analisadores de umidade (dew point)

Detectores fixos e portateis de cloro para proteo da rea

Safety Workshop: Process Safety Management (PSM)

TONI special (Total Ammonia)

Medio on-line FAST do hidrogenio (H2) em cloro MIDO (Cl2)

by: Chris Du Bois

Safety is not Expensive

WHY Quality CONTROL

EZ-Brinehigh EZ-Brine TONI special (Total Ammonia)

Safety Workshop: Process Safety Management (PSM)

Leading supplier of on-line brine analyzer systems

Associated Member Technical Correspondent

Works good, Looks Good

Safety Workshop: Process Safety Management (PSM)

Leading supplier of Safety Critical (Life Saving)

Associated Member Technical Correspondent

Works good, Looks Good

Safety Workshop: Process Safety Management (PSM)

TONI special (Total Ammonia)

TONI special (Total Ammonia)

Safety Workshop: Process Safety Management (PSM)

TONI special (Total Ammonia)

Return Brine or Depleted Brine DEPLETED HYDROGEN

WET chlorine hydrogen

Safety Workshop: Process Safety Management (PSM)

WHY ? EARLY WARNING:

Safety Workshop: Process Safety Management (PSM)

WHY ? EARLY WARNING:

Learning from incidents:

(1)ManagingRisks Nitrogen Trichloride by Shane Fast - Vice President The Chlorine

N-compounds + Cl2 NCl3

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

injection of BRINE sample in analyzer

Safety Workshop: Process Safety Management (PSM)

methodology: colorimetric measurement using

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

Safety Workshop: Process Safety Management (PSM)

Eliminating the risk of hydrogen explosions in chlor-alkali plants

Safety Workshop: Process Safety Management (PSM)

Return Brine or Depleted Brine DEPLETED HYDROGEN

WET chlorine hydrogen

FAST oxygen (O2) in WET chlorine (Cl2)

Safety Workshop: Process Safety Management (PSM)