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Chemistry

1. Solid CO2 is an example of ?


(a) Molecular crystal (b) Ionic crystal
(c) Covalent crystal (d) Metallic crystal

2. NaCl is an example of
(a) Covalent solid (b) Ionic solid
(c) Molecular solid (d) Metallic solid
3. Diamond is an example of
(a) Solid with hydrogen bonding (b) Electrovalent solid
(c) Covalent solid (d) Glass
4. Which of the following is an example of metallic crystal solid
(a) C (b) Si (c) W (d) AgCl
5. Which of the following is non-crystalline solid
(a) CsCl (b) NaCl (c) CaF2 (d) Glass
6. For cubic coordination the value of radius ratio is
(a) 0.732-1.000 (b) 0.225-0.414
(c) 0.000-0.225 (d) 0.414-0.732
7. In a face-centered cubic lattice, a unit cell is shared equally by how
many unit cells
(a) 8 (b) 4 (c) 2 (d) 6
8. The edge length of face centred unit cubic cell is 508 pm. If the
radius of the cation is 110 pm, the radius of the anion is

(a) 285 pm (b) 398 pm (c) 144 pm (d) 618 pm

9. Amorphous solids are


(a) Solid substance in real sense (b) Liquid in real sense
(c) Supercooled liquid (d) Substance with definite melting point

10. If NaCl is doped with 10-3 mol % SrCl2, then the concentration of cation
vacancies will be
(a) 1 10-3 mol % (b) 2 10-3 mol %
(c) 3 10-3 mol % (d) 4 10-3

11. Mass of one atom of X is 6. 66 10-23 g. Hence, number of moles of atom


X in 40kg is
(a) 103 mol (b) 10-3 mol
(c) 40 103 (d) 40 10 3
6.66 10-23 6.02 1023
12. What mass of ammonium phosphate (N H4)3 PO4 would contain 14.0gm
of nitrogen?
(a) 50.0g (b) 25.0g
(c) 12.5g (d) 100.0g

13. If the dot under a question mark has a mass of 1 106 gm ,how many
atoms are required to make such a dot of carbon ?
(a) 5.1016 (b) 1210-6
(c) 10-6 (d) 10-6
12 NA
14. what is the weight percentage of Carbon, Hydrogen & Oxygen
respectively in Ethanol ?
(a) 52,13,35 (b) 48, 20, 32
(c) 25,35, 40 (d) 30, 18, 52
15. A compound contains 4% H, 24% C, and 72% Cl. If its molar mass is 99
gm, then what is its molecular formula?
(a) CH2Cl (b) C2H4Cl2
(C) CHCl (d) CHCl2
16. In the manufacturing of Amonia 14gm N2 reacts with 10 gm H2 . find the
final weight of Amonia & Hydrogen respectively ?
(a) 14, 5 (b) 18, 6
(c) 17, 7 (d) None

Passage : In NaCl (Rock salt) structure, Cl- ions make f.c.c, while Na+ ions
occupy all octahedral voids, a is the edge length of unit cell. Based on the
given information answer the following 3 (17,18,19) questions?

17. Distances between two Na+ ions?


(a) a, a/2 (b) a, a/
(c) a , a/ (d) None
18. Distances between opposite (Na+ & Cl -) ions ?
(a) a, a/2 (b) a/2, a
(c)a , a (d) (a )/2, a/2
19. How many effective ions are present in a unit cell?
(a) 1,1 (b) 2,2
(c) 3,3 (d) 4,4

20. Packing fraction of H.C.P unit cell?


(a) 52% (b) 64% (c) 74% (d) 90%
21. Which one in the following contains ionic as well as covalent bond?
(A) CH4 (B) H2 (C) KCN (D) KCl

22. The oxidation state of each oxygen atom in Na2O2 is


(A) 2 each (B) 2 and 0 (C) 1 each (D) None of the above

23. Potassium crystallizes in a bcc lattice, hence the co-ordination number


of potassium metal is:
(a) 0 (b)4 (c)6 (d)8

24. In a solid lattice the cation has left a lattice site and is located at an
interstitial position, the lattice defect is
(a) Interstitial defect (b) Valency defect
(c) Frenkel defect (d) Schottky defect

25. In a cubic structure of compound which is made from X and Y, where X


atoms are at the corners of the cube and Y at the face centres of the cube.
The molecular formula of the compound is
(a) X 2Y (b) X 3Y
(c) XY 2 (d) XY 3

26. An ionic compound has a unit cell consisting of A ions at the corners of a
cube and B ions on the centres of the faces of the cube. The empirical
formula for this compound would be
(a) AB (b) A 2B
(c) AB 3 (d) A 3B

27. An aqueous solution of 6.3 g of oxalic acid dihydrate is made up of to


250 ml. The volume of 0.1 M NaOH required to completely neutralise 10 ml
of this solution is
(A) 40 ml (B) 20 ml (C) 10 ml (D) 4 ml

28. The normality of orthophosphoric acid having purity of 70% by weight


and specific gravity 1.54 would be
(A) 11N (B) 22N (C) 33N (D) 44N

29. Which ion has the lowest radius from the following ions
(A) Na + (B) Mg ++ (C) Al +++ (D) Si++++

30. If 80 g of X combines with 1.5 10 23 atoms of Y to form X 2Y without


any of either element remaining, what is the atomic weight of X ?
(a) 8.0 10 (b) 2.0 10 (c) 1.6 10 2 (d) 1.2 102

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