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ADVANCED PATTERN ONLINE TEST-1 (AONT-1) XI
TARGET : JEE (MAIN+ADVANCED) 2017
SUBJECT : CHEMISTRY
COURSE : JA**, JA, JB, 02JB
Date (fnukad) : 09-03-2017 Time: 1 Hour (le; : 1 ?k.Vk) Max. Marks (egke vad) : 80
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
i;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA

INSTRUCTIONS / funsZ'k :
A. General : A. lkekU; %
1. This booklet is your Question Paper. Do not break 1. ;g iqfLrdk vkidk iz'u&i=k gSA bldh eqgjsa rc rd u
the seals of this booklet before being instructed to do rksMsa tc rd fujh{kdksa ds }kjk bldk funsZ'k u fn;k tk;sA
so by the invigilators.

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


2. Blank spaces and blank pages are provided in the 2. dPps dke ds fy;s [kkyh i`"B vkSj [kkyh txg bl
question paper for your rough work. No additional iqfLrdk esa gh gSA dPps dke ds fy, dksbZ vfrfjDr dkxt
sheets will be provided for rough work.
ugha fn;k tk;sxkA
3. Blank papers, clipboards, log tables, slide rules, 3. dksjs dkxt] fDyi cksMZ (CLIP BOARD)] ykWx rkfydk]
calculators, cameras, cellular phones, pagers and LykbM:y] dSYdqysVj] dSejk] lsyQksu] istj vkSj fdlh
electronic gadgets are NOT allowed inside the
examination hall. izdkj ds bysDVkfud midj.k ijh{kk d{k esa vuqefr ugha

tc rd ifjos"kd funsZ'k ugha nsa rc rd iz'u i=k dh lhy dks ugha [kksaysA
gSA
4. Write you name and roll number in the space 4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke
provided on the back cover of this booklet. vkSj jksy uEcj fyf[k,A
5. Using a black ball point pen, darken the bubbles 5. ijh ewy i`"B ds cqycqyksa (BUBBLES) dks dkys ckWy
on the upper original sheet. IokbaV dye ls dkyk djsaA
6. DO NOT TAMPER WITH/MUTILATE THE ORS OR 6. vks-vkj-,l- (ORS) ;k bl iqfLrdk esa gsj&Qsj@fofr u
THE BOOKLET. djsaA
7. On breaking the seals of the booklet check that it 7. bl iqfLrdk dh eqgjsa rksM+us ds i'pkr~ i;k tkp ysa fd blesa
contains all the 20 questions and corresponding lHkh 20 iz'u vkSj muds mkj fodYi Bhd ls i<+s tk ldrs gSaA
answer choices are legible. Read carefully the
Instructions printed at the beginning of each section. lHkh [kaMksa ds izkjaHk esa fn;s gq, funsZ'kksa dks /;ku ls i<+saA
B. Filling the ORS B.
vks-vkj-,l (ORS) Hkjuk % ORS dks Hkjus ds fy, dsoy dkys
Use only Black ball point pen only for filling the ORS. cky iSu dk mi;ksx dhft,A
8. Write your Roll no. in the boxes given at the top left 8. ORS ds lcls ij cka;s dksus esa fn, x, ckDl esa viuk
corner of your ORS with black ball point pen. Also, jksy uEcj dkys cky ikbUV ls fyf[k, rFkk laxr xksys Hkh
darken the corresponding bubbles with Black ball
point pen only. Also fill your roll no on the back side of dsoy dkys isu ls Hkfj;sA ORS ds ihNs dh rjQ Hkh viuk
your ORS in the space provided (if the ORS is both side jksy uEcj fyf[k, (;fn ORS nksuksa rjQ Nih gqbZ gSA)
printed).
9. Fill your Paper Code as mentioned on the Test Paper and 9. ORS
ij viuk isij dksM fyf[k, rFkk laxr xksyksa dks dkys
darken the corresponding bubble with Black ball point pen. cky isu ls dkys dhft,A
10. If student does not fill his/her roll no. and paper code 10. ;fn fo|kFkhZ viuk jksy uEcj rFkk isij dksM lgh vkSj
correctly and properly, then his/her marks will not be mfpr rjhds ugha Hkjrk gS rc mldk ifj.kke jksd fy;k
displayed and 5 marks will be deducted (paper wise)
from the total. tkosxk rFkk iz'u&i=k esa izkIrkad ls 5 vad dkV fy, tkosaxsaA
(Please read the last page of this booklet for rest of the instructions)
i;k 'ks"k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA
Resonance Eduventures Ltd.
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CHEMISTRY
CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,

CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Maximum Marks : 40)


[kaM 1 : (vf/kdre vad : 40)
This section contains TEN questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
1 In all other cases
bl [kaM esa nl iz'u gSaA
izR;sd iz'u dk mkj 0 ls 9 rd, nksuksa 'kkfey] ds chp dk ,d ,dy vadh; iw.kkd gSA
izR;sd iz'u esa] vks- vkj- ,l- ij lgh iw.kkd ds vuq:i cqycqys dks dkyk djsaA
vadu ;kstuk :
+4 ;fn mkj ds vuq:i cqycqys dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
1 vU; lHkh voLFkkvksa esa

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
1. How many of the following ions have the same magnetic moments?
fuEu esa ls fdrus vk;u leku pqEcdh; vk?kw.kZ j[krs gSa\

CHEMISTRY
2+ 2+ 3+
(i) Fe (ii) Mn (iii) Mn
2+ 3+ +2
(iv) Cr (v) Cr (vi) Ni

2. A certain transition in H spectrum from an excited state to ground state in one or more steps gives
rise to total 10 lines, how many of these belongs to visible spectrum.
H LisDVe esa fuf'pr lae.k ,d mksftr voLFkk ls vk| voLFkk esa ,d vFkok vf/kd inksa esa gksus ls dqy 10
js[kkvksa dh o`f) gksrh gSA buesa ls fdruh js[kk, n`'; LisDVe ls lEcfU/kr gSa \

14 A
3. N is attacked by doubly charged helium ion it emits a proton and x Calculate (A Z)
7 Z .
14
7 N ij f}dvkosf'kr ghfy;e vk;u }kjk vke.k gksrk gS] ;g izksVkWu es rFkk A
Z x mRlftZr djrk gS] rc
(A Z) ifjdfyr dhft,

4. How many of the following have negative value of electron gain enthalpy
fuEu eas ls fdrus bysDVkWu xzg.k ,UFkSYih dk _.kkRed eku j[krs gSa \
(i) Li (ii) Be (iii) N (iv) C (v) O (vi) Ne

(vii) Na (viii) O (ix) Ar (x) Al (xi) S

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
5. How many of the following have higher ionization energy than Boron?
fuEu esa ls fdrus cksajkWu ls mPp vk;uu tkZ j[krs gSa\

CHEMISTRY
(i) Al (ii) N (iii) C (iv) Be (v) Li
(vi) Na (vii) O (viii) S (ix) Cl

6. How many following order are correct :


fuEu esa ls fdrus e lgh gSa\
+ +2 +3
(i) Na < Mg < Al (I.E.)
2
(ii) Cl < S < Cl < S (radius) (f=kT;k)
(iii) Li < Na < K < Rb (metallic character) (/kkfRodvfHky{k.k)
(iv) B < Si < C < N (non metallic character) (v/kkfRod vfHky{k.k)
(v) O < Se < S (Heg, magnitude) (Heg, ifjek.k esa)
(vi) Al < C < O < F (EN)

Calculate total numbers of sp - sp hybridized carbon-carbon bonds in given compound.


2 3
7.
fuEu ;kSfxd es sp - sp ldafjr dkcZu&dkcZu cU/kksa dh dqy la[;k gSa&
2 3

CH3

CH3

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
8. How many of the following option is/are incorrect?
(I) All homocyclic compounds are aromatic compound

CHEMISTRY
(II) All position isomers have same functional group
(III) Degree of unsaturation two equivalent to two double bond or one double bond and one cyclic
or two cyclic or one triple bond.
3 2
(IV) sp carbon > sp carbon > sp carbon (order of electron negativity)
(V) COCL>-CONH2>-COOR>-CHO (priority order according to IUPAC)
(VI) All metamers have same main chain and side chain.

fuEu es ls fdrus fodYi xyr gS@gSaA


(I) lHkh lepf; ;kSfxd ,jkseSfVd ;kSfxd gksrs gSaA
(II) lHkh fLFkfr leko;oh leku f;kRed lewg j[krs gSaA
(III) nks f}cU/k ;k ,d f}cU/k rFkk ,d pf; oy; ;k nks pf; oy; ;k ,d f=kcU/k es vlUr`Ir dh dksfV nks
ds rqY; gksrh gSA
3
(IV) sp dkcZu > sp2 dkcZu > sp dkcZu (fo|qr_.krk dk e)
(V) COCl > -CONH2 > -COOR > -CHO (IUPAC ds vuqlkj ofj;rk e)
(VI) lHkh e/;ko;oh leku eq[; Ja`[kyk o ik'oZ J`a[kyk j[krs gSA

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
9. How many of the following groups have higher priority (According to IUPAC Naming) in comparison
O

CHEMISTRY
to C group.

fuEu es ls fdrus lewgksa dh ojh;rk IUPAC ukedj.k ds vuqlkj C lewg dh rqyuk es mPprj gksrh gSaA
O

(i) NH2 (ii) OH (iii) CH = O (iv) CO

(v) SH (vi) COOH (vii) SO3H (viii) C Cl

O O O

(ix) C NH2 (x) O (xi) COC

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
10. For the given compounds
fn;s x;s ;kSfxdks ds fy,

CHEMISTRY
(I) CH3 CH2 CH2 CH2 NH2 (II) CH3 CH CH2 NH2

CH3

(III) CH3 CH2 N CH3 (IV) CH3 CH2 NH CH2 CH3

CH3

(V) CH3 CH NH CH3


CH3
How many statements are correct?
(A) I and II are chain isomers (B) II and IV are functional isomers
(C) IV and V are metamers of each other (D) II and V are metamers of each other
(E) II and IV are chain isomers. (F) I and II are positional isomers.

fdrus dFku lgh gSa\


(A) I o II Ja`[kyk leko;oh gSaA (B) II o IV f;kRed leko;oh gSaA
(C) IV o V ,d nwljs ds e/;ko;oh gSaA (D) II o V ,d nwljs ds e/;ko;oh gSaA
(E) II o IV Ja`[kyk leko;oh gSaA (F) I o II fLFkfr leko;oh gSaA

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY

SECTION 2 : (Maximum Marks : 40)

CHEMISTRY
This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
1 In all other cases
[kaM 2 : (vf/kdre vad : 40)
bl [kaM esa nl iz'u gSaA
izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
izR;sd iz'u esa] lHkh lgh fodYi fodYiksa ds vuq:i cqycqys cqycqykas dks vks - vkj- ,l- esa dkyk djsaA
vadu ;kstuk :
+4 ;fn flQZ lHkh lgh fodYi fodYiksa ds vuq:i cqycqys cqycqykas dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
1 vU; lHkh voLFkkvksa esa

Space for Rough Work dPps dk;Z ds fy, LFkku

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11. Which of the following statement(s) is/are incorrect?
4 2
(A) The outer electronic configuration of the ground state of chromium atom is 3d 4s
6 5

CHEMISTRY
(B) Gamma rays are electromagnetic radiations of wavelengths of 10 cm to 10 cm.
(C) The energy of electron in 3d orbital is less than that in the 4s orbital of hydrogen atom.
(D) The electron density in the xy plane in 3dx2 y2 orbital is zero.
fuEu esa ls dkSulk@dkSuls dFku xyr gS@gSa\
4 2
(A) ksfe;e ijek.kq dh vk| voLFkk dk ckg~;re bysDVkWfud foU;kl 3d 4s gSA
6 5
(B) xkek fdj.ksa 10 cm ls 10 cm dh rjaxnS/;Z dh oS|qrpqEcdh; fofdj.ksa gksrh gSA
(C) gkbMkstu ijek.kq ds 3d d{kd esa bysDVkWu dh tkZ 4s d{kd ls de gksrh gSA
(D) 3dx2 y2 d{kd esa xy ry esa bysDVkWu ?kuRo 'kwU; gSA

12. Which of the following statement is/are correct?


(A) Total energy of electron in an orbit is half of its potential energy.
(B) The energy of an electron in an orbit decreases with increase in its quantum numbers.
(C) 2 value in the xy-plane in 3 dz2 orbital is zero.
(D) The numbers of orbitals for a given value of is equal to (2 + 1).
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa\
(A) ,d d{k esa bysDVkWu dh dqy tkZ bldh fLFkfrt tkZ dh vk/kh gksrh gSA
(B) ,d d{k esa ,d bysDVkWu dh tkZ bldh Dok.Ve la[;k esa o`f) lkFk ?kVrh gSA
(C) 3 dz2 d{kd eas xy-ry esa 2 eku 'kwU; gksrk gSA
(D) ds fn, x;s eku ds fy, d{kdksa dh la[;k (2 + 1) ds cjkcj gksrh gSA

Space for Rough Work dPps dk;Z ds fy, LFkku

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13. If the value of (n + ) is more than 3 and less than 6 then what will be possible numbers of orbitals?
;fn (n + ) dk eku 3 ls vf/kd gksrk gS rFkk 6 ls de gksrk gS] rc d{kdksa dh lEHko la[;k, D;k gksxh\

CHEMISTRY
(A) 7 (B) 9 (C) 11 (D) 13

14. In the decay process:


fuEu {k; ize esa %

A B C D
The incorrect answer is:
xyr mkj gSa&
(A) A and B are isobars (B) A and D are isotopes
(C) C and D are isobars (D) A and C are isotones
(A) A rFkk B leHkkfjd gSA (B) A rFkk D leLFkkfud gSA
(C) C rFkk D leHkkfjd gSA (D) A rFkk C leU;wVkWfud gSaA

15. Which of the following statement(s) is/are correct?


fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa\
(A) O > F > Na > Mg (order of size) (vkdkj
dk e)
(B) F >Cl N > Br > I (order of electronegativity) (oS|qr_.krk dk e)
(C) Cl> F > S > O (order of electron affinity) (bysDVkWu ca/kqrk dk e)
(D) N > O > Be > B > Na (order of ionization energy) (vk;uu tkZ dk e)

Space for Rough Work dPps dk;Z ds fy, LFkku

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16. The process required the absorption of energy:
,sls ize crkb, ftlesa tkZ ds vo'kks"k.k dh vko';drk gksrh gS&

CHEMISTRY
(B) S S
2
(A) ClCl
(C) Be Be (D) Ar Ar

17. Mark out the correct option.


(A) First ionization energy Ca > K (B) IInd ionization energy Na > Mg
3 2
(C) Electron affinity Se > S (D) Ionic radius P > S
lgh fodYi pqfu,
(A) izFke vk;uu tkZ Ca > K (B) IInd vk;uu tkZ Na > Mg
3 2
(C) bysDVkWu ca/kqrk Se > S (D) vk;fud f=kT;k P > S

18. Which of the following pairs are contains functional isomers?


fuEu esa ls dkSulk@dkSuls ;qXe f;kRed leko;oh;ksa dk gS?

(A) , (B) ,

(C) , (D) ,

Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
19.

Which alkyl group is/are attached directly to the cyclohexane ring in this compound?
(A) Isopropyl (B) t-Butyl (C) Isobutyl (D) Neopentyl
fn;s x;s ;kSfxd essa dkSulk@dkSuls ,fYdy lewg lkbDyksgSDlsu oy; ls lh/ks tqM+s gq, gS ?
(A) vkblksizksfiy (B) t-C;wfVy (C) vkblksC;wfVy (D) fu;ksisfUVy

20. Which of the following option correct for below compound?


O

O C CH3

Br

C O C2H5

O
O

(A) O C CH3 is principal functional group of compound


(B) The correct IUPAC name of given compound is Ethyl-4-bromo-5-ethanoyloxy cyclohex-3-ene-1-
carboxylate.
2
(C) 4 carbon atoms are sp hybridized
Space for
(D) Cyclo is used as secondary Rough
prefix Work
for given dPps dk;Z ds fy, LFkku
compound
Space for Rough Work dPps dk;Z ds fy, LFkku

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CHEMISTRY
uhps fn;s x;s ;kSfxd ds fy, fuEu es ls dkSuls fodYi lgh gSaA

CHEMISTRY
O

O C CH3

Br

C O C2H5

(A) ;kSfxd dk eq[; f;kRed lewg O C CH3 gSA

(B) fn;s x;s ;kSfxd dk lgh IUPAC uke ,fFky-4-czkseks-5-,Fksuk;yvkWDlh lkbDyksgsDl-3-bZu-1-dkcksZDlhysV gSa

(C) 4 dkcZu ijek.kq sp2 ladfjr gSaA

(D) ;kSfxd ds fy, f}rh;d iwoZyXu ds :i es lkbDyks iz;qDr gksrk gSA

Space for Rough Work dPps dk;Z ds fy, LFkku

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ADVANCED PATTERN ONLINE TEST-1 Code
P26-16
(AONT-1) XI 0
TARGET : JEE (MAIN+ADVANCED) 2017
DATE : 09-03-2017 | COURSE : JA**, JA, JB, 02JB
11. Since it is not possible to erase and correct pen filled 11. pawfd isu ls Hkjs x, xksys feVkuk vkSj lq/kkjuk laHko ugha gS
bubble, you are advised to be extremely careful while
blfy, vki lko/kkuh iwoZd vius mkj ds xksyksa dks HkjsaA
darken the bubble corresponding to your answer.
12. Neither try to erase / rub / scratch the option nor 12. fodYi dks u feVk,a@u Lsp djsa vkSj u gh xyr (X) fpUg
make the Cross (X) mark on the option once filled.
dks HkjsaA ORS dks dkVs u gh QkMs u gh xUnk ugha djsa rFkk
Do not scribble, smudge, cut, tear, or wrinkle the
ORS. Do not put any stray marks or whitener
dksbZ Hkh fu'kku ;k lQsnh ORS ij ugha yxk;sA
anywhere on the ORS.
13. If there is any discrepancy between the written data 13. ;fn ORS esa fdlh izdkj dh fy[ks x, vkadMksa rFkk xksys
and the bubbled data in your ORS, the bubbled data
fd, vkadMksa esa fojks/kkHkkl gS] rks xksys fd, vkadMksa dks gh
will be taken as final.
lgh ekuk tkosxkA
C. Question Paper Format C. iz'u&i=k dk izk:i
The question paper consists of one part. This part bl iz'u&i=k esa ,d Hkkx gSaA bl Hkkx esa nks [kaM gSaA
consists are two section.
14. Section 1 contains 10 questions. The answer to 14. [kaM 1 esa 10 iz'u gSaA izR;sd iz'u dk mkj 0 ls 9 rd nksuksa
each question is a single-digit integer, ranging from 'kkfey ds chp ,d ,dy vadh; iw.kkZad gSA
0 to 9 (both inclusive).
15. Section 2 contains 10 multiple choice questions. 15. [kaM 2 esa 10 cgqfodYi iz'u gaSA gj iz'u esa pkj fodYi (A),
Each question has Four choices (A), (B), (C) and (D) (B), (C) vkSj (D) gSa ftuesa ls ,d ;k ,d ls vf/kd fodYi
out of which ONE OR MORE THAN ONE is correct. lgh gSaA
D. Marking Scheme D. vadu ;kstuk
16. For each question in Section 1, you will be awarded 16. [kaM 1 esa gj iz'u esa dsoy lgh mkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to
dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (1) mark
will be awarded. (1) vad iznku fd;k tk;sxkA

17. For each question in Section 2, you will be awarded 17. [kaM 2 esa gj iz'u esa dsoy lgh mkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (1) mark
(1) vad iznku fd;k tk;sxkA
will be awarded.

Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :

I have read all the instructions and shall I have verified all the information filled by
abide by them the candidate.
eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk ijh{kkFkhZ }kjk Hkjh xbZ lkjh tkudkjh dks eSusa
vo'; ikyu d:xk@d:xhA tkp fy;k gSA
...................................... ......................................
Signature of the Candidate Signature of the Invigilator
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj

Resonance Eduventures Ltd. P26-16

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(CHEMISTRY)
O
2+
1. Fe [18 Ar] 9. Higher priority than C group
n=4
O
Mn2+ [18 Ar]
C lewg d h rqy uk esamPprj ojh;rk
n=5
Mn3+ [18 Ar] O O

n=4 CH = O, C O , C O H , SO3H,
2+
Cr [18 Ar] O O O O
n=4
C Cl , C NH2 , COC
Cr3+ [18 Ar]
10. Statements (A), (B) and (C) are correct.
n=3
(A) I and II are chain isomers
Ni2+ [18 Ar] (B) II and III have different functional group
(C) IV and V are metamers
n=2 (D) II and V are functional group isomers
Sol. d Fku (A), (B) o (C) lgh gSaA
2. Electron returns to n = 2. For H atom then line.belongs to
visible spectrum (A) I o II J` a[ky k leko;oh gSaA
(B) I, II o III fHkUu f ;kRed lewg j[krsgSaA
H- ijek.kqd sfy , by sDVkWu n = 2 esaiqu% y kSV vkrk gSA ckn esa
(C) IV o V e/;ko;oh gS aA
js[kk n`'; LisDVe lslEcfU/kr gksrh gS
(D) II o V f ;kRed leko;oh gS aA
5
4 11. (A) False: The configuration is 3d54s1
(B) False: The wavelength of gamma rays is of the order of 10
3 11
to 1016 m.
(C) True: In hydrogen atom the energy of an electron depends
2
only on the principal quantum numbers of the orbital which it
occupies.
n=1 (D) Flase: In xz plane these is no electron density of an
electron occupies 3dx2 y2 orbital.
14
N 24He 17 1 (A) vlR; % foU;kl 3d54s1 gSA
3. 7 8 O 1H
(B) vlR; : xkek fd j.kks ad h rjaxnS/;Z1011 m ls1016 d ksfV d h gSA
Then rc Z = 8
A = 17 (A Z) = 17 8 = 9 (C) lR; : gkbM kst u ijek.kqesaby sDVkWu d h t kZd {kd ] t ks;g
xzg.k d jrk gS] d h d soy eq[; Dok.Ve la[;k ij fuHkZj d jrk gSA
4. Li, C, O, Na, Al, S have ve Heg but Be, N, Ne O , Ar (D) vlR; : xz ry ea sby sDVkWu t ks3dx2 y2 d {kd xzg.k d jrk
have +ve Heg because of its stable configuration. gS] d k by sDVkWu ?kuRo ughagksrk gSA
Li, C, O, Na, Al, S _ .kkkRed Heg j[krk gSy sfd u Be, N,
Ne,

O , Ar /kukRed Heg j[krs gS D;ksafd bud k LFkk;h z2 ( Z )2
12. (A) Etotal = 13.6 ev and PE = 13.6 2 ev
foU;kl gksrk gSA n2 n2
(B) Etotal n
5. N, C, Be, O, S, Cl (C) Ring of dz2 orbital present in xy plane
(D) for given value of l total no. of orbital is (2 + 1),
6. (iv) Si < B < C < N is correct order of non metallic Azimuthal quantum numbers
character) (v/kkfRod vfHky {k.k d k lgh e gS)
z2 ( Z )2
(A) Ed qy = 13.6 2
ev rFkkPE = 13.6 2 2 ev
n n
CH3
(B) Ed qy n
2 3 4 8
(C) dz2 d {kd d h oy ; xy ry esamifLFkr gksrh gSA
7. (D) d sfn, x;seku d sfy , d {kd d h d qy la[;k (2 + 1) gS,
sp2
1 sp3 5 6 7 f}xa
'kh Dok.Ve la[;k
CH3
13.
No. of orbitals
8. (I), (IV), (V), (VI) Ref Notes. uks
V~l ns[ksA (n + l) =
d {kd ksad h la[;k
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(3 + 1) = 4 3p 3 nh xbZlajpuk esavkblksizksfiy CH(CH ) lewg vuqifLFkr gS
3 2
(3 + 2) = 5 3d 5
(4 + 0) = 0 4s 1
O
(4 + 1) = 5 4p 3
(5 + 0) = 5 5s 1
O C 2CH3
Total orbitals sp
13 20. 5 6
d qy d {kd Br
4
sp2
3 sp2
sp2 1 C O CH2 CH3
2
A A 4 A4 A4
14. ZX
Z2 X
Z 1 X
Z X O
(A) and (D) are isotopes (B) is correct IUPAC name
(A) rFkk(D) leLFkkfud gSaA (C) 4C atoms sp2 hybridized
O
16. (A) Addition of electron evoled. Energy
(B) Addition of II electron is endothermic process O C 2CH3
sp
(C) Stable configuration like Be and Ar required energy Sol. 5 6
(A) by s
DVkWu
d k ;ksx] t kZfu"d kfl r Br
4
sp2
(B) II by s
DVkWu
d k ;ksx "ek'kks"kh iz e gSA 3 sp2
sp 2 1 C O CH2 CH3
(C) Be rFkkAr d sleku LFkk;h foU;kl] t kZd h vko';d rk 2

O
17. (A) IE, CA > IE, K
(B) IE, Mg > IE, Na due to stable configuration of Mg but (B) lghIUPAC uke gS A
removal of second electron is difficult in case of Na due to (C) 4C ijek.kqsp2 la
d fjr gSaA
stable configuration of Na+ ion
(C) Electron affinity of (magnitude) S > Se
(D) Order of size P3 > S2 (iso electronic species)
(A) IE, Ca > IE, K
(B) IE, Mg > IE, Na; Mg d sLFkk;h foU;kl d sd kj.k y sfd u
Na d h fLFkfr es af}rh; by sDVkWu d k fu"d klu d fBu gksrk gSA
Na+ vk;u d sLFkk;h foU;kl d sd kj.kA
(C) by s
DVkWu ca/kqrk e ifjek.kS > Se
(D) vkd kj d k e P3 > S2 (leby s DVkWfud Lih'kht )

18. 2 & 3 amines are functional isomers of each other.


Options (1) does not have same molecular formula.
2 o 3 ,ehu vkil es af ;kRed l eko;oh gksrsgSA fod Yi
(1) es
av.kql w=k leku ughagSA

t-Butyl

neopentyl

19.
isobutyl
isopropyl CH(CH3)2 group is absent in this
structure

t-Butyl

neopentyl

gy .
isobutyl

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CHEMISTRY
1. (3) 2. (3) 3. (9) 4. (6) 5. (6) 6. (5) 7. (8)

8. (4) 9. (7) 10. (3) 11. (ABD) 12. (AD) 13. (D) 14. (AD)

15. (BCD) 16. (BCD) 17. (ABD) 18. (BC) 19. (BCD) 20. (BC)

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