This Key & Hints paper contains 12 Pages GT-12 PAPER-2_05 -02-11

CODE : ORANGE
28721/QB/
VIJ-
ONCS-C /
IITJEE /
22-1-
2011 /
IITJEE

NARAYANA IIT ACADEMY

INDIA
IITJEE MODEL Exam Date:05-2-2011

Time :3:00
GRAND TEST-12 Max Marks :243
PAPER II
ID.NO :

ENGLISH MEDIUM - KEY

MATHEMATICS
1) B 2) C 3) C 4) C 5) D 6) B
7) A 8) A 9) C 10) A 11) C 12) D
13) A 14) A 15) C 16) C 17) A 18) D
19) C 20) (A) (q) 21) (A) (s) 22) (A) (s)
(B) (p) (B) (q) (B) (s)
(C) (s) (C) (p) (C) (s)
(D) (r) (D) (q) (D) (q)

PHYSICS
23) B 24) A 25) D 26) D 27) C 28) C
29) D 30) C 31) B 32) D 33) A 34) D
35) D 36) A 37) C 38) A 39) B 40) A
41) C 42) A-R 43) A-P,Q,S 44) A-P,R,S
B-R B-P,S B-P,R,S
C-P C-R,S C-R
D-Q D-Q,S D-R

CHEMISTRY
45) A 46) A 47) B 48) C 49) C 50) C
51) C 52) C 53) A 54) D 55) C 56) C
57) B 58) C 59) D 60) D 61) D 62) C
63) D 64) A p, q, s 65) (A r) 66) (A p, s)

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B p, q, r (B s) (C (B q) (C
C p, q, r p) q)
D p, q, r (D q) (D q, r)

HINTS
MATHEMATICS
1)
Area of triangle

but

Area
2)
tossing a coin, die, score 3

3)
x intercept is

Let

4) Let be the number of one rupee coins then the number of 50 paise coins may be even
or odd. If number of 50 paise coins is then number of 25 paise coins must be a
multiple of 4.
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where
Number of ways
If number of 50 paise coins is then 25 paise coins must be of the form

Number of ways
Number of selections
5)

Number of hyperbolas
6)
We have
But
7)

8)
where

9) Image of one focus w.r.t the tangent lies on the line by solving the tangent and

we get the point of contact as

10)

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11) Conceptual
12) Conceptual
13) Conceptual
P)
14) The scores of can be reached in the following two mutually exclusive events
i) by throwing head when the score is
ii) by throwing tail when score is

15)

But and a score of 2 can be obtained by throwing a tail at a single toss or a head at
the first toss as well as second toss.

16)

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P)
17)

18)

19)
Area
20) Conceptual
21) Conceptual
22) Conceptual

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PHYSICS
23)
Force required to move m2 = stretch in the spring (1)

now for m1 : - (by work energy theorem) .(2)

solve (1) and (2)
24)

25) conceptual
26)

The acceleration vector shall change the component of velocity u1

Radius of curvature means v is minimum and an is maximum. This is at point P when
component of velocity parallel to acceleration vector becomes zero, that is ua = 0

27) The free body diagram of block in fig. is as shown. N = mg +

P cos and acceleration of
block

Hence P does not change acceleration

28) Supplying the current by joining C and D we get

I = 3A

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After distributing current in different branches we get current through CD

29)

and

30)
For refraction at 1st surface .. (1)

For refraction at 2nd surface (2)

From (1) and (2) we get

31) C.A.M. at P and Q, we have

(1)
C.M.E at P and Q, we have

(2)
From (1) and (2) we have
r = 3.323 R
h = r R = 2.323 R
32) Conceptual
33) Conceptual
34) Conceptual
35) Conceptual
P)
36) Once the switch is closed, the capacitor is charged through resistance R 1 by the batterys
emf. Time constant is C.
37)
Using

= 10.4 V
38) At any moment in the circuit

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= 1.6 V
P)
39)

Net force on the loop =

Net force on the loop

40)

Net force on the loop =

Net force on the loop

41)

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Net force on the loop =

Net force on the loop

42)

Given

43) Conceptual
44) Solve using proper steps

CHEMISTRY
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45) Conceptual
46) Conceptual
47) Conceptual
48) Conceptual
49) Conceptual
50)
IE1 of N2 is larger than that of O2 because, as per MOT, HOMO of N2 is a BMO i.e
while that of O2 is an ABMO i.e. t is easier to remove an electron from an
ABMO than to remove and electron from a BMO. Again, as per MOT an electron is
always
removed from the ABMO while it is added to the LUMO. However, if the HOMO is
partly
filled, then the added electron goes to HOMO instead of LUMO. Both in the case of O 2
and
N2, the added electron goes to ABMO and hence the addition lowers the bond order of O2
from 2 to 1.5 and of N2 from 3 to 2.5. In both the cases, addition of an electron lowers the
stability of the respective species. But in case O2, the addition of an electron leads to
lowering of the spin while in case of N2 the addition raises the spin. Hence, addition of an
electron to N2 is more energy consuming than that needed for O2 . So, EA of O2 is higher
than N2. EA is conventionally measured in terms of energy released.
Electronegativity of an atom is directly proportional to its bond multiplicity. Because, the
higher the bond multiplicity smaller is the size and hence more is the electronegativity.
This is why EN of Carbon atom in different hybrid state is
Both in N2 and CO, the bond order is 3. Still then the bond energy of the two species
differs
because radii of Rather, the correct order of these radii is
(Radii along period always decreases) Therefore, CO is slightly less stable than N2.

51) Conc. of

Ksp of

52) 2
[ Cl ]
Cl2 2Cl (fast) Kc1 =
Cl
2

[ COCl ]
Cl CO COCl (fast) Kc 2 =
[ Cl ][ CO ]

COCl + Cl2 COCl2 + Cl (slow)

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Hence,

rate k 1 Cl2 Kc2 CO Kc1 Cl2

rate k 1.Kc2 . Kc1 Cl2 CO

3/2 1

k 1K c2 K c1 k another constant
53) T = K molality i
f f

Hence (A) is correct.

54) NCl3 hydrolyses to give NH3 and HOCl while PCl3 hydrolyses to give H3PO3 and HCl.
Between, HOCl and H3PO3 (hypophosphorus acid), the former is a much stronger oxidant.
HCl is not at all an oxidant because of the lowest oxidation state of halogen is -1. NH 3 is
also not an oxidant since N is in its lowest state of -3. The oxidising ability of HOCl and
H3PO3 have nothing to do with presence or absence of vacant orbital in the central atoms.
Phosphorus had vacant 3d orbital while nitrogen has no vacant orbital.
55) AgCl, Cu2Cl2, Hg2Cl2 and PbCl2 do not respond chromyl chloride test dut to least
ionization to furnish Cl ion for the test.
56) Conceptual
57) Conceptual
P)
58) Two non-metallic pnicogens are N and P (A and B). Very common oxides formed them
are (C,D,E,F,G and H) N2O, NO, N2O3, NO2, N2O5, P4O6 and P4O10.
Statement (i): The oxide D on heating to 4400C gives B (N2 or P4) directly. This implies D
cannot be P4O10 because it doesnot decompose so easily. P 4O6 on heating decomposes to
red P4 and in air P4O6 also readily changes to P4O10. Decomposition temperature of P4O6 is
also 4400C. So, B is P4, A is N2, D is P4O6 and G is P4O10. It may be noted that all oxides of
nitrogen decompose to N2 but much above 4400C. Now, It can be concluded that C, E, F
and H are all oxides of nitrogen.
Statement (ii): G being a powerful dehydrating agent converts conc HNO3 to N2O5. So, H
is N2O5.
Statement (iii) & (v): C reacts with P4 at 6100C to give P4O6 and N2 and also P4O10 and N2.
C with red hot Cu gives N2. This implies C is N2O.
Statement (iv): P4O6 hydrolyses to H3PO3 which on heating to 2000C gives H3PO4 and PH3
gas which burns with O2 to give P4O10.
Statement (Vi) and (vii): E and F are oxides of nitrogen. Since E on exposure to air
gives F, So E is NO and F is NO 2. NO and NO2 condenses to N2O3 which hydrolyses to
HNO2. Further HNO2 disproportionates to HNO3 with evolution of NO gas. NO2 also
disproportionates to HNO3 with evolution of NO gas.
C=N2O is neutral, B=P4 can be made from Ca3(PO4)2, SiO2, and Coke, D=P4O6
hydrolyses to H3PO3 which reduces AgNO3 to Ag (Black). G=P4O10 produces sugar
charcoal with sugar. Most acidic of all the oxides above is N2O5= H.

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59)
60)
P)
61) Conceptual
62) Conceptual
63) Conceptual
64) All halogens react with NaOH. Fluorine reacts with NaOH in a different way. F2 with
conc. NaOH gives off O2 while with dil. NaOH it gives off OF2 gas. Similarly, with hot
and conc. NaOH, Cl2, Br2 and I2 give NaXO3 & NaX and with cold and dil. NaOH they
give NaX and NaOX. Fluorine does not form due to absence of vacant d-orbital,
other halogens do. F2 gas is pale yellow, Cl2 is greenish, Br2 is reddish brown and I2 is
dark violet in colour
65) Conceptual
66) A p, s
B p, q
Cq
D q, r
Crystals class Axial distances Angles
Cubic
Tetragonal
Orthorhombic
Hexagonal
Trigonal and
rhombohedral a = b = c
Monoclinic
Triclinic

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